{"id":216252,"date":"2021-01-19T12:00:38","date_gmt":"2021-01-19T04:00:38","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=216252"},"modified":"2021-01-18T11:01:50","modified_gmt":"2021-01-18T03:01:50","slug":"%e5%b7%b2%e5%9b%9e%e5%a4%8d%e5%a4%a9%e6%b4%a5%e5%a4%a7%e5%ad%a6%e8%ae%b8%e8%bf%90%e5%8d%8eadv-mater-%ef%bc%9a%e9%92%be%e7%a6%bb%e5%ad%90%e7%94%b5%e6%b1%a0%e4%b8%ad%e7%9a%84%e7%94%b5%e8%a7%a3","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=216252","title":{"rendered":"\u5929\u6d25\u5927\u5b66\u8bb8\u8fd0\u534eAdv. Mater.\uff1a\u94be\u79bb\u5b50\u7535\u6c60\u4e2d\u7684\u7535\u89e3\u8d28\u548c\u7535\u6781\/\u7535\u89e3\u8d28\u754c\u9762"},"content":{"rendered":"

\u00a0<\/strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u94be\u79bb\u5b50\u7535\u6c60\uff08PIBs\uff09\u56e0\u5176\u6210\u672c\u6548\u76ca\u3001\u9ad8\u7535\u538b\u548c\u5927\u529f\u7387\u8fd0\u884c\u7684\u4f18\u70b9\u6210\u4e3a\u4e86\u672a\u6765\u50a8\u80fd\u8bbe\u5907\u7684\u5019\u9009\u8005\u3002\u7535\u6781\u6750\u6599\u7684\u5f00\u53d1\u548c\u7814\u7a76\u5728\u6700\u8fd1\u7684\u7efc\u8ff0\u8bba\u6587\u4e2d\u5f97\u5230\u4e86\u5f88\u597d\u5730\u5206\u6790\u548c\u603b\u7ed3\u3002\u4f46\u662f\uff0c\u5728\u51b3\u5b9a\u7535\u6c60\u6027\u80fd\u65b9\u9762\uff0c\u9664\u4e86\u7535\u6781\u6750\u6599\u5916\uff0c\u7535\u89e3\u8d28\u4e5f\u8d77\u7740\u5173\u952e\u4f5c\u7528\u3002\u7535\u89e3\u8d28\u4f5c\u4e3a\u8fde\u63a5\u6b63\u6781\u548c\u8d1f\u6781\u7684\u6865\u6881\uff0c\u5728\u7535\u6c60\u7684\u53ef\u9006\u5bb9\u91cf\u3001\u5bff\u547d\u3001\u500d\u7387\u5bb9\u91cf\u548c\u5b89\u5168\u6027\u65b9\u9762\u4e5f\u81f3\u5173\u91cd\u8981\u3002\u5728\u9502\u79bb\u5b50\u7535\u6c60\uff08LIBs\uff09\u548c\u94a0\u79bb\u5b50\u7535\u6c60\uff08SIBs\uff09\u4e2d\uff0c\u8fd9\u4e00\u70b9\u5df2\u5f97\u5230\u5e7f\u6cdb\u8ba4\u53ef\u3002\u4f46\u662f\u7531\u4e8e\u94be\u79bb\u5b50\uff08K+<\/sup>\uff09\u7684\u5927\u5c3a\u5bf8\u548c\u4f4e\u8def\u6613\u65af\u9178\u6027\uff0c\u4e0eLi+\u548cNa+\u7535\u89e3\u6db2\u76f8\u6bd4\uff0c\u94be\u79bb\u5b50\u7535\u6c60\u7535\u89e3\u8d28\u7684\u6eb6\u89e3\u6027\u3001\u79bb\u5b50\u7535\u5bfc\u7387\u548c\u6eb6\u5242\u5316\u884c\u4e3a\u5177\u6709\u660e\u663e\u7684\u4e0d\u540c\u3002\u6b64\u5916\uff0c\u56e0\u4e3a\u94be\u7684\u5316\u5b66\u53cd\u5e94\u6027\u66f4\u9ad8\uff0c\u6240\u4ee5\u4e0e\u7535\u89e3\u8d28\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u6709\u5173\u7684\u754c\u9762\u5bf9\u4e8ePIBs\u7684\u5f71\u54cd\u66f4\u5927\u3002<\/p>\n

