{"id":207968,"date":"2020-08-24T12:00:55","date_gmt":"2020-08-24T04:00:55","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=207968"},"modified":"2020-08-24T10:06:56","modified_gmt":"2020-08-24T02:06:56","slug":"%e5%b7%b2%e6%a0%a1%e7%a8%bf%e4%bb%b6-%e8%8b%8f%e5%a4%a7%e7%8e%8b%e5%85%86%e5%a5%8e%e5%9b%a2%e9%98%9f-am%ef%bc%9a%e4%b8%80%e4%b8%be%e5%a4%9a%e5%be%97%ef%bc%81%e5%88%a9%e7%94%a8%e5%88%86%e5%ad%90","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=207968","title":{"rendered":"\u82cf\u5927\u738b\u5146\u594e\u56e2\u961f AM\uff1a\u4e00\u4e3e\u591a\u5f97\uff01\u5229\u7528\u5206\u5b50\u6c34\u5e73\u67d4\u6027\u4e2d\u95f4\u5c42\u5b9e\u73b0\u9ad8\u6548\u3001\u67d4\u6027\u7684\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u76ee\u524d\uff0c\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff08PSCs\uff09\u7684\u529f\u7387\u8f6c\u6362\u6548\u7387\uff08PCE\uff09\u6700\u9ad8\u53ef\u8fbe25.2\uff05\u3002\u4e3a\u4e86\u83b7\u5f97\u9ad8\u6027\u80fd\u7684\u5668\u4ef6\uff0c\u5927\u91cf\u7814\u7a76\u96c6\u4e2d\u5728\u8c03\u63a7\u9499\u949b\u77ff\u7684\u5316\u5b66\u6210\u5206\u548c\u4f18\u5316\u7535\u8377\u4f20\u8f93\u5c42\u3002\u540c\u65f6\uff0c\u8fd8\u5e94\u5f3a\u8c03\u9499\u949b\u77ff\u4e0e\u63a9\u57cb\u57fa\u8d28\u4e4b\u95f4\u7684\u76f8\u5173\u6548\u5e94\u3002\u6676\u4f53\u7ed3\u6784\u4e0d\u5339\u914d\u3001\u4e24\u4fa7\u521a\u6027\u6676\u683c\u5355\u5143\u70ed\u81a8\u80c0\u4e0d\u4e00\u81f4\uff0c\u90fd\u4e0d\u5229\u4e8e\u9499\u949b\u77ff\u7684\u5fae\u89c2\u7ed3\u6784\u3002\u5728\u5206\u5b50\u6c34\u5e73\u4e0a\uff0c\u9499\u949b\u77ff\u6750\u6599\u7531\u4e8e\u5e94\u53d8\u79ef\u7d2f\u6548\u5e94\u5bfc\u81f4\u76f8\u7a33\u5b9a\u6027\u5dee\uff0c\u540c\u65f6\u4e0d\u53ef\u91ca\u653e\u7684\u6676\u683c\u5e94\u529b\u4e5f\u4f1a\u52a0\u901f\u6750\u6599\u9000\u5316\u3002\u6b64\u5916\uff0c\u5177\u6709\u56fa\u6709\u7ed3\u6784\u8106\u6027\u7684\u975e\u5747\u8d28\u754c\u9762\uff0c\u4e00\u65e6\u53d1\u751f\u673a\u68b0\u53d8\u5f62\u5c31\u6613\u7834\u788e\u3002\u867d\u7136\u5927\u91cf\u7684\u5206\u5b50\u6c34\u5e73\u5939\u5c42\u88ab\u7528\u6765\u4fee\u9970\u57fa\u4f53\/\u9499\u949b\u77ff\u5f02\u8d28\u754c\u9762\uff0c\u4f46\u662f\u5927\u591a\u6570\u4e2d\u95f4\u5c42\u96c6\u4e2d\u4e8e\u7b80\u5355\u5730\u949d\u5316\u754c\u9762\u9677\u9631\u72b6\u6001\u3002\u56e0\u6b64\uff0c\u540c\u65f6\u6ee1\u8db3\u65e0\u5e94\u53d8\u7684\