{"id":212259,"date":"2020-11-01T06:22:30","date_gmt":"2020-10-31T22:22:30","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=212259"},"modified":"2020-11-01T09:21:29","modified_gmt":"2020-11-01T01:21:29","slug":"%e5%8c%97%e5%a4%a7%e6%bd%98%e9%94%8b%e5%9b%a2%e9%98%9fangew-chem-%ef%bc%9agrotthuss%e8%b4%a8%e5%ad%90%e4%bc%a0%e8%be%93%e5%8a%a9%e5%8a%9b%e9%ab%98%e8%83%bd%e9%87%8f%e5%af%86%e5%ba%a6%e6%b0%b4","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=212259","title":{"rendered":"\u5317\u5927\u6f58\u950b\u56e2\u961fAngew. Chem.\uff1aGrotthuss\u8d28\u5b50\u4f20\u8f93\u52a9\u529b\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u6c34\u7cfb\u7535\u6c60"},"content":{"rendered":"

\u3010\u524d\u8a00\u3011<\/strong><\/p>\n

\u9502\u79bb\u5b50\u7535\u6c60\u7531\u4e8e\u6709\u673a\u7535\u89e3\u8d28\u6613\u71c3\u3001\u6750\u6599\u4ef7\u683c\u9ad8\u6602\u7b49\u8bf8\u591a\u95ee\u9898\uff0c\u4e0d\u9002\u5408\u5e94\u7528\u4e8e\u5927\u89c4\u6a21\u50a8\u80fd\u9886\u57df\u3002\u6c34\u7cfb\u4e8c\u6b21\u7535\u6c60\u7531\u4e8e\u4f4e\u6613\u71c3\u6027\u3001\u9ad8\u5143\u7d20\u4e30\u5ea6\u3001\u826f\u597d\u73af\u5883\u76f8\u5bb9\u6027\u7b49\u4f18\u52bf\u4f7f\u5176\u5728\u5927\u89c4\u6a21\u50a8\u80fd\u9886\u57df\u8868\u73b0\u51fa\u8f83\u5927\u5d4c\u9502\uff0c\u56e0\u800c\u53d7\u5230\u5b66\u754c\u548c\u4ea7\u4e1a\u754c\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u8fd1\u5e74\u6765\uff0c\u9488\u5bf9\u4e2d\u5fae\u9178\u6027\u6c34\u7cfbZn-MnO2<\/sub>\u7535\u6c60\u7684\u7814\u7a76\u591a\u6709\u53d1\u8868\u3002\u4eba\u4eec\u53d1\u73b0\uff0c\u4ee5\u950c\u76d0\u6c34\u6eb6\u6db2\u4e3a\u7535\u89e3\u6db2\u7684Zn-MnO2<\/sub>\u6c34\u7cfb\u7535\u6c60\u4e2d\uff0c\u4e0d\u8bbaMnO2<\/sub>\u6676\u578b\u5982\u4f55\uff0cH+<\/sup>\/Zn2+<\/sup>\u5171\u5d4c\u5165\u5bf9\u5bb9\u91cf\u7684\u53d1\u6325\u5747\u8d77\u5230\u5360\u4e3b\u5bfc\u5730\u4f4d\u3002\u7279\u522b\u7684\uff0cH+<\/sup>\u7684\u4f20\u8f93\u6269\u6563\u662f\u7535\u6c60\u9ad8\u500d\u7387\u6027\u80fd\u7684\u5173\u952e\u3002\u7136\u800c\uff0c\u5173\u4e8e\u8d28\u5b50\u5728MnO2<\/sub>\u6676\u683c\u7ed3\u6784\u4e2d\u4f20\u8f93\u673a\u7406\u53ca\u4fc3\u8fdb\u673a\u5236\u5f88\u5c11\u6709\u4eba\u63d0\u53ca\u3002<\/p>\n