\u00a0<\/strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5929\u6d25\u5927\u5b66\u8bb8\u8fd0\u534e\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba<\/strong>\u6982\u8ff0\u4e86PIBs\u4e2d\u7535\u89e3\u8d28\u548c\u754c\u9762\u7684\u7814\u7a76\u8fdb\u5c55\u5e76\u7ed9\u51fa\u4e86\u672a\u6765\u7684\u53d1\u5c55\u65b9\u5411\uff1a\u5305\u62ec\u6709\u673a\u6db2\u4f53\u7535\u89e3\u8d28\u3001\u79bb\u5b50\u6db2\u4f53\u7535\u89e3\u8d28\u3001\u56fa\u6001\u7535\u89e3\u8d28\u548c\u6c34\u7cfb\u7535\u89e3\u8d28\uff0c\u5e76\u5bf9\u7535\u6781\/\u7535\u89e3\u8d28\u754c\u9762\u7684\u5de5\u7a0b\u8fdb\u884c\u4e86\u8be6\u7ec6\u7684\u5206\u6790\u548c\u8ba8\u8bba\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201c<\/strong>Electrolytes and Interphases in Potassium Ion Batteries<\/strong>\u201d\u53d1\u8868\u5728Advanced Materials<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong> 1 <\/strong>\u94be\u79bb\u5b50\u7535\u6c60\u4e2d\u7535\u89e3\u8d28\u7684\u7c7b\u522b\u548c\u8981\u6c42<\/strong><\/p>\n

\"\"<\/p>\n

\u00a0<\/strong>\u56fe<\/strong> 2 <\/strong>\u5728<\/strong>PC<\/strong>\u6eb6\u5242\uff08<\/strong>A=Li+<\/strong>\uff0c<\/strong>Na+<\/strong>\uff0c<\/strong>K+<\/strong>\uff09\u4e2d\uff0c<\/strong>APF6<\/sub><\/strong>\u7535\u89e3\u8d28<\/strong>stokes<\/strong>\u534a\u5f84\u3001\u53bb\u6eb6\u5242\u5316\u80fd\u548c\u79bb\u5b50\u7535\u5bfc\u7387\u7684\u6bd4\u8f83\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u00a0<\/strong>\u56fe<\/strong> 3 Li<\/strong>\u3001<\/strong>Na<\/strong>\u548c<\/strong>K<\/strong>\u7535\u89e3\u8d28\u7684\u7269\u7406<\/strong>\/<\/strong>\u5316\u5b66\u6027\u8d28\u6bd4\u8f83<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09K+<\/sup>\u3001Li+<\/sup>\u3001Na+<\/sup>\u548cMg2+<\/sup>\u79bb\u5b50\u7684\u53bb\u6eb6\u5242\u5316\u80fd\u6bd4\u8f83\u56fe\uff1b<\/p>\n

\uff08b\uff09\u5728EC\u4e2d\uff0cK+<\/sup>\u3001Li+<\/sup>\u3001Na+<\/sup>\u7684\u5178\u578b\u6eb6\u5242\u5316\u7ed3\u6784\uff1b<\/p>\n

\uff08c\uff09\u5728EC\u4e2d\uff0cK+<\/sup>\u3001Li+<\/sup>\u3001Na+<\/sup>\u7684\u6eb6\u5242\u5316\u80fd\uff1b<\/p>\n

\uff08d\uff09\u5728\u5ba4\u6e29\u4e0b\uff0cPC\u4e2dLiFSA\u3001NaFSA\u548cKFSA\u79bb\u5b50\u7535\u5bfc\u7387\u968f\u6d53\u5ea6\u7684\u53d8\u5316\uff1b<\/p>\n

\uff08e\uff09\u5728\u5ba4\u6e29\u4e0b\uff0cPC\u4e2dLiFSA\u3001NaFSA\u548cKFSA\u7c98\u5ea6\u7684\u968f\u6d53\u5ea6\u7684\u53d8\u5316\uff1b<\/p>\n

