{"id":205485,"date":"2020-07-25T06:20:49","date_gmt":"2020-07-24T22:20:49","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=205485"},"modified":"2020-07-24T21:21:06","modified_gmt":"2020-07-24T13:21:06","slug":"%e5%b9%b2%e8%b4%a7%ef%bc%9a%e5%8e%9f%e4%bd%8d%e7%ba%a2%e5%a4%96%e5%85%89%e8%b0%b1%e5%9c%a8%e5%bc%82%e7%9b%b8%e5%82%ac%e5%8c%96%e4%b8%ad%e7%9a%84%e5%ba%94%e7%94%a8","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=205485","title":{"rendered":"\u5e72\u8d27\uff1a\u539f\u4f4d\u7ea2\u5916\u5149\u8c31\u5728\u5f02\u76f8\u50ac\u5316\u4e2d\u7684\u5e94\u7528"},"content":{"rendered":"

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\u7ea2\u5916\u5149\u8c31\uff08Infrared Spectroscopy\uff09\u662f\u73b0\u4eca\u79d1\u7814\u5de5\u4f5c\u8005\u6700\u91cd\u8981\u7684\u5206\u6790\u6280\u672f\u624b\u6bb5\u4e4b\u4e00\uff0c\u662f\u7814\u7a76\u8868\u5f81\u5206\u5b50\u7ed3\u6784\u7684\u4e00\u79cd\u6709\u6548\u624b\u6bb5\uff0c\u4e0e\u5176\u5b83\u65b9\u6cd5\u76f8\u6bd4\u8f83\uff0c\u5b83\u6700\u5927\u7684\u4f18\u52bf\u5728\u4e8e\u53ef\u4ee5\u5728\u9009\u62e9\u5408\u9002\u5236\u6837\u65b9\u5f0f\u7684\u6761\u4ef6\u4e0b\u6d4b\u5b9a\u5728\u4efb\u4f55\u72b6\u6001\u4e0b\u7684\u6837\u54c1\uff0c\u5305\u62ec\u6db2\u4f53\uff0c\u6eb6\u6db2\uff0c\u7c98\u7a20\u72b6\u6837\u54c1\uff0c\u7c89\u672b\uff0c\u819c\uff0c\u7ea4\u7ef4\uff0c\u6c14\u4f53\u7b49\u3002\u5feb\u901f\u626b\u63cf\u5085\u7acb\u53f6\u53d8\u6362\u7ea2\u5916\u5149\u8c31\u5728\u8fc7\u53bb\u7684\u4e09\u5341\u5e74\u91cc\u6781\u5927\u5730\u964d\u4f4e\u4e86\u539f\u4f4d\u6d4b\u91cf\u5b9e\u9a8c\u7684\u96be\u5ea6\u3002\u5982\u4eca\u4f4e\u900f\u8fc7\u7387\u7684\u6837\u54c1\u4ecd\u7136\u53ef\u4ee5\u5feb\u901f\u5730\u5f97\u5230\u9ad8\u4fe1\u566a\u6bd4\u7684\u8c31\u56fe\uff0c\u88ab\u52a0\u70ed\u7684\u50ac\u5316\u5242\u6837\u54c1\u7684\u7ea2\u5916\u8f90\u5c04\u5bf9\u7ea2\u5916\u68c0\u6d4b\u5668\u7684\u5f71\u54cd\u540c\u65f6\u4e5f\u6bd4\u4e0a\u4e00\u4ee3\u5229\u7528\u6ce2\u957f\u626b\u63cf\u539f\u7406\u7684\u4eea\u5668\u8981\u5c0f\u5f88\u591a\uff0c\u540c\u65f6\u6c14\u76f8\u7269\u79cd\u7684\u7ea2\u5916\u8c31\u56fe\u4e5f\u53ef\u4ee5\u901a\u8fc7\u8c31\u56fe\u7684\u51cf\u6cd5\u51cf\u53bb\u80cc\u666f\u800c\u5f88\u5bb9\u6613\u5730\u5f97\u5230\u3002\u5728\u4eea\u5668\u7075\u654f\u5ea6\u63d0\u9ad8\u7684\u524d\u63d0\u4e0b\uff0c\u8bb8\u591a\u6837\u54c1\u5206\u6790\u65b9\u6cd5\u5982\u6f2b\u53cd\u5c04\uff0c\u5206\u5b50\u7b5b\u5355\u6676\u663e\u5fae\u5149\u8c31\uff0c\u5355\u6676\u8868\u9762\u7684\u53cd\u5c04\u5438\u6536\u90fd\u53ef\u4ee5\u5e94\u7528\u4e8e\u539f\u4f4d\u7ea2\u5916\u5149\u8c31\u3002<\/p>\n

