{"id":212724,"date":"2020-11-10T06:34:43","date_gmt":"2020-11-09T22:34:43","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=212724"},"modified":"2020-11-09T21:35:53","modified_gmt":"2020-11-09T13:35:53","slug":"mofs-cof%e7%ad%89%e6%a1%86%e6%9e%b6%e6%9d%90%e6%96%99%e5%bc%80%e5%b1%b1%e7%a5%96%e5%b8%88omar-m-yaghi%e6%95%99%e6%8e%88science%e5%90%88%e9%9b%86","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=212724","title":{"rendered":"MOFs\/COF\u7b49\u6846\u67b6\u6750\u6599\u5f00\u5c71\u7956\u5e08Omar M. Yaghi\u6559\u6388Science\u5408\u96c6"},"content":{"rendered":"

Omar M. Yaghi\u6559\u6388\u53ef\u4ee5\u8bf4\u662f\u6846\u67b6\u6750\u6599\u7684\u5f00\u5c71\u9f3b\u7956\uff0c2018\u5e74\uff0c\u4ed6\u56e0\u4e3a\u901a\u8fc7\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08MOF\uff09\u548c\u5171\u4ef7\u6709\u673a\u6846\u67b6\uff08COF\uff09\u63a8\u52a8\u7f51\u72b6\u5316\u5b66\uff08Reticular Chemistry\uff09\u7684\u53d1\u5c55\u800c\u83b7\u5f97\u7d20\u6709\u8bfa\u8d1d\u5c14\u5956\u98ce\u5411\u6807\u4e4b\u79f0\u7684\u6c83\u5c14\u592b\u5956\uff0c\u4ed6\u4e5f\u662f\u76ee\u524d\u8bba\u6587\u88ab\u5f15\u7528\u6b21\u6570\u6700\u591a\u7684\u79d1\u5b66\u5bb6\u4e4b\u4e00\uff0c\u5728\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08MOF\uff09\u3001\u6cb8\u77f3\u54aa\u5511\u916f\u6846\u67b6\uff08ZIF\uff09\u4ee5\u53ca\u5171\u4ef7\u6709\u673a\u6846\u67b6\uff08MOF\uff09\u7b49\u9886\u57df\u505a\u4e86\u5960\u57fa\u6027\u548c\u5f00\u521b\u6027\u5de5\u4f5c\u3002\u6700\u51fa\u540d\u7684\u662f\u4ed61999\u5e74\u53d1\u8868\u5728Nature\u4e0a\u7684MOF-5\u7ed3\u6784[1]<\/sup>\uff0c\u8fd9\u4e2a\u7ed3\u6784\u4f7f\u7528\u4e86\u950c\u79bb\u5b50\u548c1,4-\u5bf9\u82ef\u4e8c\u7532\u9178\uff0c\u4e8c\u7ea7\u6784\u5efa\u5355\u5143\uff08SBU\uff09\u662f\u56db\u6838\u950c\u6b63\u7acb\u65b9\u4f53\u578b\u914d\u4f4d\uff0c\u800c\u4e14\u8fd9\u4e9bSBU\u6784\u6210\u4e86\u4e00\u4e2a\u4e09\u7ef4\u6846\u67b6\u7ed3\u6784\uff0c\u8fd9\u4e2a\u7ed3\u6784\u5bf9\u6c14\u4f53\u548c\u6709\u673a\u5206\u5b50\u8868\u73b0\u51fa\u5f88\u597d\u7684\u5438\u9644\u80fd\u529b\uff0c\u5e76\u4e14\u6bd4\u8868\u9762\u79ef\u9ad8\u8fbe2,900 m2<\/sup> g-1<\/sup>\u3002\u56e0\u4e3a\u8fd9\u4e00\u91cd\u8981\u53d1\u73b0\uff0c\u201cMOF\u6765\u5230\u4e86\u9ec4\u91d1\u65f6\u4ee3\u201d\u3002\u672c\u6587\u603b\u7ed3\u4e86\u8fd1\u51e0\u5e74Omar M. Yaghi\u6559\u6388\u5728Science\u4e0a\u53d1\u8868\u7684\u5173\u4e8e\u6846\u67b6\u6750\u6599\u7684\u91cd\u8981\u53d1\u73b0\u3002<\/p>\n

