{"id":216703,"date":"2021-01-26T06:28:45","date_gmt":"2021-01-25T22:28:45","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=216703"},"modified":"2021-01-25T22:28:53","modified_gmt":"2021-01-25T14:28:53","slug":"mof%e7%9a%84%e4%b8%8d%e7%a8%b3%e5%ae%9a%e6%80%a7%e5%8a%a9%e5%8a%9b%e6%96%b0%e5%9e%8b%e6%9d%90%e6%96%99%e5%88%b6%e5%a4%87","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=216703","title":{"rendered":"MOF\u7684\u4e0d\u7a33\u5b9a\u6027\u52a9\u529b\u65b0\u578b\u6750\u6599\u5236\u5907"},"content":{"rendered":"<p><strong><b>\u5f15\u8a00<\/b><\/strong><\/p>\n<p>\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08MOFs\uff09\u662f\u5177\u6709\u9ad8\u7ed3\u6676\u5ea6\u3001\u9ad8\u8868\u9762\u79ef\u548c\u7ec4\u5206\u53ef\u8c03\u6027\u7684\u70ed\u95e8\u6750\u6599\u3002\u8fd9\u79cd\u6750\u6599\u5728\u5316\u5b66\u3001\u70ed\u3001\u5149\u7b49\u5916\u6e90\u523a\u6fc0\u4e0b\uff0c\u5bb9\u6613\u88ab\u7834\u574f\uff0c\u9650\u5236\u4e86\u5176\u8fdb\u4e00\u6b65\u53d1\u5c55\u3002\u7136\u800c\uff0c\u5229\u7528\u8fd9\u4e00\u4e0d\u7a33\u5b9a\u6027\u8d28\uff0c\u4e5f\u53ef\u4ee5\u6784\u5efa\u591a\u79cdMOF\u884d\u751f\u6750\u6599\u3002\u901a\u8fc7\u8fd9\u7bc7\u6587\u7ae0\u6765\u770b\u770bMOF\u7684\u4e0d\u7a33\u5b9a\u6027\u5982\u4f55\u52a9\u529b\u65b0\u578b\u6750\u6599\u6784\u5efa\u5427\u3002<\/p>\n<p><strong><b>MOF\u8f6c\u53d8\u6210\u5206\u7ea7\u591a\u5b54MOF<\/b><\/strong><\/p>\n<p>MOF\u6750\u6599\uff0c\u7279\u522b\u662fM(II\/III)\uff08\u4e8c\/\u4e09\u4ef7\u91d1\u5c5e\uff09\u57fa\u7fa7\u9178\u7c7bMOFs\u5728\u6c34\u4e2d\u6781\u5177\u6613\u53d8\u6027\uff0c\u56e0\u6b64\u662f\u4e00\u79cd\u5728\u539f\u6709\u5fae\u5b54\u7ed3\u6784\u57fa\u7840\u4e0a\u653e\u5927\u5b54\u7ed3\u6784\u7684\u53ef\u9760\u7b56\u7565\u3002\u901a\u8fc7\u5408\u6210\u540e\u6c34\u89e3\u4f5c\u7528\uff0c\u91d1\u5c5e-\u7fa7\u9178\u76d0\u914d\u4f4d\u952e\u4f1a\u88ab\u7834\u574f\uff0c\u4ece\u800c\u5411\u6eb6\u6db2\u91ca\u653e\u6709\u673a\u914d\u4f53\u548c\u91d1\u5c5e\u79bb\u5b50\u3002\u6700\u7ec8\uff0c\u53ef\u63a7\u5236\u5fae\u5b54MOFs\u8f6c\u53d8\u5f62\u6210\u5206\u7ea7\u591a\u5b54MOFs\u3002\u7279\u522b\u662f\u901a\u8fc7\u63a7\u5236\u6c34\u89e3\u65f6\u95f4\u548c\u6e29\u5ea6\uff0c\u53ef\u4ee5\u8c03\u63a7\u4ecb\u5b54\u548c\u5fae\u5b54\u6bd4\u4f8b\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-216714 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u72471-11.png\" alt=\"\" width=\"398\" height=\"169\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u72471-11.png 