{"id":210322,"date":"2020-09-29T06:43:43","date_gmt":"2020-09-28T22:43:43","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=210322"},"modified":"2020-09-28T21:43:53","modified_gmt":"2020-09-28T13:43:53","slug":"%e5%9b%bd%e4%ba%a7%e6%9c%9f%e5%88%8a%e9%87%8c%e7%9a%84%e7%ba%b3%e7%b1%b3%e9%87%91%e5%b1%9e%e5%9b%a2%e7%b0%87%ef%bc%8c%e7%8e%a9%e5%87%ba%e4%bb%80%e4%b9%88%e8%8a%b1%e6%a0%b7%ef%bc%81","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=210322","title":{"rendered":"\u56fd\u4ea7\u671f\u520a\u91cc\u7684\u7eb3\u7c73\u91d1\u5c5e\u56e2\u7c07\uff0c\u73a9\u51fa\u4ec0\u4e48\u82b1\u6837\uff01"},"content":{"rendered":"

\u56e2\u7c07\u662f\u4ecb\u4e8e\u539f\u5b50\u3001\u5206\u5b50\u4e0e\u5927\u5757\u6750\u6599\u4e4b\u95f4\u7684\u4e00\u79cd\u7269\u8d28\u72b6\u6001\uff0c\u4e0e\u7eb3\u7c73\u6750\u6599\u548c\u5fae\u7c92\u5e76\u65e0\u4e25\u683c\u6982\u5ff5\u4e0a\u7684\u754c\u9650\u3002\u65b0\u56e2\u7c07\u6750\u6599\u7684\u5236\u5907\u53ca\u6027\u80fd\u7814\u7a76\u662f\u56e2\u7c07\u8d70\u5411\u5e94\u7528\u7684\u4e3b\u8981\u9014\u5f84\u4e4b\u4e00\uff0c\u662f\u4eba\u4eec\u6781\u611f\u5174\u8da3\u7684\u56e2\u7c07\u79d1\u5b66\u7684\u4e00\u5927\u8bfe\u9898\u3002\u4e00\u822c\u7684\u56e2\u7c07\u9897\u7c92\u5927\u5c0f\u5728\u7eb3\u7c73\u91cf\u7ea7\uff0c\u5fc5\u4f1a\u4f34\u968f\u5f88\u5f3a\u7684\u91cf\u5b50\u9650\u5236\u6548\u5e94\uff0c\u5bfc\u81f4\u8bb8\u591a\u65b0\u73b0\u8c61\u548c\u65b0\u6027\u8d28\u7684\u51fa\u73b0\uff0c\u65b0\u56e2\u7c07\u6750\u6599\u7684\u7814\u7a76\u5c1a\u5904\u4e8e\u53d1\u5c55\u9636\u6bb5\uff0c\u63a5\u4e0b\u6765\u4e00\u8d77\u8d70\u8fdb\u56fd\u4ea7\u671f\u520a\u91cc\u7684\u56e2\u7c07\u7814\u7a76\u3002<\/p>\n

N<\/b><\/strong>SR<\/b><\/strong>\uff1a<\/b><\/strong>\u96c6\u6210\u4eff\u751f\u9567\u7cfb\u8fc7\u6e21\u91d1\u5c5e\u56e2\u7c07\u548cP\u63ba\u6742\u6c2e\u5316\u78b3\u7528\u4e8e<\/b><\/strong>\u9ad8\u6548\u5149\u50ac\u5316\u6574\u4f53\u6c34\u88c2\u89e3<\/b><\/strong><\/p>\n

