{"id":206450,"date":"2020-08-01T06:54:28","date_gmt":"2020-07-31T22:54:28","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=206450"},"modified":"2020-07-31T20:54:54","modified_gmt":"2020-07-31T12:54:54","slug":"%e3%80%90ns%e7%b2%be%e8%af%bb%e3%80%91%e9%9d%9e%e7%a3%81%e5%8e%9f%e5%ad%90%e8%b0%83%e7%a3%81%e6%80%a7%ef%bc%8c%e6%98%af%e7%9c%9f%e7%9a%84%e5%90%97%ef%bc%9f","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=206450","title":{"rendered":"\u3010NS\u7cbe\u8bfb\u3011\u975e\u78c1\u539f\u5b50\u8c03\u78c1\u6027\uff0c\u662f\u771f\u7684\u5417\uff1f"},"content":{"rendered":"

\u4e00\u3001\u5bfc\u8bfb<\/b><\/strong><\/p>\n

\u00a0<\/b><\/strong>\u201c\u5982\u679c\u4f60\u613f\u610f\u4e00\u5c42\u4e00\u5c42\uff0c\u4e00\u5c42\u7684\u5265\u5f00\u6211\u7684\u5fc3\u3002\u3002\u3002\u3002\u201d\uff0c\u8033\u8fb9\u54cd\u8d77\u6768\u5b97\u7eac\u7684\u8fd9\u9996\u300a\u6d0b\u8471\u300b\uff0c\u50cf\u6781\u4e86\u4e8c\u7ef4\u6750\u6599\u7684\u524d\u4e16\u4eca\u751f\u3002\u4ece\u77f3\u58a8\u70ef\u6052\u661f\u7684\u95ea\u8000\uff0c\u5230\u5982\u4eca\u7684\u5f02\u5f69\u7eb7\u5448\uff0c\u4e8c\u7ef4\u4e16\u754c\u6b63\u5bf9\u6574\u4e2a\u6750\u6599\u3001\u5316\u5b66\u4ee5\u53ca\u51dd\u805a\u6001\u7269\u7406\u4f53\u7cfb\u5e26\u6765\u65b0\u7684\u53d8\u9769\uff08\u56fe1<\/b><\/strong>\uff09\u3002\u4eca\u5929\uff0c\u54b1\u5c31\u6765\u804a\u804a\u4e8c\u7ef4\u8303\u5fb7\u534e\u78c1\u6027\u6750\u6599\u4f53\u7cfb\u5e26\u6765\u7684\u65b0\u7a81\u7834\u3002<\/p>\n

\"\"<\/p>\n

\u56fe1 \u4e8c\u7ef4\u8303\u5fb7\u534e\u78c1\u4f53\u7684\u78c1\u6709\u5e8f\u6001\u5206\u5e03 <\/b><\/strong>(<\/b><\/strong>\u6e90\u81ea\u56fd\u5916\u79d1\u6280\u5a92\u4f53<\/b><\/strong>)<\/b><\/strong><\/p>\n

\u00a0<\/b><\/strong>\u8fd1\u65e5\uff0c\u6765\u81ea\u7f8e\u56fd\u6ce2\u58eb\u987f\u5b66\u9662\u3001\u82ac\u5170\u963f\u5c14\u6258\u5927\u5b66\uff0c\u4ee5\u53ca\u5fb7\u514b\u8428\u65af\u5927\u5b66\u8fbe\u62c9\u65af\u5206\u6821\u7684\u8054\u5408\u56e2\u961f\uff0c\u901a\u8fc7\u6539\u53d8\u8303\u5fb7\u534e\u78c1\u4f53CrCl3-<\/sub>x<\/i><\/sub><\/em>–<\/sub>y<\/i><\/sub><\/em>Brx<\/i><\/sub><\/em>Iy<\/i><\/sub><\/em>\u5757\u4f53\u5355\u6676\u4e2d\u7684\u975e\u78c1\u6027\u5364\u539f\u5b50\u7ec4\u5206\uff0c\u6210\u529f\u5b9e\u73b0\u4e86\u5bf9\u6750\u6599\u78c1\u6027\u7684\u8c03\u63a7\u3002\u8fd9\u4e00\u7814\u7a76\u6539\u53d8\u4e86\u4ee5\u5f80\u5b66\u672f\u754c\u5bf9\u78c1\u6027\u6750\u6599\u8c03\u63a7\u7684\u4f20\u7edf\u601d\u8def\uff0c\u5373\u53ea\u80fd\u901a\u8fc7\u8c03\u8282\u78c1\u6027\u539f\u5b50\u6765\u6539\u53d8\u78c1\u6027\u3002\u6709\u671b\u4fc3\u8fdb\u5927\u91cf\u65b0\u578b\u78c1\u6027\u6750\u6599\u7684\u8bde\u751f\uff0c\u4ece\u800c\u83b7\u5f97\u5177\u6709\u591a\u79cd\u529f\u80fd\u7684\u65b0\u578b\u6750\u6599\uff1b\u5e76\u4e14\uff0c\u8fd9\u9879\u7814\u7a76\u6709\u671b\u5bf9\u78c1\u6027\u5b58\u50a8\u3001\u65b0\u578b\u81ea\u65cb\u7535\u5b50\u6750\u6599\u7684\u53d1\u5c55\u5e26\u6765\u65b0\u7684\u542f\u793a\u3002<\/p>\n