398w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u72471-11-300x127.png 300w\" sizes=\"(max-width: 398px) 100vw, 398px\" \/><\/p>\n<p style=\"text-align: center;\"><strong><b>\u56fe1 \u9487\u57faMOF\u7684\u6c34\u89e3\u540e\u5408\u6210\u8f6c\u53d8<\/b><\/strong><\/p>\n<p>\u4f8b\u5982<strong><b>\u97e9\u56fd\u57fa\u7840\u79d1\u5b66\u7814\u7a76\u9662\u7684Kimoon Kim<\/b><\/strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u65e9\u57282015\u5e74\u5c31\u5236\u5907\u4e86\u4e00\u79cd\u65b0\u578b\u9487\u57faMOF\u2014\u2014POST-66(Y)\uff08\u56fe1\uff09\uff0c\u5e76\u4e14\u7814\u7a76\u4e86\u5176\u5728\u6c34\u5904\u7406\u4e0b\u7684\u5206\u7ea7\u591a\u5b54\u8f6c\u53d8\u884c\u4e3a\u3002\u8fd9\u4e00MOF\u6750\u6599\u5728\u6c34\u91cc\u6d78\u6ca1\u4e0d\u540c\u65f6\u95f4\uff0c\u6700\u957f\u81f324\u5c0f\u65f6\uff0c\u6216\u8005\u5728\u77ed\u65f6\u5185\u63d0\u5347\u4e0d\u540c\u6e29\u5ea6\uff0c\u53ef\u4ee5\u4ea7\u751f\u4e00\u7cfb\u5217\u5206\u7ea7\u591a\u5b54MOF\uff0c\u5728\u4fdd\u6301\u5176\u4e3b\u4f53\u7ed3\u6784\u7684\u540c\u65f6\uff0c\u5b54\u9699\u6709\u5de8\u5927\u7684\u53d8\u5316\u3002\u7531\u6b64\u4ea7\u751f\u7684\u5206\u7ea7\u591a\u5b54MOF\u65e2\u80fd\u7ef4\u6301\u539f\u6709\u7684\u5fae\u5b54\u7ed3\u6784\uff0c\u4e5f\u4f1a\u4ea7\u751f3-20\u7eb3\u7c73\u7684\u4ecb\u5b54\uff0c\u53ef\u6709\u6548\u88c5\u8f7d\u7eb3\u7c73\u7ea7\u5ba2\u4f53\u5982\u86cb\u767d\u8d28\uff0c\u540c\u65f6\u88c5\u8f7d\u7269\u7684\u7a33\u5b9a\u6027\u548c\u518d\u4f7f\u7528\u6027\u5f97\u5230\u4e86\u589e\u5f3a\u3002<\/p>\n<p><strong><b>\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>https:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/anie.201506391<\/p>\n<p><strong><b>MOF<\/b><\/strong><strong><b>\u8f6c\u53d8\u6210\u805a\u5408\u7269\u6750\u6599<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-216715 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u72472-11.png\" alt=\"\" width=\"560\" height=\"341\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u72472-11.png 560w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u72472-11-300x183.png 300w\" sizes=\"(max-width: 560px) 100vw, 560px\" \/><\/p>\n<p style=\"text-align: center;\"><strong><b>\u56fe2 \u7531<\/b><\/strong><strong><b>PLMOFs<\/b><\/strong><strong><b>\u5236\u5907\u6eb6\u80c0\u51dd\u80f6\u7684\u793a\u610f\u56fe<\/b><\/strong><\/p>\n<p>\u914d\u4f4d\u952e\u7684\u6613\u53d8\u6027\u53ef\u8fdb\u4e00\u6b65\u88ab\u7528\u4e8e\u5236\u5907\u805a\u5408\u7269\u3002MOFs\u4e2d\u7684\u6709\u673a\u914d\u4f53\u4ea4\u8054\u53ef\u4ee5\u5bfc\u81f4\u914d\u4f53\u7684\u9884\u7ec4\u7ec7\u884c\u4e3a\uff0c\u968f\u540e\u901a\u8fc7\u6c34\u89e3\u4f5c\u7528\u548c\u91d1\u5c5e\u7c07\u79fb\u9664\u5c31\u6709\u53ef\u80fd\u4e3a\u805a\u5408\u7269\u6750\u6599\u5236\u5907\u63d0\u4f9b\u601d\u8def\u3002\u4f8b\u5982<strong><b>\u5317\u6d77\u9053\u5927\u5b66\u7684Kenta Kokado\u548cKazuki Sada<\/b><\/strong>\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u5c31\u5408\u4f5c\u5728\u67f1\u6491\u5c42\u72b6\uff08pillared-layer\uff09MOF\uff08PLMOFs\uff09\u4e2d\u63a2\u7d22\u4ea4\u8054\u6c34\u89e3\u7b56\u7565\u5236\u5907\u805a\u5408\u7269\u7684\u53ef\u80fd\u6027\u3002\u4f5c\u4e3a\u539f\u59cb\u6750\u6599\uff0c\u53e0\u6c2e\u6807\u8bb0\u7684PLMOFs\u7531\u94dc\u79bb\u5b50\u3001\u4f5c\u4e3a\u5c42\u72b6\u914d\u4f53\u7684\u7fa7\u9178\u548c\u4f5c\u4e3a\u67f1\u6491\u914d\u4f53\u7684N\u6742\u73af\u6210\u5206\u6784\u6210\uff08\u56fe2\uff09\u3002\u4e3a\u4e86\u589e\u5f3aPLMOFs\u7684\u7ed3\u6676\u5ea6\uff0c\u6dfb\u52a0\u4ea4\u8054\u5242CL4\u53ef\u4f7f\u5c42\u72b6\u914d\u4f53\u4e0e\u4ea4\u8054\u5242\u4e4b\u95f4\u53d1\u751f\u4ea4\u8054\u53cd\u5e94\uff0c\u4ece\u800c\u5f97\u5230\u4ea4\u8054PLMOFs\u3002\u4e4b\u540e\u518d\u8fdb\u884c\u6c34\u89e3\u4f5c\u7528\uff0c\u53ef\u4f7fMOF\u6a21\u677f\u4e2d\u7684\u914d\u4f53\u8fdb\u884c\u5404\u5411\u5f02\u6027\u6392\u5217\uff0c\u5bfc\u81f4\u4ea4\u8054\u805a\u5408\u7269\u4ea7\u751f\u5404\u5411\u5f02\u6027\u6eb6\u80c0\u884c\u4e3a\uff0c\u6700\u7ec8\u751f\u6210\u6eb6\u80c0\u51dd\u80f6\u3002<\/p>\n<p><strong><b>\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>https:\/\/www.nature.com\/articles\/ncomms14442<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-216716 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u72473-8.png\" alt=\"\" width=\"453\" height=\"115\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u72473-8.png 453w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u72473-8-300x76.png 300w\" sizes=\"(max-width: 453px) 100vw, 453px\" \/><\/p>\n<p style=\"text-align: center;\"><strong><b>\u56fe3 \u5206\u5b50\u7ec7\u7269\u7684\u5f62\u6210\u793a\u610f\u56fe<\/b><\/strong><\/p>\n<p>\u8fdb\u4e00\u6b65\u5730\uff0c\u901a\u8fc7\u8c03\u8282MOF\u4e2d\u805a\u5408\u7269\u76f8\u7684\u7ec4\u6210\u548c\u5206\u5e03\uff0c\u8fd8\u80fd\u8c03\u63a7\u805a\u5408\u7269\u7684\u6027\u8d28\u548c\u7ed3\u6784\u3002<strong><b>\u5361\u5c14\u65af\u9c81\u5384\u7406\u5de5\u5b66\u9662\u7684<\/b><\/strong><strong><b>Christof