{"id":214277,"date":"2020-12-10T06:41:22","date_gmt":"2020-12-09T22:41:22","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=214277"},"modified":"2020-12-09T18:41:32","modified_gmt":"2020-12-09T10:41:32","slug":"%e7%be%8e%e5%9b%bd%e9%a9%ac%e5%87%af%e7%89%b9%e5%a4%a7%e5%ad%a6jacs%ef%bc%9a%e4%b8%89%e7%a7%8d%e5%85%89%e8%b0%b1%e6%8f%ad%e7%a4%ba2d%e5%af%bc%e7%94%b5mofs%e4%b8%ad%e7%9a%84%e7%94%b5%e8%8d%b7%e4%bc%a0","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=214277","title":{"rendered":"\u7f8e\u56fd\u9a6c\u51ef\u7279\u5927\u5b66JACS\uff1a\u4e09\u79cd\u5149\u8c31\u63ed\u793a2D\u5bfc\u7535MOFs\u4e2d\u7684\u7535\u8377\u4f20\u8f93\u673a\u5236"},"content":{"rendered":"<p>\u6784\u5efa\u5177\u6709\u7535\u8377\u4f20\u8f93\uff08CT\uff09\u7279\u6027\u7684MOFs\u7b56\u7565\u901a\u5e38\u6709\u4e24\u79cd\u65b9\u6cd5\uff0c\u5373\u952e\u5408\u548c\u7a7a\u95f4\u65b9\u6cd5\u3002\u952e\u5408\u7684\u65b9\u6cd5\u4f9d\u8d56\u4e8e\u91d1\u5c5e\u8282\u70b9\u548c\u6709\u673a\u914d\u4f53\u4e4b\u95f4\u826f\u597d\u7684\u7a7a\u95f4\u548c\u8f68\u9053\u91cd\u53e0\u6765\u5b9e\u73b0\u6709\u6548\u7684CT\u3002\u901a\u8fc7\u7a7a\u95f4\u7684\u65b9\u6cd5\u5229\u7528\u975e\u5171\u4ef7\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u5982\u5728\u6709\u673a\u8fde\u63a5\u7269\u4e4b\u95f4\u7684\u8d85\u80fd\u53e0\u52a0\uff0c\u521b\u9020\u4e86\u4e00\u4e2a\u6269\u5c55\u7684\u7535\u8377\u79bb\u57df\u9014\u5f84\u3002\u8fd9\u4e24\u79cd\u65b9\u6cd5\u90fd\u6709\u671b\u63d0\u4f9b\u4f4e\u80fd\u91cf\u7684\u7535\u8377\u4f20\u8f93\u9014\u5f84\uff0c\u65e0\u8bba\u662f\u901a\u8fc7\u8df3\u8dc3\u4f20\u8f93\u8fd8\u662f\u5e26\u4f20\u8f93\uff0c\u90fd\u53ef\u4ee5\u901a\u8fc7\u9009\u62e9\u7a33\u5b9a\u7684\u6709\u673a\u914d\u4f53\u4ee5\u53ca\u9002\u5f53\u7684\u91d1\u5c5e\u79bb\u5b50\u548c\u87af\u5408\u5355\u5143\u7684\u7ed3\u5408\u6765\u5b9e\u73b0\u3002\u4f8b\u5982\uff0c\u57fa\u4e8e\u56db\u786b\u5bcc\u74e6\u70ef\u3001\u8418\u3001\u84bd\u548c\u8418\u4e8c\u9170\u4e9a\u80fa\u914d\u4f53\u76842D-MOFs\u8868\u73b0\u51fa\u5bfc\u7535\u6027\uff0c\u5176\u6765\u6e90\u4e8e\u6709\u673a\u914d\u4f53\u4e4b\u95f4\u7684\u5c42\u95f4\u03c0-\u03c0\u5806\u79ef\uff0c\u4f7f\u5f97\u4ece\u4e00\u5c42\u5230\u53e6\u4e00\u5c42\u7684\u6709\u6548CT\u3002\u57fa\u4e8e\u914d\u4f53\u548c\u91d1\u5c5e\u7684MOF\u503e\u5411\u4e8e\u5f62\u62101D\u4e8c\u6b21\u6784\u5efa\u5355\u5143\uff0c\u663e\u793a\u7535\u8377\u79bb\u57df\u548c\u5bfc\u7535\u6027\uff0c\u8fd9\u53ef\u4ee5\u5f52\u56e0\u4e8e\u901a\u8fc7\u952e\u7684\u5c42\u5185CT\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-214278 