{"id":205003,"date":"2020-07-09T06:30:16","date_gmt":"2020-07-08T22:30:16","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=205003"},"modified":"2020-07-08T14:41:17","modified_gmt":"2020-07-08T06:41:17","slug":"%e3%80%90%e6%8a%95%e7%a8%bf%e3%80%91%e4%b8%ad%e5%9b%bd%e7%9f%b3%e6%b2%b9%e5%a4%a7%e5%ad%a6%ef%bc%88%e5%8d%8e%e4%b8%9c%ef%bc%89%e8%83%a1%e6%b6%b5%e3%80%81%e5%90%b4%e6%98%8e%e9%93%82%e6%95%99%e6%8e%88","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=205003","title":{"rendered":"\u4e2d\u56fd\u77f3\u6cb9\u5927\u5b66\uff08\u534e\u4e1c\uff09\u80e1\u6db5\u3001\u5434\u660e\u94c2\u6559\u6388\u8bfe\u9898\u7ec4ACS Nano: \u5bcc\u672c\u5f81\u7f3a\u9677\u591a\u7ea7\u5b54\u78b3\u9aa8\u67b6\u6291\u5236\u591a\u786b\u5316\u9502\u7684\u7a7f\u68ad\u6548\u5e94"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u7531\u4e8e\u5177\u6709\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u4ee5\u53ca\u5ec9\u4ef7\u6613\u5f97\u7684\u7535\u6781\u6750\u6599\uff0c\u9502\u786b\u7535\u6c60\u88ab\u8ba4\u4e3a\u662f\u6700\u5177\u5e94\u7528\u524d\u666f\u7684\u4e0b\u4e00\u4ee3\u4e8c\u6b21\u7535\u6c60\u4e4b\u4e00\uff0c\u8fd1\u5e74\u6765\u53d7\u5230\u4ea7\u5b66\u7814\u5404\u754c\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u76ee\u524d\uff0c\u9502\u786b\u7535\u6c60\u7684\u5b9e\u9645\u5e94\u7528\u4ecd\u53d7\u5230\u4e00\u7cfb\u5217\u95ee\u9898\u7684\u56f0\u6270\uff0c\u5982\u6b63\u6781\u6d3b\u6027\u786b\u7269\u79cd\u7684\u7535\u5bfc\u7387\u4f4e\u3001\u5145\u653e\u7535\u65f6\u4f53\u79ef\u53d8\u5316\u5927\u4ee5\u53ca\u4e2d\u95f4\u4ea7\u7269\u591a\u786b\u5316\u9502\u7684 \u201c\u7a7f\u68ad\u6548\u5e94\u201d\u7b49\uff0c\u4e25\u91cd\u5f71\u54cd\u4e86\u7535\u6c60\u7684\u5b9e\u9645\u6bd4\u5bb9\u91cf\uff0c\u5e93\u4f26\u6548\u7387\u4e0e\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u56fd\u77f3\u6cb9\u5927\u5b66\uff08\u534e\u4e1c\uff09\u80e1\u6db5\u3001\u5434\u660e\u94c2\u6559\u6388\u8bfe\u9898\u7ec4\u5728ACS Nano\u53d1\u8868\u9898\u4e3a\u201cIntrinsic Defect-Rich Hierarchically Porous Carbon Architectures Enabling Enhanced Capture and Catalytic Conversion of Polysulfides\u201d\u7684\u7814\u7a76\u8bba\u6587\uff0c\u63d0\u51fa\u5229\u7528\u4e00\u79cd\u7b80\u6613\u7684\u5236\u5907\u65b9\u6cd5\u6784\u7b51\u5bcc\u542b\u672c\u5f81\u7f3a\u9677\u7684\u5206\u7ea7\u5b54\u78b3\u9aa8\u67b6\u6765\u8d1f\u8f7d\u786b\uff0c\u5229\u7528\u7f3a\u9677\u4f4d\u70b9\u7684\u5f3a\u6781\u6027\u6765\u951a\u5b9a\u548c\u50ac\u5316\u8f6c\u5316\u591a\u786b\u5316\u9502\uff0c\u63d0\u5347\u9502\u786b\u7535\u6c60\u6027\u80fd\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00<\/p>\n

