{"id":216350,"date":"2021-01-19T06:49:13","date_gmt":"2021-01-18T22:49:13","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=216350"},"modified":"2021-01-18T20:49:30","modified_gmt":"2021-01-18T12:49:30","slug":"%e6%94%af%e6%98%a5%e4%b9%89%e8%8c%83%e4%bf%8a-acs-nano%ef%bc%9ati3c2tx-mxene%e5%8a%a9%e5%8a%9b%e6%b0%b4%e7%b3%bb%e8%bd%ac%e5%8c%96%e5%9e%8bzn-br%e4%bd%8e%e6%b8%a9%e7%94%b5%e6%b1%a0","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=216350","title":{"rendered":"\u652f\u6625\u4e49&\u8303\u4fca ACS Nano\uff1aTi3C2TX MXene\u52a9\u529b\u6c34\u7cfb\u8f6c\u5316\u578bZn-Br\u4f4e\u6e29\u7535\u6c60"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u6c34\u7cfb\u5364\u5316\u7269\u6c27\u5316\u8fd8\u539f\u7535\u6c60\u5177\u6709\u5185\u5728\u7684\u9ad8\u5b89\u5168\u6027\u548c\u4f4e\u6210\u672c\u7b49\u4f18\u52bf\uff0c\u88ab\u8ba4\u4e3a\u662f\u89e3\u51b3\u80fd\u6e90\u95ee\u9898\u7684\u4e00\u4e2a\u6709\u6548\u9009\u9879\u3002\u5364\u7d20\u6d3b\u6027\u7269\u8d28\u5728\u5355\u8d28\u6001\u548c\u79bb\u5b50\u6001\u4e4b\u95f4\u7684\u53ef\u9006\u8f6c\u5316\u9a71\u52a8\u4e86\u53cd\u5e94\u7684\u8fdb\u884c\uff0c\u56e0\u6b64\u4e0d\u5b58\u5728\u5d4c\u5165\u5f0f\u7535\u6781\u4e2d\u7ed3\u6784\u574d\u584c\u7684\u95ee\u9898\u3002\u5bf9\u6bd4\u6807\u51c6\u6c22\u7535\u6781\uff08SHE\uff09\uff0c\u5176\u9ad8\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\uff08I0<\/sup>\/I-1<\/sup>\u4e3a0.62 V\uff0cBr0<\/sup>\/Br-1<\/sup>\u4e3a1.08 V\uff09\u4e5f\u5e26\u6765\u7684\u5bcc\u6709\u7ade\u4e89\u529b\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002\u7136\u800c\uff0c\u5364\u7d20\u7535\u6781\u4e24\u4e2a\u56fa\u6709\u7684\u7f3a\u70b9\u4e0d\u5f97\u4e0d\u63d0\uff1a\uff081\uff09\u6d3b\u6027\u7269\u8d28\uff08I2<\/sub>\/Br2<\/sub>\uff09\u7684\u7edd\u7f18\u6027\u5bfc\u81f4\u5dee\u7684\u53cd\u5e94\u52a8\u529b\u5b66\uff1b\u5bfc\u7535\u8f7d\u4f53\u7684\u52a0\u5165\u4e0d\u53ef\u6216\u7f3a\uff1b\uff082\uff09\u53cd\u5e94\u4e2d\u95f4\u76f8\uff08\u591a\u5364\u5316\u7269\uff09\u7684\u9ad8\u5ea6\u6eb6\u89e3\u6027\u5f15\u8d77\u7535\u6c60\u7684\u7a7f\u68ad\u6548\u5e94\uff0c\u5bfc\u81f4\u5bb9\u91cf\u5728\u77ed\u65f6\u95f4\u5185\u7684\u5feb\u901f\u8870\u51cf\u3002\u56de\u987e\u5364\u7d20\u7535\u6781\u7684\u53d1\u5c55\u53f2\uff0c\u53ef\u4ee5\u53d1\u73b0\u5bf9\u4e8eBr2<\/sub>\u7535\u6781\u7684\u7814\u7a76\u62a5\u9053\u8fdc\u5c11\u4e8eI2<\/sub>\uff0c\u5c3d\u7ba1\u524d\u8005\u5177\u6709\u8f83\u9ad8\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u548c\u8f83\u8f7b\u7684\u8d28\u91cf\u3002\u8fd9\u79cd\u73b0\u8c61\u5f88\u5927\u7a0b\u5ea6\u4e0a\u662f\u56e0\u4e3aBr2<\/sub