{"id":208610,"date":"2020-09-02T06:18:14","date_gmt":"2020-09-01T22:18:14","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=208610"},"modified":"2020-09-01T22:18:33","modified_gmt":"2020-09-01T14:18:33","slug":"%e5%8f%af%e8%81%9a%e5%90%88%e5%9e%8b%e7%96%8f%e6%b0%b4%e6%94%b9%e6%80%a7%e4%b9%99%e6%b0%a7%e5%9f%ba%e5%8c%96%e8%81%9a%e6%b0%a8%e9%85%af%e4%b8%99%e7%83%af%e9%85%b8%e9%85%af%e8%81%9a%e5%90%88%e7%89%a9","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=208610","title":{"rendered":"\u53ef\u805a\u5408\u578b\u758f\u6c34\u6539\u6027\u4e59\u6c27\u57fa\u5316\u805a\u6c28\u916f\u4e19\u70ef\u9178\u916f\u805a\u5408\u7269:\u5408\u6210\u53ca\u5176\u5728\u6c34\u6027\u4f53\u7cfb\u4e2d\u7684\u7c98\u5f39\u884c\u4e3a"},"content":{"rendered":"<p><strong>\u3010\u7814\u7a76\u80cc\u666f\u3011<\/strong><\/p>\n<p>\u758f\u6c34\u6539\u6027\u4e59\u6c27\u57fa\u5316\u805a\u6c28\u916f\uff08HEURs\uff09\u5c5e\u4e8e\u4e00\u7c7b\u7279\u6b8a\u7684\u9065\u722a\u578b\u805a\u96c6\u9ad8\u5206\u5b50\uff0c\u88ab\u5e7f\u6cdb\u7528\u4f5c\u6c34\u6027\u4f53\u7cfb\u7684\u6d41\u53d8\u6dfb\u52a0\u5242\uff0c\u4ee5\u8c03\u8282\u6c34\u6027\u4f53\u7cfb\uff08\u5982\u6d82\u6599\u548c\u6cb9\u58a8\uff09\u7684\u7c98\u5f39\u6027\u3002\u7136\u800c\uff0c\u5e38\u89c4\u7684HEURs\u901a\u5e38\u662f\u4e0d\u53cd\u5e94\u7684\u5e76\u4e14\u4ee5\u6e38\u79bb\u6001\u7684\u5f62\u5f0f\u4fdd\u7559\u5728\u6700\u7ec8\u6d82\u819c\u4e2d\uff0c\u8fd9\u53ef\u80fd\u5728\u4f7f\u7528\u65f6\u95f4\u5185\u5bf9\u6700\u7ec8\u56fa\u5316\u819c\u5e26\u6765\u4e00\u4e9b\u7f3a\u9677\u548c\u635f\u574f\u3002\u6539\u5584\u6210\u819c\u6027\u80fd\u7684\u4e00\u79cd\u5438\u5f15\u4eba\u7684\u65b9\u6cd5\u53ef\u80fd\u662f\u8bbe\u8ba1\u53cd\u5e94\u6027HEURs\uff0c\u5b83\u4eec\u53ef\u4ee5\u5728\u819c\u56fa\u5316\u8fc7\u7a0b\u4e2d\u4e0e\u914d\u65b9\u4e2d\u5176\u4ed6\u7ec4\u5206\u7684\u540e\u4ea4\u8054\u53cd\u5e94\u3002\u636e\u6211\u4eec\u6240\u77e5\uff0c\u8fd9\u79cd\u5177\u6709\u53cd\u5e94\u6027\u6216\u53ef\u805a\u5408\u6027\u758f\u6c34\u7aef\u57fa\u7684\u53cd\u5e94\u6027HEURs\u76ee\u524d\u8fd8\u6ca1\u6709\u62a5\u9053\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u534e\u5357\u7406\u5de5\u5927\u5b66\u4efb\u78a7\u91ce\u6559\u6388\u4e0e\u675c\u67f1\u5eb7\u535a\u58eb<\/strong>\u8054\u5408\u62a5\u9053\u4e86\u7531\u53cd\u5e94\u6027\u7532\u57fa\u4e19\u70ef\u9178\u916f\u57fa\u56e2\u548c\u758f\u6c34\u6027\u5341\u516b\u70f7\u57fa\u5c3e\u7aef\u5b98\u80fd\u5316\u7684\u53ef\u805a\u5408\u4e19\u70ef\u9178\u578bHEUR\uff08acrylic-HEUR\uff09\u3002\u901a\u8fc7\u52a8\u6001\u5149\u6563\u5c04\uff0c\u539f\u4f4d\u6838\u78c1\u5171\u632f\uff08<sup>1<\/sup>H