{"id":214532,"date":"2020-12-15T06:03:38","date_gmt":"2020-12-14T22:03:38","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=214532"},"modified":"2020-12-14T20:03:48","modified_gmt":"2020-12-14T12:03:48","slug":"%e8%b7%9f%e7%9d%80%e9%a1%b6%e5%88%8a%e5%ad%a6%e6%b5%8b%e8%af%95%ef%bd%9c%e5%8e%9f%e4%bd%8d%e6%a0%b8%e7%a3%81%e5%85%b1%e6%8c%af%e7%9b%91%e6%8e%a7%e9%87%91%e5%b1%9e-%e6%9c%89%e6%9c%ba%e6%a1%86%e6%9e%b6","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=214532","title":{"rendered":"\u8ddf\u7740\u9876\u520a\u5b66\u6d4b\u8bd5\uff5c\u539f\u4f4d\u6838\u78c1\u5171\u632f\u76d1\u63a7\u91d1\u5c5e-\u6709\u673a\u6846\u67b6(MOFs)\u7684\u5f62\u6210\u8fc7\u7a0b"},"content":{"rendered":"

\u91d1\u5c5e-\u6709\u673a\u6846\u67b6\uff08MOFs\uff09\u6750\u6599\u88ab\u5e7f\u6cdb\u7814\u7a76\uff0c\u5e76\u5728\u4ece\u6c14\u4f53\u50a8\u5b58\u548c\u5206\u79bb\u5230\u50ac\u5316\u548c\u5316\u5b66\u4f20\u611f\u5668\u7b49\u9886\u57df\u6709\u8bb8\u591a\u5e94\u7528\u3002\u7136\u800c\uff0cMOFs\u5f62\u6210\u7684\u673a\u7406\u7814\u7a76\u4ecd\u76f8\u5bf9\u4e0d\u8db3\uff0c\u5927\u90e8\u5206\u7ed3\u6784\u4fe1\u606f\u90fd\u662f\u5408\u6210\u540e\u83b7\u5f97\u7684\u3002Van Vleet\u7b49\u4eba\u56de\u987e\u4e86\u539f\u4f4d\u6280\u672f\u5728\u76d1\u63a7MOFs\u6210\u6838\u548c\u751f\u957f\u65b9\u9762\u7684\u5e94\u7528\uff0c\u5305\u62ecX\u5c04\u7ebf\u884d\u5c04\u548c\u5176\u4ed6X\u5c04\u7ebf\u6563\u5c04\u6280\u672f\uff0c\u800cCheetham\u7b49\u4eba\u5728\u8fc7\u53bb20\u5e74\u4e2d\u63cf\u8ff0\u4e86\u5728\u7406\u89e3\u63a7\u5236\u6eb6\u6db2\u4e2dMOF\u7ed3\u6676\u7684\u53c2\u6570\u65b9\u9762\u53d6\u5f97\u7684\u8fdb\u5c55\u3002\u5c3d\u7ba1\u9884\u6210\u6838\u548c\u9884\u5e73\u8861\u7269\u79cd\u5df2\u88ab\u8bc1\u660e\u5728MOF\u5f62\u6210\u53cd\u5e94\u4e2d\u8d77\u5173\u952e\u4f5c\u7528\uff0c\u5927\u591a\u6570\u7814\u7a76\u90fd\u96c6\u4e2d\u5728\u6210\u6838\u548c\u968f\u540e\u7684\u6676\u4f53\u751f\u957f\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u8fd1\u65e5\uff0c\u82f1\u56fd\u5361\u8fea\u592b\u5927\u5b66Timothy L. Easun<\/b><\/strong>\u6559\u6388\u548c<\/b><\/strong>Kenneth. D. M. Harris<\/b><\/strong>\u7814\u7a76\u56e2\u961f\uff0c\u4ee5\u201cExploiting in-situ NMR to monitor the formation of a metal-organic framework\u201d\u4e3a\u9898\u5728Chemical Science<\/i><\/em>\u671f\u520a\u4e0a\u53d1\u8868\u91cd\u8981\u7814\u7a76\u6210\u679c\u3002\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u6846\u67b6MFM-500(Ni)\u7684\u5408\u6210\u5df2\u7ecf\u4f7f\u7528\u539f\u4f4d\u6838\u78c1\u5171\u632f\u7b56\u7565\u8fdb\u884c\u4e86\u7814\u7a76\uff0c\u8be5\u7b56\u7565\u63d0\u4f9b\u4e86\u53cd\u5e94\u548c\u7ed3\u6676\u8fc7\u7a0b\u7684\u65f6\u95f4\u6f14\u5316\u4fe1\u606f\u3002\u5728\u4f5c\u8005\u5bf9MFM-500(Ni)\u5f62\u6210\u7684\u539f\u4f4d\u6838\u78c1\u5171\u632f\u7814\u7a76\u4e2d\uff0c\u6db2\u76f81<\/sup>H\u6838\u78c1\u5171\u632f\u6570\u636e\u5728\u56fa\u5b9a\u6e29\u5ea6(60-100\u2103)\u4e0b\u8bb0\u5f55\u4e3a\u65f6\u95f4\u7684\u51fd\u6570\uff0c\u63d0\u4f9b\u4e86\u6db2\u76f8\u8fc7\u7a0b\u7684\u5b9a\u6027\u4fe1\u606f\u548c\u7ed3\u6676\u52a8\u529b\u5b66\u7684\u5b9a\u91cf\u4fe1\u606f\uff0c\u5141\u8bb8\u6210\u6838\u7684\u6d3b\u5316\u80fd(61.4\u00b19.7 kJ mol-1<\/sup>)\u548c\u751f\u957f(72.9\u00b18.6 kJ mol-1<\/sup>)\u6709\u5f85\u6d4b\u5b9a\u3002\u539f\u4f4d\u5c0f\u89d2\u5ea6X\u5c04\u7ebf\u6563\u5c04\u7814\u7a76\u63d0\u4f9b\u4e86\u5173\u4e8eMOF\u7ed3\u6676\u524d\u5feb\u901f\u81ea\u7ec4\u88c5\u7684\u7eb3\u7c73\u7ea7\u4fe1\u606f\uff0c\u539f\u4f4d\u7c89\u672bX\u5c04\u7ebf\u884d\u5c04\u8bc1\u5b9e\u4e86\u5728\u53cd\u5e94(90\u2103)\u4e2d\u552f\u4e00\u5b58\u5728\u7684\u7ed3\u6676\u76f8\u662f\u7eaf\u76f8\u7684MFM-500(Ni)\u3002\u8fd9\u9879\u5de5\u4f5c\u8868\u660e\uff0c\u539f\u4f4d\u6838\u78c1\u5171\u632f\u5b9e\u9a8c\u53ef\u4ee5\u4e3aMOF\u7684\u5408\u6210\u63d0\u4f9b\u65b0\u7684\u601d\u8def\uff0c\u4e3a\u66f4\u597d\u5730\u7406\u89e3MOFs\u662f\u5982\u4f55\u5f62\u6210\u6253\u5f00\u4e86\u6280\u672f\u5927\u95e8\u3002<\/p>\n

