{"id":209554,"date":"2020-09-22T06:12:08","date_gmt":"2020-09-21T22:12:08","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=209554"},"modified":"2020-09-21T21:12:18","modified_gmt":"2020-09-21T13:12:18","slug":"%e7%ba%a2%e5%a4%96%e5%85%89%e8%b0%b1%ef%bc%88ftir%ef%bc%89%e5%9c%a8%e6%9d%90%e6%96%99%e9%a2%86%e5%9f%9f%e7%9a%84%e5%ba%94%e7%94%a8%e4%b8%8e%e5%88%86%e6%9e%90","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=209554","title":{"rendered":"\u7ea2\u5916\u5149\u8c31\uff08FTIR\uff09\u5728\u6750\u6599\u9886\u57df\u7684\u5e94\u7528\u4e0e\u5206\u6790"},"content":{"rendered":"

\u5085\u91cc\u53f6\u53d8\u6362\u7ea2\u5916\u5149\u8c31(Fourier Transform infrared spectroscopy\uff0c\u7b80\u79f0FTIR)\uff0c\u5927\u5bb6\u5e94\u8be5\u90fd\u5341\u5206\u719f\u6089\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5851\u6599\u3001\u6d82\u5c42\u3001\u586b\u6599\u3001\u7ea4\u7ef4\u7b49\u4f17\u591a\u9ad8\u5206\u5b50\u53ca\u65e0\u673a\u975e\u91d1\u5c5e\u6750\u6599\u7684\u5b9a\u6027\u4e0e\u5b9a\u91cf\u5206\u6790\u3002\u672c\u6587\u5c06\u7b80\u5355\u4ecb\u7ecd\u4e00\u4e0bFTIR\u7684\u539f\u7406\u548c\u7279\u70b9\uff0c\u7136\u540e\u8be6\u7ec6\u5730\u4ecb\u7ecdFTIR\u5728\u6750\u6599\u9886\u57df\u7684\u5e94\u7528\u3002<\/p>\n

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\"\"<\/p>\n

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1. \u00a0\u56fa\u5316\u7387\u6d4b\u8bd5<\/p>\n

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\"\"<\/p>\n

M’\/R’\u2014\u2014\u56fa\u5316\u540e\u80f6\u7c98\u5242\u7684\u6d4b\u91cf\u5cf0\u548c\u53c2\u8003\u5cf0\u7684\u6bd4\u503c<\/p>\n

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\"\"\"\"<\/p>\n

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2. \u9ad8\u5206\u5b50\u6750\u6599\u7684\u7ec4\u6210\u5206\u5e03\u7814\u7a76[2]<\/p>\n

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\"\"<\/p>\n

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\"\"<\/p>\n

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3. \u805a\u5408\u7269\u7ed3\u6784\u53ca\u53d8\u5316\u7684\u7814\u7a76[4]<\/p>\n

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\"\"<\/p>\n

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4. \u00a0FTIR\u5728\u6750\u6599\u963b\u71c3\u5206\u6790\u4e2d\u7684\u5e94\u7528[7]<\/p>\n