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/1-3.png\" alt=\"\" width=\"600\" height=\"213\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/1-3.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/1-3-300x107.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u8fd1\u65e5\uff0c\u7f8e\u56fd\u9a6c\u51ef\u7279\u5927\u5b66<strong>Jier Huang<\/strong>\u7814\u7a76\u56e2\u961f\uff0c\u4ee5\u201cDirect Evidence of Photoinduced Charge Transport Mechanism in 2D Conductive Metal Organic Frameworks\u201d\u4e3a\u9898\u5728<em>J. Am. Chem. Soc<\/em>\u671f\u520a\u4e0a\u53d1\u8868\u91cd\u8981\u7814\u7a76\u6210\u679c\u3002\u4f5c\u8005\u7ed3\u5408\u4e09\u79cd\u5148\u8fdb\u7684\u5149\u8c31\u65b9\u6cd5\uff0c\u5305\u62ec\u65f6\u95f4\u5206\u8fa8\u5149\u8c31\u548cX\u5c04\u7ebf\u5438\u6536\u5149\u8c31\u548c\u592a\u8d6b\u5179\u5149\u8c31\uff0c\u62a5\u9053\u4e86\u4e8c\u7ef4Cu-THQ MOFs\u4e2d\u7535\u8377\u4f20\u8f93\uff08CT\uff09\u673a\u5236\u7684\u76f4\u63a5\u8bc1\u636e\uff0c\u4ee5\u53ca\u8f7d\u6d41\u5b50\u7684\u65f6\u7a7a\u884c\u4e3a\u4e0e\u5176\u5149\u7535\u5bfc\u7387\u7684\u76f8\u5173\u6027\u3002\u9664Cu-THQ\u5916\uff0c\u4f5c\u8005\u8fd8\u7814\u7a76\u4e86Cu\/Zn-THQ\u4e2d\u52a0\u5165Zn<sup>2+<\/sup>\u5ba2\u4f53\u91d1\u5c5e\u540e\u7684CT\uff0c\u4ee5\u63ed\u793a\u7a7a\u95f4\u8def\u5f84\u7684\u8d21\u732e\uff0c\u56e0\u4e3a\u6c27\u5316\u8fd8\u539f\u4e0d\u6d3b\u8dc3\u76843d<sup>10<\/sup> Zn<sup>2+<\/sup>\u7684\u5b58\u5728\u4f1a\u5e72\u6270\u957f\u8303\u56f4\u7684\u5e73\u9762\u5185CT\u3002\u4f5c\u8005\u53d1\u73b0\uff0c\u5149\u6fc0\u53d1\u540e\u4ea7\u751f\u7684Cu-THQ\u4e2d\u7684\u70ed\u8f7d\u6d41\u5b50\u6d41\u52a8\u6027\u5f3a\uff0c\u5e76\u5feb\u901f\u5b9a\u4f4d\u5230\u8f83\u4f4e\u7684\u80fd\u6001(\u51b7\u8f7d\u6d41\u5b50)\uff0c\u7535\u5b50\u5360\u636eCu\u4e2d\u5fc3\u548c\u914d\u4f53\u4e2d\u7684\u7a7a\u7a74\u3002\u4f4e\u6e29\u8f7d\u4f53\u5177\u6709\u8d85\u957f\u5bff\u547d(&gt;17 