{"id":210997,"date":"2020-10-13T12:00:36","date_gmt":"2020-10-13T04:00:36","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=210997"},"modified":"2020-10-13T10:47:54","modified_gmt":"2020-10-13T02:47:54","slug":"%e3%80%90%e5%ae%a1%e7%a8%bf%e5%b7%b2%e5%9b%9e%e5%a4%8d%e3%80%91%e5%93%88%e5%b0%94%e6%bb%a8%e5%b7%a5%e4%b8%9a%e5%a4%a7%e5%ad%a6%ef%bc%88%e6%b7%b1%e5%9c%b3%ef%bc%89%e9%bb%84%e7%87%95%e6%95%99%e6%8e%88","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=210997","title":{"rendered":"\u54c8\u5c14\u6ee8\u5de5\u4e1a\u5927\u5b66\uff08\u6df1\u5733\uff09\u9ec4\u71d5\u6559\u6388\u8bfe\u9898\u7ec4Adv. Funct. Mater.:\u6c34\u6027\u91d1\u5c5e\u79bb\u5b50\u548c\u91d1\u5c5e\u7a7a\u6c14\u7535\u6c60\u7535\u6781\u6750\u6599\u7684\u672c\u5f81\u7ed3\u6784\u4fee\u9970"},"content":{"rendered":"

\u3010\u5f15\u8a00<\/b><\/strong>\u3011<\/p>\n

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\u3010\u6210\u679c\u7b80\u4ecb<\/b><\/strong>\u3011<\/p>\n

\u8fd1\u65e5\uff0c\u54c8\u5c14\u6ee8\u5de5\u4e1a\u5927\u5b66\uff08\u6df1\u5733\uff09\u9ec4\u71d5\u6559\u6388\u7b49\u4eba<\/b><\/strong>\u6982\u62ec\u4e86\u6709\u5173\u6c34\u6027\u91d1\u5c5e\u79bb\u5b50\u548c\u91d1\u5c5e\u7a7a\u6c14\u7535\u6c60\u4e2d\u7535\u6781\u6750\u6599\u7684\u672c\u5f81\u7ed3\u6784\u6539\u6027\u7684\u6700\u65b0\u62a5\u9053\uff0c\u91cd\u70b9\u4ecb\u7ecd\u5404\u79cd\u8c03\u63a7\u7b56\u7565\uff0c\u6d89\u53ca\u7a7a\u4f4d\u8bbe\u8ba1\uff0c\u5c42\u95f4\u9884\u5d4c\u5165\uff0c\u5143\u7d20\u63ba\u6742\uff0c\u4ee5\u53ca\u4e0d\u540c\u7b56\u7565\u5bf9\u7535\u6781\u6750\u6599\u7684\u7535\u5b50\u548c\u7269\u76f8\u7ed3\u6784\u7684\u4f5c\u7528\u673a\u5236\u8fdb\u884c\u6df1\u5165\u5206\u6790\u3002 \u6700\u540e\uff0c\u4f5c\u8005\u603b\u7ed3\u4e86\u7efc\u8ff0\u7684\u7b80\u8981\u7ed3\u8bba\uff0c\u5e76\u5bf9\u6c34\u7cfb\u7535\u6c60\u7684\u53d1\u5c55\u4e2d\u6240\u9762\u4e34\u7684\u6311\u6218\u800c\u63d0\u51fa\u4e00\u4e9b\u5efa\u8bbe\u6027\u7684\u89c2\u70b9\uff0c\u4ee5\u6fc0\u53d1\u5bf9\u7528\u4e8e\u6c34\u7cfb\u7535\u6c60\u4e2d\u50a8\u80fd\u7684\u590d\u6742\u800c\u5408\u7406\u7ed3\u6784\u7684\u7535\u6781\u6750\u6599\u8bbe\u8ba1\u548c\u5236\u9020\u8fdb\u884c\u66f4\u591a\u7684\u521b\u65b0\u7814\u7a76\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a\u201c<\/b><\/strong>Intrinsic Structure Modification of Electrode Materials \u00a0for Aqueous Metal-Ion and Metal-Air Batteries<\/b><\/strong>\u201d<\/b><\/strong>\u53d1\u8868\u5728Adv. Funct. Mater.<\/b><\/strong>\u4e0a<\/b><\/strong>\u3002\u54c8\u5c14\u6ee8\u5de5\u4e1a\u5927\u5b66\uff08\u6df1\u5733\uff09\u535a\u58eb\u7814\u7a76\u751f\u51cc\u82c7\u662f\u672c\u6587\u7b2c\u4e00\u4f5c\u8005\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