\u7ea2\u5916\u5149\u8c31\u4f5c\u4e3a\u4e00\u79cd\u9274\u5b9a\u7269\u8d28\u7ed3\u6784\u7684\u7406\u60f3\u65b9\u6cd5\uff0c\u5728\u5408\u6210\u963b\u71c3\u5242\u963b\u71c3\u6750\u6599\u65f6\uff0c\u53ef\u4ee5\u9a8c\u8bc1\u4ea7\u7269\u662f\u5426\u4e0e\u9884\u8ba1\u5316\u5408\u7269\u7ed3\u6784\u4e00\u81f4\uff0c\u5728\u4ea7\u54c1\u5236\u5907\u4e0e\u5206\u79bb\u8fc7\u7a0b\u4e2d\uff0c\u8fd8\u53ef\u4ee5\u9274\u5b9a\u4ea7\u54c1\u7684\u7eaf\u5ea6\u548c\u4e0e\u6742\u8d28\u7684\u5206\u79bb\u7a0b\u5ea6\u3002\u6b64\u5916\uff0c\u7ea2\u5916\u5149\u8c31\u6cd5\u53ef\u4ee5\u7814\u7a76\u6750\u6599\u7684\u963b\u71c3\u8fc7\u7a0b\uff0c\u963b\u71c3\u6750\u6599\u4e0e\u9632\u706b\u6d82\u6599\u5728\u9ad8\u6e29\u4f5c\u7528\u4e0b\uff0c\u53cd\u5e94\u751f\u6210\u65b0\u7684\u57fa\u56e2\uff0c\u5176\u7ea2\u5916\u5149\u8c31\u4f1a\u53d1\u751f\u53d8\u5316\uff0c\u5bf9\u7167\u71c3\u70e7\u524d\u540e\u7684\u8c31\u56fe\uff0c\u53ef\u4ee5\u7814\u7a76\u963b\u71c3\u6750\u6599\u7684\u963b\u71c3\u673a\u7406\u3002<\/p>\n

\u5bf9\u7ecf\u8fc7\u70ed\u6c27\u5316\u5904\u7406\u7684\u6837\u54c1\u8fdb\u884c\u7ea2\u5916\u5206\u6790\u53ef\u4ee5\u7814\u7a76\u963b\u71c3\u578b\u5c3c\u9f996\uff08PA6\uff09\/\u805a\u4e19\u70ef\uff08PP\uff09\u7845\u7070\u77f3\u590d\u5408\u6750\u6599\u4f53\u7cfb\u7684\u963b\u71c3\u673a\u7406\uff0c\u5c06\u4e09\u805a\u6c30\u80fa\u4e09\u805a\u6c30\u9178\u76d0\uff08MCA\uff09\uff0cPA6, PP\u7845\u7070\u77f3\u590d\u5408\u6750\u6599\u4e8e\u9a6c\u5f17\u7089\u4e2d\u70ed\u6c27\u5904\u7406\uff0c\u53d1\u73b0\u968f\u7740\u70ed\u6c27\u5904\u7406\u7684\u6e29\u5ea6\u5347\u9ad8\uff0cMCA\u963b\u71c3\u4f53\u7cfb\u4e2d\uff0c1741\u4e0e1781 cm-1<\/sup>\u5904MCA\u7684\u7279\u5f81\u5438\u6536\u5cf0\u9010\u6e10\u6d88\u5931\uff0c2248 cm-1<\/sup>\u5904\u51fa\u73b0\u8148\u57fa\u7684\u7279\u5f81\u5438\u6536\u5cf0\u3002\u7136\u800cPA6\u7ecf\u8fc7\u7c7b\u4f3c\u7684\u70ed\u6c27\u5904\u7406\u5f97\u5230\u7684\u6b8b\u4f59\u7269\u4e2d\u65e0\u8148\u57fa\u57fa\u56e2\uff0c\u53ea\u662f\u57281740\u00a0cm-1<\/sup>\u9644\u8fd1\u51fa\u73b0PA6\u89e3\u805a\u5206\u89e3\u7ec8\u7aef\u57fa\u56e2-CO-NH2<\/sub>\u7684\u7279\u5f81\u5438\u6536\u5cf0\u3002\u8fd9\u4e9b\u8bf4\u660e\u5728\u70ed\u6c27\u5904\u7406\u4e2dMCA\u7684\u4e09\u55ea\u73af\u5df2\u7ecf\u6253\u5f00\uff0c\u7531\u6b64\u53ef\u77e5\uff0c\u5728\u9ad8\u6e29\u4f5c\u7528\u4e0bMCA\u53d7\u70ed\u5206\u89e3\u50ac\u5316PA6\u4ece\u89e3\u805a\u5206\u89e3\u53d8\u4e3a\u70ad\u5316\u5206\u89e3\uff0cMCA\u5bf9PA6\/PP\/\u7845\u7070\u77f3\u590d\u5408\u6750\u6599\u4f53\u7cfb\u7684\u963b\u71c3\u4f5c\u7528\uff0c\u9664\u4e86\u201c\u5347\u534e\u5438\u70ed\u201d\u7684\u7269\u7406\u963b\u71c3\u4f5c\u7528\u5916,\u8fd8\u5177\u6709\u50ac\u5316PA6\u70ad\u5316\u81a8\u80c0\u7684\u5316\u5b66\u963b\u71c3\u4f5c\u7528\u3002<\/p>\n