\u81ea\u7136\u754c\u7684\u5149\u5408\u4f5c\u7528\u662f\u4ee5Mn4<\/sub>CaO5<\/sub>\u4e3a\u6c27\u8fdb\u5316\u4e2d\u5fc3\uff0c\u5728\u5149\u7cfb\u7edfII (PS II)\u4e2d\u6709\u6548\u5730\u50ac\u5316\u6c34\u7684\u88c2\u89e3\u3002\u5728\u6b64\uff0c\u53a6\u95e8\u5927\u5b66Xiang-Jian Kong\u6559\u6388\u5c55\u793a\u4e86\u4e00\u4e2a\u4eff\u751f\u5f02\u91d1\u5c5e\u79bb\u5b50\u56e2\u7c07LnCo3<\/sub>\u00a0(Ln = Nd, Eu\u548cCe\u56e2\u7c07)\uff0c\u53ef\u4ee5\u770b\u4f5c\u662f\u5408\u6210\u7684CaMn4<\/sub>O5<\/sub>\u56e2\u7c07\u3002\u951a\u5b9aLnCo3<\/sub>\u7684\u78f7\u63ba\u6742\u7684\u77f3\u58a8\u78b3\u6c2e\u5316\u7269(PCN) \u5728\u4e0d\u9700\u8981\u4efb\u4f55\u727a\u7272\u8bd5\u5242\u7684\u60c5\u51b5\u4e0b,\u8868\u73b0\u51fa\u9ad8\u6548\u7684\u6574\u4f53\u6c34\u88c2\u89e3\u3002NdCo3 <\/sub>\/PCN-c\u5149\u50ac\u5316\u5242\u5728350nm\u5904\u5177\u6709\u826f\u597d\u7684\u6c34\u5206\u88c2\u6d3b\u6027\u548c2.0%\u7684\u91cf\u5b50\u6548\u7387\u3002\u8d85\u5feb\u77ac\u6001\u5438\u6536\u5149\u8c31(TA)\u663e\u793a\u4e86\u5149\u6fc0\u53d1\u7535\u5b50\u548c\u7a7a\u7a74\u8f6c\u79fb\u5230PCN\u548cLnCo3<\/sub>\u4e2d\uff0c\u5206\u522b\u7528\u4e8e\u6c22\u548c\u6c27\u7684\u6f14\u5316\u53cd\u5e94\u3002DFT\u8ba1\u7b97\u7ed3\u679c\u8868\u660e\uff0c\u9567\u7cfb\u5143\u7d20\u5bf9\u6c34\u7684\u534f\u540c\u6d3b\u5316\u4f5c\u7528\u4ee5\u53ca\u8fc7\u6e21\u91d1\u5c5e\u4e0aO-O\u952e\u7684\u5f62\u6210\u5bf9\u6c34\u7684\u6c27\u5316\u4f5c\u7528\u3002\u672c\u7814\u7a76\u4e0d\u4ec5\u6784\u5efa\u4e86\u4eff\u751f\u6c27\u8fdb\u5316\u4e2d\u5fc3\u7684\u5408\u6210\u6a21\u578b\uff0c\u800c\u4e14\u4e3a\u5b9e\u73b0\u5149\u9a71\u52a8\u7684\u6574\u4f53\u6c34\u5206\u89e3\u63d0\u4f9b\u4e86\u6709\u6548\u7b56\u7565\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cIntegration of Bio-Inspired Lanthanide-Transition Metal Cluster and P-doped\u00a0Carbon Nitride for Efficient Photocatalytic Overall Water Splitting\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728NSR\u4e0a\u3002<\/p>\n

DOI:\u00a010.1093\/nsr\/nwaa234\/5905425<\/p>\n

\u56fe1\u00a0NdCo3<\/sub>\/PCN-c\u7684\u5149\u50ac\u5316\u6027\u80fd<\/p>\n

\"\"<\/p>\n

SCIENTIA SINICA Chimica<\/b><\/strong>\uff1a<\/b><\/strong>\u6c14\u76f8Cr<\/b><\/strong>x<\/b><\/sub><\/strong>N<\/b><\/strong>–<\/b><\/sup><\/strong>\u00a0(x=2~7)\u9634\u79bb\u5b50\u56e2\u7c07\u4e0eCO<\/b><\/strong>2<\/b><\/sub><\/strong>\u7684\u53cd\u5e94\u7814\u7a76<\/b><\/strong><\/p>\n