>\u5728\u5e38\u6e29\u5e38\u538b\u4e0b\u5448\u73b0\u6db2\u4f53\u7684\u5b58\u5728\u5f62\u5f0f\uff0c\u4e14\u6781\u5177\u8150\u8680\u6027\u3002\u4f20\u7edf\u9002\u7528\u4e8e\u56fa\u6001I2<\/sub>\u7684\u5bfc\u7535\u8d1f\u8f7d\u4f53\uff08\u96c6\u4e2d\u4e8e\u591a\u5b54\u78b3\u5bb6\u65cf\u7b49\uff09\u5e76\u4e0d\u9002\u5408\u4e8e\u6db2\u6001Br2<\/sub>\u7cfb\u7edf\u3002\u4e8c\u7ef4MXenes\u6750\u6599\u517c\u5177\u826f\u597d\u7684\u4eb2\u6c34\u6027\u548c\u5bfc\u7535\u6027\u3001\u4e30\u5bcc\u7684\u8868\u9762\u5c01\u7aef\u7b49\u4f18\u70b9\uff0c\u7406\u8bba\u4e0a\u4e0e\u590d\u6742\u7684Br2<\/sub>\u5177\u6709\u5f88\u597d\u7684\u76f8\u5bb9\u6027\u3002\u7814\u7a76\u8bc1\u5b9e\uff0c\u4ee5O\/F\u57fa\u56e2\u5c01\u7aef\u66b4\u9732\u7684\u6781\u6027\u8fc7\u6e21\u91d1\u5c5e\u5c42\u4e0e\u591a\u5364\u5316\u7269\u5177\u6709\u826f\u597d\u7684\u4eb2\u548c\u529b\uff0c\u80fd\u591f\u6709\u6548\u6291\u5236\u53cd\u5e94\u4ea7\u7269\u7684\u6d41\u5931\u548c\u7a7f\u68ad\u884c\u4e3a\u3002\u7136\u800c\uff0c\u8003\u8651\u5230Br2<\/sub>\u5206\u5b50\u5927\u7684\u534a\u5f84\u4ee5\u53caMXene\u7684\u7eb3\u7c73\u5c42\u95f4\u95f4\u9699\uff0c\u4f20\u7edf\u7684\u7269\u7406\u5438\u9644\u548c\u6db2\u76f8\u6e17\u900f\u7b49\u65b9\u6cd5\u96be\u4ee5\u5b9e\u73b0\u4e24\u76f8\u7684\u9ad8\u6548\u590d\u5408\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u9999\u6e2f\u57ce\u5e02\u5927\u5b66\u652f\u6625\u4e49\u6559\u6388\u548c\u8303\u4fca\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba<\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u6709\u6548\u7684\u201cMXene\u589e\u5f3a\u201d\u7b56\u7565\u548c\u65b0\u578b\u7684\u7535\u6c89\u79ef\u65b9\u6cd5\uff0c\u5b9e\u73b0\u4e86Br2<\/sub>\u5355\u8d28\u5728Ti3<\/sub>C2<\/sub>TX<\/sub>\uff08TX<\/sub>\u4ee3\u8868O\/F\u7684\u8868\u9762\u7ec8\u7aef\uff09\u7eb3\u7c73\u5c42\u95f4\u7684\u5747\u5300\u5d4c\u5165\u3002Br–<\/sup>\u79bb\u5b50\u5728\u6052\u5b9a\u7535\u573a\u4f5c\u7528\u4e0b\u9996\u5148\u5d4c\u5165\u5230MXene\u5c42\u95f4\u95f4\u9699\uff0c\u7136\u540e\u5931\u53bb\u7535\u5b50\u88ab\u6c27\u5316\u6210\u5355\u8d28\u6001\u56fa\u5b9a\u4e0b\u6765\u3002\u591a\u91cd\u7535\u5316\u5b66\u5206\u6790\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u8ba1\u7b97\u8bc1\u5b9e\u4e86Br0<\/sup>\/Br–<\/sup>\u5bf9\u5728\u7eb3\u7c73\u5c42\u95f4\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u3002\u5f97\u76ca\u4e8eTi3<\/sub>C2<\/sub>TX<\/sub> MXene\u5bf9Br\u7269\u79cd\u7684\u9677\u57df\u6548\u5e94\u548c\u5929\u7136\u4eb2\u548c\u529b\uff0c\u591a\u6eb4\u5316\u7269\u7684\u7a7f\u68ad\u884c\u4e3a\u53d7\u5230\u4e86\u663e\u8457\u6291\u5236\u3002\u56e0\u6b64\uff0c\u4e0e\u950c\u8d1f\u6781\u5339\u914d\uff0cBr-Ti3<\/sub>C2<\/sub>TX<\/sub>\u6b63\u6781\u80fd\u591f\u57281 