\"\"<\/p>\n

\u56fe6. \u70ed\u6c27\u5904\u7406\u6837\u54c1\u7684\u7ea2\u5916\u5149\u8c31\u56fe[7]<\/p>\n

\u6b64\u5916\uff0c\u539f\u4f4d\u7ea2\u5916\u5149\u8c31\u6280\u672f\u53ef\u4ee5\u5728\u4e00\u5b9a\u6761\u4ef6\u4e0b\u71c3\u70e7\u53cd\u5e94\u53d1\u751f\u7684\u540c\u65f6\u8fdb\u884c\u7ea2\u5916\u5149\u8c31\u6d4b\u5b9a\uff0c\u901a\u8fc7\u67d0\u4e00\u4e2a\u6216\u51e0\u4e2a\u5438\u6536\u5cf0\u7684\u53d8\u5316\u80fd\u591f\u53cd\u6620\u51fa\u6750\u6599\u5728\u71c3\u70e7\u53cd\u5e94\u4e2d\u7684\u53d8\u5316\u3002<\/p>\n

5. \u7ea2\u5916\u5149\u8c31\u8054\u7528\u6280\u672f\u5728\u6750\u6599\u70ed\u5206\u89e3\u7814\u7a76\u4e2d\u7684\u5e94\u7528[8]<\/p>\n

FTIR\u548c\u56fa\u4f53\u539f\u4f4d\u53cd\u5e94\u6280\u672f\u3001\u5feb\u901f\u70ed\u88c2\u89e3\u539f\u4f4d\u53cd\u5e94\u6280\u672f\u4ee5\u53ca\u70ed\u5206\u6790\u6280\u672f\u7684\u8054\u7528\u5728\u5b9e\u65f6\u76d1\u6d4b\u6750\u6599\u53d7\u70ed\u5206\u89e3\u8fc7\u7a0b\u4e2d\u51dd\u805a\u76f8\u4e2d\u95f4\u4ea7\u7269\u3001\u7ec8\u6001\u4ea7\u7269\u548c\u6c14\u76f8\u4ea7\u7269\u7684\u7ec4\u6210\u4ee5\u53ca\u5206\u89e3\u8d77\u59cb\u6e29\u5ea6\u70b9\u548c\u6e29\u5ea6\u8303\u56f4\u65b9\u9762\u7684\u5e94\u7528\uff0c\u63d0\u4f9b\u4e86\u4e00\u79cd\u5207\u5b9e\u53ef\u884c\u7684\u6750\u6599\u70ed\u5206\u89e3\u673a\u7406\u7814\u7a76\u65b9\u6cd5\u3002<\/p>\n