\u4f5c\u8005\u6700\u521d\u5173\u6ce8\u7684\u662f\u5728\u539f\u4f4d\u6838\u78c1\u5171\u632f\u7814\u7a76\u4e2d\u8bb0\u5f55\u7684\u6db2\u60011<\/sup>H NMR\u8c31\uff0c\u56e0\u4e3a\u5b83\u4eec\u663e\u793a\u4e86\u5728MOF\u5f62\u6210\u8fc7\u7a0b\u4e2d\u51e0\u4e2a\u4e0d\u540c\u5171\u632f\u7684\u660e\u786e\u6f14\u5316\uff0c\u5e76\u4e14\u63d0\u4f9b\u4e86\u6bd431<\/sup>P NMR\u8c31\u66f4\u8be6\u7ec6\u7684\u4fe1\u606f\u3002\u56fe1a-e\u4e3a\u5404\u6e29\u5ea6\u4e0b\u6db2\u76f81<\/sup>H NMR\u8c31\u7684\u65f6\u95f4\u6f14\u5316\u56fe(\u5f3a\u5ea6\u7b49\u9ad8\u7ebf\u56fe);\u5b9e\u9a8c\u5f00\u59cb\u3001\u4e2d\u95f4\u548c\u7ed3\u675f\u4e09\u4e2a\u5355\u72ec\u7684\u5149\u8c31\u4e5f\u663e\u793a\u51fa\u6765\u3002\u5728\u6bcf\u4e2a\u6e29\u5ea6\u4e0b\uff0c1<\/sup>H NMR\u8c31\u5305\u542b7-8 ppm\u8303\u56f4\u5185\u7684\u5171\u632f\uff0c\u8fd9\u662f\u7531\u4e8e\u8fde\u63a5\u4f53\u4e2d\u7684\u82b3\u9999\u65cf1<\/sup>H\u73af\u5883(\u8868\u793a\u4e3aHa<\/sub>\u3001Hb<\/sub>\u548cHc<\/sub>)\u5f15\u8d77\u7684\uff0c\u5982\u56fe1f\u6240\u793a\u3002\u5728\u53cd\u5e94\u8fc7\u7a0b\u4e2d\uff0c\u8fd9\u4e00\u8303\u56f4\u5185\u7684\u4e09\u4e2a1<\/sup>H\u4fe1\u53f7\u90fd\u975e\u5355\u8c03\u5730\u968f\u65f6\u95f4\u53d8\u5316\uff0c\u6700\u521d\u662f\u964d\u4f4eppm\uff0c\u7136\u540e\u662f\u5347\u9ad8ppm\u3002<\/p>\n