M\u4e09\u6c1f\u7532\u70f7\u78fa\u9178\u950c\uff08Zn(OTf)2<\/sub>\uff09\u7535\u89e3\u6db2\u4e2d\u957f\u671f\u53ef\u9006\u5faa\u73af\u3002\u5faa\u73af2000\u6b21\u540e\uff0c\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a81%\u3002\u7814\u7a76\u7ed3\u679c\u8868\u660e\uff0c\u6574\u4e2a\u6c27\u5316\u8fd8\u539f\u8fc7\u7a0b\u662f\u4e00\u6b65\u5b8c\u6210\u7684\uff0c\u5728\u5355\u8d28\u6001\u8fdb\u800c\u79bb\u5b50\u6001\u4e4b\u95f4\u53ef\u9006\u5faa\u73af\u3002\u7535\u6c60\u653e\u7535\u7535\u538b\u9ad8\u8fbe1.75 V\uff0c\u63a5\u8fd1\u7406\u8bba\u4e0a\u9650\uff081.84 V vs Zn2+<\/sup>\/Zn\uff09\u3002\u9ad8\u6548\u7535\u5b50\u4f20\u5bfc\u5e26\u6765\u4e86\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\uff0c\u57280.5 A g-1\u548c4.0 A g-1\u6761\u4ef6\u4e0b\u7684\u5bb9\u91cf\u5206\u522b\u8fbe\u5230179.6 mAh g-1<\/sup>\u548c136.5 mAh g-1<\/sup>\u3002\u80fd\u91cf\u5bc6\u5ea6\u8fbe\u5230\u4e86259 Wh kg-1<\/sup>Br<\/sub>\uff08144 Wh kg-1<\/sup>Br-Ti3C2TX<\/sub>\uff09\u3002\u6b64\u5916\uff0c\u57fa\u4e8e\u9632\u51bb\u6c34\u7cfb\u7535\u89e3\u6db2\uff0c\u7535\u6c60\u5728\u4f4e\u6e29\u6761\u4ef6\u4e0b\u5c55\u793a\u4e86\u5feb\u901f\u8f6c\u5316\u52a8\u529b\u5b66\u3002\u5373\u4f7f\u5728-15\u2103\u4e0b\u7684\u4e25\u683c\u6761\u4ef6\u4e0b\uff0c\u5176\u5bb9\u91cf\u4e5f\u53ef\u4fdd\u6301\u5728\u5ba4\u6e29\u4e0b\u768469%\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u5728-15\u2103\u65f6\u7535\u6c60\u53ef\u7a33\u5b9a\u5faa\u73af\u8d85\u8fc710000\u6b21\uff0c\u4e14\u6ca1\u6709\u660e\u663e\u7684\u5bb9\u91cf\u8870\u51cf\uff0c\u8fdc\u8fdc\u4f18\u4e8e\u4efb\u4f55\u62a5\u9053\u7684\u6c34\u7cfbZn\/\/Br2<\/sub>\u548cZn\/\/I2<\/sub>\u79bb\u5b50\u7535\u6c60\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cConfining Aqueous Zn-Br Halide Redox Chemistry by Ti3<\/sub>C2<\/sub>TX<\/sub> MXene\u201d<\/strong>\u53d1\u5e03\u5728\u56fd\u9645\u8457\u540d\u671f\u520aACS Nano<\/strong>\u4e0a\u3002
\n \"\"
\n \u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\u3001\u65b0\u578b\u7535\u6c89\u79ef\u6cd5\u5236\u5907Br-Ti3<\/sub>C2<\/sub>TX<\/sub>\u7535\u6781\u793a\u610f\u56fe<\/strong>
\n \"\"\uff08a\uff09Br-Ti3<\/sub>C2<\/sub>TX<\/sub>\u7535\u6781\u5236\u5907\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b-c\uff09\u591a\u5c42Ti3<\/sub>C2<\/sub>TX<\/sub>\u3001Br-Ti3<\/sub>C2<\/sub>TX<\/sub>\u7535\u6781SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08d\uff09Ti\u3001Br\u3001F\u548cO\u5143\u7d20\u7684\u5bf9\u5e94EDX\u8c31\u56fe\uff1b<\/p>\n