\u968f\u7740\u6db2\u6c2e\u51b7\u5374\u7684MCT\uff08Mercury Cadmium telluride\uff09\u68c0\u6d4b\u5668\u5728\u7ea2\u5916\u5149\u8c31\u4e0a\u5728\u4f7f\u7528\u540e\uff0c\u91c7\u7528\u6f2b\u53cd\u5c04\u6280\u672f\uff08DRIFT\uff09\u53ef\u4ee5\u83b7\u5f97\u9ad8\u4fe1\u566a\u6bd4\u7684\u8c31\u56fe\uff0c\u8fd9\u6781\u5927\u5730\u63a8\u52a8\u4e86\u6f2b\u53cd\u5c04\u6280\u672f\u5728\u7ea2\u5916\u5149\u8c31\u4e0a\u7684\u5e94\u7528\u3002\u73b0\u5728\uff0c\u5927\u90e8\u5206\u7684 DRIFT \u7814\u7a76\u8005\u90fd\u4f7f\u7528\u4e86\u5546\u4e1a\u5316\u7684\u539f\u4f4d\u6f2b\u53cd\u5c04\u53cd\u5e94\u6c60\u3002\u5728\u6b64\u88c5\u7f6e\u4e2d\uff0c\u50ac\u5316\u5242\u7c89\u672b\u653e\u7f6e\u4e8e\u539f\u4f4d\u6c60\u4e2d\u7684\u6837\u54c1\u69fd\uff0c\u6837\u54c1\u69fd\u4e0b\u9762\u6709\u4e00\u4e2a\u52a0\u70ed\u5e73\u53f0\u3002\u6574\u4e2a\u6837\u54c1\u6c60\u5305\u62ec\u4e86\u6c14\u4f53\u7684\u8fdb\u51fa\u53e3\u7ba1\u8def\uff0c\u6837\u54c1\u69fd\u9876\u90e8\u7ea2\u5916\u900f\u8fc7\u7684\u7a97\u7247\u3002\u4ece\u5149\u6e90\u51fa\u6765\u7684\u7ea2\u5916\u5149\u7ecf\u8fc7\u805a\u7126\u540e\u900f\u8fc7\u7a97\u7247\u5230\u8fbe\u6837\u54c1\u8868\u9762\u5e76\u53d1\u751f\u6563\u5c04\uff0c\u6563\u5c04\u7684\u7ea2\u5916\u5149\u900f\u8fc7\u7a97\u7247\u4f20\u51fa\u540e\u7ecf\u7531\u518d\u6b21\u6c47\u805a\u540e\u901a\u8fc7\u5149\u5b66\u7cfb\u7edf\u4f20\u9001\u5230\u68c0\u6d4b\u5668\u4ece\u800c\u5f97\u5230\u8c31\u56fe\uff08\u7ea2\u5916\u6f2b\u53cd\u5c04\u88c5\u7f6e\u7684\u5149\u8def\u56fe\u5982\u56fe1\u6240\u793a\uff09\u3002\u5728\u539f\u7406\u4e0a\uff0c\u6f2b\u53cd\u5c04\u6280\u672f\u76f8\u5bf9\u900f\u5c04\u6280\u672f\u800c\u8a00\u6709\u51e0\u4e2a\u4f18\u70b9\uff0c\u9996\u5148\u6f2b\u53cd\u5c04\u6837\u54c1\u7684\u5236\u5907\u66f4\u76f4\u63a5\uff0c\u53ea\u9700\u8981\u4f7f\u7528\u7c89\u672b\u72b6\u7684\u6837\u54c1\u5c31\u53ef\u4ee5\u8fdb\u884c\u68c0\u6d4b\uff0c\u4e0d\u9700\u8981\u538b\u7247\uff1b\u6709\u4e9b\u50ac\u5316\u5242\u6837\u54c1\uff08\u89c6\u5176\u9897\u7c92\u72b6\u6001\u4e0e\u5f62\u6001\uff09\u96be\u4ee5\u6216\u8005\u751a\u81f3\u4e0d\u80fd\u538b\u6210\u8db3\u4ee5\u900f\u8fc7\u8db3\u591f\u5f3a\u5ea6\u7ea2\u5916\u5149\u7684\u8584\u7247\uff0c\u5bfc\u81f4\u65e0\u6cd5\u8fdb\u884c\u539f\u4f4d\u53cd\u5e94\u89c2\u6d4b\uff0c\u800c\u901a\u8fc7\u6f2b\u53cd\u5c04\u6280\u672f\u53ef\u4ee5\u6536\u96c6\u5230\u8db3\u591f\u5f3a\u5ea6\u7684\u7ea2\u5916\u4fe1\u53f7\u5230\u8fbe\u68c0\u6d4b\u5668\u4ece\u800c\u5f97\u5230\u4fe1\u566a\u6bd4\u5f88\u9ad8\u7684\u8c31\u56fe\u3002\u8fd9\u662f\u56e0\u4e3a\u6f2b\u53cd\u5c04\u6280\u672f\u68c0\u6d4b\u7684\u662f\u901a\u8fc7\u6837\u54c1\u7684\u6563\u5c04\u5149\uff0c\u8fd9\u4e00\u70b9\u662f\u900f\u5c04\u5149\u8c31\u65e0\u6cd5\u505a\u5230\u7684\uff0c\u5c24\u5176\u662f\u9047\u5230\u7ea2\u5916\u5149\u65e0\u6cd5\u900f\u8fc7\u7684\u6837\u54c1\u7684\u65f6\u5019\u3002\u800c\u7c89\u672b\u72b6\u7684\u50ac\u5316\u5242\u6837\u54c1\u76f8\u5bf9\u4e8e\u538b\u7247\u800c\u8a00\uff0c\u66f4\u5bb9\u6613\u5f97\u5230\u5f88\u597d\u7684\u6f2b\u53cd\u5c04\u4fe1\u53f7\u3002 \u00a0\u00a0<\/p>\n

\"\"<\/p>\n

\u56fe1<\/b><\/strong>\u00a0<\/b><\/strong>\u7ea2\u5916\u6f2b\u53cd\u5c04\u88c5\u7f6e\u7684\u5149\u8def\u56fe<\/p>\n

\u539f\u4f4d\u7ea2\u5916\u5149\u8c31\u6240\u80fd\u63d0\u4f9b\u7684\u5206\u5b50\u4fe1\u606f\u975e\u5e38\u4e30\u5bcc\u3002\u5728\u50ac\u5316\u4e2d\uff0c\u539f\u4f4d\u7ea2\u5916\u5438\u6536\u5149\u8c31\u6cd5\u901a\u5e38\u7528\u4e8e\u8bc6\u522b\u5438\u9644\u7684\u7269\u8d28\uff0c\u5e76\u4e14\u53ef\u4ee5\u89c2\u6d4b\u5fae\u89c2\u5438\u9644\u8303\u56f4\uff0c\u540c\u65f6\u53ef\u4ee5\u5728\u52a8\u529b\u5b66\u7814\u7a76\u4e2d\u8ddf\u8e2a\u5176\u968f\u65f6\u95f4\u7684\u53d8\u5316\u89c4\u5f8b\u3002\u8fd9\u91cc\uff0c\u6211\u4eec\u5c06\u63d0\u4f9b\u4e00\u4e9b\u5178\u578b\u793a\u4f8b\u6765\u8bf4\u660e\u539f\u4f4d\u7ea2\u5916\u5149\u8c31\u5728\u5f02\u76f8\u50ac\u5316\u9886\u57df\u6700\u7a81\u51fa\u7684\u529f\u80fd\u3002<\/p>\n

1 \u5438\u9644\u6001\u7814\u7a76\u548c\u50ac\u5316\u5242\u7ea2\u5916\u5149\u8c31\u8868\u5f81<\/b><\/strong><\/p>\n