\u3010\u6587\u7ae0\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u671f\uff0c\u5317\u4eac\u5927\u5b66\u6df1\u5733\u7814\u7a76\u751f\u9662\u6f58\u950b\u6559\u6388\u56e2\u961f\u5728\u56fd\u9645\u8457\u540d\u79d1\u6280\u671f\u520aAngewandte Chemie\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cBoosting the Energy Density of Aqueous Batteries via Facile Grotthuss Proton Transport\u201d\u7684\u6587\u7ae0\u3002\u6587\u7ae0\u9488\u5bf9Zn-MnO2<\/sub>\u6c34\u7cfb\u7535\u6c60\u4f53\u7cfb\u8fdb\u884c\u4e86\u8d28\u5b50\u4f20\u8f93\u673a\u7406\u65b9\u9762\u7684\u7814\u7a76\uff0c\u5177\u4f53\u6765\u8bf4\uff0c\u4f5c\u8005\u5408\u6210\u4e86\u4e00\u79cdNi\u63ba\u6742\u7684\u03b1-MnO2<\/sub>\uff0c\u901a\u8fc7\u5b9e\u9a8c\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u8ba1\u7b97\u53d1\u73b0\u4e86MnO2<\/sub>\u5728\u653e\u7535\u8fc7\u7a0b\u4e2d\u7684\u56db\u65b9\/\u6b63\u4ea4\uff08tetragonal\/orthorhombic, TO\uff09\u7578\u53d8\uff0c\u8fd9\u79cd\u7578\u53d8\u6781\u5927\u4e86\u964d\u4f4e\u03b1-MnO2<\/sub>\u7684[2\u00d72]\u5b54\u9053\u5185\u76f8\u90bbMn-O\u952e\u4e4b\u95f4\u7684\u8ddd\u79bb\uff0c\u4fc3\u8fdb\u4e86H+<\/sup>\u5728\u5b54\u9053\u5185\u7684Grothuss\u4f20\u8f93\u3002\u540c\u65f6\uff0c\u4f5c\u8005\u4e5f\u53d1\u73b0\u4e86Ni\u63ba\u6742\uff08\u66ff\u4ee3\u90e8\u5206Mn\u7684\u4f4d\u7f6e\uff09\u4f1a\u4fc3\u8fdb\u8be5TO\u7578\u53d8\u8fc7\u7a0b\uff0c\u4ece\u800c\u8fdb\u4e00\u6b65\u7684\u4fc3\u8fdb\u4e86Ni-doped \u03b1-MnO2<\/sub>\u6676\u683c\u5185H+<\/sup>\u7684\u6269\u6563\u52a8\u529b\u5b66\u3002\u57fa\u4e8e\u8be5\u7535\u5316\u5b66\u53cd\u5e94\u673a\u5236\uff0cNi-doped \u03b1-MnO2<\/sub>\u53d1\u6325\u51fa\u9ad8\u7684\u5bb9\u91cf\u548c\u80fd\u91cf\u5bc6\u5ea6\/\u529f\u7387\u5bc6\u5ea6\u3002\u672c\u6587\u4e2d\u5bf9\u672a\u6765\u6c34\u7cfb\u7535\u6c60\u9ad8\u6027\u80fd\u6b63\u6781\u6750\u6599\u7684\u8bbe\u8ba1\u8c03\u63a7\u5177\u6709\u7406\u8bba\u6307\u5bfc\u4f5c\u7528\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1 \u03b1-MnO2<\/sub><\/strong>\u7535\u6781\uff08<\/strong>KMO<\/strong>\u7535\u6781\uff09\u548c<\/strong>Ni<\/strong>\u63ba\u6742<\/strong>\u03b1-MnO2<\/sub><\/strong>\u7535\u6781\uff08<\/strong>NKMO<\/strong>\u7535\u6781\uff09\u7684\u7ed3\u6784\u8868\u5f81\u4e0e\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

(A) \u9884\u5d4c\u5165\u4e86K+<\/sup>\u79bb\u5b50\u7684Ni\u63ba\u6742\u03b1-MnO2<\/sub>\uff08NKMO\uff09\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n