ns)\uff0c\u8d1f\u8d23Cu-THQ\u4e2d\u7684\u957f\u671f\u5149\u7535\u5bfc\u7387\u548cO-Cu-O\u57fa\u5e8f\u7684\u8f93\u8fd0\uff0c\u800c\u5c42\u95f4\u914d\u4f53\u03c0-\u03c0\u5806\u79ef\u7684\u4f5c\u7528\u53ef\u4ee5\u5ffd\u7565\u4e0d\u8ba1\uff0c\u56e0\u4e3aCu-THQ\u4e2dZn<sup>2+<\/sup>\u7684\u52a0\u5165\u663e\u8457\u964d\u4f4e\u4e86\u5149\u7535\u5bfc\u7387\u3002\u8fd9\u4e9b\u524d\u6240\u672a\u6709\u7684\u7ed3\u679c\u4e0d\u4ec5\u8bc1\u660e\u4e86\u5b9e\u9a8c\u63a2\u6d4bCT\u673a\u7406\u7684\u80fd\u529b\uff0c\u800c\u4e14\u4e3a\u5408\u7406\u8bbe\u8ba1\u7528\u4e8e\u5149\u7535\u5b50\u548c\u5149\u50ac\u5316\u5e94\u7528\u7684\u4e8c\u7ef4MOFs\u63d0\u4f9b\u4e86\u91cd\u8981\u7684\u601d\u60f3\u3002<\/p>\n<p><strong>\u65b9\u6848<\/strong><strong>1. M-THQ (M = Cu or Zn)<\/strong><strong>\u7684\u793a\u610f\u56fe\u3002<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-214279 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/2-2.png\" alt=\"\" width=\"535\" height=\"175\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/2-2.png 535w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/2-2-300x98.png 300w\" sizes=\"(max-width: 535px) 100vw, 535px\" \/><\/p>\n<p>\u4e8c\u7ef4Cu-THQ\u548cCu\/Zn-THQ\uff08Cu\/Zn=44:56\uff09MOF\uff08\u65b9\u68481\uff09\u6309\u7167\u5148\u524d\u62a5\u9053\u7684\u6587\u732e\u901a\u8fc7\u52a8\u529b\u5b66\u63a7\u5236\u5408\u6210\u6b65\u9aa4\u5408\u6210\u7684\u3002THQ\u914d\u4f53\uff08\u56fe1a\uff09\u7684\u5085\u91cc\u53f6\u53d8\u6362\u7ea2\u5916\uff08FTIR\uff09\u5149\u8c31\u663e\u793a\u57283350\u548c1700 cm<sup>\u22121<\/sup>\u5904\u7684\u5438\u6536\u7279\u5f81\u5cf0\uff0c\u8fd9\u662f\u7531\u4e8eO\u2212H\u548cC=O\u4f38\u7f29\u632f\u52a8\u5f15\u8d77\u7684\u3002\u8fd9\u4e9b\u7279\u5f81\u5cf0\u5728M-THQ\u6837\u54c1\u4e2d\u6d88\u5931\uff0c\u8868\u660e\u7531\u4e8e\u4e0e\u91d1\u5c5e\u8282\u70b9\u7684\u914d\u4f4d\uff0c\u914d\u4f53\u5b8c\u5168\u8131\u8d28\u5b50\u5316\u548c\u8fd8\u539f\u3002\u540c\u65f6\uff0c\u5728MTHQ-MOFs\u7684\u5149\u8c31\u4e2d\u53d1\u73b0\u4e86\u4e00\u4e2a\u65b0\u7684\u5bbd\u8c31\u5e26\u3002\u8be5\u5e26\u53ef\u5f52\u5c5e\u4e8eNH\u4f38\u7f29\u632f\u52a8\uff0c\u5e76\u6765\u6e90\u4e8eMOF\u4e2d\u7528\u4e8e\u5e73\u8861\u7535\u8377\u7684\u4e59\u4e8c\u80fa\u5206\u5b50\u3002\u6f2b\u53cd\u5c04\u7d2b\u5916\u53ef\u89c1\u8fd1\u7ea2\u5916\u5149\u8c31\u8fdb\u4e00\u6b65\u652f\u6301M-THQ\u7684\u5f62\u6210\u3002\u5982\u56fe1b\u6240\u793a\uff0cTHQ\u914d\u4f53\u5728\u7d2b\u5916\u53ef\u89c1\u533a\u8868\u73b0\u51fa\u5e7f\u6cdb\u7684\u5438\u6536\uff0c\u5c3e\u90e8\u5ef6\u4f38\u5230\u5bf9\u5e94\u4e8en-\u03c0\u8dc3\u8fc1\u7684\u8fd1\u7ea2\u5916\u533a\u3002\u4e0eTHQ\u914d\u4f53\u7684\u5149\u8c31\u76f8\u6bd4\uff0c\u5728M-THQ\u5149\u8c31\u7684\u8fd1\u7ea2\u5916\u533a(&gt; 