\u56fe1<\/b><\/strong>.\u6c34\u6027\u91d1\u5c5e\u79bb\u5b50\u7535\u6c60\u548c\u91d1\u5c5e\u7a7a\u6c14\u7535\u6c60\u4e2d\u672c\u5f81\u7ed3\u6784\u4fee\u9970\u7684\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe2.<\/b><\/strong>\u6c34\u7cfb\u91d1\u5c5e\u79bb\u5b50\u7535\u6c60\u7684\u9633\u79bb\u5b50\u7a7a\u4f4d\u8bbe\u8ba1<\/b><\/strong><\/p>\n

\"\"<\/p>\n

a\uff09Co-Mn-O\u6750\u6599\u7684\u4e2d\u5b50\u5168\u6563\u5c04\u548c\u5bf9\u5206\u5e03\u529f\u80fd\uff08PDF\uff09\u5206\u6790<\/p>\n

b\uff09\u7531\u56db\u65b9\u5c16\u6676\u77f3Co1.21<\/sub>Mn1.75<\/sub>O3.72<\/sub>\u548c\u5c42\u72b6\u6c34\u94a0\u9530\u77ffK0.05<\/sub>MnO2<\/sub>\u00b7H2<\/sub>O\u7ec4\u6210\u7684\u53cc\u76f8Co-Mn-O\u7684\u6676\u683c\u7ed3\u6784<\/p>\n

c\uff09\u901a\u8fc7CV\u626b\u63cf\u83b7\u5f97\u7684Co-Mn-O\u6750\u6599\u7684\u539f\u4f4dXRD\u56fe\u8c31<\/p>\n

d\uff09\u57281 m Na2<\/sub>SO4<\/sub>\u7535\u89e3\u8d28\u4e2d\u4ee51mV\/s\u7684\u626b\u63cf\u901f\u7387\uff0c\u5c06\u53cc\u76f8Co-Mn-O\u6750\u6599\u7684CV\u626b\u63cf\u4ece-0.5\u52301.1V\u8fdb\u884c\u4e24\u4e2a\u5faa\u73af<\/p>\n

e\uff09\u57282\u81f320 A\/g\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7535\u6781\u5bb9\u91cf\u4e0e\u5faa\u73af\u6b21\u6570\u7684\u5173\u7cfb<\/p>\n

f\uff09\u5df2\u5f00\u53d1\u76843D ZMO\u5c16\u6676\u77f3\u9aa8\u67b6\u4e2dZn2+<\/sup>\u63d2\u5165\/\u63d0\u53d6\u7684\u793a\u610f\u56fe<\/p>\n

g\uff09\u5728\u6ca1\u6709\u548c\u6709\u9530\u7a7a\u4f4d\u7684ZMO\u5c16\u6676\u77f3\u4e2d\u4ee3\u8868\u7684Zn2+<\/sup>\u6269\u6563\u901a\u9053<\/p>\n

h\uff09GITT\u66f2\u7ebf\u548cZMO\/C\u548cZMO+C\u7535\u6781\u7684Zn2+<\/sup>\u6269\u6563\u7cfb\u6570<\/p>\n

\u56fe<\/b><\/strong>3.<\/b><\/strong>\u00a0\u6c34\u7cfb\u91d1\u5c5e\u7a7a\u6c14\u7535\u6c60\u7684\u9633\u79bb\u5b50\u7a7a\u4f4d\u8bbe\u8ba1<\/b><\/strong><\/p>\n

\"\"<\/p>\n

a\uff09\u5f62\u6001\u548c\u7ed3\u6784\u6f14\u53d8\u8fc7\u7a0b\u7684\u793a\u610f\u56fe<\/p>\n

b-c\uff09Li(Ni0.2<\/sub>Co0.6<\/sub>Mn0.2<\/sub>)O2<\/sub>\u548cDe-Li(Ni0.2<\/sub>Co0.6<\/sub>Mn0.2<\/sub>)O2<\/sub>\u7684HAADF-STEM\u56fe\u50cf\uff0c\u5e76\u4e14\u6676\u4f53\u4e2d\u7684Li\u7a7a\u4f4d\u6807\u8bb0\u4e3a\u9ec4\u8272\u5706\u5708<\/p>\n

d-e\uff09\u539f\u59cbLi(Ni0.2<\/sub>Co0.6<\/sub>Mn0.2<\/sub>)O2<\/sub>\u548cDe-Li(Ni0.2<\/sub>Co0.6<\/sub>Mn0.2<\/sub>)O2<\/sub>\u7684OER\u548cORR\u81ea\u7531\u80fd\u56fe<\/p>\n

f\uff09\u8131\u9502\u524d\u540eLi(Ni0.2<\/sub>Co0.6<\/sub>Mn0.2<\/sub>)O2<\/sub>\u548c De-Li(Ni0.2<\/sub>Co0.6<\/sub>Mn0.2<\/sub>)O2<\/sub>\u7684\u957f\u671f\u6027\u80fd\u6bd4\u8f83<\/p>\n

