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\u5728\u8fc7\u53bb\u76842020\u5e74\uff0c\u6709\u673a\u5316\u5b66\u9886\u57df\u4e00\u5171\u53d1\u8868\u4e8636\u7bc7N&S\uff0c\u6210\u4e3a\u672c\u5e74\u5ea6\u6700\u80fd\u53d1NS\u7684\u7814\u7a76\u65b9\u5411\u3002\u6211\u4eec\u5728\u4e4b\u524d\u7684\u6587\u7ae0\u4e2d\u6c47\u603b\u4e862020\u4e0a\u534a\u5e74\u6709\u673a\u5316\u5b66\u9886\u57df\u7684\u7814\u7a76\uff0c\u4e00\u517116\u7bc7\u6587\u7ae0\u3002\u8fd9\u7bc7\u6587\u7ae0\u4e3a\u5927\u5bb6\u6c47\u603b\u4e862020\u4e0b\u534a\u5e74\u6709\u673a\u5316\u5b66\u9886\u57df\u7684N&S\u6587\u7ae0\uff0c\u6211\u4eec\u4e00\u8d77\u6765\u770b\u770b\u8fd9\u4e2a\u7814\u7a76\u9886\u57df\u72ec\u7279\u7684\u9876\u520a\u9b45\u529b\u3002<\/p>\n

1.\u7f8e\u56fd\u666e\u6797\u65af\u987f\u5927\u5b66\u7684David W. C. MacMillan<\/b><\/strong>:\u91d1\u5c5e\u5149\u6c27\u5316\u8fd8\u539f\u82b3\u57fa\u548c\u70f7\u57fa\u653e\u5c04\u6027\u7532\u57fa\u5316\u7528\u4e8ePET\u914d\u4f53\u7684\u53d1\u73b0<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u6b63\u7535\u5b50\u53d1\u5c04\u65ad\u5c42\u626b\u63cf\uff08PET\uff09\u653e\u5c04\u6027\u914d\u4f53\uff08\u653e\u5c04\u6027\u6807\u8bb0\u7684\u793a\u8e2a\u5242\u5316\u5408\u7269\uff09\u5bf9\u4e8e\u4e2d\u67a2\u795e\u7ecf\u7cfb\u7edf\u836f\u7269\uff0c\u795e\u7ecf\u9000\u884c\u6027\u75be\u75c5\u548c\u8bb8\u591a\u80bf\u7624\u5b66\u76ee\u6807\u7684\u4f53\u5185\u8868\u5f81\u6781\u4e3a\u6709\u7528\u3002\u6c1a\u548cC-11\u653e\u5c04\u6027\u540c\u4f4d\u7d20\u4f53\u901a\u5e38\u5bf9\u4e8e\u653e\u5c04\u6027\u914d\u4f53\u7684\u4f53\u5916\u548c\u4f53\u5185\u8868\u5f81\u90fd\u662f\u5fc5\u9700\u7684\uff0c\u4f46\u662f\u51e0\u4e4e\u6ca1\u6709\u653e\u5c04\u6027\u6807\u8bb0\u65b9\u6848\u53ef\u7528\u4e8e\u5408\u6210\u4e24\u8005\uff0c\u4ece\u800c\u6291\u5236\u4e86PET\u653e\u5c04\u6027\u914d\u4f53\u7684\u53d1\u5c55\u3002\u7531\u4e8eC-11\u7684\u534a\u8870\u671f\u77ed\uff0c\u56e0\u6b64\u8fd9\u79cd\u653e\u5c04\u6027\u914d\u4f53\u7684\u5408\u6210\u4e5f\u9700\u8981\u975e\u5e38\u5feb\u3002<\/p>\n

\u7f8e\u56fd\u666e\u6797\u65af\u987f\u5927\u5b66\u7684David W. C. MacMillan<\/b><\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u901a\u7528\u4e14\u5feb\u901f\u7684\u91d1\u5c5e\u5149\u50ac\u5316\u8fd8\u539f\u65b9\u6cd5\uff0c\u7528\u4e8e\u901a\u8fc7\u8f7d\u6709\u82b3\u57fa\u548c\u70f7\u57fa\u6eb4\u5316\u7269\u7684\u836f\u7269\u524d\u4f53\u7684\u7532\u57fa\u5316\uff0c\u5c06\u6c1a\u548cC-11\u5408\u6210\u5230\u6240\u9700\u5316\u5408\u7269\u4e2d\u3002\u7532\u57fa\u662f\u751f\u7269\u6d3b\u6027\u5206\u5b50\u4e2d\u6700\u5e38\u89c1\u7684\u7ed3\u6784\u5143\u7d20\u4e4b\u4e00\uff0c\u56e0\u6b64\u8fd9\u79cd\u5408\u6210\u65b9\u6cd5\u7b80\u5316\u4e86\u653e\u5c04\u6027\u914d\u4f53\u7684\u53d1\u73b0\u3002\u4e3a\u4e86\u8bc1\u660e\u8be5\u6280\u672f\u7684\u9002\u7528\u8303\u56f4\uff0c\u4f5c\u8005\u8fdb\u884c\u4e8620\u79cd\u6c1a\u5316\u548c10\u79cdC-11\u6807\u8bb0\u7684\u590d\u6742\u836f\u7269\u548cPET\u653e\u5c04\u6027\u914d\u4f53\u7684\u5feb\u901f\u5408\u6210\uff0c\u5305\u62ec\u4e00\u6b65\u6cd5\u5408\u6210\u4e34\u5e8a\u4f7f\u7528\u7684\u5316\u5408\u7269[11<\/sup>C]UCB-J\u548c[11<\/sup>C]PHNO\u3002\u4f5c\u8005\u8fdb\u4e00\u6b65\u6982\u8ff0\u4e86\u8be5\u534f\u8bae\u5728\u4e34\u5e8a\u524dPET\u6210\u50cf\u4e2d\u7684\u76f4\u63a5\u6548\u7528\uff0c\u5e76\u5c06\u5176\u7528\u4e8e\u4eba\u4f53\u4e34\u5e8a\u6210\u50cf\u4e2d\u5e38\u89c4\u653e\u5c04\u6027\u793a\u8e2a\u5242\u751f\u4ea7\u7684\u81ea\u52a8\u653e\u5c04\u5408\u6210\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n

Metallaphotoredox aryl and alkyl radiomethylation for PET ligand discovery<\/b><\/strong><\/p>\n

(<\/b><\/strong>Nature<\/b><\/strong>, 2020, <\/b><\/strong>DOI: <\/b><\/strong>10.1038\/s41586-020-3015-0)<\/b><\/strong><\/p>\n

2.<\/b><\/strong>\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821John F. Hartwig<\/b><\/strong>:\u8de8\u5185\u70ef\u70c3\u7684N<\/b><\/strong>–<\/b><\/strong>H\u952e\u7684\u50ac\u5316\u4e0d\u5bf9\u79f0\u52a0\u6210<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u70ef\u70c3\u7684\u52a0\u6c22\u80fa\u5316\uff0c\u5373\u80fa\u5728\u70ef\u70c3\u4e0a\u7684N-H\u952e\u52a0\u6210\uff0c\u662f\u4e00\u79cd\u57fa\u672c\u7684\u3001\u4f46\u5177\u6709\u6311\u6218\u6027\u7684\u6709\u673a\u8f6c\u5316\uff0c\u53ef\u4ee5\u4ece\u4e24\u79cd\u4e30\u5bcc\u7684\u5316\u5b66\u539f\u6599\uff08\u70ef\u70c3\u548c\u80fa\uff09\u4e2d\u4ea7\u751f\u70f7\u57fa\u80fa\u3002\u8be5\u53cd\u5e94\u7279\u522b\u91cd\u8981\uff0c\u56e0\u4e3a\u80fa\uff0c\u5c24\u5176\u662f\u624b\u6027\u80fa\u662f\u5929\u7136\u4ea7\u7269\u548c\u836f\u7269\u4e2d\u666e\u904d\u7684\u4e9a\u7ed3\u6784\u3002\u5c3d\u7ba1\u5df2\u7ecf\u4e3a\u5f00\u53d1\u7528\u4e8e\u52a0\u6c22\u80fa\u5316\u7684\u50ac\u5316\u5242\u4ed8\u51fa\u4e86\u5de8\u5927\u7684\u52aa\u529b\uff0c\u4f46\u662f\u8fdb\u884c\u5206\u5b50\u95f4\u52a0\u6c22\u80fa\u5316\u7684\u7edd\u5927\u90e8\u5206\u70ef\u70c3\u4ec5\u9650\u4e8e\u5171\u8f6d\uff0c\u5f20\u529b\u6216\u672b\u7aef\u70ef\u70c3\u3002\u4ec5\u6709\u5c11\u6570\u4f8b\u5b50\u662f\u5728\u672a\u6d3b\u5316\u7684\u5185\u90e8\u70ef\u70c3\u4e4b\u95f4\u76f4\u63a5\u52a0\u6210\u80fa\u7684N-H\u952e\uff0c\u5305\u62ec\u5149\u50ac\u5316\u52a0\u6c22\u80fa\u5316\uff0c\u800c\u4e14\u4e0d\u77e5\u9053\u8fd9\u79cd\u70ef\u70c3\u7684\u4e0d\u5bf9\u79f0\u5206\u5b50\u95f4\u52a0\u6210\u3002<\/p>\n