\u4e8c\u3001\u7814\u7a76\u80cc\u666f<\/b><\/strong><\/p>\n

\u00a0<\/b><\/strong>\u4e00\u822c\u800c\u8a00\uff0c\u78c1\u6027\u6750\u6599\u7684\u6784\u6210\u5355\u5143\u4e2d\u90fd\u9700\u8981\u5b58\u5728\u5177\u6709\u672a\u6210\u5bf9\u7535\u5b50\u7684\u539f\u5b50\u3001\u79bb\u5b50\u6216\u5206\u5b50\uff0c\u56e0\u800c\uff0c\u5177\u6709\u672a\u586b\u6ee1\u58f3\u5c42\u7684d\u548cf\u533a\u5143\u7d20\u662f\u78c1\u6027\u6750\u6599\u7684\u4e3b\u8981\u6765\u6e90\uff0c\u94c1\u94b4\u954d\u7b49\u7ecf\u5178\u78c1\u4f53\u5c31\u662f\u6700\u663e\u8457\u7684\u4ee3\u8868\u3002\u8fd1\u5e74\u6765\uff0c\u968f\u7740\u5404\u79cd\u5947\u5f02\u78c1\u73b0\u8c61\u7684\u4e0d\u65ad\u53d1\u73b0\uff0c\u4ee5\u81ea\u65cb-\u8f68\u9053\u8026\u5408\uff08SOC\uff09\u4f5c\u4e3a\u57fa\u672c\u8981\u7d20\u7684\u78c1\u5b66\u73b0\u8c61\u6b63\u65e5\u6e10\u6210\u4e3a\u591a\u5b66\u79d1\u7814\u7a76\u7684\u7126\u70b9\u3002\u6bd4\u5982\uff0c\u57fa\u4e8eDzyaloshinski-Moriya\u4f5c\u7528\u7684\u65af\u683c\u660e\u5b50(Skyrmion)\u73b0\u8c61\u5c31\u6e90\u81eaSOC\u548c\u53cd\u6f14\u5bf9\u79f0\u6027\u7834\u7f3a\u3002\u800c\u76ee\u524d\u6700\u524d\u6cbf\u7684\u91cf\u5b50\u81ea\u65cb\u6db2\u4f53\u7684\u7269\u7406\u672c\u6e90\u4e5f\u540cSOC\u5bc6\u5207\u76f8\u5173\u3002\u6839\u636eMermin-Wagner\u5b9a\u7406\uff0c\u4e8c\u7ef4\u8303\u5fb7\u534e\u78c1\u4f53\u7684\u5355\u539f\u5b50\u5c42\u7684\u78c1\u6027\u7279\u5f81\u662f\u7531SOC\u4f5c\u7528\u548c\u78c1\u5404\u5411\u5f02\u6027\u51b3\u5b9a\u7684\uff0c\u540e\u8005\u5219\u4e3b\u8981\u540c\u5316\u5408\u7269\u7ec4\u6210\u4e2d\u7684\u78c1\u6027\u539f\u5b50\u76f8\u5173\uff0c\u56e0\u800c\u5927\u91cf\u7684\u7814\u7a76\u4e3b\u8981\u96c6\u4e2d\u4e8e\u901a\u8fc7\u6539\u53d8\u5316\u5408\u7269\u7684\u78c1\u6027\u539f\u5b50\u6765\u5b9e\u73b0\u5bf9\u6750\u6599\u78c1\u6001\u7684\u8c03\u63a7\u3002\u90a3\u4e48\uff0c\u95ee\u9898\u6765\u4e86\uff0c\u901a\u8fc7\u6539\u53d8\u975e\u78c1\u539f\u5b50\u7684\u7ec4\u6210\u80fd\u5426\u5b9e\u73b0\u5bf9\u78c1\u6027\u7684\u8c03\u63a7\uff1f\u8fd9\u4e00\u8fdd\u80cc\u76f4\u89c9\u7684\u6784\u60f3\u7a76\u7adf\u662f\u5929\u65b9\u591c\u8c2d\uff0c\u8fd8\u662f\u53e6\u6709\u4e7e\u5764\uff1f<\/p>\n