W\u00f6ll<\/b><\/strong><strong><b>\u548cMarcel Mayor<\/b><\/strong>\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u901a\u8fc7\u5916\u5ef6\u751f\u957f\u7b56\u7565\u5236\u5907\u4e86\u591a\u5c42MOF\u3002\u7814\u7a76\u4eba\u5458\u5c06quadritopic\u914d\u4f53\u5d4c\u5165\u4f5c\u4e3a\u727a\u7272\u5c42\u7684MOF\u8584\u819c\u4e2d\uff0c\u4ece\u800c\u83b7\u5f97\u591a\u6837\u5f02\u8d28\u5916\u5ef6\u7684\u6676\u4f53\u7cfb\u7edf\u3002\u968f\u540e\uff0cquadritopic\u914d\u4f53\u4e2d\u4e09\u952e\u7684Glaser-Hay\u8026\u5408\u80fd\u591f\u4ea7\u751f\u7ebf\u6027\u3001\u76f8\u4e92\u4ea4\u7ec7\u7684\u805a\u5408\u7269\u94fe\uff08\u56fe3\uff09\u3002X\u5c04\u7ebf\u884d\u5c04\u7814\u7a76\u63ed\u793a\u4e86\u8fd9\u4e00\u5c40\u90e8\u53cd\u5e94\u80fd\u591f\u7ef4\u6301MOF\u9aa8\u67b6\u7684\u5b8c\u6574\u3002\u5728\u79fb\u9664\u91d1\u5c5e\u79bb\u5b50\u540e\uff0c\u805a\u5408\u7269\u7ec7\u7269\u5c42\u5c31\u53ef\u4ee5\u88ab\u8f6c\u79fb\u5230\u57fa\u8d28\u4e0a\u8fdb\u884c\u540e\u7eed\u7814\u7a76\u5206\u6790\u3002\u539f\u5b50\u529b\u663e\u5fae\u5b66\u53d1\u73b0\uff0c\u5149\u662f\u805a\u5408\u7269\u5355\u94fe\u5c31\u53ef\u4ee5\u5f62\u6210\u89c4\u6a21\u53ef\u89c2\u7684\u4e8c\u7ef4\u7ec7\u7269\uff0c\u5176\u957f\u5ea6\u53ef\u8fbe\u5230200\u7eb3\u7c73\u6c34\u5e73\u3002<\/p>\n<p><strong><b>\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/anie.201611338<\/p>\n<p><strong><b>MOF\u8f6c\u53d8\u6210\u975e\u6676MOF\u6db2\u4f53\/\u73bb\u7483<\/b><\/strong><\/p>\n<p>MOFs\u4e0d\u4ec5\u5728\u6c34\u4e2d\u4e0d\u7a33\u5b9a\uff0c\u4e00\u5b9a\u7684\u9ad8\u6e29\u52a0\u70ed\u4e5f\u4f1a\u653e\u5927MOFs\u7684\u6613\u53d8\u6027\u3002\u56e0\u6b64\uff0c\u52a0\u70ed\u53ef\u4ee5\u8bf1\u5bfc\u6676\u4f53MOF\u60f3\u5411\u975e\u6676\u6001\u8f6c\u53d8\uff0c\u4ece\u800c\u4ea7\u751fMOF\u51dd\u80f6\u6216\u8005MOF\u73bb\u7483\u7b49\u975e\u6676\u6750\u6599\u3002<strong><b>\u5df4\u9ece\u6587\u7406\u7814\u7a76\u5927\u5b66\u7684<\/b><\/strong><strong><b>Fran\u00e7ois-Xavier Coudert<\/b><\/strong><strong><b>\u548c\u5251\u6865\u5927\u5b66\u7684<\/b><\/strong><strong><b>Thomas D. Bennett<\/b><\/strong>\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u5c31\u4ecb\u7ecd\u4e86\u4e00\u79cd\u5f3a\u5173\u8054\u7684MOF\u6db2\u4f53\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-216717 