{"id":203898,"date":"2020-06-25T06:38:34","date_gmt":"2020-06-24T22:38:34","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=203898"},"modified":"2020-06-24T21:38:43","modified_gmt":"2020-06-24T13:38:43","slug":"%e5%90%b8%e9%99%84%e5%88%86%e7%a6%bb%e4%bb%a5%e5%a4%96-%e9%81%8d%e5%9c%b0%e5%bc%80%e8%8a%b1%e7%9a%84%e9%aa%a8%e6%9e%b6%e6%9d%90%e6%96%99","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=203898","title":{"rendered":"\u5438\u9644\u5206\u79bb\u4ee5\u5916\u2014\u2014\u904d\u5730\u5f00\u82b1\u7684\u9aa8\u67b6\u6750\u6599"},"content":{"rendered":"

\u9aa8\u67b6\u6750\u6599\u56e0\u5177\u6709\u56fa\u5b9a\u4e14\u6709\u5e8f\u7684\u8d2f\u901a\u5b54\u9053\u7ed3\u6784\u5728\u5438\u9644\u5206\u79bb\u9886\u57df\u5177\u6709\u72ec\u7279\u7684\u4f18\u52bf\u3002\u968f\u7740\u9aa8\u67b6\u6750\u6599\u7684\u53d1\u5c55\uff0c\u4ee5\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08MOF\uff09\u3001\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\uff08COF\uff09\u3001\u6c22\u952e\u6709\u673a\u9aa8\u67b6\uff08HOF\uff09\u4e3a\u4ee3\u8868\u7684\u9aa8\u67b6\u6750\u6599\u9010\u6e10\u8d8b\u4e8e\u529f\u80fd\u5316\uff0c\u5176\u5b54\u7ed3\u6784\u7684\u529f\u80fd\u4fee\u9970\u7ed3\u5408\u5176\u7eb3\u7c73\u5b54\u7684\u9650\u57df\u6548\u5e94\u4e3a\u5176\u5e26\u6765\u4e86\u9664\u5438\u9644\u5206\u79bb\u5916\u7684\u66f4\u5e7f\u9614\u7684\u5e94\u7528\u7a7a\u95f4\u3002\u672c\u6587\u603b\u7ed3\u4e86\u8fd1\u671f\u9aa8\u67b6\u7ed3\u6784\u5728\u5438\u9644\u5206\u79bb\u4ee5\u5916\u7684\u5e94\u7528\u9886\u57df\u4e2d\u7684\u7814\u7a76\u8fdb\u5c55\u3002<\/p>\n

1. <\/strong>\u8fd1\u7ea2\u5916\u751f\u7269\u6210\u50cf<\/strong>[<\/sup><\/strong>1<\/sup><\/strong>]<\/sup><\/strong><\/p>\n

\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08MOFs\uff09\u53ef\u4ee5\u9ad8\u5bc6\u5ea6\u5730\u96c6\u6210\u8367\u5149Ln3+<\/sup>\u4e8e\u4e00\u4e2a\u7ed3\u6784\u548c\u7ec4\u5206\u660e\u786e\u7684\u914d\u4f4d\u73af\u5883\u4e2d\uff0c\u5e76\u53ef\u4ee5\u901a\u8fc7\u6709\u673a\u914d\u4f53\u6216\u5ba2\u4f53\u751f\u8272\u57fa\u56e2\u901a\u8fc7\u5149\u654f\u5316\u4f5c\u7528\u6fc0\u53d1Ln3+<\/sup>\u7684\u8367\u5149\u3002\u5339\u5179\u5821\u5927\u5b66<\/strong>Nathaniel L. Rosi<\/strong>\u7814\u7a76\u56e2\u961f\u91c7\u53d6\u201cship-in-a-bottle\u201d\u7684\u540e\u4fee\u9970\u7b56\u7565\u5408\u6210\u4e86\u4e24\u79cd\u542b\u6709\u9ad8\u5bc6\u5ea6\u4e19\u7094\u9178\u7532\u916f\u548cYb3+<\/sup>\u7684MOF\uff0c\u5206\u522b\u4e3aMOF-1114(Yb)\u548cMOF-1140(Yb)\uff0c\u53ef\u4ee5\u5728\u751f\u7406\u6761\u4ef6\u4e0b\u611f\u53d7\u8fd1\u7ea2\u5916\u5149\u53d1\u5c04Yb3+<\/sup>\u7684\u8367\u5149\u3002\u901a\u8fc7\u6539\u53d8\u53cd\u5e94\u6e29\u5ea6\u6216MOF\u5b54\u9699\u7387\u53ef\u4ee5\u8c03\u6574\u4ea7\u7269\u4e2d\u5404\u7ec4\u5206\u7684\u6bd4\u4f8b\uff0c\u4ece\u800c\u7b80\u4fbf\u5730\u8c03\u8282MOFs\u7684\u5438\u6536\/\u6fc0\u53d1\u6ce2\u957f\u3002\u7814\u7a76\u7ed3\u679c\u8868\u660e\uff0c\u4e19\u7094\u9178\u7532\u916f\u7684\u03c0\u4f53\u7cfb\u5bc6\u5ea6\u662f\u5f71\u54cd\u5438\u6536\u548c\u6fc0\u53d1\u6ce2\u957f\u7a97\u53e3\u7684\u4e3b\u8981\u56e0\u7d20\u3002\u5728\u5149\u5b66\u751f\u7269\u6210\u50cf\u5e94\u7528\u65b9\u9762\uff0c\u6539\u6027\u7684MOFs\u5728\u6d3b\u7ec6\u80de\u7684\u751f\u7406\u6c34\u73af\u5883\u4e2d\u4fdd\u6301\u5176\u7ed3\u6784\u7a33\u5b9a\u548c\u8367\u5149\u53d1\u5c04\u6027\u80fd\u3002\u8be5\u7814\u7a76\u7ed3\u679c\u5c55\u793a\u4e86\u5728\u5236\u5907\u6fc0\u53d1\u6ce2\u957f\u53ef\u8c03\u8282\u548c\u53ef\u4f18\u5316\u3001\u9002\u5408\u4e8e\u751f\u7269\u5e94\u7528\u7684MOF\u57fa\u8fd1\u7ea2\u5916\u6210\u50cf\u5242\u65b9\u9762\u8fc8\u51fa\u7684\u91cd\u8981\u4e00\u6b65\u3002<\/p>\n

