{"id":213489,"date":"2020-11-27T06:30:14","date_gmt":"2020-11-26T22:30:14","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=213489"},"modified":"2020-11-26T16:35:35","modified_gmt":"2020-11-26T08:35:35","slug":"%e6%97%a0%e6%9c%ba%e9%92%99%e9%92%9b%e7%9f%bf%e5%a4%aa%e9%98%b3%e8%83%bd%e7%94%b5%e6%b1%a0%e9%a2%86%e5%9f%9f%ef%bc%8cc%e4%bd%8d%e7%9c%8b%e8%bf%87%e6%9d%a5%ef%bc%81","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=213489","title":{"rendered":"\u65e0\u673a\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u9886\u57df\uff0cC\u4f4d\u770b\u8fc7\u6765\uff01"},"content":{"rendered":"

\u65e0\u673a\u9499\u949b\u77ff\u7531\u4e8e\u5176\u4f18\u5f02\u7684\u7a33\u5b9a\u6027\uff0c\u5c24\u5176\u662f\u70ed\u7a33\u5b9a\u6027\uff0c\u662f\u53d6\u4ee3\u6709\u673a-\u65e0\u673a\u6742\u5316\u9499\u949b\u77ff\u7684\u7406\u60f3\u9009\u62e9\uff0c\u5176\u5149\u7535\u8f6c\u6362\u6548\u7387\u53d1\u5c55\u81f3\u4eca\u5df2\u8fbe1<\/b><\/strong>9.03<\/b><\/strong>%\uff0c\u867d\u7136\u4e0e\u4f20\u7edf\u4f53\u7cfb\u76f8\u6bd4\u6548\u7387\u4ecd\u6709\u4e00\u5b9a\u5dee\u8ddd\uff0c\u4f46\u662f\u524d\u666f\u4e0d\u53ef\u9650\u91cf\uff01\u63a5\u4e0b\u6765\u5c06\u91cd\u70b9\u4ecb\u7ecd\u56fd\u5185\u65e0\u673a\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u9886\u57df\u4e09\u4f4d\u5927\u62ff\u53ca\u5176\u76f8\u5173\u4ee3\u8868\u4f5c\uff1a<\/b><\/strong><\/p>\n

\u4e00\u3001\u5218\u751f\u5fe0\u8bfe\u9898\u7ec4<\/b><\/strong><\/p>\n

\u7b80\u4ecb\uff1a\u5218\u751f\u5fe0\uff0c\u9655\u897f\u5e08\u8303\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u6559\u6388\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u9655\u897f\u5e08\u8303\u5927\u5b66\u65b0\u80fd\u6e90\u9ad8\u7b49\u6280\u672f\u7814\u7a76\u9662\u9662\u957f\uff0c\u9655\u897f\u7701\u80fd\u6e90\u65b0\u6750\u6599\u4e0e\u5668\u4ef6\u91cd\u70b9\u5b9e\u9a8c\u4e3b\u4efb\uff0c\u9655\u897f\u7701\u80fd\u6e90\u65b0\u6750\u6599\u5de5\u7a0b\u5b9e\u9a8c\u5ba4\u4e3b\u4efb\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u7279\u8058\u7814\u7a76\u5458\u3002\u4e3b\u8981\u7814\u7a76\u65b9\u5411\uff1a1)\uff0c\u65b0\u578b\u7eb3\u7c73\u6750\u6599\u9ad8\u6548\u7ed3\u6784\u4f18\u5316\u3001\u529f\u80fd\u9884\u6d4b\u53ca\u6750\u6599\u8bbe\u8ba1\uff1b2)\uff0c\u9499\u949b\u77ff\u7535\u6c60\u5173\u952e\u6750\u6599\u8bbe\u8ba1\u5236\u5907\u53ca\u9ad8\u6027\u80fd\u67d4\u6027\u5668\uff1b3)\uff0c\u67d4\u6027\u8584\u819c\u592a\u9633\u80fd\u7535\u6c60\uff1b4)\uff0c\u67d4\u6027\u886c\u5e95\u5927\u9762\u79ef\u591a\u7ed3\u7845\u8584\u819c\u592a\u9633\u7535\u6c60\u6280\u672f\uff1b5)\uff0c\u9ad8\u6548HIT\u7535\u6c60\u53ca\u7ec4\u4ef6\u7684\u7814\u7a76\u548c\u5f00\u53d1\u7b49\u3002<\/p>\n

\u65e0\u673a\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u4ee3\u8868\u4f5c\uff1a<\/p>\n

1\uff0cPrintable CsPbI3<\/sub>\u00a0Perovskite Solar Cells with PCE of 19% via an Additive Strategy<\/p>\n

