{"id":213796,"date":"2020-11-30T06:02:59","date_gmt":"2020-11-29T22:02:59","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=213796"},"modified":"2020-11-29T22:03:37","modified_gmt":"2020-11-29T14:03:37","slug":"%e5%8d%97%e5%b7%a5%e5%a4%a7-nano-letters%ef%bc%9a%e8%b6%85%e5%bf%ab%e5%be%ae%e6%b3%a2%e6%b4%bb%e5%8c%96%e6%9e%81%e5%8c%96%e7%94%b5%e5%ad%90%e5%88%b6%e5%a4%87%e5%a4%9a%e5%ad%94%e9%93%9d%e7%ae%94","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=213796","title":{"rendered":"\u5357\u5de5\u5927 Nano Letters\uff1a\u8d85\u5feb\u5fae\u6ce2\u6d3b\u5316\u6781\u5316\u7535\u5b50\u5236\u5907\u591a\u5b54\u94dd\u7b94\u52a9\u529b\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7535\u6c60"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u56fa\u4f53\u6750\u6599\u8868\u9762\u7684\u5408\u7406\u8bbe\u8ba1\u63a8\u52a8\u4e86\u7535\u5b50\u3001\u50ac\u5316\u3001\u80fd\u6e90\u548c\u751f\u7269\u7b49\u76f8\u5173\u7814\u7a76\u548c\u5de5\u4e1a\u6280\u672f\u7684\u5de8\u5927\u8fdb\u6b65\u3002\u4f46\u662f\uff0c\u6c89\u79ef\u3001\u76f8\u53d8\u7b49\u4f20\u7edf\u7684\u8868\u9762\u6280\u672f\u4f9d\u8d56\u4e8e\u590d\u6742\u7684\u7a0b\u5e8f\u548c\u8bbe\u5907\u3002\u8fd1\u5e74\u6765\uff0c\u7814\u7a76\u8005\u5229\u7528\u65b0\u5174\u7684\u7eb3\u7c73\u6280\u672f\uff0c\u5b9e\u73b0\u529f\u80fd\u5316\u8868\u754c\u9762\u7684\u7cbe\u786e\u8c03\u63a7\u53ca\u4fee\u9970\uff0c\u6210\u529f\u5e94\u7528\u4e8e\u4f4e\u7ef4\u7eb3\u7c73\u6750\u6599\u3001\u91cf\u5b50\u70b9\u4ee5\u53ca\u539f\u5b50\u7ea7\u5206\u6563\u7684\u754c\u9762\uff0c\u5305\u62ec\u901a\u8fc7\u6539\u53d8\u8868\u9762\u7ec4\u5206\u5b9e\u73b0\u76ee\u6807\u529f\u80fd\uff0c\u4ee5\u53ca\u501f\u52a9\u8c03\u63a7\u8868\u9762\u5f62\u8c8c\u4f18\u5316\u754c\u9762\u7279\u6027\u3002\u7136\u800c\uff0c\u91d1\u5c5e\u8868\u9762\u7684\u591a\u5b54\u7ed3\u6784\u6784\u7b51\u4ecd\u53d7\u9650\u4e8e\u9ad8\u6e29\u70e7\u7ed3\u6216\u6210\u672c\u6602\u8d35\u7684\u6280\u672f\u624b\u6bb5\uff08\u59823D\u6253\u5370\uff09\u3002\u6b64\u5916\uff0c\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\u8fd8\u9762\u4e34\u64cd\u4f5c\u96be\u5ea6\u9ad8\u3001\u89c4\u6a21\u5316\u5236\u5907\u7b49\u6311\u6218\u3002\u56e0\u6b64\uff0c\u4e9f\u5f85\u5f00\u53d1\u4e00\u79cd\u6709\u6548\u3001\u53ef\u63a7\u3001\u4f4e\u6210\u672c\u7684\u65b9\u6cd5\u4f18\u5316\u91d1\u5c5e\u7684\u52a0\u5de5\u4e0e\u4fee\u9970\uff0c\u4ece\u800c\u8fdb\u4e00\u6b65\u62d3\u5c55\u5176\u529f\u80fd\u4e0e\u5e94\u7528\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5357\u4eac\u5de5\u4e1a\u5927\u5b66\u5148