\"\"<\/p>\n

\u5bcc\u672c\u5f81\u7f3a\u9677\u591a\u7ea7\u5b54\u78b3\u9aa8\u67b6\uff08DHPCs\uff09\u5408\u6210\u8fc7\u7a0b\u793a\u610f\u56fe\u3002<\/span><\/p>\n

\u56fe\u4e8c<\/p>\n

\"\"<\/p>\n

(a)(c) \u6c2e\u63ba\u6742\u591a\u7ea7\u5b54\u78b3\u9aa8\u67b6\uff08NHPCs\uff09\u7684FESEM\u56fe\u50cf\uff1b<\/p>\n

(b)(d) DHPCs\u7684FESEM\u56fe\u50cf\uff1b<\/p>\n

(e) NHPCs \u7684TEM\u56fe\u50cf\uff1b<\/p>\n

(f) DHPCs \u7684TEM\u56fe\u50cf\u3002<\/p>\n

\u56fe\u4e09<\/p>\n

\"\"<\/p>\n

(a) NHPCs\u4e0eDHPCs\u7684XPS\u5168\u8c31\uff1b<\/p>\n

(b) NHPCs\u7684\u9ad8\u5206\u8fa8C1s\u56fe\u8c31\uff1b<\/p>\n

(c) DHPCs\u7684\u9ad8\u5206\u8fa8C1s\u56fe\u8c31;<\/p>\n

(d) NHPCs\u4e0eDHPCs\u7684Raman\u56fe\u8c31\uff1b<\/p>\n

(e) NHPCs\u4e0eDHPCs\u7684C\u7684K\u8fb9NEXAFS\u56fe\u8c31\uff1b<\/p>\n

(f) \u56fee\u5728282\u4e0e285 eV\u4e4b\u95f4\u7684\u653e\u5927\u56fe\u3002<\/p>\n

\u56fe\u56db<\/p>\n

\"\"<\/p>\n

(a) L2<\/sub>S6<\/sub>\u6eb6\u6db2\u4ee5\u53ca\u6dfb\u52a0\u7b49\u91cfNHPCs\u3001DHPCs\u540e\u4e0a\u6e05\u6db2\u7684\u7d2b\u5916\u53ef\u89c1\u5149\u8c31\u56fe\u8c31\uff0c\u63d2\u56fe\u4e3a\u5438\u9644\u524d\u540e\u6eb6\u6db2\u989c\u8272\u53d8\u5316\u7684\u7167\u7247\uff1b<\/p>\n

(b) \u4ee5NHPCs\u6216DHPCs\u4f5c\u4e3a\u5de5\u4f5c\u7535\u6781\u7684L2<\/sub>S6<\/sub>\u5bf9\u79f0\u7535\u6c60\u572850 mV s-1<\/sup>\u626b\u63cf\u901f\u7387\u4e0b\u7684CV\u66f2\u7ebf\u3002<\/p>\n

\u56fe\u4e94<\/p>\n

\"\"<\/p>\n

(a) S@NHPC\u4e0eS@DHPC\u57281 mV s-1<\/sup>\u626b\u63cf\u901f\u7387\u4e0b\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

(b)(c) S@NHPC\u4e0eS@DHPC\u57285 C\u500d\u7387\u4e0b\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

(d) S@NHPC\u4e0eS@DHPC\u57280.5 C\u500d\u7387\u4e0b\u7684\u5faa\u73af\u6027\u80fd\u56fe\uff1b<\/p>\n

(e) S@NHPC\u4e0eS@DHPC\u5728\u4e0d\u540c\u500d\u7387\u4e0b\u7684\u5faa\u73af\u6027\u80fd\u56fe\uff1b<\/p>\n

(f) S@NHPC\u4e0eS@DHPC\u7684EIS\u56fe\u8c31\uff1b<\/p>\n

(g) S@DHPC\u57282 C\u500d\u7387\u4e0b\u7684\u957f\u5faa\u73af\u6027\u80fd\u56fe\u3002<\/p>\n