(B\u548cC) \u5206\u522b\u662fKMO (C) \u548cNKMO (D) \u7684XRD\u7cbe\u4fee\u3002<\/p>\n

(D) \u4e24\u79cd\u6750\u6599CV\u66f2\u7ebf\uff080.95-1.85V, 0.1 mV s-1<\/sup>\uff09\u3002<\/p>\n

(E) \u4e24\u79cd\u6750\u65990.05C\uff081C = 308 mAh g-1<\/sup>\uff09\u7535\u6d41\u4e0b\u7684\u6052\u7535\u6d41\u5145\u7535\/\u653e\u7535\u66f2\u7ebf\u3002<\/p>\n

(F) \u4e24\u79cd\u6750\u6599\u57280.1C\u81f310C\u7684\u7535\u6d41\u8303\u56f4\u5185\u7684\u901f\u7387\u6027\u80fd\u3002<\/p>\n

(G) KMO\u548cNKMO\u7535\u6781\u7684\u80fd\u91cf\u5bc6\u5ea6\u548c\u529f\u7387\u5bc6\u5ea6\u3002<\/p>\n

(H) \u4e24\u79cd\u6750\u6599\u57284C\u7684\u7535\u6d41\u4e0b\u7684\u957f\u5faa\u73af\u6027\u80fd\u548c\u76f8\u5e94\u7684\u5e93\u4ed1\u6548\u7387\u3002<\/p>\n

\u56fe<\/strong>2 <\/strong>\u5faa\u73af\u4e2d\u7684<\/strong>H+<\/sup>\/Zn2+<\/sup><\/strong>\u5171\u5d4c\u5165\u4e0e\u7ed3\u6784\u6f14\u5316<\/strong><\/p>\n

\"\"<\/p>\n

(A) \u4e24\u79cd\u6750\u6599\u5206\u522b\u4f7f\u7528ZnSO4<\/sub> \/ DMSO\uff08\u53ea\u6709Zn2+<\/sup>\u5d4c\u5165\uff09\uff0cMnSO4<\/sub> \/ H2<\/sub>O\uff08\u53ea\u6709H+<\/sup>\u5d4c\u5165\uff09\u548cZnSO4 + MnSO4<\/sub> \/ H2<\/sub>O\uff08H+<\/sup>\/Zn2+<\/sup>\u5171\u5d4c\u5165\uff09\u4e09\u79cd\u7535\u89e3\u6db2\u7684\u6bd4\u5bb9\u91cf\u3002<\/p>\n

(B\u548cC) \u5206\u522b\u5c55\u793a\u4e86NKMO\u7535\u6781\u5728\u5b8c\u5168\u5145\u7535\u548c\u653e\u7535\u72b6\u6001\u4e0b\uff08B\uff09Mn 3s\u548c\uff08C\uff09O 1s\u5cf0\u7684XPS\u5149\u8c31\u3002<\/p>\n

(D) Zn \/ KMO\u548cZn \/ NKMO\u7535\u6c60\u5728\u4e0d\u540c\u8377\u7535\u72b6\u6001\u4e0b\u7684\u975e\u539f\u4f4dXRD\u56fe\u8c31\u3002<\/p>\n

(E) DFT\u9884\u6d4b\u7684\u6240\u6709H +<\/sup>\u5d4c\u5165\u6784\u578b\uff08\u7a7a\u5fc3\u5706\uff09\u7684\u5f62\u6210\u80fdEf<\/sub>\uff0c\u5305\u62ec\u7684KMO\u51f8\u5305\uff08\u5b9e\u5fc3\u5706\uff09\u4e2d\u7684\u57fa\u6001\uff0c\u4ee5\u53caKMO\u548cNKMO\u7684\u7406\u8bba\u7535\u538b\u66f2\u7ebf\u3002<\/p>\n