900 nm)\u89c2\u5bdf\u5230\u4e00\u4e2a\u989d\u5916\u7684\u5e7f\u6cdb\u5438\u6536\uff0c\u4f5c\u8005\u5c06\u8fd9\u79cd\u5438\u6536\u5f52\u56e0\u4e8e\u5206\u5b50\u5185\u7535\u8377\u8f6c\u79fb\u5e26\u6216Cu d-d\u8dc3\u8fc1\uff0c\u8fd9\u4e0e\u4e4b\u524d\u7684Cu-THQ\u6570\u636e\u975e\u5e38\u543b\u5408\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>1.<\/strong> <strong>Cu-THQ<\/strong><strong>\u3001<\/strong><strong>Cu\/Zn-THQ<\/strong><strong>\u548c<\/strong><strong>THQ<\/strong><strong>\u914d\u4f53\u5728\u56fa\u4f53\u72b6\u6001\u4e0b\u7684\u7ea2\u5916\u5149\u8c31\uff08<\/strong><strong>a<\/strong><strong>\uff09\u548c\u6f2b\u53cd\u5c04\u5149\u8c31\uff08<\/strong><strong>b<\/strong><strong>\uff09\u3002\uff08<\/strong><strong>c<\/strong><strong>\uff09<\/strong><strong>Cu-THQ<\/strong><strong>\u548c<\/strong><strong>Cu\/Zn-THQ<\/strong><strong>\u7684<\/strong><strong>XRD<\/strong><strong>\u56fe\u8c31\u3002\uff08<\/strong><strong>d<\/strong><strong>\uff09<\/strong><strong>M-THQ-MOF<\/strong><strong>\u4e2d<\/strong><strong>Cu<\/strong><strong>\u548c<\/strong><strong>Zn<\/strong><strong>\u7684\u5c40\u90e8\u914d\u4f4d\u51e0\u4f55\u56fe\u5f62\u3002<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-214280 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/3-2.png\" alt=\"\" width=\"600\" height=\"418\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/3-2.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/3-2-300x209.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u4f5c\u8005\u5229\u7528\u98de\u79d2\u5149\u5b66\u77ac\u6001\u5438\u6536\uff08OTA\uff09\u6280\u672f\u7814\u7a76\u4e86Cu-MOF\u548cCu\/Zn-MOF\u7684\u8f7d\u6d41\u5b50\u52a8\u529b\u5b66\u548cCT\u673a\u7406\u3002\u56fe2a\u663e\u793a\u4e86450 nm\u6fc0\u53d1\u540eCu-THQ\u7684OTA\u5149\u8c31\u3002\u5728\u6fc0\u53d1\u4e4b\u540e\uff0cOTA\u5149\u8c31\u5728470\u2212660 nm\u5904\u663e\u793a\u51fa\u5e7f\u6cdb\u7684\u8d1f\u7279\u5f81\uff0c\u5728&gt;700 nm\u5904\u663e\u793a\u51fa\u6b63\u7279\u5f81\uff08\u8868\u793a\u4e3aE1\uff09\u3002\u6700\u8fd1\u7684\u8ba1\u7b97\u7814\u7a76\u8868\u660e\uff0cCu-THQ\u8868\u73b0\u4e3a\u5177\u6709\u9ad8\u8272\u6563\u5bfc\u5e26\u7684\u534a\u5bfc\u4f53\uff0c\u8fd9\u8868\u660e\u89e3\u91caOTA\u5149\u8c31\u5e94\u4f7f\u7528\u534a\u5bfc\u4f53\u6fc0\u5b50\u6a21\u578b\u800c\u4e0d\u662f\u5206\u5b50\u6a21\u578b\u3002\u4ee5620 