{"id":213530,"date":"2020-12-04T06:54:58","date_gmt":"2020-12-03T22:54:58","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=213530"},"modified":"2020-12-03T19:52:47","modified_gmt":"2020-12-03T11:52:47","slug":"%e8%b7%9f%e7%9d%80%e9%a1%b6%e5%88%8a%e5%ad%a6%e6%b5%8b%e8%af%95%ef%bd%9cclare-p-grey%e9%94%82%e7%a6%bb%e5%ad%90%e7%94%b5%e6%b1%a0jacs%ef%bc%9a%e5%9f%ba%e4%ba%8e%e5%a4%9a%e7%a7%8dnmr%e6%8a%80%e6%9c%af","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=213530","title":{"rendered":"\u8ddf\u7740\u9876\u520a\u5b66\u6d4b\u8bd5\uff5cClare P. Grey\u9502\u79bb\u5b50\u7535\u6c60JACS\uff1a\u57fa\u4e8e\u591a\u79cdNMR\u6280\u672f\u5206\u6790\u56fa\u6001\u7535\u89e3\u8d28\u754c\u9762\u7ec4\u6210"},"content":{"rendered":"<p><strong><b>\u5f15\u8a00<\/b><\/strong><\/p>\n<p>\u5728\u7535\u6781\u8868\u9762\u5f62\u6210\u56fa\u6001\u7535\u89e3\u8d28\u754c\u9762\uff08SEI\uff09\u5bf9\u4e8e\u9502\u79bb\u5b50\u7535\u6c60\u5faa\u73af\u5bff\u547d\u6765\u8bf4\u81f3\u5173\u91cd\u8981\u3002\u5982\u679c\u6ca1\u6709SEI\uff0c\u4f1a\u4f7f\u5f97\u9502\u6e90\u88ab\u4e0d\u65ad\u6d88\u8017\u4ece\u800c\u5bfc\u81f4\u5bb9\u91cf\u8870\u51cf\u3002\u7279\u522b\u662f\u5bf9\u4e8e\u7845\u8d1f\u6781\u6765\u8bf4\uff0c\u7535\u6781\u7684\u8131\u5d4c\u9502\u73b0\u8c61\u4f34\u968f\u7740\u5de8\u5927\u7684\u4f53\u79ef\u81a8\u80c0\uff0c\u4f7f\u65b0\u9c9c\u7845\u8868\u9762\u4e0d\u65ad\u66b4\u9732\uff0c\u5bfc\u81f4SEI\u751f\u957f\u5931\u63a7\u548c\u5faa\u73af\u6027\u80fd\u4e0b\u964d\u3002\u4e3a\u4e86\u5b9e\u73b0\u7845\u4e0aSEI\u7684\u7a33\u5b9a\u5316\uff0c\u4ee5\u6c1f\u4ee3\u4e59\u70ef\u78b3\u9178\u916f\uff08FEC\uff09\u4e3a\u4ee3\u8868\u7684\u6709\u673a\u7269\u5e38\u5e38\u88ab\u4f5c\u4e3a\u727a\u7272\u6027\u7684\u7535\u89e3\u8d28\u6dfb\u52a0\u5242\uff0c\u4ee5\u671f\u63d0\u5347\u7845\u7684\u5bb9\u91cf\u4fdd\u7559\u7387\u3002\u7136\u800c\uff0c\u7531\u4e8e\u8868\u5f81\u65e0\u5e8f\u754c\u9762\u7ed3\u6784\u7684\u96be\u5ea6\u5f88\u5927\uff0c\u8fd9\u4e9b\u6dfb\u52a0\u5242\u6539\u6027SEI\u7684\u673a\u5236\u76ee\u524d\u4ecd\u7136\u4e0d\u662f\u5341\u5206\u6e05\u695a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-213531 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-1-23.png\" alt=\"\" width=\"600\" height=\"206\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-1-23.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-1-23-300x103.