\"\"<\/p>\n

\u56fe1. \u201cship-in-a-bottle\u201d\u6cd5\u5236\u5907\u7528\u4e8e\u8fd1\u7ea2\u5916\u6210\u50cf\u7684MOF\u793a\u610f\u56fe\u3002<\/p>\n

2. <\/strong>\u80fd\u91cf\u8f6c\u79fb<\/strong>[<\/sup><\/strong>2<\/sup><\/strong>]<\/sup><\/strong><\/p>\n

MOF\u7ed3\u6784\u4e2d\u8fde\u63a5\u57fa\u56e2\u4e4b\u95f4\u7684\u8ddd\u79bb\u548c\u89d2\u5ea6\u53ef\u4ee5\u5f88\u5bb9\u6613\u5730\u901a\u8fc7\u5355\u6676x<\/em>\u5c04\u7ebf\u6676\u4f53\u7b49\u591a\u79cd\u6280\u672f\u6765\u786e\u5b9a\uff0c\u6709\u673a\u914d\u4f53\u6216\u65e0\u673a\u8282\u70b9\u7684\u53ef\u8bbe\u8ba1\u6027\u53ef\u4ee5\u7cfb\u7edf\u5730\u6307\u5bfc\u5408\u6210\u65e0\u9650\u63a5\u8fd1\u7406\u60f3\u8bbe\u8ba1\u7684\u7ed3\u6784\u3002\u56e0\u6b64\uff0cMOFs\u6210\u4e3a\u63a2\u7d22\u5b9a\u5411\u80fd\u91cf\u8f6c\u79fb\u6750\u6599\u7684\u4e00\u4e2a\u5408\u9002\u5e73\u53f0\u3002\u539f\u5219\u4e0a\uff0c\u80fd\u91cf\u8f6c\u79fb\u57fa\u56e2\u53ef\u4ee5\u901a\u8fc7\u5404\u79cd\u9014\u5f84\u5f15\u5165MOFs\u4e2d\uff0c\u5305\u62ec\u91d1\u5c5e\u5230\u914d\u4f53\u3001\u91d1\u5c5e\u5230\u91d1\u5c5e\u3001\u4e3b\u4f53\u5230\u5ba2\u4f53\u548c\u914d\u4f53\u5230\u914d\u4f53\u7b49\u3002\u5176\u4e2d\uff0c\u6df7\u5408\u4e24\u4e2a\u914d\u4f53\u5728\u540c\u4e00\u4e2aMOF\u7ed3\u6784\u4e2d\u662f\u4e00\u4e2a\u7406\u60f3\u7684\u8bbe\u8ba1\u601d\u8def\u3002\u963f\u535c\u675c\u62c9\u56fd\u738b\u79d1\u6280\u5927\u5b66<\/strong>Mohamed Eddaoudi<\/strong>\u7814\u7a76\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u79cd\u65b0\u7684Zr\u57fafcu<\/em><\/strong>-MOF (Zr-ML-fcu<\/em><\/strong>-MOF)\uff0c\u5176\u4e2d\uff0c\u82ef\u5e76\u54aa\u5511\u914d\u4f53\u4e0e\u567b\u4e8c\u5511\u914d\u4f53\u6df7\u5408\u94fe\u63a5\u5728\u516d\u6838\u7c07Zr6<\/sub>O4<\/sub>(OH)4<\/sub>\u4e4b\u95f4\u3002\u5bf9\u6bd4\u5355\u72ec\u82ef\u5e76\u54aa\u5511\u914d\u4f53\u7684Zr-BI-fcu<\/em><\/strong>-MOF\u548c\u567b\u4e8c\u5511\u914d\u4f53\u7684Zr-TD-fcu<\/em><\/strong>-MOF\uff0c\u6df7\u5408\u914d\u4f53Zr-ML-fcu<\/em><\/strong>-MOF\u7684TCSPC\u8868\u73b0\u51fa\u660e\u663e\u7684\u5dee\u5f02\uff0c\u5176\u65f6\u95f4\u5e38\u6570\u4e3a108 \u00b1 12 ps\uff0c\u5e76\u8fbe\u5230\u4e8690%\u7684\u80fd\u91cf\u8f6c\u79fb\u6548\u7387\uff0c\u662fMOFs\u6750\u6599\u4e2d\u7684\u6700\u9ad8\u6548\u7387\u4e4b\u4e00\u3002\u8fd9\u9879\u5de5\u4f5c\u63d0\u51fa\u8bbe\u8ba1\u6df7\u5408\u914d\u4f53\u6765\u5408\u6210\u65b0\u578b\u7684\u5177\u6709\u9ad8\u6548\u5149\u6355\u83b7\u7684MOFs\u6750\u6599\uff0c\u7531\u4e8e\u914d\u4f53\u95f4\u7684\u8ddd\u79bb\u5bf9\u80fd\u91cf\u8f6c\u79fb\u8fc7\u7a0b\u6709\u663e\u8457\u5f71\u54cd\uff0c\u5176\u5149\u5b66\u7279\u6027\u6709\u5e0c\u671b\u901a\u8fc7\u8fdb\u4e00\u6b65\u5730\u8f7b\u5fae\u8c03\u8282\u914d\u4f53-\u914d\u4f53\u4e4b\u95f4\u7684\u8ddd\u79bb\u6765\u5b9e\u73b0\u3002<\/p>\n