\u4ee5\u7f8e\u56fd\u6ce2\u58eb\u987f\u5b66\u9662\u7684Fazel Tafti\u535a\u58eb\u9886\u8854\u7684\u56e2\u961f\uff0c\u4ee5\u201cAccessing new magnetic regimes by tuning the ligand spin-orbit coupling in van der Waals magnets<\/i><\/em>\u201d\u4e3a\u9898\u53d1\u8868\u5728Science Advances<\/i><\/b><\/em><\/strong>\u4e0a\u7684\u8fd9\u9879\u6700\u65b0\u7814\u7a76\u5e26\u6765\u4e86\u8fd9\u4e00\u6784\u60f3\u7684\u521d\u6b65\u7b54\u6848\uff0c\u636e\u6089\uff0c\u8fd9\u4e00\u6210\u679c\u7684\u7b2c\u4e00\u4f5c\u8005\u4e3a\u8be5\u6821\u7684\u4e00\u540d\u672c\u79d1\u751fThomas A. Tartaglia\uff0c\u96be\u80fd\u53ef\u8d35\u3002<\/p>\n

\u00a0<\/b><\/strong>\u4e09\u3001\u79d1\u5b66\u521b\u65b0\u70b9<\/b><\/strong><\/p>\n

1. \u901a\u8fc7\u8c03\u63a7\u975e\u78c1\u5364\u539f\u5b50\u6784\u7b51\u4e86<\/b><\/strong>CrCl<\/b><\/strong>3-<\/b><\/sub><\/strong>x<\/i><\/b><\/sub><\/em><\/strong>–<\/b><\/sub><\/strong>y<\/i><\/b><\/sub><\/em><\/strong>Br<\/b><\/strong>x<\/i><\/b><\/sub><\/em><\/strong>I<\/b><\/strong>y<\/i><\/b><\/sub><\/em><\/strong>\u5408\u91d1\u4f53\u7cfb\u5b8c\u6574\u78c1\u76f8\u56fe<\/b><\/strong>\uff1b<\/b><\/strong><\/p>\n

2. \u901a\u8fc7<\/b><\/strong>\u914d\u4f53\u95f4\u63a5\u4ea4\u6362\u4f5c\u7528<\/b><\/strong>(<\/b><\/strong>\u6539\u53d8\u975e\u78c1\u914d\u4f53\u7684\u81ea\u65cb-\u8f68\u9053\u8026\u5408\u4f5c\u7528<\/b><\/strong>)<\/b><\/strong>\uff0c\u5b9e\u73b0\u4e86\u5bf9\u5c42\u72b6\u6750\u6599\u78c1\u76f8\u4e92\u4f5c\u7528\u7684\u8c03\u63a7\uff0c\u5373\u78c1\u632b\u6027\u3001\u78c1\u573a\u8bf1\u5bfc\u7684\u5c42\u95f4\u53cd\u94c1\u78c1\u5230\u94c1\u78c1\u8f6c\u53d8\uff1b<\/b><\/strong><\/p>\n

3. \u4ec5\u901a\u8fc7\u8c03\u63a7\u5364\u7d20\u5408\u91d1\u7684\u7ec4\u5206\uff0c\u5b9e\u73b0\u4e86\u5728<\/b><\/strong>\u5757\u4f53\u8303\u5fb7\u534e\u78c1\u4f53\u4e2d\u7684\u78c1\u6027\u8c03\u63a7<\/b><\/strong>\u3002<\/b><\/strong><\/p>\n

