{"id":215743,"date":"2021-01-08T06:30:09","date_gmt":"2021-01-07T22:30:09","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=215743"},"modified":"2021-01-07T18:07:55","modified_gmt":"2021-01-07T10:07:55","slug":"carbon%ef%bc%9a%e4%b8%80%e7%a7%8d%e9%ab%98%e5%90%ab%e6%b0%ae%e7%90%83%e5%bd%a2%e5%a4%9a%e5%ad%94%e7%a2%b3%e7%94%a8%e4%ba%8e%e6%8f%90%e9%ab%98%e8%b6%85%e7%ba%a7%e7%94%b5%e5%ae%b9%e5%99%a8%e6%80%a7","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=215743","title":{"rendered":"Carbon\uff1a\u4e00\u79cd\u9ad8\u542b\u6c2e\u7403\u5f62\u591a\u5b54\u78b3\u7528\u4e8e\u63d0\u9ad8\u8d85\u7ea7\u7535\u5bb9\u5668\u6027\u80fd"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/b><\/strong><\/p>\n

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\u8fd1\u65e5\uff0c\u5317\u4eac\u5316\u5de5\u5927\u5b66\u6f58\u519b\u9752\u6559\u6388\u56e2\u961f\u901a\u8fc7\u8bbe\u8ba1\u5408\u6210\u5177\u67096\u4e2a\u6c2e\u539f\u5b50\u7684\u6709\u673a\u7fa7\u9178\u914d\u4f53\u5e76\u5236\u5907\u6210\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u6750\u6599\uff0c\u5f97\u5230\u542b\u6c2e\u7684MOFs\u524d\u9a71\u4f53\uff0c\u518d\u901a\u8fc7\u9ad8\u6e29\u78b3\u5316\u5f97\u5230\u5177\u6709\u9ad8\u542b\u6c2e\u91cf\u7279\u70b9\u7684\u591a\u5b54\u78b3\u6750\u6599NSPC\uff0c\u5bf9\u5176\u5f62\u8c8c\u7ed3\u6784\u7b49\u8fdb\u884c\u8868\u5f81\uff0c\u5176\u6c2e\u542b\u91cf\u9ad8\u8fbe11.37 at.%\uff0c\u5448\u5747\u5300\u7403\u72b6\u4e14\u6709\u8f83\u5927\u7684\u6bd4\u8868\u9762\u79ef\uff081826 m2<\/sup>g-1<\/sup>\uff09\u3002\u7814\u7a76\u5176\u7535\u5316\u5b66\u6027\u80fd\u53d1\u73b0\uff0cNSPC\u65e0\u8bba\u662f\u5728\u78b1\u6027\u8fd8\u662f\u9178\u6027\u4f53\u7cfb\u4e2d\u90fd\u8868\u73b0\u51fa\u53cc\u7535\u5c42\u50a8\u8377\u548c\u8d5d\u7535\u5bb9\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u7684\u7535\u5316\u5b66\u884c\u4e3a\u3002\u4e09\u7535\u6781\u4f53\u7cfb\u4e2d\uff0cNSPC\u57281\u00a0A g-1<\/sup>\u00a0\uff0c200 A g-1<\/sup>\u4e0b\u6bd4\u7535\u5bb9\u5206\u522b\u4e3a386.3 F g-1<\/sup>\uff0c 176.9 F g-1<\/sup>\uff0c\u7ecf10\u4e07\u6b21\u5faa\u73af\u540e\uff0c\u5bb9\u91cf\u4fdd\u7559\u7387\u4e3a97.8%\u3002\u6b64\u5916\uff0c\u5c06\u5176\u5e94\u7528\u4e8e\u5bf9\u79f0\u8d85\u7ea7\u7535\u5bb9\u5668\u4e2d\uff0c\u4e5f\u5c55\u793a\u51fa\u4e86\u4f18\u79c0\u7684\u7535\u5316\u5b66\u6027\u80fd\uff1a186.9\u00a0F g-1<\/sup>\uff081\u00a0A g-1<\/sup>\uff09\u548c98.6 F g-1<\/sup>\u00a0(150A g-1<\/sup>)\u3002\u672c\u7814\u7a76\u4e3a\u539f\u4f4d\u5236\u5907Zn-MOFs\u884d\u751f\u7684\u542b\u6c2e\u591a\u5b54\u78b3\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7684\u65b9\u6cd5\uff0c\u53ef\u5728\u5f88\u5927\u7a0b\u5ea6\u4e0a\u63d0\u9ad8\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u6750\u6599\u6027\u80fd\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a\u201cA novel in-situ preparation of N-rich spherical porous carbon as\u00a0greatly enhanced material for high-performance supercapacitors\u201d\uff08doi.org\/10.1016\/j.carbon.2020.09.004\uff09\u53d1\u8868\u5728Carbon \u6742\u5fd7\u3002\u6f58\u519b\u9752\u6559\u6388\u4e3a\u8bba\u6587\u7684\u901a\u8baf\u4f5c\u8005\uff0c\u5176\u56e2\u961f\u7855\u58eb\u7814\u7a76\u751f\u521a\u65ed\u4e3a\u7b2c\u4e00\u4f5c\u8005\u3002<\/p>\n

