{"id":214824,"date":"2020-12-21T06:23:05","date_gmt":"2020-12-20T22:23:05","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=214824"},"modified":"2020-12-20T20:23:26","modified_gmt":"2020-12-20T12:23:26","slug":"%e6%ad%a4%e6%a6%82%e5%bf%b5%e4%bb%85%e4%bb%85%e8%a2%ab%e6%8f%90%e5%87%ba10%e5%b9%b4%ef%bc%8c%e5%8d%b4%e6%88%90%e4%b8%ba%e4%bc%97%e5%a4%9a%e6%b5%b7%e5%86%85%e5%a4%96%e5%ad%a6%e8%80%85%e7%9a%84%e9%87%8d","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=214824","title":{"rendered":"\u6b64\u6982\u5ff5\u4ec5\u4ec5\u88ab\u63d0\u51fa10\u5e74\uff0c\u5374\u6210\u4e3a\u4f17\u591a\u6d77\u5185\u5916\u5b66\u8005\u7684\u91cd\u70b9\u7814\u7a76\u5bf9\u8c61"},"content":{"rendered":"<p>\u81ea\u4ece2011\u5e74\u201c\u5355\u539f\u5b50\u50ac\u5316\u201d\u88ab\u4e2d\u56fd\u79d1\u5b66\u9662\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u5f20\u6d9b\u9662\u58eb\u3001\u6e05\u534e\u5927\u5b66\u674e\u96bd\u6559\u6388\u53ca\u7f8e\u56fd\u4e9a\u5229\u6851\u90a3\u5dde\u7acb\u5927\u5b66\u5218\u666f\u6708\u6559\u6388\u5171\u540c\u63d0\u51fa\u4ee5\u540e\uff0c\u5728\u77ed\u77ed\u5341\u5e74\u95f4\uff0c\u5355\u539f\u5b50\u50ac\u5316\u8fc5\u901f\u6210\u4e3a\u50ac\u5316\u9886\u57df\u7814\u7a76\u7684\u70ed\u70b9\u8bfe\u9898\u3002\u672c\u6587\u68b3\u7406\u4e86\u6700\u8fd1\u53d1\u8868\u5728\u9876\u7ea7\u671f\u520a\u4e0a\u7684\u5355\u539f\u5b50\u50ac\u5316\u6587\u7ae0\uff0c\u8ba9\u6211\u4eec\u4e00\u8d77\u6df1\u5165\u4e86\u89e3\u8be5\u9886\u57df\u3002<\/p>\n<p><strong>1\u3001Sci. Adv\uff1a\u5355\u5c42MoS<sub>2<\/sub>\u4e0aAu\u5355\u539f\u5b50\u914d\u4f4d\u7684\u81ea\u53d1\u5316\u5b66\u529f\u80fd\u5316<\/strong><\/p>\n<p>\u91d1\u5c5e\u548c\u534a\u5bfc\u4f532D\u8fc7\u6e21\u91d1\u5c5e\u4e8c\u7f9f\u57fa\u5316\u5408\u7269\uff08TMD\uff09\u7684\u8868\u9762\u529f\u80fd\u5316\u4e3b\u8981\u4f9d\u8d56\u4e8e\u7f3a\u9677\u90e8\u4f4d\u7684\u7269\u7406\u548c\u5316\u5b66\u5438\u9644\uff0c\u8fd9\u53ef\u80fd\u4f1a\u964d\u4f4e\u4fee\u9970\u4e8c\u7ef4\u6750\u6599\u7684\u6f5c\u5728\u5e94\u7528\uff0c\u56e0\u4e3a\u7ed3\u6784\u7f3a\u9677\u4f1a\u5bf9\u7535\u5b50\u548c\u5149\u7535\u7279\u6027\u9020\u6210\u5b9e\u8d28\u6027\u7684\u4e0d\u5229\u5f71\u54cd\u3002\u8fd1\u65e5\uff0c\u7f8e\u56fd\u5bbe\u5915\u6cd5\u5c3c\u4e9a\u5dde\u7acb\u5927\u5b66Akhil Dodda\u6559\u6388\u4e0e\u5df4\u897f\u9ea6\u80af\u9521\u6559\u4f1a\u5927\u5b66Daniel Grasseschi\u6559\u6388\u5408\u4f5c\u63d0\u51fa\u4e86\u4e00\u79cd\u81ea\u53d1\u7684\u65e0\u7f3a\u9677\u529f\u80fd\u5316\u65b9\u6cd5\uff0c\u5373\u901a\u8fc7S-Au-Cl\u914d\u4f4d\u914d\u5408\u7269\u5c06Au\u5355\u539f\u5b50\u8fde\u63a5\u5230\u534a\u5bfc\u4f53MoS<sub>2<\/sub>\uff081H\uff09\u7684\u5355\u5206\u5b50\u819c\u4e0a\u3002\u8be5\u7b56\u7565\u4e3a\u901a\u8fc7p\u578b\u63ba\u6742\u6765\u8c03\u8282MoS<sub>2<\/sub>\u7684\u8d39\u7c73\u80fd\u7ea7\u548c\u6fc0\u53d1\u5149\u8c31\uff0c\u63d0\u9ad8\u5355\u5c42MoS<sub>2<\/sub>\u7684\u70ed\u8fb9\u754c\u7535\u5bfc\uff0c\u4ece\u800c\u4fc3\u8fdb\u70ed\u8017\u6563\u63d0\u4f9b\u4e86\u4e00\u79cd\u6709\u6548\u4e14\u53ef\u63a7\u7684\u9014\u5f84\u3002\u8fd9\u79cd\u57fa\u4e8e\u914d\u4f4d\u7684\u65b9\u6cd5\u4e3aTMDs\u7684\u529f\u80fd\u5316\u63d0\u4f9b\u4e86\u4e00\u6761\u6709\u6548\u4e14\u65e0\u635f\u4f24\u7684\u9014\u5f84\uff0c\u53ef\u5e94\u7528\u4e8e\u5176\u5b83\u91d1\u5c5e\u6750\u6599\uff0c\u5e76\u53ef\u7528\u4e8e\u5355\u539f\u5b50\u50ac\u5316\u3001\u91cf\u5b50\u4fe1\u606f\u5668\u4ef6\u3001\u5149\u7535\u5b50\u548c\u589e\u5f3a\u4f20\u611f\u7b49\u9886\u57df\u3002\u8be5\u6210\u679c\u4ee5\u201c<strong>Spontaneous