\u00a0<\/b><\/strong>\u56db\u3001\u6838\u5fc3\u6570\u636e\u89e3\u8bfb<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u00a0<\/b><\/strong>\u56fe2 \u8303\u5fb7\u534e\u5408\u91d1<\/b><\/strong>CrCl<\/b><\/strong>3-<\/b><\/sub><\/strong>x<\/i><\/b><\/sub><\/em><\/strong>–<\/b><\/sub><\/strong>y<\/i><\/b><\/sub><\/em><\/strong>Br<\/b><\/strong>x<\/i><\/b><\/sub><\/em><\/strong>I<\/b><\/strong>y<\/i><\/b><\/sub><\/em><\/strong>\u7684\u6676\u4f53\u7ed3\u6784<\/b><\/strong><\/p>\n

\u5177\u6709\u8702\u7a9d\u5c42\u72b6\u7ed3\u6784\u7684<\/b><\/strong>CrCl<\/b><\/strong>3-<\/b><\/sub><\/strong>x<\/i><\/b><\/sub><\/em><\/strong>–<\/b><\/sub><\/strong>y<\/i><\/b><\/sub><\/em><\/strong>Br<\/b><\/strong>x<\/i><\/b><\/sub><\/em><\/strong>I<\/b><\/strong>y<\/i><\/b><\/sub><\/em><\/strong>\u901a\u8fc7\u5316\u5b66\u6c14\u76f8\u8f93\u8fd0\u65b9\u6cd5\u5408\u6210<\/b><\/strong><\/p>\n

\uff08\u7070\uff0c\u84dd\uff0c\u7eff\u548c\u7ea2\u8272\u5c0f\u7403\u5206\u522b\u4ee3\u8868\uff1aCr<\/b><\/strong>3+<\/b><\/sup><\/strong>\uff0cCl<\/b><\/strong>–<\/b><\/sup><\/strong>\uff0cBr<\/b><\/strong>–<\/b><\/sup><\/strong>\uff0c\u548cI<\/b><\/strong>–<\/b><\/sup><\/strong>\uff09<\/b><\/strong><\/p>\n

\u5982\u56fe2<\/b><\/strong>\u6240\u793a\uff0c\u4e8c\u7ef4\u8702\u7a9d\u5c42\u72b6\u7ed3\u6784\u7531\u56f4\u7ed5Cr3+<\/sup>\u79bb\u5b50\u7684\u5171\u68f1\u516b\u9762\u4f53\u7ec4\u6210\uff0c\u5176\u4e2d\uff0cCr3+<\/sup>\u79bb\u5b50\u7684t<\/i><\/em>2g<\/sub>\u8f68\u9053\u4e0a\u6709\u4e09\u4e2a\u7535\u5b50\uff0c\u603b\u81ea\u65cb\u91cf\u5b50\u6570\u4e3a2\/3\u3002\u7531\u4e8eCrClx<\/i><\/sub><\/em>I3-<\/sub>x<\/i><\/sub><\/em>\u7ec4\u5206\u4e2d\u7684\u5364\u7d20\u539f\u5b50\u534a\u5f84\u76f8\u5dee\u8f83\u5927\uff0c\u56e0\u6b64\u6ca1\u6709\u6210\u529f\u5f97\u5230\u8be5\u7ec4\u5206\u7684\u6676\u4f53\uff0c\u5728\u56fe3<\/b><\/strong>\u76f8\u56fe\u7684\u9ed1\u8272\u533a\u57df\u4ee3\u8868\u4e86\u53ef\u80fd\u7684\u4e0d\u6eb6\u8fb9\u754c\u3002\u56e0\u800c\uff0c\u6eb4\u539f\u5b50\u5728\u6676\u4f53\u7684\u5f62\u6210\u4e2d\u53ef\u80fd\u8d77\u5230\u4e86\u5173\u952e\u4f5c\u7528\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3 <\/b><\/strong>CrCl<\/b><\/strong>3-<\/b><\/sub><\/strong>x<\/i><\/b><\/sub><\/em><\/strong>–<\/b><\/sub><\/strong>y<\/i><\/b><\/sub><\/em><\/strong>Br<\/b><\/strong>x<\/i><\/b><\/sub><\/em><\/strong>I<\/b><\/strong>y<\/i><\/b><\/sub><\/em><\/strong>\u5408\u91d1\u7684\u4e09\u5143\u76f8\u56fe\uff08\u53d8\u91cf\u4e3a\u5364\u7d20\u539f\u5b50\u7684\u542b\u91cf\uff09<\/b><\/strong><\/p>\n

