{"id":215013,"date":"2020-12-25T06:35:05","date_gmt":"2020-12-24T22:35:05","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=215013"},"modified":"2020-12-24T19:35:22","modified_gmt":"2020-12-24T11:35:22","slug":"%e6%9c%b1%e8%8b%b1%e6%88%b4%e9%bb%8e%e6%98%8enano-energy%ef%bc%9am-sa-nc%e7%9a%84%e9%80%9a%e7%94%a8%e5%a4%9a%e7%b1%b3%e8%af%ba%e7%ad%96%e7%95%a5%e5%88%b6%e5%a4%87%e5%8f%8anin4-%e6%9e%84%e5%9e%8b","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=215013","title":{"rendered":"\u6731\u82f1&#038;\u6234\u9ece\u660eNano Energy\uff1aM-SA\/NC\u7684\u901a\u7528\u591a\u7c73\u8bfa\u7b56\u7565\u5236\u5907\u53caNiN4 \u6784\u578b\u4e2dN 2s 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<\/b><\/strong><strong><b>Ni-SA\/NC\u7684\u5408\u6210\u793a\u610f\u56fe<\/b><\/strong><strong><b>\u53ca\u5f62\u8c8c\u8868\u5f81<\/b><\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-215075\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/1-29.jpg\" alt=\"\" width=\"600\" height=\"709\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/1-29.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/1-29-254x300.jpg 254w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a\uff09Ni-SA\/NC\u7684\u5408\u6210\u793a\u610f\u56fe\u3002<\/p>\n<p>b-e\uff09Ni-SA\/NC\u7684SEM\u3001TEM\u3001HRTEM\u548cSAED\u56fe\u50cf\u3002<\/p>\n<p>f\uff09Ni-SA\/NC\u7684C\uff08\u7ea2\u8272\uff09\u3001Ni\uff08\u84dd\u8272\uff09\u548cN\uff08\u7eff\u8272\uff09\u7684STEM\u56fe\u50cf\u53ca\u5176\u5bf9\u5e94\u7684\u5143\u7d20\u5206\u5e03\u3002<\/p>\n<p>g\uff09Ni-SA\/NC\u7684HAADF-STEM\u56fe\u50cf\u3002<\/p>\n<p><strong><b>\u56fe2 <\/b><\/strong><strong><b>Ni-SA\/NC\u50ac\u5316\u5242\u7684\u5316\u5b66\u72b6\u6001\u548c\u539f\u5b50\u914d\u4f4d\u73af\u5883<\/b><\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-215076\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/2-30.jpg\" alt=\"\" width=\"600\" height=\"440\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/2-30.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/2-30-300x220.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a\uff09Ni-SA\/NC\u548c\u5bf9\u7167\u6837\u54c1\u7684Ni K\u8fb9 XANES\u5149\u8c31\u3002<\/p>\n<p>b\uff09\u5728R\u7a7a\u95f4\u4e2dNi-SA\/NC\u548c\u5bf9\u7167\u6837\u54c1\u7684Ni K\u8fb9\u7684EXAFS\u5149\u8c31\u7684FT k<sup>3<\/sup>\u52a0\u6743\u03c7\uff08k\uff09\u51fd\u6570\u3002<\/p>\n<p>c\uff09Ni-SA\/NC\u7684Ni K\u8fb9\u7684EXAFS\u5149\u8c31\u7684FT k3\u52a0\u6743\u03c7\uff08k\uff09\u51fd\u6570\u7684Ni\u2013N\u62df\u5408\u66f2\u7ebf\uff08\u865a\u7ebf\u4ee3\u8868\u6240\u83b7\u5f97\u7684\u6570\u636e\uff0c\u800c\u5706\u7ebf\u8868\u793a\u62df\u5408\u66f2\u7ebf\uff09\u3002<\/p>\n<p>d\uff09Ni-SA\/NC\u7684N K\u8fb9XANES\u5149\u8c31\u3002<\/p>\n<p><strong><b>\u56fe3 M-SA\/NC<\/b><\/strong><strong><b>\u5236\u5907\u673a\u7406<\/b><\/strong><strong><b>\u5206\u6790<\/b><\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-215077\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/3-29.jpg\" alt=\"\" width=\"600\" height=\"317\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/3-29.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/3-29-300x159.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a-c\uff09P-Ni-S-SN\u5728250\u3001350\u81f3600\u00b0C\u70ed\u89e3\u7684\u539f\u4f4dTEM\u56fe\u50cf\u3002<\/p>\n<p>d\uff09\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u4eceMS-ETEM\u5f97\u5230\u7684\u70ed\u89e3P-Ni-S-SN\u4ea7\u751f\u7684\u6c14\u4f53\u91cf\u3002<\/p>\n<p>e\uff09P-Ni-S-SN\u548cP-Ni-S\u7684\u70ed\u91cd\u66f2\u7ebf\u3002<\/p>\n<p>f\uff09P-Ni-S-SN\u70ed\u89e3\u540e\u77f3\u82f1\u7ba1\u672b\u7aef\u7269\u8d28\u6c89\u79ef\u7684XRD\u56fe\u8c31\u3002<\/p>\n<p><strong><b>\u56fe4 <\/b><\/strong><strong><b>Ni-SA\/NC\u5728<\/b><\/strong><strong><b>H\u578b\u548c<\/b><\/strong><strong><b>\u6db2\u6d41\u6c60<\/b><\/strong><strong><b>\u4e2d<\/b><\/strong><strong><b>\u8bc4\u4f30CO<\/b><\/strong><strong><sub><b>2<\/b><\/sub><\/strong><strong><b>RR\u6027\u80fd<\/b><\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-215078\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/3-30.jpg\" alt=\"\" width=\"600\" height=\"317\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/3-30.