chemical functionalization via coordination of Au single atoms on monolayer MoS<sub>2<\/sub><\/strong>\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728<strong>Sci. Adv<\/strong>\u4e0a\u3002<strong>DOI: 10.1126\/sciadv.abc9308<\/strong><strong>\u3002<\/strong><\/p>\n<p><strong>\u539f\u6587\u94fe\u63a5\uff1a<\/strong><strong>https:\/\/advances.sciencemag.org\/content\/6\/49\/eabc9308.<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-214825 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/1-13.png\" alt=\"\" width=\"600\" height=\"476\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/1-13.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/1-13-300x238.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>2\u3001Chem. Rev\uff1a\u5143\u7d20\u5468\u671f\u8868\u4e0a\u7684\u5355\u539f\u5b50\u50ac\u5316\u5242<\/strong><\/p>\n<p>\u5177\u6709\u72ec\u7279\u53cd\u5e94\u6027\u7684\u5355\u539f\u5b50\u662f\u9176\u548c\u5747\u76f8\u50ac\u5316\u5242\u7684\u6838\u5fc3\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u5c3d\u7ba1\u8fd9\u4e00\u6982\u5ff5\u65e9\u5df2\u5b58\u5728\uff0c\u4f46\u5355\u539f\u5b50\u591a\u76f8\u50ac\u5316\u5242(SACs)\u76f4\u5230\u6700\u8fd1\u624d\u5f97\u5230\u91cd\u89c6\u3002\u5bbf\u4e3b\u6750\u6599\u4e0e\u5747\u76f8\u50ac\u5316\u5242\u4e2d\u7684\u914d\u4f53\u5177\u6709\u7c7b\u4f3c\u7684\u529f\u80fd\uff0c\u51b3\u5b9a\u4e86\u5355\u539f\u5b50\u7684\u7a33\u5b9a\u6027\u3001\u5c40\u90e8\u73af\u5883\u548c\u7535\u5b50\u6027\u8d28\uff0c\u4ece\u800c\u4e3a\u5b9a\u5236\u591a\u76f8\u50ac\u5316\u5242\u7684\u76ee\u6807\u5e94\u7528\u63d0\u4f9b\u4e86\u4e00\u4e2a\u5e73\u53f0\u3002\u5728\u77ed\u77ed\u5341\u5e74\u5185\uff0c\u4eba\u4eec\u76ee\u7779\u4e86\u8bb8\u591aSACs\u7684\u4f8b\u5b50\uff0c\u5b83\u4eec\u4ee5\u5176\u72ec\u7279\u7684\u53cd\u5e94\u6027\u6270\u4e71\u591a\u76f8\u50ac\u5316\u7684\u4e0d\u540c\u9886\u57df\uff0c\u5927\u5927\u4e30\u5bcc\u4e86\u4eba\u4eec\u5bf9\u8868\u9762\u5206\u5b50\u8fc7\u7a0b\u7684\u7406\u89e3\u3002\u5230\u76ee\u524d\u4e3a\u6b62\uff0cSAC\u8fd9\u4e2a\u672f\u8bed\u591a\u6307\u7684\u662f\u665a\u671f\u8fc7\u6e21\u91d1\u5c5e\u4f53\u7cfb\uff0c\u4f46\u4e5f\u6709\u8bb8\u591a\u5176\u4ed6\u5143\u7d20\u7684\u5355\u539f\u5b50\u8d77\u5173\u952e\u50ac\u5316\u4f5c\u7528\u7684\u4f8b\u5b50\u3002\u4e3a\u5e86\u795d\u8be5\u672f\u8bed\u5f15\u5165\u5341\u5468\u5e74\uff0c<strong>\u745e\u58eb\u82cf\u9ece\u4e16\u8054\u90a6\u7406\u5de5\u5b66\u9662<\/strong><strong>Javier Pe\u0301rez-Ram\u00edrez<\/strong><strong>\u6559\u6388<\/strong>\u63d0\u4f9b\u4e86\u4e00\u4e2aSACs\u7ec4\u6210\u7684\u767e\u79d1\u5168\u4e66\u3002\u901a\u8fc7\u5b9a\u4e49\u6700\u5e7f\u6cdb\u610f\u4e49\u4e0a\u7684\u5355\u539f\u5b50\u50ac\u5316\uff0c\u4f5c\u8005\u63a2\u7d22\u5168\u90e8\u5143\u7d20\u7684\u591a\u6837\u6027\uff0c\u901a\u8fc7\u6574\u4e2a\u5143\u7d20\u5468\u671f\u8868\u8fde\u63a5\u4e0d\u540c\u7684\u9886\u57df\uff0c\u5e76\u8ba8\u8bba\u5386\u53f2\u91cc\u7a0b\u7891\u548c\u6700\u8fd1\u7684\u53d1\u5c55\u3002\u7279\u522b\u662f\uff0c\u4f5c\u8005\u7814\u7a76\u4e86\u901a\u8fc7\u4e0d\u540c\u7684\u5355\u539f\u5b50-\u5bbf\u4e3b\u7ec4\u5408\u83b7\u5f97\u7684\u914d\u4f4d\u7ed3\u6784\u548c\u5173\u8054\u6027\u8d28\uff0c\u5e76\u5c06\u5b83\u4eec\u5728\u70ed\u3001\u7535\u548c\u5149\u50ac\u5316\u65b9\u9762\u7684