\u56fe<\/b><\/strong>1.<\/b><\/strong>\u00a0\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u5bf9<\/b><\/strong>MFM-500(Ni)\u5408\u6210\u7684\u539f\u4f4d\u6838\u78c1\u5171\u632f\u7814\u7a76\u4e2d\uff0c\u8bb0\u5f55\u7684<\/b><\/strong>1<\/b><\/sup><\/strong>HNMR\u8c31\u7684\u5f3a\u5ea6\u7b49\u9ad8\u7ebf\u56fe\u4f5c\u4e3a\u65f6\u95f4\u7684\u51fd\u6570<\/b><\/strong>\u3002<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u4f5c\u8005\u8003\u8651\u5728\u539f\u4f4d\u6838\u78c1\u5171\u632f\u7814\u7a76\u4e2d\u8bb0\u5f55\u768431<\/sup>P\u6838\u78c1\u5171\u632f\u8c31(\u6709\u548c\u6ca1\u67091<\/sup>H\u89e3\u8026)\u3002\u56fe2a\u663e\u793a\u4e86\u572860 \u2103\u6761\u4ef6\u4e0b\uff0cMOF\u5408\u6210\u8fc7\u7a0b\u4e2d\u8bb0\u5f55\u7684\u672a1<\/sup>H\u89e3\u8026\u5408\u7684\u539f\u4f4d31<\/sup>P NMR\u8c31\u56fe(\u63d0\u4f9b\u6db2\u76f831<\/sup>P NMR\u6570\u636e)\u968f\u65f6\u95f4\u53d8\u5316\u7684\u5f3a\u5ea6\u7b49\u503c\u7ebf\u56fe\u3002\u5728\u8fd9\u4e2a\u6e29\u5ea6\u4e0b\uff0c\u89c2\u5bdf\u5230\u4e00\u4e2a\u5355\u4e00\u7684\u3001\u5bbd\u7684\u5cf0\u503c\uff0c\u4e0d\u540c\u7684\u914d\u4f53\u73af\u5883\u4e0b\u660e\u663e\u768431<\/sup>P\u5171\u632f\u6ca1\u6709\u88ab\u89e3\u51b3\u3002\u4fe1\u53f7\u7684\u5f3a\u5ea6\u5728\u5b9e\u9a8c\u8fc7\u7a0b\u4e2d\u964d\u4f4e\uff0c\u8fd9\u4e0e\u5728\u6eb6\u6db2\u9636\u6bb5\u5931\u53bb\u8fde\u63a5\u4e00\u81f4\u3002\u5f3a\u5ea6\u4ece\u7ea69\u5c0f\u65f6\u5f00\u59cb\u663e\u8457\u4e0b\u964d(\u56fe2b)\uff0c\u5e76\u6301\u7eed\u8870\u51cf\u81f3\u7ea620\u5c0f\u65f6\uff0c\u4e0e\u572860 \u2103\u4e0b\u539f\u4f4d1<\/sup>H NMR\u6570\u636e\u4e2d\u89c2\u5bdf\u5230\u7684\u884c\u4e3a\u76f8\u5f53\u3002<\/p>\n