\"\"<\/p>\n

\u56fe2. Zr-ML-fcu<\/strong>-MOF\u5408\u6210\u53ca\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n

3. \u5149\u52a8\u529b\u6cbb\u7597<\/strong>[<\/sup><\/strong>3<\/sup><\/strong>]<\/sup><\/strong><\/p>\n

\u7eb3\u7c73\u5c3a\u5bf8\u7684\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08nMOFs\uff09\u5177\u6709\u53ef\u8c03\u8282\u7684\u591a\u5b54\u7ed3\u6784\uff0c\u9ad8\u5149\u654f\u5242\u8d1f\u8f7d\u91cf\u548c\u521a\u6027\u7ed3\u6784\uff0c\u662f\u7528\u4e8e\u5149\u52a8\u529b\u6cbb\u7597\uff08PDT\uff09\u7684\u4e00\u79cd\u65b0\u578b\u7684\u7eb3\u7c73\u589e\u654f\u5242\u3002\u901a\u8fc7\u5f15\u5165\u4e0d\u540c\u7684\u5149\u654f\u5242\u914d\u4f53\uff0c\u53ef\u4ee5\u7cbe\u7ec6\u8c03\u63a7nMOFs\u4ee5\u4f18\u5316PDT\u7684\u7597\u6548\u3002nMOFs\u7684\u521a\u6027\u7ed3\u6784\u4e0d\u4ec5\u9650\u5236\u4e86\u914d\u4f53\u7684\u7ed3\u6784\u53d8\u5316\u4ee5\u51cf\u5c11\u5355\u5206\u5b50\u5149\u5206\u89e3\uff0c\u800c\u4e14\u8fd8\u5c06\u5149\u654f\u5242\u76f8\u4e92\u9694\u79bb\u4ee5\u9632\u6b62\u5149\u654f\u5242\u95f4\u7684\u81ea\u731d\u706d\u3002\u829d\u52a0\u54e5\u5927\u5b66<\/strong>Wenbin Lin<\/strong>\u7814\u7a76\u56e2\u961f\u5408\u6210Zr MOF\u7a33\u5b9a\u83cc\u7eff\u7d20\u5b9e\u73b0\u4e86Type\u2160\u548cType\u2161\u578b\u8fd1\u7ea2\u5916\u5149\u52a8\u529b\u6cbb\u7597\u3002\u76f8\u6bd4\u4e8e\u5176\u5b83\u5149\u654f\u5242\uff0c\u83cc\u7eff\u7d20\u5728\u53ef\u89c1\u5149\u533a\u7684\u5438\u6536\u5f31\uff0c\u964d\u4f4e\u4e86\u73af\u5883\u5149\u7684\u5149\u654f\u6027\uff1b\u5728\u8fd1\u7ea2\u5916\u533a\u57df\u5438\u6536\u5f3a\uff08700\u2212850 nm\uff09\uff0c\u589e\u52a0\u4e86PDT\u7684\u6548\u679c\u3002Zr-TBB\u5728740 nm\u4e0b\u901a\u8fc7\u4ea7\u751fO2<\/sub>\u2212<\/sup>\uff0cH2<\/sub>O2<\/sub>\u548c\u2022OH\u81ea\u7531\u57fa\u5b9e\u73b0Type\u2160 PDT\uff0c\u4ea7\u751f1<\/sup>O2<\/sub>\u8fdb\u884cType\u2161 PDT\u3002\u5f97\u5230\u7684MOF Zr-TBB\u5177\u6709\u826f\u597d\u7684\u5149\u7a33\u5b9a\u6027\u3001\u6c27\u5316\u7a33\u5b9a\u6027\u4ee5\u53ca\u6c34\u7a33\u5b9a\u6027\u3002Zr-TBB\u5bf9\u4e73\u817a\u764c\u548c\u7ed3\u80a0\u764c\u5c0f\u9f20\u80bf\u7624\u6a21\u578b\u7684\u4f53\u5185\u6297\u80bf\u7624\u6548\u679c\u6781\u4f73\uff0c\u6cbb\u6108\u7387\u5206\u522b\u4e3a40%\u548c60%\u3002\u8be5\u7814\u7a76\u7ed3\u679c\u8868\u660e\uff0cnMOFs\u63d0\u4f9b\u4e86\u4e00\u4e2a\u72ec\u7279\u7684\u5e73\u53f0\u6765\u7a33\u5b9a\u7ec6\u83cc\u6c2f\u7d20\u6216\u5176\u5b83\u4e0d\u7a33\u5b9a\u7684\u5149\u654f\u5206\u5b50\uff0c\u4ece\u800c\u8bbe\u8ba1\u65b0\u7684\u7eb3\u7c73\u5149\u654f\u5242\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3. Zr-TBB\u9aa8\u67b6\u7a33\u5b9a\u83cc\u7eff\u7d20\u4e0d\u88ab\u6c27\u5316\u3002<\/p>\n

4. \u8d28\u5b50\u4f20\u8f93<\/strong>[<\/sup><\/strong>4<\/sup><\/strong>]<\/sup><\/strong><\/p>\n

