{"id":209702,"date":"2020-09-21T06:16:22","date_gmt":"2020-09-20T22:16:22","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=209702"},"modified":"2020-09-20T20:17:16","modified_gmt":"2020-09-20T12:17:16","slug":"%e7%ae%80%e5%8d%95%e5%8d%b4%e5%8d%8e%e4%b8%bd%ef%bc%8c%e5%b8%b8%e8%a7%81%e9%87%91%e5%b1%9e%e6%b0%a7%e5%8c%96%e7%89%a9%e5%8f%88%e5%9c%a8%e9%a1%b6%e5%88%8a%e5%a4%a7%e6%94%be%e5%bc%82%e5%bd%a9","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=209702","title":{"rendered":"\u7b80\u5355\u5374\u534e\u4e3d\uff0c\u5e38\u89c1\u91d1\u5c5e\u6c27\u5316\u7269\u53c8\u5728\u9876\u520a\u5927\u653e\u5f02\u5f69"},"content":{"rendered":"

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\u56fe1. TiO2<\/sub> NAs\u5236\u5907\u548c\u8868\u5f81<\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1a<\/p>\n

https:\/\/doi.org\/10.1002\/anie.202010110<\/p>\n

2. JACS\uff1aCu2<\/sub>O\u7eb3\u7c73\u6676\u63ba\u6742\u6c2f\u4fc3\u8fdb\u5206\u5b50\u6c27\u76f4\u63a5\u73af\u6c27\u5316\u4e19\u70ef[2]<\/sup><\/p>\n

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\u56fe2. \u50ac\u5316\u5242\u8868\u5f81\u3001\u50ac\u5316\u6027\u80fd\u6bd4\u8f83<\/p>\n

\"\"<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/p>\n

https:\/\/dx.doi.org\/10.1021\/jacs.0c03882<\/p>\n

3. Science\uff1a\u5ba4\u6e29\u6761\u4ef6\u4e0b\u5236\u5907\u9ad8\u6bd4\u8868\u9762\u79ef\u03b1-Al2<\/sub>O3<\/sub>\u7eb3\u7c73\u9897\u7c92[3]<\/sup><\/p>\n

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\u56fe3. \u03b1-Al2<\/sub>O3<\/sub>\u5408\u6210\u793a\u610f\u56fe<\/p>\n

\"\"<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/p>\n

http:\/\/science.sciencemag.org\/content\/366\/6464\/485<\/p>\n

4. NC\uff1aNi-\u03b3-Fe2<\/sub>O3<\/sub>\u9ad8\u6548\u5206\u89e3\u6c34[4]<\/sup><\/p>\n

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\u7535\u5316\u5b66\u5206\u89e3\u6c34\u5236\u6c22\u88ab\u8ba4\u4e3a\u662f\u6700\u6709\u524d\u9014\u7684\u65b9\u6cd5\u4e4b\u4e00\u3002\u6c22\u53ef\u5728\u7531\u6790\u6c22\u53cd\u5e94(HER)\u9634\u6781\u548c\u6790\u6c27\u53cd\u5e94(OER)\u9633\u6781\u7ec4\u6210\u7684\u7535\u89e3\u69fd\u88c5\u7f6e\u4e2d\u4ea7\u751f\u3002\u7136\u800c\uff0c\u8d35\u91d1\u5c5e\u57fa\u7535\u6781\u6750\u6599\u7684\u4f7f\u7528\u663e\u8457\u589e\u52a0\u4e86\u7ecf\u6d4e\u6210\u672c\u3002\u5728\u78b1\u6027\u4ecb\u8d28\u4e2d\uff0c\u57fa\u4e8e\u4f4e\u6210\u672c\u7684\u8fc7\u6e21\u91d1\u5c5e\u954d\u548c\u94c1\u7684\u6c27\u5316\u7269\/\u6c22\u6c27\u5316\u7269\u50ac\u5316\u5242\u5728OER\u4e2d\u88ab\u8ba4\u4e3a\u662f\u6709\u524d\u9014\u7684\u50ac\u5316\u5242\uff0c\u5176\u8fc7\u7535\u4f4d\u53ef\u4f4e\u81f3\u7ea6200 mV\u4ee5\u8fbe\u523010 mA cm\u20132<\/sup>\u7535\u6d41\u5bc6\u5ea6\uff0c\u7136\u800c\uff0c\u5b83\u4eec\u901a\u5e38\u4e0d\u9002\u7528\u4e8eHER\u3002\u5728\u6b64\uff0c\u6fb3\u5927\u5229\u4e9a\u65b0\u5357\u5a01\u5c14\u58eb\u5927\u5b66\u8d75\u5ddd\u6559\u6388\u7b49\u5c55\u793a\u4e86\u4e00\u79cd\u5177\u6709\u72ec\u7279\u7684\u954d-\u94c1\u6c27\u5316\u7269\u754c\u9762\u7684\u7eb3\u7c73\u9897\u7c92\u50ac\u5316\u5242(Ni-Fe NP)\u3002\u8be5\u50ac\u5316\u5242\u7531\u91d1\u5c5eNi\u4e0e\u03b3-Fe2<\/sub>O3<\/sub>\u5f62\u6210\u5f02\u8d28\u754c\u9762\uff0c\u754c\u9762\u5904\u91d1\u5c5eNi\u548c\u03b3-Fe2<\/sub>O3<\/sub>\u4ea7\u751f\u5f3a\u7535\u5b50\u8026\u5408\u6548\u5e94\uff0c\u8d4b\u4e88\u5176\u4f18\u5f02\u7684HER\u50ac\u5316\u6027\u80fd\uff0c\u751a\u81f3\u53ef\u4e0e\u57fa\u51c6Pt\/C\u50ac\u5316\u5242\u76f8\u6bd4\u8f83\u3002\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba(DFT)\u8ba1\u7b97\u8868\u660e\uff0cNi-\u03b3-Fe2<\/sub>O3<\/sub>\u754c\u9762\u5904\u5f62\u6210\u7684Ni-O-Fe\u952e\u6539\u53d8\u4e86\u4e2d\u95f4\u6c22\u539f\u5b50\u5438\u9644\u7684\u5409\u5e03\u65af\u81ea\u7531\u80fd(\u25b3GH*<\/sub>)\uff0c\u4ece\u800c\u8fdb\u4e00\u6b65\u63d0\u9ad8\u4e86HER\u50ac\u5316\u6027\u80fd\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u8be5\u50ac\u5316\u5242\u8fd8\u8868\u73b0\u51fa\u975e\u51e1\u7684OER\u6d3b\u6027\uff0c\u50ac\u5316\u5242\u5728\u7535\u6d41\u5bc6\u5ea6\u8fbe\u523010 mA cm\u20132<\/sup> \u65f6\u8fc7\u7535\u4f4d\u4ec5\u4e3a210 mV\uff0c\u8fd9\u4f7f\u5f97\u80fd\u591f\u4e3a\u5168\u7535\u89e3\u6c34\u53cd\u5e94\u63d0\u4f9b\u6d3b\u6027\u548c\u7a33\u5b9a\u7684\u53cc\u529f\u80fd\u50ac\u5316\u5242\u3002<\/p>\n