\"\"<\/p>\n

\u56fe1. Omar M. Yaghi\u6559\u6388\u7684\u91cd\u8981\u6210\u679c<\/p>\n

\u4e00\u3001\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u4e0e\u5206\u5b50\u7f16\u7ec7[2]<\/sup><\/strong><\/p>\n

Omar M. Yaghi\u6559\u6388\u57282016\u5e74\u66fe\u4f7f\u7528\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u521b\u5efa\u4e86\u4e00\u79cd\u5206\u5b50\u7ec7\u7269\u7c7b\u4f3c\u7269\uff0c\u8be5\u6210\u679c\u53d1\u8868\u5728Science\u4e0a\u3002\u94dc\u91d1\u5c5e\u7edc\u5408\u7269\u4e0a\u7684\u83f2\u54af\u5549\u914d\u4f53\u901a\u8fc7\u4e9a\u80fa\u952e\u5f15\u5bfc\u6709\u673a\u8fde\u63a5\u57fa\u7684\u6dfb\u52a0\uff0c\u4ece\u800c\u5f62\u6210\u5177\u6709\u7f16\u7ec7\u7eb9\u7406\u7684\u87ba\u65cb\u6709\u673a\u7ebf\u3002\u53bb\u9664\u94dc\u53ef\u4ee5\u4f7f\u7ebf\u675f\u5f7c\u6b64\u6ed1\u52a8\uff0c\u5e76\u4f7f\u6750\u6599\u7684\u5f39\u6027\u589e\u52a010\u500d\u3002<\/p>\n

\u901a\u8fc7\u919b\u5b98\u80fd\u5316\u7684\u94dc\uff08I\uff09-\u53cc\u83f2\u54af\u5549\u56db\u6c1f\u787c\u9178\uff0cCu(PDB)2<\/sub>(BF4<\/sub>)\u548c\u8054\u82ef\u80fa\u7f29\u5408\u53cd\u5e94\uff0c\u5408\u6210\u4e86\u7531\u87ba\u65cb\u6709\u673a\u7ebf\u6784\u6210\u7684\u4e09\u7ef4\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\uff08COF-505\uff09\uff0c\u8be5\u9aa8\u67b6\u4ee5\u89c4\u5219\u7684\u95f4\u9694\u76f8\u4e92\u7f16\u7ec7\u3002\u94dc\u4e2d\u5fc3\u5728\u62d3\u6251\u4e0a\u72ec\u7acb\u4e8eCOF\u7ed3\u6784\u5185\u7684\u7f16\u7ec7\uff0c\u5e76\u4e14\u5f53\u505a\u6a21\u677f\u5c06\u7ebf\u5f15\u5165\u7f16\u7ec7\u56fe\u6848\uff0c\u800c\u4e0d\u662f\u66f4\u5e38\u89c1\u7684\u5e73\u884c\u6392\u5217\u65b9\u5f0f\u3002\u94dc\u79bb\u5b50\u53ef\u88ab\u53ef\u9006\u5730\u53bb\u9664\u548c\u6dfb\u52a0\uff0c\u800c\u4e0d\u4f1a\u635f\u5931COF\u7ed3\u6784\uff0c\u4e3a\u6b64\uff0c\u8131\u91d1\u5c5e\u4f1a\u589e\u52a0\u5341\u500d\u7684\u5f39\u6027\u3002COF-505\u4e2d\u7684\u7ebf\u5177\u6709\u8bb8\u591a\u81ea\u7531\u5ea6\uff0c\u53ef\u4ee5\u5728\u6574\u4e2a\u6750\u6599\u8303\u56f4\u5185\u5728\u5b83\u4eec\u4e4b\u95f4\u53d1\u751f\u5de8\u5927\u7684\u504f\u5dee\uff0c\u800c\u4e0d\u4f1a\u5f71\u54cd\u6574\u4e2a\u7ed3\u6784\u7684\u7f16\u7ec7\u3002<\/p>\n