\u6c34\u4e2d\u7a33\u5b9a\u7684\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08MOFs\uff09\u7531\u4e8e\u5176\u6c38\u4e45\u7684\u5b54\u9699\u3001\u53ef\u8c03\u7684\u5b54\u5f84\u548c\u53ef\u5b9a\u5236\u7684\u8868\u9762\u7279\u6027\uff0c\u6700\u8fd1\u88ab\u7814\u7a76\u6210\u4e3a\u65b0\u578b\u7684\u79bb\u5b50\u5bfc\u7535\u6750\u6599\u3002\u5c3d\u7ba1\u4fee\u9970\u5404\u79cd\u529f\u80fd\u7684MOFs\u5df2\u88ab\u8bc1\u660e\u662f\u6709\u524d\u9014\u7684\u8d28\u5b50\u5bfc\u7535\u6750\u6599\uff0c\u7136\u800c\uff0c\u5927\u591a\u6570\u7814\u7a76\u6750\u6599\u662f\u901a\u8fc7\u538b\u5236MOF\u9897\u7c92\u6210\u7247\u6216\u4ee5MOF\u4e3a\u586b\u6599\u5236\u5907\u6df7\u5408\u57fa\u8d28\u819c\uff0c\u7531\u4e8eMOF\u9897\u7c92\u95f4\u7684\u7a7a\u9699\u6216MOF\u4e0e\u57fa\u8d28\u4e4b\u95f4\u7684\u754c\u9762\u7f3a\u9677\u7684\u5b58\u5728\uff0cMOF\u7ed3\u6784\u4e2d\u5185\u5728\u5b54\u9053\u7684\u4f18\u52bf\u4e0d\u80fd\u5f97\u5230\u5145\u5206\u4f53\u73b0\uff0c\u5e76\u4e14\uff0cMOF\u5b54\u9053\u7684\u8d28\u5b50\u9009\u62e9\u6027\u4f20\u8f93\u7684\u7814\u7a76\u5f88\u5c11\u88ab\u63a2\u8ba8\u3002\u751f\u7269\u8d28\u5b50\u901a\u9053\u662f\u5c0f\u4e8e1 nm\u7684\u86cb\u767d\u5b54\uff0c\u5177\u6709\u8d85\u9ad8\u7684\u8d28\u5b50\uff08H+<\/sup>\uff09\u9009\u62e9\u6027\u3002\u53d7\u5230\u751f\u7269\u8d28\u5b50\u901a\u9053\u7684\u542f\u53d1\uff0c\u83ab\u7eb3\u4ec0\u5927\u5b66<\/strong>Huanting Wang<\/strong>\u7814\u7a76\u56e2\u961f\u62a5\u9053\u4e86\u78fa\u5316MOFs\uff0c\u5177\u6709\u4e9a\u7eb3\u7c73\u7684\u7a97\u53e3\u548c\u9ad8\u5bc6\u5ea6\u7684\u78fa\u9178\u57fa\u6765\u6a21\u62df\u5929\u7136\u8d28\u5b50\u901a\u9053\uff0c\u5b9e\u73b0\u4e86\u9ad8\u9009\u62e9\u6027\u8d28\u5b50\u4f20\u5bfc\u3002\u4e9a\u7eb3\u7c73MOF\u901a\u9053\u901a\u8fc7\u539f\u4f4d\u751f\u957fZr\u57faMOFs (UiO-66, UiO-66-NH2<\/sub>, UiO-66-(NH2<\/sub>)2<\/sub>)\u4e8e\u805a\u5bf9\u82ef\u4e8c\u7532\u9178\u4e59\u4e8c\u9187\u916f\uff08PET\uff09\u7eb3\u7c73\u901a\u9053\u4e2d\uff0c\u7136\u540e\u8fdb\u884c\u78fa\u4e59\u9178\uff08SAA\uff09\u7684\u540e\u4fee\u9970\u3002UiO\u7684\u79bb\u5b50\u9009\u62e9\u6027\u8868\u73b0\u4e3a\uff1aH+<\/sup>\u226b K+<\/sup>> Na+<\/sup>> Li+<\/sup>\uff0c\u78fa\u5316\u540e\u7684UiO-66\u7684\u8d28\u5b50\u9009\u62e9\u6027\u660e\u663e\u9ad8\u4e8e\u539f\u59cbUiO-66\u901a\u9053\u3002\u5176\u4e2d\uff0cUiO-66-(NH-SAG)2<\/sub>\u8868\u73b0\u51fa\u8d85\u9ad8\u7684\u8d28\u5b50\u9009\u62e9\u6027\uff0cH+<\/sup>\/Li+<\/sup>\u9ad8\u8fbe~100\uff0cH+<\/sup>\/Na+<\/sup>\u4e3a~80\uff0cH+<\/sup>\/K+<\/sup>\u4e3a~70\uff0c\u662fUiO-66-NH-SAG\u7684~3\u500d\uff0c\u662fUiO-66@SAG\u7684~15\u500d\u3002\u78fa\u5316MOF\u901a\u9053\u7684\u8d85\u9ad8\u8d28\u5b50\u9009\u62e9\u6027\u4e3b\u8981\u5f52\u56e0\u4e8e\u9ad8\u5bc6\u5ea6\u78fa\u9178\u57fa\u56e2\u4fee\u9970\u7684\u7a84\u7eb3\u7c73\u5b54\u9053\uff0c\u6709\u5229\u4e8e\u8d28\u5b50\u5feb\u901f\u8f93\u8fd0\u7684\u540c\u65f6\u963b\u6b62\u5176\u5b83\u9633\u79bb\u5b50\u901a\u8fc7\u3002\u8be5\u7814\u7a76\u5de5\u4f5c\u4e3a\u5f00\u53d1\u9009\u62e9\u6027\u79bb\u5b50\u4f20\u5bfc\u548c\u9ad8\u6548\u79bb\u5b50\u5206\u79bb\u7684\u529f\u80fdMOF\u6750\u6599\u5f00\u8f9f\u4e86\u9014\u5f84\u3002<\/p>\n

\"\"<\/p>\n

\u56fe4. \u751f\u7269\u8d28\u5b50\u901a\u9053\u542f\u53d1\u7684\u4eba\u5de5MOF\u8d28\u5b50\u901a\u9053\u3002<\/p>\n

5. \u94a0\u79bb\u5b50\u7535\u6c60<\/strong>[<\/sup><\/strong>5<\/sup><\/strong>]<\/sup><\/strong><\/p>\n

