{"id":208332,"date":"2020-09-05T06:30:21","date_gmt":"2020-09-04T22:30:21","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=208332"},"modified":"2020-09-04T20:09:40","modified_gmt":"2020-09-04T12:09:40","slug":"%e8%b6%85%e7%87%83%ef%bc%81mof%e5%86%8d%e5%8f%91%e4%b8%a4%e7%af%87science%ef%bc%8cyaghi%e3%80%81%e6%9c%b1%e9%81%93%e6%9c%ac%e3%80%81%e4%b8%a5%e7%ba%af%e5%8d%8e%e3%80%81%e4%ba%8e%e5%90%89%e7%ba%a2","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=208332","title":{"rendered":"\u8d85\u71c3\uff01MOF\u518d\u53d1\u4e24\u7bc7Science\uff0cYaghi\u3001\u6731\u9053\u672c\u3001\u4e25\u7eaf\u534e\u3001\u4e8e\u5409\u7ea2\u3001\u5468\u5b8f\u624d\u3001\u9648\u90a6\u6797\u3001\u5b59\u5b66\u826f\u7b49\u73a9\u8f6c\u660e\u661fMOF\u6750\u6599"},"content":{"rendered":"<div><strong>1\u3001 Science\uff1a\u591a\u53d8\u91cf\u91d1\u5c5e-\u6709\u673a\u6846\u67b6\u4e2d\u91d1\u5c5e\u7684\u6392\u5e8f<\/strong><\/div>\n<div>\u00a0<\/div>\n<div><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-208333 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72471-36.png\" alt=\"\" width=\"600\" height=\"780\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72471-36.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72471-36-231x300.png 231w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/div>\n<div>\u00a0<\/div>\n<div>\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821Omar M. Yaghi\u548c\u5fb7\u56fd\u6ce2\u9e3f\u9c81\u5c14\u5927\u5b66Tong Li\u7b49\u4eba\u5728\u542b\u6709\u94b4\uff08Co\uff09\u3001\u9549\uff08Cd\uff09\u3001\u94c5\uff08Pb\uff09\u548c\u9530\uff08Mn\uff09\u7684\u591a\u5143\u91d1\u5c5e\u6709\u673a\u6846\u67b674\u4e2d\u7ed8\u5236\u4e86\u91d1\u5c5e\u6c27\u5316\u7269\u68d2\u6676\u4f53\u4e2d\u7684\u91d1\u5c5e\u5e8f\u5217\u3002\u8fd9\u4e9b\u6676\u4f53\u7684\u539f\u5b50\u63a2\u9488\u65ad\u5c42\u626b\u63cf\u663e\u793a\u4e86\u7814\u7a76\u4eba\u5458\u6240\u63cf\u8ff0\u7684\u91d1\u5c5e\u79bb\u5b50\u7684\u5f02\u8d28\u6027\u7a7a\u95f4\u5e8f\u5217\uff0c\u8fd9\u4e9b\u5e8f\u5217\u53d6\u51b3\u4e8e\u6240\u4f7f\u7528\u7684\u91d1\u5c5e\u548c\u5408\u6210\u6e29\u5ea6\uff0c\u4f8b\u5982\u968f\u673a\uff08Co, Cd, 120\u2103\uff09\u3001\u77ed\u91cd\u590d\uff08Co, Cd, 85\u2103\uff09\u3001\u957f\u91cd\u590d\uff08Co, Pb, 85\u2103\uff09\u548c\u63d2\u5165\uff08Co, Mn, 85\u2103\uff09\u3002\u5728\u4e0d\u6539\u53d8\u5e8f\u5217\u7c7b\u578b\u7684\u60c5\u51b5\u4e0b\uff0c\u7814\u7a76\u4eba\u5458\u68c0\u6d4b\u4e86\u4e09\u79cd\u6676\u4f53\uff0c12\u4e2a\u6837\u54c1\u4e2dCo\u7684\u6469\u5c14\u5206\u6570\u57280.4 ~ 