\u56e0\u6b64\uff0c\u901a\u8fc7\u5085\u91cc\u53f6\u53d8\u6362\u7ea2\u5916\u5149\u8c31\u6280\u672f\u548c\u56fa\u4f53\u539f\u4f4d\u53cd\u5e94\u6280\u672f\u7684\u8054\u7528\uff08Thermolysis\/RSFT-IR\uff09\u53ef\u4ee5\u786e\u8ba4\u6709\u673a\u5316\u5408\u7269\u5728\u53d7\u70ed\u5206\u89e3\u8fc7\u7a0b\u4e2d\u51dd\u805a\u76f8\u7684\u4e2d\u95f4\u4ea7\u7269\u7684\u5316\u5b66\u7ed3\u6784\uff0c\u5e76\u901a\u8fc7\u5347\u6e29\u65f6\u95f4\u70b9\u3001\u6e29\u5ea6\u8bb0\u5f55\u7b49\u63a8\u5bfc\u51fa\u4e2d\u95f4\u51dd\u805a\u76f8\u4ea7\u7269\u548c\u7ec8\u6001\u51dd\u805a\u76f8\u4ea7\u7269\u7684\u751f\u6210\u6e29\u5ea6\u8303\u56f4\uff0c\u8fdb\u800c\u8be6\u7ec6\u4e86\u89e3\u6d4b\u8bd5\u5316\u5408\u7269\u7684\u53d7\u70ed\u5206\u89e3\u673a\u7406\u3002<\/p>\n

\"\"<\/p>\n

\u56fe7. DADNE\u70ed\u5206\u89e3\u8fc7\u7a0b\u6c14\u76f8\u4ea7\u7269\u7684\u7ea2\u5916\u5438\u6536\u5149\u8c31[8]<\/p>\n

6. FTIR\u5728\u94c1\u57fa\u8d85\u5bfc\u6750\u6599\u4e2d\u7684\u5e94\u7528[9]<\/p>\n

\u65b0\u7684\u8d85\u5bfc\u6750\u6599\u88ab\u53d1\u73b0\u7684\u65f6\u5019\uff0c\u7269\u7406\u5b66\u5bb6\u9996\u5148\u5173\u5fc3\u7684\u662f\u8d85\u5bfc\u80fd\u9699\u7684\u5927\u5c0f\u4ee5\u53ca\u5bf9\u79f0\u6027\uff0c\u56e0\u4e3a\u8fd9\u4e9b\u4fe1\u606f\u76f4\u63a5\u5173\u7cfb\u5230\u8d85\u5bfc\u7535\u5b50\u914d\u5bf9\u7684\u673a\u5236\u3002\u7406\u8bba\u8ba1\u7b97\u8868\u660e\u94c1\u57fa\u8d85\u5bfc\u4f53\u662f\u4e00\u7c7b\u975e\u5e38\u89c4\u8d85\u5bfc\u4f53\u3002\u5176\u7535\u5b50\u914d\u5bf9\u6001\u662f\u7531\u53cd\u94c1\u78c1\u81ea\u65cb\u6da8\u843d\u5f15\u8d77\u7684\uff0c\u7531\u6b64\u5bfc\u81f4\u7684\u8d85\u5bfc\u80fd\u9699\u5177\u6709s\u00b1\u5bf9\u79f0\u6027\u3002\u7ea2\u5916\u5149\u8c31\u5bf9\u8d85\u5bfc\u80fd\u9699\u4ee5\u53ca\u80fd\u9699\u4e2d\u53ef\u80fd\u51fa\u73b0\u7684\u672a\u914d\u5bf9\u51c6\u7c92\u5b50\u975e\u5e38\u654f\u611f\uff0c\u56e0\u6b64\uff0c\u53ef\u4ee5\u7528\u6765\u7814\u7a76\u94c1\u57fa\u8d85\u5bfc\u4f53\u4e2d\u8d85\u5bfc\u80fd\u9699\u5bf9\u79f0\u6027\u7684\u95ee\u9898\u3002<\/p>\n

\"\"<\/p>\n

\u56fe8. 5 K\u65f6\u6700\u4f73\u63ba\u6742\u7684 Ba(Fe0.92<\/sub>Co0.08<\/sub>)2<\/sub>As2<\/sub>\u00a0(Tc = 25 K)\u548c Ba0.6<\/sub>K0.4<\/sub>Fe2<\/sub>As2<\/sub>\u00a0(Tc = 38 K) \u7684\u5149\u7535\u5bfc\u8c31[9]<\/p>\n