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\"\"<\/p>\n

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\"\"<\/p>\n

(a)Zn-TDPAT\u7684SEM\u56fe\u50cf\u53ca\u5176\u5bf9\u5e94\u7684\u5143\u7d20\u6620\u5c04\u56fe\uff1b(b)NSPC\u7684SEM\u56fe\u50cf\u53ca\u5176\u5bf9\u5e94\u7684\u5143\u7d20\u6620\u5c04\u56fe\uff1b(c)Zn-TDPAT\u7684TEM\u56fe\uff1b(d)NSPC\u7684TEM\u56fe(\u63d2\u5165\u56fe:SAED\u6a21\u5f0f)\uff1b<\/p>\n

\u56fe3\u4e3a<\/b><\/strong>Z<\/b><\/strong>n<\/b><\/strong>-TDPAT<\/b><\/strong>\u548c<\/b><\/strong>NSPC<\/b><\/strong>\u7684\u6bd4\u8868\u9762\u5206\u6790\u53ca\u5143\u7d20\u5206\u6790\u56fe\u3002<\/b><\/strong>(a)(b)\u56fe\u663e\u793aZn-TDPAT\u548cNSPC\u5bf9\u5e94\u7684BET\u6bd4\u8868\u9762\u79ef\u548c\u6c2e\u6c14\u5438\u9644\u91cf\u5206\u522b\u4e3a148 m2<\/sup>\u00a0g-1<\/sup>\uff080.27 cm3<\/sup>\u00a0g-1<\/sup>\uff09\uff0c1,826 m2<\/sup>\u00a0g-1<\/sup>\uff081.47 cm3<\/sup>\u00a0g-1<\/sup>\uff09\u3002\u8868\u660e\u6709\u673a\u914d\u4f53\u4e0a\u7fa7\u57fa\u7684\u5206\u89e3\u4ee5\u53ca\u950c\u539f\u5b50\u7684\u5347\u534e\u79bb\u53bb\u5f88\u5927\u7a0b\u5ea6\u4e0a\u589e\u52a0\u4e86\u751f\u6210\u7684\u591a\u5b54\u78b3\u7684\u6bd4\u8868\u9762\u79ef\u3002\u5bf9XPS\u8c31\u56fe\u8fdb\u884c\u79ef\u5206\u8ba1\u7b97\u53ef\u4ee5\u5f97\u51faNSPC\u7684\u6574\u4f53\u6c2e\u5143\u7d20\u8868\u9762\u539f\u5b50\u7387\u4e3a11.37 at.%\uff0c\u8868\u660e\u6c2e\u5143\u7d20\u5df2\u6210\u529f\u63ba\u6742\u5230\u78b3\u6750\u6599\u4e2d\u3002<\/p>\n