\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821John F. Hartwig<\/b><\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u9633\u79bb\u5b50\u94f1\u4f53\u7cfb\uff0c\u8be5\u4f53\u7cfb\u50ac\u5316\u4e00\u7cfb\u5217\u672a\u6d3b\u5316\u7684\u5185\u90e8\u70ef\u70c3\u7684\u5206\u5b50\u95f4\u52a0\u6c22\u80fa\u5316\uff0c\u4ece\u800c\u4f7f\u5176\u5177\u6709\u9ad8\u5bf9\u6620\u9009\u62e9\u6027\uff0c\u4ece\u800c\u5f62\u6210\u624b\u6027\u80fa\u3002\u8be5\u50ac\u5316\u5242\u5305\u542b\u5e26\u6709\u4e09\u7532\u57fa\u7532\u7845\u70f7\u57fa\u53d6\u4ee3\u7684\u82b3\u57fa\u81a6\u914d\u4f53\u548c\u4e00\u4e2a\u4e09\u9170\u4e9a\u80fa\u6297\u8861\u9634\u79bb\u5b50\uff0c\u53cd\u5e94\u8bbe\u8ba1\u5305\u62ec2-\u6c28\u57fa-6-\u7532\u57fa\u5421\u5576\u4f5c\u4e3a\u80fa\uff0c\u4ee5\u63d0\u9ad8\u50ac\u5316\u5faa\u73af\u5185\u591a\u4e2a\u6b65\u9aa4\u7684\u901f\u7387\uff0c\u540c\u65f6\u5145\u5f53\u6c28\u66ff\u4ee3\u7269\u3002\u8fd9\u4e9b\u8bbe\u8ba1\u539f\u5219\u6307\u51fa\u4e86\u5728\u672a\u6d3b\u5316\u7684\u5185\u90e8\u70ef\u70c3\u4e4b\u95f4\u6dfb\u52a0\u5176\u4ed6\u8bd5\u5242\u7684N-H\u952e\u4ee5\u53caO-H\u548cC-H\u952e\u7684\u65b9\u5f0f\uff0c\u4ee5\u7b80\u5316\u57fa\u672c\u539f\u6599\u4e2d\u529f\u80fd\u5206\u5b50\u7684\u5408\u6210\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n

Catalytic asymmetric addition of an amine N<\/b><\/strong>–<\/b><\/strong>H bond across internal alkenes<\/b><\/strong><\/p>\n

(<\/b><\/strong>Nature<\/b><\/strong>, 2020, <\/b><\/strong>DOI: <\/b><\/strong>10.1038\/s41586-020-2919-z)<\/b><\/strong><\/p>\n

3.<\/b><\/strong>\u82f1\u56fd\u5e03\u91cc\u65af\u6258\u5927\u5b66Adam Noble&Varinder K. Aggarwal<\/b><\/strong>:\u65e0\u91d1\u5c5e\u7684\u5149\u8bf1\u5bfc\u70f7\u70c3\u7684C<\/b><\/strong>(<\/b><\/strong>sp3<\/b><\/strong>)-<\/b><\/strong>H\u787c\u5316<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u787c\u9178\u53ca\u5176\u884d\u751f\u7269\u662f\u5316\u5b66\u4e2d\u6700\u6709\u7528\u7684\u8bd5\u5242\uff0c\u5176\u5e94\u7528\u8303\u56f4\u6db5\u76d6\u836f\u7269\uff0c\u519c\u7528\u5316\u5b66\u54c1\u548c\u529f\u80fd\u6750\u6599\u3002\u50ac\u5316C-H\u787c\u5316\u662f\u5c06\u8fd9\u4e9b\u548c\u5176\u4ed6\u787c\u57fa\u56e2\u5f15\u5165\u6709\u673a\u5206\u5b50\u7684\u4e00\u79cd\u6709\u6548\u65b9\u6cd5\uff0c\u56e0\u4e3a\u5b83\u53ef\u7528\u4e8e\u76f4\u63a5\u5b98\u80fd\u5316\u539f\u6599\u5316\u5b66\u54c1\u7684C-H\u952e\uff0c\u800c\u65e0\u9700\u8fdb\u884c\u5e95\u7269\u9884\u6d3b\u5316\u3002\u8fd9\u4e9b\u53cd\u5e94\u4f20\u7edf\u4e0a\u4f9d\u8d56\u4e8e\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u8fdb\u884cC-H\u952e\u65ad\u88c2\uff0c\u56e0\u6b64\uff0c\u5bf9\u4e8e\u82b3\u65cfC(sp2)-H\u952e\u4e0e\u8102\u65cfC(sp3)-H\u952e\u7684\u787c\u5316\u663e\u793a\u51fa\u5f88\u9ad8\u7684\u9009\u62e9\u6027\u3002<\/p>\n

\u82f1\u56fd\u5e03\u91cc\u65af\u6258\u5927\u5b66Adam Noble&Varinder K. Aggarwal<\/b><\/strong>\u62a5\u9053\u4e86\u4f7f\u7528\u6c22\u539f\u5b50\u8f6c\u79fb\u50ac\u5316\u7684\u65e0\u91d1\u5c5e\u787c\u5316\u53cd\u5e94\uff0c\u5176\u4e2dC(sp3)-H\u952e\u7684\u5747\u76f8\u88c2\u89e3\u4ea7\u751f\u70f7\u57fa\u81ea\u7531\u57fa\uff0c\u8be5\u70f7\u57fa\u81ea\u7531\u57fa\u901a\u8fc7\u4e0e\u4e8c\u787c\u8bd5\u5242\u76f4\u63a5\u53cd\u5e94\u800c\u88ab\u787c\u5316\u3002\u8be5\u53cd\u5e94\u901a\u8fc7N-\u70f7\u6c27\u57fa\u90bb\u82ef\u4e8c\u7532\u9170\u4e9a\u80fa\u57fa\u6c27\u5316\u5242\u4e0e\u6c2f\u5316\u7269\u6c22\u539f\u5b50\u8f6c\u79fb\u50ac\u5316\u5242\u4e4b\u95f4\u7684\u7d2b\u5149\u5149\u8bf1\u5bfc\u7535\u5b50\u8f6c\u79fb\u800c\u8fdb\u884c\u3002\u901a\u5e38\uff0c\u8f83\u5f31\u7684\u4ef2\uff0c\u53d4\uff0c\u751a\u81f3\u82c4\u57faCH\u952e\u4f18\u5148\u5c06\u8f83\u5f3a\u7684CH\u952e\u7532\u57fa\u5316\u3002\u673a\u7406\u7814\u7a76\u8868\u660e\uff0c\u9ad8\u7532\u57fa\u9009\u62e9\u6027\u662f\u7531\u4e8e\u6c2f\u81ea\u7531\u57fa-\u787c\u201c\u9178\u916f\u201d\u914d\u5408\u7269\u7684\u5f62\u6210\uff0c\u8be5\u914d\u5408\u7269\u9009\u62e9\u6027\u5730\u88c2\u89e3\u4e86\u7a7a\u95f4\u4e0d\u53d7\u963b\u788d\u7684CH\u952e\u3002\u901a\u8fc7\u4f7f\u7528\u5149\u8bf1\u5bfc\u7684\u6c22\u539f\u5b50\u8f6c\u79fb\u7b56\u7565\uff0c\u8fd9\u79cd\u65e0\u91d1\u5c5e\u7684C(sp3)-H\u787c\u9178\u916f\u5316\u53ef\u4ee5\u5c06\u672a\u53cd\u5e94\u7684\u70f7\u70c3\u5728\u6e29\u548c\u7684\u6761\u4ef6\u4e0b\u8f6c\u5316\u4e3a\u6709\u4ef7\u503c\u7684\u6709\u673a\u787c\u8bd5\u5242\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n

Metal-free photoinduced C(sp3)<\/b><\/strong>–<\/b><\/strong>H borylation of alkanes<\/b><\/strong><\/p>\n

(<\/b><\/strong>Nature<\/b><\/strong>, 2020, <\/b><\/strong>DOI: <\/b><\/strong>10.1038\/s41586-020-2831-6)<\/b><\/strong><\/p>\n

4.<\/b><\/strong>\u52a0\u5dde\u5927\u5b66\u6d1b\u6749\u77f6\u5206\u6821Yi Tang\u3001K. N. Houk\u548c\u4e2d\u79d1\u9662\u6709\u673a\u6240\u5468\u4f73\u6d77<\/b><\/strong>:\u9176\u4fc3Alder-ene\u53cd\u5e94<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u5316\u5b66\u7814\u7a76\u4e2d\u7684\u4e00\u9879\u6301\u7eed\u6311\u6218\u662f\u8bbe\u8ba1\u80fd\u591f\u63a7\u5236\u590d\u6742\u5206\u5b50\u53cd\u5e94\u7684\u50ac\u5316\u5242\u3002\u5316\u5b66\u5bb6\u4f9d\u9760\u6709\u673a\u50ac\u5316\u5242\u6216\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5242\u6765\u63a7\u5236\u7acb\u4f53\u9009\u62e9\u6027\uff0c\u533a\u57df\u9009\u62e9\u6027\u548c\u5468\u5411\u9009\u62e9\u6027\uff08\u53ef\u80fd\u7684\u5468\u73af\u53cd\u5e94\u4e4b\u95f4\u7684\u9009\u62e9\u6027\uff09\u3002\u5927\u81ea\u7136\u53ef\u4ee5\u901a\u8fc7\u591a\u79cd\u9176\u6765\u5b9e\u73b0\u8fd9\u4e9b\u7c7b\u578b\u7684\u9009\u62e9\u6027\uff0c\u8fd9\u662f\u4e00\u79cd\u50ac\u5316\u5468\u73af\u53cd\u5e94\u7684\u9176\u5bb6\u65cf\u3002\u6700\u5178\u578b\u7684\u9176\u4fc3\u73af\u5468\u53cd\u5e94\u662f\u73af\u52a0\u6210\u53cd\u5e94\uff0c\u5f88\u96be\u5408\u7406\u5730\u5b9e\u73b0\u89c2\u5bdf\u5230\u7684\u9009\u62e9\u6027\u3002<\/p>\n

\u00a0\u52a0\u5dde\u5927\u5b66\u6d1b\u6749\u77f6\u5206\u6821Yi Tang\u3001K. N. Houk\u548c\u4e2d\u79d1\u9662\u6709\u673a\u6240\u5468\u4f73\u6d77<\/b><\/strong>\u53d1\u73b0\u4e86\u4e24\u4e2a\u540c\u6e90\u7684\u5468\u73af\u9176\u7ec4\uff0c\u5b83\u4eec\u50ac\u5316\u4e0d\u540c\u7684\u53cd\u5e94\uff1a\u4e00\u7ec4\u50ac\u5316\u5728\u751f\u7269\u5b66\u4e0a\u672a\u77e5\u7684Alder-ene\u53cd\u5e94\uff1b\u7b2c\u4e8c\u4e2a\u50ac\u5316\u7acb\u4f53\u9009\u62e9\u6027Diels-Alder\u53cd\u5e94\u3002\u5728\u8ba1\u7b97\u7814\u7a76\u7684\u6307\u5bfc\u4e0b\uff0c\u4f5c\u8005\u5408\u7406\u5316\u4e86\u89c2\u5bdf\u5230\u7684\u53cd\u5e94\u6027\u5dee\u5f02\uff0c\u5e76\u8bbe\u8ba1\u4e86\u7a81\u53d8\u9176\uff0c\u8fd9\u4e9b\u9176\u9006\u5411\u9009\u62e9\u6027\u4eceAlder-ene\u5230\u5f02Diels-Alder\uff0c\u53cd\u4e4b\u4ea6\u7136\u3002\u4f53\u5916\u751f\u5316\u8868\u5f81\uff0c\u8ba1\u7b97\u7814\u7a76\uff0c\u9176\u5171\u6676\u4f53\u7ed3\u6784\u548c\u7a81\u53d8\u7814\u7a76\u7684\u7ed3\u5408\u8bf4\u660e\u4e86\u5728\u51e0\u4e4e\u76f8\u540c\u7684\u6d3b\u6027\u4f4d\u70b9\u5982\u4f55\u5b9e\u73b0\u9ad8\u533a\u57df\u9009\u62e9\u6027\u548c\u5468\u9009\u62e9\u6027\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n

