{"id":202363,"date":"2020-05-25T06:33:07","date_gmt":"2020-05-24T22:33:07","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=202363"},"modified":"2020-05-24T16:33:28","modified_gmt":"2020-05-24T08:33:28","slug":"%e5%8e%a6%e5%a4%a7-matter%ef%bc%9a%e6%9c%ba%e5%99%a8%e5%ad%a6%e4%b9%a0%e6%8c%87%e5%af%bc%e7%ba%b3%e7%b1%b3%e7%ba%a7mofs%e7%9a%84%e5%bd%a2%e6%80%81%e8%b0%83%e6%8e%a7","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=202363","title":{"rendered":"\u53a6\u5927 Matter\uff1a\u673a\u5668\u5b66\u4e60\u6307\u5bfc\u7eb3\u7c73\u7ea7MOFs\u7684\u5f62\u6001\u8c03\u63a7"},"content":{"rendered":"

\u3010\u6587\u7ae0\u4eae\u70b9\u3011<\/strong><\/p>\n

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\n \"\"\uff08A\uff09\u5229\u7528\u5f69\u8272\u7ebf\u8868\u793a\u7684\u5b9e\u9a8c\u6570\u636e\uff1b<\/p>\n

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\n \"\"\uff08A\uff09\u5728\u76f8\u56fe\u4e0a\uff0c\u5229\u7528\u989c\u8272\u7f16\u7801\u7684[Hf12<\/sub>]\/[Hf6<\/sub>]\uff08\u5f52\u4e00\u5316\u4e3a0-1\uff09\u7684\u5206\u5e03\u53ca\u5176\u4e0e\u4e0d\u540c\u76f8\u533a\u7684\u5173\u7cfb\uff0c\u7528\u4e0d\u540c\u989c\u8272\u7684\u7ebf\u6761\u6807\u8bb0\uff1b<\/p>\n

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\n \"\"\uff08A\uff09hxl-UiO-67\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08B\uff09\u57fa\u4e8e498\u4e2a\u6837\u672c\u4e2d\u7684228\u4e2a\u7684\u6d4b\u8bd5\u96c6\u5bf9\u9884\u6743\u91cd\u8fdb\u884c\u5fae\u8c03\u540e\uff0c\u901a\u8fc7Mask R-CNN\u8bc6\u522b\u7ad9\u7acb\u7eb3\u7c73\u7247\u5e76\u4ee5\u77e9\u5f62\u6807\u51fa\uff1b<\/p>\n

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\n \"\"\uff08A-B\uff09hcp-UiO-67\u5728UiO-67\u7684\uff08111\uff09\u8868\u9762\u4e0a\u7684\u5916\u5ef6\u751f\u957f\u53ef\u6709\u6548\u9501\u5b9a\u8868\u9762\uff1b<\/p>\n

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\uff08F\uff09\u5728UiO-67\u7684\uff08110\uff09\u8868\u9762\u4e0a\u5916\u5ef6\u751f\u957f\u7532\u9178\u76d0\u53ef\u6709\u6548\u9501\u5b9a\u8868\u9762\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u7814\u7a76\u4eba\u5458\u4eceHf4+<\/sup>\u548cBPDC\u914d\u4f53\u5408\u6210\u7eb3\u7c73MOFs\u7684\u6761\u4ef6\u51fa\u53d1\uff0c\u7cfb\u7edf\u5730\u7814\u7a76\u63ed\u793a\u4e86\u76f8\u5173MOFs\u6676\u4f53\u751f\u957f\uff0c\u5229\u7528\u673a\u5668\u5b66\u4e60\u6280\u672f\u8fdb\u884c\u4e86\u6570\u636e\u5206\u6790\u3002\u57fa\u4e8e\u201c\u51b3\u7b56\u6811\u201d\u7684\u5206\u6790\u4ece\u4f17\u591a\u53d8\u91cf\u4e2d\u63d0\u53d6\u4e86\u56fa\u5b9a\u6e29\u5ea6\u4e0b\u4e24\u4e2a\u6700\u5173\u952e\u7684\u56e0\u5b50H2<\/sub>O\u548cHCO2<\/sub>H\uff0c\u4ee5\u51b3\u5b9ahxl-UiO\u7684\u76f8\u5206\u5e03\u548c\u539a\u5ea6\u3002\u901a\u8fc7\u539f\u4f4d\u6db2\u4f53TEM\u548cMS\u89c2\u5bdf\u5408\u6210\u6eb6\u6db2\u4e2d\u7684Hf6<\/sub>\u548cHf12<\/sub> SBUs\uff0c\u652f\u6301\u5f62\u6210SBUs\uf0e0\u5c01\u7aef\u57fa\u56e2\u7684\u914d\u4f53\u4ea4\u6362\uf0e0\u4ea4\u8054\u6210\u56fa\u4f53\u7f51\u7edc\u7684\u6676\u4f53\u751f\u957f\u673a\u5236\u3002\u901a\u8fc7\u4ed4\u7ec6\u5206\u6790\u76f8\u56fe\u4ee5\u53ca\u6676\u4f53\u5f62\u6001\u4e0e\u6676\u4f53\u751f\u957f\u6761\u4ef6\u4e4b\u95f4\u7684\u5173\u7cfb\uff0c\u53d1\u73b0\u5728\u6eb6\u6db2\u4e2d\u5f62\u6210Hf12<\/sub> SBUs\u7684\u91cd\u8981\u6027\u3002\u6b64\u5916\uff0c\u8fd8\u53d1\u73b0hxl-UiO\u7684\u539a\u5ea6\u548c\u6a2a\u5411\u5c3a\u5bf8\u4f1a\u968f\u7740\u6eb6\u6db2\u4e2d\u914d\u4f53\u7684\u6d53\u5ea6\u7684\u5347\u9ad8\u800c\u589e\u52a0\u3002\u636e\u6b64\uff0c\u7814\u7a76\u4eba\u5458\u8bbe\u8ba1\u4e86\u5408\u6210\u5e8f\u5217\u6765\u521b\u5efa\u590d\u6742\u5f62\u72b6\u7684MOF\u7eb3\u7c73\u6676\u4f53\u3002\u8fd9\u4e9bnMOFs\u7531\u4e8e\u5e95\u7269\u6269\u6563\u7684\u4e0d\u540c\u800c\u5448\u73b0\u51fa\u4e0d\u540c\u7684\u8868\u89c2\u50ac\u5316\u6d3b\u6027\u3002\u4ece\u8be5\u5de5\u4f5c\u4e2d\u83b7\u5f97\u7684\u77e5\u8bc6\u52a0\u6df1\u4e86\u5bf9MOF\u751f\u957f\u7684\u7406\u89e3\uff0c\u5e76\u4e3a\u8bbe\u8ba1\u4e0d\u540c\u5f62\u6001\u7684nMOFs\u63d0\u4f9b\u4e86\u6307\u5bfc\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aMachine-Learning-Guided Morphology Engineering of Nanoscale Metal-Organic Frameworks<\/strong>\uff08Matter<\/em>, 2020<\/strong>, DOI: 10.1016\/j.matt.2020.04.021\uff09<\/p>\n