nm\u4e3a\u4e2d\u5fc3\u7684EB\u5e26\u6062\u590d\uff0cE1\u968f\u65f6\u95f4\u8fc5\u901f\u8870\u51cf\uff0c\u5728700 nm\u5904\u89c2\u5bdf\u5230\u4e00\u4e2a\u7b49\u7535\u4f4d\u70b9\uff0c\u8fd9\u8868\u660e\u5b83\u4eec\u4ee3\u8868\u7740\u76f8\u540c\u7684\u5f1b\u8c6b\u8fc7\u7a0b\uff0c\u5373CB\u4e2d\u7684\u7535\u5b50\u4e0eVB\u4e2d\u7684\u7a7a\u7a74\u91cd\u65b0\u7ed3\u5408\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u5728\u223c525 nm\u5904\u7684\u7535\u5b50\u675f\u57285ps\u540e\u6f14\u5316\u4e3a\u6b63\uff0c\u8fd9\u8868\u660e\u223c525 nm\u5904\u7684\u7535\u5b50\u5438\u6536\u4e0e\u76f8\u540c\u533a\u57df\u7684\u7535\u5b50\u5438\u6536\u91cd\u53e0\uff08\u8868\u793a\u4e3aE2\uff09\uff0c\u5176\u4e2dE2\u4e0eE1\u5177\u6709\u4e0d\u540c\u7684\u6027\u8d28\uff0c\u56e0\u4e3aE2\u5728\u65e9\u671f\u7684\u8870\u53d8\u901f\u5ea6\u6bd4E1\u6162\u3002\u901a\u8fc7\u6bd4\u8f83\u5b83\u4eec\u7684\u52a8\u529b\u5b66\u8f68\u8ff9\uff08\u56fe2b\uff09\u53ef\u4ee5\u66f4\u6e05\u695a\u5730\u770b\u5230\u8fd9\u4e9b\u5149\u8c31\u6f14\u53d8\uff0c\u5176\u4e2dEB\uff08620 nm\uff09\u7684\u52a8\u529b\u5b66\u9075\u5faaE1\uff08700 nm\uff09\uff0c\u4f46E2\uff08525nm\uff09\u5728\u968f\u540e\u7684\u65f6\u95f4\u53d8\u4e3a\u6b63\u503c\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>2.<\/strong> <strong>Cu-THQ<\/strong><strong>\uff08<\/strong><strong>a<\/strong><strong>\uff09\u548c<\/strong><strong>Cu\/Zn-THQ<\/strong><strong>\uff08<\/strong><strong>c<\/strong><strong>\uff09\u7684<\/strong><strong>OTA<\/strong><strong>\u5149\u8c31\u3002\uff08<\/strong><strong>b<\/strong><strong>\uff09<\/strong><strong> 750<\/strong><strong>\u3001<\/strong><strong>620<\/strong><strong>\u548c<\/strong><strong>525nm<\/strong><strong>\u4e0b<\/strong><strong>Cu-THQ<\/strong><strong>\u7684\u52a8\u529b\u5b66\u8f68\u8ff9\u6bd4\u8f83\u3002\uff08<\/strong><strong>d<\/strong><strong>\uff09<\/strong><strong> 620nm<\/strong><strong>\u4e0b<\/strong><strong>Cu-THQ<\/strong><strong>\u548c<\/strong><strong>580nm-Cu\/Zn-THQ<\/strong><strong>\u7535\u5b50\u675f\u5e26\u52a8\u529b\u5b66\u8f68\u8ff9\u7684\u6bd4\u8f83\u3002<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-214281 