{"id":207800,"date":"2020-08-23T06:49:47","date_gmt":"2020-08-22T22:49:47","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=207800"},"modified":"2020-08-22T17:49:56","modified_gmt":"2020-08-22T09:49:56","slug":"%e8%b7%9f%e7%9d%80%e9%a1%b6%e5%88%8a%e5%ad%a6%e6%b5%8b%e8%af%95%ef%bd%9c%e6%8b%89%e6%9b%bc%e5%85%89%e8%b0%b1%e5%b8%a6%e4%bd%a0%e7%8e%a9%e8%bd%ac%e5%8a%9f%e8%83%bd%e5%8c%96%e7%9f%b3%e5%a2%a8%e7%83%af","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=207800","title":{"rendered":"\u8ddf\u7740\u9876\u520a\u5b66\u6d4b\u8bd5\uff5c\u62c9\u66fc\u5149\u8c31\u5e26\u4f60\u73a9\u8f6c\u529f\u80fd\u5316\u77f3\u58a8\u70ef"},"content":{"rendered":"<p>\u62c9\u66fc\u5149\u8c31\u5728\u5206\u6790\u63ba\u6742\u6548\u5e94\uff0c\u5e94\u53d8\uff0c\u6c27\u5316\u548c\u6837\u54c1\u7684\u8d28\u91cf\uff0c\u5206\u5b50\u529f\u80fd\u5316\u548c\u5c42\u6570\u65b9\u9762\u6709\u7740\u975e\u5e38\u5927\u7684\u4f5c\u7528\u3002\u5178\u578b\u7684\u62c9\u66fc\u632f\u52a8\u6a21\u5f0f\u7279\u5f81\u5bf9\u6837\u54c1\u7684\u7ec4\u6210\u7ed3\u6784\u548c\u529f\u80fd\u57fa\u56e2\u5177\u6709\u91cd\u8981\u7684\u6307\u793a\u610f\u4e49\u3002\u6240\u4ee5\uff0c\u9488\u5bf9\u529f\u80fd\u5316\u77f3\u58a8\u70ef\u884d\u751f\u7269\u7684\u529f\u80fd\u57fa\u56e2\u7684\u5206\u6790\u6311\u6218\uff0c\u5f17\u91cc\u5fb7\u91cc\u5e0c-\u4e9a\u5386\u5c71\u5927 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LabRAM\u5171\u805a\u7126\u62c9\u66fc\u663e\u5fae\u955c(\u6fc0\u53d1\u6ce2\u957f:405\u3001457\u3001473\u3001532\u548c633\u00a0nm)\uff0c\u5176\u6fc0\u5149\u5149\u6591\u5c3a\u5bf8\u7ea6\u4e3a1\u00a0\u03bcm\u3002<\/p>\n<p>\u5de5\u6b32\u5584\u5176\u4e8b\uff0c\u5fc5\u5148\u5229\u5176\u5668\uff0c\u4e86\u89e3\u4e86\u6d4b\u8bd5\u6761\u4ef6\u4e4b\u540e\uff0c\u63a5\u4e0b\u6765\u5c31\u770b\u770b\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\u5982\u4f55\u5c06\u65e0\u7f3a\u9677\u7684KC<sub>8<\/sub>\u77f3\u58a8\u5316\u5408\u7269\u5728\u529f\u80fd\u5316\u4e4b\u540e\u7684\u53d8\u5316\u663e\u73b0\u51fa\u6765\u3002\u9996\u5148\uff0c\u5c06\u5408\u6210\u7684GIC\u66b4\u9732\u5728H<sub>2<\/sub>O\u84b8\u6c7d\u4e0b\uff0c\u968f\u7740\u66b4\u9732\u65f6\u95f4\u7684\u63a8\u957f\uff0c\u8868\u660e\u529f\u80fd\u5316\u7684GIC\u4e0d\u540c\u6a21\u6001\u7684\u53d8\u5316\u663e\u800c\u6613\u89c1\u3002\u4ece\u62c9\u66fc\u5149\u8c31\u56fe\u4e2d\u8be6\u7ec6\u7684\u7ebf\u5f62\u5206\u6790\u4e2d\u53