\"\"<\/b><\/strong><\/p>\n

(a)Zn-TDPAT\u548cNSPC\u7684\u6c2e\u6c14\u5438\u8131\u9644\u66f2\u7ebf\uff1b(b)\u5b54\u5f84\u5206\u5e03\u66f2\u7ebf\u56fe\uff1b(c)Zn-TDPAT\u548cNSPC\u7684XPS\u5168\u8c31\uff1b(d)Zn-TDPAT\u548cNSPC\u7684\u9ad8\u5206\u8fa8\u7387C 1s\u8c31\uff1b(e)Zn-TDPAT\u548cNSPC\u7684\u9ad8\u5206\u8fa8\u7387O 1s\u8c31\uff1b(f)Zn-TDPAT\u548cNSPC\u7684\u9ad8\u5206\u8fa8\u7387N 1s\u8c31<\/p>\n

\u56fe4\u4e3aN<\/b><\/strong>SPC<\/b><\/strong>\u5728\u4e09\u7535\u6781\u4f53\u7cfb\u4e2d\u7684\u7535\u5316\u5b66\u6027\u80fd\u56fe\u3002<\/b><\/strong>(a)\u56fe\u663e\u793a\u5145\u653e\u7535\u65f6\u95f4\u4e0e\u7535\u538b\u5173\u7cfb\u66f2\u7ebf\u5448\u4e09\u89d2\u5f62\uff0c\u4f46\u653e\u7535\u65f6\u95f4\u7565\u5927\u4e8e\u5145\u7535\u65f6\u95f4\uff0c\u8868\u660e\u5728\u53cc\u7535\u5c42\u7535\u5316\u5b66\u8fc7\u7a0b\u4e2d\u6df7\u5408\u4e86\u6c2e\u539f\u5b50\u7684\u8d5d\u7535\u5bb9\u7535\u5316\u5b66\u884c\u4e3a\u3002(c)\u56fe\u663e\u793a\u572810,000\u6b21\u5faa\u73af\u8fc7\u7a0b\u4e2d\uff0cCV\u66f2\u7ebf\u59cb\u7ec8\u4fdd\u6301\u91cd\u5408\uff0c\u77e9\u5f62\u5f62\u72b6\u4fdd\u6301\u4e0d\u53d8\uff0c\u8868\u660e\u5faa\u73af\u7a33\u5b9a\u6027\u826f\u597d\u3002(e)\u56fe\u663e\u793a10\uff0c000\u6b21\u5faa\u73af\u4f0f\u5b89\u540e\u7684Nyquist\u56fe\u548c\u7b49\u6548\u7535\u8def\u56fe\u62df\u5408\u7684Nyquist\u56fe\u57fa\u672c\u543b\u5408\uff0c\u6d4b\u8bd5\u7ed3\u679c\u8868\u660eNSPC\u7535\u6781\u5728\u957f\u65f6\u95f4\u5de5\u4f5c\u540e\uff0c\u80fd\u83b7\u5f97\u8f83\u9ad8\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\u3002<\/p>\n

\"\"<\/p>\n

(a)NSPC\u7535\u6781\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5145\u653e\u7535\u66f2\u7ebf(1-200 A g-1<\/sup>)\uff1b(b)\u6bd4\u7535\u5bb9\u968f\u7535\u6d41\u5bc6\u5ea6\u53d8\u5316\u66f2\u7ebf\uff1b(c)200 mV s-1<\/sup>\u4e0b\u5faa\u73af10000\u5708CV\u66f2\u7ebf\uff1b(d) 20\u300150\u3001100\uff0c150\u548c200 A g-1<\/sup>\u00a0\u4e0b\u5faa\u73af\u60c5\u51b5\uff1bNSPC\u7535\u6781\u5728200mV s-1<\/sup>\u4e0b\u5faa\u73af\u4f0f\u5b89\u6d4b\u8bd51\u4e07\u6b21\u524d\u540eEIS\u7ed3\u679c\uff1a(e) \u5948\u594e\u65af\u7279\u56fe\u53ca\u7b49\u6548\u7535\u8def\u56fe\uff1b(f)\u00a0\u6ce2\u5fb7\u76f8\u56fe\uff1b(g)\u963b\u6297\u7684\u5b9e\u90e8\u865a\u90e8\u53d8\u5316\u66f2\u7ebf\uff1b(h)\u00a0\u6bd4\u5bb9\u91cf\u53d8\u5316<\/p>\n