\"\"<\/p>\n

\u56fe2. \u7f16\u7ec7\u548c\u7ea0\u7f20\u3002\u5bf9\u6bd4\u4e86\u7247\u6750\uff08C\uff09\uff0c3\u7ef4\uff08D\uff09\u7684\u7f20\u7ed3\u4ee5\u53ca\u73af\u7684\u4e92\u9501\uff08\u63d2\u5165\uff09\uff0c\u4ee5\u4e8c\u7ef4\uff08A\uff09\u548c\u4e09\u7ef4\uff08B\uff09\u5c3a\u5bf8\u7f16\u7ec7\u7ebf\u7684\u63d2\u56fe\u3002<\/p>\n

\u4e8c\u3001\u8fdb\u5316\uff1a\u539f\u5b50\uff0c\u5206\u5b50\uff0c\u6846\u67b6[3]<\/sup><\/strong><\/p>\n

Omar M. Yaghi\u6559\u63882017\u5e74\u7684\u65f6\u5019\u53c8\u5728Science\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cThe atom, the molecule, and the covalent organic framework\u201d\u7684\u7efc\u8ff0\uff0c\u603b\u7ed3\u4e86\u5171\u4ef7\u6709\u673a\u6846\u67b6\uff08COF\uff09\u7684\u7814\u7a76\u8fdb\u5c55\u548c\u53d1\u5c55\u6f5c\u529b\uff0c\u5177\u4f53\u5185\u5bb9\u5305\u62ec\uff1a\u5316\u5b66\u4e2d\u5206\u5b50\u6982\u5ff5\u5ef6\u4f38\u7684\u53d1\u5c55\u3001\u5171\u4ef7\u6709\u673a\u6846\u67b6\u7269\u7684\u57fa\u672c\u6982\u5ff5\u3001\u6846\u67b6\u53cd\u5e94\u53ca\u5176\u6027\u8d28\u3001\u6846\u67b6\u4e2d\u5171\u4ef7\u952e\u548c\u673a\u68b0\u529b\u7684\u7ed3\u5408\u3001\u4e0d\u540c\u7ef4\u6570\u6846\u67b6\u7ed3\u6784\u7684\u7ea0\u7f20\u3001\u672a\u6765\u7684\u5c55\u671b\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3. \u539f\u5b50\u3001\u5206\u5b50\u4ee5\u53ca\u5171\u4ef7\u6709\u673a\u7269\u6846\u67b6<\/p>\n

\u4eceLewis\u5173\u4e8e\u5171\u4ef7\u952e\u7684\u6982\u5ff5\u6027\u5de5\u4f5c\u4ee5\u6765\uff0c\u6709\u673a\u7269\u5408\u6210\u65b9\u6cd5\u7684\u7cfb\u7edf\u53d1\u5c55\u4fc3\u8fdb\u4e86\u5316\u5b66\u4e2d\u7684\u591a\u9879\u91cd\u8981\u8fdb\u5c55\u3002\u5927\u578b\u5927\u5206\u5b50\u7ed3\u6784\uff08\u4e00\u7ef4\u805a\u5408\u7269\uff09\u7684\u53d1\u73b0\u6253\u5f00\u4e86\u6709\u673a\u529f\u80fd\u6750\u6599\u7684\u7814\u7a76\u9886\u57df\u3002\u975e\u5171\u4ef7\u952e\u7684\u4f5c\u7528\u4e3b\u5bfc\u4e86\u5206\u5b50\u7684\u8bc6\u522b\u8fc7\u7a0b\uff0c\u4f7f\u8fd9\u4e9b\u5206\u5b50\u5f62\u6210\u6709\u89c4\u5f8b\u7684\u5f62\u5f0f\u6765\u5f62\u6210\u66f4\u590d\u6742\u7684\u529f\u80fd\u7cfb\u7edf\uff0c\u4f7f\u673a\u68b0\u7ed3\u5408\u5f15\u5165\u5230\u4e86\u6846\u67b6\u7684\u5f62\u6210\u4e2d\u3002<\/p>\n

\"\"<\/p>\n

\u56fe4. \u6e90\u81ea\u4e8eLewis\u539f\u59cb\u5171\u4ef7\u952e\u6982\u5ff5\u7684\u53d1\u5c55\u5e74\u8868<\/p>\n