\u5ba4\u6e29\u4e0b\u5c06\u4e8c\u6c27\u5316\u78b3(CO2<\/sub>)\u9ad8\u6548\u8fd8\u539f\u4e3a\u4e00\u6c27\u5316\u78b3(CO)\u5bf9\u4e8eCO2<\/sub>\u8d44\u6e90\u7684\u5229\u7528\u81f3\u5173\u91cd\u8981\u3002\u5317\u4eac\u7406\u5de5\u5927\u5b66\u9a6c\u5609\u74a7\u6559\u6388\u7b49\u4eba\u901a\u8fc7\u9ad8\u5206\u8fa8\u7387\u53cd\u5c04\u5f0f\u98de\u884c\u65f6\u95f4\u8d28\u8c31\u7ed3\u5408\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba(DFT)\u8ba1\u7b97, \u5728\u70ed\u78b0\u649e\u6761\u4ef6\u4e0b\u5229\u7528\u94ec\u6c2e\u9634\u79bb\u5b50\u56e2\u7c07Crx<\/sub>N–<\/sup>\u00a0(x=2~7)\u5b9e\u73b0\u4e86\u8fde\u7eed\u8fd8\u539f\u4e24\u4e2aCO2<\/sub>\u5206\u5b50. Crx<\/sub>N–<\/sup>\u00a0(x=2~7)\u548cCr2<\/sub>NH–<\/sup>\u56e2\u7c07\u53ef\u4ee5\u4e0eCO2\u53cd\u5e94\u5206\u522b\u751f\u6210Crx<\/sub>NO–<\/sup>\/CO\u548cCr2<\/sub>NHO–<\/sup>\/CO, \u4e4b\u540e\u4e2d\u95f4\u4ea7\u7269\u4e09\u5143\u9634\u79bb\u5b50Crx<\/sub>NO–<\/sup>\u53ef\u4ee5\u8fdb\u4e00\u6b65\u8fd8\u539f\u7b2c\u4e8c\u4e2aCO2<\/sub>\u751f\u6210Crx<\/sub>NO2<\/sub>–<\/sup>\u548cCO\u5206\u5b50. \u4e0a\u8ff0\u8fde\u7eed\u53cd\u5e94\u5177\u6709\u9ad8\u53cd\u5e94\u6d3b\u6027, \u5e76\u4e14\u65e0CO2<\/sub>\u5438\u9644\u4ea7\u7269\u751f\u6210. \u968f\u7740\u56e2\u7c07\u4e2d\u94ec\u539f\u5b50\u6570\u76ee\u4ece2\u589e\u52a0\u52307 (Cr2<\/sub>N–<\/sup>~Cr7<\/sub>N–<\/sup>), \u56e2\u7c07\u7684\u53cd\u5e94\u6d3b\u6027\u5148\u589e\u52a0\u540e\u7565\u6709\u964d\u4f4e\u3002DFT\u8ba1\u7b97\u7ed9\u51fa\u4e86\u8be5\u7c7b\u6d3b\u6027\u9634\u79bb\u5b50\u7684\u7ed3\u6784\u548c\u8fde\u7eed\u53cd\u5e94\u7684\u53cd\u5e94\u673a\u7406. \u8fd9\u9879\u5de5\u4f5c\u4e3a\u9006\u6c34\u7164\u6c14\u50ac\u5316\u5242\u8868\u9762\u6d3b\u6027\u4f4d\u7684\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cThe study on the reaction of gas-phase Crx<\/sub>N–<\/sup>\u00a0(x=2~7) anion clusters with CO2<\/sub>\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728SCIENTIA SINICA Chimica\u4e0a\u3002<\/p>\n

DOI: 10.1360\/SSC-2020-0061<\/p>\n

\u56fe2\u00a0DFT\u8ba1\u7b97\u7684Cr2<\/sub>N–<\/sup>\u00a0(7<\/sup>IA1, 7<\/sup>IA5) (a)\u548cCr2<\/sub>NO–<\/sup>\u00a0(7<\/sup>IA21)(b)\u4e0eCO2<\/sub>\u53cd\u5e94\u7684\u52bf\u80fd\u9762\u66f2\u7ebf<\/p>\n

\"\"<\/p>\n

Nano<\/b><\/strong>\u00a0Research<\/b><\/strong>\uff1a<\/b><\/strong>\u91d1\u5c5e\u56e2\u7c07\u57fa\u91d1\u5c5e\u6709\u673a\u7eb3\u7c73\u7ba1\u7684\u9ad8\u8d28\u5b50\u5bfc\u7535\u6027<\/b><\/strong><\/p>\n