g\uff09\u4f5c\u4e3a\u7a7a\u6c14\u9634\u6781\u7684\u53cc\u529f\u80fdDe-Li(Ni0.2<\/sub>Co0.6<\/sub>Mn0.2<\/sub>)O2<\/sub>\u50ac\u5316\u5242\u57285 mA\/cm2<\/sup>\u4e0b\u7684\u5145\u653e\u7535\u5faa\u73af\u6027\u80fd<\/p>\n

h\uff09\u53cc\u529f\u80fdDe-Li(Ni0.2<\/sub>Co0.6<\/sub>Mn0.2<\/sub>)O2<\/sub>\u50ac\u5316\u5242\u5728200 mA\/cm2<\/sup>\u4e0b\u4e0eIrO2<\/sub>\/C\u548cPt\/C\u76f8\u6bd4\u7684\u5145\u653e\u7535\u6781\u5316\u66f2\u7ebf<\/p>\n

\u56fe<\/b><\/strong>4.\u6c34\u7cfb\u91d1\u5c5e\u79bb\u5b50\u7535\u6c60\u7684\u9633\u79bb\u5b50\u7a7a\u4f4d\u8bbe\u8ba1<\/b><\/strong><\/p>\n

\"\"<\/p>\n

a-d\uff09p-VO\u7684\u7535\u8377\u5206\u5e03\u548c\u7ed3\u6784\u56fe\uff0cOd-VO\u7684\u7535\u8377\u5206\u5e03\u548c\u7ed3\u6784\u56fe<\/p>\n

e-f\uff09GITT\u66f2\u7ebf\u548cp-VO\u548cOd-VO\u7535\u6781\u7684Zn2+<\/sup>\u6269\u6563\u7cfb\u6570\u6bd4\u8f83<\/p>\n

g\uff09\u5145\u653e\u7535\u5faa\u73af\u540e\uff0cOd-VO\u548cp-VO\u7535\u6781\u5728\u626b\u63cf\u901f\u5ea6\u4e3a0.2mV\/s\u65f6\u7684CV\u66f2\u7ebf<\/p>\n

h\uff09Od-VO\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a0.2\u81f35 A\/g\u65f6\u7684\u5145\u7535\/\u653e\u7535\u66f2\u7ebf<\/p>\n

i\uff09\u5728\u5404\u79cd\u7535\u6d41\u5bc6\u5ea6\u4e0bOd-VO\u548cp-VO\u7684\u901f\u7387\u80fd\u529b\u548c\u76f8\u5e94\u7684\u5e93\u4ed1\u6548\u7387\uff08CE\uff09<\/p>\n

j\uff09Od-VO\u548cp-VO\u5728200mA\/g\u548c\u76f8\u5e94\u7684CE\u4e0b\u53ef\u5faa\u73af200\u6b21<\/p>\n

\u56fe<\/b><\/strong>5<\/b><\/strong>.<\/b><\/strong>\u00a0\u6c34\u7cfb\u91d1\u5c5e\u7a7a\u6c14\u7535\u6c60\u7684\u6c27\u7a7a\u4f4d\u8bbe\u8ba1<\/b><\/strong><\/p>\n

\"\"<\/p>\n

a-b\uff09O2<\/sub>\u548cHO2<\/sub>\u5728\u4e0d\u540c\u8868\u9762\u4e0a\u7684\u5438\u9644\u6784\u578b<\/p>\n

c\uff09\u94dd\u7a7a\u6c14\u7535\u6c60\u7684\u793a\u610f\u6027\u914d\u7f6e<\/p>\n

d\uff09\u539f\u59cbMnO2<\/sub>\u548cA-MnO2<\/sub>\u7684\u5f00\u8def\u7535\u538b\u66f2\u7ebf\u6bd4\u8f83<\/p>\n

e\uff09\u653e\u7535\u6781\u5316\u66f2\u7ebf\u548c\u76f8\u5e94\u7684\u529f\u7387\u5bc6\u5ea6<\/p>\n

f\uff09\u57fa\u4e8e\u539f\u59cbMnO2<\/sub>\u548cA-MnO2<\/sub>\u50ac\u5316\u5242\u7684Al-\u7a7a\u6c14\u7535\u6c60\u5728100mA\/cm2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u957f\u671f\u8010\u7528\u6027<\/p>\n

g\uff09\u7531\u94dd\u5236\u7a7a\u6c14\u7535\u6c60\u4f9b\u7535\u7684\u4e24\u4e2a\u7cfb\u5217\u768465\u4e2a\u201c SJTU\u201d\u5f62\u72b6\u7684LED<\/p>\n

\u56fe<\/b><\/strong>6<\/b><\/strong>.<\/b><\/strong>\u91d1\u5c5e\u79bb\u5b50\u9884\u5d4c\u5165\uff08\u5355\u4ef7\u6c34\u7cfb\u91d1\u5c5e\u79bb\u5b50\u7535\u6c60\uff09<\/b><\/strong><\/p>\n