\u4e3b\u8981\u5e94\u7528\u8054\u7cfb\u8d77\u6765\uff0c\u63ed\u793a\u4e86\u5143\u7d20\u7279\u5b9a\u8fdb\u5316\u3001\u5bbf\u4e3b\u8bbe\u8ba1\u548c\u7528\u9014\u65b9\u9762\u7684\u8d8b\u52bf\u3002\u6700\u540e\uff0c\u4f5c\u8005\u5f3a\u8c03\u4e86\u8be5\u9886\u57df\u7684\u524d\u6cbf\u9886\u57df\uff0c\u5305\u62ec\u591a\u91d1\u5c5e\u56ca\u6ce1\u3001\u539f\u5b50\u63a5\u8fd1\u63a7\u5236\u4ee5\u53ca\u591a\u6b65\u53cd\u5e94\u548c\u7ea7\u8054\u53cd\u5e94\u7684\u53ef\u80fd\u5e94\u7528\uff0c\u786e\u5b9a\u4e86\u6311\u6218\uff0c\u5e76\u63d0\u51fa\u4e86\u8fd9\u4e00\u84ec\u52c3\u53d1\u5c55\u9886\u57df\u7684\u672a\u6765\u53d1\u5c55\u65b9\u5411\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201c<strong>Single-Atom Catalysts across the Periodic Table<\/strong>\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728<strong>Chem. Rev<\/strong>\u4e0a\u3002<strong>DOI:<\/strong> <strong>10.1021\/acs.chemrev.0c00576<\/strong><strong>\u3002<\/strong><\/p>\n<p><strong>\u539f\u6587\u94fe\u63a5\uff1a<\/strong><strong>https:\/\/pubs.acs.org\/doi\/10.1021\/acs.chemrev.0c00576.<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-214826 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/2-10.png\" alt=\"\" width=\"287\" height=\"280\" \/><\/p>\n<p><strong>3\u3001Appl. Catal. B Environ\uff1a\u6c34\u70ed\u548c\u5149\u70ed\u5355\u539f\u5b50\u50ac\u5316\u7684\u5076\u8054\u53cd\u5e94\u4f7f\u6c34\u88c2\u89e3\u6210\u6c22<\/strong><\/p>\n<p>\u5149\u50ac\u5316\u6790\u6c22\u53cd\u5e94(PER)\u5b58\u5728\u592a\u9633\u80fd\u6548\u7387\u4e0d\u8db3\u3001\u8d35\u91d1\u5c5e\u8f85\u52a9\u50ac\u5316\u5242\u6210\u672c\u9ad8\u3001\u5bf9\u53ef\u89c1\u5149\u548c\u7ea2\u5916\u5149\u54cd\u5e94\u4f4e\u7684\u7f3a\u70b9\u3002\u8fd1\u65e5\uff0c<strong>\u6fb3\u5927\u5229\u4e9a\u79d1\u5ef7\u79d1\u6280\u5927\u5b66\u848b\u4e09\u5e73\u6559\u6388<\/strong>\u548c<strong>\u963f\u5fb7\u83b1\u5fb7\u5927\u5b66\u738b\u5c11\u5f6c\u6559\u6388\u4e0e\u57c3\u8fea\u65af\u79d1\u6587\u5927\u5b66\u5b59\u7ea2\u65d7\u6559\u6388\u5408\u4f5c<\/strong>\u62a5\u9053\u4e86\u5355\u539f\u5b50\u94f6\u63ba\u6742\u7684g-C<sub>3<\/sub>N<sub>4 <\/sub>(SAAg-g-CN)\u4f5c\u4e3a\u4e00\u79cd\u4f4e\u6210\u672c\u3001\u7a33\u5b9a\u7684\u50ac\u5316\u5242\uff0c\u5728PER\u548c\u592a\u9633\u80fd\u70ed\u8f85\u52a9PER\u8fc7\u7a0b\u4e2d\u5177\u6709\u6bd4Ag\u7eb3\u7c73\u9897\u7c92\u4fee\u9970\u7684g-C<sub>3<\/sub>N<sub>4<\/sub> (AgNP-g-CN)\u548cPtNP-g-C<sub>3<\/sub>N<sub>4<\/sub>\u66f4\u9ad8\u7684\u6d3b\u6027\u3002SAAg-g-CN\u5177\u6709\u4f18\u5f02\u7684\u6d3b\u6027\uff0c\u8fd9\u5f97\u76ca\u4e8e\u5176\u5438\u9644\u6c22\u539f\u5b50\u7684\u5409\u5e03\u65af\u81ea\u7531\u80fd(\u0394G<sub>H*<\/sub>)\u548cSAAg-g-CN\u7a33\u5b9a\u7684N-Ag\u952e\u7ed3\u6784\u300255\u2103\u65f6SAAg-g-CN\u7684PER\u901f\u7387\u662f25\u2103\u65f6\u76842\u500d\uff0c\u540c\u65f6AgNP-g-CN\u548cPtNP-g-CN\u7531\u4e8e\u91d1\u5c5eNPs\u7684\u56e2\u805a\u4f5c\u7528\uff0c\u5176PER\u6027\u80fd\u5747\u5448\u4e0b\u964d\u8d8b\u52bf\u3002\u8be5\u7814\u7a76\u8868\u660eSAAg-g-CN\u5177\u6709\u8d85\u9ad8\u7684\u5149\u6d3b\u6027\u548c\u5149\u70ed\u7a33\u5b9a\u6027\uff0c\u5728\u4fc3\u8fdb\u592a\u9633\u80fd\u7684\u5145\u5206\u5229\u7528\u65b9\u9762\u5177\u6709\u6f5c\u529b\u3002\u8be5\u6210\u679c\u4ee5\u201c<strong>Coupling Hydrothermal and Photothermal Single-atom Catalysis toward Excellent Water Splitting to Hydrogen<\/strong>\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728<strong>Appl. Catal. B Environ<\/strong>\u4e0a\u3002<strong>DOI<\/strong><strong>\uff1a<\/strong><strong>10.1016\/j.apcatb.2020.119660<\/strong><strong>\u3002<\/strong><\/p>\n<p><strong>\u539f\u6587\u94fe\u63a5\uff1a<\/strong><\/p>\n<p><strong>https:\/\/www.sciencedirect.com\/science\/article\/abs\/pii\/S0926337320310778?via%3Dihub.