0.9\u4e4b\u95f4\u53d8\u5316\u3002\u4e0e\u91d1\u5c5e\u6c27\u5316\u7269\u76f8\u6bd4\uff0c\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u5728\u6746\u72b6\u4f53\u4e2d\u5177\u6709\u8f83\u9ad8\u7684\u8010\u53d7\u6027\uff0c\u56e0\u800c\u5177\u6709\u4e0d\u540c\u7684\u91d1\u5c5e\u5e8f\u5217\u3002\u8be5\u7814\u7a76\u4e3aMOFs\u4e2d\u4e0d\u540c\u91d1\u5c5e\u6392\u5217\u7684\u5f62\u5f0f\u63d0\u4f9b\u4e86\u5168\u65b0\u7684\u89c6\u89d2\uff0c\u800c\u4e14\u4e3aMOFs\u672a\u6765\u7684\u7814\u7a76\u548c\u5e94\u7528\u5f00\u62d3\u65b0\u65b9\u5411\u3002<\/div>\n<div>\u00a0<\/div>\n<div>\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/science.sciencemag.org\/content\/369\/6504\/674<\/div>\n<div>\u00a0<\/div>\n<div><strong>2\u3001 Science: \u53ef\u7528\u4e8e\u9ad8\u6548CO2\u5438\u9644\u7684\u9541-\u56db\u80faMOF\u6750\u6599<\/strong><\/div>\n<div>\u00a0<\/div>\n<div><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-208334 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72472-35.png\" alt=\"\" width=\"600\" height=\"515\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72472-35.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72472-35-300x258.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/div>\n<div>\u00a0<\/div>\n<div>\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821Jeffrey R. Long\u7b49\u4eba\u5f00\u53d1\u51fa\u4e86\u4e00\u7c7b\u56db\u80fa\u5b98\u80fd\u5316\u7684\u91d1\u5c5e-\u6709\u673a\u9aa8\u67b6\uff0c\u4e0e\u4ee5\u524d\u7684\u4e8c\u80fa\u5b98\u80fd\u5316\u7684\u6750\u6599\u76f8\u6bd4\uff0c\u7531\u4e8e\u591a\u79cd\u6709\u5e8f\u7684\u91d1\u5c5e-\u80fa\u76f8\u4e92\u4f5c\u7528\uff0c\u5b83\u4eec\u8868\u73b0\u51fa\u534f\u540c\u7684CO<sub>2<\/sub>\u5438\u9644\u5e76\u5927\u5927\u63d0\u9ad8\u4e86\u7a33\u5b9a\u6027\u3002\u8fd9\u4e9b\u6750\u6599\u4e2d\u80fa\u914d\u4f4d\u7684\u6027\u8d28\u5bfc\u81f4\u4e86\u4e8c\u6c27\u5316\u78b3\u7684\u4e24\u6b65\u5438\u9644\u4ee5\u53ca\u9002\u7528\u4e8e\u4ece\u6a21\u62df\u5929\u7136\u6c14\u70df\u9053\u6c14\u6355\u96c6\u4e8c\u6c27\u5316\u78b3\u7684\u5927\u5438\u9644\u7113\u3002\u6700\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u8fd9\u4e9b\u56db\u80fa\u5b98\u80fd\u5316\u9aa8\u67b6\u7684\u589e\u5f3a\u7684\u7a33\u5b9a\u6027\u5141\u8bb8\u4f7f\u7528\u76f4\u63a5\u84b8\u6c7d\u63a5\u89e6\u8fdb\u884c\u518d\u751f\uff0c\u4e0e\u4f20\u7edf\u5de5\u827a\u76f8\u6bd4\uff0c\u8be5\u9014\u5f84\u53ef\u4ee5\u8282\u7701\u5927\u91cf\u80fd\u6e90\u3002\u603b\u4f53\u800c\u8a00\uff0c\u8fd9\u9879\u5de5\u4f5c\u4e2d\u5b9e\u65bd\u7684\u5206\u5b50\u7ea7\u8bbe\u8ba1\u7b56\u7565\u4ee3\u8868\u4e86\u4ece\u5929\u7136\u6c14\u70df\u9053\u6c14\u6392\u653e\u4e2d\u5438\u9644\u5f0fCO<sub>2<\/sub>\u6355\u96c6\u7684\u5de5\u4e1a\u53ef\u884c\u6027\uff0c\u8fd9\u5728\u5168\u7403\u80fd\u6e90\u683c\u5c40\u4e2d\u65e5\u76ca\u91cd\u8981\u3002<\/div>\n<div>\u00a0<\/div>\n<div>\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/science.sciencemag.org\/content\/369\/6502\/392<\/div>\n<div>\u00a0<\/div>\n<div><strong>3\u3001 