\u56fe<\/b><\/strong>5\u4e3aNSPC\u5bf9\u79f0\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u7535\u5316\u5b66\u6027\u80fd\u56fe\u3002<\/b><\/strong>\u80fd\u91cf\u5bc6\u5ea6\u548c\u529f\u7387\u5bc6\u5ea6\u662f\u8bc4\u4ef7\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u5b9e\u9645\u5e94\u7528\u6027\u80fd\u7684\u4e24\u4e2a\u91cd\u8981\u53c2\u6570\u3002\u5728\u76f8\u5e94\u529f\u7387\u5bc6\u5ea6\u4e3a1.6 kW Kg-1<\/sup>\u65f6\uff0cNSPC\u7535\u6781\u6750\u6599\u7684\u6700\u4f73\u80fd\u91cf\u5bc6\u5ea6\u7ea6\u4e3a50.9 Wh Kg-1<\/sup>\uff0c\u5373\u4f7f\u5728\u529f\u7387\u5bc6\u5ea6\u4e3a30.8 kW Kg-1<\/sup>\u65f6\uff0c\u5176\u80fd\u91cf\u5bc6\u5ea6\u4ecd\u53ef\u4fdd\u6301\u572842.7 Wh Kg-1<\/sup>\u00a0(83.9%)\u5de6\u53f3\u3002<\/p>\n

\"\"<\/p>\n

(a)\u57286M\u00a0KOH\u7535\u89e3\u8d28\u4e2d\u4e0d\u540c\u7684\u7535\u538b\u7a97\u53e3\u4e0b\u7684CV\u66f2\u7ebf\u00a0(0 – 1.8 V)\uff1b(b)\u4e0d\u540c\u626b\u63cf\u901f\u7387(5 – 1000 mV s-1<\/sup>)\u00a0\u4e0b\u7684CV\u66f2\u7ebf\uff1b(c)\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6(1 – 150 g–<\/sup>1<\/sup>)\u4e0b\u7684\u5feb\u901f\u5145\u653e\u7535\u66f2\u7ebf\uff1b(d)\u6bd4\u7535\u5bb9\u4e0e\u7535\u6d41\u5bc6\u5ea6\u5bf9\u6bd4\u56fe(1 – 150 g–<\/sup>1<\/sup>)\uff1b\u00a0(e)Ragone\u56fe(\u80fd\u91cf\u5bc6\u5ea6vs\u529f\u7387\u5bc6\u5ea6)\uff1b(f)NSPC\u57fa\u5bf9\u79f0\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u7535\u8377\u5b58\u50a8\u673a\u5236<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/b><\/strong><\/p>\n

\u8bbe\u8ba1\u5408\u6210\u5177\u67096\u4e2a\u6c2e\u539f\u5b50\u7684\u6709\u673a\u7fa7\u9178\u914d\u4f53\u5e76\u5236\u5907\u6210\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u6750\u6599\uff0c\u5f97\u5230\u542b\u6c2e\u7684MOFs\u524d\u9a71\u4f53Zn-TDPAT\uff0c\u518d\u901a\u8fc7\u9ad8\u6e29\u78b3\u5316\u5f97\u5230\u5177\u6709\u9ad8\u542b\u6c2e\u91cf\u7279\u70b9\u7684\u591a\u5b54\u78b3\u6750\u6599NSPC\uff0c\u5e76\u5bf9\u5176\u5236\u5907\u6761\u4ef6\u53ca\u9ad8\u6e29\u78b3\u5316\u5de5\u827a\u8fdb\u884c\u4f18\u5316\u7814\u7a76\uff1b\u7ed3\u679c\u5982\u4e0b\uff1a<\/p>\n