\u7ea2\u5916\u5149\u8c31\u5df2\u7ecf\u5e7f\u6cdb\u5e94\u7528\u4e8e\u50ac\u5316\u5242\u8868\u9762\u6027\u8d28\u7684\u7814\u7a76\uff0c\u5176\u4e2d\u6700\u6709\u6548\u548c\u5e7f\u6cdb\u5e94\u7528\u7684\u662f\u7814\u7a76\u5438\u9644\u5728\u50ac\u5316\u5242\u8868\u9762\u7684\u6240\u8c13\u201c\u63a2\u9488\u5206\u5b50\u201d\u7684\u7ea2\u5916\u5149\u8c31\uff0c\u5982\uff1aNO\u3001CO\u3001CO2<\/sub>\u3001NH3<\/sub>\u3001C3<\/sub>H5<\/sub>N\u7b49\uff0c\u7ea2\u5916\u5149\u8c31\u8868\u5f81\u53ef\u4ee5\u63d0\u4f9b\u50ac\u5316\u5242\u8868\u9762\u5c24\u5176\u662f\u539f\u4f4d\u53cd\u5e94\u6761\u4ef6\u4e0b\u50ac\u5316\u5242\u8868\u9762\u5b58\u5728\u7684\u201c\u6d3b\u6027\u4e2d\u5fc3\u201d\u548c\u8868\u9762\u5438\u9644\u7269\u79cd\u7684\u4fe1\u606f\uff0c\u56e0\u6b64\u5bf9\u4e8e\u63ed\u793a\u50ac\u5316\u53cd\u5e94\u673a\u7406\u5341\u5206\u91cd\u8981\u3002<\/p>\n

1.1 \u63a2\u9488\u5206\u5b50\u7684\u5438\u9644\u6001\u7814\u7a76<\/b><\/strong><\/p>\n

\u4f8b\u5982\uff0c\u8463\u5e06\u6559\u6388\u8bfe\u9898\u7ec4\u901a\u8fc7\u539f\u4f4d\u7ea2\u5916\u8bc1\u5b9e\uff0c\u7531\u4e8eBi2<\/sub>O2<\/sub>CO3<\/sub>\u5149\u50ac\u5316\u5242{110}\u548c{001}\u9762\u4e0a\u539f\u5b50\u6392\u5217\u7684\u5dee\u5f02\uff0cBi2<\/sub>O2<\/sub>CO3<\/sub>-001\u5728\u5438\u9644\u6d3b\u5316\u8fc7\u7a0b\u4e2d\u4f7fNO\u8f6c\u5316\u4e3aNO–<\/sup>\u6216\u987a\u5f0fN2<\/sub>O2<\/sub>2-<\/sup>\uff0c\u800cBi2<\/sub>O2<\/sub>CO3<\/sub>-110\u5219\u8bf1\u5bfcNO\u5438\u9644\u6d3b\u5316\u4e3aNO+<\/sup>\u6216N2<\/sub>O3<\/sub>\u3002\u4e0d\u540c\u7684\u5438\u9644\u6d3b\u5316\u8def\u5f84\u5c06\u5f71\u54cd\u5149\u50ac\u5316\u53bb\u9664NO\u7684\u6548\u679c\u3002[<\/sup>1]<\/sup><\/p>\n

\"\"<\/p>\n

\u56fe2<\/b><\/strong>\u00a0<\/b><\/strong>Bi2<\/sub>O2<\/sub>CO3<\/sub>\u4e0d\u540c\u6676\u9762\u5438\u9644NO\u7684\u539f\u4f4d\u7ea2\u5916\u56fe\u8c31\u3002[<\/sup>1]<\/sup><\/p>\n

1.2\u51e0\u4f55\u6548\u5e94\u548c\u7535\u5b50\u6548\u5e94\u7814\u7a76<\/b><\/strong><\/p>\n

\u5728\u9ad8\u5206\u6563\u91d1\u5c5e\u50ac\u5316\u5242\u4e2d\u5f15\u5165\u7b2c\u4e8c\u91d1\u5c5e\u7ec4\u5143\uff0c\u7531\u4e8e\u91d1\u5c5e\u95f4\u7684\u51e0\u4f55\u6548\u5e94\u548c\u7535\u5b50\u6548\u5e94\u53ef\u663e\u8457\u6539\u53d8\u50ac\u5316\u5242\u7684\u5438\u9644\u6027\u80fd\u4ece\u800c\u6539\u53d8\u50ac\u5316\u6d3b\u6027\u3002\u5982\u5728Pd-Ag\/SiO2\u50ac\u5316\u5242\u4f53\u7cfb\u4e2d\uff0cAg\u5bf9Pd\u8d77\u7a00\u91ca\u4f5c\u7528\uff0c\u5f53Ag\u542b\u91cf\u589e\u52a0\uff0c\u6210\u53cc\u5b58\u5728\u7684Pd\u6d53\u5ea6\u51cf\u5c11\uff0c\u56e0\u800c\u6865\u5f0fCO\u51cf\u5c11\uff0c\u7ebf\u5f0fCO\u589e\u52a0\uff0c\u8bf4\u660e\u51e0\u4f55\u6548\u5e94\u6539\u53d8\u4e86CO\u5728Pd-Ag\/SiO2\u4f53\u7cfb\u4e2d\u7684\u5438\u9644\u6027\u80fd\u3002\u540c\u65f6\uff0c\u968fAg\u542b\u91cf\u7684\u589e\u52a0\uff0cCO\u5438\u9644\u8c31\u5e26\u7ea2\u79fb\u52a0\u5927\uff0c\u8bf4\u660ePd-Ag\u4e4b\u95f4\u5b58\u5728\u7535\u5b50\u6548\u5e94\u3002<\/p>\n

1.3\u5206\u5b50\u7684\u7ade\u4e89\u5438\u9644\u53ca\u5438\u9644\u5206\u5b50\u95f4\u76f8\u4e92\u4f5c\u7528\u7814\u7a76<\/b><\/strong><\/p>\n