\u4e09\u3001\u5b66DNA\u6d4b\u591a\u5143MOF\u4e2d\u7cbe\u786e\u7684\u91d1\u5c5e\u5e8f\u5217[4]<\/sup><\/strong><\/p>\n

\u4e0d\u77e5\u9053\u5927\u5bb6\u6709\u6ca1\u6709\u8bbe\u60f3\u8fc7\uff0c\u901a\u8fc7\u5408\u6210\u6280\u672f\uff0c\u4eba\u9020\u5206\u5b50\u6709\u4e00\u5929\u53ef\u80fd\u6210\u4e3a\u7c7b\u4f3c\u8ba1\u7b97\u673a\u4fe1\u606f\u5355\u5143\uff0c\u6216\u8005\u53ef\u7f16\u7a0b\u7269\u8d28\u7684\u57fa\u7840\uff0c\u7c7b\u4f3c\u4e8e\u78b1\u57fa\u5bf9\u5e8f\u5217\u786e\u5b9aDNA\u4fe1\u606f\u5185\u5bb9\u7684\u65b9\u6cd5\uff0c\u4ee5\u539f\u5b50\u7684\u7a7a\u95f4\u6392\u5217\u65b9\u5f0f\u4e3a\u4fe1\u606f\u8fdb\u884c\u7f16\u7801\u3002Omar M. Yaghi\u8bfe\u9898\u7ec4\u7814\u7a76\u53d1\u73b0\uff0c\u539f\u5b50\u63a2\u9488\u5c42\u6790\u6210\u50cf\u53ef\u7528\u4e8e\u8bfb\u53d6\u591a\u5143\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u4e2d\u91d1\u5c5e\u79bb\u5b50\u7684\u590d\u6742\u7a7a\u95f4\u6392\u5217\u3002\u8be5\u7814\u7a76\u7ed3\u679c\u4eca\u5e748\u6708\u4efd\u53d1\u8868\u5728\u300aScience\u300b\u6742\u5fd7\u4e0a\u3002<\/p>\n

\u5927\u591a\u6570\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08MOF\uff09\u4e2d\u53ea\u6709\u4e00\u79cd\u91d1\u5c5e\u8fde\u63a5\u6709\u673a\u914d\u4f53\uff0c\u800c\u5305\u542b\u591a\u79cd\u91d1\u5c5e\u7684\u591a\u5143MOF\u53ef\u4ee5\u5728\u5438\u9644\u548c\u50ac\u5316\u4e2d\u63d0\u4f9b\u66f4\u597d\u7684\u9009\u62e9\u6027\uff0c\u4f46\u662f\u786e\u5b9a\u8fd9\u4e9b\u6750\u6599\u4e2d\u91d1\u5c5e\u7684\u6392\u5217\u65b9\u5f0f\u662f\u6781\u5177\u6311\u6218\u6027\u7684\u3002\u672c\u6587\u5c06\u8981\u4ecb\u7ecd\u7684\u8fd9\u4efd\u5de5\u4f5c\u4e2d\uff0c\u7814\u7a76\u4eba\u53d1\u73b0\u539f\u5b50\u63a2\u9488\u5c42\u6790\u6210\u50cf(APT)\u53ef\u4ee5\u63ed\u793a\u5305\u542b\u94b4\uff0c\u9549\uff0c\u94c5\u548c\u9530\u79bb\u5b50\u7ec4\u5408\u7684MOF-74\u5355\u6676\u7684\u91d1\u5c5e\u5e8f\u5217\u3002\u4f5c\u8005\u4eec\u9009\u53d6\u7684MOF\u4e2d\uff0c\u91d1\u5c5e\u5f62\u6210\u6c27\u5316\u68d2\uff0c\u8fd9\u4e9b\u6c27\u5316\u68d2\u901a\u8fc7\u6709\u673a\u8fde\u63a5\u4f53\u8fde\u63a5\u6210\u8702\u7a9d\u72b6\u6676\u4f53<\/p>\n