\u56fe<\/b><\/strong>2. (a)\u663e\u793a\u572860 \u2103\u4e0b\u539f\u4f4d<\/b><\/strong>31<\/b><\/sup><\/strong>P NMR\u8c31(\u672a\u8bb0\u5f55<\/b><\/strong>1<\/b><\/sup><\/strong>H\u89e3\u8026)\u968f\u65f6\u95f4\u53d8\u5316\u7684\u5f3a\u5ea6\u7b49<\/b><\/strong>\u9ad8<\/b><\/strong>\u7ebf\u56fe\uff0c\u8868\u793a\u6db2\u76f8<\/b><\/strong>31<\/b><\/sup><\/strong>P NMR\u4fe1\u53f7\u3002(b)\u6db2\u6001<\/b><\/strong>31<\/b><\/sup><\/strong>P NMR\u4fe1\u53f7\u7684\u5f3a\u5ea6\u4e0e\u65f6\u95f4\u56fe\u3002<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u4e3a\u4e86\u5206\u6790\u5408\u6210\u8fc7\u7a0b\u4e2d\u56fa\u4f53\u7269\u8d28\u7684\u5f62\u6210\uff0c\u4f5c\u8005\u8fdb\u884c\u4e8690 \u2103\u4e0b\u53cd\u5e94\u7684\u539f\u4f4d\u7814\u7a76\uff0c\u8bb0\u5f55\u4e86\u7c89\u672bXRD\u8c31\u968f\u65f6\u95f4\u7684\u53d8\u5316\u3002\u8bf1\u5bfc\u671f\u7ea6\u4e3a80\u5206\u949f\uff0c\u5728\u5f62\u6210\u8db3\u4ee5\u7528X\u5c04\u7ebf\u884d\u5c04\u89c2\u5bdf\u5230\u7684\u9897\u7c92\u5927\u5c0f\u7684\u6676\u4f53\u6750\u6599\u4e4b\u524d\u3002\u7c89\u672bXRD\u6570\u636e\u8bc1\u5b9e\u7b2c\u4e00\u4e2a\u51fa\u73b0\u7684\u6676\u76f8\u4e3aMFM-500(Ni)\uff0c\u5728\u53cd\u5e94\u7684\u4efb\u4f55\u9636\u6bb5\u5747\u672a\u89c2\u5bdf\u5230\u5176\u4ed6\u6676\u76f8\u3002\u6b64\u5916\uff0cMOF\u5b58\u5728\u91cf\u7684\u521d\u59cb\u589e\u52a0\u4e0eBTPPA\u914d\u4f53\u5bfc\u81f4\u76841<\/sup>H NMR\u4fe1\u53f7\u7684\u635f\u5931\u7387\u662f\u4e00\u81f4\u7684(\u56fe3)\u3002\u4e0d\u5e78\u7684\u662f\uff0c\u7531\u4e8e\u9ad8\u6d53\u5ea6\u7684\u53cd\u5e94\u6eb6\u6db2\uff08\u7528\u4e8e\u6a21\u62df\u539f\u4f4d\u6838\u78c1\u5171\u632f\u7814\u7a76\u4e2d\u7684\u6761\u4ef6\uff09\u5bfc\u81f4\u5feb\u901f\u5f62\u6210\u7ed3\u6676\u56e2\u5757\uff0c\u8fd9\u4e9b\u56e2\u5757\u503e\u5411\u4e8e\u4e0d\u53ef\u9884\u6d4b\u5730\u4ece\u6837\u54c1\u7ba1\u4e2d\u7684\u6d4b\u91cf\u533a\u57df\u6389\u843d\uff0c\u56e0\u6b64\u65e0\u6cd5\u4ece\u7c89\u672bXRD\u6570\u636e\u53ef\u9760\u5730\u786e\u5b9a\u53cd\u5e94\u52a8\u529b\u5b66\u4fe1\u53f7\u5f3a\u5ea6\u4e0d\u89c4\u5219\u4e0b\u964d\u3002\u76f8\u53cd\uff0c\u57fa\u4e8e\u4f5c\u8005\u7684\u539f\u4f4d1<\/sup>H NMR\u7814\u7a76\u7ed3\u679c\uff0cMOF\u5f62\u6210\u8fc7\u7a0b\u7684\u5b9a\u91cf\u52a8\u529b\u5b66\u5206\u6790\u5982\u4e0b;\u5728\u8fd9\u65b9\u9762\uff0c\u539f\u4f4d\u6838\u78c1\u5171\u632f\u65b9\u6cd5\u7684\u4e00\u4e2a\u660e\u663e\u4f18\u52bf\u662f\uff0c\u6570\u636e\u662f\u5728\u6574\u4e2a\u5b9e\u9a8c\u8fc7\u7a0b\u4e2d\u6d4b\u91cf\u7684\u6837\u672c\u4f53\u79ef\u3002\u539f\u4f4d\u7c89\u672bXRD\u5b9e\u9a8c\u4e2d\u4ea7\u7269\u5f62\u6210\u7684\u8bf1\u5bfc\u65f6\u95f4\u7a0d\u957f\uff0c\u8fd9\u662f\u7531\u4e8e\u9700\u8981\u5f62\u6210\u8db3\u591f\u5927\u5c0f\u7684\u6676\u7c92\uff0c\u4ee5\u4fbf\u5728\u7c89\u672bXRD\u6570\u636e\u4e2d\u89c2\u5bdf\u5230\u5c16\u5cf0\u3002\u4e3a\u4e86\u8868\u5f81\u7c89\u672bXRD\u6d4b\u91cf\u4e2d\u53ef\u80fd\u770b\u4e0d\u5230\u7684\u66f4\u5c0f\u9897\u7c92\u7684\u5f62\u6210\uff0c\u4f7f\u7528\u5c0f\u89d2\u5ea6X\u5c04\u7ebf\u6563\u5c04(SAXS)\u5bf9MFM-500(Ni)\u7684\u5f62\u6210\u8fdb\u884c\u4e86\u539f\u4f4d\u7814\u7a76\u3002<\/p>\n