NMR\uff09\u548c\u6d41\u53d8\u5b66\u6d4b\u91cf\uff0c\u53ef\u4ee5\u6e05\u695a\u5730\u9610\u660e\u57fa\u4e8e\u9ad8\u53cd\u5e94\u6027\u7532\u57fa\u4e19\u70ef\u9178\u916f\u57fa\u7684\u4e19\u70ef\u9178\u578bHEUR\u7684\u5178\u578b\u81ea\u7531\u57fa\u805a\u5408\u7279\u5f81\u3002\u4e19\u70ef\u9178\u578bHEUR\u5728\u6c34\u6027\u7d2b\u5916\u7ebf\u4e73\u6db2\u4e2d\u7684\u4f18\u5f02\u589e\u7a20\u6027\u80fd\u53ca\u5176\u4e0e\u7d2b\u5916\u7ebf\u53ef\u56fa\u5316\u57fa\u4f53\u6811\u8102\u7684\u6709\u6548\u5171\u805a\u53cd\u5e94\u6027\u5df2\u901a\u8fc7\u5728\u7d2b\u5916\u7ebf\u7167\u5c04\u4e0b\u8fdb\u884c\u7684\u539f\u4f4d\u6d41\u53d8\u6d4b\u91cf\u5f97\u5230\u4e86\u8be6\u7ec6\u8bc1\u660e\u3002\u4e0e\u4f20\u7edf\u7684\u975e\u53cd\u5e94\u6027HEUR\u76f8\u6bd4\uff0c\u4e19\u70ef\u9178\u578bHEUR\u7684\u5171\u805a\u53cd\u5e94\u6027\u4f7f\u5176\u7279\u522b\u9002\u7528\u4e8e\u6c34\u6027UV\u6d82\u6599\uff0c\u4ece\u800c\u907f\u514d\u4e86\u5176\u4ece\u6700\u7ec8\u7684UV\u56fa\u5316\u819c\u4e2d\u8fc1\u79fb\u51fa\u6765\u7684\u60c5\u51b5\u3002\u8fd9\u9879\u5de5\u4f5c\u4e0d\u4ec5\u53ef\u4ee5\u4e3a\u5236\u5907\u5177\u6709\u9ad8\u5316\u5b66\u53cd\u5e94\u6027\u7684HEUR\u805a\u5408\u7269\u5f00\u8f9f\u65b0\u7684\u89c6\u91ce\uff0c\u800c\u4e14\u6709\u671b\u5c06\u53ef\u805a\u5408\u7684HEURs\u7528\u4f5c\u5de5\u4e1a\u4e0a\u4f18\u826f\u7684\u7f14\u5408\u589e\u7a20\u5242\u7684\u6f5c\u529b\u3002\u8be5\u6587\u7ae0\u8fd1\u65e5\u4ee5\u9898\u4e3a\u201c<strong>Polymerizable Hydrophobically Modified Ethoxylated Urethane Acrylate Polymer: Synthesis and Viscoelastic Behavior in Aqueous Systems<\/strong>\u201d\u53d1\u8868\u5728\u77e5\u540d\u671f\u520a<strong>Macromolecules<\/strong>\u4e0a\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe\u4e00\u3001\u4e19\u70ef\u9178\u578b<\/strong><strong>HEUR<\/strong><strong>\u5728\u7d2b\u5916\u7ebf\u7167\u5c04\u4e0b\u7684\u5316\u5b66\u53cd\u5e94\u6027<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-208612\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/1-1.jpeg\" alt=\"\" width=\"600\" height=\"484\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/1-1.jpeg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/1-1-300x242.jpeg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u5728\u7d2b\u5916\u7ebf\u7167\u5c040\u300110\u300130\u548c60 s\u540e\uff0c\u4e19\u70ef\u9178-HEUR\u548c\u5149\u5f15\u53d1\u5242\uff081173\uff09\u5728CDCl<sub>3<\/sub>\u4e2d\u7684\u6df7\u5408\u7269\u7684\u539f\u4f4d<sup>1<\/sup>H NMR\u5149\u8c31\u3002<\/p>\n<p><strong>\u56fe\u4e8c\u3001\u4e19\u70ef\u9178\u578b<\/strong><strong>HEUR<\/strong><strong>\u5728\u7d2b\u5916\u7ebf\u8f90\u5c04\u4e0b\u7684\u805a\u5408\u53cd\u5e94\u6027<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-208613\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/2-1.jpeg\" alt=\"\" width=\"600\" height=\"247\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/2-1.jpeg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/2-1-300x124.jpeg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09\u75281173\u5149\u5f15\u53d1\u5242\u5bf90.3g\/L\u4e19\u70ef\u9178\u578bHEUR\u6c34\u6eb6\u6db2\u8fdb\u884c\u7d2b\u5916\u8f90\u71670\u300110\u300120\u300140\u548c90s\u540e\u7684\u5f1b\u8c6b\u65f6\u95f4\u5206\u5e03\u3002<\/p>\n<p>\uff08b\uff09\u7d2b\u5916\u8f90\u5c04\u8bf1\u5bfc\u80f6\u675f\u6838\u5fc3\u7532\u57fa\u4e19\u