(1) \u901a\u8fc7\u8c03\u8282\u53cd\u5e94\u6e29\u5ea6\u548c\u65f6\u95f4\u3001\u78b3\u5316\u6e29\u5ea6\uff0c\u5236\u5907\u4e86\u5177\u6709\u5747\u4e00\u5c3a\u5bf8\u7684\u7403\u5f62\u542b\u6c2eZn-TDPAT\u548c\u4fdd\u6301\u4e86\u7403\u5f62\u5f62\u8c8c\u53ca\u7535\u5316\u5b66\u6027\u80fd\u6700\u4f73\u7684\u542b\u6c2e\u591a\u5b54\u78b3NSPC\u3002<\/p>\n

\u00a0(2) \u7535\u5316\u5b66\u6d4b\u8bd5\u8868\u660e\uff0cNSPC\u65e0\u8bba\u662f\u5728\u78b1\u6027\u8fd8\u662f\u9178\u6027\u4f53\u7cfb\u4e2d\u90fd\u8868\u73b0\u51fa\u53cc\u7535\u5c42\u50a8\u8377\u548c\u8d5d\u7535\u5bb9\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u7684\u7535\u5316\u5b66\u884c\u4e3a\u3002NSPC\u7535\u6781\u5728\u4e09\u7535\u6781\u4f53\u7cfb\u4e2d1\u00a0A g-1<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u6bd4\u5bb9\u91cf\u4e3a386.3 F g-1<\/sup>\uff1b200 A g-1<\/sup>\u4e0b\u6bd4\u5bb9\u91cf\u4e3a176.9 F g-1<\/sup>\uff0c\u7ecf10\u4e07\u6b21\u5faa\u73af\uff08150 A g-1<\/sup>\uff09\u540e\uff0c\u5bb9\u91cf\u4fdd\u7559\u7387\u4e3a97.8%\u3002\u4e3a\u7814\u7a76\u5176\u5b9e\u9645\u5e94\u7528\uff0c\u7ec4\u88c5\u4e3a\u57fa\u4e8eNSPC\u7684\u5bf9\u79f0\u56fa\u4f53\u8d85\u7ea7\u7535\u5bb9\u5668\uff0c\u57281\u00a0A g-1<\/sup>\u4e0b\u83b7\u5f97\u4e86186.9 F g-1<\/sup>\u7684\u6bd4\u5bb9\u91cf\u3002\u8be5\u5668\u4ef6\u57281.4 V\u7684\u6700\u4f73\u7535\u538b\u7a97\u53e3\u4e0b\u5177\u670950.9 Wh kg-1<\/sup>\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002\u672c\u7814\u7a76\u63d0\u51fa\u4e86\u4e00\u79cd\u5229\u7528MOFs\u884d\u751f\u51fa\u7684\u9ad8\u542b\u6c2e\u7403\u72b6\u7ed3\u6784\u7684\u591a\u5b54\u78b3\u5728\u50a8\u80fd\u53ca\u5176\u5b83\u76f8\u5173\u9886\u57df\u5e94\u7528\u7684\u65b9\u6cd5\u3002<\/p>\n

\u3010\u6587\u732e\u4fe1\u606f\u3011<\/b><\/strong><\/p>\n

A novel in-situ preparation of N-rich spherical porous carbon as\u00a0greatly enhanced material for high-performance supercapacitors\uff08doi.org\/10.1016\/j.carbon.2020.09.004\uff09<\/p>\n

\u672c\u6587\u7531\u4f5c\u8005\u6295\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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