Angew\uff1a\u5177\u6709\u4e09\u7ef4\u7ed3\u6784\u7684\u987a\u78c1\u5bfc\u7535\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6<\/strong><\/div>\n<div>\u00a0<\/div>\n<div><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-208335 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72473-35.png\" alt=\"\" width=\"543\" height=\"419\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72473-35.png 543w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72473-35-300x231.png 300w\" sizes=\"(max-width: 543px) 100vw, 543px\" \/><\/div>\n<div>\u00a0<\/div>\n<div>\u4e2d\u79d1\u9662\u5316\u5b66\u7814\u7a76\u6240\u6731\u9053\u672c\u9662\u58eb\uff0c\u5b59\u794e\u840c\u526f\u7814\u7a76\u5458\u548c\u5317\u4eac\u5927\u5b66\u5b59\u4fca\u826f\u6559\u6388\u7b49\u4eba\u901a\u8fc7\u4e8c\u4ef7\u91d1\u5c5e\u4e59\u9178\u76d0\u4e0eTHBQ\u7684\u53cd\u5e94\u5236\u5907\u4e86\u4e09\u79cd\u7ed3\u6676\u826f\u597d\u7684\u4e09\u7ef4\u534a\u5bfc\u4f53MOF\uff0c\u5373Fe-THBQ\uff0cCo-THBQ\u548cMn-THBQ\u3002 Fe-THBQ\u5728300 K\u65f6\u5177\u67092.7 \u00d710<sup>-3<\/sup> S cm<sup>-1<\/sup>\u7684\u7535\u5bfc\u7387\uff0c\u8fd9\u662f\u57fa\u4e8eTHBQ\u7684MOF\u4e2d\u6700\u9ad8\u7684\u7535\u5bfc\u7387\u3002\u800c\u4e14\uff0c\u5176\u8f83\u5927\u7684\u8d1f\u585e\u8d1d\u514b\u7cfb\u6570\u8868\u660eFe-THBQ\u6709\u6f5c\u529b\u6210\u4e3a\u4e00\u79cd\u6709\u6548\u7684n\u578b\u70ed\u7535\u6750\u6599\u3002\u8fd9\u4e9bMOF\u5728\u53ef\u89c1\u5149\u533a\u57df\u7684\u5f3a\u70c8\u5438\u6536\u4e3a\u5728\u5149\u6536\u96c6\u6750\u6599\u4e2d\u7684\u5e94\u7528\u63d0\u4f9b\u4e86\u53ef\u80fd\u6027\u3002\u7b80\u800c\u8a00\u4e4b\uff0c\u8fd9\u9879\u5de5\u4f5c\u4e0d\u4ec5\u4e30\u5bcc\u4e86\u4e09\u7ef4\u534a\u5bfc\u4f53MOF\u7684\u79cd\u7c7b\uff0c\u800c\u4e14\u7a81\u51fa\u4e86\u6df7\u5408\u4ef7\u91d1\u5c5e\u7c07\u7684\u91cd\u8981\u6027\uff0c\u8fd9\u53ef\u80fd\u662f\u63d0\u9ad8MOF\u5bfc\u7535\u6027\u7684\u6709\u6548\u7b56\u7565\uff0c\u5e76\u4e3a\u5bfc\u7535\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u542f\u53d1\u3002<\/div>\n<div>\u00a0<\/div>\n<div>\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1002\/anie.202009253<\/div>\n<div>\u00a0<\/div>\n<div><strong>4\u3001 EES\uff1a\u94c8\u63ba\u6742\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u4ecb\u5bfc\u5c42\u72b6\u53cc\u6c22\u6c27\u5316\u7269\u5fae\u80f6\u56ca\u7684\u5236\u5907<\/strong><\/div>\n<div>\u00a0<\/div>\n<div><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-208336 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72474-30.png\" alt=\"\" width=\"572\" height=\"366\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72474-30.png 