\u5b9e\u9645\u7684\u50ac\u5316\u53cd\u5e94\u4e2d\uff0c\u5e38\u5e38\u5b58\u5728\u591a\u79cd\u5438\u9644\u5206\u5b50\u5171\u5b58\uff0c\u56e0\u6b64\u7814\u7a76\u4e0d\u540c\u79cd\u7c7b\u5206\u5b50\u5728\u50ac\u5316\u5242\u8868\u9762\u7684\u7ade\u4e89\u5438\u9644\u4ee5\u53ca\u5206\u5b50\u95f4\u76f8\u4e92\u4f5c\u7528\u81f3\u5173\u91cd\u8981\u3002\u4f8b\u5982\uff0c\u5f20\u793c\u77e5\u6559\u6388\u8bfe\u9898\u7ec4\u5229\u7528\u539f\u4f4d\u7ea2\u5916\u7814\u7a76\u4e86\u5728BiOCl\u5149\u50ac\u5316\u5242\u6c27\u5316\u53bb\u9664NO\u7684\u53cd\u5e94\u4f53\u7cfb\u4e2d\uff0cNO\u5206\u5b50\u4e0eO2<\/sub>\u5206\u5b50\u7684\u7ade\u4e89\u5438\u9644\u3002[<\/sup>2]<\/sup>\u9996\u5148\uff0c\u5728\u6ca1\u6709 O2\u7684\u60c5\u51b5\u4e0b\uff0c\u5fae\u91cf\u6d53\u5ea6\u7684 NO \u5728\u9ed1\u6697\u4e2d 298 K \u4e0b\u5728 \u5177\u6709\u6c27\u7a7a\u4f4dBiOCl\uff08BOC-OV\uff09\u8868\u9762\u4e0a\u5728 1091\u00a0cm-1<\/sup>\u00a0\u548c 1630\u00a0cm-1<\/sup>\u5904\u4ea7\u751f\u4e24\u4e2a\u4e0d\u540c\u7684\u8c31\u5e26\uff08\u56fe3\uff09\u3002\u524d\u4e00\u5e26\u968f\u7740\u66b4\u9732\u65f6\u95f4\u9010\u6e10\u589e\u52a0\uff0c\u53ef\u80fd\u662f\u7531\u5e26\u8d1f\u7535\u8377\u7684\u8868\u9762 OV-NO-\u7269\u8d28\u4ea7\u751f\u7684\uff0c\u800c\u540e\u4e00\u4e2a\u5bbd\u5e26\u5219\u5f52\u56e0\u4e8e\u5438\u9644\u7684\u672a\u79bb\u89e3\u6c34\u3002 \u5728 NO \u5438\u9644\u5e73\u8861\u8fbe\u5230\u540e\uff0c\u5c06O2<\/sub>\u6cf5\u5165\uff0c\u7136\u540e\u5f15\u5165\u53ef\u89c1\u5149\u7167\u5c04\u5f15\u53d1\u5149\u50ac\u5316\u53cd\u5e94\u3002\u9c9c\u660e\u5730\u89c2\u5bdf\u5230 FTIR \u5149\u8c31\u7684\u663e\u7740\u53d8\u5316\uff08\u56fe3a\uff09\u3002\u9996\u5148\uff0c1081\u00a0cm-1<\/sup>\u5904\u7684\u8c31\u5e26\u9010\u6e10\u51cf\u5c11\u5e76\u53d8\u4e3a\u8d1f\u503c\uff0c\u4f34\u968f\u7740 1003\u00a0cm-1<\/sup>\u5904\u8c31\u5e26\u7684\u9010\u6e10\u589e\u52a0\u3002\u5728 1003 cm-1<\/sup>\u5904\u7684\u8fd9\u4e2a\u8c31\u5e26\u53ef\u5f52\u56e0\u4e8e\u8868\u9762\u6865\u63a5\u7684\u2022O2<\/sub>\u2212<\/sup>\u7269\u79cd\u7684\u00a0O-O \u4f38\u7f29\u6a21\u5f0f\uff0c\u8fd9\u8868\u660eO2<\/sub>\u4e0a\u7684O2<\/sub>\u5feb\u901f\u5730\u88ab\u00a0NO \u53d6\u4ee3\uff0cN<\/b><\/strong>O<\/b><\/strong>\u548c<\/b><\/strong>O<\/b><\/strong>2<\/b><\/sub><\/strong>\u5b58\u5728\u660e\u663e\u7684\u7ade\u4e89\u5438\u9644\u8fc7\u7a0b<\/b><\/strong>\u3002\u5176\u6b21\uff0c\u00a0\u5982\u51e0\u4e2a\u53ef\u8fa8\u522b\u5e26\u7684\u51fa\u73b0\u6240\u53cd\u6620\u7684\uff0cNO \u88ab\u7acb\u5373\u8f6c\u5316\u4e3a\u5176\u4ed6\u6c2e\u7269\u79cd\u3002\u5728\u00a01274 cm-1<\/sup>\u7684\u8c31\u5e26\u88ab\u6307\u5b9a\u4e3a\u5355\u9f7f\u6001\u7684\u785d\u9178\u03bd3<\/sub>\u00b4\u00b4\u632f\u52a8\u6a21\u5f0f\uff0c\u57281477 cm-1<\/sup>\u5904\u7684\u5bbd\u8c31\u5e26\u5f52\u56e0\u4e8e\u51e0\u4e4e\u5bf9\u79f0\u7684\u8868\u9762\u785d\u9178\u76d0\u3002\u5bbd\u8c31\u5e26\u5728\u00a01600 \u5230\u00a01800 cm-1<\/sup>\u662f\u5178\u578b\u7684\u4e0e\u00a0NO\u548c\u6e38\u79bb\u6001\u785d\u9178\u76d0\u7ed3\u5408\u7684\u7ed3\u5408\u5e26\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u2022O2<\/sub>\u2212<\/sup>\u548c\u00a0NO3<\/sub>\u2212<\/sup>\u7269\u8d28\u7684\u7ea2\u5916\u5438\u6536\u5f3a\u5ea6\u968f\u7740\u00a0NO \u7684\u51cf\u5c11\u800c\u7ebf\u6027\u589e\u52a0\uff0c\u8bf4\u660e\u00a0NO \u6c27\u5316\u4e3a\u785d\u9178\u6839\u7528\u5149\u8bf1\u5bfc\u7684O2<\/sub>\u2212<\/sup>\u4ecb\u5bfc\uff08\u56fe\u00a03b\uff09\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3<\/b><\/strong>\u00a0(a)\u00a0\u5728\u00a0BOC-OV \u7684\u5149\u50ac\u5316\u00a0NO \u6c27\u5316\u671f\u95f4\u8bb0\u5f55\u7684\u539f\u4f4d\u00a0FTIR \u5149\u8c31\uff1b\uff08b\uff09\u2022O2<\/sub>\u2212<\/sup>\/ NO3<\/sub>\u2212<\/sup>\u5438\u5149\u5ea6\u589e\u52a0\u7684\u52a8\u6001\u53d8\u5316\u4f34\u968f\u7740\u00a0NO \u5438\u6536\u5cf0\u51cf\u5c11\u3002<\/p>\n