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u4e3a\u4e86\u9610\u91caFEC\u5728\u9502\u79bb\u5b50\u7535\u6c60\u4e2d\u4f5c\u4e3a\u6dfb\u52a0\u5242\u7684\u4f5c\u7528\uff0c<strong><b>\u5251\u6865\u5927\u5b66\u7684<\/b><\/strong><strong><b>Clare P. Grey<\/b><\/strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u5c06\u6eb6\u6db2\u548c\u56fa\u6001\u6838\u78c1\u5171\u632f\uff08NMR\uff09\u6280\u672f\u7ed3\u5408\u8d77\u6765\uff0c\u8868\u5f81\u5206\u6790\u4e86\u7845\u7eb3\u7c73\u7ebfSEI\u4e2d\u53ef\u6eb6\/\u4e0d\u53ef\u6eb6FEC\u5206\u89e3\u4ea7\u7269\u7684\u5f62\u6210\u8fc7\u7a0b\u3002\u4e3a\u4e86\u63d0\u9ad8NMR\u7684\u68c0\u6d4b\u7075\u654f\u5ea6\uff0c\u7814\u7a76\u4eba\u5458\u8fd8\u5408\u6210\u4e86\u6807\u8bb0\u5904\u7406\u7684<sup>13<\/sup>C<sub>3<\/sub>-FEC\uff0c\u540c\u65f6\u5229\u7528\u52a8\u6001\u6838\u6781\u5316\uff08DNP\uff09\u589e\u5f3a\u6765\u5b9e\u73b0\u56fa\u6001NMR\uff0c\u4ee5\u4fbf\u66f4\u52a0\u5168\u9762\u5730\u4e86\u89e3\u6709\u673aSEI\u3002\u7ed3\u679c\u663e\u793a\uff0c\u53ef\u6eb6\/\u4e0d\u53ef\u6eb6SEI\u4ea7\u7269\u4e2d\u5747\u6709\u6570\u79cd\u4e2d\u95f4\u7269\u5f62\u6210\uff0c\u8868\u660eFEC\u7684\u52a0\u5165\u53ef\u80fd\u662fSEI\u7a33\u5b9a\u6027\u589e\u5f3a\u7684\u4e3b\u8981\u539f\u56e0\u3002\u8be5\u6210\u679c\u4ee5\u201c<strong><b>Identifying the Structural Basis for the Increased Stability of the Solid Electrolyte Interphase Formed on Silicon with the Additive Fluoroethylene Carbonate<\/b><\/strong>\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u4e8e<strong><b>Journal of the American Chemical Society<\/b><\/strong>\u3002<\/p>\n<p><strong><b>\u6eb6\u6db2NMR\u68c0\u6d4b\u53ef\u6eb6\u964d\u89e3\u4ea7\u7269<\/b><\/strong><\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-213535 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-5-15.png\" alt=\"\" width=\"381\" height=\"175\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-5-15.png 381w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-5-15-300x138.png 300w\" sizes=\"(max-width: 381px) 100vw, 381px\" \/><\/b><\/strong><\/p>\n<p style=\"text-align: center;\"><strong><b>\u88681 <\/b><\/strong>\u6570\u79cd\u7535\u89e3\u8d28\u7ec4\u5206<\/p>\n<p>\u5982\u88681\u6240\u793a\uff0c\u8be5\u5de5\u4f5c\u9009\u62e9\u4e86\u591a\u79cd\u7535\u89e3\u8d28\u8fdb\u884c\u7814\u7a76\u3002\u4e3a\u4e86\u5206\u6790\u53ef\u6eb6\u4ea7\u7269\uff0c\u65b0\u9c9c\u7535\u89e3\u8d28\u3001\u5faa\u73af\u4e00\u5708\u548c\u5faa\u73af30\u5708\u4e4b\u540e\u7684\u7535\u89e3\u8d28\u5c06\u5229\u7528\u6eb6\u6db2\u6838\u78c1\u6c22\u8c31\u5206\u522b\u8fdb\u884c\u68c0\u6d4b\u6bd4\u8f83\u3002\u5982\u56fe1\u6240\u793a\uff0c\u4e0eLP30\u7535\u89e3\u8d28\u76f8\u6bd4\uff0c\u542bFEC\u7684\u6837\u54c1\u57283-5ppm\u5316\u5b66