<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-214827 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/3-11.png\" alt=\"\" width=\"600\" height=\"323\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/3-11.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/3-11-300x162.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>4\u3001J. Am. Chem. Soc\uff1aFe-N-C\u5355\u539f\u5b50\u50ac\u5316\u5242\u5185\u5728\u53cd\u5e94\u4e2d\u95f4\u4f53\u8bf1\u5bfc\u7684\u81ea\u8c03\u8282\u6d3b\u6027<\/strong><\/p>\n<p>Fe-N-C\u5355\u539f\u5b50\u50ac\u5316\u5242\u5177\u6709\u5f88\u9ad8\u7684\u6c27\u8fd8\u539f\u6d3b\u6027\u3002\u7136\u800c\uff0c\u6d3b\u6027\u4e2d\u5fc3\u5982\u4f55\u4ecb\u5bfc\u50ac\u5316\u4f5c\u7528\u4ecd\u5b58\u5728\u4e89\u8bae\uff0c\u9884\u6d4b\u7684\u7535\u4f4d\u504f\u79bb\u5b9e\u9a8c\u7ed3\u679c\uff0c\u963b\u788d\u4e86\u7406\u60f3SAC\u7684\u53d1\u5c55\u3002\u8fd1\u65e5\uff0c<strong>\u5357\u6d0b\u7406\u5de5\u5927\u5b66\u5468\u6606\u6559\u6388<\/strong>\u5229\u7528\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\uff0c\u63d0\u51fa\u4e86\u4e00\u4e2aFe-N-C SACs\u4e0aORR\u7684\u5fae\u89c2\u52a8\u529b\u5b66\u6a21\u578b\uff0c\u63ed\u793a\u4e86\u5176\u5185\u90e8\u4e2d\u95f4\u4f53\u8bf1\u5bfc\u7684\u81ea\u8c03\u8282\u673a\u5236\u3002\u6a21\u62df\u7ed3\u679c\u8868\u660e\uff0c\u8be5\u4f53\u7cfb\u7684\u5355\u539f\u5b50Fe\u4f4dFe-N-C\u7684FeN<sub>4<\/sub>\u4e2d\u5fc3\u88ab0.28 ~ 1.00 V\u7684\u4e2d\u95f4\u4f53OH*\u8986\u76d6\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u8fd9\u6837\u7684OH*\u6210\u4e3a\u6d3b\u6027\u90e8\u5206Fe(OH)N<sub>4<\/sub>\u7684\u4e00\u90e8\u5206\uff0c\u5e76\u80fd\u4f18\u5316Fe\u4f4d\u70b9\u4e0a\u7684\u4e2d\u95f4\u7ed1\u5b9a\uff0c\u663e\u793a\u51fa~0.88 V\u7684\u7406\u8bba\u534a\u6ce2\u7535\u4f4d\u3002\u504f\u7535\u6d41\u5bc6\u5ea6\u5206\u6790\u8868\u660e\uff0c\u4e0e\u6e38\u79bb\u7535\u6d41\u76f8\u6bd4\uff0c\u4e8c\u8005\u7684\u7ed3\u5408\u8def\u5f84\u5360\u4e3b\u5bfc\u5730\u4f4d\u3002\u6b64\u5916\uff0c\u4f5c\u8005\u8fd8\u516c\u5e03\u4e86Mn-N-C\u548cCo-N-C SACs\u4e0a\u7684ORR\u3002\u8fd9\u4e00\u5de5\u4f5c\u8bc1\u660e\u4e86\u8bc4\u4f30\u5355\u539f\u5b50\u50ac\u5316\u4e2d\u5185\u5728\u4e2d\u95f4\u4f53\u6548\u5e94\u7684\u5fc5\u8981\u6027\uff0c\u5e76\u4e3a\u9ad8\u6027\u80fdSACs\u7684\u5408\u7406\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u6307\u5bfc\u4f5c\u7528\u3002\u8be5\u6210\u679c\u4ee5\u201c<strong>Self-Adjusting Activity Induced by Intrinsic Reaction Intermediate in Fe-N-C Single-Atom Catalysts<\/strong>\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728<strong>J. Am. Chem. Soc<\/strong>\u4e0a\u3002<strong>DOI:<\/strong> <strong>\/10.1021\/jacs.9b07712<\/strong><strong>\u3002<\/strong><\/p>\n<p><strong>\u539f\u6587\u94fe\u63a5\uff1a<\/strong><strong>https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.9b07712.