u5916\u5ef6\u57fa\u5e95\u548c\u9499\u949b\u77ff\u8584\u819c\u5728\u754c\u9762\u5904\u7684\u4f4e\u9677\u9631\u72b6\u6001\uff0c\u5177\u6709\u91cd\u8981\u610f\u4e49\u548c\u5e94\u7528\u524d\u666f\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u82cf\u5dde\u5927\u5b66\u7684\u738b\u5146\u594e\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u56e2\u961f<\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u5229\u7528\u8d28\u5b50\u5316\u94f5\u7845\u70f7\u5076\u8054\u5242\uff08PASCA-Br\uff09\u5728TiO2<\/sub>\u548c\u9499\u949b\u77ff\u5c42\u7684\u5939\u5c42\u95f4\uff0c\u5f62\u6210\u5177\u6709\u6676\u683c\u5355\u5143\u7ed3\u6784\u7684\u6210\u5206\uff0c\u4ece\u800c\u5bf9\u4e24\u8005\u8fdb\u884c\u5b9a\u5411\u7684\u63a7\u5236\u3002\u5728\u4e2d\u95f4\u5c42\u4e0a\u4fa7\u7684\u6795\u72b6\u70f7\u57fa\u6eb4\u5316\u94f5\u672b\u7aef\u4e3a\u9499\u949b\u77ff\u63d0\u4f9b\u4e86\u826f\u597d\u5339\u914d\u7684\u751f\u957f\u4f4d\u70b9\uff0c\u4ece\u800c\u51cf\u8f7b\u4e86\u754c\u9762\u5e94\u53d8\u548c\u6676\u683c\u7578\u53d8\u3002\u540c\u65f6\uff0c\u5176\u4f18\u5f02\u7684\u5316\u5b66\u76f8\u5bb9\u6027\u5bf9\u4fee\u590d\u88f8\u9732\u9499\u949b\u77ff\u6676\u4f53\u4e2d\u672a\u914d\u4f4dPb\u539f\u5b50\u548c\u5364\u7d20\u7a7a\u4f4d\u5177\u6709\u7406\u60f3\u7684\u6548\u679c\u3002\u6b64\u5916\uff0cPASCA-Br\u4e2d\u95f4\u5c42\u8fd8\u53ef\u4ee5\u7528\u4f5c\u673a\u68b0\u7f13\u51b2\u5c42\uff0c\u4ece\u800c\u5728\u5f2f\u66f2\u65f6\u4ea7\u751f\u8f83\u5c11\u7684\u9499\u949b\u77ff\u88c2\u75d5\u3002\u603b\u4e4b\uff0c\u6240\u5f00\u53d1\u7684\u5206\u5b50\u7ea7\u67d4\u6027\u4e2d\u95f4\u5c42\u4e3aPSCs\u53ca\u5176\u5e94\u7528\u63d0\u4f9b\u4e86\u4e00\u79cd\u5f88\u6709\u524d\u9014\u7684\u754c\u9762\u5de5\u7a0b\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cPerovskite Films with Reduced Interfacial Strains via a Molecular-Level Flexible Interlayer for Photovoltaic Application\u201d<\/strong>\u53d1\u5e03\u5728\u56fd\u9645\u8457\u540d\u671f\u520aAdv. Mater.<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\u3001TiO2<\/sub>\/PASCA-Br\u8584\u819c\u7684\u5236\u5907\u4e0e\u8868\u5f81<\/strong>
\n \"\"\uff08a\uff09TiO2<\/sub>\u548cPASCA-Br\u5c42\u7684\u5236\u9020\u8fc7\u7a0b\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b-c\uff09TiO2<\/sub>\u548cTiO2<\/sub>\/PASCA-Br\u8584\u819c\u5bf9Ti 2p\u548cO 1s\u7684XPS\u5149\u8c31\uff1b<\/p>\n