An enzymatic Alder-ene reaction<\/b><\/strong><\/p>\n

(Nature, 2020, <\/b><\/strong>DOI: <\/b><\/strong>10.1038\/s41586-020-2743-5)<\/b><\/strong><\/p>\n

5.<\/b><\/strong>\u52a0\u5dde\u5927\u5b66\u6d1b\u6749\u77f6\u5206\u6821K. N. Houk&Neil K. Garg:\u73af\u72b6\u8054\u70ef\u53c2\u4e0e\u7684\u4e0d\u5bf9\u79f0\u954d\u50ac\u5316<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u5e94\u53d8\u7684\u73af\u72b6\u6709\u673a\u5206\u5b50\uff0c\u4f8b\u5982\u82b3\u70c3\uff0c\u73af\u72b6\u7094\u70c3\u548c\u73af\u72b6\u70ef\uff0c\u56e0\u5176\u4e0d\u5bfb\u5e38\u7684\u7ed3\u6784\u548c\u9ad8\u5316\u5b66\u53cd\u5e94\u6027\u800c\u5f15\u8d77\u5316\u5b66\u5bb6\u7684\u5174\u8da3\u8d85\u8fc7\u4e00\u4e2a\u4e16\u7eaa\u3002\u8868\u5f81\u8fd9\u4e9b\u77ac\u65f6\u4e2d\u95f4\u4f53\u7684\u76f8\u5f53\u5927\u7684\u73af\u5e94\u53d8\u5728\u8bb8\u591a\u53cd\u5e94\u4e2d\u8d4b\u4e88\u4e86\u9ad8\u53cd\u5e94\u6d3b\u6027\uff0c\u901a\u5e38\u4f1a\u751f\u6210\u7ed3\u6784\u590d\u6742\u7684\u4ea7\u7269\u3002\u5c3d\u7ba1\u5df2\u7ecf\u62a5\u9053\u4e86\u4f7f\u7528\u5316\u5b66\u8ba1\u91cf\u624b\u6027\u8bd5\u5242\u63a7\u5236\u8fd9\u4e9b\u53cd\u5e94\u4e2d\u7edd\u5bf9\u7acb\u4f53\u5316\u5b66\u7684\u7b56\u7565\uff0c\u4f46\u4ecd\u7136\u96be\u4ee5\u5b9e\u73b0\u50ac\u5316\u4e0d\u5bf9\u79f0\u53d8\u4f53\u751f\u6210\u5bf9\u6620\u4f53\u5bcc\u96c6\u7684\u4ea7\u7269\u3002<\/p>\n

\u52a0\u5dde\u5927\u5b66\u6d1b\u6749\u77f6\u5206\u6821K. N. Houk&Neil K. Garg<\/b><\/strong>\u62a5\u9053\u5728\u50ac\u5316\u4e0d\u5bf9\u79f0\u53cd\u5e94\u4e2d\u5916\u6d88\u65cb\u73af\u72b6\u8054\u70ef\u4e2d\u95f4\u4f53\u7684\u622a\u83b7\uff0c\u5e76\u4e3a\u63a7\u5236\u8fd9\u79cd\u8f6c\u5316\u4e2d\u7684\u7edd\u5bf9\u7acb\u4f53\u5316\u5b66\u7684\u4e24\u79cd\u4e0d\u540c\u673a\u5236\u63d0\u4f9b\u4e86\u8bc1\u636e\uff1a\u73af\u72b6\u8054\u70ef\u5bf9\u6620\u5f02\u6784\u4f53\u7684\u52a8\u529b\u5b66\u5206\u5316\u548c\u4e2d\u95f4\u4f53\u03c0-\u70ef\u4e19\u57fa\u954d\u914d\u5408\u7269\u7684\u8131\u5bf9\u79f0\u3002\u8ba1\u7b97\u7814\u7a76\u6697\u793a\u4e86\u4e00\u79cd\u50ac\u5316\u673a\u7406\uff0c\u8be5\u673a\u7406\u6d89\u53ca\u901a\u8fc7\u7acb\u4f53\u9009\u62e9\u6027\u70ef\u70c3\u7684\u63d2\u5165\uff0c\u73af\u72b6\u8054\u70ef\u5bf9\u6620\u5f02\u6784\u4f53\u7684\u521d\u59cb\u52a8\u529b\u5b66\u5206\u5316\uff0c\u635f\u5931\u6240\u5f97\u7684\u7acb\u4f53\u5316\u5b66\u4fe1\u606f\uff0c\u4ee5\u53ca\u968f\u540e\u901a\u8fc7\u4e2d\u95f4\u03c0-\u70ef\u4e19\u57fa\u954d\u914d\u5408\u7269\u7684\u4e0d\u5bf9\u79f0\u5316\u5f15\u5165\u7edd\u5bf9\u7acb\u4f53\u5316\u5b66\u3002\u8fd9\u4e9b\u7ed3\u679c\u63ed\u793a\u4e86\u73af\u70ef\u5177\u6709\u7684\u53cd\u5e94\u6027\uff0c\u8d85\u8d8a\u4e86\u5148\u524d\u62a5\u9053\u7684\u4f20\u7edf\u73af\u52a0\u6210\u548c\u4eb2\u6838\u6355\u83b7\uff0c\u4ece\u800c\u6269\u5927\u4e86\u53ef\u4ece\u6b64\u7c7b\u4e2d\u95f4\u4f53\u83b7\u5f97\u7684\u4ea7\u54c1\u7c7b\u578b\u3002\u6b64\u5916\uff0c\u8ba1\u7b97\u7814\u7a76\u63d0\u51fa\u4e86\u4e24\u79cd\u6f5c\u5728\u7684\u7b56\u7565\uff0c\u7528\u4e8e\u63a7\u5236\u73af\u70ef\u53cd\u5e94\u4e2d\u7684\u7acb\u4f53\u63a7\u5236\u3002\u7ed3\u5408\u8d77\u6765\uff0c\u8fd9\u4e9b\u7ed3\u679c\u4e3a\u5f00\u53d1\u6d89\u53ca\u8fd9\u4e9b\u7ecf\u5178\u907f\u514d\u7684\u4e2d\u95f4\u4f53\u7684\u50ac\u5316\u4e0d\u5bf9\u79f0\u53cd\u5e94\u5960\u5b9a\u4e86\u57fa\u7840\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n

Intercepting fleeting cyclic allenes with asymmetric nickel catalysis.<\/b><\/strong><\/p>\n

(Nature, 2020, <\/b><\/strong>DOI: <\/b><\/strong>10.1038\/s41586-020-2701-2)<\/b><\/strong><\/p>\n

6.<\/b><\/strong>\u8036\u9c81\u5927\u5b66Patrick L. Holland<\/b><\/strong>:<\/b><\/strong>\u901a\u8fc7\u82b3\u57fa\u8fc1\u79fb\u8026\u5408\u4e8c\u6c2e\u548c\u78b3\u6c22\u5316\u5408\u7269<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u78b3\u6c22\u5316\u5408\u7269\u548c\u5927\u6c14\u6c2e\uff08N2<\/sub>\uff09\u7684\u6d3b\u5316\u4ecd\u7136\u662f\u4e00\u4e2a\u6311\u6218\uff0c\u56e0\u4e3a\u8fd9\u4e9b\u5206\u5b50\u901a\u5e38\u662f\u60f0\u6027\u7684\u3002\u7531N2<\/sub>\u5f62\u6210\u78b3-\u6c2e\u952e\u901a\u5e38\u9700\u8981\u5177\u6709\u53cd\u5e94\u6027\u7684\u6709\u673a\u524d\u4f53\uff0c\u8fd9\u4e9b\u524d\u4f53\u4e0e\u4fc3\u8fdbN2<\/sub>\u53cd\u5e94\u6027\u7684\u8fd8\u539f\u6761\u4ef6\u4e0d\u76f8\u5bb9\uff0c\u540e\u8005\u963b\u6b62\u4e86\u50ac\u5316\u4f5c\u7528\u3002<\/p>\n

\u8036\u9c81\u5927\u5b66Patrick L. Holland<\/b><\/strong>\u62a5\u9053\u4e86\u4e8c\u916e\u652f\u6301\u7684\u94c1\u7cfb\u7edf\uff0c\u8be5\u7cfb\u7edf\u4f9d\u6b21\u6fc0\u6d3b\u82ef\u548cN2<\/sub>\u4ee5\u5f62\u6210\u82ef\u80fa\u884d\u751f\u7269\u3002\u8be5\u5076\u8054\u53cd\u5e94\u7684\u5173\u952e\u662f\u8fd8\u539f\u7684\u94c1\u4e8c\u6c2e\u914d\u5408\u7269\u7684\u90e8\u5206\u7532\u7845\u70f7\u57fa\u5316\uff0c\u7136\u540e\u82ef\u884d\u751f\u7684\u82b3\u57fa\u8fc1\u79fb\u5230\u6c2e\u4e0a\u3002\u8fdb\u4e00\u6b65\u7684\u8fd8\u539f\u4f1a\u91ca\u653e\u51faN2<\/sub>\u884d\u751f\u7684\u82ef\u80fa\uff0c\u5e76\u4e14\u751f\u6210\u7684\u94c1\u7269\u8d28\u53ef\u4ee5\u91cd\u65b0\u8fdb\u5165\u5faa\u73af\u9014\u5f84\u3002\u901a\u8fc7\u4f7f\u7528\u94a0\u7c89\uff0c\u51a0\u919a\uff0c\u4e09\u7532\u57fa\u7532\u7845\u70f7\u57fa\u6eb4\u5316\u7269\u548cN2<\/sub>\u7684\u6df7\u5408\u7269\u4f5c\u4e3a\u6c2e\u6e90\uff0c\u6613\u4e8e\u5236\u5907\u7684\u4e8c\u916e\u5316\u6eb4\u5316\u94c1\u914d\u5408\u7269\u4ecb\u5bfc\u4e86\u51e0\u79cd\u77f3\u6cb9\u884d\u751f\u7684\u82b3\u70c3\u7684\u4e00\u9505\u8f6c\u5316\u4e3a\u76f8\u5e94\u7684\u7532\u7845\u70f7\u57fa\u5316\u82ef\u80fa\u884d\u751f\u7269\u3002\u6cbf\u5faa\u73af\u9014\u5f84\u7684\u8bb8\u591a\u5316\u5408\u7269\u5df2\u88ab\u5206\u79bb\u5e76\u8fdb\u884c\u6676\u4f53\u5b66\u8868\u5f81\uff0c\u5b83\u4eec\u7684\u53cd\u5e94\u6027\u652f\u6301\u4e86\u4f9d\u6b21\u8fdb\u884c\u70c3\u6d3b\u5316\u548cN2<\/sub>\u529f\u80fd\u5316\u7684\u673a\u5236\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n