\u4ed6\u4eec\u8bc1\u660e\u901a\u8fc7\u6539\u53d8\u91d1\u5c5e\u7684\u6bd4\u4f8b\u548c\u5408\u6210\u6e29\u5ea6\u53ef\u4ee5\u8c03\u8282\u91d1\u5c5e\u5e8f\u5217\uff0c\u8fd9\u4e9b\u5e8f\u5217\u53ef\u4ee5\u662f\u968f\u673a\u7684\uff0c\u77ed\u7684\u6216\u957f\u7684\u91cd\u590d\u5355\u5143\u6216\u8005\u5355\u4e2a\u91d1\u5c5e\u63d2\u5165\u7684\u5f62\u5f0f\uff0c\u63ed\u793a\u4e86MOF\u4e2d\u91d1\u5c5e\u79bb\u5b50\u7684\u5f02\u8d28\u7a7a\u95f4\u5e8f\u5217\u3002<\/p>\n

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\"\"<\/p>\n

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\"\"<\/p>\n

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\"\"<\/p>\n

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\"\"<\/p>\n

\u56fe8. \u8de8\u76f8\u90bb\u91d1\u5c5e\u6c27\u5316\u7269\u68d2\u7684\u91d1\u5c5e\u6392\u5217\u3002<\/p>\n

\u4ece\u957f\u8fdc\u6765\u770b\uff0c\u5177\u6709\u7a0b\u5e8f\u5316\u7684\u539f\u5b50\u5e8f\u5217\u7684\u7ed3\u6784\u53ef\u4ee5\u5b8c\u5168\u6539\u53d8\u6211\u4eec\u5bf9\u6750\u6599\u5408\u6210\u7684\u601d\u8003\u65b9\u5f0f\uff0c\u6750\u6599\u7684\u5408\u6210\u53ef\u80fd\u8fbe\u5230\u5ab2\u7f8e\u751f\u7269\u5b66\u7684\u7cbe\u786e\u5ea6\u548c\u590d\u6742\u6027\u7684\u5168\u65b0\u6c34\u5e73\u3002<\/p>\n

\u53c2\u8003\u6587\u732e\uff1a<\/p>\n

[1]H. L Li, M. M. Eddaoudi, M. O’Keeffe, O. M. Yaghi, Design and synthesis of an exceptionally stable and highly porous metal-organic framework, Nature, 1999 (402).<\/p>\n

[2]Yuzhong Liu, Yanhang Ma, Yingbo Zhao, Xixi Sun, Felipe G\u00e1ndara, Hiroyasu Furukawa, Zheng Liu, Hanyu Zhu, Chenhui Zhu, Kazutomo Suenaga, Peter Oleynikov, Ahmad S. Alshammari, Xiang Zhang, Osamu Terasaki, Omar M. Yaghi, Weaving of organic threads into a crystalline covalent organic framework, Science, 2016 (351) 365-369.<\/p>\n

[3]Christian S. Diercks, Omar M. Yaghi, The atom, the molecule, and the covalent organic framework, Science, 2017 (355) eaal1585.<\/p>\n

[4]Zhe Ji, Tong Li, Omar M. Yaghi, Sequencing of metals in multivariate metal-organic frameworks, Science, 2020 (369) 674-680.<\/p>\n

\u672c\u6587\u7531\u6625\u6625\u4f9b\u7a3f\u3002<\/p>\n

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Omar M. Yaghi\u6559\u6388\u53ef\u4ee5\u8bf4\u662f\u6846\u67b6\u6750\u6599\u7684\u5f00\u5c71\u9f3b\u7956\uff0c2018\u5e74\uff0c\u4ed6\u56e0\u4e3a\u901a\u8fc7\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08MOF\uff09\u548c\u5171\u4ef7\u6709\u673a\u6846\u67b6\uff08COF\uff09\u63a8\u52a8\u7f51\u72b6\u5316\u5b66\uff08Reticular …<\/p>\n","protected":false},"author":11454,"featured_media":212726,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1187],"tags":[],"class_list":["post-212724","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zhuanlan"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/212724"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=212724"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/212724\/revisions"}],"predecessor-version":[{"id":212837,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/212724\/revisions\/212837"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/212726"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=212724"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=212724"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=212724"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}