\"\"<\/p>\n

a\uff09ac-Kx<\/sub>V2<\/sub>O5<\/sub>\u7684\u793a\u610f\u56fe\uff0c\u5728V2<\/sub>O5<\/sub>\u53cc\u5c42\u4e4b\u95f4\u5177\u6709\u8f83\u5927\u7684\u5c42\u95f4\u95f4\u9694\u4ee5K0.25<\/sub>V2<\/sub>O5<\/sub>\u00b7nH2<\/sub>O\u5206\u5b50\u4e3a\u652f\u67f1<\/p>\n

b\uff09\u5c42\u95f4\u95f4\u8ddd\u5c0f\u7684\u6b63\u4ea4V2<\/sub>O5<\/sub><\/p>\n

c\uff09\u5206\u5c42Kx<\/sub>V2<\/sub>O5<\/sub>\u7684XRD\u56fe<\/p>\n

d\uff09\u5177\u6709\u53cc\u76f8\u7eb3\u7c73\u7ed3\u6784\u7684\u5206\u5c42Kx<\/sub>V2<\/sub>O5<\/sub>\uff08x = 0.25\uff09\u7684HRTEM\u56fe\u50cf<\/p>\n

e-f\uff09\u5206\u5c42Kx<\/sub>V2<\/sub>O5<\/sub>\u7684\u7ed3\u6676\u533a\u548c\u975e\u6676\u533a\u7684FFT\u6a21\u5f0f<\/p>\n

g\uff09\u57fa\u4e8e3D\u53cc\u8fde\u7eed\u7eb3\u7c73\u591a\u5b54Au\u7535\u6d41\u96c6\u7535\u6781\u7684\u6c34\u6027K +<\/sup>\u79bb\u5b50\u5fae\u7535\u6c60\u7684\u7ed3\u6784\u56fe<\/p>\n

h-j\uff09V-Mn AR-PIMB\u6c34\u6eb6\u6db2\u548c\u5176\u4ed6\u53ef\u5145\u7535\u78b1\u91d1\u5c5e\u79bb\u5b50\u6c34\u6eb6\u6db2\u7684\u5806\u5bb9\u91cf\uff0c\u81ea\u653e\u7535\u6027\u80fd\u4ee5\u53ca\u5806\u80fd\u91cf\u548c\u529f\u7387\u5bc6\u5ea6\u6bd4\u8f83<\/p>\n

\u56fe<\/b><\/strong>7. \u91d1\u5c5e\u79bb\u5b50\u9884\u5d4c\u5165\uff08\u591a\u4ef7\u6c34\u7cfb\u91d1\u5c5e\u79bb\u5b50\u7535\u6c60\uff09<\/b><\/strong><\/p>\n

\"\"<\/p>\n

a\uff09NVO\u7eb3\u7c73\u7ebf\u7684\u9ad8\u5206\u8fa8\u7387TEM\u56fe\u50cf\u548c\u63d2\u56fe\u4e2d\u7684SAED\u56fe\u6848<\/p>\n

b\uff09\u7531Na\uff0cV\u548cO\u5143\u7d20\u7ec4\u6210\u7684NVO\u7eb3\u7c73\u7ebf\u7684SEM-EDX\u6620\u5c04\u56fe\u50cf<\/p>\n

c\uff09NVO\u7eb3\u7c73\u7ebf\u7684XRD\u56fe\u6848\u548c\u6676\u4f53\u7ed3\u6784<\/p>\n

d-e\uff09\u4e0d\u540c\u5145\u7535\/\u653e\u7535\u72b6\u6001\u4e0bNVO\u7535\u6781\u7684\u5f02\u4f4dXRD\u56fe\u8c31\u4ee5\u53ca\u57280.2 A\/g\u65f6\u7684\u76f8\u5e94\u6052\u7535\u6d41\u5145\u653e\u7535\u66f2\u7ebf<\/p>\n

f\uff09NVO\u57281.0 A\/g\u4e0b\u53ef\u8fdb\u884c1000\u6b21\u5faa\u73af\u7684\u957f\u5faa\u73af\u6027\u80fd<\/p>\n

g\uff09\u6240\u83b7\u5f97\u7684Ni0.25<\/span><\/sub>V2<\/span><\/sub>O5<\/span><\/sub>\u00b7H2<\/span><\/sub>O\u7684HRTEM<\/p>\n

h\uff09\u7531\u901a\u9053I\u548cII\u7ec4\u6210\u7684Ni0.25<\/sub>V2<\/sub>O5<\/sub>\u00b7H2<\/sub>O\u7684B3LYP-D3\u8ba1\u7b97\u7ed3\u6784<\/p>\n

i\uff09Ni0.25<\/sub>V2<\/sub>O5<\/sub>\u00b7H2<\/sub>O\u9634\u6781\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a0.2\u81f35 A\/g\u65f6\u7684\u6052\u7535\u6d41\u5145\u653e\u7535\u66f2\u7ebf<\/p>\n