2 \u6c27\u5316\u7269\u3001\u5206\u5b50\u7b5b\u50ac\u5316\u5242\u7684\u7ea2\u5916\u5149\u8c31\u8868\u5f81<\/b><\/strong><\/p>\n

2.1 \u56fa\u4f53\u8868\u9762\u9178\u6027\u6d4b\u5b9a<\/b><\/strong><\/p>\n

\u56fa\u4f53\u8868\u9762\u9178\u6027\u4f4d\u4e00\u822c\u53ef\u770b\u4f5c\u662f\u6c27\u5316\u7269\u50ac\u5316\u5242\u8868\u9762\u7684\u6d3b\u6027\u4f4d\u3002\u5728\u4f17\u591a\u50ac\u5316\u53cd\u5e94\u5982\u50ac\u5316\u88c2\u5316\u3001\u5f02\u6784\u5316\u3001\u805a\u5408\u7b49\u53cd\u5e94\u4e2d\u70c3\u7c7b\u5206\u5b50\u4e0e\u8868\u9762\u9178\u6027\u4f4d\u76f8\u4e92\u4f5c\u7528\u5f62\u6210\u6b63\u78b3\u79bb\u5b50\uff0c\u8be5\u6b63\u78b3\u79bb\u5b50\u662f\u53cd\u5e94\u7684\u4e2d\u95f4\u7269\u79cd\u3002\u6b63\u78b3\u79bb\u5b50\u7406\u8bba\u53ef\u4ee5\u6210\u529f\u89e3\u91ca\u70c3\u7c7b\u5728\u9178\u6027\u8868\u9762\u4e0a\u7684\u53cd\u5e94\uff0c\u4e5f\u5bf9\u9178\u6027\u4f4d\u7684\u5b58\u5728\u63d0\u4f9b\u4e86\u6709\u529b\u8bc1\u660e\u3002<\/p>\n

\u4e3a\u4e86\u8868\u5f81\u56fa\u4f53\u9178\u50ac\u5316\u5242\u7684\u6027\u8d28\uff0c\u9700\u8981\u6d4b\u5b9a\u8868\u9762\u9178\u6027\u4f4d\u7684\u7c7b\u578b(Lewis\u9178\uff0cBronsted\u9178)\u3001\u5f3a\u5ea6\u548c\u9178\u91cf\u3002\u6d4b\u5b9a\u8868\u9762\u9178\u6027\u7684\u65b9\u6cd5\u5f88\u591a\uff0c\u5982\u78b1\u6ef4\u5b9a\u6cd5\u3001\u78b1\u6027\u6c14\u4f53\u5438\u9644\u6cd5\u3001\u70ed\u5dee\u6cd5\u7b49\uff0c\u4f46\u8fd9\u4e9b\u65b9\u6cd5\u90fd\u4e0d\u80fd\u533a\u5206L\u9178\u548cB\u9178\u90e8\u4f4d\u3002\u7ea2\u5916\u5149\u8c31\u6cd5\u5219\u5e7f\u6cdb\u7528\u6765\u7814\u7a76\u56fa\u4f53\u50ac\u5316\u5242\u8868\u9762\u9178\u6027\uff0c\u5b83\u53ef\u4ee5\u6709\u6548\u533a\u5206L\u9178\u548cB\u9178\uff0c\u5728\u8be5\u65b9\u6cd5\u4e2d\uff0c\u5e38\u7528\u78b1\u6027\u5438\u9644\u8d28\u5982\u6c28\u3001\u5421\u5576\u3001\u4e09\u7532\u57fa\u80fa\u3001\u6b63\u4e01\u80fa\u7b49\u6765\u8868\u5f81\u9178\u6027\u4f4d\uff0c\u5176\u4e2d\u5e94\u7528\u6bd4\u8f83\u5e7f\u6cdb\u7684\u662f\u5421\u5576\u548c\u6c28\u3002<\/p>\n

2.2 \u6c27\u5316\u7269\u8868\u9762\u7f9f\u57fa\u7684\u7814\u7a76<\/b><\/strong><\/p>\n

\u6c27\u5316\u7269\u5c24\u5176\u662f\u5927\u6bd4\u8868\u9762\u7684\u6c27\u5316\u7269\u7684\u8868\u9762\u7ed3\u6784\u7f9f\u57fa\u540c\u8bb8\u591a\u50ac\u5316\u53cd\u5e94\u5982\u8131\u6c34\u53cd\u5e94\u3001\u7532\u9178\u5206\u89e3\u53cd\u5e94\u7b49\u6709\u5173\uff0c\u800c\u8868\u9762\u7ed3\u6784\u7f9f\u57fa\u7684\u6027\u8d28\u53c8\u540c\u8868\u9762\u9178\u6027\u6709\u5bc6\u5207\u7684\u5173\u7cfb\uff0c\u591a\u5e74\u6765\uff0c\u4eba\u4eec\u5bf9\u6c27\u5316\u7269\u8868\u9762\u7f9f\u57fa\u8fdb\u884c\u4e86\u5927\u91cf\u7684\u7814\u7a76\uff0c\u5176\u4e2d\u5927\u90e8\u5206\u7814\u7a76\u7740\u773c\u4e8e\u6c27\u5316\u7269\u8868\u9762\u7f9f\u57fa\u7684\u7ed3\u6784\u3001\u6027\u8d28\u4ee5\u53ca\u540c\u9178\u6027\u4e2d\u5fc3\u7684\u5173\u7cfb\uff0c\u8fdb\u800c\u540c\u50ac\u5316\u5242\u7684\u53cd\u5e94\u6027\u80fd\u76f8\u5173\u8054\u3002\u7814\u7a76\u50ac\u5316\u5242\u8868\u9762\u7ed3\u6784\u7f9f\u57fa\u7684\u65b9\u6cd5\u5f88\u591a\uff0c\u4f46\u5353\u6709\u6210\u6548\u7684\u662f\u7ea2\u5916\u5149\u8c31\u6cd5\u3002<\/p>\n