Coupling dinitrogen and hydrocarbons through aryl migration.<\/b><\/strong><\/p>\n

(Nature, 2020, DOI: 10.1038\/s41586-020-2565-5)<\/b><\/strong><\/p>\n

7.<\/b><\/strong>\u66fc\u5f7b\u65af\u7279\u5927\u5b66Daniele Leonori:\u82ef\u80fa\u5408\u6210\u7684\u5149\u5316\u5b66\u8131\u6c22\u7b56\u7565<\/b><\/strong><\/p>\n

\u00a0\"\"<\/b><\/strong><\/p>\n

\u5c06\u4e24\u4e2a\u5206\u5b50\u7247\u6bb5\u8fde\u63a5\u5728\u4e00\u8d77\u7684\u5316\u5b66\u53cd\u5e94\uff08\u4ea4\u53c9\u5076\u8054\uff09\u5bf9\u4e8e\u53d1\u73b0\u548c\u5236\u9020\u836f\u7269\u548c\u519c\u7528\u5316\u5b66\u54c1\u81f3\u5173\u91cd\u8981\u3002\u76ee\u524d\u4ec5\u5728\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7684\u65b9\u6cd5\u4e2d\u624d\u80fd\u5c06\u80fa\u5f15\u5165\u5230\u7279\u5b9a\u4f4d\u7f6e\u548c\u9884\u5b9a\u4f4d\u7f6e\u7684\u5b98\u80fd\u5316\u82b3\u65cf\u5316\u5408\u7269\u4e0a\uff0c\u5e76\u4e14\u9700\u8981\u542b\u5364\u7d20\u6216\u787c\u7684\u5e95\u7269\u3002\u8fd9\u4e9b\u57fa\u56e2\u5728\u82b3\u65cf\u5355\u5143\u5468\u56f4\u7684\u5f15\u5165\u53d6\u51b3\u4e8e\u8be5\u65b9\u6cd5\u7684\u56fa\u6709\u53cd\u5e94\u6d3b\u6027\uff08\u4eb2\u7535\u5b50\u5364\u5316\u6216C-H\u787c\u5316\uff09\uff0c\u56e0\u6b64\u901a\u5e38\u4e0d\u53ef\u80fd\u5bf9\u6240\u6709\u4f4d\u7f6e\u8fdb\u884c\u9009\u62e9\u6027\u9776\u5411\u3002<\/p>\n

\u66fc\u5f7b\u65af\u7279\u5927\u5b66Daniele Leonori<\/b><\/strong>\u62a5\u9053\u4e86\u82ef\u80fa\u7684\u975e\u89c4\u8303\u4ea4\u53c9\u5076\u8054\u65b9\u6cd5\uff0c\u5229\u7528\u9971\u548c\u73af\u5df1\u916e\u4f5c\u4e3a\u4eb2\u7535\u4eb2\u7535\u5b50\u66ff\u4ee3\u7269\u3002\u80fa\u548c\u7fb0\u57fa\u4e4b\u95f4\u7684\u7f29\u5408\u662f\u81ea\u7136\u754c\u4e2d\u7ecf\u5e38\u53d1\u751f\u7684\u8fc7\u7a0b\uff0c\u6709\u673a\u5316\u5b66\u5bb6\u7ecf\u5e38\u4f7f\u7528\u8be5\u8fc7\u7a0b\uff0c\u53ef\u4ee5\u5f62\u6210\u9884\u5b9a\u7684\u4f4d\u70b9\u9009\u62e9\u6027\u78b3-\u6c2e\uff08C-N\uff09\u952e\uff0c\u800c\u5149-\u6c27\u5316\u8fd8\u539f\u548c\u94b4-\u57fa\u7684\u50ac\u5316\u4f53\u7cfb\u5728\u5230\u8fbe\u82ef\u80fa\u7684\u9014\u4e2d\u9010\u6e10\u4f7f\u73af\u5df1\u70ef\u73af\u8131\u9971\u548c\u3002\u9274\u4e8e\u53ef\u4ee5\u4f7f\u7528\u6210\u719f\u7684\u7fb0\u57fa\u53cd\u5e94\u6027\u901a\u8fc7\u5b8c\u5168\u7684\u533a\u57df\u63a7\u5236\u6765\u8f7b\u677e\u83b7\u5f97\u5b98\u80fd\u5316\u7684\u73af\u5df1\u916e\uff0c\u56e0\u6b64\u8be5\u65b9\u6cd5\u7ed5\u5f00\u4e86\u82b3\u9999\u65cf\u5316\u5b66\u4e2d\u4e00\u4e9b\u5e38\u89c1\u7684\u9009\u62e9\u6027\u95ee\u9898\u3002\u4f5c\u8005\u901a\u8fc7\u5236\u5907\u5546\u4e1a\u836f\u7269\u4ee5\u53ca\u5bf9\u5929\u7136\u4ea7\u7269\uff0c\u7c7b\u56fa\u9187\u548c\u841c\u70ef\u539f\u6599\u8fdb\u884c\u540e\u671f\u6c28\u57fa\u5316\u82b3\u9999\u5316\u6765\u8bc1\u660e\u8fd9\u79cdC-N\u5076\u8054\u65b9\u6848\u7684\u5b9e\u7528\u6027\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n

A photochemical dehydrogenative strategy for aniline synthesis.<\/b><\/strong><\/p>\n

(Nature, 2020, DOI: 10.1038\/s41586-020-2539-7)<\/b><\/strong><\/p>\n

8.<\/b><\/strong>\u4e1c\u4eac\u5de5\u4e1a\u5927\u5b66Masaaki Kitano&Hideo Hosono:\u7a7a\u4f4d\u6fc0\u6d3b\u7684N2<\/sub>\u6d3b\u5316\uff0c\u53ef\u5728\u8d1f\u8f7dNi\u7684\u50ac\u5316\u5242\u4e0a\u5408\u6210\u6c28<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u6c28\uff08NH3<\/sub>\uff09\u5bf9\u80a5\u6599\u884c\u4e1a\u81f3\u5173\u91cd\u8981\uff0c\u662f\u6700\u5e38\u751f\u4ea7\u7684\u5316\u5b66\u54c1\u4e4b\u4e00\u3002\u7531\u4e8e\u5176\u5927\u91cf\u7684\u952e\u80fd\uff0c\u76f4\u63a5\u4f7f\u7528\u5927\u6c14\u4e2d\u7684\u6c2e\uff08N2<\/sub>\uff09\u4e00\u76f4\u5177\u6709\u6311\u6218\u6027\uff0c\u76f4\u5230Haber-Bosch\u5de5\u827a\u5f97\u4ee5\u53d1\u5c55\u3002\u968f\u540e\uff0c\u4eba\u4eec\u63a2\u7d22\u4e86\u8bb8\u591a\u7b56\u7565\u6765\u51cf\u5c11N\u2261N\u952e\u7684\u6d3b\u5316\u52bf\u5792\u5e76\u4f7f\u8be5\u8fc7\u7a0b\u66f4\u6709\u6548\u3002\u8fd9\u4e9b\u63aa\u65bd\u5305\u62ec\u4f7f\u7528\u78b1\u91d1\u5c5e\u548c\u78b1\u571f\u91d1\u5c5e\u6c27\u5316\u7269\u4f5c\u4e3a\u4fc3\u8fdb\u5242\uff0c\u4ee5\u901a\u8fc7\u8fc7\u6e21\u91d1\u5c5e\u5c06\u7535\u5b50\u4ece\u4fc3\u8fdb\u5242\u8f6c\u79fb\u81f3N2<\/sub>\u7684\u53cd\u952e\uff0c\u4ece\u800c\u63d0\u9ad8\u4f20\u7edf\u7684\u94c1\u548c\u948c\u57fa\u50ac\u5316\u5242\u7684\u6027\u80fd\u3002\u9a7b\u6781\u4f53\u8f7d\u4f53\u8fdb\u4e00\u6b65\u964d\u4f4e\u4e86\u6fc0\u6d3b\u52bf\u5792\uff0c\u56e0\u4e3a\u5176\u4f4e\u529f\u51fd\u548c\u9ad8\u7535\u5b50\u5bc6\u5ea6\u589e\u5f3a\u4e86\u7535\u5b50\u5411\u8fc7\u6e21\u91d1\u5c5e\u7684\u8f6c\u79fb\u3002\u8fd9\u79cd\u7b56\u7565\u4fc3\u8fdb\u4e86N2<\/sub>\u5206\u89e3\u4ea7\u751f\u6c28\u7684\u5408\u6210\uff0c\u5e76\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\u5b9e\u73b0\u4e86\u50ac\u5316\u64cd\u4f5c\u3002\u4f46\u662f\uff0c\u5b83\u9700\u8981\u4f7f\u7528\u6602\u8d35\u7684\u948c\u3002\u76ee\u524d\u5df2\u7ecf\u53d1\u73b0\u5305\u542b\u8868\u9762\u6c2e\u7a7a\u4f4d\u7684\u6c2e\u5316\u7269\u53ef\u4ee5\u6d3b\u5316N2<\/sub>\u3002<\/p>\n

