{"id":212857,"date":"2020-11-11T06:30:34","date_gmt":"2020-11-10T22:30:34","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=212857"},"modified":"2020-11-12T22:24:31","modified_gmt":"2020-11-12T14:24:31","slug":"%e3%80%90%e6%8a%95%e7%a8%bf%e3%80%91%e5%8c%97%e5%a4%a7%e6%bd%98%e9%94%8b%e5%9b%a2%e9%98%9fadv-mater-%ef%bc%9a%e9%a2%84%e5%b5%8c%e5%85%a5%e7%ad%96%e7%95%a5%e5%8a%a9%e5%8a%9b%e9%94%b0%e6%b0%a7%e5%8c%96","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=212857","title":{"rendered":"\u5317\u5927\u6f58\u950b\u56e2\u961fAdv. Mater.\uff1a\u9884\u5d4c\u5165\u7b56\u7565\u52a9\u529b\u9530\u6c27\u5316\u7269\u6b63\u6781\u6750\u6599\u7535\u5316\u5b66\u50a8\u80fd"},"content":{"rendered":"

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\u56fe3<\/b><\/strong>\u00a0(a-c) Cu2+<\/sup>\u9884\u5d4c\u5165\u03b4-MnO2<\/sub>\u7684XRD\uff0cXPS\u548c\u500d\u7387\u6027\u80fd;\u00a0(d-f) Zn+<\/sup>\u9884\u5d4c\u5165\u03b4-MnO2<\/sub>\u7684XRD\uff0c\u5e26\u9699\u548c\u4e0d\u540c\u7535\u6d41\u4e0b\u7684\u7535\u5bb9;\u00a0(g, h) Na+<\/sup>\u9884\u5d4c\u5165\u7684\u03b4-MnO2<\/sub>\u7ed3\u6784\u793a\u610f\u56fe\u548c\u80fd\u5e26\u56fe(\u56fe\u7247\u6765\u6e90\uff1aAdvanced Materials\uff09<\/p>\n

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Radhiyah\u7b4911<\/sup>\u62a5\u9053\u4e86\u4e00\u79cdNa+<\/sup>\u9884\u5d4c\u5165\u7684\u03b4-MnO2<\/sub>\uff0c\u8fd9\u79cd\u03b4-MnO2<\/sub>\u6709\u7740\u4e24\u500d\u4e8e\u672a\u9884\u5d4c\u5165\u7684\u03b4-MnO2<\/sub>\u7684\u7535\u5bb9\u91cf\uff0c\u8fd9\u662f\u7531\u4e8eNa+<\/sup>\u9884\u5d4c\u5165\u4f7f\u5f97\u5b83\u7684BET\u589e\u52a0\u4e86\u5f88\u591a\u3002\uff08\u56fe4 a-c<\/b><\/strong>\uff09Inoue\u7b4912<\/sup>\u62a5\u9053\uff0cCo2+<\/sup>\u3001Ni2+<\/sup>\u3001Pb2+<\/sup>\u9884\u5d4c\u5165\u7684MnO2<\/sub>\u7531\u4e8e\u5176\u591a\u5c42\u7ed3\u6784\u4ece\u5e73\u884c\u4e8e\u57fa\u5e95\u53d8\u6210\u4e86\u5782\u76f4\u4e8e\u57fa\u5e95\uff0c\u95f4\u63a5\u63d0\u9ad8\u4e86\u5176\u6d3b\u6027\u4f4d\u70b9\u7684\u6570\u91cf\u3002\uff08\u56fe<\/b><\/strong>4<\/b><\/strong>\u00a0d, e<\/b><\/strong>\uff09<\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>4<\/b><\/strong>\u00a0(a-c) Na+<\/sup>\u9884\u5d4c\u5165\u7684\u03b4-MnO2<\/sub>\u7684BET\u548c\u7535\u5bb9;\u00a0(d, e) \u63ba\u6742\u4e86Co2+<\/sup>\u3001Ni2+<\/sup>\u6216Pb2+<\/sup>\u7684MnO2<\/sub>\u7684SEM\u56fe\u50cf\u53ca\u7535\u5316\u5b66\u8fc7\u7a0b\u7ed3\u6784\u6f14\u53d8\u3002(\u56fe\u7247\u6765\u6e90\uff1aAdvanced Materials\uff09<\/p>\n