ef\u4ee5\u786e\u5b9a7\u4e2a\u4e3b\u8981\u7279\u5f81\u5cf0\u3002\u6700\u7a81\u51fa\u7684\u662f\u77f3\u58a8E<sub>2g<\/sub>\u00a0G\u6a21\u5f0f\uff08~1575\u00a0cm<sup>-1<\/sup>\uff09\u5904\u7684\u53d8\u5316\u3002\u800c\u9664\u53bb\u4f17\u6240\u5468\u77e5\u7684D\u6a21\u5f0f\uff08~1340\u00a0cm<sup>-1<\/sup>\uff09\uff0c\u9996\u6b21\u786e\u5b9a\u4e86\u5176\u4ed65\u4e2a\u632f\u52a8\u6a21\u5f0f\uff08D<sub>1<\/sub>-D<sub>5<\/sub>\uff09\u7684\uff0c\u5206\u522b\u662fD<sub>1<\/sub>\uff08~1325 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loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-207803 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72473-24.png\" alt=\"\" width=\"600\" height=\"467\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72473-24.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72473-24-300x234.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/> <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-207804 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72474-20.png\" alt=\"\" width=\"600\" height=\"98\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72474-20.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72474-20-300x49.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u4e3a\u4e86\u786e\u5b9a\u5728~1580\u00a0cm<sup>-1<\/sup>\u7684\u77f3\u58a8\u70ef\u4e2d\u5f15\u5165sp<sup>3<\/sup>\u7f3a\u9677\u4f4d\u70b9\u548c\u76f8\u5bf9\u5e94\u989d\u5916\u7684C-C\u632f\u52a8\u6a21\u5f0f\u6240\u5f15\u8d77\u7684\u504f\u79bb\u6b63\u5e38\u7684\u6676\u683c\u78b3\u952e\u632f\u52a8\u8026\u5408\u7684E<sub>2g<\/sub>\u00a0G\u548cC=C sp<sup>2<\/sup>\u6a21\u5f0f\uff0c\u8ba1\u7b97\u4e86\u539f\u59cb\u77f3\u58a8\u70ef\u9644\u52a0-H\u6216-OH\u57fa\u56e2\u4e4b\u540e\u7684\u62c9\u66fc\u632f\u52a8\u54cd\u5e94\u3002\u5efa\u7acb\u7684\u6a21\u578b\u662f1\u4e2a-H\u6216-OH\u57fa\u56e2(~3.125%\u7684\u81ea\u7531\u5ea6)\u529f\u80fd\u5316\u7684\u77f3\u58a8\u70ef(32\u4e2a\u6676\u683c\u78b3\u539f\u5b50)\u76844\u00d74\u8d85\u6676\u80de\u3002\u9644\u52a0sp<sup>3<\/sup>\u6742\u5316\u7684\u6676\u683c\u78b3\u539f\u5b50\u88ab\u6807\u8bb0\u4e3aC<sub>A<\/sub>\uff0c\u800c\u76f4\u63a5\u76f8\u90bb\u7684\u57fa\u78b3\u539f\u5b50\u88ab\u6807\u8bb0\u4e3aC<sub>B<\/sub>\uff0cC<sub>B<\/sub>\u65c1\u8fb9\u7684\u662fC<sub>C<\/sub>\u548cC<sub>D<\/sub>\u3002\u8ba1\u7b97\u5f97\u5230\u7684\u52a0\u6c22G-H\u548c\u7f9f\u57faG-OH\u7684\u62