572w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72474-30-300x192.png 300w\" sizes=\"(max-width: 572px) 100vw, 572px\" \/><\/div>\n<div>\u00a0<\/div>\n<div>\u5170\u5dde\u5927\u5b66\u4e25\u7eaf\u534e\u9662\u58eb\u3001\u5510\u745c\u6559\u6388\u548c\u9999\u6e2f\u7406\u5de5\u5927\u5b66\u9ec4\u52c3\u9f99\u6559\u6388\u7b49\u4eba\u8bc1\u660e\u4e86\u4e00\u79cd\u7b80\u4fbf\u7684\u4e00\u6b65\u5408\u6210\u7b56\u7565\uff0c\u901a\u8fc7\u5229\u7528\u94c8\u7684\u7ade\u4e89\u914d\u4f4d\u548c\u5bf9\u6c27\u7684\u9ad8\u4eb2\u548c\u529b\u6765\u7a33\u5b9aMIL-88A\u7684\u521d\u59cb\u5f62\u6001\uff0c\u4ece\u800c\u6784\u5efa3D LDHs\u5fae\u80f6\u56ca\u3002\u901a\u8fc7\u5408\u7406\u5730\u8c03\u8282Ce\u79bb\u5b50\u548c\u5c3f\u7d20\u7684\u63ba\u6742\u91cf\uff0c\u53ef\u4ee5\u5f88\u5bb9\u6613\u5730\u63a7\u5236Ni-Fe-Ce-LDH\u5fae\u80f6\u56ca\u4e0a\u90e8\u7ed3\u6784\u7684\u957f\u5bbd\u6bd4\u3002\u72ec\u7279\u76843D Ni-FeCe-LDH\u5fae\u80f6\u56ca\u8868\u73b0\u51fa\u5353\u8d8a\u7684OER\u6027\u80fd\uff0c\u572810 mA cm<sup>2<\/sup>\u65f6\u5177\u6709242 mV\u7684\u4f4e\u8fc7\u7535\u52bf\uff0c\u4ee5\u53ca\u81f3\u5c1124 h\u7684\u957f\u671f\u8010\u4e45\u6027\u3002\u901a\u8fc7DFT\u8ba1\u7b97\uff0c\u63ed\u793a\u4e86Ce\u79bb\u5b50\u63ba\u6742\u5242\u5728\u4f18\u5316OER\u7684\u5c40\u90e8\u7535\u5b50\u7ed3\u6784\u4ee5\u53ca\u4fc3\u8fdb\u5408\u6210\u8fc7\u7a0b\u4e2d\u5f62\u6001\u8f6c\u53d8\u673a\u7406\u65b9\u9762\u7684\u91cd\u8981\u4f5c\u7528\u3002\u8fd9\u4e9b\u53d1\u73b0\u4e0d\u4ec5\u4e3a\u4e86\u89e3\u6676\u4f53\u751f\u957f\u8fc7\u7a0b\u4e2d\u7684\u7a00\u571f\u63ba\u6742\u63d0\u4f9b\u4e86\u5b9d\u8d35\u7684\u7ecf\u9a8c\uff0c\u800c\u4e14\u4e3a\u57fa\u4e8e\u7a00\u571f\u79bb\u5b50\u7684\u8def\u6613\u65af\u9178\u6027\u8d28\u548c\u4eb2\u548c\u914d\u4f4d\u80fd\u529b\u7684\u901a\u7528\u7b56\u7565\u63d0\u4f9b\u4e86\u672a\u6765\u7684\u7ed3\u6784\u8bbe\u8ba1\u548c\u5fae\u56ca\u7ed3\u6784\u5236\u9020\u65b9\u6cd5\u3002\u56e0\u6b64\uff0c\u8fd9\u9879\u5de5\u4f5c\u8fdb\u4e00\u6b65\u62d3\u5bbd\u4e86\u7a00\u571f\u4ecb\u5bfc\u7b56\u7565\u5728\u65b0\u578b\u50ac\u5316\u5242\u548c\u6750\u6599\u5236\u5907\u7684\u672a\u6765\u8bbe\u8ba1\u4e2d\u7684\u5e94\u7528\u3002<\/div>\n<div>\u00a0<\/div>\n<div>\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1039\/D0EE02113J<\/div>\n<div>\u00a0<\/div>\n<div><strong>5\u3001 Matter\uff1a\u5177\u6709\u589e\u5f3a\u7684\u50ac\u5316\u7a33\u5b9a\u6027\u7684MOF @\u4ecb\u5b54SiO<sub>2<\/sub>\u5375\u58f3\u7eb3\u7c73\u53cd\u5e94\u5668\u7684\u7eff\u8272\u9009\u62e9\u6027\u6c34\u8680\u523b\u5236\u5907\u7b56\u7565<\/strong><\/div>\n<div>\u00a0<\/div>\n<div><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-208337 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72475-24.png\" alt=\"\" width=\"600\" height=\"600\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72475-24.