\u4e1c\u4eac\u5de5\u4e1a\u5927\u5b66Masaaki Kitano&Hideo Hosono<\/b><\/strong>\u53d1\u73b0\u7531\u4e8e\u907f\u514d\u4e86\u5e38\u89c1\u7684\u7ed3\u57a2\u5173\u7cfb\u7684\u53cc\u4f4d\u673a\u7406\uff0c\u954d\u8d1f\u8f7d\u7684\u6c2e\u5316\u9567\uff08LaN\uff09\u80fd\u591f\u5b9e\u73b0\u7a33\u5b9a\u4e14\u9ad8\u6548\u7684\u6c28\u5408\u6210\u3002\u52a8\u529b\u5b66\u548c\u540c\u4f4d\u7d20\u6807\u8bb0\u5b9e\u9a8c\u4ee5\u53ca\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u8bc1\u660e\uff0c\u6c2e\u7a7a\u4f4d\u662f\u5728\u4f4e\u5f62\u6210\u80fd\u7684LaN\u4e0a\u4ea7\u751f\u7684\uff0c\u5e76\u6709\u6548\u5730\u7ed3\u5408\u548c\u6d3b\u5316N2<\/sub>\u3002\u6b64\u5916\uff0c\u52a0\u8f7d\u5230\u6c2e\u5316\u7269\u4e0a\u7684\u954d\u91d1\u5c5e\u4f1a\u5206\u89e3H2<\/sub>\u3002\u4f7f\u7528\u4e0d\u540c\u7684\u4f4d\u70b9\u6d3b\u5316\u4e24\u79cd\u53cd\u5e94\u7269\u4ee5\u53ca\u5b83\u4eec\u4e4b\u95f4\u7684\u534f\u540c\u4f5c\u7528\uff0c\u5bfc\u81f4\u8d1f\u8f7d\u954d\u7684LaN\u50ac\u5316\u5242\u7684\u6d3b\u6027\u8fdc\u8fdc\u8d85\u8fc7\u4f20\u7edf\u7684\u94b4\u57fa\u548c\u954d\u57fa\u50ac\u5316\u5242\u7684\u6d3b\u6027\uff0c\u4e0e\u948c\u57fa\u50ac\u5316\u5242\u3002\u7ed3\u679c\u8bf4\u660e\u4e86\u5728\u53cd\u5e94\u5faa\u73af\u4e2d\u4f7f\u7528\u7a7a\u4f4d\u7684\u6f5c\u529b\uff0c\u5e76\u4ecb\u7ecd\u4e86\u4f7f\u7528\u81ea\u7136\u5bcc\u96c6\u5143\u7d20\u7684\u6c28\u5408\u6210\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u6982\u5ff5\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n

Vacancy-enabled N2 activation for ammonia synthesis on an Ni-loaded catalyst.<\/b><\/strong><\/p>\n

(Nature, 2020, DOI: 10.1038\/s41586-020-2464-9)<\/b><\/strong><\/p>\n

9.\u4f5b\u7f57\u91cc\u8fbe\u5dde\u7acb\u5927\u5b66<\/b><\/strong>&<\/b><\/strong>\u7ebd\u7ea6\u5dde\u7acb\u5927\u5b66\u5e03\u6cd5\u7f57\u5206\u6821<\/b><\/strong>&<\/b><\/strong>\u4e9a\u741b\u5de5\u4e1a\u5927\u5b66:\u5421\u54af\u70f7\u4e8c\u786b\u4ee3\u6c28\u57fa\u7532\u9178\u9514\u7684\u538b\u7f29\u53ef\u589e\u5f3a\u5171\u4ef7<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u9514\u5728\u5143\u7d20\u7cfb\u5217\u4e2d\u662f\u72ec\u7279\u7684\uff0c\u56e0\u4e3a\u5176\u534a\u653e\u7f29\u76845f7<\/sup>\u5916\u58f3\u6bd4\u5176\u4ed65fn<\/sup>\u914d\u7f6e\u5177\u6709\u66f4\u4f4e\u7684\u80fd\u91cf\uff0c\u4ece\u800c\u4f7f\u5176\u65e2\u4e0d\u5177\u6709\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\uff0c\u53c8\u4e0d\u6613\u5f62\u6210\u4e0e5f\u5916\u58f3\u63a5\u5408\u7684\u5316\u5b66\u952e\u3002\u5728\u9ad8\u538b\u4e0b\uff0c\u91d1\u5c5e\u9514\u7ecf\u5386\u4e86\u4ece\u5c40\u57df5f\u7535\u5b50\u5230\u8fed\u4ee3\u7535\u5b50\u7684\u8f6c\u53d8\u3002\u8fd9\u79cd\u8f6c\u53d8\u4f34\u968f\u7740\u7531\u9514\u539f\u5b50\u4e4b\u95f4\u7684\u78c1\u6027\u76f8\u4e92\u4f5c\u7528\u6240\u51b3\u5b9a\u7684\u6676\u4f53\u7ed3\u6784\u3002\u56e0\u6b64\uff0c\u4ea7\u751f\u4e86\u4e00\u4e2a\u95ee\u9898\uff0c\u5373\u662f\u5426\u53ef\u4ee5\u901a\u8fc7\u65bd\u52a0\u538b\u529b\u6765\u6539\u53d8cur\uff08iii\uff09-\u914d\u4f53\u76f8\u4e92\u4f5c\u7528\u4e2d\u7684\u524d\u6cbf\u91d1\u5c5e\u8f68\u9053\uff0c\u4ece\u800c\u4f7f\u5176\u8bf1\u5bfc\u5f62\u6210\u5177\u6709\u4e00\u5b9a\u5171\u4ef7\u5ea6\u7684\u91d1\u5c5e-\u914d\u4f53\u952e\u3002<\/p>\n

\u00a0\u4f5b\u7f57\u91cc\u8fbe\u5dde\u7acb\u5927\u5b66<\/b><\/strong>&<\/b><\/strong>\u7ebd\u7ea6\u5dde\u7acb\u5927\u5b66\u5e03\u6cd5\u7f57\u5206\u6821<\/b><\/strong>&<\/b><\/strong>\u4e9a\u741b\u5de5\u4e1a\u5927\u5b66<\/b><\/strong>\u62a5\u9053\u4e86\u5728\u9ad8\u538b\u4e0b[Cm(pydtc)4]-\u4e2d\u7684f\u786b\u952e\u4e2d5f\/6d\u8f68\u9053\u7684\u76f8\u5bf9\u4f5c\u7528\u53d8\u5316\u7684\u5b9e\u9a8c\u548c\u8ba1\u7b97\u8bc1\u636e\u3002\u5c06\u8fd9\u4e9b\u7ed3\u679c\u4e0e[Nd(pydtc)4<\/sub>]-\u548c\u4ec5\u5177\u6709\u9514\u6c27\u952e\u7684Cm\uff08iii\uff09\u7194\u4f53\u7684\u5149\u8c31\u8fdb\u884c\u6bd4\u8f83\u3002\u4e0e[Cm(pydtc)4<\/sub>]-\u5149\u8c31\u4e2d\u89c2\u5bdf\u5230\u7684\u53d8\u5316\u76f8\u6bd4\uff0c\u6240\u89c2\u5bdf\u5230[Nd(pydtc)4<\/sub>]-\u5438\u6536\u5149\u8c31\u4e2df-f\u8dc3\u8fc1\u548c\u9514\u7684f-f\u53d1\u5c04\u5149\u8c31\u4e2d\u7684\u8f83\u5c0f\u53d8\u5316\uff0c\u8fd9\u4e0e\u5176\u952e\u7684\u6027\u8d28\u7684\u8f83\u5c0f\u6270\u52a8\u6709\u5173\u3002\u8fd9\u4e9b\u7ed3\u679c\u8868\u660e\uff0c\u5728\u9ad8\u538b\u4e0b\uff0c\u91d1\u5c5e\u8f68\u9053\u5bf9\u9514\u786b\u952e\u7684\u8d21\u732e\u663e\u7740\u589e\u5f3a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n

Compression of curium pyrrolidine-dithiocarbamate enhances covalenc<\/b><\/strong>y<\/b><\/strong>.<\/b><\/strong><\/p>\n

(<\/b><\/strong>Nature<\/b><\/strong>, 2020, DOI:10.1038\/s41586-020-2479-2)<\/b><\/strong><\/p>\n

10.\u5a01\u65af\u5eb7\u661f\u5927\u5b66\u9ea6\u8fea\u900a\u5206\u6821Shannon S. Stahl:\u91cf\u8eab\u5b9a\u5236\u7684\u918c\u7c7b\u652f\u6301\u9ad8\u5468\u8f6c\u91cf\u7684Pd\u50ac\u5316\u5242\uff0c\u7528\u4e8eO2<\/sub>\u6c27\u5316C\u2013H\u82b3\u57fa\u5316<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u94af\uff08II\uff09\u50ac\u5316\u7684\u78b3\u6c22\uff08CH\uff09\u6c27\u5316\u53cd\u5e94\u53ef\u4ee5\u7528\u4e8e\u836f\u7269\uff0c\u519c\u7528\u5316\u5b66\u54c1\u548c\u5176\u4ed6\u590d\u6742\u6709\u673a\u5206\u5b50\u7684\u5408\u6210\u3002\u00a0\u7136\u800c\uff0c\u73b0\u6709\u65b9\u6cd5\u901a\u5e38\u5728\u9ad8\u94af\uff08Pd\uff09\u8d1f\u8f7d\uff08\u4f8b\u598210\u6469\u5c14\uff05\uff09\u4e0b\u8868\u73b0\u51fa\u4e0d\u826f\u7684\u50ac\u5316\u5242\u6027\u80fd\uff0c\u5e76\u4e14\u9700\u8981\uff08\u8d85\uff09\u5316\u5b66\u8ba1\u91cf\u7684\u6c27\u5316\u5242\uff0c\u4f8b\u5982\u82ef\u918c\u548c\u94f6\uff08I\uff09\u76d0\u3002<\/p>\n