\u56fe4\u662fTiO2\u5728\u4e0d\u540c\u6e29\u5ea6\u62bd\u771f\u7a7a\u5f97\u5230\u7684\u8868\u9762\u7f9f\u57fa\u7ea2\u5916\u5438\u6536\u8c31\u56fe\uff0c[<\/sup>3]<\/sup>\u6bcf\u6b21\u6e29\u5ea6\u95f4\u9694\u4e3a50\u2103\u3002\u4ece\u56fe4A\u4e2d\u53ef\u77e5\u572850~200\u2103\u4e0b\u62bd\u771f\u7a7a\u65f6\uff0cTiO2<\/sub>\u8868\u9762\u542b\u67094~5\u4e2a\u4e0d\u540c\u7684\u7f9f\u57fa\u3002\u968f\u7740\u6e29\u5ea6\u5347\u9ad8\uff0c\u7f9f\u57fa\u968f\u6e29\u5ea6\u7684\u5347\u9ad8\u800c\u53d8\u5316\u7684\u8d8b\u52bf\u6709\u4e24\u79cd\uff1a\u4e00\u79cd\u662f\u6ce2\u6570\u4e3a3631.5\u00a0cm-1<\/sup>\u7684\u7f9f\u57fa\uff0c\uff0c\u5176\u5438\u6536\u5f3a\u5ea6\u968f\u7740\u6e29\u5ea6\u5347\u9ad8\u5feb\u901f\u4e0b\u964d\uff0c\u5728\u6e29\u5ea6\u4e3a150\u2103\u65f6\u5c31\u5b8c\u5168\u6d88\u5931\u3002\u53e6\u4e00\u79cd\u662f\u57283647.31\u00a0cm-1<\/sup>\u30013683.2 cm-1<\/sup>\u30013735.44 cm-1<\/sup>\u30013418.09 cm-1<\/sup>\u5904\u7684\u7f9f\u57fa\uff0c\u5176\u5438\u6536\u5f3a\u5ea6\u968f\u6e29\u5ea6\u5347\u9ad8\u9010\u6e10\u51cf\u5c0f\u81f3250\u2103\u65f6(\u56fe4B)\u51e0\u4e4e\u5b8c\u5168\u6d88\u5931\u3002\u4e24\u79cd\u7f9f\u57fa\u7684\u4e0d\u540c\u53d8\u5316\u8d8b\u52bf\u8bf4\u660e\u5438\u9644\u5728TiO2<\/sub>\u8868\u9762\u7684H2<\/sub>O\u5206\u5b50\u53ef\u80fd\u6709\u4e24\u79cd\u72b6\u6001\uff0c\u4e00\u79cd\u4e0eTiO2<\/sub>\u8868\u9762\u7ed3\u5408\u529b\u5f88\u5f31\uff0c\u5728\u8f83\u4f4e\u6e29\u5ea6\u4e0b\u5c31\u5bb9\u6613\u8131\u9644\uff1b\u800c\u53e6\u4e00\u79cd\u5219\u4e0eTiO2<\/sub>\u7ed3\u5408\u8f83\u5f3a\uff0c\u9700\u8981\u5728\u8f83\u9ad8\u7684\u6e29\u5ea6\u624d\u80fd\u5b8c\u5168\u8131\u9644\u3002\u4ece\u56fe4B\u5219\u53ef\u770b\u5230\uff0c\u5f53\u6e29\u5ea6\u9ad8\u4e8e250\u2103\u65f6\uff0c\u7f9f\u57fa\u7684\u79cd\u7c7b\u548c\u6570\u91cf\u90fd\u4e0e\u56fe4A\u90fd\u6709\u660e\u663e\u7684\u533a\u522b\uff0cTiO2<\/sub>\u8868\u9762\u53ea\u5269\u4e24\u4e2a\u7f9f\u57fa(3715.19 cm-1<\/sup>\u548c3670 cm-1<\/sup>)\uff0c\u5176\u4e2d3715.19 cm-1<\/sup>\u968f\u6e29\u5ea6\u5347\u9ad8\u7565\u6709\u589e\u5f3a\u4f46\u53d8\u5316\u5e45\u5ea6\u5f88\u5c0f\uff0c\u800c3670 cm-1<\/sup>\u7684\u5438\u6536\u5f3a\u5ea6\u5219\u968f\u6e29\u5ea6\u5347\u9ad8\u9010\u6e10\u51cf\u5c0f\uff0c\u540c\u65f6\u8fd8\u51fa\u73b0\u65b0\u7684\u3001\u5438\u6536\u5f3a\u5ea6\u5f88\u5f31\u7684\u7f9f\u57fa(3641 cm-1<\/sup>)\uff0c\u8bf4\u660e\u8fd9\u662f\u4e24\u4e2a\u4e0d\u540c\u6027\u8d28\u7684\u7f9f\u57fa\u3002<\/p>\n

\"\"<\/p>\n

\u56fe4\u00a0<\/strong>\u4e0d\u540c\u6e29\u5ea6\u4e0b\u62bd\u771f\u7a7a\u7684TiO2\u8868\u9762\u7f9f\u57fa\u7ea2\u5916\u5438\u6536\u8c31\u3002\u00a0<\/b><\/strong><\/p>\n

2.3 \u6c27\u5316\u7269\u8868\u9762\u6c27\u7269\u79cd\u7814\u7a76<\/b><\/strong><\/p>\n

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3 \u539f\u4f4d\u7ea2\u5916\u5149\u8c31\u5e94\u7528\u4e8e\u53cd\u5e94\u673a\u7406\u7814\u7a76<\/b><\/strong><\/p>\n