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72475-24-150x150.png 150w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72475-24-300x300.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/div>\n<div>\u00a0<\/div>\n<div>\u5409\u6797\u5927\u5b66\u4e8e\u5409\u7ea2\u9662\u58eb\u548c\u8d3e\u660e\u541b\u6559\u6388\u7b49\u4eba\u8bbe\u8ba1\u4e86\u4e00\u79cd\u5177\u6709\u4ecb\u5b54\u58f3\u7684MOF @ mSiO<sub>2<\/sub>-YS\u6838\u58f3\u7eb3\u7c73\u7ed3\u6784\uff0c\u5e76\u901a\u8fc7mSiO2\u6d82\u5c42\u548c\u9009\u62e9\u6027\u6c34\u8680\u523b\u7b56\u7565\u8fdb\u884c\u4e86\u5408\u6210\u3002\u6c34\u5bf9\u6c34\u70ed\u4e0d\u7a33\u5b9aMOF\u8868\u9762\u7684\u9009\u62e9\u6027\u8680\u523b\u662f\u5f62\u6210\u6838\u58f3\u7ed3\u6784\u7684\u7eff\u8272\u4e14\u7ecf\u6d4e\u9ad8\u6548\u7684\u65b9\u6cd5\u3002\u5728CO<sub>2<\/sub>\u73af\u52a0\u6210\u53cd\u5e94\u4e2d\uff0c\u6838\u58f3\u7eb3\u7c73\u50ac\u5316\u5242\u6bd4\u88f8MOF\u6676\u4f53\u8868\u73b0\u51fa\u66f4\u9ad8\u7684\u50ac\u5316\u7a33\u5b9a\u6027\uff0c\u4e14\u4e09\u6b21\u5faa\u73af\u540e\u4ea7\u7269\u6536\u7387\u4fdd\u6301\u4e0d\u53d8\uff0c\u8fd9\u662f\u56e0\u4e3a\u5176\u5177\u6709\u53ef\u6e17\u900f\u7684\u4ecb\u5b54SiO<sub>2<\/sub>\u58f3\u3001MOF\u8868\u9762\u66b4\u9732\u7684\u6d3b\u6027\u4f4d\u70b9\u548c\u4fdd\u62a4\u58f3\u3002\u8fd9\u79cd\u7528\u4e8e\u4ecb\u5b54\u521a\u6027\u58f3\u4e2d\u4e0d\u7a33\u5b9aMOF\u7eb3\u7c73\u6676\u4f53\u7684\u5c01\u88c5\u548c\u9009\u62e9\u6027\u6c34\u8680\u523b\u65b9\u6cd5\u4e5f\u53ef\u4ee5\u7528\u4e8e\u5236\u9020\u5176\u5b83\u6838\u58f3\u7eb3\u7c73\u53cd\u5e94\u5668\uff0c\u8fd9\u53ef\u80fd\u4e3a\u5f00\u53d1\u7528\u4e8e\u5404\u79cd\u5e94\u7528\uff08\u4f8b\u5982\u50ac\u5316\u548c\u5206\u79bb\uff09\u7684\u591a\u529f\u80fd\u7eb3\u7c73\u7ed3\u6784\u5f00\u8f9f\u65b0\u7684\u65b9\u5411\u3002<\/div>\n<div>\u00a0<\/div>\n<div>\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1016\/j.matt.2020.06.021<\/div>\n<div>\u00a0<\/div>\n<div><strong>6\u3001 JACS\uff1a\u901a\u8fc7\u94fe\u57fa\u65e0\u673a\u6784\u7b51\u5355\u5143\u8c03\u6574\u6d3b\u6027\u4f4d\u70b9\u4e4b\u95f4\u7684\u95f4\u8ddd\u7528\u4e8e\u6c27\u8fd8\u539f\u53cd\u5e94\u7684\u535f\u5549\u9506\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6<\/strong><\/div>\n<div>\u00a0<\/div>\n<div><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-208338 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72476-21.png\" alt=\"\" width=\"522\" height=\"300\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72476-21.png 522w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72476-21-300x172.png 300w\" sizes=\"(max-width: 522px) 100vw, 