\uff08d\uff09TiO2<\/sub>\/PASCA-Br\u548cPASCA-Br\u8584\u819c\u7684Si 2p\u7684XPS\u5149\u8c31\uff1b<\/p>\n

\uff08e\uff09APTES\u548cPASCA-Br\u4fee\u9970\u754c\u9762\u7684\u8d28\u5b50\u5316\u6c28\u57fa\u672b\u7aef\uff08R-NH3<\/sub>Br\uff09\u548c\u6676\u683c\u7ed3\u6784\u3002<\/p>\n

\u56fe\u4e8c\u3001\u4e0d\u540c\u57fa\u5e95\u4e0a\u9499\u949b\u77ff\u8584\u819c\u5728\u5e73\u9762\u5185\u5916\u4e0a\u7684\u6676\u683c\u5e94\u53d8<\/strong>
\n \"\"\uff08a\uff09\u6c89\u79ef\u5728TiO2<\/sub>\u3001TiO2<\/sub>\/APTES\u548cTiO2<\/sub>\/PASCA-Br\u57fa\u5e95\u4e0a\u7684\u9499\u949b\u77ff\u8584\u819c\u7684\u5e73\u9762\u5185\u548c\u5e73\u9762\u5916GIXRD\u7ed3\u679c\uff1b<\/p>\n

\uff08b\uff09\u9499\u949b\u77ff\u8584\u819c\u7684\u76f8\u5e94\u6676\u4f53\u5e94\u53d8\u5728\u5e73\u9762\u5185\u548c\u5e73\u9762\u5916\u7684\u65b9\u5411\uff1b<\/p>\n

\uff08c\uff09\u8ba1\u7b97\u7684\u9762\u5185\u548c\u9762\u5916\u6676\u683c\u5e94\u53d8\u3002<\/p>\n

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\n \"\"\uff08a\uff09\u754c\u9762\u5904\u9499\u949b\u77ff\u6676\u4f53\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\uff09\u4ece\u6b63\u53cd\u9762\u5728\u4e0d\u540c\u57fa\u5e95\u5c42\u4e0a\u9499\u949b\u77ff\u8584\u819c\u7684\u7a33\u6001PL\u5f3a\u5ea6\uff1b<\/p>\n

\uff08c\uff09\u5728\u4e0d\u540c\u57fa\u5e95\u5c42\u4e0a\u9499\u949b\u77ff\u8584\u819c\u7684\u77ac\u6001PL\u5f3a\u5ea6\uff1b<\/p>\n

\uff08d-e\uff09\u4e0d\u540c\u57fa\u5e95\u5c42\u4e0a\uff0c\u5668\u4ef6\u7684Mott-Schottky\u6570\u636e\u548cTPC\u6570\u636e\u3002<\/p>\n

\u56fe\u56db\u3001\u5668\u4ef6\u7684\u6027\u80fd<\/strong>
\n \"\"\uff08a\uff09\u5728\u9ed1\u6697\u4e2d\uff0c\u4ec5\u7535\u5b50\u5668\u4ef6\u7684\u6e29\u5ea6\u76f8\u5173\u7684J<\/em>–V<\/em>\u66f2\u7ebf\uff1b<\/p>\n

\uff08b\uff09\u4e0d\u540c\u6e29\u5ea6\u4e0b\uff0c\u8ba1\u7b97\u51fa\u7684\u00b5<\/em>e<\/sub>\u503c\uff1b<\/p>\n

\uff08c\uff09\u57fa\u4e8e\u4e0d\u540c\u57fa\u5e95\u5c42\u7684tDOS\u5206\u5e03\uff1b<\/p>\n

\uff08d\uff09\u5728FTO\u57fa\u5e95\u4e0a\uff0c\u57fa\u4e8eTiO2<\/sub>\u3001TiO2<\/sub>\/APTES\u548cTiO2<\/sub>\/PASCA-Br\u7684\u5668\u4ef6\u7684J<\/em>–V<\/em>\u66f2\u7ebf\uff1b<\/p>\n

\uff08e\uff09-dV<\/em>\/dJ<\/em>\u4e0e\uff08d\uff09\u4e2d\u7684(J<\/em>SC<\/sub>–J<\/em>)-1<\/sup>\u56fe\uff1b<\/p>\n

\uff08f\uff09\u76f8\u5e94\u7684\u5668\u4ef6\u7a33\u5b9a\u7684\u4fdd\u5b58\u4e861\u4e2a\u6708\u3002<\/p>\n

