{"id":208979,"date":"2020-12-03T12:00:48","date_gmt":"2020-12-03T04:00:48","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=208979"},"modified":"2020-12-03T11:57:40","modified_gmt":"2020-12-03T03:57:40","slug":"%e3%80%90%e5%b7%b2%e6%a0%a1%e7%a8%bf%e3%80%91%e4%b8%ad%e7%a7%91%e5%a4%a7%e5%ad%a3%e6%81%92%e6%98%9fangew%e5%90%ab%e9%92%b4%e5%82%ac%e5%8c%96%e5%89%82%e5%8f%af%e6%98%be%e8%91%97%e6%8f%90%e9%ab%98al-s","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=208979","title":{"rendered":"\u4e2d\u79d1\u5927\u5b63\u6052\u661fAngew:\u542b\u94b4\u50ac\u5316\u5242\u53ef\u663e\u8457\u63d0\u9ad8Al-S\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd"},"content":{"rendered":"<p><strong>\u3010\u7814\u7a76\u80cc\u666f\u3011<\/strong><\/p>\n<p>\u53ef\u5145\u7535\u94dd\u786b\uff08Al-S\uff09\u7535\u6c60\u7531\u4e8e\u5176\u5b89\u5168\u6027\u3001\u8f83\u5927\u7684\u80fd\u91cf\u5bc6\u5ea6\uff088050 mAh cm<sup>-3<\/sup>\uff09\u548c\u6bd4\u5bb9\u91cf\uff082890 mAh g<sup>-1<\/sup>\uff09\u4ee5\u53ca\u7ec4\u6210\u7535\u6781\u6750\u6599\u7684\u9ad8\u5730\u7403\u4e30\u5ea6\u800c\u88ab\u8ba4\u4e3a\u662f\u9502\u79bb\u5b50\u7535\u6c60\u7cfb\u7edf\u4ee5\u5916\u7684\u6f5c\u5728\u66ff\u4ee3\u54c1\uff0c\u4f46\u662f\uff0c\u7531\u4e8e\u786b\u6b63\u6781\u7684\u8fdf\u6ede\u52a8\u529b\u5b66\u54cd\u5e94\u5bfc\u81f4\u9ad8\u5145\u653e\u7535\u7535\u538b\u6ede\u540e\u548c\u4f4e\u80fd\u91cf\u5bc6\u5ea6\uff0c\u4ece\u800c\u964d\u4f4e\u4e86\u6574\u4f53\u50a8\u80fd\u6548\u7387\u3002\u6b64\u5916\uff0c\u5bff\u547d\u77ed\u662f\u9650\u5236Al-S\u7535\u6c60\u5411\u5e94\u7528\u53d1\u5c55\u7684\u4e3b\u8981\u95ee\u9898\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u5b63\u6052\u661f\u6559\u6388\u56e2\u961f<\/strong>\u7814\u7a76\u4e86Co\uff08II\uff0cIII\uff09\u5bf9\u53ef\u5145\u7535Al-S\u7535\u6c60\u4e2d\u786b\u7684\u7535\u5316\u5b66\u8f6c\u5316\u53cd\u5e94\u7684\u50ac\u5316\u4f5c\u7528\uff0c\u4ece\u800c\u964d\u4f4e\u4e86\u653e\u7535\u7535\u538b\u6ede\u540e\uff0c\u63d0\u9ad8\u4e86\u5bb9\u91cf\u4fdd\u6301\u7387\u548c\u901f\u7387\u5bb9\u91cf\u3002\u5f53Co\uff08II\uff0cIII\uff09\u56fa\u5b9a\u5728\u6b63\u6781\u7684\u78b3\u57fa\u4f53\u4e2d\u6216\u6eb6\u89e3\u5728\u79bb\u5b50\u6db2\u4f53\u57fa\u7535\u89e3\u8d28\u4e2d\u65f6\uff0c\u89c2\u5bdf\u5230\u4e86Co\uff08II\uff0cIII\uff09\u5bf9\u786b\u7684\u7535\u5316\u5b66\u8f6c\u5316\u7684\u50ac\u5316\u4f5c\u7528\uff0cXPS\u5206\u6790\u8868\u660e\uff0cCo\uff08II\uff0cIII\uff09\u7684\u4ef7\u6001\u53d8\u5316\u4e0eCo\uff08II\uff0cIII\uff09\u7684\u4ef7\u6001\u53d8\u5316\u6709\u5173\u3002\u4ee5\u78b3\u57fa\u56fa\u4f53\u8f7dCo\uff08II\uff0cIII\uff09\u4e3a\u6b63\u6781\u7ec4\u88c5\u7684Al-S\u7535\u6c60\u5177\u6709~0.8v\u7684\u4f4e\u7535\u538b\u6ede\u56de\u7279\u6027\uff0c\u57281A g<sup>-1<\/sup>\u6761\u4ef6\u4e0b\u8fdb\u884c200\u6b21\u5145\u653e\u7535\u5faa\u73af\u540e\uff0c\u6bd4\u5bb9\u91cf\u4fdd\u6301\u4e3a500 mAh