\u957f\u671f\u4ee5\u6765\u4eba\u4eec\u7814\u7a76\u4e86\u5404\u79cd\u5206\u5b50\u5728\u50ac\u5316\u5242\u8868\u9762\u7684\u5438\u9644\u6001\u5e76\u83b7\u5f97\u4e86\u8bb8\u591a\u91cd\u8981\u7684\u4fe1\u606f\uff0c\u4f46\u662f\u8fd9\u4e9b\u4fe1\u606f\u90fd\u662f\u5728\u53cd\u5e94\u6ca1\u6709\u53d1\u751f\u65f6\u6d4b\u5f97\u7684\u3002\u800c\u53cd\u5e94\u6761\u4ef6\u4e0b\u7684\u5438\u9644\u7269\u79cd\u7684\u7c7b\u578b\u3001\u7ed3\u6784\u3001\u6027\u80fd\u4e0e\u5438\u9644\u6761\u4ef6\u4e0b\u7684\u5438\u9644\u7269\u79cd\u7684\u7c7b\u578b\u3001\u7ed3\u6784\u3001\u6027\u80fd\u6709\u5f88\u5927\u5dee\u522b\uff0c\u56e0\u6b64\uff0c\u4ec5\u5229\u7528\u5438\u9644\u6761\u4ef6\u4e0b\u5206\u522b\u6d4b\u5f97\u7684\u5438\u9644\u7269\u79cd\u4fe1\u606f\u65e0\u6cd5\u51c6\u786e\u9610\u660e\u53cd\u5e94\u673a\u7406\uff0c\u4e3a\u6b64\uff0c\u8fdb\u884c\u53cd\u5e94\u6761\u4ef6\u4e0b\u5438\u9644\u7269\u79cd\u7684\u7814\u7a76\u5341\u5206\u5fc5\u8981\u3002\u800c\u5728\u53cd\u5e94\u6761\u4ef6\u4e0b\u50ac\u5316\u5242\u8868\u9762\u5438\u9644\u7684\u7269\u79cd\u5e76\u672a\u90fd\u53c2\u4e0e\u53cd\u5e94\uff0c\u56e0\u6b64\u5982\u4f55\u5728\u591a\u79cd\u5438\u9644\u7269\u79cd\u4e2d\u8bc6\u522b\u51fa\u53c2\u4e0e\u53cd\u5e94\u7684\u201c\u4e2d\u95f4\u7269\u79cd\u201d\u662f\u975e\u5e38\u91cd\u8981\u7684\u8bfe\u9898\u3002\u539f\u4f4d\u7ea2\u5916\u5149\u8c31\u53ef\u4ee5\u6d4b\u91cf\u50ac\u5316\u5242\u5728\u53cd\u5e94\u72b6\u6001\u4e0b\u5438\u9644\u7269\u79cd\u7684\u52a8\u6001\u884c\u4e3a\uff0c\u56e0\u6b64\u53ef\u4ee5\u83b7\u5f97\u50ac\u5316\u5242\u8868\u9762\u7269\u79cd\u7684\u52a8\u6001\u4fe1\u606f\uff0c\u5e76\u53ef\u636e\u6b64\u63a8\u65ad\u53cd\u5e94\u673a\u7406\u3002<\/p>\n

\u4f8b\u5982\uff0c\u5f20\u793c\u77e5\u6559\u6388\u8bfe\u9898\u7ec4\u4e3a\u4e86\u76f4\u63a5\u89c2\u5bdf BOC-001 \u548c BOC-010\u4e0a NO\u5149\u50ac\u5316\u6c27\u5316\u53cd\u5e94\u8fc7\u7a0b\uff0c\u91c7\u7528\u539f\u4f4d\u6f2b\u53cd\u5c04\u5085\u91cc\u53f6\u53d8\u6362\u7ea2\u5916\u5149\u8c31\u6765\u76d1\u6d4b\u50ac\u5316\u5242\u8868\u9762\u7269\u79cd\u968f\u65f6\u95f4\u7684\u53d8\u5316\uff0c[4<\/sup>]<\/sup>\u5982\u56fe 5\u6240\u793a\u4e3a\u539f\u4f4d\u7ea2\u5916\u68c0\u6d4b\u88c5\u7f6e\u7684\u6c14\u4f53\u7ba1\u7ebf\u548c\u53cd\u5e94\u6c60\u3002BOC-001 \u548c BOC-010\uff08\u56fe 6a-d\uff09\u5728NO\u548cO2<\/sub>\u6c14\u6c1b\u4e2d\uff0c\u968f\u7740\u7d2b\u5916\u5149\u7167\u5c04\u65f6\u95f4\u5ef6\u957f\u4e00\u7cfb\u5217\u5438\u6536\u5cf0\u663e\u8457\u589e\u52a0\uff0c\u8fd9\u4e9b\u5438\u6536\u5cf0\u88ab\u786e\u5b9a\u4e3a\u5404\u79cd\u4e9a\u785d\u9178\u76d0\u548c\u785d\u9178\u76d0\u3002\u901a\u8fc7\u5206\u6790\u8fd9\u4e9b\u4e9a\u785d\u9178\u76d0\u548c\u785d\u9178\u76d0\u7684\u79cd\u7c7b\uff0c\u53ef\u4ee5\u5206\u6790\u5f97\u51fa\u5149\u50ac\u5316\u6c27\u5316NO\u53cd\u5e94\u7684\u673a\u7406\u3002<\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>5<\/b><\/strong>\u00a0\u8bbe\u8ba1\u7528\u4e8e\u539f\u4f4d\u7ea2\u5916\u68c0\u6d4b\u88c5\u7f6e\u7684\u6c14\u4f53\u7ba1\u7ebf\u548c\u53cd\u5e94\u6c60\u3002\u5c06\u5927\u91cf\u7684 NO\u548cO2\u6cf5\u5165\u6765\u6784\u9020\u9971\u548c\u7684 NO\u548cO2\u6c1b\u56f4\u3002\u4e4b\u540e\u6253\u5f00\u53ef\u89c1\u5149\uff0c\u901a\u8fc7 MCT \u68c0\u6d4b\u5668\u968f\u540c\u53cd\u5e94\u539f\u4f4d\u6536\u96c6 IR \u4fe1\u53f7\u3002<\/p>\n

\"\"<\/p>\n

\u56fe6<\/b><\/strong>\u00a0BOC-001\uff08a\uff09\u548cBOC-010\uff08b\uff09\u5728UV\u4e0bNO\u5149\u50ac\u5316\u6c27\u5316\u8fc7\u7a0b\u4e2d\u7684\u539f\u4f4d FTIR \u5149\u8c31\u3002\uff08c\uff09BOC \u5728 UV \u5149\u4e0b\uff0c\u5cf0\u503c\u5f3a\u5ea6\uff081270\u00a0cm-1<\/sup>\uff09\u968f\u65f6\u95f4\u53d8\u5316\u3002\uff08d\uff09\u5728 UV \u5149\u4e0b\uff0c30\u5206\u949f\u65f6 BOC\u5149\u50ac\u5316\u6c27\u5316NO\u7684\u539f\u4f4d FTIR \u5149\u8c31\u3002\u5149\u8c31\u662f\u80cc\u666f\u6821\u6b63\u7684\u3002<\/p>\n