Jabeen\u7b4913<\/sup>\u53d1\u73b0\uff0c\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\uff0cK+<\/sup>\u9884\u5d4c\u5165\u7684\u03b1-MnO2<\/sub>\u4e2d\u7684K+<\/sup>\u79bb\u5b50\u53ef\u4ee5\u88abNa+<\/sup>\u79bb\u5b50\u53d6\u4ee3\uff0c\u4ece\u800c\u589e\u5f3a\u4e86\u6750\u6599\u7684\u8d5d\u7535\u5bb9\u6548\u5e94\uff0c\u4e5f\u5c31\u662f\u8bf4\uff0cK+<\/sup>\u7684\u5d4c\u5165\u4f7f\u5f97\u03b1-MnO2<\/sub>\u66b4\u9732\u4e86\u6d3b\u6027\u4f4d\u70b9\u3002\uff08\u56fe<\/b><\/strong>5<\/b><\/strong>\u00a0<\/b><\/strong>a<\/b><\/strong>\uff09Lin\u7b4914<\/sup>\u4eba\u7814\u7a76\u4e86\u4f5c\u4e3a\u7535\u5bb9\u5668\u6b63\u6781\u6750\u6599\u7684Na+<\/sup>\u9884\u5d4c\u5165\u7684\u03b4-MnO2<\/sub>\uff0c\u53d1\u73b0Na+<\/sup>\u9884\u5d4c\u5165\u6781\u5927\u7a0b\u5ea6\u4e0a\u964d\u4f4e\u4e86\u03b4-MnO2<\/sub>\u6750\u6599\u7684\u7ed3\u6676\u5ea6\uff0c\u4ece\u800c\u4f7f\u5f97Na+<\/sup>\u79bb\u5b50\u5728\u6750\u6599\u7684\u5c42\u95f4\u66f4\u52a0\u5bb9\u6613\u8fdb\u51fa\uff0c\u4e5f\u5c31\u662f\u8bf4\uff0c\u6750\u6599\u7684\u6d3b\u6027\u4f4d\u70b9\u8fdb\u4e00\u6b65\u88ab\u5229\u7528\u8d77\u6765\u3002\uff08\u56fe5 b, c<\/b><\/strong>\uff09<\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>5<\/b><\/strong>\u00a0<\/b><\/strong>(a) K+<\/sup>\u9884\u5d4c\u5165\u7684\u03b1-MnO2<\/sub>\u5145\u653e\u7535\u8fc7\u7a0b\uff1b(b, c) Na+<\/sup>\u9884\u5d4c\u5165\u524d\u540e\u03b4-MnO2<\/sub>\u7684\u7ed3\u6784\u53d8\u5316\u4ee5\u53ca\u5176\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u53d1\u751f\u7684\u53d8\u5316\u3002(\u56fe\u7247\u6765\u6e90\uff1aAdvanced Materials\uff09<\/p>\n

\u589e\u5f3a<\/b><\/strong>\u79bb\u5b50<\/b><\/strong>\u6269\u6563\u52a8\u529b\u5b66<\/b><\/strong><\/p>\n

Nam\u7b492<\/sup>\u53d1\u73b0\u5728\u4e00\u79cdNa+<\/sup>\u79bb\u5b50\u548c\u6c34\u5206\u5b50\u5171\u540c\u9884\u5d4c\u5165\u7684\u03b4-MnO2<\/sub>\uff08Na0.71<\/sub>MnO2<\/sub>\u00b70.25H2<\/sub>O\uff09\u4e2d\uff0c\u7531\u4e8e\u6c34\u5206\u5b50\u7684\u7535\u8377\u5c4f\u853d\u6548\u5e94\uff0c\u5176\u5b58\u5728\u6781\u5927\u7a0b\u5ea6\u4e0a\u589e\u5f3a\u4e86Na+<\/sup>\u79bb\u5b50\u5728\u6676\u683c\u548c\u754c\u9762\u5904\u7684\u6269\u6563\u52a8\u529b\u5b66\u3002\u4ed6\u4eec\u4e5f\u6d4b\u91cf\u4e86EIS\u548c\u6269\u6563\u7cfb\u6570\uff0c\u540c\u6837\u8bc1\u660e\u4e86\u8fd9\u4e00\u70b9\u3002\uff08\u56fe6 c-e<\/b><\/strong>\uff09<\/p>\n

\"\"<\/p>\n

\u56fe6<\/b><\/strong>\u00a0(c-e) Na0.71<\/sub>MnO2<\/sub>\u00b70.25H2<\/sub>O\u7684\u7ed3\u6784\u793a\u610f\u56fe\u3001EIS\u548cGITT(\u56fe\u7247\u6765\u6e90\uff1aAdvanced Materials\uff09<\/p>\n