\"\"<\/p>\n

\u4f20\u7edfCsPbI3<\/sub>\u9499\u949b\u77ff\u7684\u5236\u5907\u5de5\u827a\u5e76\u4e0d\u80fd\u6279\u91cf\u751f\u4ea7\uff0c\u4f5c\u8005\u63d0\u51fa\u4e00\u79cd\u5728\u7a7a\u6c14\u4e2d\u4fdd\u6301100 \u2103\u5feb\u901f\u522e\u6d82\u6210\u819c\u5236\u5907\u7535\u5b50\u4f20\u8f93\u5c42\u548c\u5149\u5438\u6536\u5c42\u7684\u65b9\u6cd5\uff0c\u5728\u6b64\u57fa\u7840\u4e0a\u5f15\u5165\u5fae\u91cf\u6dfb\u52a0\u5242Zn(C6<\/sub>F5<\/sub>)2<\/sub>\uff0c\u4ece\u800c\u4fdd\u8bc1\u9ad8\u8d28\u91cf\u9ad8\u7a33\u5b9a\u7684CsPbI3<\/sub>\u9499\u949b\u77ff\u6210\u819c\u3002\u6d4b\u8bd5\u8868\u660e\uff0cZn(C6<\/sub>F5<\/sub>)2<\/sub>\u503e\u5411\u4e8e\u805a\u96c6\u5728\u9499\u949b\u77ff\/SnO2<\/sub>\u7684\u754c\u9762\u5904\uff0c\u4ece\u800c\u5f62\u6210\u68af\u5ea6\u80fd\u5e26\u5e76\u4e14\u6291\u5236\u9499\u949b\u77ff\u4e2d\u7f3a\u9677\u6001\u4ea7\u751f\uff0c\u6700\u7ec8\u901a\u8fc7\u8fd9\u79cd\u522e\u6d82\u5370\u5237\u7684\u65b9\u6cd5\uff0c\u5236\u5907\u5f97\u5230\u4e86\u5149\u7535\u8f6c\u6362\u6548\u7387\u9ad8\u8fbe19%\u7684\u7535\u6c60\uff0c700 h\u7a33\u5b9a\u6027\u6d4b\u8bd5\u540e\uff0c\u65e0\u5c01\u88c5\u7684\u5668\u4ef6\u5728\u7a7a\u6c14\u4e2d\u6548\u7387\u4ec5\u635f\u5931\u4e862%\u3002<\/p>\n

2\uff0cControlled n\u2010Doping in Air\u2010Stable CsPbI2<\/sub>Br Perovskite Solar Cells with a Record Efficiency of 16.79%<\/p>\n

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CsPbI2<\/sub>Br\u9499\u949b\u77ff\u4f18\u5f02\u7684\u5149\u7535\u6027\u80fd\u548c\u70ed\u7a33\u5b9a\u6027\u80fd\uff0c\u4f7f\u5176\u6210\u4e3a\u4e00\u79cd\u975e\u5e38\u6709\u524d\u666f\u7684\u5546\u4e1a\u5149\u4f0f\u6750\u6599\uff0c\u7136\u800c\u5176\u5149\u7535\u8f6c\u6362\u6548\u7387\u548cCsPbI3<\/sub>\u4f53\u7cfb\u76f8\u6bd4\u8fd8\u662f\u5b58\u5728\u5f88\u5927\u5dee\u8ddd\u3002\u672c\u6587\u901a\u8fc7\u5bf9\u9499\u949b\u77ff\u8584\u819c\u8fdb\u884c\u949d\u5316\u548cn\u578b\u63ba\u6742CaCl2<\/sub>\uff0c\u63d0\u9ad8\u4e86\u9499\u949b\u77ff\u7684\u7ed3\u6676\u5ea6\uff0c\u7f3a\u9677\u6001\u5bc6\u5ea6\u4e5f\u663e\u8457\u964d\u4f4e\uff0c\u540c\u65f6\uff0c\u5728\u5f15\u5165CaCl2<\/sub>\u540e\uff0c\u9499\u949b\u77ff\u7684\u8d39\u7c73\u80fd\u7ea7\u53d8\u5316\uff0c\u6210\u4e3a\u91cd\u63ba\u6742n\u578b\u534a\u5bfc\u4f53\u3002\u57fa\u4e8e\u8be5\u4f53\u7cfb\u5236\u5907\u7684\u7535\u6c60\u6700\u7ec8\u83b7\u5f97\u4e8616.79%\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\uff0c\u5f00\u8def\u7535\u538b\u8fbe\u52301.32 V\uff0c\u540c\u65f6\u8be5\u4f53\u7cfb\u4e5f\u5c55\u73b0\u51fa\u4f18\u5f02\u7684\u7a7a\u6c14\u7a33\u5b9a\u6027\u80fd\uff0c\u5728\u7ecf\u8fc71000 h\u540e\uff0c\u7535\u6c60\u4ecd\u4fdd\u6301\u521d\u59cb\u6548\u7387\u768490%\u3002<\/p>\n