\u8fdb\u6750\u6599\u7814\u7a76\u9662\u9ec4\u7ef4\u9662\u58eb\u3001\u6731\u7eaa\u6b23\u6559\u6388\u548c\u82ae\u7428\u526f\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba<\/strong>\u62a5\u9053\u4e86\u57fa\u4e8eFe(NO3<\/sub>)3<\/sub>\u8bf1\u5bfc\u6c27\u5316\u523b\u8680\uff0c\u8d85\u5feb\u901f\u3001\u5927\u89c4\u6a21\u5236\u5907\u5177\u6709\u591a\u5b54\u7ed3\u6784\u7684\u94dd\u7b94\u3002\u5229\u7528\u5fae\u6ce2\u76f8\u4e92\u4f5c\u7528\u7684\u6709\u6548\u7535\u5b50\u6781\u5316\u8026\u5408\uff0c\u5728\u51e0\u5206\u949f\u5185\u5c31\u53ef\u4ee5\u5728\u5404\u79cd\u5546\u4e1a\u5316\u94dd\u7b94\u4e0a\u5b9e\u73b0\u76f4\u63a5\u7684\u8868\u9762\u4fee\u9970\uff0c\u5e76\u4e14\u6210\u529f\u5730\u5c06\u5176\u6269\u5c55\u5230\u5757\u72b6\u94dd\u5408\u91d1\u4e0a\u3002\u4f5c\u4e3a\u5e94\u7528\u5c55\u793a\uff0c\u5c06\u5177\u6709\u53ef\u8c03\u8868\u9762\u80fd\u7684\u591a\u5b54\u94dd\u7b94\u4f5c\u4e3a\u7535\u6c60\u96c6\u6d41\u4f53\uff0c\u5728\u63d0\u9ad8\u5faa\u73af\u7a33\u5b9a\u6027\u548c\u80fd\u91cf\u5bc6\u5ea6\u65b9\u9762\u663e\u793a\u51fa\u5de8\u5927\u7684\u5e94\u7528\u6f5c\u529b\u3002\u57fa\u4e8e\u6b64\u6784\u5efa\u7684LiFePO4<\/sub>-Li\u7535\u6c60\u5728550\u6b21\u5faa\u73af\u540e\uff0c\u53ef\u9006\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a85.2\uff05\uff08\u4e0e\u5546\u7528Al\/C\u94dd\u7b94\u76f8\u5f53\uff09\uff0c\u800c\u80fd\u91cf\u5bc6\u5ea6\u7ea6\u662f\u57fa\u4e8e\u539f\u59cb\u94dd\u7b94\u7684LiFePO4<\/sub>-Li\u7535\u6c60\u76843\u500d\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cUltrafast Microwave Activating Polarized Electron for Scalable Porous Al toward High-Energy-Density Batteries\u201d<\/strong>\u53d1\u8868\u5728\u56fd\u9645\u8457\u540d\u671f\u520aNano Letters<\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\u3001\u591a\u5b54\u94dd\u7b94\u7684\u5236\u5907\u793a\u610f\u56fe\u53ca\u5176SEM\u56fe<\/strong>
\n \"\"\uff08a\uff09\u5fae\u6ce2\u8bf1\u5bfc\u5236\u5907\u591a\u5b54\u94dd\u7b94\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b, f\uff09\u539f\u59cbAl\u7684\u8868\u9762\u548c\u6a2a\u622a\u9762SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08c, g\uff09\u591a\u5b54\u94dd\u7b94Al-MW10\u7684\u8868\u9762\u548c\u6a2a\u622a\u9762SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08d, h\uff09\u591a\u5b54\u94dd\u7b94Al-MW20\u7684\u8868\u9762\u548c\u6a2a\u622a\u9762SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08e, i\uff09\u591a\u5b54\u94dd\u7b94Al-MW30\u7684\u8868\u9762\u548c\u6a2a\u622a\u9762SEM\u56fe\u50cf\u3002<\/p>\n