c9\u66fc\u5149\u8c31\u5206\u522b\u5982\u56fe2d\u6240\u793a\u3002\u5728G-H\u60c5\u51b5\u4e0b\uff0cG-H\u6742\u5316\u7684\u53d8\u5316\u662f\u4f34\u968f\u7740\u6c22\u5316\u7684C\u539f\u5b50\u5728z\u65b9\u5411\u4e0a\u63d0\u53470.46\u00a0\u00c5\u00a0(\u56fe2c)\u3002\u968f\u7740\u8fd9\u4e00\u4f4d\u79fb\uff0c\u77f3\u58a8\u70ef\u7684C<sub>B<\/sub>-C<sub>A<\/sub>-C<sub>B<\/sub>\u4e8c\u9762\u89d2\u4ece\u03b3=120\u00b0\u5f00\u59cb\u53d8\u5316\u5230G-H\u7684\u03b3=114.5\u00b0\u548cG-OH\u7684\u03b3=113.7\u00b0\u3002\u7406\u8bba\u5206\u6790\u7ed9\u51fa\u4e86sp<sup>3<\/sup>\u7f3a\u9677\u5468\u56f4\u6676\u683c\u78b3\u539f\u5b50\u6fc0\u53d1\u7684\u58f0\u5b50\u80fd\u91cf\u53d7\u65b0\u5f62\u6210\u7684C-H\u952e\u7684\u5f71\u54cd\u3002\u7531\u4e8eC-H\/sp<sup>3<\/sup>\u4e2d\u5fc3\u7684\u51e0\u4f55\u7ed3\u6784\u504f\u79bb\u4e86\u6b63\u56db\u9762\u4f53\u7684\u89d2\u5ea6109.5\u00b0\uff0c\u6240\u4ee5\u56f4\u7ed5C-H\/sp<sup>3<\/sup>\u4e2d\u5fc3(\u03b3 (C<sub>B<\/sub>C<sub>A<\/sub>C<sub>B<\/sub>)=114.5\u00b0)\u7684\u51e0\u4f55\u7ed3\u6784\u53d1\u751f\u4e86\u6536\u7f29\uff0c\u540c\u65f6\u4ea7\u751f\u4e861300\u00a0cm<sup>-1<\/sup>\u548c1600\u00a0cm<sup>-1<\/sup>\u4e2d\u51fa\u73b0\u7684\u989d\u5916\u632f\u52a8\u6a21\u5f0fD<sub>1<\/sub>-D<sub>5<\/sub>\u7279\u5f81\u5cf0\u3002\u5f53\u81ea\u7531\u5ea6\u589e\u52a0\u65f6\uff0c\u5f2f\u66f2\u7ed3\u6784\u91d1\u521a\u77f3\u56e2\u7c07\u7ed3\u6784\u6700\u7ec8\u4f1a\u5f3a\u70c8\u91cd\u7ec4nK<sup>+<\/sup>C<sub>8<\/sub><sup>(n-x)-<\/sup>H<sub>x<\/sub>\u548cnK<sup>+<\/sup>C<sub>8<\/sub><sup>(n-x)-<\/sup>H<sub>x<\/sub>(OH)<sub>y<\/sub>\u7684\u62c9\u66fc\u5149\u8c31\u3002\u65b0\u89c2\u5bdf\u5230\u7684D<sub>1<\/sub>-D<sub>5<\/sub>\u6a21\u5f0f\u53ea\u5728\u8d85\u8fc7\u4e00\u5b9a\u7684\u81ea\u7531\u5ea6(~0.5%)\u540e\u624d\u5f00\u59cb\u51fa\u73b0\u5728\u5149\u8c31\u4e2d\u3002\u5728\u66f4\u9ad8\u7684\u5b98\u80fd\u5316\u7a0b\u5ea6\u4e0b(&gt;3%)\uff0c\u5982\u6c27\u5316\u77f3\u58a8\u70ef\u4e2d\uff0c\u8fd9\u4e9b\u6a21\u5f0f\u4f1a\u53d8\u5bbd\uff0c\u5bfc\u81f4\u62c9\u66fc\u5149\u8c31\u7684\u7ed3\u6784\u5927\u5927\u964d\u4f4e\u3002\u6240\u4ee5\u5728\u529f\u80fd\u5316\u8303\u56f4\u4e3a0.5%~2%\u5185\u5f97\u5230\u7684D<sub>1<\/sub>-D<sub>5<\/sub>\u6a21\u5f0f\u7684\u5206\u8fa8\u7387\u548c\u5206\u5e03\u53ef\u8fbe\u6700\u4f73\u6548\u679c\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-207805 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72475-18.png\" alt=\"\" width=\"600\" height=\"491\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72475-18.