\uff08f\uff0cg\uff09\u4e0e\u7eaf\u6eb6\u5242\u76f8\u6bd4\uff0c\u79bb\u5b50-\u6eb6\u5242\u914d\u5408\u7269\u7684LUMO\uff08f\uff09\u548cHOMO\uff08g\uff09\u80fd\u7ea7\u53d8\u5316\u56fe\u3002<\/p>\n

\u00a0<\/strong>\u56fe<\/strong> 4 <\/strong>\u94be\u79bb\u5b50\u7535\u6c60\u4e2d\uff0c<\/strong>K<\/strong>\u76d0\u3001\u6eb6\u5242\u548c\u6dfb\u52a0\u5242\u7684<\/strong>LUMO<\/strong>\u548c<\/strong>HOMO<\/strong>\u80fd\u7ea7\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u94be\u79bb\u5b50\u7535\u6c60\u4e2d\uff0c\u6eb6\u5242\u548c\u6dfb\u52a0\u5242\u7684LUMO\u548cHOMO\u80fd\u7ea7\u56fe\uff1b<\/p>\n

\uff08b\uff09\u94be\u79bb\u5b50\u7535\u6c60\u4e2d\uff0cK\u76d0\u7684LUMO\u548cHOMO\u80fd\u7ea7\u56fe\u3002<\/p>\n

\u00a0<\/strong>\u56fe<\/strong> 5 <\/strong>\u5e38\u89c4\u6709\u673a\u6db2\u6001\u7535\u89e3\u8d28\u7684\u6027\u80fd\u6bd4\u8f83<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09KFSA\u3001KTFSA\u3001KPF6<\/sub>\u3001KBF4<\/sub>\u3001KClO4<\/sub>\u5728\u542b0.5 mol\u76d0\u30011 dm3<\/sup>\u7684\u6df7\u5408\u7269\u4e2d\u6405\u62cc12 h\u540e\u7684\u6eb6\u89e3\u7167\u7247\uff1b<\/p>\n

\uff08b\uff09\u916f\u57fa\u7535\u89e3\u8d28\uff08KPF6<\/sub>\/EC:DMC\uff09\u4e2d\u77f3\u58a8\u8d1f\u6781\u7684GITT\u548c\u653e\u7535\u7535\u538b\u66f2\u7ebf\uff1b<\/p>\n

\uff08c\uff09\u919a\u57fa\u7535\u89e3\u8d28\uff08KPF6<\/sub>\/DME\uff09\u4e2d\u77f3\u58a8\u8d1f\u6781\u7684GITT\u548c\u653e\u7535\u7535\u538b\u66f2\u7ebf\uff1b<\/p>\n

\uff08d\uff09\u57280.05 mA cm-2<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u4e0d\u540c\u7535\u89e3\u8d28\u7684\u94dc\u57fa\u677f\u4e0aK\u9540\u8986\u548c\u5265\u79bb\u6027\u80fd\u3002<\/p>\n

\u00a0<\/strong>\u56fe<\/strong> 6<\/strong> \u9ad8\u6d53\u548c\u4e0d\u53ef\u71c3\u6709\u673a\u6db2\u4f53\u7535\u89e3\u8d28\u7684\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u4e0d\u540cKTFSI\u6d53\u5ea6\u5bf9PTCDA-2C\u7535\u6781\u7684\u7535\u5316\u5b66\u5faa\u73af\u6027\u7684\u5f71\u54cd\uff1b<\/p>\n

\uff08b\uff09\u5728\u5ba4\u6e29\u4e0b\uff0cKFSI\/TMP\u7535\u89e3\u8d28\u7684\u6d53\u5ea6\u4e0e\u79bb\u5b50\u7535\u5bfc\u7387\u7684\u5173\u7cfb\uff1b<\/p>\n

\uff08c\uff093.3 M KFSI\/TMP\u7535\u89e3\u8d28\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\uff1b<\/p>\n

\uff08d\uff091 M KPF6<\/sub>\/EC:DEC\u7535\u89e3\u8d28\u7684\u53ef\u71c3\u6027\u6d4b\u8bd5\u56fe\uff1b<\/p>\n

\uff08e\uff093.3 M KFSI \/ TMP\u7684\u7535\u89e3\u8d28\u7684\u53ef\u71c3\u6027\u6d4b\u8bd5\u56fe\u3002<\/p>\n