Ba0.6<\/sub>K0.4<\/sub>Fe2<\/sub>As2<\/sub>\u7684\u5149\u7535\u5bfc\u8c31\u5728\u5927\u7ea6160\u00a0cm-1<\/sup>\u4ee5\u4e0b\u964d\u4e3a0\uff0c\u8bf4\u660e\u8d85\u5bfc\u80fd\u9699\u662fs\u6ce2\u5bf9\u79f0\u7684\uff0c\u80fd\u9699\u4e2d\u4e0d\u5b58\u5728\u672a\u914d\u5bf9\u7684\u51c6\u7c92\u5b50\u3002\u800cBa(Fe0.92<\/sub>Co0.08<\/sub>)2<\/sub>As2<\/sub>\u7684\u5149\u7535\u5bfc\u867d\u7136\u5728\u4f4e\u9891\u4e0b\u51fa\u73b0\u4e86\u5f88\u9661\u7684\u4e0b\u964d\uff08\u8868\u660e\u8d85\u5bfc\u80fd\u9699\u7684\u6253\u5f00\uff09\uff0c\u4f46\u6ca1\u6709\u964d\u81f3\u96f6\u3002\u4f4e\u9891\u7684\u5149\u7535\u5bfc\u8c31\u4ecd\u7136\u9700\u8981\u4e00\u4e2aDrude\u5206\u91cf\u6765\u63cf\u8ff0\uff08\u4ee3\u8868\u672a\u914d\u5bf9\u51c6\u7c92\u5b50\uff09\uff0c\u5982\u56fe\u4e2d\u84dd\u8272\u9634\u5f71\u90e8\u5206\u6240\u793a\uff0c\u8fd9\u8bf4\u660e\u8d85\u5bfc\u80fd\u9699\u4e2d\u5b58\u5728\u5927\u91cf\u7684\u672a\u914d\u5bf9\u8f7d\u6d41\u5b50\u3002<\/p>\n

\u7ed3\u8bed\uff1a<\/p>\n

\u968f\u7740\u79d1\u5b66\u6280\u672f\u7684\u53d1\u5c55\uff0c\u7ea2\u5916\u5149\u8c31\u6280\u672f\u7684\u53d1\u5c55\u4e5f\u5341\u5206\u8fc5\u901f\uff0c\u6280\u672f\u5f97\u5230\u4e86\u62d3\u5c55\uff0c\u5e94\u7528\u9886\u57df\u4e0d\u65ad\u53d8\u5bbd\u3002\u5982\u53cd\u5c04\u5149\u8c31\u3001\u5149\u58f0\u5149\u8c31\u6cd5\u3001\u65f6\u95f4\u5206\u8fa8\u5149\u8c31\u6cd5\u7b49\u3002\u8be5\u6280\u672f\u4e0e\u5176\u5b83\u6280\u672f\u8054\u5408\u68c0\u6d4b\u4e5f\u5df2\u6210\u4e3a\u53d1\u5c55\u8d8b\u52bf\uff0c\u4e0d\u65ad\u62d3\u5c55\u7ea2\u5916\u5149\u8c31\u6cd5\u7684\u5e94\u7528\u9886\u57df\u3002<\/p>\n

\u53c2\u8003\u6587\u732e\uff1a<\/p>\n

[1] \u9646\u5b87\u7fd4, \u7ea2\u5916\u5149\u8c31\u6d4b\u5b9aUV\u80f6(D)\u56fa\u5316\u7387\u7684\u63a2\u7a76, \u79d1\u6280\u89c6\u754c, 000 (2019) 190-191.<\/p>\n

[2] \u767d\u4e91, \u80e1\u5149\u8f89, \u674e\u7434\u6885, \u9648\u65b0\u542f, \u9ad9\u5ce1, \u5218\u4f1f\u4e3d, \u5085\u91cc\u53f6\u53d8\u6362\u7ea2\u5916\u5149\u8c31\u6cd5\u5728\u9ad8\u5206\u5b50\u6750\u6599\u7814\u7a76\u4e2d\u7684\u5e94\u7528, \u5206\u6790\u4eea\u5668, 220 (2018) 50-53.<\/p>\n