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72475-18-300x246.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/> <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-207806 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72476-15.png\" alt=\"\" width=\"600\" height=\"100\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72476-15.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72476-15-300x50.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u4e3a\u4e86\u8fdb\u4e00\u6b65\u8bc1\u660e\u62c9\u66fc\u5149\u8c31\u8868\u5f81\u7684\u4f5c\u7528\u529b\uff0c\u4f5c\u8005\u5bf9\u9ad8\u5ea6\u529f\u80fd\u5316\u7684\u77f3\u58a8\u70ef\u8fdb\u884c\u4e86\u8868\u5f81\u3002\u5229\u7528\u56db\u6c22\u544b\u5583(THF)\u5236\u5907\u51fa\u77f3\u58a8\u70ef\u8584\u7247\uff0c\u518d\u5c06\u5176\u66b4\u9732\u5728\u6c27\u6c14\u548c\u6c34\u84b8\u6c14\u4e2d\uff0c\u68c0\u6d4b\u5176\u62c9\u66fc\u7279\u5f81\u5cf0\u3002\u5728~1200\u00a0cm<sup>-1<\/sup>\u81f3~1600\u00a0cm<sup>-1<\/sup>\u4e4b\u95f4\u7684\u62c9\u66fc\u4f4d\u79fb\u4f53\u7cfb\u4e2d\u53ef\u4ee5\u89c2\u5bdf\u5230\u4e09\u79cd\u5e7f\u6cdb\u7684\u91cd\u53e0\u6a21\u5f0f\uff0c\u5728\u53cc\u5171\u632f\u533a~2500\u00a0cm<sup>-1<\/sup>\u81f3~3400\u00a0cm<sup>-1<\/sup>\u4e4b\u95f4\uff0c\u4e09\u4e2a\u4e3b\u8981\u7ec4\u62102D\uff0cD+G\u548c2D*\u53ef\u4ee5\u88ab\u8bc6\u522b\u3002\u5c06\u4e0e\u7f3a\u9677\u90e8\u4f4d\u76f8\u5173D\u2019\u2019\u2019\uff0cD\u2019\u2019\u548cD\u2019\u7684\u62c9\u66fc\u632f\u52a8\u6a21\u5f0f\u62df\u5408\u5230\u62c9\u66fc\u56fe\u8c31\u4e2d\uff0c\u8fd9\u4e9b\u632f\u52a8\u6a21\u5f0f\u4e0e\u4e4b\u524d\u7684\u8f7b\u5ea6\u529f\u80fd\u5316\u7684D<sub>1<\/sub>-D<sub>5<\/sub>\u632f\u52a8\u6a21\u5f0f\u7684\u62c9\u66fc\u4f4d\u79fb\u4f4d\u7f6e\u662f\u76f8\u540c\u3002\u56e0\u6b64\uff0cD<sub>1<\/sub>\u3001D<sub>2<\/sub>\/D<sub>3<\/sub>\u548cD<sub>4<\/sub>\/D<sub>5<\/sub>\u6a21\u6001\u53ef\u4ee5\u4e0eD\u2019\u2019\u2019\uff0cD\u2019\u2019\u548cD\u2019\u95f4\u5e26\u76f8\u5173\u8054\u3002\u8fd9\u4e9b\u632f\u52a8\u6a21\u5f0f\u5206\u914d\u5230\u8ba1\u7b97\u632f\u52a8\u6a21\u5f0f\u4e2d\uff0c\u5206\u522b\u4e3aC<sub>A<\/sub>-C<sub>B<\/sub>(D1\uff0cD\u2019\u2019\u2019)\uff0cC<sub>B<\/sub>-C<sub>C<\/sub>(D<sub>2<\/sub>\/D<sub>3<\/sub>\uff0cD\u2019\