522px\" \/><\/div>\n<div>\u00a0<\/div>\n<div>\u7f8e\u56fd\u5fb7\u5dde\u519c\u5de5\u5927\u5b66\u5468\u5b8f\u624d\u6559\u6388\u3001\u745e\u5178\u65af\u5fb7\u54e5\u5c14\u6469\u5927\u5b66\u9ec4\u54f2\u660a\u548c\u9655\u897f\u5e08\u8303\u5927\u5b66\u90d1\u6d69\u94e8\u526f\u6559\u6388\u7b49\u4eba\u5f00\u53d1\u4e86\u4e00\u79cd\u65b0\u7684\u57fa\u4e8eZr\u6c27\u5316\u7269\u94fe\u7684MOF PCN-226\u3002\u91d1\u5c5e\u535f\u5549\u88ab\u5e76\u5165\u9aa8\u67b6\u4e2d\uff0c\u53ef\u4ee5\u7528\u4f5c\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u50ac\u5316\u5242\u3002 PCN-226\u5177\u6709\u51fa\u8272\u7684\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u53ef\u589e\u5f3a\u5176\u5728\u6c34\u6eb6\u6db2\u4e2d\u4f5c\u4e3a\u7535\u50ac\u5316\u5242\u7684\u76f8\u5bb9\u6027\u3002\u7814\u7a76\u4eba\u5458\u5f3a\u8c03\u4e86\u5728\u7535\u5316\u5b66\u5e94\u7528\u7684MOF\u8bbe\u8ba1\u4e2d\u57fa\u4e8e\u94fe\u76843D\u7ed3\u6784\u7684\u91cd\u8981\u6027\u3002\u5c24\u5176\u662f\uff0c\u57fa\u4e8e\u94fe\u7684MOF\u4e0d\u4ec5\u5141\u8bb8\u5e76\u5165\u5bc6\u6392\u7684\u9ad8\u5bc6\u5ea6\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u4f4d\u70b9\uff0c\u800c\u4e14\u8fd8\u53ef\u4ee5\u8c03\u6574\u8fd9\u4e9b\u6d3b\u6027\u4f4d\u70b9\u4e4b\u95f4\u7684\u95f4\u9694\u3002\u7531\u4e8e\u91c7\u7528\u4e86\u8fd9\u79cd\u7b56\u7565\uff0c PCN-226\u5177\u6709\u51fa\u8272\u7684\u6d3b\u6027\u3002MOF\u7ed3\u6784\u7684\u53ef\u8c03\u8c10\u6027\u548c\u53ef\u8bbe\u8ba1\u6027\u5c06\u4fc3\u8fdb\u57fa\u4e8e\u94fe\u76843D MOF\u4f5c\u4e3a\u7535\u50ac\u5316\u5242\u7684\u53d1\u5c55\u3002\u8fd9\u5c06\u8fdb\u4e00\u6b65\u7f29\u5c0f\u7f51\u72b6\u5316\u5b66\u4e0e\u6750\u6599\u50ac\u5316\u4e4b\u95f4\u7684\u5dee\u8ddd\uff0c\u7279\u522b\u662f\u5728\u7535\u50ac\u5316\u65b9\u9762\uff0c\u8fd9\u5927\u5927\u4fc3\u8fdb\u4e86\u7eff\u8272\u80fd\u6e90\u7684\u8f6c\u5316\u548c\u5b58\u50a8\u3002<\/div>\n<div>\u00a0<\/div>\n<div>\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/pubs.acs.org\/doi\/10.1021\/jacs.0c06329<\/div>\n<div>\u00a0<\/div>\n<div><strong>7\u3001Angew\uff1a\u7528\u4e8e\u6bd4\u7387\u6e29\u5ea6\u4f20\u611f\u7684\u9567\u7cfb\u5143\u7d20PolyMOF\u6742\u5316\u819c<\/strong><\/div>\n<div>\u00a0<\/div>\n<div><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-208339 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72477-19.png\" alt=\"\" width=\"554\" height=\"482\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72477-19.png 554w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72477-19-300x261.png 300w\" sizes=\"(max-width: 554px) 100vw, 