\u56fe3<\/b><\/strong>\u4e3a\u91c7\u7528\u65bd\u52a0\u5e73\u884c\u4e8e\u8702\u7a9d\u9762\u7684\u78c1\u573a\u6d4b\u8bd5\u7684\u4e09\u5143\u76f8\u56fe\uff0c\u5c45\u91cc(T<\/i><\/em>C<\/sub>)\u548c\u5916\u65af\u6e29\u5ea6(\u03b8W<\/sub>)\u53ef\u4ee5\u901a\u8fc7\u5364\u7d20\u7ec4\u5206\u7684\u6539\u53d8\u5b9e\u73b0\u8fde\u7eed\u53ef\u8c03\uff0c\u4ece\u800c\u5927\u5927\u6269\u5c55\u4e86\u5364\u5316\u94ec\u4f53\u7cfb\u7684\u8303\u5fb7\u534e\u78c1\u4f53\u79cd\u7c7b\uff0c\u5e76\u4e14\u5177\u6709\u53ef\u63a7\u7684\u78c1\u6027\u3002\u5e76\u4e14\u6839\u636e\u76f8\u56fe\u53ef\u4ee5\u6e05\u6670\u7684\u5f97\u51fa\uff0c\u9760\u8fd1CrCl3\u7ec4\u5206\u7684\u4e24\u4e2a\u8f6c\u53d8\u6e29\u5ea6\u6700\u5c0f\uff0c\u9760\u8fd1CrI3<\/sub>\u7ec4\u5206\u7684\u5219\u6700\u5927\uff0c\u4ece\u800c\u8868\u660e\uff0c\u968f\u7740\u5364\u7d20\u79bb\u5b50\u534a\u5f84\u7684\u589e\u5927\uff0cT<\/i><\/em>C<\/sub>\u548c\u03b8W<\/sub>\u6e29\u5ea6\u5448\u73b0\u589e\u52a0\u7684\u8d8b\u52bf\u3002<\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u56fe4 \u78c1\u963b\u632b\u76f8\u56fe\uff08<\/b><\/strong>f<\/i><\/b><\/em><\/strong>\u4e3a\u78c1\u963b\u632b\u56e0\u5b50\uff09<\/b><\/strong><\/p>\n

\u6b64\u5916\uff0c\u6839\u636e\u4e09\u5364\u5316\u94ec\u4f53\u7cfb\u7684\u54c8\u5bc6\u987f\u91cf\uff0c\u7814\u7a76\u8005\u8fd8\u5b9a\u6027\u7684\u7ed9\u51fa\u4e86\u53ef\u80fd\u5b58\u5728\u78c1\u963b\u632b\u7279\u6027\u7684\u76f8\u56fe\uff08\u56fe4<\/b><\/strong>\uff09\u3002\u5177\u6709\u78c1\u963b\u632b\u7279\u6027\u7684\u7ec4\u5206\u66f4\u9760\u8fd1\u5bcc\u6c2f\u7ec4\u5206\uff0c\u5176\u4e2d\uff0c\u963b\u632b\u56e0\u5b50\u6700\u5927\u7684\u7ec4\u5206\u4e3aCrCl2.55<\/sub>Br0.45<\/sub>\uff0c\u5e76\u8fdb\u4e00\u6b65\u901a\u8fc7DFT\u8ba1\u7b97\u5f97\u4ee5\u9a8c\u8bc1\u3002<\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u56fe5 \u5757\u4f53\u5408\u91d1\u7684\u53d8\u78c1\u8f6c\u53d8<\/b><\/strong><\/p>\n

\u00a0<\/b><\/strong>(a)<\/b><\/strong>\u00a0CrCl<\/b><\/strong>0.8<\/b><\/sub><\/strong>Br<\/b><\/strong>1.2<\/b><\/sub><\/strong>I<\/b><\/strong>1.0<\/b><\/sub><\/strong>\u7ec4\u5206\u7684M-B\u66f2\u7ebf\uff08\u7ea2\u548c\u84dd\u8272\u66f2\u7ebf\u5206\u522b\u8868\u793a\u5782\u76f4\u548c\u5e73\u884c\u4e8e\u8702\u7a9d\u5c42\u7684\u78c1\u573a\u6761\u4ef6<\/b><\/strong>;(b)<\/b><\/strong>\u653e\u5927\u7684\u5c40\u90e8\u66f2\u7ebf\u89c6\u56fe\uff1b<\/b><\/strong>(c)<\/b><\/strong>\u00a0\u6837\u54c1\u7684\u5149\u5b66\u7167\u7247\u3001\u626b\u63cf\u7535\u955c\u56fe\u50cf\u4ee5\u53caEDX\u5143\u7d20\u6210\u50cf\u56fe<\/b><\/strong><\/p>\n