g<sup>-1<\/sup>\uff0c3A g<sup>-1<\/sup>\u5faa\u73af\u65f6\u6bd4\u5bb9\u91cf\u4fdd\u6301\u4e3a300 mAh g<sup>-1<\/sup>\uff0c\u8868\u660e\u6539\u8fdb\u7684\u53cd\u5e94\u52a8\u529b\u5b66\u548c\u6b63\u6781\u786b\u5229\u7528\u7387\u3002\u8be5\u6587\u7ae0\u8fd1\u65e5\u4ee5\u9898\u4e3a\u201c<strong>Rechargeable Aluminum-Sulfur Battery with Improved Electrochemical Performance by Cobalt- Containing Electrocatalyst<\/strong>\u201d\u53d1\u8868\u5728\u77e5\u540d\u671f\u520a<strong>Angew. Chem. Int. Ed.<\/strong>\u4e0a\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe\u4e00\u3001\u7535\u6781\u6027\u80fd\u6d4b\u8bd5<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-214027\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/09\/1-44.jpg\" alt=\"\" width=\"600\" height=\"175\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/09\/1-44.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/09\/1-44-300x88.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>&nbsp;<\/p>\n<p>\uff08a\uff09\u5bf9\u79f0\u7535\u6c60\u7684CV\u66f2\u7ebf\u3002<\/p>\n<p>\uff08b\uff09\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a1A g<sup>-1<\/sup>\u7684\u60c5\u51b5\u4e0b\uff0c\u5728\u4e0d\u540c\u6b63\u6781\u6750\u6599\u7ec4\u6210\u7684Al-S\u7535\u6c60\u7684\u7b2c\u4e00\u4e2a\u5faa\u73af\u4e2d\u6d4b\u91cf\u7684\u6052\u6d41\u653e\u7535\u5145\u7535\u66f2\u7ebf\u3002<\/p>\n<p>\uff08c\uff09Al-S\u7535\u6c60\u7684\u7535\u538b\u6ede\u540e\uff0c\u5373\u5145\u7535\u548c\u653e\u7535\u5e73\u5747\u7535\u538b\u4e4b\u95f4\u7684\u5dee\u503c\u66f2\u7ebf\u3002<\/p>\n<p><strong>\u56fe\u4e8c\u3001<\/strong><strong>Al-S<\/strong><strong>\u7535\u6c60<\/strong><strong>\u4e2d<\/strong><strong>Co<\/strong><strong>\uff08<\/strong><strong>II<\/strong><strong>\uff0c<\/strong><strong>III<\/strong><strong>\uff09\u7684\u5316\u5b66\u72b6\u6001\u7814\u7a76<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-214028\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/09\/2-45.jpg\" alt=\"\" width=\"600\" height=\"717\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/09\/2-45.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/09\/2-45-251x300.jpg 251w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>&nbsp;<\/p>\n<p>\uff08a\uff09\u5728Co\/C\u548cS@Co\/C\u590d\u5408\u7c89\u672b\u4e0a\u8fdb\u884c\u7684Co 2p\u5149\u8c31\u7684XPS\u3002<\/p>\n<p>\uff08b\uff09\u5728\u65e0\u94b4\u7535\u89e3\u6db2\u4e2d\u5faa\u73af\u7684S@Co\/C\u6b63\u6781\u548c\u5728\u542bCoCl<sub>2<\/sub>\u7535\u89e3\u6db2\u4e2d\u5faa\u73af\u7684S@C\u6b63\u6781\u4e0a\u8fdb\u884c\u7684Co 2p\u5149\u8c31\u5206\u6790\u3002<\/p>\n<p>\uff08c-d\uff09\u5728\u65e0\u94b4\u7535\u89e3\u6db2\u548cCoCl<sub>2<\/sub>\u7535\u89e3\u6db2\u4e2d\uff0c\u7528S@Co\/C\u7ec4\u88c5\u7684Al-S\u7535\u6c60\u7684\u6b63\u6781\u548c\u8d1f\u6781\u4e0a\u7684S 2p\u7684XPS\u5149\u8c31\u3002\u5206\u522b\u57280.1\u548c1.8 