\uff08e-f\uff09Ti3<\/sub>C2<\/sub>TX<\/sub>\u548cBr-Ti3<\/sub>C2<\/sub>TX<\/sub>\u7535\u6781\u7684XRD\u8c31\u56fe<\/p>\n

\uff08g\uff09\u9ad8\u7cbe\u5ea6\u7684Br 3d XPS\u62df\u5408\u8c31\u56fe\u3002<\/p>\n

\u56fe\u4e8c\u3001Br-Ti3<\/sub>C2<\/sub>TX<\/sub>\u7535\u6781\u57281 M Zn(OTf)2<\/sub>\u7535\u89e3\u6db2\u4e2d\u7684\u6c27\u5316\u8fd8\u539f\u6027\u8d28<\/strong>
\n \"\"\uff08a-b\uff09\u7eafTi3<\/sub>C2<\/sub>TX<\/sub>\u7535\u6781\u548cBr-Ti3<\/sub>C2<\/sub>TX<\/sub>\u7535\u6781\u572810 mV\/s\u626b\u901f\u65f6\u7684\u5faa\u73af\u4f0f\u5b89\uff08CV\uff09\u66f2\u7ebf\uff1b<\/p>\n

\uff08c\uff09\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\uff0cBr-Ti3<\/sub>C2<\/sub>TX<\/sub>\u57281-10 mV\/s\u626b\u901f\u8303\u56f4\u5185\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

\uff08d\uff09\u57280.5-4.0 A g-1<\/sup>\u7535\u6d41\u5bc6\u5ea6\u8303\u56f4\u5185\uff0cBr-Ti3<\/sub>C2<\/sub>TX<\/sub>\u7535\u6781\u7684\u500d\u7387\u6027\u80fd\uff1b<\/p>\n

\uff08e\uff09Br-Ti3<\/sub>C2<\/sub>TX<\/sub>\u500d\u7387\u6027\u80fd\u5bf9\u5e94\u7684GCD\u66f2\u7ebf\uff1b<\/p>\n

\uff08f\uff09Ragone\u56fe\u5bf9\u6bd4\uff1b<\/p>\n

\uff08g\uff09Br-Ti3<\/sub>C2<\/sub>TX<\/sub>\u7535\u6781\u57282 A g-1<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u957f\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

\u56fe\u4e09\u3001\u975e\u539f\u4f4d\u7279\u5f81\u548cDFT\u6a21\u62df\u63ed\u793a\u6c27\u5316\u8fd8\u539f\u673a\u7406<\/strong>
\n \"\"\uff08a-b\uff09\u5728\u5145\/\u653e\u7535\u8fc7\u7a0b\u4e2d\uff0c\u5728\u9009\u5b9a\u7535\u538b\u4e0bBr-Ti3<\/sub>C2<\/sub>TX<\/sub>\u7535\u6781\u7684XRD\u8c31\u56fe\u548c\u62df\u5408\u7684Br 3d XPS\u8c31\u56fe\uff1b<\/p>\n

\uff08c\uff091000\u6b21\u5faa\u73af\u540e\uff0c\u5b8c\u5168\u5145\u7535\u72b6\u6001\u4e0b\u7684Br2<\/sub>-Ti3<\/sub>C2<\/sub>TX<\/sub>\u7535\u6781\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08d\uff09SEM\u56fe\u50cf\u4ee5\u53ca\u76f8\u5e94\u7684Ti\u548cBr\u5143\u7d20\u7684EDX\u8c31\u56fe\uff1b<\/p>\n

\uff08e\uff09Ti3<\/sub>C2<\/sub>TX<\/sub> MXene\u7684\u6676\u4f53\u7ed3\u6784\u548c\u53ef\u80fd\u7684MXene-Br\u76f8\u4e92\u4f5c\u7528\u4f4d\u70b9\uff1b<\/p>\n

\uff08f\uff09Br\u7269\u79cd\u5728Ti3<\/sub>C2<\/sub>TX<\/sub> MXene\u4e0a\u5438\u9644\u80fd\uff1b<\/p>\n

\uff08g\uff09Ti\u4f4d\u70b9\u5904\u5438\u9644\u591a\u79cdBr\u7269\u79cd\u7684\u6700\u4f73\u7535\u8377\u5bc6\u5ea6\u6a21\u5f0f\uff1b<\/p>\n