\u56fe<\/b><\/strong>8\u6c34\u5206\u5b50\u9884\u5d4c\u5165\uff08\u5355\u4ef7\u6c34\u7cfb\u91d1\u5c5e\u79bb\u5b50\u7535\u6c60\uff09<\/b><\/strong><\/p>\n

\"\"<\/p>\n

a\uff09\u5177\u6709\u90e8\u5206\u548c\u5b8c\u5168\u6c34\u5408\u65e0\u5e8f\u6761\u4ef6\u7684KVO\u7684\u4e2d\u5b50PDF<\/p>\n

b\uff09\u901a\u8fc7\u62df\u5408PDF\u5206\u6790\u5bf9\uff08i\uff09\u90e8\u5206\u6c34\u5408KVO\u548c\uff08ii\uff09\u5168\u6c34\u5408KVO\u7684\u7cbe\u5236\u7ed3\u6784<\/p>\n

c\uff09\uff08i\uff09\u65e0\u5e8fKVO\u7eb3\u7c73\u7247\u548c\uff08ii\uff09\u6709\u5e8fKVO\u6750\u6599\u5728\u4e09\u4e2aCV\u5faa\u73af\u4e2d\u4ee51 mV\/s\u7684\u626b\u63cf\u901f\u7387\u7684\u539f\u4f4dXRD\u5149\u8c31\u7b49\u9ad8\u7ebf\u56fe<\/p>\n

d\uff095000\u6b21\u5145\/\u653e\u7535\u5faa\u73af\u7684KVO\u5e93\u4ed1\u6548\u7387<\/p>\n

\u56fe<\/b><\/strong>9<\/b><\/strong>.<\/b><\/strong>\u00a0\u6c34\u5206\u5b50\u9884\u5d4c\u5165\uff08\u591a\u4ef7\u6c34\u7cfb\u91d1\u5c5e\u79bb\u5b50\u7535\u6c60\uff09<\/b><\/strong><\/p>\n

\"\"<\/p>\n

a\uff09\u539f\u59cbVOG\uff0c\u5206\u522b\u5145\u7535\u81f31.3V\u548c\u653e\u7535\u81f30.2V\u540e\u7684VOG\u7684\u6676\u4f53\u7ed3\u6784\u56fe<\/p>\n

b\uff09VOG\uff0cVOG-350\u548cVOG-350\u7a7a\u6c14\u7684\u7c89\u672bXRD\u56fe<\/p>\n

c\uff09\u5236\u5907\u7684VOG\u572860mA\/g\u65f6\u7684\u5145\u653e\u7535\u66f2\u7ebf<\/p>\n

d\uff09VOG\u548cVOG-350\u57280.3\u81f330 A \/ g\u7684\u5404\u79cd\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u901f\u7387\u80fd\u529b<\/p>\n

e\uff09VOG\u548cVOG-350\u57286 A \/ g\u4e0b\u7684\u5faa\u73af\u6027\u80fd<\/p>\n

f\uff09cw-MnO2<\/sub>\u7684XRD\u56fe\u8c31\u548c\uff08\u63d2\u56fe\uff09\u6676\u4f53\u7ed3\u6784<\/p>\n

g-h\uff09\u5404\u79cd\u653e\u7535\u548c\u5145\u7535\u72b6\u6001\u4e0bcw-MnO2<\/sub>\u7684XANES\u5149\u8c31<\/p>\n

\u56fe<\/b><\/strong>10.<\/b><\/strong>\u5177\u6709\u6269\u5c55\u63d2\u5c42\u7ed3\u6784\u7684\u805a\u82ef\u80fa\uff08PANI\uff09\u63d2\u5c42MnO<\/b><\/strong>2<\/b><\/sub><\/strong>\u7eb3\u7c73\u5c42<\/b><\/strong><\/p>\n