\u5a01\u65af\u5eb7\u661f\u5927\u5b66\u9ea6\u8fea\u900a\u5206\u6821Shannon S. Stahl<\/b><\/strong>\u63a2\u8ba8\u4e86\u4ee3\u8868\u6027\u7684Pd\u50ac\u5316\u7684CH-H\u6c27\u5316\u82b3\u57fa\u5316\u53cd\u5e94\u7684\u673a\u7406\uff0c\u5e76\u9610\u660e\u4e86\u7834\u574f\u50ac\u5316\u5242\u6027\u80fd\u7684\u673a\u7406\uff0c\u5305\u62ec\u6d88\u8017\u5e95\u7269\u7684\u526f\u53cd\u5e94\u548c\u87af\u5408\u4f5c\u4e3a\u975e\u6d3b\u6027\u7269\u8d28\u7684\u50ac\u5316\u5242\u3002\u918c\u52a9\u50ac\u5316\u5242\u7684\u7cfb\u7edf\u8c03\u8282\u514b\u670d\u4e86\u8fd9\u4e9b\u6709\u5bb3\u7279\u5f81\u3002\u4f7f\u75282,5-\u4e8c\u53d4\u4e01\u57fa\u5bf9\u82ef\u918c\u53ef\u4ee5\u6709\u6548\u5730\u5229\u7528\u5206\u5b50\u6c27\u4f5c\u4e3a\u6c27\u5316\u5242\uff0c\u63d0\u9ad8\u53cd\u5e94\u6536\u7387\uff0c\u5e76\u901a\u8fc7Pd\u50ac\u5316\u5242\u63d0\u4f9b> 1900\u7684\u5468\u8f6c\u7387\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n

Tailored quinones support high-turnover Pd catalysts for oxidative C<\/b><\/strong>–<\/b><\/strong>H arylation with O2.<\/b><\/strong><\/p>\n

(Science, 2020, DOI: 10.1126\/science.abd108<\/b><\/strong>5<\/b><\/strong>)<\/b><\/strong><\/p>\n

11.\u52a0\u5dde\u5927\u5b66\u5723\u5df4\u5df4\u62c9\u5206\u6821Susannah L. Scott:\u901a\u8fc7\u4e32\u8054\u6c22\u89e3\/\u82b3\u6784\u5316\u5c06\u805a\u4e59\u70ef\u4e0a\u94fe\u6210\u957f\u94fe\u70f7\u57fa\u82b3\u70c3<\/b><\/strong>\u00a0\"\"<\/b><\/strong><\/p>\n

\u5f53\u524d\u7684\u5851\u6599\u751f\u4ea7\u89c4\u6a21\u4ee5\u53ca\u968f\u4e4b\u800c\u6765\u7684\u5e9f\u7269\u5904\u7406\u95ee\u9898\u4ee3\u8868\u4e86\u5316\u5b66\u5faa\u73af\u5229\u7528\u7684\u5927\u90e8\u5206\u672a\u5f00\u53d1\u7684\u673a\u4f1a\u3002\u5728\u4e0d\u6dfb\u52a0\u6eb6\u5242\u6216\u5206\u5b50\u6c22\u7684\u60c5\u51b5\u4e0b\uff0c\u8d1f\u8f7d\u5728\u6c27\u5316\u94dd\u4e0a\u7684\u94c2\u8fdb\u884c\u7684\u4e32\u8054\u50ac\u5316\u8f6c\u5316\u5c06\u9ad8\u6536\u7387\uff08\u6700\u9ad880\uff05\u91cd\u91cf\u767e\u5206\u6bd4\uff09\u7684\u5404\u79cd\u805a\u4e59\u70ef\u7b49\u7ea7\u8f6c\u5316\u4e3a\u4f4e\u5206\u5b50\u91cf\u6db2\u4f53\/\u8721\u4ea7\u54c1\uff0c\u51e0\u4e4e\u4e0d\u4ea7\u751f\u8f7b\u8d28\u6c14\u4f53\u3002\u4e3b\u8981\u6210\u5206\u662f\u6709\u4ef7\u503c\u7684\u957f\u94fe\u70f7\u57fa\u82b3\u70c3\u548c\u70f7\u57fa\u73af\u70f7\u70c3\u3002\u5c3d\u7ba1\u53cd\u5e94\u6e29\u5ea6\u9002\u4e2d\u4e8e280\u00b0C\uff0c\u4f46\u653e\u70ed\u6c22\u89e3\u4e0e\u5438\u70ed\u82b3\u6784\u5316\u7684\u8026\u5408\u4f7f\u5f97\u6574\u4e2a\u8f6c\u5316\u8fc7\u7a0b\u5728\u70ed\u529b\u5b66\u4e0a\u662f\u53ef\u53ca\u7684\u3002\u8be5\u65b9\u6cd5\u8bc1\u660e\u4e86\u5e9f\u805a\u70ef\u70c3\u5982\u4f55\u6210\u4e3a\u751f\u4ea7\u5206\u5b50\u70c3\u4ea7\u54c1\u7684\u53ef\u884c\u539f\u6599\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n

Polyethylene upcycling to long-chain alkylaromatics by tandem hydrogenolysis\/aromatization.<\/b><\/strong><\/p>\n

(Science, 2020, DOI: 10.1126\/science.abc5441)<\/b><\/strong><\/p>\n

12.\u97e9\u56fd\u79d1\u5b66\u6280\u672f\u9662Sang Woo Han&Mu-Hyun Baik:\u7535\u611f\u5e94\u6548\u5e94<\/b><\/strong>\u2014\u2014<\/b><\/strong>\u7535\u6781\u4f5c\u4e3a\u5177\u6709\u53ef\u8c03\u7535\u5b50\u7279\u6027\u7684\u5b98\u80fd\u56e2<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u4ee3\u66ff\u65bd\u52a0\u4e0d\u540c\u611f\u5e94\u4f5c\u7528\u7684\u5b98\u80fd\u56e2\uff0c\u97e9\u56fd\u79d1\u5b66\u6280\u672f\u9662Sang Woo Han&Mu-Hyun Baik<\/b><\/strong>\u5c06\u643a\u5e26\u5def\u57fa\u7684\u5206\u5b50\u56fa\u5b9a\u5728\u91d1\u7535\u6781\u4e0a\u3002\u901a\u8fc7\u65bd\u52a0\u4e0d\u540c\u7684\u7535\u538b\uff0c\u53ef\u4ee5\u8c03\u8282\u56fa\u5b9a\u5206\u5b50\u7684\u6027\u8d28\u3002\u901a\u8fc7\u65bd\u52a0\u76f8\u5bf9\u4e8e\u5f00\u8def\u7535\u52bf\u7684\u20130.25\u4f0f\u7279\u7684\u8d1f\u7535\u538b\uff0c\u53ef\u4ee5\u5b8c\u5168\u6291\u5236\u78b1\u50ac\u5316\u7684\u82ef\u7532\u9178\u916f\u7682\u5316\u3002\u6b64\u5916\uff0c\u5f53\u5c06\u82b3\u57fa\u5364\u5316\u7269\u886c\u5e95\u56fa\u5b9a\u5728\u91d1\u7535\u6781\u4e0a\u65f6\uff0c\u53ef\u4ee5\u901a\u8fc7\u65bd\u52a0\u7535\u538b\u6765\u6539\u53d8\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u7684\u901f\u7387\u3002\u6700\u540e\uff0c\u663e\u793a\u51fa\u4e24\u6b65\u7fa7\u9178\u9170\u80fa\u5316\u53d7\u76ca\u4e8e\u6dfb\u52a0\u78b3\u4e8c\u4e9a\u80fa\u5076\u8054\u5242\u548c\u5f15\u5165\u80fa\u4e4b\u95f4\u7684\u65bd\u52a0\u7535\u538b\u7684\u5207\u6362\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n

Electro-inductive effect: Electrodes as functional groups with tunable electronic properties.<\/b><\/strong><\/p>\n

(Science, 2020, DOI: 10.1126\/science.abb6375)<\/b><\/strong><\/p>\n

13.\u683c\u62c9\u65af\u54e5\u5927\u5b66Leroy Cronin<\/b><\/strong>\uff1a<\/b><\/strong>\u7528\u4e8e\u5316\u5b66\u5408\u6210\u6587\u732e\u6570\u5b57\u5316\u548c\u81ea\u52a8\u6267\u884c\u7684\u901a\u7528\u7cfb\u7edf<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u7528\u4e8e\u5316\u5b66\u5408\u6210\u7684\u673a\u5668\u4eba\u7cfb\u7edf\u8d8a\u6765\u8d8a\u6d41\u884c\uff0c\u4f46\u662f\u7531\u4e8e\u7f3a\u4e4f\u6807\u51c6\u7684\u64cd\u4f5c\u7cfb\u7edf\u6216\u65e0\u6cd5\u901a\u8fc7\u81ea\u7136\u8bed\u8a00\u5904\u7406\u76f4\u63a5\u8bbf\u95ee\u6587\u732e\u7684\u80fd\u529b\uff0c\u56e0\u6b64\u53ef\u80fd\u96be\u4ee5\u8fd0\u884c\u548c\u7ef4\u62a4\u3002\u683c\u62c9\u65af\u54e5\u5927\u5b66Leroy Cronin<\/b><\/strong>\u5c55\u793a\u4e86\u4e00\u79cd\u53ef\u6269\u5c55\u7684\u5316\u5b66\u6267\u884c\u67b6\u6784\uff0c\u8be5\u67b6\u6784\u53ef\u4ee5\u901a\u8fc7\u81ea\u52a8\u9605\u8bfb\u6587\u732e\u6765\u586b\u5145\uff0c\u4ece\u800c\u5b9e\u73b0\u4e86\u901a\u7528\u7684\u81ea\u4e3b\u5de5\u4f5c\u6d41\u7a0b\u3002\u65e0\u9700\u4efb\u4f55\u7f16\u7a0b\u77e5\u8bc6\uff0c\u5c31\u53ef\u4ee5\u7528\u81ea\u7136\u8bed\u8a00\u7ea0\u6b63\u673a\u5668\u4eba\u7efc\u5408\u4ee3\u7801\uff0c\u5e76\u4e14\u7531\u4e8e\u8be5\u6807\u51c6\uff0c\u5b83\u662f\u72ec\u7acb\u4e8e\u786c\u4ef6\u7684\u3002\u7136\u540e\uff0c\u53ef\u4ee5\u5c06\u8be5\u5316\u5b66\u4ee3\u7801\u4e0e\u63cf\u8ff0\u786c\u4ef6\u6a21\u5757\u7684\u56fe\u5f62\u7ed3\u5408\u8d77\u6765\uff0c\u5e76\u7f16\u8bd1\u6210\u7279\u5b9a\u4e8e\u5e73\u53f0\u7684\u4f4e\u7ea7\u673a\u68b0\u624b\u6307\u4ee4\u4ee5\u6267\u884c\u3002\u6587\u7ae0\u5c55\u793a\u4e86\u6765\u81ea\u6587\u732e\u768412\u79cd\u5316\u5408\u7269\u7684\u81ea\u52a8\u5408\u6210\uff0c\u5305\u62ec\u6b62\u75db\u836f\u5229\u591a\u5361\u56e0\uff0c\u9ad8\u7898\u70f7\u6c27\u5316\u8bd5\u5242\u548c\u6c1f\u5316\u5242AlkylFluor\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n