V\u7535\u538b\u4e0b\uff08\u76f8\u5bf9\u4e8eAl\/Al<sup>3+<\/sup>\uff09\u5bf9Al-S\u7535\u6c60\u8fdb\u884c\u4e86\u89e3\u538b\uff0c\u83b7\u5f97\u4e86\u7535\u6c60\u653e\u7535\u548c\u5145\u7535\u72b6\u6001\u7684XPS\u6570\u636e\u3002<\/p>\n<p><strong>\u56fe\u4e09\u3001<\/strong><strong>Al-S<\/strong><strong>\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\u7814\u7a76<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-214029\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/09\/3-43.jpg\" alt=\"\" width=\"600\" height=\"463\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/09\/3-43.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/09\/3-43-300x232.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>&nbsp;<\/p>\n<p>\uff08a\uff09\u88c5\u6709S@Co\/C\u548cS@C\u6b63\u6781\u7684Al-S\u7535\u6c60\u7684CV\u3002<\/p>\n<p>\uff08b\uff09\u57281 A g<sup>-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u6d4b\u5f97\u7684\u7531S@Co\/C\u6b63\u6781\u7ec4\u6210\u7684Al-S\u7535\u6c60\u7684\u6052\u7535\u6d41\u653e\u7535-\u653e\u7535\u66f2\u7ebf\u53ca\u5176\u7535\u538b\u6ede\u540e\u3002<\/p>\n<p>\uff08c\uff09S@Co\/C\u6b63\u6781\u7684\u901f\u7387\u6027\u80fd\u3002<\/p>\n<p>\uff08d\uff09\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a1 A g<sup>-1<\/sup>\u65f6S@Co\/C\u548cS@C\u6b63\u6781\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n<p><strong>\u56fe\u56db\u3001\u7535\u6c60\u5bb9\u91cf\u4fdd\u6301\u7387\u7814\u7a76<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-214030\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/09\/4-43.jpg\" alt=\"\" width=\"600\" height=\"294\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/09\/4-43.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/09\/4-43-300x147.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>&nbsp;<\/p>\n<p>\uff08a\uff09\u5728\u88c5\u6709S@Co\/C\u548cS@C\u6b63\u6781\u7684Al-S\u7535\u6c60\u4e2d\uff0c\u7ecf\u8fc710\u4e2a\u653e\u7535-\u5145\u7535\u5faa\u73af\u540e\uff0c\u7535\u89e3\u6db2\u7684UV-vis\u5149\u8c31\u3002<\/p>\n<p>\uff08b\uff09S@Co\/C\u6b63\u6781\u5728\u653e\u7535\u548c\u5145\u7535\u72b6\u6001\u7684XRD\u56fe\u8c31\u3002<\/p>\n<p>\uff08c\uff09\u5728\u653e\u7535\u72b6\u6001\u548c\u5145\u7535\u72b6\u6001\u4e0b\u5728S@Co\/C\u6b63\u6781\u4e0a\u6d4b\u5f97\u7684S 2p\u7684XPS\u8c31\u56fe\u3002<\/p>\n<p><strong>\u3010\u7ed3\u8bba\u5c55\u671b\u3011<\/strong><\/p>\n<p>\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u5c06Co\uff08II\uff0cIII\uff09\u7528\u4f5cAl-S\u7535\u6c60\u7684\u7535\u5316\u5b66\u50ac\u5316\u5242\u3002\u5728\u7535\u6c60\u4e2d\u52a0\u5165Co\uff08II\uff0cIII\uff09\uff0c\u53ef\u63d0\u9ad8\u591a\u786b\u5316\u7269\u7684\u53cd\u5e94\u6d3b\u6027\uff0c\u964d\u4f4e\u7535\u538b\u6ede\u540e\u3002\u5f53Co\uff08II\uff0cIII\uff09\u56fa\u5b9a\u5728\u6b63\u6781\u7684\u78b3\u57fa\u4f53\u4e2d\u6216\u6eb6\u89e3\u5728\u79bb\u5b50\u6db2\u4f53\u57fa\u7