\uff08h\uff09\u5438\u9644Br\u7269\u79cd\u524d\u540e\uff0cTi3<\/sub>C2<\/sub>TX<\/sub> MXene\u603b\u6001\u5bc6\u5ea6\uff08DOS\uff09\u5206\u5e03\u56fe\uff1b<\/p>\n

\uff08i-k\uff09\u5438\u9644Br\u7269\u79cd\u540eTi 3d\u3001C 2p\u3001O 2p\u548cBr 4p\u8f68\u9053\u7684\u8be6\u7ec6DOS\u3002<\/p>\n

\u56fe\u56db\u3001Br-Ti3<\/sub>C2<\/sub>TX<\/sub>\u7535\u6781\u5728\u4f4e\u6e29\u3001\u9ad8\u6d53\u5ea6\u7535\u89e3\u8d28\u4e2d\u5feb\u901f\u9ad8\u6548\u7684\u6c27\u5316\u8fd8\u539f\u5316\u5b66\u53cd\u5e94<\/strong>
\n \"\"\uff08a\uff09Br-Ti3<\/sub>C2<\/sub>TX<\/sub>\u7535\u6781\u5728-15\u81f325 \u2103\u7684\u4e0d\u540c\u6e29\u5ea6\u5185\u7684\u5faa\u73af\u6027\u80fd\uff1b<\/p>\n

\uff08b\uff09\u5bf9\u5e94\u7684GCD\u66f2\u7ebf\uff1b<\/p>\n

\uff08c\uff09dQ<\/em>\/dV<\/em>\u66f2\u7ebf\uff1b<\/p>\n

\uff08d-f\uff09\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\uff0cBr-Ti3<\/sub>C2<\/sub>TX<\/sub>\u7535\u6781\u7684\u653e\u7535\u7535\u538b\u548c\u6781\u5316\u7535\u538b\u66f2\u7ebf\u3001EIS\u5149\u8c31\u4ee5\u53caRct\u3001Ro\u503c\u4ee5\u53ca\u4f4e\u9891\u533a\u76f4\u7ebf\u659c\u7387\uff1b<\/p>\n

\uff08g\uff09Br-Ti3<\/sub>C2<\/sub>TX<\/sub>\u7535\u6781\u5728\u4f4e\u6e29\u73af\u5883\uff08-15 \u2103\uff09\u4e2d\u7684\u957f\u5faa\u73af\u6027\u80fd\uff1b<\/p>\n