A universal system for digitization and automatic execution of the chemical synthesis literature.<\/b><\/strong><\/p>\n

(<\/b><\/strong>Science<\/b><\/strong>, 2020, DOI: 10.1126\/science.abc2986)<\/b><\/strong><\/p>\n

14.<\/b><\/strong>\u5317\u6d77\u9053\u5927\u5b66Masaya Sawamura:\u8102\u80aa\u65cf\u9170\u80fa\u548c\u916f\u4e0e\u6a21\u5757\u5316\u94f1\u50ac\u5316\u5242\u7684\u4e0d\u5bf9\u79f0\u8fdc\u7a0bC-H\u787c\u5316<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u5728C\u2013H\u952e\u5b98\u80fd\u5316\u5316\u5b66\u4e2d\uff0c\u5c24\u5176\u662f\u5728\u7ebf\u6027\u8102\u65cf\u9971\u548c\u70c3\u9aa8\u67b6\u4e2d\uff0c\u4f4d\u70b9\u9009\u62e9\u6027\u548c\u7acb\u4f53\u63a7\u5236\u4ecd\u7136\u662f\u4e3b\u8981\u6311\u6218\u3002\u5317\u6d77\u9053\u5927\u5b66Masaya Sawamura<\/b><\/strong>\u62a5\u9053\u4e86\u8fdc\u7a0bC(sp3)\u2013H\u952e\u4e0e\u8102\u65cf\u4ef2\u548c\u53d4\u9170\u80fa\u548c\u916f\u4e2d\u7684\u7fb0\u57fa\u7684\u9ad8\u5ea6\u5bf9\u6620\u9009\u62e9\u6027\u548c\u4f4d\u70b9\u9009\u62e9\u6027\u50ac\u5316\u787c\u5316\u3002\u624b\u6027CH\u6d3b\u5316\u50ac\u5316\u5242\u7531\u94f1\u4e2d\u5fc3\uff0c\u624b\u6027\u5355\u4e9a\u78f7\u9178\u916f\u914d\u4f53\uff0c\u975e\u624b\u6027\u8132-\u5421\u5576\u53d7\u4f53\u914d\u4f53\u548c\u9891\u54ea\u9187\u787c\u70f7\u57fa\u7ec4\u6210\u3002\u91cf\u5b50\u5316\u5b66\u8ba1\u7b97\u652f\u6301\u7531\u50ac\u5316\u5242\u7ec4\u5206\u5f62\u6210\u7684\u9176\u6837\u7ed3\u6784\u8154\uff0c\u8be5\u50ac\u5316\u5242\u8154\u901a\u8fc7\u591a\u79cd\u975e\u5171\u4ef7\u76f8\u4e92\u4f5c\u7528\u7ed3\u5408\u5e95\u7269\u3002\u8bc1\u5b9e\u4e86\u5bf9\u6620\u4f53\u5bcc\u96c6\u7684\u787c\u70f7\u57fa\u7fa7\u9178\u884d\u751f\u7269\u7684\u591a\u529f\u80fd\u5408\u6210\u7528\u9014\u3002\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n

Asymmetric remote C<\/b><\/strong>–<\/b><\/strong>H borylation of aliphatic amides and esters with a modular iridium catalyst.<\/b><\/strong><\/p>\n

(Science, 2020, DOI: 10.1126\/science.abc8320)<\/b><\/strong><\/p>\n

15<\/b><\/strong>.\u65af\u514b\u5229\u666e\u65af\u7814\u7a76\u6240Hans Renata:\u901a\u8fc7\u6df7\u5408\u6c27\u5316\u6cd5\u53d1\u6563\u5408\u6210\u590d\u6742\u7684\u4e8c\u841c<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u591a\u73af\u4e8c\u841c\u663e\u793a\u51fa\u8bb8\u591a\u91cd\u8981\u7684\u751f\u7269\u5b66\u6d3b\u6027\uff0c\u4f46\u662f\u7531\u4e8e\u5176\u7ed3\u6784\u590d\u6742\u6027\uff0c\u4ece\u5934\u5408\u6210\u5408\u6210\u8fd9\u4e9b\u5206\u5b50\u5177\u6709\u5f88\u9ad8\u7684\u6311\u6218\u6027\u3002\u7531\u4e8e\u7f3a\u4e4f\u7528\u4e8e\u652f\u67b6\u4fee\u9970\u7684\u5316\u5b66\u5de5\u5177\uff0c\u534a\u5408\u6210\u9014\u5f84\u4e5f\u53d7\u5230\u9650\u5236\u3002\u65af\u514b\u5229\u666e\u65af\u7814\u7a76\u6240Hans Renata<\/b><\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u5316\u5b66\u9176\u5b66\u5e73\u53f0\uff0c\u53ef\u901a\u8fc7\u7b56\u7565\u6027\u5730\u7ed3\u5408\u5316\u5b66\u548c\u9176\u4fc3\u6c27\u5316\u65b9\u6cd5\u7684\u6df7\u5408\u6c27\u5316\u65b9\u6cd5\u6765\u83b7\u5f97\u9ad8\u5ea6\u6c27\u5316\u7684\u4e8c\u841c\u3002\u8fd9\u79cd\u65b9\u6cd5\u53ef\u4ee5\u9009\u62e9\u6027\u6c27\u5316\u4eb2\u672c\u78b3\u73af\u4e0a\u4ee5\u524d\u65e0\u6cd5\u63a5\u8fd1\u7684\u4f4d\u70b9\uff0c\u5e76\u4f7f\u975e\u751f\u7269\u9aa8\u67b6\u91cd\u6392\u6210\u4e3a\u5176\u4ed6\u57fa\u7840\u7ed3\u6784\u3002\u4f5c\u8005\u4ece\u751c\u83ca\u9187\u4e2d\u5408\u6210\u4e86\u4e5d\u79cd\u5177\u6709\u5bcc\u6c27\u5316\u6a21\u5f0f\u548c\u9aa8\u9abc\u591a\u6837\u6027\u7684\u590d\u6742\u5929\u7136\u4ea7\u7269\uff0c\u5171\u8ba1\u5341\u6b65\u4ee5\u5185\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n

Divergent synthesis of complex diterpenes through a hybrid oxidative approach.<\/b><\/strong><\/p>\n

(Science, 2020, DOI: 10.1126\/science.abb8271)<\/b><\/strong><\/p>\n

16.\u897f\u8499\u83f2\u838e\u5927\u5b66Robert Britton:\u6838\u82f7\u9178\u7c7b\u4f3c\u7269\u7684\u4ece\u5934\u5f00\u59cb\u5408\u6210<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u6838\u82f7\u7c7b\u4f3c\u7269\u901a\u5e38\u7528\u4e8e\u6cbb\u7597\u764c\u75c7\u548c\u75c5\u6bd2\u611f\u67d3\u3002\u5b83\u4eec\u7684\u5408\u6210\u5f97\u76ca\u4e8e\u6570\u5341\u5e74\u7684\u7814\u7a76\uff0c\u4f46\u5f80\u5f80\u4f9d\u8d56\u4e8e\u624b\u6027\u78b3\u6c34\u5316\u5408\u7269\u539f\u6599\u7684\u6709\u9650\u50a8\u5907\u3002\u897f\u8499\u83f2\u838e\u5927\u5b66Robert Britton<\/b><\/strong>\u63d0\u51fa\u4e86\u4e00\u79cd\u4ece\u7b80\u5355\u7684\u975e\u624b\u6027\u6750\u6599\u5feb\u901f\u6784\u5efa\u6838\u82f7\u7c7b\u4f3c\u7269\u7684\u8fc7\u7a0b\u3002\u4ec5\u4f7f\u7528\u812f\u6c28\u9178\u50ac\u5316\uff0c\u5c06\u6742\u82b3\u57fa\u53d6\u4ee3\u7684\u4e59\u919b\u8fdb\u884c\u6c1f\u5316\uff0c\u7136\u540e\u5728\u5355\u9505\u53cd\u5e94\u4e2d\u76f4\u63a5\u53c2\u4e0e\u5bf9\u6620\u9009\u62e9\u6027\u919b\u9187\u7f29\u5408\u53cd\u5e94\u3002\u968f\u540e\u7684\u5206\u5b50\u5185\u6c1f\u5316\u7269\u7f6e\u6362\u53cd\u5e94\u63d0\u4f9b\u4e86\u529f\u80fd\u5316\u7684\u6838\u82f7\u7c7b\u4f3c\u7269\u3002D-\u6216L-\u6838\u82f7\u7c7b\u4f3c\u7269\uff0c\u9501\u5b9a\u7684\u6838\u9178\uff0c\u4e9a\u6c28\u57fa\u6838\u82f7\u4ee5\u53caC2′-\u548cC4′-\u4fee\u9970\u7684\u6838\u82f7\u7c7b\u4f3c\u7269\u7684\u591a\u8c31\u5408\u6210\u6cd5\u7a81\u51fa\u4e86\u8be5\u8fc7\u7a0b\u7684\u591a\u529f\u80fd\u6027\u3002\u8fd9\u79cd\u4ece\u5934\u5f00\u59cb\u7684\u5408\u6210\u4e3a\u591a\u6837\u6027\u7684\u5236\u5907\u521b\u9020\u4e86\u673a\u4f1a\uff0c\u5e76\u5c06\u652f\u6301\u836f\u7269\u53d1\u73b0\u548c\u5f00\u53d1\u65b9\u9762\u7684\u5de5\u4f5c\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n