\u798f\u5efa\u5e08\u8303\u5927\u5b66Chulong Liu\u6559\u6388\u8054\u5408\u4e2d\u56fd\u79d1\u5b66\u9662\u798f\u5efa\u7269\u8d28\u7ed3\u6784\u7814\u7a76\u6240Zhangjing Zhang\u3001Shengchang Xiang\u6559\u6388\u5408\u6210\u4e24\u79cd\u65b0\u578b\u9634\u79bb\u5b50\u5355\u58c1\u6709\u673a\u91d1\u5c5e\u7eb3\u7c73\u7ba1(MONTs) [(CH3<\/sub>)2<\/sub>NH2<\/sub>][In(cdc)(thb)]\u00b72DMF\u00b79.5H2<\/sub>O (FJU-105) \u548c[(CH3<\/sub>)2<\/sub>NH2<\/sub>][In(cdc)(H-btc)]\u00b72DMA\u00b711H2<\/sub>O (FJU-106) (H2<\/sub>cdc = 9H-carbazole-3,6-dicarboxylic acid, H2<\/sub>thb = 2,5-thiophene dicarboxylicacid, H3<\/sub>btc = 1,3,5-benzene tricarboxylic acid)\u3002\u00a0[In6<\/sub>(cdc)6<\/sub>]6+<\/sup>\u56e2\u7c07\u4f5c\u4e3a\u6784\u9020\u5355\u5143\uff0cFJU-106\u7684\u5185\u8868\u9762\u88abH-btc\u8fde\u63a5\u7684\u4e0d\u534f\u8c03-COOH\u57fa\u56e2\u529f\u80fd\u5316\uff0c\u5bfc\u81f4\u6bd4FJU-105\u66f4\u9ad8\u7684\u8d28\u5b50\u4f20\u5bfc\u3002\u572870\u2103\u4e0b\uff0cFJU-106\u8868\u73b0\u51fa\u4e86\u8d28\u5b50\u4f20\u5bfc\u6027\u80fd\u53ef\u8fbe1.80\u00d710\u22122<\/sup>\u00a0S\u00b7cm\u22121<\/sup>\u3002FJU-105\u548cFJU-106\u662fMONT\u8d28\u5b50\u5bfc\u4f53\u5728\u96f6\u4e0b\u6e29\u5ea6\u4e0b\u5de5\u4f5c\u7684\u7b2c\u4e00\u4e2a\u4f8b\u5b50\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cHigh proton conductivity in metalloring-cluster based metal-organic nanotubes\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nano\u00a0Research\u4e0a\u3002<\/p>\n

DOI: 10.1007\/s12274-020-2785-x<\/p>\n

\u56fe3\u00a0FJU-105 \u548cFJU-106\u6676\u4f53\u7ed3\u6784<\/p>\n

\"\"<\/p>\n

JEC<\/b><\/strong>\uff1aC<\/b><\/strong>u-Cu<\/b><\/strong>2<\/b><\/sub><\/strong>O\u7eb3\u7c73\u56e2\u7c07\u5177\u6709\u7a33\u5b9a\u6027\u548c\u9009\u62e9\u6027<\/b><\/strong>C<\/b><\/strong>O<\/b><\/strong>2<\/b><\/sub><\/strong>\u7535\u5316\u5b66\u8fd8\u539f<\/b><\/strong><\/p>\n

\u8fd1\u5e74\u6765\uff0c\u5229\u7528\u7535\u5316\u5b66\u624b\u6bb5\u5c06\u4e8c\u6c27\u5316\u78b3\u8f6c\u5316\u4e3a\u5177\u6709\u9644\u52a0\u503c\u7684\u5316\u5b66\u54c1\u5df2\u88ab\u8ba4\u4e3a\u662f\u80fd\u6e90\u548c\u73af\u5883\u53ef\u6301\u7eed\u53d1\u5c55\u7684\u6700\u6709\u524d\u666f\u7684\u6218\u7565\u4e4b\u4e00\u3002\u5317\u4eac\u6797\u4e1a\u5927\u5b66Qiang Wang\u6559\u6388\u7b49\u4eba\u7814\u7a76\u4e86\u94dc\u57fa\u5c42\u72b6\u53cc\u6c22\u6c27\u5316\u7269(LDH)\u7684\u7535\u884d\u751f\u590d\u5408\u6750\u6599\u5bf9CO2<\/sub>\u7535\u5316\u5b66\u8fd8\u539f\u7684\u4f5c\u7528\u3002\u57fa\u4e8eCu-Cu2<\/sub>O\u7684\u7eb3\u7c73\u590d\u5408\u6750\u6599(HPR-LDH)\u662f\u901a\u8fc7\u7535\u5b50\u7b56\u7565\u5f97\u5230\u7684\uff0cLDH\u7684\u7a33\u5b9a\u6027\u53ef\u8fbe20\u5c0f\u65f6\uff0c\u5bf9C2<\/sub>H4<\/sub>\u6709\u9009\u62e9\u6027\uff0c\u6cd5\u62c9\u7b2c\u6548\u7387\u9ad8\u8fbe36%\uff0c\u663e\u8457\u6291\u5236CH4<\/sub>\u548cH2<\/sub>\u3002\u9ad8\u8d1f\u8fd8\u539f\u7535\u4f4d\u884d\u751f\u50ac\u5316\u5242(HPR-LDH)\u5728\u7532\u70f7\u9009\u62e9\u6027\u751f\u4ea7\u4e59\u70ef\u65b9\u9762\u4fdd\u6301\u957f\u671f\u7a33\u5b9a\uff0c\u6b64\u5916\uff0c\u8fd9\u79cd\u7531LDH\u5236\u5907\u7684\u7535\u5b50\u884d\u751f\u590d\u5408\u6750\u6599\u7684\u72ec\u7279\u7b56\u7565\u5c06\u4e3a\u901a\u8fc7\u6291\u5236HER\u6765\u63d0\u9ad8\u7535\u5316\u5b66CO2<\/sub>\u8f6c\u5316\u8fc7\u7a0b\u4e2dC-C\u5076\u8054\u4ea7\u7269\u7684O-Cu\u7ec4\u5408\u50ac\u5316\u5242\u7684\u8010\u4e45\u6027\u63d0\u4f9b\u65b0\u7684\u601d\u8def\u3002XRD\u3001SEM\u3001ESR\u548cXPS\u5206\u6790\u8bc1\u5b9e\u4e86HPR-LDH\u5bf9\u4e59\u70ef\u7684\u957f\u671f\u9009\u62e9\u6027\u662f\u7531\u4e8e\u4e9a\u8868\u9762\u6c27\u7684\u5b58\u5728\u3002\u6240\u8bbe\u8ba1\u7684\u590d\u5408\u50ac\u5316\u5242\u5927\u5927\u63d0\u9ad8\u4e86\u7a33\u5b9a\u6027\u548c\u9009\u62e9\u6027\uff0c\u540c\u65f6\u4e5f\u964d\u4f4e\u4e86CO2<\/sub>\u7535\u8fd8\u539f\u7684\u8fc7\u7535\u4f4d\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cElectro-derived Cu-Cu2<\/sub>O nanocluster from LDH for stable and selective C2<\/sub>\u00a0hydrocarbons production from CO2 <\/sub>electrochemical reduction\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728JEC\u4e0a\u3002<\/p>\n

