{"id":202434,"date":"2020-06-01T06:12:05","date_gmt":"2020-05-31T22:12:05","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=202434"},"modified":"2020-05-31T22:12:46","modified_gmt":"2020-05-31T14:12:46","slug":"%e8%8b%8f%e5%b7%9e%e5%a4%a7%e5%ad%a6uiuc%ef%bc%9a%e9%80%9a%e8%bf%87n-%e7%be%a7%e5%9f%ba%e7%8e%af%e5%86%85%e9%85%b8%e9%85%90%e7%9a%84%e5%bf%ab%e9%80%9f%e8%81%9a%e5%90%88%e5%88%b6%e5%a4%87%e8%81%9a","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=202434","title":{"rendered":"\u82cf\u5dde\u5927\u5b66&UIUC\uff1a\u901a\u8fc7N-\u7fa7\u57fa\u73af\u5185\u9178\u9150\u7684\u5feb\u901f\u805a\u5408\u5236\u5907\u805a\u591a\u80bd\u5355\u5206\u5b50\u80f6\u675f"},"content":{"rendered":"

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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

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\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\u3001\u805a\u5408\u4ea7\u7269\u5206\u5b50\u91cf\u53ca\u5206\u6563\u5ea6\u8868\u5f81<\/strong><\/p>\n

\u5728\u5206\u5b50\u7684\u8bbe\u8ba1\u548c\u5408\u6210\u4e0a\uff0c\u9996\u5148\u9009\u62e9\u6811\u72b6\u5206\u5b50PAMAM\u4f5c\u4e3a\u5927\u5206\u5b50\u5f15\u53d1\u5242\uff0c\u8c37\u6c28\u9178\u82c4\u916fNCA\u4f5c\u4e3a\u6a21\u578b\u5355\u4f53\u5206\u5b50\u8fdb\u884c\u805a\u5408\u3002\u805a\u5408\u53cd\u5e94\u5728DCM\u6eb6\u5242\u4e2d\u8fdb\u884c\uff0c\u4ea7\u7269\u7684\u5206\u5b50\u91cf\u548c\u5206\u6563\u5ea6\u901a\u8fc7SEC\u8868\u5f81\u5f97\u5230\u3002\u7ed3\u679c\u663e\u793a\uff0c\u968f\u7740\u5927\u5206\u5b50\u5f15\u53d1\u5242\u8868\u9762\u6c28\u57fa\u7684\u53d8\u5316\uff0c\u6240\u5f97\u5230\u7684\u5355\u5206\u5b50\u80f6\u675f\u5206\u5b50\u91cf\u80fd\u591f\u4e0e\u9884\u671f\u503c\u76f8\u543b\u5408\uff0c\u5e76\u4e14\u5206\u6563\u5ea6\u8f83\u4f4e\uff1b\u800c\u91c7\u7528\u540c\u4e00\u5f15\u53d1\u5242\u6539\u53d8\u5355\u4f53\u6bd4\u4f8b\u65f6\uff0c\u4e5f\u80fd\u5f97\u5230\u9884\u671f\u5206\u5b50\u91cf\u7684\u4f4e\u5206\u6563\u5ea6\u4ea7\u7269\uff0c\u8fd9\u663e\u793a\u4e86\u8be5\u805a\u5408\u65b9\u6cd5\u5177\u6709\u6d3b\u6027\u7279\u5f81\u3002<\/p>\n

\"\"<\/p>\n

\uff08a\uff09 PAMAM\u548cBLG-NCA\u7684\u5316\u5b66\u7ed3\u6784\u3002<\/p>\n

\uff08b\uff09 \u4e0d\u540cPAMAM\u5f15\u53d1\u5242\u5408\u6210\u805a\u5408\u7269\u7684GPC\u793a\u8e2a\u3002<\/p>\n

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\uff08d\uff09\u5728DCM\u4e2d\u805a\u5408\u7684G5-g-PBLG\u5728[M]0\/[I]0\u6bd4\u4e3a25\uff5e3200\u65f6\u7684\u5206\u5b50\u91cf\u548c\u5206\u6563\u6027\u3002<\/p>\n

\u56fe\u4e8c\u3001\u4e0d\u540c\u624b\u6027\u5355\u4f53\u805a\u5408\u7684\u5355\u4f53\u8f6c\u5316\u60c5\u51b5<\/strong><\/p>\n