\u56fe<\/b><\/strong>3. <\/b><\/strong>\u4ece\u539f\u4f4d<\/b><\/strong>1<\/b><\/sup><\/strong>H NMR\u6570\u636e\u83b7\u5f97\u7684BTPPA<\/b><\/strong>\u914d\u4f53<\/b><\/strong>\u7684\u4e09\u4e2a\u82b3\u9999\u5cf0\u7684\u5f3a\u5ea6-\u65f6\u95f4\u66f2\u7ebf\uff0c\u4ee5\u53ca\u4f7f\u7528Gualtieri\u6a21\u578b\u83b7\u5f97\u7684\u62df\u5408<\/b><\/strong>\uff08\u7ea2\u7ebf\uff09<\/b><\/strong>\u3002<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u4f5c\u8005\u53d1\u73b0\u975e\u539f\u4f4dSAXS\u548c\u539f\u4f4d\u7c89\u672bXRD\u4e3aMFM-500(Ni)\u7684\u751f\u957f\u8fc7\u7a0b\u63d0\u4f9b\u4e86\u4e92\u8865\u548c\u9a8c\u8bc1\u4fe1\u606f\uff0c\u8868\u660e\u67f1\u72b6\u94fe\u63a5\u57fa\u805a\u96c6\u7269\u7684\u5f62\u6210\u5148\u4e8e\u6676\u4f53MFM-500(Ni)\u7684\u51fa\u73b0\u3002\u83b7\u53d6\u5173\u4e8eMOF\u5f62\u6210\u65e9\u671f\u9636\u6bb5\u7684\u7cbe\u786e\u5316\u5b66\u4fe1\u606f\u4ecd\u7136\u5177\u6709\u6311\u6218\u6027\uff0c\u672a\u6765\u7684\u529b\u5b66\u7814\u7a76\u6700\u597d\u5c06\u6700\u521d\u7684\u91cd\u70b9\u653e\u5728\u53ef\u7528\u7684\u6700\u7b80\u5355\u4f53\u7cfb\u4e0a(\u4f8b\u5982\u5355\u6eb6\u5242)\u3002\u6b64\u5916\uff0c\u5728\u8fc7\u7a0b\u4e2d\u4e2d\u95f4\u4f53\u548c\u4ea7\u7269\u7684\u6d53\u5ea6\u975e\u5e38\u4f4e\u7684\u65e9\u671f\uff0c\u5f00\u53d1\u65b0\u7684\u52a8\u6001\u6838\u6781\u5316(DNP)\u65b9\u6cd5\u53ef\u80fd\u4f1a\u63d0\u9ad8\u7075\u654f\u5ea6\uff0c\u4ece\u800c\u63d0\u4f9b\u65b0\u7684\u89c1\u89e3\u3002\u8fd9\u6837\u7684\u5b9e\u9a8c\u53ef\u4ee5\u57fa\u4e8e\u73b0\u6709\u7684\u9759\u6001\u7814\u7a76\u6765\u8868\u5f81MOFs\u540e\u5408\u6210\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aExploiting in-situ NMR to monitor the formation of a metal-organic framework,\u00a0Chem. Sci.<\/i><\/b><\/em><\/strong>, 2021, DOI: 10.1039\/D0SC04892E.<\/p>\n

\u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2021\/sc\/d0sc04892e#!divAbstract.<\/p>\n

\u672c\u6587\u7531\u79d1\u7814\u767e\u6653\u751f\u4f9b\u7a3f\u3002<\/p>\n

\u672c\u5185\u5bb9\u4e3a\u4f5c\u8005\u72ec\u7acb\u89c2\u70b9\uff0c\u4e0d\u4ee3\u8868\u6750\u6599\u4eba\u7f51\u7acb\u573a\u3002<\/p>\n

\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n

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