DOI: 10.1016\/j.jechem.2019.12.013<\/p>\n

\u56fe4\u00a0\u4e0d\u540c\u7535\u52bf\u4e0b\u6c14\u4f53\u4ea7\u7269\u7684\u6cd5\u62c9\u7b2c\u6548\u7387<\/p>\n

\"\"<\/p>\n

iS<\/b><\/strong>cienc<\/b><\/strong>e<\/b><\/strong>\uff1a<\/b><\/strong>ATP<\/b><\/strong>\u7535\u8377\u7684\u7eb3\u7c73\u56e2\u7c07\u7528\u4e8e<\/b><\/strong>\u86cb\u767d\u8d28\u7684\u9012\u9001\u548c\u6d3b\u6027\u8c03\u8282<\/b><\/strong><\/p>\n

\u86cb\u767d\u8d28\u7c7b\u836f\u7269\u5728\u5e02\u573a\u4e0a\u5360\u6709\u5f88\u5927\u7684\u4efd\u989d\uff0c\u5728\u8bb8\u591a\u75be\u75c5\u7684\u6cbb\u7597\u4e2d\u6709\u7740\u5e7f\u9614\u7684\u524d\u666f\u3002\u7136\u800c\uff0c\u7531\u4e8e\u9488\u5bf9\u7ec6\u80de\u5185\u73af\u5883\u7684\u86cb\u767d\u8f6c\u5bfc\u548c\u6d3b\u6027\u8c03\u8282\u6548\u7387\u4f4e\u4e0b\uff0c\u73b0\u6709\u7684\u86cb\u767d\u836f\u7269\u5c40\u9650\u4e8e\u7ec6\u80de\u5916\u9776\u70b9\u3002\u5728\u672c\u7814\u7a76\u4e2d\uff0c\u4e2d\u56fd\u533b\u836f\u5927\u5b66Minjie Sun\u6559\u6388\u7b49\u4eba\u6784\u5efa\u4e86ATP\u5145\u7535\u5e73\u53f0\u6765\u514b\u670d\u4e0a\u8ff0\u764c\u75c7\u836f\u7269\u7684\u969c\u788d\u3002\u5408\u6210\u4e86\u82ef\u57fa\u787c\u9178\u4fee\u9970\u805a\u4e59\u4e8c\u9187(PCD)\uff0c\u5e76\u4e0e\u9176\u7ed3\u5408\uff0c\u4fdd\u62a4\u5176\u5728\u8840\u6db2\u5faa\u73af\u4e2d\u7684\u6d3b\u6027\u3002\u5f53PCD\u7eb3\u7c73\u56e2\u7c07\u5230\u8fbe\u80bf\u7624\u90e8\u4f4d\u65f6\uff0c\u5b83\u4eec\u6709\u6548\u5730\u5c06\u9176\u8fd0\u8f93\u5230\u7ec6\u80de\u4e2d\uff0c\u7136\u540e\u5728ATP\u5145\u7535\u540e\u6062\u590d\u5176\u50ac\u5316\u6d3b\u6027\u3002\u91cd\u8981\u7684\u662f\uff0c\u7ea7\u8054\u9176\u7cfb\u7edf(GOx&HRPA)\u9009\u62e9\u6027\u5730\u8bf1\u5bfc\u9965\u997f\u6cbb\u7597\u4ee5\u53ca\u80bf\u7624\u7684\u5149\u58f0\u6210\u50cf\u3002\u7ed3\u679c\u8868\u660e\uff0c\u8be5\u667a\u80fd\u7eb3\u7c73\u56e2\u7c07\u53ef\u5e7f\u6cdb\u5e94\u7528\u4e8e\u86cb\u767d\u8f6c\u5bfc\u548c\u9176\u6d3b\u6027\u8c03\u8282\uff0c\u53ef\u52a0\u5feb\u86cb\u767d\u836f\u7269\u5411\u7ec6\u80de\u5185\u9776\u70b9\u7684\u4e34\u5e8a\u8f6c\u5316\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cATP-Charged Nanoclusters Enable Intracellular Protein Delivery and Activity Modulation for Cancer Theranostics\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728iScience\u4e0a\u3002<\/p>\n