\"\"<\/p>\n

a\uff09\u5177\u6709\u6269\u5c55\u63d2\u5c42\u7ed3\u6784\u7684\u805a\u82ef\u80fa\uff08PANI\uff09\u63d2\u5c42MnO2<\/sub>\u7eb3\u7c73\u5c42\u7684\u793a\u610f\u56fe<\/p>\n

b\uff09PANI\u63d2\u5165\u7684MnO2<\/sub>\u7eb3\u7c73\u5c42\u7684\u9ad8\u5206\u8fa8\u7387TEM\u56fe\u50cf<\/p>\n

c-d\uff09PANI\u63d2\u5165\u7684MnO2<\/sub>\u7eb3\u7c73\u5c42\u7684\u5f02\u4f4dX\u5c04\u7ebf\u7c89\u672b\u884d\u5c04\uff08XRD\uff09\u56fe\u548c\u4ecea\u4e2d\u9009\u62e9\u7684\u5f02\u4f4dXRD\u56fe\uff08\u5bf9\u5e94\u4e8e\u5728c\u4e2d\u4ee53\u300110\u300113\u548c19\u8868\u793a\u7684XRD\u56fe\uff09<\/p>\n

e\uff09\u663e\u793aH+<\/sup>\u548cZn2+<\/sup>\u987a\u5e8f\u63d2\u5165\u7684\u793a\u610f\u56fe<\/p>\n

f\uff09\u5728200\u81f33000mA\/g\u7684\u5404\u79cd\u7535\u6d41\u5bc6\u5ea6\u4e0b\u63d2\u5165PANI\u7684MnO2<\/sub>\u7684\u901f\u7387\u6027\u80fd<\/p>\n

g\uff09\u5728200mA\/g\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u63d2\u5165PANI\u7684MnO2<\/sub>\u7684\u5faa\u73af\u6027\u80fd<\/p>\n

\u56fe<\/b><\/strong>11<\/b><\/strong>.<\/b><\/strong>PEDOT\u63d2\u5c42NVO\u5c42\u6750\u6599<\/b><\/strong><\/p>\n

\"\"<\/p>\n

a\uff09PEDOT\u63d2\u5c42NVO\u5c42\u6750\u6599\u7684\u5236\u5907\u8fc7\u7a0b\u793a\u610f\u56fe<\/p>\n

b-c\uff09NVO\u6837\u54c1\u548cPEDOT-NVO\u6837\u54c1\u7684HRTEM\u56fe\u50cf<\/p>\n

d-f\uff09\u5728\u7b2c\u4e8c\u4e2a\u5faa\u73af\u7684\u653e\u7535\u548c\u5145\u7535\u72b6\u6001\u4e0bPEDOT-NVO\u9634\u6781\u7684\u5f02\u4f4dXRD\u56fe\u6848\uff0c\u4ee5\u53ca\u9009\u5b9a\u533a\u57df\u4e2d\u5305\u542b\u7684\u56fe\u6848\u7684\u76f8\u5e94\u653e\u5927<\/p>\n

g\uff09NVO\u548cPEDOT-NVO\u7684\u901f\u7387\u4e3a0.2 A\/g\u65f6\u7684\u5145\u653e\u7535\u66f2\u7ebf<\/p>\n

h\uff09\u57280.05\u81f310 A\/g\u7684\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u76f8\u5e94\u7535\u6781\u7684\u901f\u7387\u80fd\u529b<\/p>\n

i\uff09NVO\u548cPEDOT-NVO\u4ee50.2 A\/g\u7684\u5faa\u73af\u6027\u80fd\u6bd4\u8f83<\/p>\n

j\uff09\u5728\u63d2\u5165Zn2+<\/span><\/sup>\u4e4b\u524d\u548c\u4e4b\u540e\u5f15\u5165PEDOT\u7684NVO\u4f18\u5316\u7ed3\u6784\u56fe<\/p>\n

\u56fe<\/b><\/strong>12<\/b><\/strong>.<\/b><\/strong>\u91d1\u5c5e\u5143\u7d20\u63ba\u6742\uff08\u6c34\u7cfb\u91d1\u5c5e\u79bb\u5b50\u7535\u6c60\uff09<\/b><\/strong><\/p>\n

\"\"<\/p>\n

a\uff09\u7535\u5316\u5b66\u8fc7\u7a0b\u4e2dCoFe(CN)6<\/sub>\u9aa8\u67b6\u4e2d\u53ef\u9006Zn2+<\/sup>\u5d4c\u5165\/\u53bb\u5d4c\u5165\u7684\u793a\u610f\u56fe<\/p>\n

b\uff09CoFe(CN)6<\/sub>\u7684Rietveld\u7cbe\u70bc\u7ed3\u679c<\/p>\n

c-d\uff09\u57280.3\u81f30.6 A\/g\u7684\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u901f\u7387\u6027\u80fd\u548c\u76f8\u5e94\u7684\u6052\u7535\u6d41\u5145\/\u653e\u7535\u66f2\u7ebf<\/p>\n

e\uff09\u6052\u7535\u6d41\u5145\u653e\u7535\u66f2\u7ebf\u4e3a0.3 A\/g<\/p>\n

f\uff09\u6536\u96c6\u4ece\u4e0d\u540c\u989c\u8272\u7403\u4f53\u6307\u793a\u7684\u76f8\u5173\u7535\u4f4d\u7684Ex-XRD\u56fe\u6848\u8fdb\u884c\u7ed3\u6784\u5206\u6790\uff0c\u5e76\u5728\u9009\u5b9a\u7535\u4f4d\u4e0b\u6536\u96c6ex-XRD\u56fe\u6848<\/p>\n