Nam\u7b4915<\/sup>\u8fd8\u5408\u6210\u4e86\u4e00\u79cd\u91c7\u7528\u975e\u5e38\u89c4\u65b9\u6cd5\u5c06\u7ed3\u6676\u6c34\u56fa\u5b9a\u5728\u5176\u5c42\u95f4\u7684\u03b4-MnO2<\/sub>\u3002\u4ed6\u4eec\u901a\u8fc7STEM\u7b49\u5b9e\u9a8c\u65b9\u6cd5\u53d1\u73b0\uff0c\u8fd9\u79cdMnO2<\/sub>\u4e2d\u7684\u7ed3\u6676\u6c34\u53ef\u4ee5\u5c4f\u853d\u5d4c\u5165\u7684Mg2+<\/sup>\u79bb\u5b50\u548c\u4e3b\u4f53\u9634\u79bb\u5b50\u4e4b\u95f4\u7684\u9759\u7535\u76f8\u4e92\u4f5c\u7528\uff0c\u4ece\u800c\u5f97\u5230\u4e86\u8f83\u9ad8\u7684\u5bb9\u91cf\uff0c\u5982\u56fe\u6240\u793a\u3002\uff08\u56fe<\/b><\/strong>7<\/b><\/strong>\u00a0<\/b><\/strong>a<\/b><\/strong>, b<\/b><\/strong>\uff09\u3002\u540c\u65f6\uff0cNam\u4ed6\u4eec16<\/sup>\u8fd8\u62a5\u9053\u4e86\u4e00\u79cd\u7ed3\u6676\u6c34\u9884\u5d4c\u5165\u7684\u03b4-MnO2<\/sub>\uff0c\u8fd9\u79cd\u03b4-MnO2<\/sub>\u53ef\u4ee5\u5f88\u5927\u7a0b\u5ea6\u4e0a\u964d\u4f4eZn2+<\/sup>\u79bb\u5b50\u4f20\u8f93\u52bf\u5792\uff0c\u5982\u56fe\u6240\u793a\uff0c\u5728\u7ed3\u6676\u6c34\u9884\u5d4c\u5165\u7684\u03b4-MnO2<\/sub>\u5185\uff0cZn2+<\/sup>\u548cH2<\/sub>O\u7684\u914d\u4f4d\u6570\u4e3a4-6\u4e4b\u95f4\uff0c\u5b58\u5728\u7ed3\u6676\u6c34\u65f6\u5176\u6269\u6563\u52bf\u5792\u4e3a0.32eV\uff0c\u4e0d\u5b58\u5728\u7ed3\u6676\u6c34\u65f6\u5176\u6269\u6563\u52bf\u5792\u662f1.03eV\uff0c\u4e5f\u5c31\u662f\u8bf4\uff0c\u7ed3\u6676\u6c34\u7684\u7535\u8377\u5c4f\u853d\u4f5c\u7528\u5927\u5927\u589e\u5f3a\u4e86\u6269\u6563\u52a8\u529b\u5b66\uff0c\u63d0\u9ad8\u4e86\u6750\u6599\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\uff08\u56fe7 c-e<\/b><\/strong>\uff09<\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>7<\/b><\/strong>\u00a0(a, b) Mg2+<\/sup>\u79bb\u5b50\u5d4c\u5165\u03b4-MnO2<\/sub>\u7684\u793a\u610f\u56fe\u53ca\u5176\u5145\u653e\u7535\u548c\u500d\u7387\u66f2\u7ebf;\u00a0(c-e) Zn2+<\/sup>\u7684\u914d\u4f4d\u6570\uff0c\u6269\u6563\u52bf\u5792\u548c\u7ed3\u6676\u6c34\u9884\u5d4c\u5165\u7684\u03b4-MnO2<\/sub>\u7684\u5145\u653e\u7535\u548c\u500d\u7387\u66f2\u7ebf(\u56fe\u7247\u6765\u6e90\uff1aAdvanced Materials\uff09<\/p>\n