\u56fe4. Ni-\u03b3-Fe2<\/sub>O3<\/sub>\u7eb3\u7c73\u7c92\u5b50\u8bbe\u8ba1\u548c\u8868\u5f81<\/p>\n

\"\"<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/p>\n

https:\/\/doi.org\/10.1038\/s41467-019-13415-8<\/p>\n

5. AM\uff1a\u8010\u76d0\u592a\u9633\u80fd\u6d77\u6c34\u6de1\u5316\u7eb3\u7c73\u7ea4\u7ef4\u6c14\u51dd\u80f6\u83b7\u7a81\u7834[5]<\/sup><\/p>\n

\"\"<\/p>\n

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\u56fe5. \u5e38\u89c4\u592a\u9633\u80fd\u84b8\u53d1\u5668\u548cCNFAs\u76d0\u8fd0\u8f93\uff0c\u6c34\u8fd0\u8f93\uff0c\u5149\u5438\u6536\u548c\u84b8\u53d1\u793a\u610f\u56fe<\/p>\n

\"\"<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/p>\n

https:\/\/doi.org\/10.1002\/adma.201908269<\/p>\n

\u53c2\u8003\u6587\u732e<\/p>\n

[1] Liu Y T, Zhang M, Wang Y, et al. Conductive and Elastic TiO2<\/sub> Nanofibrous Aerogels: A New Concept toward Self-Supported Electrocatalysts with Superior Activity and Durability [J]. Angewandte Chemie International Edition.<\/p>\n

[2] Zhan C, Wang Q, Zhou L, et al. Critical roles of doping Cl on Cu2<\/sub>O nanocrystals for direct epoxidation of propylene by molecular oxygen [J]. Journal of the American Chemical Society, 2020, 142(33): 14134-14141.<\/p>\n

[3] Amrute A P, \u0141odziana Z, Schreyer H, et al. High-surface-area corundum by mechanochemically induced phase transformation of boehmite [J]. Science, 2019, 366(6464): 485-489.<\/p>\n

[4] Suryanto B H R, Wang Y, Hocking R K, et al. Overall electrochemical splitting of water at the heterogeneous interface of nickel and iron oxide[J]. Nature communications, 2019, 10(1): 1-10.<\/p>\n

[5] Dong X, Cao L, Si Y, et al. Cellular Structured CNTs@ SiO2<\/sub> Nanofibrous Aerogels with Vertically Aligned Vessels for Salt\u2010Resistant Solar Desalination [J]. Advanced Materials, 2020, 32(34): 1908269.<\/p>\n

\u672c\u6587\u7531whuchx\u4f9b\u7a3f\u3002<\/p>\n

\u672c\u5185\u5bb9\u4e3a\u4f5c\u8005\u72ec\u7acb\u89c2\u70b9\uff0c\u4e0d\u4ee3\u8868\u6750\u6599\u4eba\u7f51\u7acb\u573a\u3002<\/p>\n

\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n

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