<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-214828 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/4-11.png\" alt=\"\" width=\"418\" height=\"303\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/4-11.png 418w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/4-11-300x217.png 300w\" sizes=\"(max-width: 418px) 100vw, 418px\" \/><\/p>\n<p><strong>5\u3001Materials Today\uff1a\u5355\u539f\u5b50\u4e0d\u662f\u5b64\u7acb\u7684:\u5355\u539f\u5b50\u50ac\u5316\u4e2d\u7684\u91d1\u5c5e-\u8f7d\u4f53\u76f8\u4e92\u4f5c\u7528<\/strong><\/p>\n<p>\u5355\u539f\u5b50\u50ac\u5316\u5242\uff08SACs\uff09\u901a\u8fc7\u4f18\u5316\u6d3b\u6027\u4e2d\u5fc3\u7684\u66b4\u9732\uff0c\u63d0\u9ad8\u4e86\u50ac\u5316\u5242\u7684\u672c\u5f81\u6d3b\u6027\u548c\u9009\u62e9\u6027\uff0c\u8fd1\u5e74\u6765\u53d7\u5230\u4e86\u591a\u76f8\u50ac\u5316\u548c\u7535\u50ac\u5316\u9886\u57df\u7684\u5173\u6ce8\u3002SACs\u7684\u5408\u6210\u53ca\u5176\u884c\u4e3a\u7814\u7a76\u6709\u52a9\u4e8e\u9610\u660e\u51e0\u4e2a\u5173\u952e\u50ac\u5316\u53cd\u5e94\u7684\u52a8\u529b\u5b66\u548c\u70ed\u529b\u5b66\u3002\u7136\u800c\uff0c\u4e86\u89e3\u91d1\u5c5e\u5355\u539f\u5b50\u6d3b\u6027\u4e2d\u5fc3\u4e0e\u8f7d\u4f53\u57fa\u8d28\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u662f\u5355\u539f\u5b50\u50ac\u5316\u5242\u53d1\u5c55\u9762\u4e34\u7684\u4e00\u4e2a\u91cd\u5927\u6311\u6218\u3002\u8fd9\u79cd\u76f8\u4e92\u4f5c\u7528\u5bf9\u4e8e\u4f18\u5316\u53cd\u5e94\u52a8\u529b\u5b66\u548c\u6700\u5927\u9650\u5ea6\u5730\u63d0\u9ad8\u50ac\u5316\u6027\u80fd\u81f3\u5173\u91cd\u8981\u3002<strong>\u6cd5\u56fd\u8499\u5f7c\u5229\u57c3\u7b2c\u4e00\u5927\u5b66<\/strong><strong>Damien Voiry<\/strong><strong>\u6559\u6388<\/strong>\u63a2\u8ba8\u4e86\u5355\u539f\u5b50\u50ac\u5316\u7684\u6700\u65b0\u8fdb\u5c55\uff0c\u5e76\u5bf9\u91d1\u5c5e-\u8f7d\u4f53\u76f8\u4e92\u4f5c\u7528\u7684\u7814\u7a76\u73b0\u72b6\u8fdb\u884c\u4e86\u6279\u5224\u6027\u5206\u6790\u3002\u6700\u540e\uff0c\u4f5c\u8005\u8fd8\u8ba8\u8bba\u4e86\u8be5\u9886\u57df\u76ee\u524d\u9762\u4e34\u7684\u6311\u6218\u548c\u672a\u6765\u7684\u53d1\u5c55\u673a\u9047\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201c<strong>Single atom is not alone: Metal\u2013support<\/strong><\/p>\n<p><strong>interactions in single-atom catalysis<\/strong>\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728<strong>Materials Today<\/strong>\u7684\u671f\u520a\u4e0a\u3002<strong>DOI:<\/strong> <strong>10.1016\/j.mattod.2020.07.002<\/strong><strong>\u3002<\/strong><\/p>\n<p><strong>\u539f\u6587\u94fe\u63a5\uff1a<\/strong><\/p>\n<p><strong>https:\/\/www.sciencedirect.com\/science\/article\/abs\/pii\/S1369702120302285?via%3Dihub.<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-214829 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/5-6.png\" alt=\"\" width=\"600\" height=\"488\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/5-6.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/5-6-300x244.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>6\u3001ACS Catal\uff1a\u5355\u539f\u5b50\u50ac\u5316\u5242\u4e0a\u975e\u5e38\u89c4\u6c27\u8fd8\u539f\u53cd\u5e94\u673a\u7406\u53ca\u6bd4\u4f8b\u5173\u7cfb<\/strong><\/p>\n<p>\u7535\u5316\u5b66\u6c27\u8fd8\u539f\u53cd\u5e94\uff08ORR\uff09\u673a\u7406\u4e00\u822c\u8ba4\u4e3a\u662fO<sub>2<\/sub>\u2192OOH*\u2192O*\u2192OH*\u2192H<sub>2<\/sub>O\uff08O*\u673a\u7406\uff09\u3002\u8fd9\u79cdO*\u673a\u5236\u9884\u6d4b\u4e86Co\/N\/C\u7684\u5408\u7406ORR\u534a\u6ce2\u7535\u4f4d\uff08E<sub>1\/2<\/sub>\uff09\uff0c\u4f46\u4f4e\u4f30\u4e86Fe\/N\/C\u7684ORR\u534a\u6ce2\u7535\u4f4d\u3002\u5728\u6b64\uff0c<strong>\u65b0\u52a0\u5761\u5357\u6d0b\u7406\u5de5\u5927\u5b66\u674e\u8ff0\u5468\u6559\u6388<\/strong>\u63d0\u51fa\u4e86\u4e00\u79cd\u975e\u5e38\u89c4\u76842OH*ORR\u673a\u5236\uff08O<sub>2<\/sub>\u2192OOH*\u21922OH*\u2192OH*\u2192H<sub>2<\/sub>O\uff09\uff0c\u7531\u4e8e2OH*\u548cO*\u7684\u81ea\u7531\u80fd\uff08\u0394G\uff09\u662f\u76f8\u7b49\u7684\uff0c\u6839\u636e\u8457\u540d\u7684\u6bd4\u4f8b\u5173\u7cfb\uff1a2\u0394G\uff08OH*\uff09=\u0394G\uff08O*\uff09\u3002\u8fd9\u79cd\u6bd4\u4f8b\u5173\u7cfb\u9002\u7528\u4e8e\u6d3b\u6027\u4e2d\u5fc3\u63a5\u8fd1\u8fde\u7eed\u7684\u4f20\u7edf\u50ac\u5316\u5242\u3002\u4f5c\u8005\u53d1\u73b0\u5728\u5355\u539f\u5b50\u50ac\u5316\u5242\uff08Me\/N\/C\uff0cMe=Fe\uff0cCo\u7b49\uff09\u4e0a\uff0c\u0394G\uff082OH*\uff09=\u0394G\uff08O*\uff09+1.5eV\uff0c\u8fd9\u662f\u4e00\u4e2a\u4e0d\u53ef\u5ffd\u89c6\u7684\u6bd4\u4f8b\u5173\u7cfb\u3002\u8003\u8651\u5230O*\u548c2OH*\u4e24\u79cd\u673a\u7406\uff0cCo\/N\/C\u548cFe\/N\/C\u7684ORR E<sub>1\/2<\/sub>\u4e0e\u5b9e\u9a8c\u7ed3\u679c\u975e\u5e38\u7b26\u5408\u3002\u8fd9\u9879\u5de5\u4f5c\u63ed\u793a\u4e86\u5355\u539f\u5b50\u50ac\u5316\u4e2dORR\u53cd\u5e94\u673a\u7406\u548c\u6bd4\u4f8b\u5173\u7cfb\u7684\u7ed3\u6784\u4f9d\u8d56\u6027\uff0c\u5bf9\u5176\u5b83\u5355\u539f\u5b50\u50ac\u5316\u53cd\u5e94\u5982\u6790\u6c27\u3001N<sub>2<\/sub>\u8fd8\u539f\u7b49\u4e5f\u5177\u6709\u542f\u53d1\u610f\u4e49\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201c<strong>Unconventional Oxygen Reduction Reaction Mechanism and Scaling Relation on Single-Atom Catalysts<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u8457\u540d\u671f\u520a<strong>ACS Catal<\/strong>\u4e0a\u3002<strong>DOI:<\/strong> <strong>10.1021\/acscatal.0c00815<\/strong><strong>\u3002<\/strong><\/p>\n<p><strong>\u539f\u6587\u94fe\u63a5\uff1a<\/strong><strong>https:\/\/pubs.acs.org\/doi\/10.1021\/acscatal.0c00815.<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-214830 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/6-2.png\" alt=\"\" width=\"500\" height=\"273\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/6-2.png 500w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/6-2-300x164.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p><strong>7\u3001Materials Today\uff1a\u5355\u94dc\u539f\u5b50\u5728\u6c34\u51dd\u80f6\u6846\u67b6\u4e2d\u7684\u8d85\u5206\u5b50\u9650\u5236\u9ad8\u539f\u5b50\u5229\u7528\u7387\u6c27\u8fd8\u539f\u7535\u50ac\u5316<\/strong><\/p>\n<p>\u5355\u539f\u5b50\u50ac\u5316\u5df2\u6210\u4e3a\u591a\u76f8\u50ac\u5316\u9886\u57df\u7684\u4e00\u4e2a\u524d\u6cbf\u9886\u57df\u3002\u4eba\u4eec\u4e00\u76f4\u81f4\u529b\u4e8e\u5f00\u53d1\u5408\u6210\u5355\u539f\u5b50\u50ac\u5316\u5242\u7684\u591a\u79cd\u65b9\u6cd5\uff0c\u7136\u800c\uff0c\u8be5\u9886\u57df\u7684\u4e3b\u8981\u76ee\u6807\u662f\u4ece\u6839\u672c\u4e0a\u4e86\u89e3\u50ac\u5316\u5242\u7684\u590d\u6742\u6027\u53ca\u5176\u5728\u7279\u5b9a\u53cd\u5e94\u4e2d\u7684\u6027\u80fd\uff0c\u5e76\u5bf9\u4e0d\u540c\u7684\u6280\u672f\u8fdb\u884c\u8865\u5145\u3002\u8fd1\u65e5\uff0c<strong>\u5fb7\u514b\u8428\u65af\u5927\u5b66\u5965\u65af\u6c40\u5206\u6821\u4f59\u6842\u534e\u6559\u6388\u548c\u56db\u5ddd\u5927\u5b66\u8096\u4e39\u6559\u6388\u5408\u4f5c<\/strong>\u5f00\u53d1\u4e86\u4e00\u79cd\u8d85\u5206\u5b50\u6c34\u51dd\u80f6\u7b56\u7565\uff0c\u53ef\u4ee5\u6709\u6