Zhao\u7b493<\/sup>\u4f7f\u7528\u4e86\u4e00\u79cd\u6709\u6548\u7684\u9884\u5d4c\u5165\u65b9\u6cd5\uff0c\u5408\u6210\u51fa\u4e86\u5c42\u95f4\u8ddd\u589e\u5927\u7684\u5c42\u72b6MnO2<\/sub>\uff0c\u7279\u522b\u662fTMA+<\/sup>\/H+<\/sup>\u5171\u540c\u9884\u5d4c\u5165\u7684\u5c42\u72b6MnO2<\/sub>\uff0c\u5c55\u73b0\u51fa\u826f\u597d\u7684\u5d4cNa+<\/sup>\u79bb\u5b50\u80fd\u529b\u3002\u5176\u4e2d\u4ee5TMA+<\/sup>\/H+<\/sup>=1000\u7684\u65f6\u5019MnO2<\/sub>\u7684\u5c42\u95f4\u8ddd\u6700\u5927\uff0c\u540c\u65f6\u500d\u7387\u6027\u80fd\u4e5f\u6700\u4f73\u3002\uff08\u56fe8 a-c<\/b><\/strong>\uff09Cao\u7b4917<\/sup>\u53d1\u73b0\u901a\u8fc7\u63a7\u5236\u5408\u6210\u65f6\u52a0\u5165\u7684KMnO4<\/sub>\u53ef\u4ee5\u63a7\u5236\u5408\u6210\u7684\u03b4-MnO2<\/sub>\u5185\u9884\u5d4c\u5165K+<\/sup>\u79bb\u5b50\u7684\u542b\u91cf\u3002\u4e0d\u8fc7\u4ed6\u4eec\u8fd8\u53d1\u73b0\uff0cK+<\/sup>\u79bb\u5b50\u7684\u542b\u91cf\u5e76\u4e0d\u662f\u8d8a\u591a\u8d8a\u597d\u3002\u4e00\u65b9\u9762\u9884\u5d4c\u5165K+<\/sup>\u53ef\u4ee5\u6269\u5927\u5c42\u95f4\u8ddd\uff0c\u589e\u5f3a\u6269\u6563\u52a8\u529b\u5b66\u3002\u4f46\u662f\u53e6\u4e00\u65b9\u9762\uff0cK+<\/sup>\u672c\u8eab\u7531\u4e8e\u5176\u5e26\u6b63\u7535\uff0c\u4e5f\u4f1a\u963b\u788d\u9633\u79bb\u5b50\u5728\u5176\u4e2d\u7684\u6269\u6563\u3002\u4f5c\u8005\u901a\u8fc7\u5b9e\u9a8c\u53d1\u73b0\u9002\u91cf\u7684K+<\/sup>\u9884\u5d4c\u5165\u7684K0.19<\/sub>MnO2<\/sub>\u8868\u73b0\u51fa\u6700\u5927\u7684\u6269\u6563\u7cfb\u6570\u548c\u6bd4\u7535\u5bb9\u3002\uff08\u56fe8 d-f<\/b><\/strong>\uff09<\/p>\n

\"\"<\/p>\n

\u56fe8<\/b><\/strong>\u00a0(a-c) TMA+<\/sup>\/H+<\/sup>\u5171\u540c\u9884\u5d4c\u5165\u7684\u5c42\u72b6MnO2<\/sub>\u7684XRD\uff0c\u4e0d\u540c\u7535\u6d41\u7684\u7535\u5bb9\u91cf\u548cEIS\uff1b(d-f) K+<\/sup>\u79bb\u5b50\u7684\u03b4-MnO2<\/sub>\u7684\u7ed3\u6784\u793a\u610f\u56fe\u3001\u6bd4\u7535\u5bb9\u548c\u6269\u6563\u7cfb\u6570(\u56fe\u7247\u6765\u6e90\uff1aAdvanced Materials\uff09<\/p>\n