\u56fe\u4e8c\u3001\u6d53\u5ea6\u548c\u4e0d\u540c\u524d\u4f53\u5bf9\u94dd\u7b94\u8868\u9762\u7684\u5f71\u54cd<\/strong>
\n \"\"\uff08a-d\uff09\u7531\u4e0d\u540c\u6d53\u5ea6\u7684Fe(NO3<\/sub>)3<\/sub>\u5236\u5907\u7684Al\u7b94\u7684SEM\u56fe\uff1a25 mM\u30012.5 mM\u300112.5 mM\u3001125 mM\uff1b<\/p>\n

\uff08e-h\uff09pH=1.29\u7684\u4e0d\u540c\u524d\u4f53\u6eb6\u6db2\u5236\u5907\u7684Al\u7b94\u7684SEM\u56fe\u50cf\uff1aCo(NO3<\/sub>)2<\/sub>\u3001Ni(NO3<\/sub>)2<\/sub>\u3001HNO3<\/sub>\u3001FeCl3<\/sub>\u3002<\/p>\n

\u56fe\u4e09\u3001\u5fae\u6ce2\u7167\u5c04\u5bf9\u591a\u79cd\u94dd\u57fa\u8868\u9762\u7684\u5f71\u54cd<\/strong>
\n \"\"\uff08a, c, e, g, i\uff09\u539f\u59cb\u5408\u91d1Al\/Mn\u3001Al\/Mg\u3001Al\/Si\u3001Al\/C\u548cAl\/PP\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08b, d, f, h, j\uff09\u572825 mM Fe(NO3<\/sub>)3<\/sub>\u4e0b\u5fae\u6ce2\u5904\u7406\u540e\u7684\u5408\u91d1Al\/Mn\u3001Al\/Mg\u3001Al\/Si\u3001Al\/C\u548cAl\/PP\u7684SEM\u56fe\u50cf \u3002<\/p>\n

\u56fe\u56db\u3001\u4e0d\u540c\u5fae\u6ce2\u7167\u5c04\u65f6\u95f4\u5bf9\u94dd\u7b94\u6027\u8d28\u7684\u5f71\u54cd<\/strong>
\n \"\"\uff08a-b\uff09\u539a\u5ea6\u3001\u8d28\u91cf\u4e0e\u5fae\u6ce2\u65f6\u95f4\u7684\u5173\u7cfb\uff0c\u7ebf\u6027\u62df\u5408\u7528\u4e8e\u4f30\u8ba1\u4e0d\u540c\u5fae\u6ce2\u65f6\u95f4\u540e\u94dd\u7b94\u7684\u539a\u5ea6\u548c\u8d28\u91cf\uff1b<\/p>\n

\uff08c-d\uff09\u5e94\u529b\u548c\u7535\u963b\u7387\u968f\u5fae\u6ce2\u65f6\u95f4\u7684\u53d8\u5316\uff1b<\/p>\n

\uff08e-f\uff09H2<\/sub>O\u548cNMP\u5728Al\u3001Al-MW10\u3001Al-MW20\u548cAl-MW30\u8868\u9762\u7684\u6da6\u6e7f\u6027\uff1b<\/p>\n

\uff08g\uff09Al\u3001Al-MW10\u3001Al-MW20\u548cAl-MW30\u76842D\/3D AFM\u56fe\u50cf\u3002<\/p>\n

\u56fe\u4e94\u3001\u57fa\u4e8e\u4e0d\u540c\u94dd\u7b94\u7684LiFePO4<\/sub>\u6b63\u6781\u7684\u6027\u80fd<\/strong>
\n \"\"\uff08a\uff09\u4ee5\u591a\u5b54Al\u3001\u539f\u59cbAl\u548c\u5546\u7528Al\/C\u7b94\u4e3a\u96c6\u6d41\u4f53\u7684LiFePO4<\/sub>\u6b63\u6781\u57281 C\u4e0b\u7684\u5faa\u73af\u6027\u80fd\uff1b<\/p>\n

\uff08b\uff09LiFePO4<\/sub>\u6b63\u6781\u7684\u5178\u578bC-V\u66f2\u7ebf\uff0c\u5176\u4e2d\u626b\u63cf\u901f\u7387\u4e3a0.2 mV s-1<\/sup>\uff1b<\/p>\n