554px\" \/><\/div>\n<div>\u00a0<\/div>\n<div>\u7f8e\u56fd\u5fb7\u514b\u8428\u65af\u5927\u5b66\u5723\u5b89\u4e1c\u5c3c\u5965\u5206\u6821\u9648\u90a6\u6797\u3001\u6cb3\u5317\u5de5\u4e1a\u5927\u5b66\u674e\u5fd7\u5f3a\u526f\u6559\u6388\u548c\u674e\u7115\u8363\u6559\u6388\u7b49\u4eba\u901a\u8fc7\u5c06Ln-MOF\u4e0eBMA\u5355\u4f53\u5149\u8bf1\u5bfc\u5171\u805a\u5408\uff0c\u5f00\u53d1\u4e86\u4e00\u79cd\u65b0\u9896\u7684\u72ec\u7acb\u5f0f\u4e14\u5747\u8d28\u7684\u819c\u53d1\u5149\u6bd4\u4f8b\u6e29\u5ea6\u8ba1\u3002\u6240\u5f97\u7684\u6742\u5316\u819c\u663e\u793a\u51fa\u826f\u597d\u7684\u7ed3\u6784\u5b8c\u6574\u6027\uff0c\u5e76\u4ee5\u67d4\u6027\u5f62\u5f0f\u4fdd\u7559\u4e86\u6df7\u5408\u9567\u7cfbMOF\u7684\u6e29\u5ea6\u611f\u6d4b\u884c\u4e3a\u3002\u6b64\u5916\uff0cpolyMOF\u6df7\u5408\u819c\u53d1\u5149\u6e29\u5ea6\u8ba1\u5177\u6709\u51fa\u8272\u7684\u53ef\u52a0\u5de5\u6027\uff0c\u5305\u62ec\u67d4\u97e7\u6027\uff0c\u53ef\u5b9a\u5236\u6027\u548c\u7c98\u9644\u6027\u3002\u800c\u4e14\uff0c\u5373\u4f7f\u5728\u9ad8\u6e7f\u5ea6\u548c\u5f3a\u9178\/\u78b1\u6027\u4ecb\u8d28\u7b49\u6076\u52a3\u73af\u5883\u4e0b\u5de5\u4f5c\uff0c\u4e5f\u53ef\u4ee5\u4fdd\u6301\u6df7\u5408\u819c\u7684\u6e29\u5ea6\u76d1\u63a7\u80fd\u529b\u3002\u5f97\u76ca\u4e8eMOF\u548c\u805a\u5408\u7269\u57fa\u8d28\u7684\u53ef\u8c03\u7ed3\u6784\uff0c\u5177\u6709\u6240\u9700\u4f20\u611f\u884c\u4e3a\u7684polyMOF\u6742\u5316\u819c\u7684\u5e94\u7528\u8303\u56f4\u53ef\u4ee5\u8fdb\u4e00\u6b65\u6269\u5c55\u3002\u8fd9\u9879\u5de5\u4f5c\u5c06\u52a0\u901f\u53d1\u5149\u6d4b\u6e29\u6750\u6599\u7684\u5546\u4e1a\u5e94\u7528\u3002<\/div>\n<div>\u00a0<\/div>\n<div>\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1002\/anie.202009765<\/div>\n<div>\u00a0<\/div>\n<div><strong>8\u3001AEM\uff1aMOF\u884d\u751f\u7684\u5355\u539f\u5b50\u50ac\u5316\u5242\u7528\u4e8e\u7535\u5316\u5b66\u5e94\u7528\u7684\u7814\u7a76\u8fdb\u5c55<\/strong><\/div>\n<div>\u00a0<\/div>\n<div><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-208340 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72478-18.png\" alt=\"\" width=\"533\" height=\"415\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72478-18.png 533w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/\u56fe\u72478-18-300x234.png 300w\" sizes=\"(max-width: 533px) 100vw, 533px\" \/><\/div>\n<div>\u00a0<\/div>\n<div>\u52a0\u62ff\u5927\u897f\u5b89\u5927\u7565\u5927\u5b66\u5b59\u5b66\u826f\u6559\u6388\u548c\u6df1\u5733\u5927\u5b66\u9a86\u9759\u5229\u6559\u6388\u7b49\u4eba\u603b\u7ed3\u4e86\u4ece\u5178\u578bMOF\u7b56\u7565\u8bbe\u8ba1\u7684\u65b0\u578bSAC\u7684\u6700\u65b0\u8fdb\u5c55\uff0c\u5e76\u4ed4\u7ec6\u8ba8\u8bba\u4e86\u6bcf\u79cd\u7b56\u7565\u7684\u5404\u81ea\u5408\u6210\u673a\u7406\u3002\u7136\u540e\u4f9d\u6b21\u8ba8\u8bba\u4e86\u5c40\u90e8\u7535\u5b50\u7ed3\u6784\u548c\u534f\u8c03\u73af\u5883\u4ee5\u53ca\u7a33\u5b9a\u7684SAC\u6d3b\u52a8\u4e2d\u5fc3\u7684