Wang\u7b4918<\/sup>\u7814\u7a76\u53d1\u73b0\uff0c\u901a\u8fc7\u5c06\u03b4-MnO2<\/sub>\u5185\u7684\u9884\u5d4c\u5165\u79bb\u5b50\u4eceK+<\/sup>\u66ff\u6362\u6210TMA+<\/sup>\u540e\uff0c\u6750\u6599\u7684\u5c42\u95f4\u8ddd\u6709\u4e86\u663e\u8457\u7684\u589e\u52a0\uff0c\u5927\u5e45\u964d\u4f4e\u4e86Mg2+<\/sup>\u79bb\u5b50\u7684\u5d4c\u5165\u8fc7\u7535\u52bf\uff0c\u63d0\u9ad8\u4e86\u6750\u6599\u5d4c\u5165Mg2+<\/sup>\u7684\u6bd4\u5bb9\u91cf\u548c\u500d\u7387\u6027\u80fd\u3002\uff08\u56fe9 a-d<\/b><\/strong>\uff09Lu’s group19<\/sup>\u53d1\u73b0\u5728\u03b4-MnO2<\/sub>\u4e2d\u5f15\u5165La3+<\/sup>\u79bb\u5b50\u9884\u5d4c\u5165\u540e\uff0c\u5176\u5c42\u95f4\u8ddd\u4ece6.9 \u00c5\u63d0\u9ad8\u52307.6 \u00c5\uff0c\u540c\u65f6\u6750\u6599\u5c55\u73b0\u7684\u6bd4\u5bb9\u91cf\u548c\u63d0\u9ad8\u548c\u963b\u6297\u7684\u964d\u4f4e\u3002\uff08\u56fe9 e-g<\/b><\/strong>\uff09\u7efc\u4e0a\u6240\u8ff0\uff0c\u589e\u5f3a\u6269\u6563\u52a8\u529b\u5b66\u662f\u9884\u5d4c\u5165\u6548\u5e94\u7684\u6700\u4e3b\u8981\u90e8\u5206\u4e4b\u4e00\uff0c\u5177\u4f53\u6765\u8bf4\u53ef\u4ee5\u5206\u4e3a\u7535\u8377\u5c4f\u853d\u6548\u5e94\u548c\u6269\u5927\u5c42\u95f4\u8ddd\uff0c\u5e76\u4e14\u8fd9\u4e9b\u6548\u5e94\u90fd\u4e0d\u662f\u5355\u72ec\u7684\u800c\u662f\u76f8\u8f85\u76f8\u6210\u7684\u3002<\/p>\n

\"\"<\/p>\n

\u56fe9<\/b><\/strong>\u00a0(a-d) \u03b4-MnO2<\/sub>\u9884\u5d4c\u5165K+<\/sup>\u79bb\u5b50\u66ff\u6362\u4e3aTMA+<\/sup>\u540e\u7684XRD\uff0c\u5145\u653e\u7535\u66f2\u7ebf\uff0c\u500d\u7387\u6027\u80fd\u7684\u53d8\u5316\uff1b(e-g) \u03b4-MnO2<\/sub>\u5d4c\u5165La3+<\/sup>\u79bb\u5b50\u524d\u540e\u7684XRD\uff0c\u500d\u7387\u6027\u80fd\u548cEIS(\u56fe\u7247\u6765\u6e90\uff1aAdvanced Materials\uff09<\/p>\n

\u7a33\u5b9a\u6676\u683c\u7ed3\u6784<\/b><\/strong><\/p>\n

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\"\"<\/p>\n

\u56fe10<\/b><\/strong>\u00a0(a, b) K+<\/sup>\u79bb\u5b50\u9884\u5d4c\u5165\u03b1-MnO2<\/sub>\u540eMn2+<\/sup>\u6eb6\u51fa\u91cf\u7684\u53d8\u5316\u548c\u5faa\u73af\u6027\u80fd\uff1b(c-e) \u4e24\u79cd\u5c42\u95f4\u8ddd\u4e0d\u540c\u7684\u03b4-MnO2<\/sub>\u5176Mn2+<\/sup>\u6eb6\u51fa\u7684\u53ef\u80fd\u6027\u4e0d\u540c\uff1b(f-h) Zn-Mn\u54d1\u94c3\u7ed3\u6784\u793a\u610f\u56fe\u4ee5\u53ca\u542b\u7ed3\u6676\u6c34\u7684MnO2<\/sub>\u7684\u5faa\u73af\u548c\u500d\u7387\u6027\u80fd(\u56fe\u7247\u6765\u6e90\uff1aAdvanced Materials\uff09<\/p>\n

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\"\"<\/p>\n

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\"\"<\/p>\n

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\u56e2\u961f\u4ecb\u7ecd<\/b><\/strong><\/p>\n

\u8d75\u5e86\u8d3a\uff08\u535a\u58eb\uff09\uff0c\u5b8b\u5965\u91ce\uff08\u7855\u58eb\u751f\uff09\u548c\u4e01\u6536\u9999\uff08\u7855\u58eb\u751f\uff09\u662f\u6587\u7ae0\u7684\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\uff0c\u6f58\u950b\u6559\u6388\u662f\u6587\u7ae0\u7684\u901a\u8baf\u4f5c\u8005\u3002<\/p>\n