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/3-30-300x159.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/> <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-215079\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/4-28.jpg\" alt=\"\" width=\"600\" height=\"286\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/4-28.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/4-28-300x143.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a\uff09LSV\u66f2\u7ebf\u00a0\uff08H\u578b\u6c60\uff09\u3002<\/p>\n<p>b\uff09\u5728\u4e0d\u540c\u65bd\u52a0\u7535\u538b\u4e0bCO\u4ea7\u7387\u7684FE\u66f2\u7ebf\uff08H\u578b\u6c60\uff09\u3002<\/p>\n<p>c\uff09CO\u4ea7\u7387\u7684\u5854\u83f2\u5c14\u66f2\u7ebf\uff08H\u578b\u6c60\uff09\u3002<\/p>\n<p>d\uff09Ni-SA\/NC\u5728-0.66 V\u7684\u7535\u538b\u4e0b\u8fdb\u884c20 h\u7684\u957f\u671f\u7a33\u5b9a\u6027\u6d4b\u8bd5\uff08H\u578b\u6c60\uff09\u3002<\/p>\n<p>e\uff09LSV\u66f2\u7ebf\uff08\u6db2\u6d41\u6c60\uff09\u3002<\/p>\n<p>f\uff09\u5728\u4e0d\u540c\u65bd\u52a0\u7535\u538b\u4e0bCO\u4ea7\u7387\u7684FE\u66f2\u7ebf\uff08\u6db2\u6d41\u6c60\uff09\u3002<\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>5<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>\u7406\u8bba\u8ba1\u7b97<\/b><\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-215080\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/5-20.jpg\" alt=\"\" width=\"600\" height=\"520\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/5-20.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/5-20-300x260.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a\uff09\u5728NiN<sub>4<\/sub>-PD-2-N3\u3001NiN<sub>4<\/sub>-PL-2-N4\u548cNiN<sub>4<\/sub>-GH-2-N3\u4f4d\u70b9\u5c06CO<sub>2<\/sub>\u8f6c\u5316\u4e3aCO\u7684\u81ea\u7531\u80fd\u56fe\u3002<\/p>\n<p>b\uff09NiN<sub>4<\/sub>-PD-2-N3\u3001NiN<sub>4<\/sub>-PL-2-N4\u548cNiN<sub>4<\/sub>-GH-2-N3\u4f4d\u70b9\u7684\u504f\u6001\u5bc6\u5ea6\uff08PDOS\uff09\u3002 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src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/6-11.jpg\" alt=\"\" width=\"600\" height=\"600\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/6-11.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/6-11-150x150.jpg 150w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/12\/6-11-300x300.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a-h\uff09\u5206\u522b\u4e3aM-SA\/NC\uff0cM = Fe\u3001Co\u3001Mn\u3001Mo\u3001Pd\u3001FeCo\u3001FeNi\u3001FeCoNi\u7684HAADF-STEM\u56fe\u50cf\u3002\u6bd4\u4f8b\u5c3a\uff1a2 nm\u3002<\/p>\n<p>i\uff09~20 g 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2s\u7535\u5b50\u6210\u5206\u8f83\u9ad8\uff0c\u4e3b\u8981\u7531\u4e8e\u5176\u90bb\u8fd1\u7684\u5421\u54afN\u9020\u6210\u7684\u9ad8\u7535\u5b50\u79ef\u7d2f\uff0c\u5177\u6709\u8f83\u5f3a\u7684\u5f62\u6210COOH*\u7684\u80fd\u529b\u3002\u56e2\u961f\u8ba4\u4e3a\uff0c\u8fd9\u4e00\u53d1\u73b0\u4e0d\u4ec5\u4e3a\u5f00\u53d1\u5355\u539f\u5b50\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u4e00\u79cd\u7b80\u5355\u800c\u6709\u4ef7\u503c\u7684\u65b9\u6cd5\uff0c\u800c\u4e14\u5bf9\u5421\u54afN\u8bf1\u5bfcCO<sub>2<\/sub>RR\u7684\u7535\u5b50\u8f6c\u79fb\u673a\u5236\u6709\u4e86\u66f4\u6df1\u523b\u7684\u8ba4\u8bc6\u3002<\/p>\n<p><strong><b>\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><a href=\"https:\/\/www.sciencedirect.com\/science\/article\/pii\/S2211285520312623\"><u>Universal Domino Reaction Strategy for Mass Production of Single-atom Metal-nitrogen Catalysts for Boosting CO<\/u><u><sub>2<\/sub><\/u><u>\u00a0Electroreduction<\/u><\/a>\uff08Nano Energy\uff0c 2020\uff0cDOI:10.1016\/j.nanoen.2020.105689\uff09<\/p>\n<p>\u672c\u6587\u7531<strong><b>\u6728\u6587\u97ec<\/b><\/strong>\u7ffb\u8bd1\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c<a href=\"mailto:\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\"><u>\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com<\/u><\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 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