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/4-2.png\" alt=\"\" width=\"525\" height=\"444\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/4-2.png 525w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/4-2-300x254.png 300w\" sizes=\"(max-width: 525px) 100vw, 525px\" \/><\/p>\n<p>\u4e3a\u4e86\u6df1\u5165\u4e86\u89e3\u957f\u5bff\u547d\u5c42\u5185\u6fc0\u5b50\u7684\u6027\u8d28\uff0c\u4f5c\u8005\u4f7f\u7528X\u5c04\u7ebf\u77ac\u6001\u5438\u6536\uff08XTA\uff09\u5149\u8c31\u6cd5\u6d4b\u91cf\u4e86Cu-THQ\u548cCu\/Zn-THQ\u4e2dCu\u4e2d\u5fc3\u7684\u7535\u5b50\u7ed3\u6784\uff0c\u8fd9\u662f\u4e00\u79cd\u5bf9\u5143\u7d20\u654f\u611f\u7684\u5f3a\u5927\u6280\u672f\uff0c\u5141\u8bb8\u5728\u5149\u6fc0\u53d1\u4e0b\u76f4\u63a5\u63a2\u6d4bCu\u4f4d\u7684\u7535\u5b50\u5bc6\u5ea6400 nm\u6fc0\u5149\u8109\u51b2\u3002\u56fe3a\u663e\u793a\u4e86Cu-THQ\u7684\u57fa\u6001X\u5c04\u7ebf\u5438\u6536\u8fd1\u8fb9\u7ed3\u6784\uff08XANES\uff09\u5149\u8c31\u53ca\u5176\u6fc0\u53d1\u540e\u5728100ps\u548c5ns\u4e0b\u91c7\u96c6\u7684XANES\u5dee\u8c31\u3002\u7528\u6fc0\u5149\u6fc0\u53d1\u5149\u8c31\u51cf\u53bb\u6fc0\u5149\u79bb\uff08\u57fa\u6001\uff09\u5149\u8c31\u5f97\u5230\u4e86\u5dee\u5206\u5149\u8c31\u3002\u57288.983\u548c8.989 keV\u4e0b\u89c2\u5bdf\u5230\u7684\u4e24\u4e2a\u663e\u8457\u7684\u7279\u5f81\u5cf0\uff0c\u5206\u522b\u5f52\u5c5e\u4e8e1s\u21924p<sub>z<\/sub>\u548c\u4e3b\u8981\u76841s\u21924p<sub>xy<\/sub>\u8dc3\u8fc1\uff0c\u8868\u660e\u5438\u6536\u8fb9\u5411\u4f4e\u80fd\u79fb\u52a8\u3002\u7531\u4e8eCu\u548cTHQ\u914d\u4f53\u662fCu-THQ\u4e2d\u552f\u4e00\u7684\u4e24\u4e2a\u7ec4\u5206\uff0cCu\u4e2d\u5fc3\u7684\u8fd8\u539f\u5fc5\u7136\u4f34\u968f\u7740THQ\u7684\u6c27\u5316\uff0c\u8bf4\u660e\u5c42\u5185\u6fc0\u5b50\u7684\u6027\u8d28\u662f\u7535\u5b50\u4f4d\u4e8eCu\u4e2d\u5fc3\uff0c\u7a7a\u7a74\u4f4d\u4e8eTHQ\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>3. <\/strong><strong>\u7528<\/strong><strong>100ps<\/strong><strong>\u548c<\/strong><strong>5ns<\/strong><strong>\u7684\u6fc0\u5149\u5f00\u542f\u5149\u8c31\u51cf\u53bb\u6fc0\u5149\u79bb\uff08\u57fa\u6001\uff09\u5149\u8c31\uff08\u9ed1\u56fe\uff09\u5f97\u5230<\/strong><strong>Cu-THQ<\/strong><strong>\uff08<\/strong><strong>a<\/strong><strong>\uff09\u548c<\/strong><strong>Cu\/Zn-THQ<\/strong><strong>\uff08<\/strong><strong>b<\/strong><strong>\uff09\u7684\u5dee\u5206<\/strong><strong>XANES<\/strong><strong>\u5149\u8c31\u3002\uff08<\/strong><strong>c<\/strong><strong>\uff09<\/strong><strong>Cu-THQ<\/strong><strong>\u5728<\/strong><strong>8.989 