(F) x = 1.375\u65f6\u7684Hx<\/sub>Ni1\/16<\/sub>K1\/8<\/sub>Mn15\/16<\/sub>O2<\/sub>\u7684\u4f18\u5316\u7ed3\u6784\uff0c\u5176\u4e2d\u67d0\u4e9bMn\u79bb\u5b50\u4ece\u516b\u9762\u4f53\u4f4d\u7f6e\u88ab\u7f6e\u6362\u3002<\/p>\n

(G) H +\u79bb\u5b50\u63d2\u5165KMO\u548cNKMO\u540e\uff0c\u5176\u57fa\u6001\u6784\u578b\u7684\u6f14\u53d8\u3002<\/p>\n

\u56fe<\/strong>3 Ni<\/strong>\u63ba\u6742\u5bf9\u56db\u65b9\u6b63\u4ea4\uff08<\/strong>TO<\/strong>\uff09\u7578\u53d8\u7684\u5f71\u54cd<\/strong><\/p>\n

\"\"<\/p>\n

(A) \u4e24\u79cd\u6750\u6599\u5206\u522b\u5d4c\u5165\u4e0d\u540c\u91cfH+<\/sup>\u79bb\u5b50\u540e\uff0c\u9884\u6d4b\u7684\uff08200\uff09\u5e73\u9762\u5c42\u95f4\u8dddd\u548c\u89d2\u5171\u4eab[MnO6<\/sub>]\u516b\u9762\u4f53\u4e4b\u95f4\u7684\u8fde\u63a5\u89d2\u03b8\u7684\u53d8\u5316\u3002<\/p>\n

(B) \u03b1-MnO2<\/sub>\u4e2d\u539f\u59cb\u548c\u626d\u66f2\u7684\u6c27\u9aa8\u67b6\u7684\u793a\u610f\u56fe\uff0c\u4ee5\u53caO 2p\u548c\u8fc7\u6e21\u91d1\u5c5e3d\u72b6\u6001\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u3002<\/p>\n

(C\u548cD) KMO (C) \u548c NKMO (D) \u4e2dMn\u548cNi 3d\u8f68\u9053\u7684DOS\uff0c\u4ee5\u53ca\u76f8\u5e94\u7684\u80fd\u5e26\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n

(E\u548cF) NKMO\u7535\u6781\u7684\u5b8c\u5168\u5145\u7535 (E) \u548c\u5b8c\u5168\u653e\u7535 (F) \u72b6\u6001\u7684STEM\u5206\u6790\u548c\u76f8\u5e94\u7684SAED\u6a21\u5f0f\u3002<\/p>\n

\u56fe<\/strong>4 <\/strong>\u7578\u53d8\u7684<\/strong>\u03b1-MnO2<\/sub><\/strong>\u4e2d\u7684\u8d28\u5b50\u52a8\u529b\u5b66<\/strong><\/p>\n

\"\"<\/p>\n

(A) H +<\/sup>\u79bb\u5b50\u5728\u03b1-MnO2<\/sub>\u4e2d\u6cbf\u7740[2\u00d72]\u96a7\u9053\u7684\u76f4\u63a5\u8dc3\u8fc1\u7684\u8fc1\u79fb\u8def\u5f84\u3002<\/p>\n

(B) \u7578\u53d8\u7684\u03b1-MnO2<\/sub>\u4e2d\uff0c\u4e09\u4e2aH +<\/sup>\u79bb\u5b50\u6cbf[2\u00d72]\u96a7\u9053\u7684Grotthuss\u8d28\u5b50\u4f20\u8f93\u3002<\/p>\n

(C) \u4e24\u79cdH +<\/sup>\u8fc1\u79fb\u673a\u5236\u7684\u76f8\u5e94\u80fd\u5792\u3002<\/p>\n

(D) Grotthuss\u673a\u5236\u4e0bH+<\/sup>\u9635\u5217\u534f\u540c\u6269\u6563\u7684\u793a\u610f\u56fe\u3002<\/p>\n