A short de novo synthesis of nucleoside analogs.<\/b><\/strong><\/p>\n

(Science, 2020, DOI: 10.1126\/science.abb3231)<\/b><\/strong><\/p>\n

17.<\/b><\/strong>\u963f\u5c14\u4f2f\u5854\u5927\u5b66Rylan J. Lundgren\uff1a\u5728\u4e8c\u7532\u57fa\u7532\u9170\u80fa\u6eb6\u6db2\u4e2d\u7531\u7a33\u5b9a\u7684\u6709\u673a\u9178\u76f4\u63a5\u53ef\u9006\u8131\u7fa7<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u6709\u673a\u5316\u5b66\u4e2d\u8bb8\u591a\u7ecf\u5178\u7684\u548c\u65b0\u5174\u7684\u65b9\u6cd5\u5b66\u90fd\u4f9d\u9760\u4e8c\u6c27\u5316\u78b3\uff08CO2<\/sub>\uff09\u7684\u6324\u538b\u6765\u751f\u6210\u53cd\u5e94\u6027\u4e2d\u95f4\u4f53\uff0c\u4ee5\u5f62\u6210\u952e\u3002\u6d89\u53ca\u5fae\u89c2\u53cd\u8f6c\u7684\u5408\u6210\u53cd\u5e94-\u53cd\u5e94\u6027\u4e2d\u95f4\u4f53\u7684\u7fa7\u5316\u53cd\u5e94\u901a\u5e38\u662f\u5728\u975e\u5e38\u4e0d\u540c\u7684\u6761\u4ef6\u4e0b\u8fdb\u884c\u7684\u3002\u963f\u5c14\u4f2f\u5854\u5927\u5b66Rylan J. Lundgren<\/b><\/strong>\u62a5\u9053\u8bf4\uff0c\u5316\u5b66\u7a33\u5b9a\u7684C(sp3)\u7fa7\u9178\u76d0\uff0c\u5982\u82b3\u9178\u548c\u4e19\u4e8c\u9178\u534a\u916f\uff0c\u5728\u4e8c\u7532\u57fa\u7532\u9170\u80fa\u6eb6\u6db2\u4e2d\u7ecf\u5386\u672a\u50ac\u5316\u7684\u53ef\u9006\u8131\u7fa7\u4f5c\u7528\u3002\u8131\u7fa7-\u7fa7\u5316\u53d1\u751f\u4e8e\u5728\u5176\u4ed6\u76f8\u540c\u6761\u4ef6\u4e0b\u5bf9bronster\u9178\u7684\u539f\u8131\u7fa7\u5177\u6709\u6297\u6027\u7684\u5e95\u7269\u3002\u540c\u4f4d\u7d20\u6807\u8bb0\u7684\u7fa7\u9178\u53ef\u901a\u8fc7\u7b80\u5355\u5730\u63d0\u4f9b13<\/sup>CO2<\/sub>\u6c14\u6c1b\u4ee5\u5728\u6781\u6027\u975e\u8d28\u5b50\u4f20\u9012\u6eb6\u5242\u4e2d\u4f7f\u7fa7\u9178\u76d0\u5f62\u6210\uff0c\u4ece\u800c\u4ee5\u9ad8\u5316\u5b66\u548c\u540c\u4f4d\u7d20\u4ea7\u7387\u5236\u5907\u3002\u5bf9\u6eb6\u6db2\u4e2d\u7fa7\u9178\u76d0\u53cd\u5e94\u6027\u7684\u4e86\u89e3\u4e3a\u6355\u83b7\u919b\uff0c\u916e\u548ca,b-\u4e0d\u9971\u548c\u916f\u63d0\u4f9b\u4e86\u6761\u4ef6\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n

Direct reversible decarboxylation from stable organic acids in dimethylformamide solution.<\/b><\/strong><\/p>\n

(Science, 2020, DOI: 10.1126\/science.abb412<\/b><\/strong>9<\/b><\/strong>)<\/b><\/strong><\/p>\n

1<\/b><\/strong>8<\/b><\/strong>.<\/b><\/strong>\u660e\u65af\u7279\u5927\u5b66John J. Molloy&Ryan Gilmour:\u901a\u8fc7\u9009\u62e9\u6027\u80fd\u91cf\u8f6c\u79fb\u50ac\u5316\u5b9e\u73b0\u787c\u7684\u70ef\u70c3\u7684\u51e0\u4f55\u5f02\u6784<\/b><\/strong><\/p>\n

\"\"\u00a0<\/b><\/strong><\/p>\n

\u57fa\u4e8e\u5f02\u6784\u5316\u7684\u7b56\u7565\uff0c\u80fd\u591f\u4f7f\u7531\u51e0\u4f55\u5b9a\u4e49\u7684\u70ef\u70c3\u5173\u952e\u6784\u5f62\u7684\u590d\u6742\u591a\u70ef\u7acb\u4f53\u53d1\u6563\u5730\u6784\u5efa\u4ecd\u7136\u660e\u663e\u6b20\u53d1\u8fbe\u3002\u7406\u60f3\u5316\u7684\u4f4e\u5206\u5b50\u91cf\u524d\u4f53\u4e2d\u5bf9\u539f\u5b50\u6548\u7387\u7684\u8003\u8651\uff0c\u8fdb\u4e00\u6b65\u51cf\u8f7b\u4e86\u5f02\u6784\u5316\u56fa\u6709\u7684\u70ed\u529b\u5b66\u7ea6\u675f\u3002\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u660e\u65af\u7279\u5927\u5b66John J. Molloy&Ryan Gilmour<\/b><\/strong>\u62a5\u544a\u4e86\u4e00\u4e2a\u901a\u7528\u7684C3\u652f\u67b6\uff0c\u8be5\u652f\u67b6\u53ef\u4ee5\u5f02\u6784\u5316\u5e76\u53cc\u5411\u6269\u5c55\u3002\u57fa\u4e8e\u9ad8\u6548\u7684\u4e09\u91cd\u6001\u80fd\u91cf\u8f6c\u79fb\uff0c\u03b2-\u787c\u57fa\u4e19\u70ef\u9178\u916f\u7684\u9009\u62e9\u6027\u5f02\u6784\u5316\u53d6\u51b3\u4e8e\u787cp\u8f68\u9053\u5728\u5e95\u7269\u751f\u8272\u56e2\u4e2d\u7684\u53c2\u4e0e\u3002\u4ea7\u54c1\u4e2d\u7684C(sp2)\u2013B\u952e\u65cb\u8f6c90\u00b0\u4f1a\u5bfc\u81f4\u91cd\u65b0\u52b1\u78c1\u6548\u7387\u4f4e\u4e0b\u5e76\u8d4b\u4e88\u65b9\u5411\u6027\u3002\u8fd9\u79cd\u5fae\u5999\u7684\u7acb\u4f53\u7535\u5b50\u95e8\u63a7\u673a\u5236\u53ef\u5b9e\u73b0\u6e05\u6670\u5b9a\u4e49\u7684\u89c6\u9ec4\u9178\u884d\u751f\u7269\u7684\u7acb\u4f53\u63a7\u5236\u5408\u6210\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n

Boron-enabled geometric isomerization of alkenes via selective energy-transfer catalysis.<\/b><\/strong><\/p>\n

(Science, 2020, DOI: 10.1126\/science.abb7235)<\/b><\/strong><\/p>\n

1<\/b><\/strong>9<\/b><\/strong>.\u57c3\u56e0\u970d\u82ac\u7406\u5de5\u5927\u5b66Timothy No\u00ebl\uff1a<\/b><\/strong>\u5149\u50ac\u5316<\/b><\/strong>\u8f7b\u8d28\u70c3\u7684C<\/b><\/strong>(<\/b><\/strong>sp3<\/b><\/strong>)-<\/b><\/strong>H<\/b><\/strong>\u5b98\u80fd\u5316<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u6c14\u6001\u70c3\u7684\u76f4\u63a5\u6d3b\u5316\u4ecd\u7136\u662f\u5316\u5b66\u754c\u7684\u4e3b\u8981\u6311\u6218\u3002\u7531\u4e8e\u8fd9\u4e9b\u5316\u5408\u7269\u7684\u56fa\u6709\u60f0\u6027\uff0c\u901a\u5e38\u9700\u8981\u82db\u523b\u7684\u53cd\u5e94\u6761\u4ef6\u624d\u80fd\u88c2\u89e3C(sp3)\u2013H\u952e\uff0c\u9664\u975e\u5728\u5408\u6210\u6709\u673a\u5316\u5b66\u4e2d\u6709\u6f5c\u5728\u7684\u5e94\u7528\u3002\u57c3\u56e0\u970d\u82ac\u7406\u5de5\u5927\u5b66Timothy No\u00ebl<\/b><\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u901a\u7528\u4e14\u6e29\u548c\u7684\u7b56\u7565\uff0c\u8be5\u65b9\u6cd5\u662f\u5728\u5ba4\u6e29\u4e0b\u4f7f\u7528\u5ec9\u4ef7\u7684\u7678\u4e8c\u9178\u76d0\u4f5c\u4e3a\u5149\u50ac\u5316\u5242\uff0c\u901a\u8fc7\u6c22\u539f\u5b50\u8f6c\u79fb\u6765\u6fc0\u6d3b\u7532\u70f7\uff0c\u4e59\u70f7\uff0c\u4e19\u70f7\u548c\u5f02\u4e01\u70f7\u4e2d\u7684C(sp3)\u2013H\u952e\u3002\u76f8\u5e94\u7684\u4ee5\u78b3\u4e3a\u4e2d\u5fc3\u7684\u81ea\u7531\u57fa\u53ef\u4ee5\u88ab\u591a\u79cd\u8fc8\u514b\u5c14\u53d7\u4f53\u6709\u6548\u5730\u6355\u83b7\uff0c\u4ece\u800c\u4ee5\u826f\u597d\u7684\u5206\u79bb\u6536\u7387\u548c\u9ad8\u9009\u62e9\u6027\u4ea7\u751f\u76f8\u5e94\u7684\u52a0\u6c22\u70f7\u57fa\u5316\u52a0\u5408\u7269\uff0838\u4e2a\u5b9e\u4f8b\uff09\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n

C(sp3)<\/b><\/strong>–<\/b><\/strong>H functionalizations of light hydrocarbons using decatungstate photocatalysis in flow.<\/b><\/strong><\/p>\n

(Science, 2020, DOI: 10.1126\/science.abb4688)<\/b><\/strong><\/p>\n

\u672c\u6587\u7531tt\u4f9b\u7a3f\u3002<\/p>\n

\u672c\u5185\u5bb9\u4e3a\u4f5c\u8005\u72ec\u7acb\u89c2\u70b9\uff0c\u4e0d\u4ee3\u8868\u6750\u6599\u4eba\u7f51\u7acb\u573a\u3002<\/p>\n

\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n

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