keV<\/strong><strong>\u548c<\/strong><strong>Cu\/Zn-THQ<\/strong><strong>\u5728<\/strong><strong>8.983 keV<\/strong><strong>\u4e0b\u7684<\/strong><strong>XTA<\/strong><strong>\u52a8\u529b\u5b66\u6bd4\u8f83\u3002\uff08<\/strong><strong>d<\/strong><strong>\uff09<\/strong><strong>Cu-THQ<\/strong><strong>\u4e0e<\/strong><strong>Cu\/Zn-THQ<\/strong><strong>\u7684<\/strong><strong>OPTP<\/strong><strong>\u75d5\u91cf\u6bd4\u8f83\u3002<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-214282 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/5-2.png\" alt=\"\" width=\"541\" height=\"409\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/5-2.png 541w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/5-2-300x227.png 300w\" sizes=\"(max-width: 541px) 100vw, 541px\" \/><\/p>\n<p>\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u5229\u7528\u4e09\u79cd\u5148\u8fdb\u7684\u65f6\u95f4\u5206\u8fa8\u5149\u8c31\u6280\u672f\uff0c\u62a5\u9053\u4e86Cu-THQ-MOF\u4e2d\u7535\u8377\u8f93\u8fd0\u673a\u5236\u7684\u76f4\u63a5\u8bc1\u636e\uff0c\u4ee5\u53ca\u8f7d\u6d41\u5b50\u7684\u65f6\u95f4\u548c\u7a7a\u95f4\u884c\u4e3a\u4e0e\u5176\u5149\u7535\u5bfc\u7684\u76f8\u5173\u6027\u3002\u4f5c\u8005\u53d1\u73b0\uff0c\u5149\u6fc0\u53d1\u540e\u4ea7\u751f\u7684\u70ed\u8f7d\u6d41\u5b50\uff08\u9ad8\u8fc1\u79fb\u7387\uff09\u7ecf\u5386\u4e86\u4e00\u4e2a\u8d85\u5feb\u7684\u5c40\u57df\u5316\u8fc7\u7a0b\uff0c\u5e76\u653e\u677e\u5230\u4f4e\u80fd\u6001\uff08\u51b7\u8f7d\u6d41\u5b50\uff09\uff0c\u5177\u6709\u8d85\u957f\u7684\u5bff\u547d\uff08&gt;17ns\uff09\u3002\u957f\u5bff\u547d\u7684\u51b7\u8f7d\u6d41\u5b50\u901a\u8fc7O\u2212Cu\u2212O\u57fa\u5e8f\u8fdb\u884c\u4f20\u8f93\uff0c\u800c\u914d\u4f53\u7684\u5c42\u95f4\u03c0\u2212\u03c0\u5806\u79ef\u51e0\u4e4e\u6ca1\u6709\u8d21\u732e\uff0c\u8fd9\u662fCu-THQ\u957f\u671f\u5149\u7535\u5bfc\u7684\u539f\u56e0\u3002\u8fd9\u4e9b\u53d1\u73b0\u662f\u53f2\u65e0\u524d\u4f8b\u7684\uff1a\u5728Cu-THQ\u4e2d\u53d1\u73b0\u5177\u6709\u9ad8\u8fc1\u79fb\u7387\u7684\u70ed\u8f7d\u6d41\u5b50\u8868\u660e\u4e86\u8bbe\u8ba1\u7cfb\u7edf\u7684\u91cd\u8981\u6027\uff0c\u8fd9\u79cd\u7cfb\u7edf\u53ef\u4ee5\u5728\u70ed\u8f7d\u6d41\u5b50\u51b7\u5374\u4e4b\u524d\u5c06\u5176\u5206\u