\u56fe\u516d<\/p>\n

\"\"<\/p>\n

(a) (e) \u77f3\u58a8\u70ef\uff1b(b) (f) \u6c2e\u63ba\u6742\u77f3\u58a8\u70ef\uff1b(c) (g) \u5177585\u578b\u7f3a\u9677\u7684\u77f3\u58a8\u70ef\u4ee5\u53ca(d) (h) \u517759\u578b\u7f3a\u9677\u7684\u77f3\u58a8\u70ef\u4e0aLi2<\/sub>S\u4e0eLi2<\/sub>S4<\/sub>\u7684\u5438\u9644\u6784\u578b\u4fef\u89c6\u56fe\u548c\u4fa7\u89c6\u56fe\uff1b<\/p>\n

(i) DHPC\u8868\u9762\u4e0a\u786b\u7269\u79cd\u7684\u56fa\u5b9a\u4e0e\u8f6c\u5316\u793a\u610f\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u9996\u6b21\u63ed\u793a\u4e86\u78b3\u6750\u6599\u672c\u5f81\u7f3a\u9677\u5bf9\u591a\u786b\u5316\u9502\u7684\u5f3a\u5438\u9644\u80fd\u529b\u548c\u50ac\u5316\u8f6c\u5316\u6027\u80fd\u3002\u901a\u8fc7\u7b80\u4fbf\u7684\u4e24\u6b65\u9000\u706b\u6cd5\uff0c\u53ef\u4ee5\u5927\u89c4\u6a21\u751f\u4ea7\u5bcc\u542b\u672c\u5f81\u7f3a\u9677\u7684\u5206\u7ea7\u5b54\u78b3\u9aa8\u67b6\u3002\u8fd9\u79cd\u78b3\u6750\u6599\u53ef\u5b9e\u73b0\u9ad8\u8fbe90%\uff08\u8d28\u91cf\u6bd4\uff09\u7684\u786b\u8d1f\u8f7d\u91cf\u3002\u8f7d\u786b\u540e\u7684S@DHPCs\u57280.5\u00a0C\u500d\u7387\u4e0b\u6bd4\u5bb9\u91cf\u4e3a1182 mAh g-1<\/sup>\u3001\u500d\u7387\u6027\u80fd\u4f73\u3001\u7a33\u5b9a\u6027\u4f18\u826f\uff0c\u5373\u4f7f\u57282 C\u7684\u9ad8\u500d\u7387\u4e0b\uff0c\u5708\u5747\u5bb9\u91cf\u8870\u51cf\u4ec5\u4e3a0.06 %\u3002<\/p>\n

\u6587\u732e\u8fde\u63a5\uff1aIntrinsic Defect-Rich Hierarchically Porous Carbon Architectures Enabling Enhanced Capture and Catalytic Conversion of Polysulfides. ACS Nano 2020, 14 (5), 6222-6231.<\/u><\/a><\/p>\n

\u672c\u6587\u7531\u4e2d\u56fd\u77f3\u6cb9\u5927\u5b66\uff08\u534e\u4e1c\uff09\u91cd\u8d28\u6cb9\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u6295\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u7531\u4e8e\u5177\u6709\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u4ee5\u53ca\u5ec9\u4ef7\u6613\u5f97\u7684\u7535\u6781\u6750\u6599\uff0c\u9502\u786b\u7535\u6c60\u88ab\u8ba4\u4e3a\u662f\u6700\u5177\u5e94\u7528\u524d\u666f\u7684\u4e0b\u4e00\u4ee3\u4e8c\u6b21\u7535\u6c60\u4e4b\u4e00\uff0c\u8fd1\u5e74\u6765\u53d7\u5230\u4ea7\u5b66\u7814\u5404\u754c\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u76ee\u524d\uff0c\u9502\u786b\u7535\u6c60\u7684\u5b9e\u9645\u5e94\u7528\u4ecd…<\/p>\n","protected":false},"author":11454,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-205003","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/205003"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=205003"}],"version-history":[{"count":5,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/205003\/revisions"}],"predecessor-version":[{"id":205069,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/205003\/revisions\/205069"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=205003"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=205003"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=205003"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}