(E) KMO\u548cNKMO\u7535\u6781\u57281.39 V\u7535\u538b\u4e0b\uff08\u76f8\u5bf9\u4e8eZn \/ Zn2 +<\/sup>\uff09\u7684EIS\u3002<\/p>\n

(F) \u53ef\u80fd\u7684TO\u7578\u53d8\u5982\u4f55\u8c03\u8282\u03b1-MnO2<\/sub>\u5bb9\u91cf\u7684\u673a\u5236\u6a21\u578b\u3002<\/p>\n

\u3010\u603b\u7ed3\u4e0e\u5c55\u671b\u3011<\/strong><\/p>\n

\u4e0eH+<\/sup>\u7684\u76f4\u63a5\u8dc3\u8fc1\u76f8\u6bd4\uff0c\u57fa\u4e8eGrotthuss\u673a\u5236\u8fdb\u884c\u6269\u6563\u4f20\u8f93\u4f1a\u6781\u5927\u964d\u4f4eH +<\/sup>\u8fc1\u79fb\u7684\u6269\u6563\u52bf\u5792\uff0c\u56e0\u6b64\u8fd9\u79cd\u6269\u6563\u673a\u5236\u80fd\u663e\u8457\u6539\u5584H+<\/sup>\u7684\u52a8\u529b\u5b66\uff0c\u5e76\u5141\u8bb8H+<\/sup>\u5feb\u901f\u8fdb\u5165\u03b1-MnO2<\/sub>\u6676\u683c\u4e2d\u7684\u6c27\u5316\u8fd8\u539f\u4f4d\u70b9\uff0c\u4fc3\u8fdb\u6d3b\u6027\u6750\u6599\u5bb9\u91cf\u53d1\u6325\u3002\u540c\u65f6\uff0c\u4f5c\u8005\u9996\u6b21\u62a5\u9053\u4e86\u57fa\u4e8eTO\u7578\u53d8\u7684H+<\/sup>\u7684Grothuss\u6269\u6563\u673a\u5236\uff0c\u5e76\u63d0\u51faNi\u63ba\u6742\u4fc3\u8fdb\u4e86\u8be5\u6269\u6563\u673a\u5236\u4e0b\u7684H+<\/sup>\u6269\u6563\u4f20\u8f93\u3002\u7279\u522b\u7684\uff0c\u672c\u6587\u5e76\u6ca1\u6709\u4ee5\u964d\u4f4e\u7535\u538b\u6216\u8005\u964d\u4f4e\u5faa\u73af\u6027\u80fd\u6765\u5b9e\u73b0\u5bb9\u91cf\u7684\u63d0\u9ad8\uff0c\u56e0\u6b64\u8fd9\u786e\u4fdd\u4e86\u7535\u6c60\u957f\u5faa\u73af\u671f\u95f4\u7684\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u3002\u4f5c\u8005\u9884\u8ba1\uff0c\u901a\u8fc7\u7efc\u5408\u7eb3\u7c73\u7ed3\u6784\u7684\u8c03\u6574\u4e0e\u8bbe\u8ba1\uff0c\u53ef\u4ee5\u8fdb\u4e00\u6b65\u63d0\u9ad8\u03b1-MnO2<\/sub>\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u8fd9\u503c\u5f97\u8fdb\u4e00\u6b65\u63a2\u7a76\u3002<\/p>\n

\u3010\u56e2\u961f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u8d75\u5e86\u8d3a\uff08\u535a\u58eb\uff09\u3001\u5b8b\u5965\u91ce\uff08\u7855\u58eb\u751f\uff09\u548c\u8d75\u6587\u5149\uff08\u5de5\u7a0b\u5e08\uff09\u662f\u672c\u6587\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\u3002<\/p>\n