\u5177\u6709\u53ef\u8bbe\u8ba1\u5468\u671f\u9aa8\u67b6\u548c\u6709\u5e8f\u7eb3\u7c73\u5b54\u7684\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\uff08COFs\uff09\u4f5c\u4e3a\u53ef\u5145\u7535\u7535\u6c60\u6b63\u6781\u6750\u6599\u8d8a\u6765\u8d8a\u53d7\u5230\u4eba\u4eec\u7684\u5173\u6ce8\u3002\u4e3a\u4e86\u9ad8\u6548\u5730\u5e94\u7528\u4e8e\u7535\u6c60\u7535\u6781\uff0cCOFs\u7684\u9aa8\u67b6\u9700\u8981\u542b\u6709\u6d3b\u6027\u57fa\u56e2\uff0c\u5982C=O\u548cC=N\u952e\uff0c\u5176\u4e2dO\u548cN\u539f\u5b50\u53ef\u4ee5\u4e0e\u79bb\u5b50\u7ed3\u5408\u3002\u6b64\u5916\uff0c\u7eb3\u7c73\u5b54\u9700\u8db3\u591f\u5927\u4ee5\u5141\u8bb8\u79bb\u5b50\u7684\u6d41\u52a8\u8f93\u8fd0\uff0c\u4e14\u6ca1\u6709\u660e\u663e\u7684\u4f53\u79ef\u81a8\u80c0\u3002\u7136\u800c\uff0c\u76ee\u524d\u62a5\u9053\u7684\u9634\u6781\u5b58\u5728\u5bb9\u91cf\u6709\u9650\u3001\u901f\u7387\u6027\u80fd\u4e0d\u7406\u60f3\u7684\u95ee\u9898\u3002\u5357\u5f00\u5927\u5b66<\/strong>Jun Chen<\/strong>\u7814\u7a76\u56e2\u961f\u62a5\u9053\u4e86\u591a\u7fb0\u57fa\u7684\u8702\u7a9d\u72b6\u5bcc\u6c2e\u5171\u4ef7\u6709\u673a\u9aa8\u67b6TQBQ-COF\u3002N\u539f\u5b50\u7684\u5f15\u5165\u51cf\u5c0f\u4e86\u6700\u4f4e\u7a7a\u5206\u5b50\u8f68\u9053\uff08LUMO\uff09\u548c\u6700\u9ad8\u5360\u636e\u5206\u5b50\u8f68\u9053\uff08HOMO\uff09\u4e4b\u95f4\u7684\u80fd\u9699\uff0c\u589e\u5f3a\u7535\u5b50\u7535\u5bfc\u7387\uff08\u7ea610\u22129<\/sup> S cm\u22121<\/sup>\uff09\uff0c\u63d0\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\uff08\u653e\u7535\u4ea7\u7269\u7ea6\u4e3a10\u22124<\/sup> s cm\u22121<\/sup>\uff09\u3002\u8be5\u4e0d\u6eb6\u6027\u7535\u6781\u7684\u6bd4\u5bb9\u91cf\u4e3a452.0 mAh g\u22121<\/sup>\uff0c\u5177\u6709\u826f\u597d\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff081000\u6b21\u5faa\u73af\u540e\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a96%\uff09\u548c\u9ad8\u901f\u7387\u6027\u80fd\uff08134.3 mAh g\u22121<\/sup>,10.0 A g\u22121<\/sup>\uff09\u3002\u901a\u8fc7\u5085\u7acb\u53f6\u53d8\u6362\u7ea2\u5916\u5149\u8c31\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\uff0c\u8bc1\u660e\u4e86\u5421\u55ea\u548c\u7fb0\u57fa\u5747\u4e3a\u6d3b\u6027\u4f4d\u70b9\uff0c\u4e14\u6bcf\u4e2a\u91cd\u590d\u5355\u5143\u53ef\u4ee5\u5b58\u50a812\u4e2a\u94a0\u79bb\u5b50\uff0c\u5176\u4e2d6\u4e2a\u5728\u5e73\u9762\u5185\uff0c6\u4e2a\u5728\u5e73\u9762\u5916\u3002\u6b64\u5916\uff0c\u7ec4\u88c5\u7684\u888b\u88c5\u7535\u6c60\uff0c\u7535\u6c60\u5bb9\u91cf\u4e3a81 mAh\uff0c\u7535\u538b\u5e73\u53f0\u4e3a1.86 V\uff0c\u5bf9\u5e94\u7684\u91cd\u91cf\u80fd\u91cf\u5bc6\u5ea6\u548c\u4f53\u79ef\u80fd\u91cf\u5bc6\u5ea6\u5206\u522b\u4e3a101.1 Wh kg\u22121<\/sup>\u548c78.5 Wh L\u22121<\/sup>\uff0c\u8868\u660e\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\u5728\u53ef\u5145\u7535\u7535\u6c60\u4e2d\u7684\u6f5c\u5728\u5b9e\u9645\u5e94\u7528\u3002<\/p>\n

\"\"<\/p>\n

\u56fe5. TQBQ-COF\u7684Na+<\/sup>\u5b58\u50a8\u6a21\u578b\u3002<\/p>\n

6. \u4e0d\u5bf9\u79f0\u50ac\u5316\u52a0\u6c22<\/strong>[<\/sup><\/strong>6<\/sup><\/strong>]<\/sup><\/strong><\/p>\n