\u8d75\u5e86\u8d3a\u535a\u58eb\uff0c\u5317\u4eac\u5927\u5b66\u65b0\u6750\u6599\u5b66\u9662\u526f\u7814\u7a76\u5458\uff0c\u76ee\u524d\u81f4\u529b\u4e8e\u7535\u50ac\u5316\u5242\u6750\u6599\u8bbe\u8ba1\u53ca\u6c34\u7cfb\u7535\u6c60\u5f00\u53d1\u76f8\u5173\u7684\u7814\u7a76\uff0c\u5728Adv. Mater.\u3001Angew. Chem.\u3001Adv. Funct. Mater.\u7b49\u671f\u520a\u53d1\u8868SCI\u8bba\u6587\u5341\u4f59\u7bc7\uff1b<\/p>\n

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\u6587\u7ae0\u94fe\u63a5<\/b><\/strong><\/p>\n

Pre-intercalation strategy in manganese oxides for electrochemical energy storage: review and prospect<\/p>\n

\u6587\u7ae0\u94fe\u63a5\uff1ahttps:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/adma.202002450<\/u><\/a><\/p>\n

\u53c2\u8003\u6587\u732e<\/b><\/strong><\/p>\n

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9. Radhamani, A. V.; \u00a0Krishna Surendra, M.; Rao, M. S. R., Zn doped \u03b4-MnO2 nano flakes: An efficient electrode material for aqueous and solid state asymmetric supercapacitors. Applied Surface Science <\/i><\/em>2018,<\/b><\/strong>450<\/i><\/em>, 209-218.<\/p>\n

10. Xia, H.; \u00a0Zhu, X.; \u00a0Liu, J.; \u00a0Liu, Q.; \u00a0Lan, S.; \u00a0Zhang, Q.; \u00a0Liu, X.; \u00a0Seo, J. K.; \u00a0Chen, T.; \u00a0Gu, L.; Meng, Y. S., A monoclinic polymorph of sodium birnessite for ultrafast and ultrastable sodium ion storage. Nat Commun <\/i><\/em>2018,<\/b><\/strong>9<\/i><\/em>(1), 5100.<\/p>\n

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17. Cao, L. L.; \u00a0Yu, B. Z.; \u00a0Cheng, T.; \u00a0Zheng, X. L.; \u00a0Li, X. H.; \u00a0Li, W. L.; \u00a0Ren, Z. Y.; Fan, H. M., Optimized K+ pre-intercalation in layered manganese dioxide nanoflake arrays with high intercalation pseudocapacitance. Ceramics International <\/i><\/em>2017,<\/b><\/strong>43<\/i><\/em>(17), 14897-14904.<\/p>\n

18. Wang, M.; Yagi, S., Layered birnessite MnO2 with enlarged interlayer spacing for fast Mg-ion storage. Journal of Alloys and Compounds <\/i><\/em>2020,<\/b><\/strong>820<\/i><\/em>, 153135.<\/p>\n

19. Zhang, H.; \u00a0Liu, Q.; \u00a0Wang, J.; \u00a0Chen, K.; \u00a0Xue, D.; \u00a0Liu, J.; Lu, X., Boosting the Zn-ion storage capability of birnessite manganese oxide nanoflorets by La3+ intercalation. Journal of Materials Chemistry A <\/i><\/em>2019,<\/b><\/strong>7<\/i><\/em>(38), 22079-22083.<\/p>\n

20. Fang, G.; \u00a0Zhu, C.; \u00a0Chen, M.; \u00a0Zhou, J.; \u00a0Tang, B.; \u00a0Cao, X.; \u00a0Zheng, X.; \u00a0Pan, A.; Liang, S., Suppressing Manganese Dissolution in Potassium Manganate with Rich Oxygen Defects Engaged High\u2010Energy\u2010Density and Durable Aqueous Zinc\u2010Ion Battery. Advanced Functional Materials <\/i><\/em>2019,<\/b><\/strong>29<\/i><\/em>(15).<\/p>\n

21. Huang, J.; \u00a0Poyraz, A. S.; \u00a0Takeuchi, K. J.; \u00a0Takeuchi, E. S.; Marschilok, A. C., MxMn8O16 (M = Ag or K) as promising cathode materials for secondary Mg based batteries: the role of the cation M. Chemical Communications <\/i><\/em>2016,<\/b><\/strong>52<\/i><\/em>(21), 4088-4091.<\/p>\n

22. Liu, G.; \u00a0Huang, H.; \u00a0Bi, R.; \u00a0Xiao, X.; \u00a0Ma, T.; Zhang, L., K+ Pre-intercalated Manganese Dioxide with Enhanced Zn2+ Diffusion for High Rate and Durable Aqueous Zinc-Ion Battery. Journal of Materials Chemistry A <\/i><\/em>2019,<\/b><\/strong>7<\/i><\/em>(36), 20806-20812.<\/p>\n