\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb<\/strong><\/p>\n

\u53a6\u95e8\u5927\u5b66\u6c6a\u9a8b\u56e2\u961f<\/strong>\u81f4\u529b\u4e8e\u5f00\u53d1\u4e00\u7c7b\u4e8c\u7ef4\u91d1\u5c5e\u6709\u673a\u6846\u67b6 (Metal-Organic Frameworks = MOFs) (Angew. Chem. Int. Ed.<\/em> 2016<\/strong>, 55,4962\uff1bChinese Journal of Chemistry<\/em> 2018<\/strong>, 36, 754)\uff0c\u4ed6\u4eec\u79f0\u4e4b\u4e3a \u201c\u91d1\u5c5e\u6709\u673a\u5355\u5c42\u201d (Metal-Organic Layer = MOL)\uff0c\u8c10\u97f3\u4e2d\u6587\u7684\u201c\u819c\u201d\u3002MOL\u548cMOF\u7531\u6709\u673a\u914d\u4f53\u548c\u91d1\u5c5e\u8282\u70b9\u914d\u4f4d\u8fde\u63a5\u5f62\u6210\u7f51\u7edc\u7ed3\u6784\uff0c\u53ef\u6709\u5e8f\u7ec4\u88c5\u6709\u673a\u5206\u5b50\uff0c\u5728\u5fae\u89c2\u5c3a\u5ea6\u4e32\u8054\u4e0d\u540c\u529f\u80fd\u7ec4\u5206\u3002\u6c6a\u9a8b\u56e2\u961f\u5e0c\u671b\u4ee5\u8fd9\u7c7b\u4e8c\u7ef4\u6750\u6599\u4e3a\u57fa\u7840\uff0c\u4e0e\u56ca\u6ce1\u7ed3\u6784\u7ed3\u5408\uff0c\u7ec4\u88c5\u201c\u4eba\u9020\u53f6\u7eff\u4f53\u201d\u3002MOL\u7684\u8d85\u8584\u4e8c\u7ef4\u7ed3\u6784\u53ef\u534f\u52a9\u4e24\u4fa7\u7684\u7535\u8377\u5206\u79bb\uff0cMOL\/MOF\u4e0a\u8bbe\u8ba1\u7684\u9ad8\u6548\u50ac\u5316\u4f4d\u70b9\u53ef\u5f00\u5c55\u50a8\u80fd\u53cd\u5e94(J. Am. Chem. Soc.<\/em> 2019<\/strong>, 141, 44, 17875\uff1bNature Catalysis<\/em>, 2019<\/strong>, 2, 709-717\uff1bJ. Am. Chem. Soc.<\/em> 2019<\/strong>, 141, 17875\uff1bJ. Am. Chem. Soc.<\/em> 2017<\/strong>, 139, 3834)\uff0c\u9ad8\u6548\u7684\u80fd\u91cf\u8f6c\u79fb\u53ef\u5c06\u5149\u80fd\u4f20\u9012\u81f3\u53cd\u5e94\u4e2d\u5fc3(J. Am. Chem. Soc.<\/em>, 2017<\/strong>, 139, 7020)\uff0cMOL\u7684\u8868\u9762\u4fee\u9970\u5316\u5b66(Angew. Chem. Int. Ed.<\/em> 2017<\/strong>, 56, 9740) \u4f7f\u5f97\u591a\u4e2a\u529f\u80fd\u6a21\u5757\u80fd\u6709\u5e8f\u7ec4\u88c5\u3001\u534f\u540c\u8fd0\u4f5c\uff0c\u5b8c\u6210\u590d\u6742\u7684\u529f\u80fd\u3002<\/p>\n

\u672c\u6587\u7531CQR\u7f16\u8bd1\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1atougao@cailiaoren.com.<\/p>\n

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