\u56fe\u4e94\u3001\u4e0d\u540c\u6761\u4ef6\u4e0b\u9499\u949b\u77ff\u8584\u819c\u7684\u6027\u80fd\u53d8\u5316<\/strong>
\n \"\"\uff08a\uff09\u4e0d\u540c\u57fa\u8d28\u4e0a\uff0c\u9499\u949b\u77ff\u8584\u819c\u7684\u9876\u90e8SEM\u5f62\u8c8c\uff1b<\/p>\n

\uff08b\uff09\u5f2f\u66f2\u5b9e\u9a8c\u4e09\u904d\u540e\uff0c\u9499\u949b\u77ff\u4e0d\u540c\u819c\u7247\u7684\u5149\u5b66\u56fe\u50cf\uff1b<\/p>\n

\uff08c\uff09\u4e0d\u540c\u7684\u5f2f\u66f2\u89d2\u5ea6\u4e0b\uff0cPCE\u7684\u53d8\u5316\uff1b<\/p>\n

\uff08d\uff09\u4e0d\u540c\u7684\u62c9\u5e94\u529b\u4e0b\uff0c\u6c89\u79ef\u5728\u4e0d\u540c\u57fa\u5e95\u5c42\u4e0a\u9499\u949b\u77ff\u8584\u819c\u7684\u62c9\u4f38\u5e94\u53d8\uff1b<\/p>\n

\uff08e\uff09\u5728PEN\u67d4\u6027\u57fa\u677f\u4e0a\uff0c\u57fa\u4e8eTiO2<\/sub>\u3001TiO2<\/sub>\/APTES\u548cTiO2<\/sub>\/PASCA-Br\u7684\u5668\u4ef6\u7684J<\/em>–V<\/em>\u66f2\u7ebf\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u62a5\u9053\u4e86\u4e00\u79cdPASCA-Br\u7684\u7845\u70f7\u5076\u8054\u5242\uff0c\u5c06\u5176\u4f5c\u4e3aTiO2<\/sub>\u548c\u9499\u949b\u77ff\u5c42\u4e4b\u95f4\u7684\u8584\u5c42\u3002\u9996\u5148\uff0c\u6795\u72b6\u70f7\u57fa\u6eb4\u5316\u94f5\u672b\u7aef\u53ef\u4f5c\u4e3a\u9499\u949b\u77ff\u751f\u957f\u7684\u826f\u597d\u5339\u914d\u751f\u957f\u4f4d\u70b9\uff0c\u4ece\u800c\u51cf\u8f7b\u6676\u683c\u7578\u53d8\u548c\u754c\u9762\u5e94\u53d8\u3002\u5176\u6b21\uff0cPASCA-Br\u4e2d\u7684R-NH3<\/sub>Br\u672b\u7aef\u53ef\u4e0e\u672a\u914d\u4f4d\u7684Pb\u539f\u5b50\u5f62\u6210\u7262\u56fa\u7684\u5316\u5b66\u952e\uff0c\u4ece\u800c\u663e\u7740\u964d\u4f4e\u6676\u683c\u7578\u53d8\u3002\u6700\u540e\uff0cPASCA-Br\u8fd8\u53ef\u4ee5\u901a\u8fc7\u6539\u5584\u9499\u949b\u77ff\u8584\u819c\u7684\u5f2f\u66f2\u548c\u62c9\u4f38\u80fd\u529b\u800c\u7528\u4f5c\u673a\u68b0\u7f13\u51b2\u5c42\u3002\u603b\u4e4b\uff0c\u6240\u5f00\u53d1\u7684\u65b9\u6cd5\u9002\u7528\u4e8e\u67d4\u6027\u8bbe\u5907\u4e2d\u4e0d\u540c\u7684\u65e0\u673a\u548c\u6709\u673a\u57fa\u5e95\u5c42\u3002\u8fd9\u79cd\u7b56\u7565\u4e3a\u5236\u9020\u9ad8\u6548\u3001\u65e0\u5e94\u53d8\u7684\u67d4\u6027PSCs\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aPerovskite Films with Reduced Interfacial Strains via a Molecular-Level Flexible Interlayer for Photovoltaic Application<\/a><\/strong>\uff08Adv. Mater.<\/em>, 2020<\/strong>, DOI: 10.1002\/adma.202001479\uff09<\/p>\n

\u672c\u6587\u7531CQR\u7f16\u8bd1\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1atougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu.<\/p>\n","protected":false},"excerpt":{"rendered":"

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