79bb\u3002\u901a\u8fc7Cu-THQ\u4e2d\u7684O\u2212Cu\u2212O\u57fa\u5e8f\u8fd0\u8f93\u7684\u957f\u5bff\u547d\u79fb\u52a8\u8f7d\u4f53\u7684\u53d1\u73b0\u5e76\u4e0d\u610f\u5473\u7740\u53ea\u6709\u901a\u8fc7\u8c03\u6574\u94fe\u7ed3\u6784\u6765\u8fdb\u4e00\u6b65\u4f18\u5316\u8fd9\u4e9b\u6750\u6599\u7684\u53ef\u80fd\u6027\uff0c\u800c\u4e14\u8fd9\u4e9b\u957f\u5bff\u547d\u6fc0\u5b50\u7684\u63d0\u53d6\u6709\u671b\u6709\u6548\u5730\u5e94\u7528\u4e8e\u5149\u50ac\u5316\u3001\u592a\u9633\u80fd\u7535\u6c60\u548c\u5149\u7535\u9886\u57df\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aDirect Evidence of Photoinduced Charge Transport Mechanism in 2D Conductive Metal Organic Frameworks, <strong><em>J. Am. Chem. Soc.<\/em><\/strong><strong><em>\uff0c<\/em><\/strong>2020<strong><em>. <\/em><\/strong>DOI\uff1a10.1021\/jacs.0c09000.<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/pubs.acs.org\/doi\/10.1021\/jacs.0c09000.<\/p>\n<p>\u672c\u6587\u7531\u79d1\u7814\u767e\u6653\u751f\u4f9b\u7a3f\u3002<\/p>\n<p>\u672c\u5185\u5bb9\u4e3a\u4f5c\u8005\u72ec\u7acb\u89c2\u70b9\uff0c\u4e0d\u4ee3\u8868\u6750\u6599\u4eba\u7f51\u7acb\u573a\u3002<\/p>\n<p>\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u6784\u5efa\u5177\u6709\u7535\u8377\u4f20\u8f93\uff08CT\uff09\u7279\u6027\u7684MOFs\u7b56\u7565\u901a\u5e38\u6709\u4e24\u79cd\u65b9\u6cd5\uff0c\u5373\u952e\u5408\u548c\u7a7a\u95f4\u65b9\u6cd5\u3002\u952e\u5408\u7684\u65b9\u6cd5\u4f9d\u8d56\u4e8e\u91d1\u5c5e\u8282\u70b9\u548c\u6709\u673a\u914d\u4f53\u4e4b\u95f4\u826f\u597d\u7684\u7a7a\u95f4\u548c\u8f68\u9053\u91cd\u53e0\u6765\u5b9e\u73b0\u6709\u6548\u7684CT\u3002\u901a\u8fc7\u7a7a\u95f4&#8230;<\/p>\n","protected":false},"author":11454,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-214277","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/214277"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=214277"}],"version-history":[{"count":2,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/214277\/revisions"}],"predecessor-version":[{"id":214346,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/214277\/revisions\/214346"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=214277"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=214277"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=214277"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}