u2019)\u548cC<sub>C<\/sub>-C<sub>D<\/sub>\u00a0(D<sub>4<\/sub>\/D<sub>5<\/sub>\uff0cD\u2019)(\u56fe3b)\u3002\u5728\u5b8c\u5168\u518d\u6c27\u5316\u540e\uff0c\u53ef\u4ee5\u8bc6\u522b\u51fa\u5728\u4e2d\u95f4\u8377\u7535\u72b6\u6001\u4e0b\u65e0\u6cd5\u89c2\u5bdf\u5230\u7684D*\u6a21\u5f0f\u3002\u4e0e\u5b8c\u5168\u518d\u6c27\u5316\u77f3\u58a8\u70ef\u7684D\u2019\u2019\u2019\uff0cD\u2019\u2019\u548cD\u2019\u76f8\u6bd4\uff0c\u90e8\u5206\u53cd\u5e94\u77f3\u58a8\u70ef\u7684D<sub>1<\/sub>-D<sub>5<\/sub>\u7684\u4f4d\u7f6e\u548c\u5f3a\u5ea6\u4e5f\u6709\u6240\u4e0d\u540c\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-207807 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72477-13.png\" alt=\"\" width=\"600\" height=\"333\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72477-13.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72477-13-300x167.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe4\u5c55\u793a\u4e86\u4e09\u79cd\u4e0d\u540c\u81ea\u7531\u5ea6\u7684\u6837\u54c1\u7684\u62c9\u66fc\u5149\u8c31\uff0c\u5c55\u793a\u4e86\u968f\u7740sp<sup>3<\/sup>\u78b3\u539f\u5b50\u542b\u91cf\u7684\u589e\u52a0\u6240\u5bf9\u5e94\u7684\u62c9\u66fc\u7279\u5f81\u5cf0\u7684\u53d8\u5316\u3002\u56fe4a\u4e2d\uff0cI<sub>D<\/sub>\/I<sub>G<\/sub>\u7684\u6bd4\u503c\u53ef\u4ee5\u786e\u5b9a\u81ea\u7531\u5ea6\uff0cD\u6a21\u5f0f\u7684\u7a84\u5bbd\u5ea6\uff0822\u00a0cm<sup>-1<\/sup>\uff09\u4e0e\u81ea\u7531\u5ea6\uff08~0.23%\uff09\u76f8\u5173\u8054\uff0c\u5728\u5982\u6b64\u4f4e\u7684\u81ea\u7531\u5ea6\u4e4b\u4e0b\u53ef\u4ee5\u5bb9\u6613\u5730\u53cd\u8936\u79ef\u51faD\u3001G\u548cD*\u632f\u52a8\u6a21\u5f0f\u3002\u968f\u7740\u81ea\u7531\u5ea6\u7684\u8fdb\u4e00\u6b65\u589e\u52a0\uff0cD\/G\u6bd4\u503c\u4e0b\u964d\uff0c\u8fd9\u4e9b\u6a21\u5f0f\u7684\u53cd\u8936\u79ef\u5c06\u4f1a\u53d8\u5f97\u66f4\u6709\u96be\u5ea6\u3002\u5728\u81ea\u7531\u5ea6\u4e3a~1.6%\u7684\u60c5\u51b5\u4e0b\uff0cKC<sub>8<\/sub>\u4e0eH<sub>2<\/sub>O\u7684\u539f\u4f4d\u53cd\u5e94\u4e2d\u53d1\u73b0\u4e86D<sub>1<\/sub>-D<sub>5<\/sub>\u7684\u62c9\u66fc\u5e26\uff0c\u800c\u8fd9\u4e3b\u8981\u5f52\u529f\u4e8e\u81ea\u7531\u5ea6\u5206\u5e03\u57280.5%-2%\u4e4b\u95f4\u3002\u540c\u65f6\uff0c\u56fe4\u4e2d\u7684\u52a8\u753b\u6f14\u793a\u4e5f\u53ef\u4ee5\u89c2\u5bdf\u5230\u7684\u62c9\u66fc\u5e26\u4e0e\u77f3\u58a8\u70ef\u8584\u7247\u4e0a\u5404\u4e2a\u7ed3\u6784\u4e4b\u95f4\u7684\u5173\u7cfb\u3