\uff08c\uff09\u57281 C\u4e0b\uff0c\u57fa\u4e8e\u4e0d\u540cAl\u7b94\u7684LiFePO4<\/sub>\u6b63\u6781\u7684\u653e\u7535\u80fd\u91cf\u5bc6\u5ea6\uff1b<\/p>\n

\uff08d\uff09\u57fa\u4e8e\u4e0d\u540cAl\u7b94\u7684LiFePO4<\/sub>\u6b63\u6781\u7684\u5948\u594e\u65af\u7279\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u672c\u6587\u63d0\u51fa\u4e86\u4e00\u79cd\u9ad8\u6548\u3001\u7701\u65f6\u7684\u5fae\u6ce2\u8f85\u52a9\u5236\u5907\u591a\u5b54\u94dd\u7b94\u7684\u7b56\u7565\u3002\u91d1\u5c5eAl\u8868\u9762\u7684\u5927\u91cf\u81ea\u7531\u7535\u5b50\u53ef\u4ee5\u88ab\u7535\u78c1\u80fd\u6781\u5316\uff0c\u800cFe(NO3<\/sub>)3<\/sub>\u5728\u5feb\u901f\u52a0\u70ed\u7684\u56fa\u6db2\u754c\u9762\u4e0a\u8bf1\u5bfc\u6709\u6548\u8680\u523b\uff0c\u4ece\u800c\u5728\u591a\u79cdAl\u7b94\u8868\u9762\u5b9e\u73b0\u591a\u5b54\u7f51\u7edc\u7ed3\u6784\u7684\u6784\u5efa\u3002\u5f97\u76ca\u4e8e\u96c6\u6d41\u4f53\u7684\u51cf\u8584\u51cf\u91cd\u548c\u754c\u9762\u7535\u63a5\u89e6\u4f18\u5316\uff0c\u8d1f\u8f7d\u5728\u591a\u5b54Al\u7b94\u4e0a\u7684LiFePO4<\/sub>\u6b63\u6781\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u548c\u80fd\u91cf\u5bc6\u5ea6\u5f97\u5230\u6709\u6548\u63d0\u9ad8\u3002\u8fd9\u79cd\u53ef\u6269\u5c55\u7684\u7b56\u7565\u4e0d\u4ec5\u4e3a\u5f00\u53d1\u4e0b\u4e00\u4ee3\u80fd\u6e90\u76f8\u5173\u5668\u4ef6\u63d0\u4f9b\u4e86\u65b0\u7684\u53ef\u80fd\u6027\uff0c\u8fd8\u62d3\u5c55\u4e86\u8868\u9762\u5316\u5b66\u5728\u591a\u79cd\u5e94\u7528\u573a\u666f\u4e2d\u7684\u5de8\u5927\u6f5c\u529b\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aUltrafast Microwave Activating Polarized Electron for Scalable Porous Al toward High-Energy-Density Batteries<\/a><\/strong> \uff08Nano Letters<\/em>, 2020<\/strong>, DOI: 10.1021\/acs.nanolett.0c03762\uff09<\/p>\n

\u672c\u6587\u7531CQR\u7f16\u8bd1\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1atougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenvip.<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011 \u56fa\u4f53\u6750\u6599\u8868\u9762\u7684\u5408\u7406\u8bbe\u8ba1\u63a8\u52a8\u4e86\u7535\u5b50\u3001\u50ac\u5316\u3001\u80fd\u6e90\u548c\u751f\u7269\u7b49\u76f8\u5173\u7814\u7a76\u548c\u5de5\u4e1a\u6280\u672f\u7684\u5de8\u5927\u8fdb\u6b65\u3002\u4f46\u662f\uff0c\u6c89\u79ef\u3001\u76f8\u53d8\u7b49\u4f20\u7edf\u7684\u8868\u9762\u6280\u672f\u4f9d\u8d56\u4e8e\u590d\u6742\u7684\u7a0b\u5e8f\u548c\u8bbe\u5907\u3002\u8fd1\u5e74\u6765\uff0c…<\/p>\n","protected":false},"author":7770,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[4533],"class_list":["post-213796","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-al"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/213796"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/7770"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=213796"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/213796\/revisions"}],"predecessor-version":[{"id":213853,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/213796\/revisions\/213853"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=213796"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=213796"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=213796"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}