\u4f4d\u79fb\u8303\u56f4\u5185\u6ca1\u6709\u51fa\u73b0\u6838\u78c1\u5171\u632f\u4fe1\u53f7\uff0c\u8868\u660e\u542bFEC\u7684\u6837\u54c1\u51fa\u73b0\u4e86\u4e0d\u540c\u7684\u5206\u89e3\u4ea7\u7269\u3002\u800c\u5728LP30\u4e2d\uff0c\u5316\u5b66\u4f4d\u79fb4.3ppm\u5904\u7684\u5f3a\u4fe1\u53f7\u88ab\u5f52\u5c5e\u4e8e\u9502\u4e59\u70ef\u78b3\u9178\u6c22\u94a0\uff08LEDC\uff09\u3002LEDC\u662f\u78b3\u9178\u4e59\u70ef\u916f\uff08EC\uff09\u7684\u5206\u89e3\u4ea7\u7269\uff1b\u7136\u800c\u7ecf\u8fc730\u6b21\u5faa\u73af\u540e\uff0cLEDC\u5219\u4f1a\u6d88\u5931\uff0c\u8bf4\u660eLEDC\u662f\u4e00\u79cd\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u4f1a\u8fdb\u4e00\u6b65\u5206\u89e3\u7684\u4e9a\u7a33\u6001\u5316\u5b66\u79cd\u3002\u5982\u56fe1b\u548c1c\u8fdb\u4e00\u6b65\u5bf9\u6bd4\u53d1\u73b0\uff0c\u542bFEC\u7684LP30\u6837\u54c1\u5206\u522b\u57289.5-9.7ppm\u30017.77ppm\u4ee5\u53ca5.0-6.2ppm\u5904\u51fa\u73b0\u4e86\u4e09\u91cd\u5cf0\u3001\u5355\u5cf0\u548c\u591a\u91cd\u5cf0\u7c07\uff0c\u800c\u4e0d\u542bFEC\u7684LP30\u6837\u54c1\u53ea\u57288.42ppm\u5904\u51fa\u73b0\u5355\u5cf0\uff0c\u8868\u660eFEC\u7684\u52a0\u5165\u80fd\u591f\u5f62\u6210\u4e0d\u540c\u7684\u5316\u5408\u7269\u3002\u4e0d\u4ec5\u5982\u6b64\uff0c\u901a\u8fc7\u6bd4\u8f833-5ppm\u7684\u5cf0\u5f3a\u53ef\u4ee5\u5f97\u77e5\uff0cLP30\u7535\u89e3\u8d28\u4e2d\u4ea7\u751f\u4e86\u975e\u5e38\u53ef\u89c2\u7684\u53ef\u6eb6\u6027\u4f4e\u805a\u7269\uff0c\u800c\u542bFEC\u6837\u54c1\u7684\u5cf0\u5f3a\u5219\u5f31\u5f97\u591a\uff0c\u8868\u660eFEC\u7684\u5b58\u5728\u5bfc\u81f4\u53ef\u6eb6\u6027SEI\u5f62\u6210\u8f83\u5c11\u3002<\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-213532 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-2-14.png\" alt=\"\" width=\"600\" height=\"494\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-2-14.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-2-14-300x247.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p style=\"text-align: center;\"><strong><b>\u56fe1<\/b><\/strong>\u00a0\u4e0d\u540c\u7535\u89e3\u8d28\u7684\u6eb6\u6db2\u6838\u78c1\u6c22\u8c31\u8868\u5f81<\/p>\n<p>\u5728\u56fe1\u4e2d\u542bFEC\u7684LP30\u8fd8\u53d1\u73b0\u4e86\u88ab\u5f52\u5c5e\u4e8e\u7531\u6570\u79cd\u7ebf\u6027\u805a\u73af\u6c27\u4e59\u70f7\uff08PEO\uff09\u7ec4\u6210\u7684\u4f4e\u805a\u7269\uff08\u56fe1a\u4e2d\u7684a-d\u4fe1\u53f7\u5cf0\uff09\u3002\u4e3a\u4e86\u8fdb\u4e00\u6b65\u5206\u6790\u8fd9\u4e9b\u4f4e\u805a\u7269\u7684\u5f52\u5c5e\uff0c\u4f5c\u8005\u8fdb\u884c\u4e86\u4e8c\u7ef4\u76f8\u5173NMR\u8c31\u5b66\u5b9e\u9a8c\u3002\u56fe2\u7684\u5f02\u6838\u5355\u91cf\u5b50\u76f8\u5173\u8c31\uff08HSQC\uff09\u663e\u793a\uff0cLP30 + <sup>13<\/sup>C<sub>3<\/sub>-FEC\u6837\u54c1\u57286.07\u30015.88\u30015.78\u30015.20ppm\uff08z1\u3001z2\u3001z3\u3001z4\uff09\u5904\u5c55\u73b0\u51fa\u4e86\u591a\u91cd\u5cf0\u7279\u5f81\u3002\u5176\u4e2d\u6c22\u6838\u5171\u632fz1\u3001z2\u4e0e99.1\u3001100.6ppm\u5904\u7684\u78b3\u6838\u5171\u632f\u5206\u522b\u76f8\u5173\u8054\uff0c\u8fd9\u4e9b\u5171\u632f\u5747\u53ef\u4ee5\u88ab\u8ba4\u4e3a\u662f\u5177\u6709\u4e24\u4e2a\u6c27\u57fa\u56e2\u7684\u8d28\u5b50\u5316\u78b3\u3002\u800c\u6839\u636e<sup>13<\/sup>C-<sup>13<\/sup>C\u76f8\u5173\u8c31\uff08COSY\uff09\uff0c100.3\u548c98.8ppm\u5904\u7684\u679d\u72b6\u78b3\u76f4\u63a5\u4e0e70.2ppm\u5904\u7684\u73af\u6c27\u4e59\u70f7\u78b3\u76f8\u8fde\u3002\u7efc\u5408HSQC\u548cCOSY\u53ef\u77e5\uff0c\u4f4e\u805a\u7269\u4e2d\u7684\u7ed3\u6784\u6a21\u5757\u4e3aROCH<sub>2<\/sub>CH(OR)<sub>2<\/sub>\uff0c\u8868\u660e\u542bFEC\u7535\u89e3\u8d28\u4e2d\u5728\u6301\u7eed\u5faa\u73af\u8fc7\u7a0b\u4e2d\u5f62\u6210\u4e86\u679d\u72b6\u4f4e\u805a\u7269\u3002\u540c\u7406\uff0c\u5bf9z3\u548cz4\u8fdb\u884c\u5f52\u5c5e\u5206\u6790\u53ef\u77e5\uff0c\u5faa\u73af\u8fc7\u7a0b\u4e2d\u8fd8\u51fa\u73b0\u4e86ROCOOCH(CH2OR\u2019)<sub>2<\/sub>\u4ee5\u53cavinoxyl\u5316\u5408\u7269\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-213533 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-3-18.png\" alt=\"\" width=\"347\" height=\"529\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-3-18.png 347w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-3-18-197x300.png 197w\" sizes=\"(max-width: 347px) 100vw, 347px\" \/><\/p>\n<p style=\"text-align: center;\"><strong><b>\u56fe2<\/b><\/strong>\u00a02D\u6eb6\u6db2NMR\u56fe\u8c31<\/p>\n<p>\u9664\u4e86\u8868\u5f81\u53ef\u6eb6\u6027\u5206\u89e3\u4ea7\u7269\u4ee5\u5916\uff0c\u6587\u7ae0\u8fd8\u5229\u7528\u56fa\u6001NMR\u548cDNP NMR\u8c31\u5b66\u65b9\u6cd5\u8868\u5f81\u4e86SEI\u4e2d\u7684\u4e0d\u53ef\u6eb6\u7269\u8d28\u3002\u4f5c\u8005\u5c06\u7ecf\u8fc7\u5faa\u73af\u7684\u7845\u7eb3\u7c73\u7ebf\u8fdb\u884c\u771f\u7a7a\u5e72\u71e5\u5904\u7406\uff0c\u518d\u5229\u7528<sup>1<\/sup>H\u2212<sup>13<\/sup>C\u4ea4\u53c9\u6781\u5316\uff08CP\uff09NMR\u65b9\u6cd5\u5bf9\u56fa\u6001NMR\u5f97\u5230\u7684\u8c31\u5b66\u6570\u636e\u8fdb\u884c\u6bd4\u8f83\u3002\u5982\u56fe3\u6240\u793a\uff0c\u9664\u4e86\u6eb6\u5242\u5cf0\u4ee5\u5916\uff0c\u5229\u7528\u56fa\u6001NMR\u548cDNP