[3] \u91d1\u6a31\u534e, \u987e\u4e2d\u6021, \u5f3a\u97f3, \u6c88\u52bc, \u7a0b\u6b32\u6653, \u6768\u52c7, \u675c\u5609\u742a, \u5085\u91cc\u53f6\u53d8\u6362\u663e\u5fae\u7ea2\u5916\u5149\u8c31\u6cd5\u9274\u5b9a\u591a\u5c42\u590d\u5408\u8584\u819c\u6210\u5206, \u7406\u5316\u68c0\u9a8c-\u5316\u5b66\u5206\u518c, 52 (2016) 219-221.<\/p>\n

[4] \u5c1a\u5efa\u7586, \u5f20\u5e05, \u5f20\u65b0\u6167, \u6731\u5c0f\u71d5, \u5218\u82b3, \u7ea2\u5916\u5149\u8c31\u5728\u9ad8\u5206\u5b50\u6750\u6599\u7814\u7a76\u4e2d\u7684\u5e94\u7528, \u79d1\u6280\u521b\u65b0\u4e0e\u5e94\u7528, 000 (2019) 175-176.<\/p>\n

[5] \u674e\u5706, \u6dc0\u7c89\u63a5\u679d\u5171\u805a\u4e19\u70ef\u9170\u80fa\u805a\u5408\u7269\u51dd\u80f6\u4f53\u7cfb\u7684\u7814\u7a76\u4e0e\u5e94\u7528, \u4e2d\u56fd\u5730\u8d28\u5927\u5b66(\u5317\u4eac).<\/p>\n

[6] \u9ec4\u4e9a\u66e6, \u8d3e\u946b, \u674e\u5fb7\u5f3a, \u5c1a\u5efa\u7586, \u5f20\u96ea\u6885, \u738b\u519b, \u5218\u5fd7\u52c7, \u81ea\u7136\u6761\u4ef6\u4e0b\u53ef\u964d\u89e3\u519c\u819c\u5149\u964d\u89e3\u6027\u80fd\u7684\u7814\u7a76, \u77f3\u6cb3\u5b50\u5927\u5b66\u5b66\u62a5(\u81ea\u79d1\u7248), (2012) 113-117.<\/p>\n

[7] \u8521\u56fd\u5b8f, \u7ea2\u5916\u5149\u8c31\u6cd5\u5728\u6750\u6599\u963b\u71c3\u5206\u6790\u4e2d\u7684\u5e94\u7528, \u6b66\u8b66\u5b66\u9662\u5b66\u62a5, 21 (2005) 22-23.<\/p>\n

[8] \u674e\u5409\u796f, \u5218\u5c0f\u521a, \u4ed8\u5c0f\u9f99, \u6a0a\u5b66\u5fe0, \u7ea2\u5916\u5149\u8c31\u8054\u7528\u6280\u672f\u5728\u6750\u6599\u70ed\u5206\u89e3\u7814\u7a76\u4e2d\u7684\u5e94\u7528, \u5316\u5b66\u63a8\u8fdb\u5242\u4e0e\u9ad8\u5206\u5b50\u6750\u6599, 09 (2011) 29-32.<\/p>\n

[9] \u6234\u8000\u6c11, \u7ea2\u5916\u5149\u8c31\u5728\u94c1\u57fa\u8d85\u5bfc\u6750\u6599\u7814\u7a76\u4e2d\u7684\u5e94\u7528, \u7269\u7406\u5b66\u8fdb\u5c55, 038 (2018) 147-162.<\/p>\n

\u672c\u6587\u7531\u6625\u6625\u4f9b\u7a3f\u3002<\/p>\n

\u672c\u5185\u5bb9\u4e3a\u4f5c\u8005\u72ec\u7acb\u89c2\u70b9\uff0c\u4e0d\u4ee3\u8868\u6750\u6599\u4eba\u7f51\u7acb\u573a\u3002<\/p>\n

\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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