\u00a0<\/strong>\u56fe<\/strong> 7 <\/strong>\u79bb\u5b50\u6db2\u4f53\u7535\u89e3\u8d28\u7684\u6784\u9020\u548c\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09KFSA\/C3<\/sub>C1<\/sub>pyrrFSA\u539f\u7406\u56fe\u548c\u76f8\u56fe\uff1b<\/p>\n

\uff08b\uff090.2 M KFSA\/C3<\/sub>C1<\/sub>pyrrFSA\u7535\u89e3\u8d28\u7684\u5faa\u73af\u4f0f\u5b89\u56fe\uff1b<\/p>\n

\uff08c\uff09PDIBs\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08d\uff09\u57280.3 M KTFSI\/Pyr14<\/sub>TFSI+2 wt\uff05ES\u7535\u89e3\u8d28\u4e2d\uff0cPDIBs\u7684\u653e\u7535\u5bb9\u91cf\u548c\u5e93\u4ed1\u6548\u7387\u3002<\/p>\n

\u00a0<\/strong>\u56fe<\/strong> 8 <\/strong>\u56fa\u6001\u7535\u89e3\u8d28\u7684\u7ed3\u6784\u548c\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u5728150 \u00b0C\u4e0b\uff0c\u672a\u7ecf\u5904\u7406\u7684\u03b2”-Al2<\/sub>O3<\/sub>\u56fa\u4f53\u7535\u89e3\u8d28\u6837\u54c1\u4e0a\u7684\u6db2\u6001Na\u3001K\u6216Na-K\u5408\u91d1\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\uff09\u805a\u5408\u7269\u51dd\u80f6\u7535\u89e3\u8d28\u4e2d\u4ea4\u8054\u7684PMMA\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08c\uff09\u805a\u5408\u7269\u51dd\u80f6\u7535\u89e3\u8d28\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u968f\u6e29\u5ea6\u7684\u53d8\u5316\uff1b<\/p>\n

\uff08d\uff09\u805a\u78b3\u9178\u4e9a\u4e19\u916f\uff08PPC\uff09-KFSI\u4e0e\u7ea4\u7ef4\u7d20\u975e\u7ec7\u9020\u9aa8\u67b6-\u56fa\u4f53\u805a\u5408\u7269\u7535\u89e3\u8d28\uff08PPCB-SPE\uff09\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08e\uff09\u572820 mA g-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0cPTCDA\u7535\u6781\u5728PPCB-SPE\u548c\u6709\u673a\u6db2\u4f53\u7535\u89e3\u8d28\u91cc\u7684\u5faa\u73af\u6027\u80fd\u6bd4\u8f83\u3002<\/p>\n

\u00a0<\/strong>\u56fe<\/strong> 9 <\/strong>\u6c34\u7cfb\u7535\u89e3\u8d28\u7684\u7ed3\u6784\u548c\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u6d53\u7f29\u4e59\u9178\u94be\uff0830 M KAc\uff09\u4f5c\u4e3a\u76d0\u5305\u6c34\u7535\u89e3\u8d28\uff1b<\/p>\n

\uff08b\uff09\u57280.5\u548c0.1 mV s-1<\/sup>\u626b\u901f\u4e0b\uff0cKTi2<\/sub>(PO4<\/sub>)3<\/sub>\u8d1f\u6781\u572830m KAc\u4e0b\u7684CV\u4e0e\u975e\u6c34\u7535\u89e3\u8d28\u7684CV\u6bd4\u8f83\uff1b<\/p>\n

\uff08c\uff09\u572810 mV s-1<\/sup>\u626b\u901f\u4e0b\uff0cPTCDI\u57281 M\u548c22 M KCF3<\/sub>SO3<\/sub>\u7535\u89e3\u8d28\u4e2d\u7684\u7ebf\u6027\u4f0f\u5b89\u66f2\u7ebf\uff1b<\/p>\n

\uff08d\uff09KFeMnHCF-3565||22 M KCF3<\/sub>SO3<\/sub>||PTCDI\u5168\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\uff1b<\/p>\n

