{"id":208253,"date":"2020-08-27T09:00:22","date_gmt":"2020-08-27T01:00:22","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=208253"},"modified":"2020-08-27T08:57:32","modified_gmt":"2020-08-27T00:57:32","slug":"%e6%9c%80%e6%96%b0nature%e9%95%8d%e5%82%ac%e5%8c%96%e5%89%82%e5%8f%af%e6%88%aa%e7%95%99%e7%9e%ac%e6%80%81%e7%8e%af%e4%b8%99%e4%ba%8c%e7%83%af%e4%b8%ad%e9%97%b4%e4%ba%a7%e7%89%a9","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=208253","title":{"rendered":"\u6700\u65b0Nature:\u954d\u50ac\u5316\u5242\u53ef\u622a\u7559\u77ac\u6001\u73af\u4e19\u4e8c\u70ef\u4e2d\u95f4\u4ea7\u7269"},"content":{"rendered":"<p><strong><b>\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n<p>\u5927\u73af\u6709\u673a\u5206\u5b50\uff08cyclic organic molecules\uff09\u8bf8\u5982\u82b3\u7094\u3001\u73af\u7094\u3001\u73af\u4e19\u4e8c\u70ef\uff08cyclic allene\uff09\u7b49\u5728\u8fc7\u53bb\u7684\u4e00\u4e2a\u591a\u4e16\u7eaa\u91cc\u4e00\u76f4\u662f\u5316\u5b66\u5bb6\u7684\u7814\u7a76\u5bf9\u8c61\u3002\u8fd9\u4e9b\u77ac\u6001\u4e2d\u95f4\u7269\u5177\u6709\u9ad8\u5ea6\u7684\u73af\u5f20\u529b\uff08ring strain\uff09\uff0c\u5728\u73af\u52a0\u6210\u53cd\u5e94\u548c\u4eb2\u6838\u53cd\u5e94\u4e2d\u5c55\u73b0\u51fa\u9ad8\u6d3b\u6027\u7279\u70b9\uff0c\u4ece\u800c\u884d\u751f\u51fa\u7ed3\u6784\u590d\u6742\u7684\u4ea7\u7269\u3002\u867d\u7136\u5229\u7528\u5316\u5b66\u8ba1\u91cf\u7684\u624b\u6027\u8bd5\u5242\u53ef\u4ee5\u63a7\u5236\u8fd9\u4e9b\u53cd\u5e94\u4e2d\u7684\u7acb\u4f53\u5316\u5b66\uff0c\u4f46\u5b9e\u73b0\u53ef\u4ea7\u751f\u9ad8\u542b\u91cf\u5bf9\u6620\u4f53\u4ea7\u7269\u7684\u975e\u5bf9\u79f0\u50ac\u5316\u53cd\u5e94\u4f9d\u7136\u9887\u5177\u6311\u6218\u3002<\/p>\n<p>\u3010<strong><b>\u6210\u679c\u7b80\u4ecb<\/b><\/strong>\u3011<\/p>\n<p><strong><b>\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u6d1b\u6749\u77f6\u5206\u6821\u7684<\/b><\/strong><strong><b>K. N.<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>Houk<\/b><\/strong><strong><b>\u548c<\/b><\/strong><strong><b>N.<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>K<\/b><\/strong><strong><b>. <\/b><\/strong><strong><b>Garg<\/b><\/strong>\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u63d0\u51fa\u4e86\u4e00\u79cd\u53ef\u5728\u975e\u5bf9\u79f0\u50ac\u5316\u53cd\u5e94\u4e2d\u622a\u7559\u5916\u6d88\u65cb\u73af\u4e19\u4e8c\u70ef\u4e2d\u95f4\u7269\u7684\u65b9\u6cd5\uff0c\u540c\u65f6\u63d0\u51fa\u4e86\u4e24\u79cd\u53ef\u63a7\u5236\u8fd9\u4e00\u8f6c\u5316\u53cd\u5e94\u7acb\u4f53\u5316\u5b66\u7684\u622a\u7136\u4e0d\u540c\u7684\u673a\u5236\u3002\u8ba1\u7b97\u7814\u7a76\u8868\u660e\uff0c\u50ac\u5316\u673a\u5236\u6d89\u53ca\u5230\u73af\u4e19\u4e8c\u70ef\u5bf9\u6620\u4f53\u7684\u521d\u59cb\u52a8\u529b\u5b66\u5dee\u5f02\uff0c\u7531\u6b64\u5bfc\u81f4\u4e86\u7acb\u4f53\u5316\u5b66\u4fe1\u606f\u7684\u635f\u5931\uff0c\u5e76\u901a\u8fc7\u4e2d\u95f4\u4f53\u590d\u5408\u7269\u7684\u53bb\u5bf9\u79f0\u5316\u5b9e\u73b0\u4e86\u7edd\u5bf9\u6784\u578b\u7684\u5f15\u5165\u3002\u8fd9\u4e9b\u7ed3\u679c\u63ed\u793a\u4e86\u73af\u4e19\u4e8c\u70ef\u9664\u73af\u52a0\u6210\u548c\u4eb2\u6838\u53cd\u5e94\u5916\u5177\u6709\u65b0\u7684\u53cd\u5e94\u6d3b\u6027\uff0c\u4e3a\u8fdb\u4e00\u6b65\u63a8\u52a8\u4e86\u975e\u5bf9\u79f0\u50ac\u5316\u53cd\u5e94\u7684\u53d1\u5c55\u30022020\u5e7408\u670826\u65e5\uff0c\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201c<strong><b>Intercepting fleeting cyclic allenes with asymmetric nickel catalysis<\/b><\/strong>\u201d\u7684\u6587\u7ae0\u5728\u7ebf\u53d1\u8868\u5728<strong><b>Nature<\/b><\/strong>\u4e0a\u3002<\/p>\n<p>\u3010<strong><b>\u56fe\u6587\u5bfc\u8bfb<\/b><\/strong>\u3011<\/p>\n<p><strong><b>\u56fe1<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>\u73af\u4e2d\u95f4\u4f53\u53ca\u5176\u53cd\u5e94\u8bbe\u8ba1<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-208255\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72471-33.png\" alt=\"\" width=\"600\" height=\"352\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72471-33.