70ef\u9178\u57fa\u56e2\u81ea\u7531\u57fa\u805a\u5408\u5bf9\u80f6\u675f\u548c\u80f6\u675f\u805a\u96c6\u4f53\u5f1b\u8c6b\u884c\u4e3a\u5f71\u54cd\u7684\u793a\u610f\u56fe\u3002<\/p>\n<p><strong>\u56fe\u4e09\u3001\u4e19\u70ef\u9178\u578b<\/strong><strong>HEUR<\/strong><strong>\u6c34\u6eb6\u6db2\u7684\u7c98\u5f39\u6027\u8d28<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-208614\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/3-1.jpeg\" alt=\"\" width=\"600\" height=\"460\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/3-1.jpeg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/3-1-300x230.jpeg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a-c\uff09\u7d2b\u5916\uff08\u03b3=5%\uff0c\u03c9=3.14 rad\/s\uff09\u6761\u4ef6\u4e0b\u542b0.85mg\/1173\u7684\uff08a\uff0915\u3001\uff08b\uff0925\u548c\uff08c\uff0935g\/L\u4e19\u70ef\u9178\u578bHEUR\u6c34\u6eb6\u6db2\u7684G\u2032\u3001G\u3003\u548c\u635f\u8017\u89d2\u6b63\u5207\uff08tan\u03b4\uff09\u7684\u52a8\u6001\u53d8\u5316\u3002<\/p>\n<p>\uff08d-f\uff09\u7d2b\u5916\u7ebf\u7167\u5c04\uff08\u03b3=5%\uff09\u524d\u540e\uff08d\uff0915\u3001\uff08e\uff0925\u548c\uff08f\uff0935g\/L\u4e19\u70ef\u9178\u578bHEUR\u6c34\u6eb6\u6db2\u7684\u9891\u7387\u626b\u63cf\u6d4b\u91cf\u3002<\/p>\n<p><strong>\u56fe\u56db\u3001\u4e19\u70ef\u9178<\/strong><strong>-HEUR<\/strong><strong>\u7684\u526a\u5207\u6d41\u53d8\u6027\u80fd<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-208615\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/4-1.jpeg\" alt=\"\" width=\"600\" height=\"388\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/4-1.jpeg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/4-1-300x194.jpeg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u572825\u00b0C\u4e0b\u6307\u5b9a\u6d53\u5ea6\u4e0b\u7684\u4e19\u70ef\u9178\u578bHEUR\u6c34\u6eb6\u6db2\u7684\u7a33\u6001\uff08a\uff09\u548c\u632f\u8361\uff08b\uff09\u526a\u5207\u6d4b\u91cf\u3002<\/p>\n<p><strong>\u56fe\u4e94\u3001\u4e19\u70ef\u9178<\/strong><strong>-HEUR<\/strong><strong>\u7684\u589e\u7a20\u6027\u80fd<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-208616\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/5-1.jpeg\" alt=\"\" width=\"600\" height=\"287\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/5-1.jpeg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/5-1-300x144.jpeg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09\u4e0d\u540c\u4e19\u70ef\u9178\u578bHEUR\u63ba\u91cf\u7684WUV 47\u4e73\u5316\u6db2\u572825\u2103\u65f6\u7684\u7a33\u5b9a\u526a\u5207\u6d41\u53d8\u5b66\u3002<\/p>\n<p>\uff08b\uff09\u572825\u2103\u65f6\u63ba\u51650.3 wt %\u7684\u4e19\u70ef\u9178\u578bHEUR\u7684WUV 