\u4e8c\u3001\u8d75\u4e00\u65b0\u8bfe\u9898\u7ec4<\/b><\/strong><\/p>\n

\u7b80\u4ecb\uff1a\u8d75\u4e00\u65b0\uff0c\u4e0a\u6d77\u4ea4\u901a\u5927\u5b66\u6559\u6388\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u6770\u9752\u57fa\u91d1\u83b7\u5f97\u8005<\/b><\/strong>\u3002\u4e3b\u8981\u7814\u7a76\u65b9\u5411\uff1a1)\uff0c\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u53ca\u5149\u7535\u5668\u4ef6\uff1b2)\uff0c\u53ef\u6301\u7eed\u73af\u5883\u529f\u80fd\u6750\u6599\u53ca\u5e9f\u5f03\u7269\u8d44\u6e90\u5316\u3002\u5728Science, Sci Adv, Nat Commun\uff0cJACS, Angew Chem, Chem Soc Rev, Joule, EES, ES&T \u7b49\u8457\u540d\u671f\u520a\u53d1\u8868\u8bba\u6587100\u4f59\u7bc7\uff0c\u5f15\u752810000\u4f59\u6b21\uff0c\u8fde\u7eed\u5165\u9009\u79d1\u777f\u7ef4\u5b892018\uff0c2019\uff0c2020\u5e74\u7684\u5168\u7403\u9ad8\u88ab\u5f15\u79d1\u5b66\u5bb6\u3002<\/p>\n

\u65e0\u673a\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u4ee3\u8868\u4f5c\uff1a<\/p>\n

1\uff0cThermodynamically stabilized \u03b2-CsPbI3<\/sub>-based perovskite solar cells with efficiencies> 18%<\/p>\n

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\u03b2-CsPbI3<\/sub>\u7684\u5e26\u9699\u662f\u5438\u5149\u6750\u6599\u7684\u7406\u60f3\u9009\u62e9\uff0c\u4f46\u662f\u5236\u5907\u5f97\u5230\u7a33\u5b9a\u7684\u03b2\u76f8\u4ecd\u5145\u6ee1\u6311\u6218\uff0c\u672c\u6587\u83b7\u5f97\u4e86\u9ad8\u8d28\u91cf\u4e14\u7a33\u5b9a\u7684\u03b2-CsPbI3<\/sub>\uff0c\u540c\u6b65\u8f90\u5c04XRD\u7ed3\u679c\u8868\u660eCsPbI3<\/sub>\u6676\u7c92\u7684\u9ad8\u5ea6\u53d6\u5411\uff0c\u7535\u611f\u8026\u5408\u7b49\u79bb\u5b50\u4f53\u8d28\u8c31\u548c\u4e8c\u6b21\u79bb\u5b50\u8d28\u8c31\u4e5f\u9a8c\u8bc1\u4e86\u8584\u819c\u5168\u65e0\u673a\u6210\u5206\u7684\u7ec4\u6210\u3002\u4f5c\u8005\u8fdb\u4e00\u6b65\u901a\u8fc7\u7898\u5316\u80c6\u78b1\u5904\u7406\u9499\u949b\u77ff\u4ee5\u51cf\u5c11\u88c2\u7eb9\u548c\u5b54\u6d1e\uff0c\u63d0\u9ad8\u8584\u819c\u8d28\u91cf\uff0c\u4ece\u800c\u63d0\u9ad8\u8f7d\u6d41\u5b50\u5bff\u547d\uff0c\u57fa\u4e8e\u6b64\u5236\u5907\u5f97\u5230\u7684\u7535\u6c60\u5177\u6709\u4f18\u5f02\u7684\u53ef\u91cd\u590d\u5236\u5907\u6027\u80fd\uff0c\u5e76\u4e14\u572845 \u00b1 5\u00b0C\u7684\u5927\u6c14\u73af\u5883\u4e2d\uff0c\u5149\u7535\u8f6c\u6362\u6548\u7387\u7a33\u5b9a\u572818.4%\u3002<\/p>\n

2\uff0cThe Role of Dimethylammonium Iodine in CsPbI3<\/sub>\u00a0Perovskite Fabrication: Additive or Dopant?<\/p>\n