\u6b64\u5916\uff0c\u8fd9\u9879\u6210\u679c\u7684\u7b2c\u4e8c\u4e2a\u91cd\u8981\u53d1\u73b0\u662f\u5728\u5757\u4f53\u5355\u6676\u7684\u5b58\u5728\u78c1\u573a\u8bf1\u5bfc\u7684\u53d8\u78c1\u8f6c\u53d8(metamagnetic transition)\u3002\u56fe5a-b<\/b><\/strong>\u7684\u6570\u636e\u663e\u793a\uff0c\u5f53\u78c1\u573a\u5782\u76f4\u65bd\u52a0\u65f6\u624d\u4f1a\u4ea7\u751f\u53cd\u94c1\u78c1\u5411\u94c1\u78c1\u6709\u5e8f\u7684\u8f6c\u53d8\uff0c\u4e34\u754c\u78c1\u573a\u4e3a0.7T\u3002\u8fd9\u662f\u9996\u6b21\u5728\u8be5\u7c7b\u4e8c\u7ef4\u78c1\u4f53\u7684\u5757\u4f53\u5355\u6676\u4e2d\u89c2\u5bdf\u5230\u8fd9\u4e00\u73b0\u8c61\u3002\u4e4b\u524d\u7684\u62a5\u9053\u4e3b\u8981\u96c6\u4e2d\u4e8e\u53cc\u5c42\u4e8c\u7ef4\u6837\u54c1\u4e2d\uff08Nature 546, 270\u2013273 (2017)<\/i><\/em>\uff1b<\/i><\/em>Nat. Nanotechnol. 13, 549\u2013553 (2018)<\/i><\/em>.\uff09\u8fdb\u4e00\u6b65\u7684\u5143\u7d20\u548c\u5f62\u8c8c\u8868\u5f81\uff08\u56fe5c\uff09\u63ed\u793a\u4e86\u8fd9\u4e00\u73b0\u8c61\u7684\u4ea7\u751f\u5e76\u975e\u539f\u5b50\u5316\u5b66\u65e0\u5e8f\uff0c\u5e94\u8be5\u662f\u6765\u81ea\u6750\u6599\u7684\u672c\u5f81\u7279\u6027\u3002<\/p>\n

\u4e94<\/b><\/strong>\u3001<\/b><\/strong>\u6210\u679c\u542f\u793a<\/b><\/strong>\u00a0<\/b><\/strong><\/p>\n

\u8fd9\u9879\u6700\u65b0\u6210\u679c\u63ed\u793a\u4e86\u975e\u78c1\u6027\u539f\u5b50\u7684SOC\u53ef\u4ee5\u5b9e\u73b0\u5bf9\u4f53\u7cfb\u6574\u4f53\u78c1\u76f8\u4e92\u4f5c\u7528\u7684\u8c03\u8282\uff0c\u4ece\u800c\u8bf1\u53d1\u5404\u79cd\u65b0\u5947\u7684\u78c1\u6548\u5e94\uff0c\u5982\u963b\u632b\u3001\u91cf\u5b50\u81ea\u65cb\u6db2\u4f53\u3001\u91cf\u5b50\u4e34\u754c\u76f8\u53d8\u7b49\u3002\u4f46\u8fd9\u4e00\u7814\u7a76\u4ec5\u4ec5\u63ed\u793a\u4e86\u8fd9\u4e00\u5168\u65b0\u9886\u57df\u7684\u51b0\u5c71\u4e00\u89d2\uff0c\u5176\u4e2d\u4ecd\u6709\u4e00\u4e9b\u4e9f\u5f85\u89e3\u51b3\u7684\u79d1\u5b66\u70b9\u503c\u5f97\u7ee7\u7eed\u63a2\u5bfb\u3002\u7b14\u8005\u4ee5\u4e3a\uff0c\u4ee5\u4e0b\u65b9\u9762\u503c\u5f97\u6750\u6599\u7269\u7406\u754c\u7684\u540c\u884c\u7ee7\u7eed\u5f00\u5c55\u6df1\u5165\u63a2\u7d22\uff1a<\/p>\n