NMR\u5f97\u5230\u7684\u8c31\u56fe\u5e76\u6ca1\u6709\u5dee\u5f02\uff0c\u8868\u660e\u5177\u6709\u53cc\u6e38\u79bb\u57fa\u56e2\u7684\u6eb6\u6db2\u4e0d\u4f1a\u6539\u53d8SEI\u7684\u5316\u5b66\u7ed3\u6784\u3002\u5982\u56fe3a\uff0c\u542b25%\uff08\u4f53\u79ef\u5206\u6570\uff09EC\u7684\u6837\u54c1\uff08LP30 + <sup>13<\/sup>C<sub>3<\/sub>-EC\uff09\u572868ppm\u5904\u6709\u4e00\u4e2a\u5bbd\u5cf0\uff0c\u540c\u65f661ppm\u5904\u6709\u4e00\u4e2a\u80a9\u5cf0\u3002\u800c\u5728DNP NMR\u4e2d61ppm\u5904\u7684\u5cf0\u53d8\u5f97\u66f4\u4e3a\u5c16\u9510\uff0c\u8868\u660e\u6709\u673aSEI\u7269\u8d28\u7684\u52a8\u529b\u5b66\u5728\u4f4e\u6e29\u4e0b\u51cf\u6162\u4e86\u3002\u6b64\u5916\uff0c\u8102\u80aa\u65cf\u78b3\u5cf0\u5f3a\u5728\u56fa\u6001\u548cDNP NMR\u90fd\u663e\u5f97\u975e\u5e38\u5f31\uff0c\u63a8\u6d4b\u5f62\u6210\u7684SEI\u4e3b\u8981\u7531\u53ea\u542b\u6709\u5c11\u91cf\u8102\u80aa\u65cf\u5355\u5143\u7684PEO\u7ec4\u6210\u3002\u800c\u5bf9\u4e8eLP30 + <sup>13<\/sup>C<sub>3<\/sub>-FEC\uff08\u56fe3b\uff09\u6837\u54c1\u6765\u8bf4\uff0c68ppm\u7684\u5cf0\u5f62\u66f4\u52a0\u5c16\u9510\uff0c\u800c61ppm\u5904\u7684\u5355\u5cf0\u53ef\u80fd\u4e0e68ppm\u5904\u53d1\u751f\u4e86\u91cd\u53e0\uff0c\u8bf4\u660e\u6837\u54c1\u4e2d\u8fd8\u6709EC\u6b8b\u7559\u3002\u800cDNP NMR\u768468ppm\u5904\u5cf0\u5f62\u53d8\u5bbd\uff0c\u4e5f\u8868\u660e\u6837\u54c1\u5f02\u8d28\u6027\u66f4\u9ad8\uff0c\u4ece\u800c\u5bfc\u81f4\u4e86\u66f4\u52a0\u5bbd\u6cdb\u7684\u5316\u5b66\u4f4d\u79fb\u5206\u5e03\u3002<\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-213534 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-4-15.png\" alt=\"\" width=\"455\" height=\"455\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-4-15.png 455w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-4-15-150x150.png 150w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-4-15-300x300.png 300w\" sizes=\"(max-width: 455px) 100vw, 455px\" \/><\/b><\/strong><\/p>\n<p style=\"text-align: center;\"><strong><b>\u56fe3<\/b><\/strong>\u00a0\u7845\u7eb3\u7c73\u7ebf\u7684<sup>1<\/sup>H\u2212<sup>13<\/sup>C\u00a0CP NMR\u8c31<\/p>\n<p><strong><b>\u7ed3\u8bed<\/b><\/strong><\/p>\n<p>\u8fd9\u9879\u5de5\u4f5c\u5229\u7528NMR\u6280\u672f\u8868\u5f81\u4e86\u7845\u7eb3\u7c73\u7ebf\u4e0aSEI\u4e2d\u7684\u6709\u673a\u7269\u8d28\uff0c\u4ee5\u4e86\u89e3FEC\u4f5c\u4e3a\u7535\u89e3\u8d28\u6dfb\u52a0\u5242\u5728\u63d0\u5347\u9502\u79bb\u5b50\u7535\u6c60\u6027\u80fd\u65b9\u9762\u7684\u4f5c\u7528\u3002\u7814\u7a76\u8868\u660e\uff0c\u6807\u51c6EC\/DMC\u7535\u89e3\u8d28\u4f1a\u5728\u957f\u671f\u5faa\u73af\u8fc7\u7a0b\u4e2d\u5206\u89e3\u5e76\u5f62\u6210\u4