\u9ec4\u96c5\u4e3d\u7b49\u4eba\u5229\u7528\u900f\u5c04\u539f\u4f4d\u7ea2\u5916\u5149\u8c31\u6cd5\u7814\u7a76\u4e86Gd3+<\/sup>\u63ba\u6742TiO2<\/sub>\u5149\u50ac\u5316\u964d\u89e3\u4e59\u70ef\u7684\u6027\u80fd\uff0c\u7ed3\u679c\u8868\u660e\uff0c\u4e0eTiO2<\/sub>\u76f8\u6bd4\uff0c\u63ba\u6742Gd3+<\/sup>\u7684\u6837\u54c1\u5149\u50ac\u5316\u6d3b\u6027\u6709\u660e\u663e\u63d0\u9ad8\u3002\u5176\u5229\u7528\u539f\u4f4d\u7ea2\u5916\u5149\u8c31\u6cd5\u7814\u7a76 La\/ TiO2<\/sub>\u5bf9\u6709\u673a\u6c61\u67d3\u7269\u7684\u5149\u50ac\u5316\u964d\u89e3\uff0c\u7ed3\u679c\u8868\u660e\uff0cLa\uff0fTiO2<\/sub>\u6837\u54c1\u5bf9\u4e59\u70ef\u3001\u4e19\u916e\u3001\u82ef\u7684\u5149\u50ac\u5316\u6027\u80fd\u4e0e\u7eaf TiO2 \u76f8\u6bd4\u5747\u6709\u4e0d\u540c\u7a0b\u5ea6\u7684\u6539\u5584\uff0c\u4e59\u70ef\u53ef\u4ee5\u88ab\u5149\u50ac\u5316\u6c27\u5316\u5b8c\u5168\u77ff\u5316\u751f\u6210 CO2<\/sub>\uff0c\u800c\u4e19\u916e\u88ab\u5149\u50ac\u5316\u6c27\u5316\u53ef\u80fd\u751f\u6210\u4e2d\u95f4\u4ea7\u7269\u4e19\u9178\uff0c\u82ef\u88ab\u5149\u50ac\u5316\u6c27\u5316\u53ef\u80fd\u751f\u6210\u4e2d\u95f4\u4ea7\u7269\u82ef\u915a\u548c\u82ef\u918c\u3002[5]<\/sup><\/p>\n

\u56e0\u6b64\uff0c\u539f\u4f4d\u7ea2\u5916\u5438\u6536\u5149\u8c31\u6cd5\u662f\u4e00\u79cd\u591a\u529f\u80fd\uff0c\u4fe1\u606f\u91cf\u5927\uff0c\u4ef7\u683c\u4fbf\u5b9c\u4e14\u6613\u4e8e\u5b9e\u73b0\u7684\u6280\u672f\uff0c\u975e\u5e38\u9002\u5408\u50ac\u5316\u7cfb\u7edf\u7684\u7814\u7a76\u3002\u5b66\u4e60\u539f\u4f4d\u7ea2\u5916\u5438\u6536\u5149\u8c31\u6cd5\u53ef\u4ee5\u4e3a\u4e86\u89e3\u50ac\u5316\u5242\u7ed3\u6784\u3001\u53cd\u5e94\u52a8\u6001\u5b66\u4ee5\u53ca\u50ac\u5316\u53cd\u5e94\u7684\u4e2d\u95f4\u4ea7\u7269\u7684\u80fd\u91cf\u5b66\u63d0\u4f9b\u57fa\u7840\uff0c\u8fdb\u800c\u53ef\u4e3a\u5f00\u53d1\u65b0\u50ac\u5316\u5242\u548c\u6539\u826f\u73b0\u6709\u50ac\u5316\u5242\u63d0\u4f9b\u66f4\u6df1\u523b\u7684\u8ba4\u8bc6\u3002<\/p>\n

\u53c2\u8003\u6587\u732e\uff1a<\/p>\n

[1] Facet-dependent photocatalytic NO conversion pathways predetermined by adsorption activation patterns, Nanoscale<\/i><\/b><\/em><\/strong>,<\/i><\/b><\/em><\/strong>\u00a02019, 11, 2366-2373.<\/p>\n

[2] Oxygen Vacancies Mediated Complete Visible Light NO Oxidation\u00a0via Side-On Bridging Superoxide Radicals, Environ. Sci. Technol.<\/i><\/b><\/em><\/strong>\u00a02018, 52, 8659\u22128665.<\/p>\n

[3] TiO2<\/sub>\u8868\u9762\u7f9f\u57fa\u7684\u7ea2\u5916\u5149\u8c31\u7814\u7a76\u30022006\u5e74\u5168\u56fd\u592a\u9633\u80fd\u5149\u5316\u5b66\u4e0e\u5149\u50ac\u5316\u5b66\u672f\u4f1a\u8bae\u7279\u8f91\u3002<\/p>\n

[4] Interfacial Charging\u2212Decharging Strategy for Efficient and Selective\u00a0Aerobic NO Oxidation on Oxygen Vacancy, Environ. Sci. Technol.<\/i><\/b><\/em><\/strong>\u00a02019, 53, 6964\u22126971.<\/p>\n

[5] \u539f\u4f4d\u7ea2\u5916\u5149\u8c31\u6cd5\u7814\u7a76La\/TiO2<\/sub>\u5bf9\u6709\u673a\u6c61\u67d3\u7269\u7684\u5149\u50ac\u5316\u964d\u89e3\u3002\u65e0\u673a\u5316\u5b66\u5b66\u62a5\uff0c2006\uff0c22,\u00a01275-1281.<\/p>\n

\u672c\u6587\u7531\u5a55\u53ef\u601d\u4f9b\u7a3f\u3002<\/p>\n

\u672c\u5185\u5bb9\u4e3a\u4f5c\u8005\u72ec\u7acb\u89c2\u70b9\uff0c\u4e0d\u4ee3\u8868\u6750\u6599\u4eba\u7f51\u7acb\u573a\u3002<\/p>\n

\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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