\u674e\u821c\u5b81\u535a\u58eb\uff0c\u5317\u4eac\u5927\u5b66\u65b0\u6750\u6599\u5b66\u9662\u526f\u7814\u7a76\u5458\uff0c\u76ee\u524d\u81f4\u529b\u4e8e\u7535\u5316\u5b66\u8fc7\u7a0b\u7684\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\u6a21\u62df\u7814\u7a76\uff0c\u548c\u7535\u6c60\u6750\u6599\u4e0e\u50ac\u5316\u6750\u6599\u7684\u9ad8\u901a\u91cf\u8ba1\u7b97\u7b5b\u9009\u3002\u5728 Chem.Mater.\u7b49\u671f\u520a\u53d1\u8868SCI\u8bba\u658730\u4f59\u7bc7\u3002<\/p>\n

\u8d75\u5e86\u8d3a\u535a\u58eb\uff0c\u5317\u4eac\u5927\u5b66\u65b0\u6750\u6599\u5b66\u9662\u526f\u7814\u7a76\u5458\uff0c\u76ee\u524d\u81f4\u529b\u4e8e\u7535\u50ac\u5316\u5242\u6750\u6599\u8bbe\u8ba1\u53ca\u6c34\u7cfb\u7535\u6c60\u5f00\u53d1\u76f8\u5173\u7684\u7814\u7a76\uff0c\u5728Adv. Mater.\u3001Angew. Chem.\u3001Adv. Funct. Mater.\u7b49\u671f\u520a\u53d1\u8868SCI\u8bba\u658710\u4f59\u7bc7\uff1b<\/p>\n

\u6f58\u950b\u6559\u6388\uff0c\u5317\u4eac\u5927\u5b66\u65b0\u6750\u6599\u5b66\u9662\u521b\u9662\u9662\u957f\u3001\u5317\u4eac\u5927\u5b66\u6559\u6388\uff0c\u79d1\u6280\u90e8\u201c\u7535\u52a8\u6c7d\u8f66\u52a8\u529b\u7535\u6c60\u4e0e\u6750\u6599\u56fd\u9645\u8054\u5408\u7814\u7a76\u4e2d\u5fc3\u201d\uff08\u56fd\u5bb6\u7ea7\u7814\u53d1\u4e2d\u5fc3\uff09\u4e3b\u4efb\u3002\u81f4\u529b\u4e8e\u6750\u6599\u57fa\u56e0\u4e0e\u5927\u6570\u636e\u7cfb\u7edf\u7814\u53d1\u3001\u7ed3\u6784\u5316\u5b66\u65b0\u8303\u5f0f\u63a2\u7d22\u3001 \u57fa\u4e8e\u4e2d\u5b50\u5927\u79d1\u5b66\u88c5\u7f6e\u7684\u6750\u6599\u548c\u5668\u4ef6\u7efc\u5408\u8868\u5f81\u7cfb\u7edf\u5efa\u8bbe\u4e0e\u5e94\u7528\u3002\u5148\u540e\u83b7\u56fd\u9645\u7535\u52a8\u8f66\u9502\u7535\u6c60\u534f\u4f1a\u6770\u51fa\u7814\u7a76\u5956(2016)\u3001\u7f8e\u56fd\u7535\u5316\u5b66\u5b66\u4f1a\u7535\u6c60\u79d1\u6280\u5956(2018)\u548c\u6df1\u5733\u5e02\u81ea\u7136\u79d1\u5b66\u4e00\u7b49\u5956(2019)\u3002\u5728Nature Nanotech.\u7b49\u671f\u520a\u53d1\u8868SCI\u8bba\u6587250\u4f59\u7bc7\uff0c2015-19\u8fde\u7eed5\u5e74\u5165\u9009\u7231\u601d\u552f\u5c14\u4e2d\u56fd\u9ad8\u88ab\u5f15\u5b66\u8005\u3002<\/p>\n

\u3010\u6587\u7ae0\u94fe\u63a5\u3011<\/strong><\/p>\n

Boosting the Energy Density of Aqueous Batteries via Facile Grotthuss Proton Transport<\/p>\n

\u6587\u7ae0\u94fe\u63a5\uff1ahttps:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202011588<\/p>\n

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