\u539f\u4f4d\u548c\u5f02\u4f4d\u8868\u5f81\u6280\u672f\u3002\u5728\u603b\u7ed3MOF\u884d\u751f\u7684SAC\u5728\u7535\u50ac\u5316\u4e2d\u7684\u5148\u8fdb\u8fdb\u5c55\u65f6\uff0c\u53ef\u4ee5\u5f97\u51fa\u7ed3\u8bba\uff0cSAC\u4e0d\u4ec5\u5728\u5404\u79cd\u53cd\u5e94\u4e2d\u663e\u793a\u51fa\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u800c\u4e14\u6709\u52a9\u4e8e\u7406\u89e3\u4e0d\u540c\u7684\u53cd\u5e94\u673a\u7406\u548c\u9014\u5f84\u3002\u5c3d\u7ba1\u7814\u7a76\u4eba\u5458\u5df2\u4ed8\u51fa\u4e86\u5de8\u5927\u7684\u52aa\u529b\uff0c\u4f46\u4ecd\u9700\u8981\u514b\u670dSAC\u7684\u51e0\u4e2a\u5173\u952e\u6311\u6218\uff0c\u4ee5\u5b9e\u73b0\u672a\u6765\u7684\u5b9e\u9645\u5e94\u7528\u3002\u9664\u4e86\u5728\u65b0\u578b\u7535\u50ac\u5316\u5242\u7684\u672a\u6765\u8bbe\u8ba1\u4e2d\u8981\u8003\u8651\u6210\u672c\u548c\u53ef\u7528\u6027\u4ee5\u5916\uff0c\u8fd8\u5fc5\u987b\u89e3\u51b3\u7535\u50ac\u5316\u6d3b\u6027\uff0c\u9009\u62e9\u6027\u548c\u7a33\u5b9a\u6027\u3002 SAC\u7684\u6027\u80fd\u5728\u5f88\u5927\u7a0b\u5ea6\u4e0a\u53d6\u51b3\u4e8e\u5176\u5185\u5728\u7279\u6027\u548c\u4e0e\u6d3b\u52a8\u4e2d\u5fc3\u76f8\u5173\u7684\u5916\u90e8\u56e0\u7d20\u3002<\/div>\n<div>\u00a0<\/div>\n<div>\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1002\/aenm.202001561<\/div>\n<p>\u672c\u6587\u7531eric\u4f9b\u7a3f\u3002<\/p>\n<p>\u672c\u5185\u5bb9\u4e3a\u4f5c\u8005\u72ec\u7acb\u89c2\u70b9\uff0c\u4e0d\u4ee3\u8868\u6750\u6599\u4eba\u7f51\u7acb\u573a\u3002<\/p>\n<p>\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>1\u3001 Science\uff1a\u591a\u53d8\u91cf\u91d1\u5c5e-\u6709\u673a\u6846\u67b6\u4e2d\u91d1\u5c5e\u7684\u6392\u5e8f \u00a0 \u00a0 \u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821Omar M. Yaghi\u548c\u5fb7\u56fd\u6ce2\u9e3f\u9c81\u5c14\u5927\u5b66Tong Li\u7b49\u4eba\u5728\u542b\u6709\u94b4\uff08C&#8230;<\/p>\n","protected":false},"author":11454,"featured_media":208343,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1187],"tags":[],"class_list":["post-208332","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zhuanlan"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/208332"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=208332"}],"version-history":[{"count":4,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/208332\/revisions"}],"predecessor-version":[{"id":208345,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/208332\/revisions\/208345"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/208343"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=208332"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=208332"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=208332"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}