{"id":203412,"date":"2020-06-11T08:23:27","date_gmt":"2020-06-11T00:23:27","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=203412"},"modified":"2020-06-11T08:23:27","modified_gmt":"2020-06-11T00:23:27","slug":"%e6%9c%80%e6%96%b0nature%e5%85%89%e8%af%b1%e5%af%bc%e9%85%b6%e5%82%ac%e5%8c%96%e7%9a%84%e5%88%86%e5%ad%90%e9%97%b4%e8%87%aa%e7%94%b1%e5%9f%ba%e5%8a%a0%e6%b0%a2%e7%83%b7%e5%9f%ba%e5%8c%96","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=203412","title":{"rendered":"\u6700\u65b0Nature:\u5149\u8bf1\u5bfc\u9176\u50ac\u5316\u7684\u5206\u5b50\u95f4\u81ea\u7531\u57fa\u52a0\u6c22\u70f7\u57fa\u5316"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u9176\u5728\u975e\u5bf9\u79f0\u5408\u6210\u4e2d\u626e\u6f14\u7740\u91cd\u8981\u7684\u89d2\u8272\uff0c\u800c\u4e00\u822c\u53ea\u6709\u5929\u7136\u9176\u53cd\u5e94\u624d\u80fd\u53c2\u4e0e\u8fd9\u7c7b\u5408\u6210\u3002\u8fd1\u6765\uff0c\u5c3d\u7ba1\u5149\u50ac\u5316\u7684\u53d1\u5c55\u6fc0\u53d1\u4e86\u4eba\u4eec\u5bf9\u9176\u7684\u65b0\u578b\u6d3b\u6027\u7684\u63a2\u7d22\uff0c\u5149\u8bf1\u5bfc\u9176\u50ac\u5316\u8fd8\u672a\u88ab\u7528\u4e8e\u4e24\u5206\u5b50\u7684\u8026\u5408\u53cd\u5e94\u3002\u8fd9\u5176\u4e2d\u6700\u5927\u7684\u969c\u788d\u5728\u4e8e\u9176\u7684\u5185\u751f\u6027\u5149\u6d3b\u6027\u8f83\u5dee\u4ee5\u53ca\u65e0\u6cd5\u63a7\u5236\u81ea\u7531\u57fa\u4e2d\u95f4\u4ea7\u7269\u3002<\/p>\n<p>\u3010<strong>\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n<p><strong>\u7f8e\u56fd\u4f0a\u5229\u8bfa\u4f0a\u5927\u5b66\u5384\u5df4\u7eb3-\u9999\u69df\u5206\u6821\u7684<\/strong><strong>\u8d75\u60e0\u6c11<\/strong>\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u62a5\u9053\u4e86\u53ef\u89c1\u5149\u8bf1\u5bfc\u7684ene-\u8fd8\u539f\u9176\u50ac\u5316\u7aef\u70ef\u70c3\u7684\u5206\u5b50\u95f4\u81ea\u7531\u57fa\u70f7\u57fa\u5316\u65b9\u6cd5\u3002\u673a\u7406\u7814\u7a76\u8868\u660e\uff0c\u5728\u9176\u6d3b\u6027\u4f4d\u70b9\u5f62\u6210\u7684\u57fa\u8d28\/ene-\u8fd8\u539f\u9176\u590d\u5408\u7269\u89e6\u53d1\u4e86\u5bf9\u6620\u9009\u62e9\u6027\u7684\u5149\u8bf1\u5bfc\u81ea\u7531\u57fa\u53cd\u5e94\u3002\u8fd9\u79cd\u65b9\u6cd5\u5bf9\u6570\u79cd\u5e26\u03b3-stereocentre\u7684\u7fb0\u57fa\u5316\u5408\u7269\u5747\u5177\u6709\u4f18\u5f02\u7684\u4ea7\u91cf\uff08\u8fbe\u523099%\uff09\u548c\u5bf9\u6620\u9009\u62e9\u6027\uff08\u5bf9\u6620\u4f53\u8fc7\u91cf99%\uff09\uff0c\u7a81\u7834\u4e86\u5316\u5b66\u50ac\u5316\u7684\u5c40\u9650\u30022020\u5e7406\u670808\u65e5\uff0c\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201c<strong>Photoenzymatic enantioselective intermolecular radical hydroalkylation<\/strong>\u201d\u7684\u6587\u7ae0\u5728\u7ebf\u53d1\u8868\u5728<strong>Nature<\/strong>\u4e0a\u3002<\/p>\n<p>\u3010<strong>\u56fe\u6587\u5bfc\u8bfb<\/strong>\u3011<\/p>\n<p><strong>\u56fe1 <\/strong><strong>\u50ac\u5316\u7684\u975e\u5bf9\u79f0\u81ea\u7531\u57fa\u70f7\u57fa\u5316<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-203413\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/06\/1-18.jpg\" alt=\"\" width=\"426\" height=\"549\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/06\/1-18.jpg 426w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/06\/1-18-233x300.jpg 233w\" sizes=\"(max-width: 426px) 100vw, 426px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>2<\/strong> <strong>\u53cd\u5e94\u8fc7\u7a0b\u3001\u5b9e\u9a8c\u63a7\u5236\u4ee5\u53ca\u5206\u6790<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-203414\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/06\/2-18.jpg\" alt=\"\" width=\"529\" height=\"549\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/06\/2-18.jpg 529w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/06\/2-18-289x300.jpg 289w\" sizes=\"(max-width: 529px) 100vw, 529px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>3<\/strong> <strong>\u63a8\u6d4b\u7684\u53cd\u5e94\u5faa\u73af<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-203417\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/06\/3-19.jpg\" alt=\"\" width=\"600\" height=\"390\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/06\/3-19.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/06\/3-19-300x195.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>4 <\/strong><strong>\u673a\u7406\u7814\u7a76<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-203416\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/06\/4-20.jpg\" alt=\"\" width=\"207\" height=\"524\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/06\/4-20.jpg 207w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/06\/4-20-119x300.jpg 119w\" sizes=\"(max-width: 207px) 100vw, 207px\" \/><\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"https:\/\/www.nature.com\/articles\/s41586-020-2406-6\" target=\"_blank\" rel=\"noopener\">Photoenzymatic enantioselective intermolecular radical hydroalkylation<\/a>\uff08Nature, 2020, DOI: 10.1038\/s41586-020-2406-6\uff09<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u5b66\u672f\u7ec4NanoCJ\u4f9b\u7a3f\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 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