002\u81ea\u7136\u73af\u5883\u6761\u4ef6\u4e0b\u5145\u5206\u53cd\u5e94\u4e4b\u540e\u7684\u8fbe\u5230\u6700\u5927\u81ea\u7531\u5ea6\u7684KC<sub>8<\/sub>\uff0c\u53ef\u7531\u81ea\u7531\u5ea6\u4e3a~6%\uff0c\u5373GO\u4f5c\u4e3a\u7406\u60f3\u7684\u53c2\u7167\u7269\u3002\u56e0\u6b64\uff0c\u5bf9\u6c27\u5316\u77f3\u58a8\u70ef\u548cG(THF)(OH)(H)\u4e2d\u6240\u6709\u6307\u5b9a\u7684\u62c9\u66fc\u95f4\u5e26\u8fdb\u884c\u5206\u6790(\u56fe3a)\uff0c\u53ef\u4ee5\u4f5c\u4e3a\u53c2\u8003\u8868\u5f81\u81ea\u7531\u5ea6\u4e3a2%\u7684\u9644\u52a0\u7269\u3002\u5728\u8fd9\u4e2a\u8303\u56f4\u5185\uff0c\u62c9\u66fc\u5149\u8c31\u4e2d\u6240\u6709\u989d\u5916\u7684\u7ec4\u5206(D\u2019\u2019\u2019\uff0cD\u2019\u2019\u548cD\u2019)\u90fd\u53ef\u4ee5\u6e05\u6670\u5730\u8bc6\u522b\u51fa\u6765\uff0c\u800c\u4e14\u89c2\u5bdf\u5230\u7684\u6307\u7eb9\u5b8c\u5168\u5339\u914d\u6a21\u62df\u5149\u8c31\u7684G-H\u548cG-OH(\u56fe3d)\u6240\u8ba1\u7b97\u7684~3%\u7684\u81ea\u7531\u5ea6\u3002\u8fd9\u4e0e\u5bf9\u529f\u80fd\u5316\u5316\u5b66\u6c14\u76f8\u6c89\u79ef\u77f3\u58a8\u70ef\u7684\u8868\u9762\u589e\u5f3a\u62c9\u66fc\u6563\u5c04\u7814\u7a76\u5b8c\u5168\u4e00\u81f4\uff0c\u5728\u8fd9\u4e9b\u7814\u7a76\u4e2d\uff0c\u81ea\u7531\u5ea6~0.5%\u7684\u5316\u5b66\u4fee\u9970\u77f3\u58a8\u70ef\u7684\u8f7b\u5fae\u5149\u8c31\u4f1a\u5bfc\u81f4D\u548cG\u6a21\u533a\u76f8\u5bf9\u8f83\u5f31\u7684\u62c9\u66fc\u5e26\u3002\u56e0\u6b64\uff0c\u4f5c\u8005\u53ef\u4ee5\u5f97\u51fa\u8fd9\u6837\u7684\u7ed3\u8bba\uff1a\u5728\u8fbe\u5230\u6700\u5927\u81ea\u7531\u5ea6\u4e3a~12.5%(\u57fa\u4e8eK\/C=1:8)\u7684\u8fc7\u7a0b\u4e2d\uff0c\u4f34\u968f\u7740\u9644\u52a0\u7269\u7684\u56e2\u805a\u548c\u672a\u6539\u53d8sp<sup>2<\/sup>\u7eb3\u7c73\u7ed3\u6784\u57df\u7684\u5f62\u6210\u3002\u56e0\u6b64\uff0c\u62c9\u66fc\u5149\u8c31\u5bf9\u4e8e\u529f\u80fd\u5316\u77f3\u58a8\u70ef\u7684\u7814\u7a76\u5177\u6709\u975e\u5e38\u91cd\u5927\u7684\u610f\u4e49\uff0c\u5bf9\u4ee5\u540e\u77f3\u58a8\u70ef\u529f\u80fd\u5316\u7684\u7814\u7a76\u63d0\u4f9b\u4e86\u4e00\u4e2a\u66f4\u52a0\u7cbe\u786e\u7684\u6d4b\u8bd5\u8868\u5f81\u624b\u6bb5\u3002<\/p>\n<p>\u53c2\u8003\u6587\u732e\uff1aVecera, P., Chacontorres, J. C., Pichler, T., Reich, S., Soni, H. R., Gorling, A., &#8230; &amp; Hirsch, A. (2017). Precise determination of graphene functionalization by in situ Raman spectroscopy.. 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