DOI: 10.1016\/j.isci.2020.100872<\/p>\n

\u56fe5\u00a0\u5e26ATP\u7535\u8377\u7684\u7eb3\u7c73\u56e2\u7c07\u4e0e\u7ea7\u8054\u50ac\u5316\u653e\u5927PA\u6210\u50cf\u5f15\u5bfc\u7684\u764c\u75c7\u6cbb\u7597\u7684\u793a\u610f\u56fe<\/p>\n

\"\"<\/p>\n

Acta Phys.-Chim. Sin. <\/b><\/strong>\uff1a\u201c\u975e\u4fdd\u62a4\u578b\u201d\u91d1\u5c5e\u80f6\u4f53\u7eb3\u7c73\u7c07\u5f62\u6210\u673a\u7406\u7814\u7a76<\/b><\/strong><\/p>\n

\u5317\u4eac\u5927\u5b66\u738b\u8fdc\u6559\u6388\u8054\u5408\u5948\u826f\u5973\u5b50\u5927\u5b66Masafumi Harada\u6559\u6388\u7b49\u4eba\u91c7\u7528\u539f\u4f4d\u5feb\u901f\u626b\u63cfX\u5c04\u7ebf\u5438\u6536\u7cbe\u7ec6\u7ed3\u6784\u8c31(QXAFS)\u3001\u539f\u4f4d\u7d2b\u5916-\u53ef\u89c1(UV-Vis)\u5438\u6536\u5149\u8c31\u3001\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\u548c\u52a8\u6001\u5149\u6563\u5c04\u6280\u672f\u7814\u7a76\u4e86\u78b1-\u4e59\u4e8c\u9187\u6cd5\u5408\u6210\u4e2d\u975e\u4fdd\u62a4\u578b\u91d1\u5c5e\u80f6\u4f53\u7eb3\u7c73\u7c07\u7684\u5f62\u6210\u8fc7\u7a0b\u4e0e\u673a\u7406\u3002\u7ed3\u679c\u8868\u660e\uff0c\u5728\u78b1-\u4e59\u4e8c\u9187\u6cd5\u5408\u6210\u975e\u4fdd\u62a4\u578bPt\u91d1\u5c5e\u7eb3\u7c73\u7c07\u7684\u8fc7\u7a0b\u4e2d\uff0c\u5ba4\u6e29\u4e0b\u5373\u6709\u90e8\u5206Pt(IV)\u88ab\u8fd8\u539f\u81f3Pt(II)\u3002\u968f\u7740\u53cd\u5e94\u6e29\u5ea6\u7684\u5347\u9ad8\uff0cOH\u2212<\/sup>\u9010\u6e10\u53d6\u4ee3\u4e0ePt\u79bb\u5b50\u914d\u4f4d\u7684Cl\u2212<\/sup>\uff0c\u5728Pt-Pt\u952e\u5f62\u6210\u4e4b\u524d\uff0c\u53cd\u5e94\u4f53\u7cfb\u7684UV-Vis\u5438\u6536\u5149\u8c31\u4e2d\u53ef\u89c2\u5bdf\u5230\u660e\u663e\u7684\u7eb3\u7c73\u7c92\u5b50\u7684\u6563\u5c04\u4fe1\u53f7\uff0c\u539f\u4f4dQXAFS\u5206\u6790\u8868\u660ePt\u7eb3\u7c73\u7c07\u662f\u7531Pt\u6c27\u5316\u7269\u7eb3\u7c73\u7c92\u5b50\u8fd8\u539f\u6240\u5f62\u6210\u7684\uff1b\u5728Ru\u91d1\u5c5e\u7eb3\u7c73\u7c07\u7684\u5f62\u6210\u8fc7\u7a0b\u4e2d\uff0cOH\u2212<\/sup>\u9996\u5148\u53d6\u4ee3\u4e86RuCl3<\/sub>\u4e2d\u7684Cl\u2212<\/sup>\uff0c\u5f62\u6210\u7f9f\u57fa\u914d\u5408\u7269Ru(OH)6<\/sub>3\u2212<\/sup>\uff0c\u540e\u8005\u8fdb\u4e00\u6b65\u7f29\u5408\u5f62\u6210\u6c27\u5316\u948c\u7eb3\u7c73\u7c92\u5b50\uff0c\u6700\u7ec8Ru\u91d1\u5c5e\u7eb3\u7c73\u7c07\u7531\u4e59\u4e8c\u9187\u8fd8\u539f\u6c27\u5316\u948c\u7eb3\u7c73\u7c92\u5b50\u5f62\u6210\u3002\u7531\u4e8e\u5148\u5f62\u6210\u4e86\u6c27\u5316\u7269\u7eb3\u7c73\u7c92\u5b50\uff0c\u540e\u7eed\u7684\u8fd8\u539f\u53cd\u5e94\u88ab\u9650\u5236\u5728\u6c27\u5316\u7269\u7eb3\u7c73\u7c92\u5b50\u5185\uff0c\u4f7f\u6700\u7ec8\u5f97\u5230\u7684\u975e\u4fdd\u62a4\u578b\u91d1\u5c5e\u7eb3\u7c73\u7c07\u5177\u6709\u5c3a\u5bf8\u5c0f\u3001\u5206\u5e03\u7a84\u7684\u7279\u70b9\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cInsight into the Formation Mechanism of \u201cUnprotected\u201d Metal Nanoclusters\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Acta Phys.-Chim. Sin.\u4e0a\u3002<\/p>\n