47\u4e73\u5316\u6db2\u7684\u591a\u6b21\u4ea4\u66ff\u526a\u5207\u901f\u7387\u8bd5\u9a8c\u3002<\/p>\n<p><strong>\u56fe\u516d\u3001\u4e19\u70ef\u9178\u578b<\/strong><strong>HEUR<\/strong><strong>\u4e0e\u6c34\u6027<\/strong><strong>UV<\/strong><strong>\u6811\u8102\u7684\u5171\u805a<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-208617\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/6-1.jpeg\" alt=\"\" width=\"600\" height=\"279\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/6-1.jpeg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/08\/6-1-300x140.jpeg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09\u4e24\u79cdHEUR\u589e\u7a20\u4e73\u6db2\u5728\u632f\u8361\u526a\u5207\u8fc7\u7a0b\u4e2d\u526a\u5207\u5f39\u6027\u6a21\u91cf\u968f\u65f6\u95f4\u7684\u53d8\u5316\uff08\u03b3=5%\uff0c\u03c9=6.28 rad\/s\uff09\u3002<\/p>\n<p>\uff08b\uff09\u4e24\u79cd\u4ea4\u8054\u4e73\u6db2\u7684\u5e94\u529b\u677e\u5f1b\u6d4b\u91cf\uff08\u03b3=10%\uff09\u3002<\/p>\n<p>\uff08c\uff09\u677e\u5f1b\u4e24\u4e2aUV\u56fa\u5316\u4e73\u6db2\u6837\u54c1\u7684\u4e00\u534a\u521d\u59cb\u5e94\u529b\u7684\u65f6\u95f4\u3002<\/p>\n<p><strong>\u3010\u7ed3\u8bba\u5c55\u671b\u3011<\/strong><\/p>\n<p>\u7efc\u4e0a\u6240\u8ff0\uff0c\u672c\u6587\u62a5\u9053\u4e86\u4e00\u79cd\u542b\u7532\u57fa\u4e19\u70ef\u9178\u7aef\u57fa\u7684\u53ef\u805a\u5408HEUR\u805a\u5408\u7269\uff08\u4e19\u70ef\u9178\u578bHEUR\uff09\u3002\u4e19\u70ef\u9178\u578bHEUR\u5728\u7d2b\u5916\u5149\u7167\u5c04\u4e0b\uff0c\u4e0d\u4ec5\u5177\u6709\u826f\u597d\u7684\u589e\u7a20\u6027\u80fd\uff0c\u800c\u4e14\u5728\u6c34\u6eb6\u6db2\u4e2d\u5177\u6709\u9ad8\u805a\u5408\u6027\u3002\u4e19\u70ef\u9178\u578bHEUR\u589e\u7a20\u4e73\u6db2\u5728\u591a\u79cd\u4ea4\u53d8\u526a\u5207\u6761\u4ef6\u4e0b\u8868\u73b0\u51fa\u826f\u597d\u7684\u7c98\u5ea6\u6062\u590d\u6027\u80fd\u3002\u4e19\u70ef\u9178\u578bHEUR\u805a\u5408\u7269\u7684\u53cd\u5e94\u7279\u6027\u4f7f\u5176\u7279\u522b\u9002\u7528\u4e8e\u6c34\u6027UV\u6d82\u6599\uff0c\u56e0\u4e3a\u4e0e\u57fa\u4f53UV\u6811\u8102\u6216\u53cd\u5e94\u6027\u5355\u4f53\u8fdb\u884c\u5316\u5b66\u4ea4\u8054\u53ef\u663e\u8457\u51cf\u5c11\u5176\u4ece\u6700\u7ec8\u56fa\u5316\u819c\u4e2d\u7684\u8fc1\u79fb\u3002\u8fd9\u9879\u5de5\u4f5c\u5bf9\u4e8e\u5f00\u53d1\u7528\u4e8e\u6c34\u6027UV\u7cfb\u7edf\uff08\u5982\u6d82\u6599\u3001\u6d82\u6599\u3001\u7c98\u5408\u5242\u3001\u6cb9\u58a8\u3001\u67d3\u6599\u7b49\uff09\u7684\u9ad8\u7ea7HEUR\u7f14\u5408\u589e\u7a20\u5242\u53ef\u80fd\u5f88\u6709\u610f\u4e49\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"https:\/\/pubs.acs.org\/doi\/full\/10.1021\/acs.macromol.0c00982\" target=\"_blank\" rel=\"noopener\">Polymerizable Hydrophobically Modified Ethoxylated Urethane Acrylate Polymer: Synthesis and Viscoelastic Behavior in Aqueous Systems<\/a> (<em>Macromolecules<\/em>, <strong>2020<\/strong>, DOI: 10.1021\/acs.macromol.0c00982)<\/p>\n<p>\u672c\u6587\u7531\u5927\u5175\u54e5\u4f9b\u7a3f\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1a<a href=\"mailto:tougao@cailiaoren.com\">tougao@cailiaoren.com<\/a><\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenvip\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u7814\u7a76\u80cc\u666f\u3011 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