\u5355\u4f53\u8f6c\u5316\u7387\u65b9\u9762\uff0c\u901a\u8fc7\u5085\u91cc\u53f6\u53d8\u6362\u7ea2\u5916\u65b9\u6cd5\u8fdb\u884c\u4e86\u8ddf\u8e2a\u89c2\u6d4b\u3002<\/p>\n

\"\"<\/p>\n

\uff08a\uff09FT-IR\u5149\u8c31\u663e\u793a\u4e86DCM\u4e2dG5\u5f15\u53d1\u7684BLG-NCA\u7684\u8f6c\u5316\u3002<\/p>\n

\uff08b\uff09\u4e0d\u540cPAMAM\u5f15\u53d1\u5242\u5728[M]0\/[I]0\u6bd4\u503c\u4e3a100\u65f6\u5f15\u53d1BLG-NCA\u7684\u8f6c\u5316\u3002<\/p>\n

\uff08c\uff09G5\u5728\u4e0d\u540c[M]0\/[I]0\u6bd4\u7387\u4e0b\u542f\u52a8\u7684BLG-NCA\u8f6c\u6362\u3002<\/p>\n

\uff08d\uff09\u7531G5\u5728[M]0\/[I]0\u6bd4\u503c\u4e3a100\u65f6\u542f\u52a8\u7684BLG-NCA\u3001BDG-NCA\u548cBDLG-NCA\u7684\u8f6c\u6362\u3002<\/p>\n

\u56fe\u4e09\u3001\u4e0d\u540c\u5206\u5b50\u91cf\u7684\u5355\u5206\u5b50\u80f6\u675f\u7c92\u5f84\u53ca<\/strong>cryo-TEM<\/strong>\u56fe\u50cf<\/strong><\/p>\n

\u5728\u5bf9\u805a\u5408\u4ea7\u7269\u5355\u5206\u5b50\u80f6\u675f\u7684\u7c92\u5f84\u8868\u5f81\u4e2d\uff0c\u5b9e\u9a8c\u53d1\u73b0\u7531\u4e0d\u540c\u6811\u72b6\u5206\u5b50\u5f15\u53d1\u5242\u805a\u5408\u800c\u6210\u7684DLS\u6d4b\u5b9a\u7c92\u5f84\u5206\u5e03\u90fd\u6781\u7a84\uff0c\u5e76\u4e14\u5927\u5c0f\u4e0e\u5206\u5b50\u91cf\u5bc6\u5207\u76f8\u5173\uff0c\u8fd9\u8bf4\u660e\u6b64\u805a\u5408\u65b9\u6cd5\u53ef\u4ee5\u901a\u8fc7\u63a7\u5236\u805a\u5408\u5ea6\u5bf9\u80f6\u675f\u7c92\u5f84\u8fdb\u884c\u7cbe\u786e\u8c03\u63a7\u3002\u51b7\u51bb\u7535\u955c\u56fe\u50cf\u5219\u8fdb\u4e00\u6b65\u5c55\u793a\u4e86\u80f6\u675f\u89c4\u6574\u4e14\u5747\u4e00\u7684\u7ed3\u6784\u3002<\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u5404\u79cd\u5355\u5206\u5b50\u80f6\u675f\u7684\u7c92\u5f84\u5206\u5e03\u3002<\/p>\n

\uff08b\uff09G5-g-PBLG400\u80f6\u675f\u7684\u653e\u5927\u7684DLS\u76f4\u65b9\u56fe\u3002<\/p>\n

\uff08c\uff09\u7531DLS\u6d4b\u5b9a\u7684\u5355\u5206\u5b50\u80f6\u675f\u7684\u76f4\u5f84\u548c\u5206\u6563\u6027\u3002<\/p>\n

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\u3010\u7ed3\u8bba\u5c55\u671b\u3011<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1aUnimolecular Polypeptide Micelles via Ultrafast Polymerization of N-Carboxyanhydrides<\/a> (J. Am. Chem. Soc.<\/em>, 2020<\/strong>, DOI: 10.1021\/jacs.0c01173)<\/p>\n

\u8bfe\u9898\u7ec4\u7b80\u4ecb\uff1a<\/strong><\/p>\n

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