DOI: 10.3866\/PKU.WHXB201907008<\/p>\n

\u56fe6\u00a0UV-Vis \u5438\u6536\u5149\u8c31\u6d4b\u8bd5\u7ed3\u679c<\/p>\n

\"\"<\/p>\n

Chinese J. Struct. Chem.<\/b><\/strong>\uff1a\u7b3c\u578b\u56e2\u7c07\u4ece\u7ed3\u6784\u9884\u6d4b\u5230\u529f\u80fd\u7eb3\u7c73\u6750\u6599\u4e00\u4f53\u5316\u7684\u7cbe\u51c6\u8bbe\u8ba1<\/b><\/strong><\/p>\n

\u4e9a\u7eb3\u7c73\u5c3a\u5bf8\u7684\u539f\u5b50\u56e2\u7c07\u56e0\u5176\u591a\u53d8\u7684\u5316\u5b66\u7ec4\u5206\u548c\u539f\u5b50\u7ed3\u6784\u4e3a\u65b0\u578b\u529f\u80fd\u6750\u6599\u7684\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u91cd\u8981\u7ec4\u6210\u5355\u5143\u3002\u5176\u4e2d\uff0c\u63ba\u6742\u7b3c\u578b\u56e2\u7c07\u5177\u6709\u8f83\u9ad8\u7684\u7a33\u5b9a\u6027\u548c\u9ad8\u5ea6\u53ef\u8c03\u63a7\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\uff0c\u56e0\u800c\u5907\u53d7\u5173\u6ce8\u3002\u5927\u8fde\u7406\u5de5\u5927\u5b66\u8d75\u7eaa\u519b\u6559\u6388\u7b49\u4eba\u9996\u5148\u7b80\u8981\u4ecb\u7ecd\u4e86\u63ba\u6742\u7b3c\u578b\u56e2\u7c07\u7684\u7814\u7a76\u5386\u53f2\u4ee5\u53ca\u672c\u8bfe\u9898\u7ec4\u53d1\u5c55\u7684\u7528\u4e8e\u56e2\u7c07\u7ed3\u6784\u9884\u6d4b\u7684\u9057\u4f20\u7b97\u6cd5\u7a0b\u5e8fCGA\u3002\u63a5\u7740\uff0c\u4ee5\u4e09\u7c7b\u63ba\u6742\u7b3c\u578b\u56e2\u7c07\u4e3a\u4f8b\u8ba8\u8bba\u4e86\u5176\u57fa\u6001\u7ed3\u6784\u3001\u78c1\u6027\u548c\u50ac\u5316\u7279\u6027\u3002\u6700\u540e\uff0c\u5bf9\u56e2\u7c07\u7ed3\u6784\u9884\u6d4b\u4e0e\u7b3c\u5f62\u56e2\u7c07\u7814\u7a76\u7684\u672a\u6765\u53d1\u5c55\u65b9\u5411\u8fdb\u884c\u4e86\u5c55\u671b\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cCage Clusters: from Structure Prediction to Rational Design of Functional Nanomaterials\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Chinese J. Struct. Chem.\u4e0a\u3002<\/p>\n