\u56fe<\/b><\/strong>13. \u91d1\u5c5e\u5143\u7d20\u63ba\u6742\uff08\u6c34\u7cfb\u91d1\u5c5e\u7a7a\u6c14\u7535\u6c60\uff09<\/b><\/strong><\/p>\n

\"\"<\/p>\n

a\uff09\u5728OER\u548cORR\u7684\u78b3\u5e03\u4e0a\u751f\u957f\u7684Fe-Co4<\/sub>N@N-C\u7eb3\u7c73\u7247\u7684\u793a\u610f\u56fe<\/p>\n

b-c\uff09\u5305\u542bCo\uff0cC\uff0cFe\u548cN\u5143\u7d20\u7684Fe-Co4<\/sub>N@N-C\u7535\u50ac\u5316\u5242\u7684\u9ad8\u5206\u8fa8\u7387TEM\u56fe\u50cf\u548cTEM-EDS\u6620\u5c04<\/p>\n

d\uff09Fe-Co4<\/sub>N@N-C\u548cPt\/C+RuO2<\/sub>\u57285mA\/cm1<\/sup>\u5904\u7684\u6bd4\u653e\u7535\u5bb9\u91cf\u66f2\u7ebf<\/p>\n

e\uff09Fe-Co4<\/sub>N@N-C\u548cPt\/C+RuO2<\/sub>\u7684\u653e\u7535\u6781\u5316\u66f2\u7ebf\u53ca\u76f8\u5e94\u7684\u529f\u7387\u5bc6\u5ea6<\/p>\n

f\uff09\u7531Fe-Co4<\/sub>N@N-C\u548cPt\/C+RuO2<\/sub>\u7535\u50ac\u5316\u5242\u7ec4\u88c5\u800c\u6210\u7684\u6db2\u6001Zn-\u7a7a\u6c14\u53ef\u5145\u7535\u7535\u6c60\u57285mA\/cm2<\/sup>\u7684\u5145\u653e\u7535\u5faa\u73af\u66f2\u7ebf<\/p>\n

g\uff09\u5728\u4e0d\u540c\u7684\u5f2f\u66f2\u6761\u4ef6\uff080o<\/sup>C\uff0c30o<\/sup>C\u548c60o<\/sup>C\uff09\u4e0b\uff0c\u6320\u6027\u56fa\u6001Zn-\u7a7a\u6c14\u7535\u6c60\u57284 mA\/cm2<\/sup>\u7684\u957f\u5faa\u73af\u66f2\u7ebf<\/p>\n

\u56fe<\/b><\/strong>14<\/b><\/strong>.<\/b><\/strong>\u975e\u91d1\u5c5e\u5143\u7d20\u63ba\u6742\uff08\u6c34\u7cfb\u91d1\u5c5e\u79bb\u5b50\u7535\u6c60\uff09<\/b><\/strong><\/p>\n

\"\"<\/p>\n

a-b\uff09\u539f\u59cb\u6c27\u6c2e\u5316\u9492\u548c\u521d\u59cb\u7535\u8377\u4ea7\u7269\u7684\u9ad8\u89d2\u5ea6\u73af\u5f62\u6697\u573a\uff08HAADF\uff09\u539f\u5b50\u5206\u8fa8\u7387\u56fe\u50cf\uff0c\u8868\u660e\u5f62\u6210\u4e86\u5927\u91cf\u7684\u7a7a\u4f4d\/\u7f3a\u9677<\/p>\n

c\uff09\u5177\u6709\u5927\u91cf\u6c27\u539f\u5b50\u4ee5\u53ca\u6c27\u539f\u5b50\u548c\u6c2e\u5316\u7269\u539f\u5b50\u7684\u968f\u673a\u5206\u6563\u7684\u521d\u59cb\u5145\u7535\u4ea7\u7269\u7684\u539f\u5b50\u5206\u8fa8\u7387\u5143\u7d20\u6620\u5c04\u56fe\u50cf<\/p>\n

d\uff09\u524d\u4e24\u4e2a\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u5ca9\u76d0VNx<\/sub>Oy<\/sub>\u57280.1C\u65f6\u7684\u5145\u653e\u7535\u66f2\u7ebf<\/p>\n

e\uff09\u64cd\u4f5cXRD\u5cf0\u5f3a\u5ea6\u4e0e\u5faa\u73af\u65f6\u95f4\u7684\u4e8c\u7ef4\u8f6e\u5ed3\u56fe<\/p>\n

f\uff09\u4e0d\u540c\u5145\u653e\u7535\u72b6\u6001\u4e0b\u6c27\u6c2e\u5316\u9492\u7684\u7535\u5b50\u987a\u78c1\u5171\u632f\uff08EPR\uff09\u8c31<\/p>\n