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u72474-8.png\" alt=\"\" width=\"599\" height=\"331\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u72474-8.png 599w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u72474-8-300x166.png 300w\" sizes=\"(max-width: 599px) 100vw, 599px\" \/><\/p>\n<p style=\"text-align: center;\"><strong><b>\u56fe4 ZIF-4\u6676\u4f53\u3001\u73bb\u7483\u7684\u7ed3\u6784\u53ca\u5176\u5728\u52a0\u70ed\u6761\u4ef6\u4e0b\u7684\u7ed3\u6784\u6f14\u53d8<\/b><\/strong><\/p>\n<p>\u4e00\u822c\u7684MOF\u7cfb\u7edf\u56e0\u4e3a\u6709\u673a\u6a21\u5757\u7684\u5206\u89e3\u800c\u65e0\u6cd5\u89c2\u5bdf\u5230\u5176\u771f\u6b63\u7684\u7194\u878d\u884c\u4e3a\uff0c\u800cBennett\u7b49\u4eba\u5374\u62a5\u9053\u4e86\u5728\u67d0\u4e9b\u7279\u5b9a\u7684MOF\u4e2d\u53ef\u4ee5\u89c2\u5bdf\u5230\u7194\u878d\u3002\u4ed6\u4eec\u7279\u522b\u7814\u7a76ZIF-4\u8fd9\u4e00\u7c7bMOF\uff0cZIF-4\u542b\u6709\u950c-\u6c2e\u914d\u4f4d\u952e\uff0c\u7194\u70b9\u4e3a865K\u3002\u5728ZIF-4\u7684\u5236\u5907\u8fc7\u7a0b\u4e2d\uff0c\u7814\u7a76\u4eba\u5458\u5728\u81ea\u7136\u51b7\u5374\u5230\u5ba4\u6e29\u524d\u53c8\u5c06\u6750\u6599\u52a0\u70ed\u5230865K\uff0c\u53d1\u73b0\u7194\u878d\u7684MOF\u53d1\u751f\u4ece\u56fa\u5230\u6db2\u7684\u76f8\u8f6c\u53d8\u8fc7\u7a0b\uff08\u56fe4\uff09\u3002\u5b9e\u9a8c\u548c\u7406\u8bba\u7814\u7a76\u8868\u660e\uff0c\u8fd9\u4e00\u73b0\u8c61\u4e0eMOF\u7684\u7194\u878d\u6e29\u5ea6\u548c\u914d\u4f53\u5206\u89e3\u6e29\u5ea6\u4e4b\u95f4\u7684\u590d\u6742\u5e73\u8861\u606f\u606f\u76f8\u5173\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u4e0e\u73bb\u7483\u6001\u76f8\u6bd4\uff0c\u6db2\u6001MOF\u53ef\u4ee5\u4fdd\u7559\u5316\u5b66\u6784\u8c61\u548c\u914d\u4f4d\u952e\u6a21\u5f0f\uff0c\u5b54\u9699\u7ed3\u6784\u5f97\u5230\u4fdd\u7559\u7684\u540c\u65f6\u5176\u5b54\u5bb9\u4e5f\u6bd4\u73bb\u7483\u6001\u5927\uff0c\u662f\u4e00\u79cd\u5c11\u89c1\u7684\u591a\u5b54\u6db2\u4f53\u3002<\/p>\n<p><strong><b>\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>https:\/\/www.nature.com\/articles\/nmat4998<\/p>\n<p><strong><b>MOF\u8f6c\u53d8\u6210\u91d1\u5c5e\/\u91d1\u5c5e\u6c27\u5316\u7269\u7eb3\u7c73\u9897\u7c92<\/b><\/strong><\/p>\n<p>\u76f8\u6bd4\u4e8e\u52a0\u70ed\u7194\u878d\uff0c\u6761\u4ef6\u66f4\u52a0\u82db\u523b\u7684\u70ed\u89e3\u4f5c\u7528\u80fd\u591f\u5b8c\u5168\u5206\u89e3MOF\uff0c\u800c\u7ecf\u8fc7\u8fd9\u4e00\u8fc7\u7a0b\u6b8b\u7559\u4e0b\u7684\u975e\u6325\u53d1\u6027\u91d1\u5c5e\u5219\u53ef\u4ee5\u5f62\u6210\u91d1\u5c5e\u6c27\u5316\u7269\u79cd\u3002\u