\u8bbe\u8ba1\u548c\u5f00\u53d1\u9ad8\u6d3b\u6027\u3001\u9ad8\u9009\u62e9\u6027\u7684\u591a\u5b54\u8f7d\u4f53\u50ac\u5316\u5242\u5bf9\u7cbe\u7ec6\u5316\u5b66\u54c1\u548c\u836f\u54c1\u7684\u751f\u6001\u53cb\u597d\u5408\u6210\u5177\u6709\u91cd\u8981\u610f\u4e49\uff0c\u4f46\u4e5f\u6781\u5177\u6311\u6218\u6027\u3002\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08MOFs\uff09\u901a\u8fc7\u529f\u80fd\u5316\u7684\u6709\u673a\u914d\u4f53\u3001\u65e0\u673a\u8282\u70b9\u4ee5\u53ca\u9650\u57df\u5b54\u9053\u4e3a\u591a\u76f8\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u4e00\u4e2a\u7406\u60f3\u7684\u5e73\u53f0\u3002\u7279\u522b\u662fZr(IV)\u57faMOFs\u56e0\u5176\u9ad8\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u548c\u4e30\u5bcc\u7684\u62d3\u6251\u7ed3\u6784\u800c\u5728\u5176\u5b83MOFs\u4e2d\u8131\u9896\u800c\u51fa\uff0c\u5e76\u4f5c\u4e3a\u5927\u5c3a\u5ea6\u591a\u76f8\u50ac\u5316\u7684\u8f7d\u4f53\u800c\u5907\u53d7\u5173\u6ce8\u3002\u7136\u800c\uff0c\u5236\u5907\u5728\u9178\u6027\u6216\u78b1\u6027\u6c34\u89e3\u6761\u4ef6\u4e0b\u7a33\u5b9a\u3001\u5177\u6709\u8f83\u9ad8\u7684\u6d3b\u6027\u548c\u9009\u62e9\u6027\u7684MOF\u50ac\u5316\u5242\uff0c\u7279\u522b\u662f\u5bf9\u6620\u4f53\u9009\u62e9\u6027\uff0c\u4f9d\u7136\u5177\u6709\u5de8\u5927\u7684\u6311\u6218\u3002\u4e3b\u8981\u662f\u7531\u4e8e\u8fd9\u79cd\u7acb\u4f53\u9009\u62e9\u6027\u662f\u7531\u56fa\u8f7d\u50ac\u5316\u5242\u7684\u5c40\u90e8\u624b\u6027\u5fae\u73af\u5883\u51b3\u5b9a\u7684\uff0c\u8fd9\u4e00\u70b9\u8fd8\u5f88\u96be\u63a7\u5236\u3002\u4e0a\u6d77\u4ea4\u901a\u5927\u5b66<\/strong>Yong Cui<\/strong>\u7814\u7a76\u56e2\u961f\u62a5\u9053\u4e86\u4ee51,1′-\u8054\u82ef\u915a\u4e3a\u6709\u673a\u914d\u4f53\u7684\u5177\u6709\u4e0d\u540c\u62d3\u6251\u7ed3\u6784\u7684\u9ad8\u7a33\u5b9a\u6027\u624b\u6027Zr(IV)\u57faZr-CMOFs\uff0c\u901a\u8fc7\u540e\u4fee\u9970\u542bIr\u914d\u5408\u7269\uff0c\u6240\u5f97\u7684MOFs\u5728\u6cb8\u6c34\u3001\u5f3a\u9178\u6027\u548c\u5f31\u78b1\u6027\u6c34\u6eb6\u6db2\u4e2d\u5747\u8868\u73b0\u51fa\u8f83\u9ad8\u7684\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u5176\u4e2d\uff0cflu<\/em><\/strong> Zr-CMOFs\u5bf9\u03b1-\u8131\u6c22\u6c28\u57fa\u9178\u916f\u7684\u4e0d\u5bf9\u79f0\u52a0\u6c22\u5177\u6709\u8f83\u9ad8\u7684\u5bf9\u6620\u9009\u62e9\u6027\uff0c\u5e76\u89c2\u5bdf\u5230\u5176\u50ac\u5316\u884c\u4e3a\u5bf9\u7f51\u7edc\u7ed3\u6784\u6709\u663e\u8457\u7684\u4f9d\u8d56\u6027\uff0c\u56e0ith<\/em><\/strong> Zr-CMOFs\u4e2d\u4e8c\u7f9f\u57fa\u5468\u56f4\u7684\u7a7a\u95f4\u62e5\u6324\uff0c\u963b\u6b62\u4e86P(NMe2<\/sub>)3<\/sub>\u7684\u4fee\u9970\u3002\u8be5\u7814\u7a76\u5f3a\u8c03\u4e86\u6846\u67b6\u7ed3\u6784\u5728\u51b3\u5b9a\u50ac\u5316\u6027\u80fd\u4e2d\u7684\u5173\u952e\u4f5c\u7528\uff0c\u4e3a\u5f00\u53d1\u4ee5Zr-MOFs\u4e3a\u7a33\u5b9a\u8f7d\u4f53\u7528\u4e8e\u591a\u76f8\u50ac\u5316\u5960\u5b9a\u4e86\u57fa\u7840\u3002<\/p>\n