DOI: 10.14102\/j.cnki.0254\u20135861.2011\u20132922<\/p>\n

\u56fe7\u00a0\u56e2\u7c07\u7ed3\u6784\u9884\u6d4b\u5230\u529f\u80fd\u8bbe\u8ba1\u793a\u610f\u56fe<\/p>\n

\"\"<\/p>\n

Chinese J. Struct. Chem.<\/b><\/strong>\uff1a\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07\u4e2d\u7684\u914d\u4f53\u5de5\u7a0b\uff1a\u4ece\u7ed3\u6784\u63a7\u5236\u5230\u529f\u80fd\u8c03\u8282<\/b><\/strong><\/p>\n

\u914d\u4f53\u4fdd\u62a4\u7684\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07\u56e0\u5176\u72ec\u7279\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\u548c\u5b9e\u9645\u5e94\u7528\u800c\u53d7\u5230\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\u3002\u4eba\u4eec\u81f4\u529b\u4e8e\u5b9e\u73b0\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07\u7684\u5408\u7406\u5408\u6210\u548c\u7ed3\u6784\u6027\u8d28\u5173\u7cfb\u7684\u5efa\u7acb\u3002\u914d\u4f53\u4f5c\u4e3a\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07\u4e2d\u4e0d\u53ef\u6216\u7f3a\u7684\u4e00\u90e8\u5206\uff0c\u5728\u56e2\u7c07\u7ed3\u6784\u548c\u6027\u8d28\u7684\u63a7\u5236\u4e0a\u626e\u6f14\u7740\u591a\u79cd\u89d2\u8272\u3002\u5728\u672c\u7efc\u8ff0\u4e2d\uff0c\u6e05\u534e\u5927\u5b66\u738b\u6cc9\u660e\u6559\u6388\u9610\u8ff0\u4e86\u914d\u4f53\u5de5\u7a0b\u5728\u63a7\u5236\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07\u7684\u51e0\u4f55\u7ed3\u6784\u3001\u5149\u5b66\u548c\u50ac\u5316\u6027\u80fd\u65b9\u9762\u53d1\u6325\u7684\u91cd\u8981\u4f5c\u7528\uff0c\u5c55\u793a\u4e86\u914d\u4f53\u5de5\u7a0b\u5728\u56e2\u7c07\u8868\u9762\u91d1\u5c5e\u4f4d\u70b9\u8bbe\u8ba1\u548c\u6784\u5efa\u65b9\u9762\u5177\u6709\u5e7f\u9614\u7684\u5e94\u7528\u524d\u666f\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cLigand Engineering in Metal Nanoclusters: from Structural Control to Functional Modulation\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Chinese J. Struct. Chem.\u4e0a\u3002<\/p>\n

DOI: 10.14102\/j.cnki.0254\u20135861.2011-2928<\/p>\n

\u56fe8\u00a0\u786b\u9187\u914d\u4f53\u4fdd\u62a4\u7684Au25\u548c\u7094\u914d\u4f53\u4fdd\u62a4\u7684Au25\u7684\u7ed3\u6784<\/p>\n

\"\"<\/p>\n

\u6587\u4e2d\u5982\u6709\u4e0d\u59a5\u4e4b\u5904\uff0c\u6b22\u8fce\u8bc4\u8bba\u533a\u7559\u8a00~<\/p>\n

\u672c\u6587\u7531Junas\u4f9b\u7a3f\u3002<\/p>\n

\u672c\u5185\u5bb9\u4e3a\u4f5c\u8005\u72ec\u7acb\u89c2\u70b9\uff0c\u4e0d\u4ee3\u8868\u6750\u6599\u4eba\u7f51\u7acb\u573a\u3002<\/p>\n

\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

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