23. Zhao, Y.; \u00a0Han, C.; \u00a0Yang, J.; \u00a0Su, J.; \u00a0Xu, X.; \u00a0Li, S.; \u00a0Xu, L.; \u00a0Fang, R.; \u00a0Jiang, H.; \u00a0Zou, X.; \u00a0Song, B.; \u00a0Mai, L.; Zhang, Q., Stable Alkali Metal Ion Intercalation Compounds as Optimized Metal Oxide Nanowire Cathodes for Lithium Batteries. Nano Letters <\/i><\/em>2015,<\/b><\/strong>15<\/i><\/em>(3), 2180-2185.<\/p>\n

24. Shan, X.; \u00a0Guo, F.; \u00a0Charles, D. S.; \u00a0Lebens-Higgins, Z.; \u00a0Abdel Razek, S.; \u00a0Wu, J.; \u00a0Xu, W.; \u00a0Yang, W.; \u00a0Page, K. L.; \u00a0Neuefeind, J. C.; \u00a0Feygenson, M.; \u00a0Piper, L. F. J.; Teng, X., Structural water and disordered structure promote aqueous sodium-ion energy storage in sodium-birnessite. Nat Commun <\/i><\/em>2019,<\/b><\/strong>10<\/i><\/em>(1), 4975.<\/p>\n

\u56e2\u961f\u6c34\u7cfb\u7535\u6c60\u76f8\u5173\u5de5\u4f5c\uff08<\/strong>2018-2020<\/strong>\uff09<\/strong><\/p>\n

1.Jiaxin Zheng, Guoyu Tan, Peng Shan, Tongchao Liu, Jiangtao Hu, Yancong Feng, Luyi Yang, Mingjian Zhang, Zonghai Chen, Yuan Lin, Jun Lu, Joerg C. Neuefeind, Yang Ren, Khalil Amine, Lin-Wang Wang, Kang Xu, and Feng Pan<\/strong>*, Understanding Thermodynamic and Kinetic Contributions in Expanding the Stability Window of Aqueous Electrolytes. Chem<\/em><\/strong> 2018, 4, 1-11.<\/p>\n

2.Qinghe Zhao1<\/sup><\/strong>, Jinlong Yang1<\/sup>, Mingqiang Liu, Rui Wang, Guangxing Zhang, Han Wang, Hanting Tang, Chaokun Liu, Zongwei Mei, Haibiao Chen, Feng Pan<\/strong>*, Tuning Electronic Push\/Pull of Ni-Based Hydroxides to Enhance Hydrogen and Oxygen Evolution Reactions for Water Splitting. ACS Catal.<\/em><\/strong>, 2018. 8, 5621\u22125629.<\/p>\n

3.Mingqiang Liu1<\/sup>, Qinghe Zhao1<\/sup><\/strong>, Hao Liu, Jinglong Yang, Xin Chen, Luyi Yang, Yanhui Cui, Weiyuan Huang, Wenguang Zhao, Aoye Song, Yuetao Wang, Shouxiang Ding, Yongli Song, Guoyu Qian, Haibiao Chen, Feng Pan*<\/strong>, Tuning phase evolution of \u03b2-MnO2<\/sub> during microwave hydrothermal synthesis for high-performance aqueous Zn ion battery. Nano Energy<\/em><\/strong>, 2019. 64, 103942.<\/p>\n

4.Qinghe Zhao1<\/sup><\/strong>, Xin Chen1<\/sup>, Ziqi Wang, Luyi Yang, Runzhi Qin, Jinlong Yang, Yongli Song, Shouxiang Ding, Mouyi Weng, Weiyuan Huang, Jiajie Liu, Wenguang Zhao, Guoyu Qian, Kai Yang, Yanhui Cui, Haibiao Chen, Feng Pan*<\/strong>, Unravelling H+<\/sup>\/Zn2+<\/sup> synergistic intercalation in a novel phase of manganese oxide for high-performance aqueous rechargeable battery. Small<\/em><\/strong>, 2019, 1904545.<\/p>\n

5.Ziqi Wang, Jiangtao Hu, Lei Han, Zijian Wang, Hongbin Wang, Qinghe Zhao, Jiajie Liu, Feng Pan*<\/strong>, A MOF-based single-ion Zn2+<\/sup> solid electrolyte leading to dendrite-free rechargeable Zn batteries. Nano Energy<\/em><\/strong>, 2019. 56, 92\u201399.<\/p>\n