548\u5730\u5206\u79bb\u4e92\u8fde\u78b3\u7ea4\u7ef4\u4e0a\u7684\u94dc\u539f\u5b50\uff0c\u4f5c\u4e3a\u78b1\u6027\u6c27\u8fd8\u539f\u53cd\u5e94\uff08ORR\uff09\u7684\u9ad8\u6548\u7535\u50ac\u5316\u5242\u3002\u4f5c\u8005\u7528X\u5c04\u7ebf\u5438\u6536\u5149\u8c31\u548c\u50cf\u5dee\u6821\u6b63\u626b\u63cf\u900f\u5c04\u7535\u955c\u8bc1\u5b9e\u4e86Cu-N<sub>2<\/sub>\u7684\u914d\u4f4d\u72b6\u6001\u548c\u539f\u5b50\u8272\u6563\u3002\u6b64\u5916\uff0c\u5229\u7528\u626b\u63cf\u7535\u5316\u5b66\u663e\u5fae\u955c\u7684\u8868\u9762\u63a2\u8be2\u6a21\u5f0f\uff08SI-SECM\uff09\u6280\u672f\u7814\u7a76\u4e86\u53c2\u4e0e\u50ac\u5316\u7684Cu\uff08I\uff09\u4f4d\u4e0e\u603bCu\uff08I\uff09\u4f4d\u4e4b\u6bd4\u7684\u539f\u5b50\u5229\u7528\u7387\uff08\u03b7<sub>atom<\/sub>\uff09\u3002\u5408\u6210\u7684Cu-SACs\u7684\u539f\u5b50\u5229\u7528\u7387\u572890%\u4ee5\u4e0a\uff0c\u4e0eSACs\u7684\u7406\u8bba\u503c\uff08100%\uff09\u975e\u5e38\u63a5\u8fd1\uff0c\u8fd9\u610f\u5473\u7740\u6240\u63d0\u51fa\u7684\u8d85\u5206\u5b50\u65b9\u6cd5\u53ef\u4ee5\u5b9e\u73b0Cu\u4f4d\u7684\u8d85\u9ad8\u88f8\u9732\u3002SI-SECM\u539f\u4f4d\u65f6\u95f4\u5206\u8fa8\u6ef4\u5b9a\u548c\u7b2c\u4e00\u4e3b\u5143\u8ba1\u7b97\u8fdb\u4e00\u6b65\u8868\u660e\uff0c\u5728\u5b64\u7acb\u7684Cu-N<sub>2<\/sub>\u4f4d\u70b9\u4e0a\u5177\u6709\u663e\u8457\u7684ORR\u6d3b\u6027\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201c<strong>Supramolecular confinement of single Cu atoms in hydrogel frameworks for oxygen reduction electrocatalysis with high atom utilization<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u8457\u540d\u671f\u520a<strong>Materials Today<\/strong>\u4e0a\u3002<strong>DOI:<\/strong> <strong>10.1016\/j.mattod.2019.10.006<\/strong><strong>\u3002<\/strong><\/p>\n<p><strong>\u539f\u6587\u94fe\u63a5\uff1a<\/strong><\/p>\n<p><strong>https:\/\/www.sciencedirect.com\/science\/article\/abs\/pii\/S1369702119308089?via%3Dihub.<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-214831 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/7-3.png\" alt=\"\" width=\"600\" height=\"385\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/7-3.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/7-3-300x193.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>8\u3001ACS Catal\uff1a\u7532\u9187\u5728\u6a21\u578b\u5355\u539f\u5b50\u50ac\u5316\u5242\u4e0a\u7684\u4f4e\u6e29\u6c27\u5316\u5236\u7532\u919b\uff1aFe<sub>3<\/sub>O<sub>4<\/sub>\uff08001\uff09\u4e0a\u7684Pd\u539f\u5b50<\/strong><\/p>\n<p>\u5355\u539f\u5b50\u50ac\u5316\u7531\u4e8e\u5728\u63d0\u9ad8\u9009\u62e9\u6027\u3001\u53cd\u5e94\u6027\u548c\u50ac\u5316\u5242\u6210\u672c\u7b49\u65b9\u9762\u7684\u6f5c\u529b\uff0c\u4e00\u76f4\u662f\u4eba\u4eec\u65e5\u76ca\u5173\u6ce8\u7684\u8bdd\u9898\u3002\u7136\u800c\uff0c\u5728\u73b0\u5b9e\u7684\u53cd\u5e94\u6761\u4ef6\u4e0b\uff0c\u5355\u539f\u5b50\u50ac\u5316\u5242\u4ecd\u7136\u96be\u4ee5\u8868\u5f81\uff0c\u8fd9\u5bfc\u81f4\u4e86\u5bf9\u5355\u539f\u5b50\u6027\u80fd\u7684\u4e89\u8bae\uff0c\u9700\u8981\u8fdb\u884c\u6a21\u578b\u7814\u7a76\u3002\u8fd1\u65e5\uff0c<strong>\u7f8e\u56fd\u897f\u5317\u592a\u5e73\u6d0b\u56fd\u5bb6\u5b9e\u9a8c\u5ba4<\/strong><strong>Roger Rousseau<\/strong><strong>\u6559\u6388\u548c<\/strong><strong>Zdenek