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72471-33-300x176.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>\u56fe2<\/b><\/strong><strong><b>\u00a0\u73af\u53cd\u5e94\u4e2d\u7684\u73af\u4e19\u4e8c\u70ef<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-208256\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72472-32.png\" alt=\"\" width=\"593\" height=\"467\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72472-32.png 593w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72472-32-300x236.png 300w\" sizes=\"(max-width: 593px) 100vw, 593px\" \/><\/p>\n<p><strong><b>\u56fe3<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>\u975e\u5bf9\u79f0\u73af\u4f18\u5316<\/b><\/strong><\/p>\n<p><strong><b>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-208257\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72473-32.png\" alt=\"\" width=\"391\" height=\"546\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72473-32.png 391w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72473-32-215x300.png 215w\" sizes=\"(max-width: 391px) 100vw, 391px\" \/><\/b><\/strong><\/p>\n<p><strong><b>\u56fe4 \u975e\u5bf9\u79f0\u73af\u53cd\u5e94\u673a\u5236\u7684\u8ba1\u7b97\u7814\u7a76<\/b><\/strong><\/p>\n<p><strong><b>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-208258\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72474-28.png\" alt=\"\" width=\"518\" height=\"519\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72474-28.png 518w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72474-28-150x150.png 150w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72474-28-300x300.png 300w\" sizes=\"(max-width: 518px) 100vw, 518px\" \/><\/b><\/strong><\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"https:\/\/www.nature.com\/articles\/s41586-020-2701-2\"><u>Intercepting fleeting cyclic allenes with asymmetric nickel catalysis<\/u><\/a>\uff08Nature, 2020, DOI: 10.1038\/s41586-020-2701-2\uff09<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u5b66\u672f\u7ec4NanoCJ\u4f9b\u7a3f\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u5927\u73af\u6709\u673a\u5206\u5b50\uff08cyclic organic molecules\uff09\u8bf8\u5982\u82b3\u7094\u3001\u73af\u7094\u3001\u73af\u4e19\u4e8c\u70ef\uff08cyclic allene\uff09\u7b49\u5728\u8fc7\u53bb\u7684\u4e00\u4e2a\u591a\u4e16\u7eaa\u91cc\u4e00\u76f4\u662f\u5316\u5b66&#8230;<\/p>\n","protected":false},"author":14360,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-208253","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/208253"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/14360"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=208253"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/208253\/revisions"}],"predecessor-version":[{"id":208260,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/208253\/revisions\/208260"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=208253"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=208253"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=208253"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}