6.Mingqiang Liu, Luyi Yang, Hao Liu, Anna Amine, Qinghe Zhao, Yongli Song, Jinlong Yang, Ke Wang, Feng Pan*<\/strong>, Artificial Solid-Electrolyte Interface Facilitating Dendrite-Free Zinc Metal Anodes via Nanowetting Effect. ACS Appl. Mater. Interfaces<\/em><\/strong>, 2019. 11, 32046-32051.<\/p>\n

7.Yanhui Cui, Qinghe Zhao, Xiaojun Wu, Zijian Wang, Runzhi Qin, Yuetao Wang, Mingqiang Liu, Yongli Song, Guoyu Qian, Zhibo Song, Luyi Yang, Feng Pan*<\/strong>, Quasi-Solid Single Zn-ion Conductor with High Conductivity Enabling Dendrite-Free Zn Metal Anode. Energy Storage Materials<\/em><\/strong>, 2020, 27, 1\u20138.<\/p>\n

8.Yanhui Cui1<\/sup>, Qinghe Zhao1<\/sup><\/strong>, Xiaojun Wu, Xin Chen, Yuetao Wang, Runzhi Qin, Shouxiang Ding, Yongli Song, Junwei Wu, Kai Yang, Zijian Wang, Zongwei Mei, Zhibo Song, Hong Wu, Zhongyi Jiang, Guoyu Qian, Jinlong Yang, Luyi Yang, Feng Pan*<\/strong>, An interface bridged organic-inorganic layer suppressing dendrite and side reactions for ultra-long life aqueous Zn metal anodes. Chem. Int. Ed<\/em><\/strong>., 2020. 10.1002\/anie.202005472<\/p>\n

9.Qinghe Zhao1<\/sup><\/strong>, Aoye Song1<\/sup>, Shouxiang Ding1<\/sup>, Runzhi Qin, Yanhui Cui, Shunning Li, Feng Pan<\/strong>*, Pre-Intercalation Strategy in Manganese Oxides for Electrochemical Energy Storage: Review and Prospect. Advanced Materials<\/em><\/strong>, 2020, 2002450.<\/p>\n

10.Haocong Yi1<\/sup>, Runzhi Qin1<\/sup>, Shouxiang Ding, Yuetao Wang, Shunning Li, Qinghe Zhao*<\/strong>, Feng Pan*<\/strong>, Structure and Properties of Prussian Blue Analogues in Energy Storage and Conversion Applications. Funct. Mater.<\/em><\/strong>, 2020, 2006970.<\/p>\n

11.Jiangtao Hu, Wenju Ren, Xin Chen, Yiwei Li, Weiyuan Huang, Kai Yang, Luyi Yang, Yuan Lin, Jiaxin Zheng, Feng Pan*<\/strong>, The role of anions on the Helmholtz Plane for the solid-liquid interface in aqueous rechargeable lithium batteries. Nano Energy<\/em><\/strong>, 2020, 74, 104864.<\/p>\n

12.Hao Jia, Ziqi Wang, Benjamin Tawiah, Yidi Wang, Cheuk-Ying Chan, Bin Fei, Feng Pan<\/strong>*, Recent advances in zinc anodes for high-performance aqueous Zn-ion batteries. Nano Energy<\/em><\/strong>, 2020, 70, 104523.<\/p>\n

13.Qinghe Zhao<\/strong>, Aoye Song, Wenguang Zhao, Runzhi Qin, Shouxiang Ding, Xin Chen, Yongli Song, Luyi Yang, Hai Lin, Shunning Li*, Feng Pan*<\/strong>, Boosting the Energy Density of Aqueous Batteries via Facile Grotthuss Proton Transport. Chem. Int. Ed.<\/em><\/strong>, 2020. doi.org\/10.1002\/anie.202011588<\/p>\n

14.Runzhi Qin, Yuetao Wang, Mingzheng Zhang, Yan Wang, Shouxiang Ding, Aoye Song, Haocong Yi, Luyi Yang, Yongli Song, Yanhui Cui, Jian Liu, Ziqi Wang, Shunning Li*, Qinghe Zhao*<\/strong>, Feng Pan*<\/strong>. Tuning Zn2+<\/sup> coordination environment to suppress dendrite formation for high-performance Zn-ion batteries. Nano Energy<\/em><\/strong>, 2021. 80: p. 105478.<\/p>\n

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