\uff08e\uff091 M\u548c30 M KFSI\u4e0e\u03b2-PTCDA\u7684\u76f8\u4e92\u4f5c\u7528\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08f\uff09\u57282 M NaOH\u6eb6\u6db2\u4e2d\u6d78\u6ce1\u5faa\u73af\u540e\u7684\u9694\u819c\u7684\u6eb6\u89e3\u5ea6\u6d4b\u8bd5\u3002<\/p>\n

\u00a0<\/strong>\u56fe<\/strong> 10 <\/strong>\u4e0d\u540c\u7535\u89e3\u8d28\u4e2d\u7684<\/strong>SEI<\/strong>\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff0cb\uff09\u5728KPF6 <\/sub>\u7684DME\u548cPC\u7535\u89e3\u6db2\u5faa\u73af\u540e\u4e2d\uff0cK2<\/sub>TP\u7535\u6781\u7684HRTEM\u56fe\u50cf\uff1b<\/p>\n

\uff08c\uff0cd\uff09\u57281 M KFSI\/DME\u7535\u89e3\u6db2\u4e2d\u5faa\u73af\u540e\uff0cK\u8d1f\u6781\u8868\u9762\u4e0ac\uff09S 2p\u533a\u548cd\uff09F 1s\u533a\u7684XPS\u8868\u5f81\uff1b<\/p>\n

\uff08e-f\uff09\u5728\u4e0d\u540c\u7535\u89e3\u6db2\u4e2d\uff0cBi\/rGO\u7535\u6781\u7684\u7eb3\u7c73\u538b\u75d5\u529b\u7684\u8868\u9762\u9ad8\u5ea6\u56fe\u548c\u8868\u9762\u7535\u52bf\u56fe:\uff08e\uff0cg\uff09KPF6<\/sub>\u7535\u89e3\u6db2\u548c\uff08f\uff0ch\uff09KFSI\u7535\u89e3\u6db2\u3002<\/p>\n

\u00a0<\/strong>\u56fe<\/strong> 11 SEI<\/strong>\u5f62\u6210\u4e0e\u7535\u89e3\u8d28\u7684\u4f9d\u8d56\u6027<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff0cb\uff09KFSI\u548cKPF6<\/sub>\u57fa\u7535\u89e3\u8d28\u4e2d\uff0c\u6eb6\u5242\u5316K+<\/sup>\u79bb\u5b50\u548c\u76d0-\u6eb6\u5242\u6df7\u5408\u7269\u7684\uff08a\uff09\u6eb6\u5242\u5316\u80fd\u548c\uff08b\uff09HOMO\u548cLUMO\u80fd\u7ea7\u56fe\uff1b<\/p>\n

\uff08c\uff09\u7535\u89e3\u8d28\u4e2d\uff0c\u6eb6\u5242\u5206\u5b50\u548c\u76f8\u5173\u7684FSI–<\/sup>\u9634\u79bb\u5b50\u7684HOMO\u548cLUMO\u80fd\u7ea7\u56fe\uff1b<\/p>\n

\uff08d\uff09\u4e0e\u7eaf\u6eb6\u5242\u76f8\u6bd4\uff0c1\u30013\u548c5 M KTFSI\/DME\u7535\u89e3\u8d28\u7684\u62c9\u66fc\u5149\u8c31\u56fe\uff1b<\/p>\n

\uff08e\uff09DFT-MD\u6a21\u62df\u76840.9 M KFSI\/TEP\u548c2 M KFSI\/TEP\u7535\u89e3\u8d28\u7684\u80fd\u6001\u5bc6\u5ea6\u56fe\u3002<\/p>\n

\u00a0<\/strong>\u56fe<\/strong> 12 PIBs<\/strong>\u7535\u89e3\u8d28\u548c\u7535\u6781<\/strong>\/<\/strong>\u7535\u89e3\u8d28<\/strong>\u754c\u9762\u7684\u7814\u53d1\u548c\u8bbe\u8ba1\u6982\u8ff0<\/strong><\/p>\n

\u00a0\"\"<\/strong><\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5<\/strong>Electrolytes and Interphases in Potassium Ion Batteries<\/a><\/strong>\uff08Advanced Materials DOI: 10.1002\/adma.202003741\uff09\u3002<\/p>\n

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