g\uff09Zn2+<\/span><\/sup>\u5728\u5316\u5b66\u8ba1\u91cf\u6bd4VN<\/span>0.9<\/span><\/sub>O<\/span>0.15<\/span><\/sub>\u548c\u65e0\u5e8f\u5ca9\u76d0VNx<\/sub>Oy<\/sub>\uff08x\u22480.2\uff0cy\u22482.1\uff09\u4e2d\u7684\u6269\u6563\u7cfb\u6570\u4ee5\u53ca\u653e\u7535\u6df1\u5ea6<\/p>\n

h\uff09\u57281 C\u81f3600 C\u7684\u5404\u79cd\u901f\u7387\u4e0bVNx<\/sub>Oy<\/sub>\u7684\u901f\u7387\u80fd\u529b\uff08x\u22480.2\uff0cy\u22482.1\uff09<\/p>\n

\u56fe<\/b><\/strong>15<\/b><\/strong>.<\/b><\/strong>N<\/b><\/strong>\u56fe<\/b><\/strong>13. \u975e\u91d1\u5c5e\u5143\u7d20\u63ba\u6742\uff08\u6c34\u7cfb\u91d1\u5c5e\u7a7a\u6c14\u7535\u6c60\uff09<\/b><\/strong><\/p>\n

\"\"<\/p>\n

a\uff09\u7531C\uff0cN\u548cO\u5143\u7d20\u7ec4\u6210\u7684NDGs-800\u7684\u5143\u7d20\u6620\u5c04\u56fe<\/p>\n

b\uff09NDGs-800\u7684\u9ad8\u5206\u8fa8\u7387N 1s\u5149\u8c31\u5206\u522b\u4e0e\u5421\u5576-N\uff0c\u5421\u54af-N\uff0c\u77f3\u58a8-N\u548c\u5421\u5576N + -O-\u76f8\u5173<\/p>\n

c\uff09\u6bd4\u8f83NDGs-x<\/sub>\u548cPt\/C\u50ac\u5316\u5242\u7684\u52a8\u7535\u6d41\u5bc6\u5ea6\uff08Jk\uff09\u548cE1\/2<\/p>\n

d\uff09\u57281 m KOH\u7535\u89e3\u8d28\u4e2d\u4ee52 mV\/s\u7684\u626b\u63cf\u901f\u7387\u626b\u63cfOEs\u7684DGs-800\uff0cNDGs-800\uff0cRuO2<\/sub>\/C\u548cPt\/C\u50ac\u5316\u5242\u7684LSV\u66f2\u7ebf<\/p>\n

e\uff09\u7528\u4e8eOER\u50ac\u5316\u7684DGs-800\uff0cNDGs-800\uff0cRuO2<\/sub>\/C\u548cPt\/C\u50ac\u5316\u5242\u7684\u76f8\u5e94Tafel\u56fe<\/p>\n

fg\uff09\u77f3\u58a8\u70ef\u5e95\u7269\u4e2d\u76847\u79cd\u7c7b\u578b\u7684\u5421\u5576-N\u542b\u4f4d\u70b9\uff081N\uff0c2N\uff0c3N-1\u30013N-2\u30014N\uff0c5N\u548c6N\uff09\u4ee5\u53ca\u6cbf\u7740ORR\u548cOER\u9014\u5f84\u7684* OH\u7684\u5bf9\u5e94\u8d85\u7535\u52bf\u4e0e\u5438\u9644\u80fd \u4e0d\u8003\u8651pH\u7684\u5f71\u54cd<\/p>\n

h\uff09\u57284N\uff08\u56db\u4ef7\u5421\u5576N\uff09\u4f4d\u70b9\u7684ORR\u548cOER\u7684\u5409\u5e03\u65af\u81ea\u7531\u80fd\u56fe<\/p>\n

i\uff09\u572810mA\/cm2<\/sup>\u7684\u6052\u5b9a\u5145\u653e\u7535\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u53ef\u5145\u7535Zn-\u7a7a\u6c14\u7535\u6c60\u7684\u5145\u653e\u7535\u5faa\u73af\u6027\u80fd<\/p>\n

\u3010<\/b><\/strong>\u5c0f\u7ed3<\/b><\/strong>\u3011<\/b><\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5<\/b><\/strong>\uff1aIntrinsic Structure Modification of Electrode Materials \u00a0for Aqueous Metal-Ion and Metal-Air Batteries, Adv. Funct. Mater., <\/i><\/em>2020, DOI:10.1002\/adfm.202006855<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u5b66\u672f\u7ec4tt\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002 \u00a0<\/p>\n

\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb<\/b><\/strong><\/p>\n

\"\"<\/p>\n

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