e00\u7cfb\u5217\u53ef\u6eb6\u6027\u4f4e\u805a\u7269\uff1b\u800cFEC\u7684\u52a0\u5165\u80fd\u591f\u5f62\u6210\u7a33\u5b9a\u7684SEI\u5e76\u4e14\u6291\u5236EC\/DMC\u7684\u5206\u89e3\uff0c\u4ece\u800c\u63d0\u5347\u521d\u59cb\u5faa\u73af\u8fc7\u7a0b\u7684\u5e93\u4ed1\u6548\u7387\u3002\u6b64\u5916\uff0cFEC\u7684\u964d\u89e3\u4ea7\u7269\u53ef\u4ee5\u589e\u52a0\u4ea4\u8054\u6a21\u5757\u7684\u6570\u91cf\u3002\u800c\u7814\u7a76\u4e5f\u8ba4\u4e3a\u8fd9\u4e00\u4ea4\u8054\u805a\u5408\u7269\u7684\u5f62\u6210\u662f\u7a33\u5b9aSEI\u7684\u5173\u952e\u3002\u8fd9\u4e00\u89c2\u70b9\u4e0d\u4ec5\u80fd\u591f\u63a8\u52a8\u7535\u89e3\u8d28\u6dfb\u52a0\u5242\u7684\u7814\u7a76\uff0c\u8fd8\u4e3a\u8bbe\u8ba1\u6709\u5229\u4e8e\u6539\u5584\u9502\u79bb\u5b50\u7535\u6c60\u6027\u80fd\u7684SEI\u5316\u5b66\u63d0\u4f9b\u4e86\u601d\u8def\u3002<\/p>\n<p><strong><b>\u53c2\u8003\u6587\u732e\uff1a<\/b><\/strong>Identifying the Structural Basis for the Increased Stability of the Solid\u00a0Electrolyte Interphase Formed on Silicon with the Additive\u00a0Fluoroethylene Carbonate<\/p>\n<p><strong><b>\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.7b06834<\/p>\n<p>\u672c\u6587\u7531nanoCJ\u4f9b\u7a3f\u3002<\/p>\n<p>\u672c\u5185\u5bb9\u4e3a\u4f5c\u8005\u72ec\u7acb\u89c2\u70b9\uff0c\u4e0d\u4ee3\u8868\u6750\u6599\u4eba\u7f51\u7acb\u573a\u3002<\/p>\n<p>\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u5f15\u8a00 \u5728\u7535\u6781\u8868\u9762\u5f62\u6210\u56fa\u6001\u7535\u89e3\u8d28\u754c\u9762\uff08SEI\uff09\u5bf9\u4e8e\u9502\u79bb\u5b50\u7535\u6c60\u5faa\u73af\u5bff\u547d\u6765\u8bf4\u81f3\u5173\u91cd\u8981\u3002\u5982\u679c\u6ca1\u6709SEI\uff0c\u4f1a\u4f7f\u5f97\u9502\u6e90\u88ab\u4e0d\u65ad\u6d88\u8017\u4ece\u800c\u5bfc\u81f4\u5bb9\u91cf\u8870\u51cf\u3002\u7279\u522b\u662f\u5bf9\u4e8e\u7845\u8d1f\u6781\u6765\u8bf4\uff0c\u7535\u6781&#8230;<\/p>\n","protected":false},"author":11454,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-213530","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/213530"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=213530"}],"version-history":[{"count":2,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/213530\/revisions"}],"predecessor-version":[{"id":213537,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/213530\/revisions\/213537"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=213530"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=213530"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=213530"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}