535\u89e3\u8d28\u4e2d\u65f6\uff0c\u53ef\u4ee5\u89c2\u5bdf\u5230Co\uff08II\uff0cIII\uff09\u5bf9\u786b\u7535\u5316\u5b66\u8f6c\u5316\u7684\u50ac\u5316\u4f5c\u7528\uff0c\u8fd9\u79cd\u50ac\u5316\u4f5c\u7528\u53ef\u80fd\u4e0eCo\uff08II\uff0cIII\uff09\u5728\u653e\u7535-\u5145\u7535\u5faa\u73af\u4e2d\u7684\u4ef7\u6001\u53d8\u5316\u6709\u5173\u3002\u5f53\u78b3\u57fa\u4f53\u56fa\u5b9aCo\uff08II\uff0cIII\uff09\u65f6\uff0c\u8868\u73b0\u51fa\uf07e0.8v\u7684\u4f4e\u7535\u538b\u6ede\u540e\uff0c\u57281 A g<sup>-1<\/sup>\u4e0b\u8fdb\u884c200\u6b21\u5145\u653e\u7535\u5faa\u73af\u540e\uff0c\u6bd4\u5bb9\u91cf\u4fdd\u6301\u4e3a\uf07e500 mAh g<sup>-1<\/sup>\uff0c3 A g<sup>-1<\/sup>\u5faa\u73af\u65f6\u6bd4\u5bb9\u91cf\u4fdd\u6301\u4e3a300 mAh g<sup>-1<\/sup>\uff0c\u8868\u660e\u53cd\u5e94\u52a8\u529b\u5b66\u548c\u6b63\u6781\u786b\u5229\u7528\u7387\u6709\u6240\u63d0\u9ad8\u3002\u8fd9\u4e00\u5de5\u4f5c\u5bf9\u94dd\u786b\u7535\u6c60\u4e2d\u7684\u7535\u5316\u5b66\u50ac\u5316\u5242\u7684\u7814\u7a76\u5177\u6709\u4e00\u5b9a\u7684\u53c2\u8003\u4ef7\u503c\uff0c\u5bf9\u8fdb\u4e00\u6b65\u63d0\u9ad8\u94dd\u786b\u7535\u6c60\u7684\u52a8\u529b\u5b66\u54cd\u5e94\u548c\u7535\u5316\u5b66\u6027\u80fd\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/anie.202008481\">Rechargeable Aluminum\u2010Sulfur Battery with Improved Electrochemical Performance by Cobalt\u2010Containing Electrocatalyst<\/a> (<em>Angew. Chem. Int. Ed<\/em>, <strong>2020<\/strong>, DOI: 10.1002\/anie.202008481)<\/p>\n<p>\u672c\u6587\u7531\u5927\u5175\u54e5\u4f9b\u7a3f\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1a<a href=\"mailto:tougao@cailiaoren.com\">tougao@cailiaoren.com<\/a><\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u7814\u7a76\u80cc\u666f\u3011 \u53ef\u5145\u7535\u94dd\u786b\uff08Al-S\uff09\u7535\u6c60\u7531\u4e8e\u5176\u5b89\u5168\u6027\u3001\u8f83\u5927\u7684\u80fd\u91cf\u5bc6\u5ea6\uff088050 mAh cm-3\uff09\u548c\u6bd4\u5bb9\u91cf\uff082890 mAh g-1\uff09\u4ee5\u53ca\u7ec4\u6210\u7535\u6781\u6750\u6599\u7684\u9ad8\u5730\u7403\u4e30&#8230;<\/p>\n","protected":false},"author":1004,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[4471],"class_list":["post-208979","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-4471"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/208979"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/1004"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=208979"}],"version-history":[{"count":7,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/208979\/revisions"}],"predecessor-version":[{"id":214125,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/208979\/revisions\/214125"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=208979"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=208979"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=208979"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}