\u6750\u6599\u5408\u6210\u65b9\u9762\uff1a<\/b><\/strong><\/p>\n

\u80fd\u5426\u5b9e\u73b0<\/b><\/strong>CrCl<\/b><\/strong>x<\/i><\/b><\/sub><\/em><\/strong>I<\/b><\/strong>3-<\/b><\/sub><\/strong>x<\/i><\/b><\/sub><\/em><\/strong>\u5316\u5b66\u7ec4\u6210\u7684\u5355\u6676\u548c\u4e8c\u7ef4\u6750\u6599\u7684\u5408\u6210\uff1f<\/b><\/strong><\/p>\n

\u80fd\u5426\u540c\u65f6\u5b9e\u73b0\u78c1\u6027\u539f\u5b50\u63ba\u6742Cr\u4f4d\u7684\u591a\u91cd\u63ba\u6742\u6676\u4f53\u7684\u5408\u6210\uff1f<\/b><\/strong><\/p>\n

\u6750\u6599\u7269\u7406\u65b9\u9762\uff1a<\/b><\/strong><\/p>\n

\u901a\u8fc7\u975e\u78c1\u7ec4\u5206\u8c03\u63a7\uff0c\u80fd\u5426\u5728\u8303\u5fb7\u534e\u78c1\u4f53\u4e2d\u8fdb\u4e00\u6b65\u5b9e\u73b0\u91cf\u5b50\u4e34\u754c\u4e0e\u91cf\u5b50\u6db2\u4f53\uff1f<\/b><\/strong><\/p>\n

\u6784\u7b51\u975e\u78c1\u7ec4\u5206\u7f3a\u9677\uff0c\u80fd\u5426\u5b9e\u73b0\u540c\u8c03\u63a7\u7ec4\u5206\u7c7b\u4f3c\u7684\u78c1\u6001\u8c03\u8282\uff0c\u5176\u80cc\u540e\u7684\u7269\u7406\u673a\u5236\u662f\u4ec0\u4e48\uff1f<\/b><\/strong><\/p>\n

\u6210\u679c\u4fe1\u606f\uff1a<\/b><\/strong><\/p>\n

Accessing new magnetic regimes by tuning the ligand spin-orbit coupling in van der Waals magnets<\/p>\n

Science Advances<\/i><\/em>\u00a0(2020).\u00a0DOI: 10.1126\/sciadv.abb9379<\/u><\/a><\/p>\n

\u672c\u6587\u7531Free-Writon<\/i><\/em>\u4f9b\u7a3f\u3002<\/p>\n

\u672c\u5185\u5bb9\u4e3a\u4f5c\u8005\u72ec\u7acb\u89c2\u70b9\uff0c\u4e0d\u4ee3\u8868\u6750\u6599\u4eba\u7f51\u7acb\u573a\u3002<\/p>\n

\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u4e00\u3001\u5bfc\u8bfb \u00a0\u201c\u5982\u679c\u4f60\u613f\u610f\u4e00\u5c42\u4e00\u5c42\uff0c\u4e00\u5c42\u7684\u5265\u5f00\u6211\u7684\u5fc3\u3002\u3002\u3002\u3002\u201d\uff0c\u8033\u8fb9\u54cd\u8d77\u6768\u5b97\u7eac\u7684\u8fd9\u9996\u300a\u6d0b\u8471\u300b\uff0c\u50cf\u6781\u4e86\u4e8c\u7ef4\u6750\u6599\u7684\u524d\u4e16\u4eca\u751f\u3002\u4ece\u77f3\u58a8\u70ef\u6052\u661f\u7684\u95ea\u8000\uff0c\u5230\u5982\u4eca\u7684\u5f02\u5f69\u7eb7\u5448\uff0c\u4e8c\u7ef4…<\/p>\n","protected":false},"author":11454,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-206450","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/206450"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=206450"}],"version-history":[{"count":2,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/206450\/revisions"}],"predecessor-version":[{"id":206638,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/206450\/revisions\/206638"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=206450"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=206450"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=206450"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}