\uff08h\uff09\u5faa\u73af\u5bff\u547d\u4e0e\u5bb9\u91cf\u4fdd\u6301\u7387\u5bf9\u6bd4\uff08LT:\u4f4e\u6e29\uff1bRT: \u5ba4\u6e29\uff09\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u5c55\u793a\u4e86\u6709\u6548\u7684\u201cMXene\u589e\u5f3a\u201d\u7b56\u7565\u4ee5\u53ca\u65b0\u578b\u7535\u5316\u5b66\u6c89\u79ef\u5de5\u827a\u3002Br–<\/sup>\u79bb\u5b50\u5728\u7535\u573a\u9a71\u52a8\u4e0b\u9996\u5148\u5d4c\u5165Ti3<\/sub>C2<\/sub>TX<\/sub> MXene\u7eb3\u7c73\u5c42\u95f4\uff0c\u7136\u540e\u88ab\u539f\u4f4d\u6c27\u5316\u4e3aBr2<\/sub>\u5355\u8d28\u56fa\u5b9a\u4e0b\u6765\u3002\u5176\u4e2d\uff0c\u7eb3\u7c73\u7ea7\u5c3a\u5ea6\u7684\u7a7a\u95f4\u9650\u5236\u4e86\u5728\u8f6c\u5316\u8fc7\u7a0b\u4e2d\u591a\u79cd\u6d3b\u6027Br\u7269\u79cd\u7684\u6eb6\u89e3\u548c\u635f\u8017\u3002\u5728Br\/MXene\u7684\u754c\u9762\u533a\u57df\u5185\u5feb\u901f\u7684\u7535\u5b50\u8f6c\u79fb\u6781\u5927\u589e\u5f3a\u4e86Br2<\/sub>\/Br–<\/sup>\u5bf9\u7684\u6c27\u5316\u8fd8\u539f\u52a8\u529b\u5b66\u3002\u56e0\u6b64\uff0c\u5728\u73af\u5883\u6e29\u5ea6\u548c\u4f4e\u6e29\u6761\u4ef6\u4e0b\uff0c Br2<\/sub>\u7684\u7535\u6c60\u7684\u500d\u7387\u6027\u80fd\u548c\u5faa\u73af\u6027\u5747\u5f97\u5230\u4e86\u8f83\u5927\u63d0\u5347\u3002\u5728\u6c34\u7cfbZn\u7535\u6c60\u4f53\u7cfb\u4e2d\uff0cBr-Ti3<\/sub>C2<\/sub>TX<\/sub>\u6b63\u6781\u7684\u653e\u7535\u7535\u538b\u53ef\u8fbe\u52301.75 V\uff0c\u63a5\u8fd1\u7406\u8bba\u503c\u3002\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u8be5\u7535\u6c60\u5c55\u73b0\u51fa\u4f18\u5f02\u7684\u5bb9\u91cf\u3001\u80fd\u91cf\u5bc6\u5ea6\u3001\u500d\u7387\u6027\u80fd\u4ee5\u53ca\u5bb9\u91cf\u4fdd\u6301\u7387\u3002\u6b64\u5916\uff0c\u8be5\u7535\u6c60\u5728\u82db\u523b\u7684\u4f4e\u6e29\u6761\u4ef6\u4e0b\u540c\u6837\u5177\u6709\u4f18\u5f02\u7684\u6c27\u5316\u8fd8\u539f\u52a8\u529b\u5b66\u3002\u5728-15 \u2103\u4e0b\u7535\u6c60\u4f9d\u7136\u53ef\u4ee5\u7ef4\u630169\uff05\u7684\u5ba4\u6e29\u5bb9\u91cf\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u5728-15 \u2103\u4e0b\u5faa\u73af10000\u6b21\uff0c\u7535\u6c60\u6ca1\u6709\u53d1\u73b0\u53ef\u89c1\u7684\u5bb9\u91cf\u8870\u51cf\u3002DFT\u6a21\u62df\u548c\u591a\u91cd\u5b9e\u9a8c\u5149\u8c31\u9a8c\u8bc1\u4e86Ti3<\/sub>C2<\/sub>TX<\/sub> MXene\u4e0e\u6d3b\u6027Br\u7269\u79cd\u4e4b\u95f4\u7684\u5929\u7136\u7684\u4eb2\u548c\u529b\u4ee5\u53caBr2<\/sub>\uff0cTi3<\/sub>C2<\/sub>TX<\/sub>\u4e24\u8005\u95f4\u9ad8\u6548\u7684\u7535\u5b50\u8f6c\u79fb\u3002\u603b\u4e4b\uff0c\u672c\u6587\u63d0\u51fa\u7684\u201cMXene\u589e\u5f3a\u201d\u7b56\u7565\u548c\u7535\u6c89\u79ef\u5de5\u827a\u6709\u671b\u5e94\u7528\u4e8e\u5176\u4ed6\u91d1\u5c5e\u5364\u7d20\u7535\u6c60\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aConfining Aqueous Zn-Br Halide Redox Chemistry by Ti3<\/sub>C2<\/sub>TX<\/sub> MXene<\/a><\/strong>. ACS Nano<\/em>, 2021<\/strong>, DOI: 10.1021\/acsnano.0c09380.<\/p>\n

\u672c\u6587\u7531CQR\u7f16\u8bd1\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1atougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011 \u6c34\u7cfb\u5364\u5316\u7269\u6c27\u5316\u8fd8\u539f\u7535\u6c60\u5177\u6709\u5185\u5728\u7684\u9ad8\u5b89\u5168\u6027\u548c\u4f4e\u6210\u672c\u7b49\u4f18\u52bf\uff0c\u88ab\u8ba4\u4e3a\u662f\u89e3\u51b3\u80fd\u6e90\u95ee\u9898\u7684\u4e00\u4e2a\u6709\u6548\u9009\u9879\u3002\u5364\u7d20\u6d3b\u6027\u7269\u8d28\u5728\u5355\u8d28\u6001\u548c\u79bb\u5b50\u6001\u4e4b\u95f4\u7684\u53ef\u9006\u8f6c\u5316\u9a71\u52a8\u4e86\u53cd\u5e94\u7684…<\/p>\n","protected":false},"author":7770,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[4563],"class_list":["post-216350","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-ti3c2tx-mxene"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/216350"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/7770"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=216350"}],"version-history":[{"count":2,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/216350\/revisions"}],"predecessor-version":[{"id":216429,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/216350\/revisions\/216429"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=216350"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=216350"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=216350"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}