Dohn\u00e1lek<\/strong><strong>\u6559\u6388<\/strong>\u5408\u4f5c\u7814\u7a76\u4e86\u5728\u8d85\u9ad8\u771f\u7a7a\u6761\u4ef6\u4e0b\u7532\u9187\u4e0eFe<sub>3<\/sub>O<sub>4<\/sub>\uff08001\uff09\u8d1f\u8f7d\u7684\u5355\u94af\u539f\u5b50\u7684\u53cd\u5e94\u3002\u5728\u4e0d\u542b\u94af\u7684Fe<sub>3<\/sub>O<sub>4<\/sub>\uff08001\uff09\u4e0a\uff0c\u4e00\u5c0f\u90e8\u5206\u7532\u9187\u5728516 K\u4e0b\u901a\u8fc7\u7532\u6c27\u57fa\u4e2d\u95f4\u4f53\u8f6c\u5316\u4e3a\u7532\u919b\u3002\u5355\u94af\u539f\u5b50\u7684\u52a0\u5165\u4f7fC-H\u952e\u65ad\u88c2\u7684\u963b\u788d\u964d\u4f4e\u4e862\u500d\uff0c\u5bfc\u81f4\u7532\u919b\u5728290 K\u89e3\u5438\u3002\u4f46\u662f\uff0c\u5728\u7532\u9187\u5b58\u5728\u4e0b\uff0cPd\u539f\u5b50\u5728300 K\u4e0b\u5f00\u59cb\u70e7\u7ed3\uff0c\u800c\u94af\u56e2\u7c07\u5219\u4e0d\u8868\u73b0\u51fa\u76f8\u540c\u7684\u5316\u5b66\u6027\u8d28\u3002\u5355\u539f\u5b50\u5927\u5927\u964d\u4f4e\u4e86\u7532\u9187\u6c27\u5316\u7684\u963b\u788d\uff0c\u5c3d\u7ba1\u5b83\u4eec\u7684\u7a33\u5b9a\u6027\u4ecd\u7136\u662f\u4e2a\u95ee\u9898\u3002\u8be5\u9879\u7814\u7a76\u6210\u679c\u4ee5\u201c<strong>Low Temperature Oxidation of Methanol to Formaldehyde on a Model Single Atom Catalyst: Pd Atoms on Fe<sub>3<\/sub>O<sub>4<\/sub>(001)<\/strong>\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728<strong>ACS Catal<\/strong>\u4e0a\u3002<strong>DOI:<\/strong> <strong>10.1021\/acscatal.9b03891<\/strong><strong>\u3002<\/strong><\/p>\n<p><strong>\u539f\u6587\u94fe\u63a5\uff1a<\/strong><strong>https:\/\/pubs.acs.org\/doi\/10.1021\/acscatal.9b03891.<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-214832 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/8.png\" alt=\"\" width=\"600\" height=\"354\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/8.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/8-300x177.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u672c\u6587\u7531\u79d1\u7814\u767e\u6653\u751f\u4f9b\u7a3f\u3002<\/p>\n<p>\u672c\u5185\u5bb9\u4e3a\u4f5c\u8005\u72ec\u7acb\u89c2\u70b9\uff0c\u4e0d\u4ee3\u8868\u6750\u6599\u4eba\u7f51\u7acb\u573a\u3002<\/p>\n<p>\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u81ea\u4ece2011\u5e74\u201c\u5355\u539f\u5b50\u50ac\u5316\u201d\u88ab\u4e2d\u56fd\u79d1\u5b66\u9662\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u5f20\u6d9b\u9662\u58eb\u3001\u6e05\u534e\u5927\u5b66\u674e\u96bd\u6559\u6388\u53ca\u7f8e\u56fd\u4e9a\u5229\u6851\u90a3\u5dde\u7acb\u5927\u5b66\u5218\u666f\u6708\u6559\u6388\u5171\u540c\u63d0\u51fa\u4ee5\u540e\uff0c\u5728\u77ed\u77ed\u5341\u5e74\u95f4\uff0c\u5355\u539f\u5b50\u50ac\u5316\u8fc5\u901f\u6210&#8230;<\/p>\n","protected":false},"author":11454,"featured_media":214833,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1187],"tags":[],"class_list":["post-214824","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zhuanlan"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/214824"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=214824"}],"version-history":[{"count":1,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/214824\/revisions"}],"predecessor-version":[{"id":214834,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/214824\/revisions\/214834"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/214833"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=214824"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=214824"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=214824"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}