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\u901a\u8fc7\u5f15\u5165DMAI\u53ef\u4ee5\u6709\u6548\u7a33\u5b9a\u03b2-CsPbI3<\/sub>\uff0c\u4f5c\u8005\u9a8c\u8bc1\u4e86DMAI\u7684\u4f5c\u7528\u8fc7\u7a0b\uff0c\u4f5c\u4e3a\u4e00\u79cd\u6709\u6548\u7684\u6dfb\u52a0\u5242\uff0c\u53c2\u4e0e\u5230CsPbI3<\/sub>\u9499\u949b\u77ff\u7684\u7ed3\u6676\u8fc7\u7a0b\u4e2d\u3002\u70ed\u91cd\u5206\u6790\u7ed3\u679c\u8868\u660e\u6e7f\u5ea6\u4f1a\u5f71\u54cdDMAI\u7684\u5347\u534e\u8fc7\u7a0b\uff0c\u5408\u9002\u7684\u6c14\u6c1b\u6709\u52a9\u4e8e\u53bb\u9664\u8584\u819c\u4e2d\u7684DMAI\uff0c\u4e8c\u6b21\u79bb\u5b50\u8d28\u8c31\u548c\u6838\u78c1\u5171\u632f\u8c31\u7ed3\u679c\u5747\u8868\u660eDMAI\u5e76\u4e0d\u4f1a\u8fdb\u5165CsPbI3<\/sub>\u7684\u6676\u683c\u4e2d\uff0c\u4e14\u9499\u949b\u77ff\u4e2d\u5982\u679c\u6709\u5269\u4f59\u7684DMAI\uff0c\u4e0d\u5229\u4e8e\u7535\u6c60\u7684\u5149\u7535\u6027\u80fd\u548c\u7a33\u5b9a\u6027\u80fd\u3002\u901a\u8fc7PTA-Cl\u949d\u5316\u7684\u9499\u949b\u77ff\u8584\u819c\u7ec4\u88c5\u7535\u6c60\u540e\uff0c\u83b7\u5f97\u4e8619.03%\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\u3002<\/p>\n

\u4e09\u3001\u6e38\u7ecf\u78a7\u8bfe\u9898\u7ec4<\/b><\/strong><\/p>\n

\u7b80\u4ecb\uff1a\u6e38\u7ecf\u78a7\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u534a\u5bfc\u4f53\u7814\u7a76\u6240\u7814\u7a76\u5458\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u6770\u9752\u57fa\u91d1\u83b7\u5f97\u8005<\/b><\/strong>\u3002\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u4e3a\uff1a1\uff09\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u53ca\u5149\u7535\u5668\u4ef6\uff1b2\uff09\u9499\u949b\u77ff\u53d1\u5149\u4e8c\u6781\u7ba1\u3002\u8fd1\u5e74\u6765\uff0c\u53d1\u8868\u5b66\u672f\u8bba\u658779\u7bc7\uff0c\u901a\u8baf\/\u7b2c\u4e00\u4f5c\u8005Nature\u7cfb\u5217\u7814\u7a76\u8bba\u658710\u7bc7\uff0c\u5176\u4e2d1\u7bc7\u5f15\u7528\u8d85\u8fc72000\u6b21\uff0c\u5168\u90e8\u8bba\u6587\u603b\u5171\u88abSCI\u5f15\u752816000\u4f59\u6b21\u3002<\/p>\n

\u65e0\u673a\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u4ee3\u8868\u4f5c\uff1a<\/p>\n

1\uff0cSolvent-controlled growth of inorganic perovskite films in dry environment for efficient and stable solar cells<\/p>\n

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CsPbI3<\/sub>\u7684\u03b1\u76f8\u7531\u4e8e\u70ed\u529b\u5b66\u4e0d\u7a33\u5b9a\uff0c\u56e0\u6b64\u5728\u5ba4\u6e29\u96be\u4ee5\u5236\u5907\u7ec4\u88c5\u7535\u6c60\u3002\u4f5c\u8005\u901a\u8fc7\u5728\u5e72\u71e5\u73af\u5883\u4e2d\u63a7\u5236\u6eb6\u5242\u6325\u53d1\u8fc7\u7a0b\uff0c\u83b7\u5f97\u5ba4\u6e29\u7a33\u5b9a\u7684\u03b1\u76f8\u3002\u57fa\u4e8e\u8be5\u4f53\u7cfb\u7684\u7535\u6c60\u83b7\u5f97\u4e8615.7%\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\uff0c\u4e14\u5728\u5149\u7167\u7a33\u5b9a\u6027\u6d4b\u8bd5\u4e2d\uff0c\u7535\u6c60\u5728\u8d85\u8fc7500 h\u5149\u7167\u540e\u6548\u7387\u6ca1\u6709\u8870\u51cf\uff0c\u5c55\u793a\u51fa\u4f18\u5f02\u7684\u7a33\u5b9a\u6027\u80fd\u3002<\/p>\n

2\uff0cCesium lead inorganic solar cell with efficiency beyond 18% via reduced charge recombination<\/p>\n

\"\"<\/p>\n

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\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n

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