\"\"<\/p>\n

\u56fe 6. \u4e0d\u540c\u7f51\u7edc\u7ed3\u6784\u7684Zr-CMOFs\u7528\u4e8e\u4e0d\u5bf9\u79f0\u52a0\u6c22\u3002<\/p>\n

\u5c0f\u7ed3\uff1a<\/strong><\/p>\n

\u9aa8\u67b6\u6750\u6599\u5177\u6709\u7a33\u5b9a\u4e14\u53ef\u4fee\u9970\u7684\u5b54\u7ed3\u6784\uff0c\u5176\u5c3a\u5bf8\u6548\u5e94\u5728\u5206\u5b50\u7b5b\u5206\u9886\u57df\u5177\u6709\u91cd\u8981\u7684\u5e94\u7528\u524d\u666f\u3002\u968f\u7740\u9aa8\u67b6\u6750\u6599\u540e\u4fee\u9970\u53ca\u529f\u80fd\u5316\u7684\u53d1\u5c55\uff0c\u5b54\u7ed3\u6784\u7684\u9650\u57df\u7a7a\u95f4\u53ca\u754c\u9762\u6027\u8d28\u88ab\u9010\u6e10\u5f00\u53d1\uff0c\u53ef\u4ee5\u4f5c\u4e3a\u6709\u6548\u8f7d\u4f53\u5728\u5404\u79cd\u5e94\u7528\u9886\u57df\u5d2d\u9732\u5934\u89d2\u3002\u76ee\u524d\u7684\u62a5\u9053\u4e2d\uff0c\u6c34\u76f8\u4e2d\u7684\u5e94\u7528\u7814\u7a76\u65e5\u8d8b\u706b\u70ed\u800c\u6709\u673a\u76f8\u4e2d\u7684\u5e94\u7528\u7814\u7a76\u5374\u95e8\u53ef\u7f57\u96c0\uff0c\u7136\u800c\u6c34\u4e2d\u7a33\u5b9a\u7684\u9aa8\u67b6\u6750\u6599\u4f9d\u7136\u6709\u9650\uff0c\u591a\u6570\u4e3aZr-MOF\uff0c\u4f9d\u7136\u5177\u6709\u5e7f\u9614\u7684\u63a2\u7d22\u7a7a\u95f4\u3002<\/p>\n

\u53c2\u8003\u6587\u732e<\/strong><\/p>\n

1. Muldoon, P. F.; Collet, G.; Eliseeva, S. V., et al., Ship-in-a-bottle preparation of long wavelength molecular antennae in lanthanide metal-organic frameworks for biological imaging. J. Am. Chem. Soc.<\/em>, 2020<\/strong>, 142(19): 8776-8781<\/p>\n

2. Jia, J.; Gutierrez-Arzaluz, L.; Shekhah, O., et al., Access to highly efficient energy transfer in metal-organic frameworks via mixed linkers approach. J. Am. Chem. Soc.<\/em>, 2020<\/strong>, 142(19): 8580-8584<\/p>\n

3. Luo, T.; Ni, K.; Culbert, A., et al., Nanoscale metal-organic frameworks stabilize bacteriochlorins for type \u2160 and type \u2161 photodynamic therapy. J. Am. Chem. Soc<\/em>., 2020<\/strong>, 142(16): 7334-7339<\/p>\n

4. Li, X.; Zhang, H.; Hou, J., et al., Sulfonated sub-1-nm metal-organic framework channels with ultrahigh proton selectivity. J. Am. Chem. Soc.<\/em>, 2020<\/strong>, 142(21): 9827-9833<\/p>\n

5. Shi, R.; Liu, L.; Lu, Y., et al., Nitrogen-rich covalent organic frameworks with multiple carbonyls for high-performance sodium batteries. Nat. Commun.<\/em>, 2020<\/strong>, 11(1): 178<\/p>\n

6. Jiang, H.; Zhang, W.; Kang, X., et al., Topology-based functionalization of robust chiral Zr-based metal-organic frameworks for catalytic enantioselective hydrogenation. J. Am. Chem. Soc.<\/em>, 2020<\/strong>, 142(21): 9642-9652.<\/p>\n

\u672c\u6587\u7531Netlap\u4f9b\u7a3f\u3002<\/p>\n

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