4f5c\u4e3a\u70ed\u89e3\u4ea7\u7269\uff0c\u8fd9\u4e9b\u91d1\u5c5e\u6c27\u5316\u7269\u79cd\u7531\u4e8e\u5931\u53bb\u4e86\u78b3\u9aa8\u67b6\u800c\u503e\u5411\u4e8e\u5f62\u6210\u4ecb\u5b54\u6216\u5fae\u5b54\u5b54\u9699\uff0c\uff0c\u8fdb\u800c\u53ef\u4ee5\u751f\u6210\u591a\u5b54\u91d1\u5c5e\u6216\u8005\u91d1\u5c5e\u6c27\u5316\u7269\u9897\u7c92\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-216718 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u72475-8.png\" alt=\"\" width=\"600\" height=\"475\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u72475-8.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u72475-8-300x238.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong><b>\u56fe5 \u6fc0\u5149\u8bf1\u5bfc\u91d1\u5c5e\u7c07\u6210\u5f62<\/b><\/strong><\/p>\n<p><strong><b>\u6b66\u6c49\u5927\u5b66\u7684Haoqing Jiang\u548cGary J. Cheng<\/b><\/strong>\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u56e2\u961f\u4ee5MOF\u6750\u6599\u4e3a\u524d\u9a71\u4f53\uff0c\u5229\u7528\u89c4\u6a21\u5316\u6fc0\u5149\u5408\u6210\u65b9\u6cd5\u5236\u5907\u7eb3\u7c73\u6750\u6599\u3002\u5982\u56fe5\u6240\u793a\uff0c\u901a\u8fc7\u5bf9\u94c8\u57faMOF\uff08Ce-MOFs\uff09\u4e2d\u88c5\u8f7d\u7684\u76f8\u5e94\u91d1\u5c5e\u79bb\u5b50\u8fdb\u884c\u76f4\u63a5\u6fc0\u5149\u8f6c\u6362\uff0c\u7c92\u5f84\u5c0f\u4e8e5\u7eb3\u7c73\u7684\u5bc6\u5806\u7f3a\u9677\u7684\u6c27\u5316\u94c8\u7eb3\u7c73\u9897\u7c92\u53ef\u4ee5\u4f5c\u4e3a\u652f\u6491\u7269\u901a\u8fc7\u5f3a\u5076\u8054\u4f5c\u7528\u7a33\u5b9a\u5c0f\u4e8e2\u7eb3\u7c73\u7684\u94c2\u3001\u91d1\u3001\u94d1\u4ee5\u53ca\u948c\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u3002\u7814\u7a76\u663e\u793a\uff0cCe-MOFs\u53ef\u4ee5\u4f5c\u4e3a\u7406\u60f3\u7684\u5206\u6563\u524d\u9a71\u4f53\uff0c\u53ef\u4ee5\u5229\u7528\u6709\u5e8f\u6392\u5217\u7684\u5b54\u7ed3\u6784\u5747\u4e00\u88c5\u8f7d\u8d35\u91d1\u5c5e\u79bb\u5b50\u3002\u8d85\u5feb\u6fc0\u5149\u6c7d\u5316\u548c\u51b7\u5374\u80fd\u591f\u5f62\u6210\u5747\u4e00\u3001\u8d85\u7ec6\u3001\u6df7\u5408\u5747\u5300\u548c\u5bc6\u96c6\u7684\u91d1\u5c5e\/\u91d1\u5c5e\u6c27\u5316\u7269\u7eb3\u7c73\u9897\u7c92\u3002\u6fc0\u5149\u8bf1\u5bfc\u8d85\u5feb\u53cd\u5e94\u80fd\u591f\u5bfc\u81f4\u6c27\u5316\u94c8\u7eb3\u7c73\u9897\u7c92\u7684\u6c89\u79ef\uff0c\u5e76\u4ea7\u751f\u4e30\u5bcc\u7684\u8868\u9762\u7f3a\u9677\u3002\u7279\u522b\u662f\u5bf9\u4e8e\u6df7\u5408\u5747\u5300\u7684\u94c2\u548c\u6c27\u5316\u94c8\u6210\u5206\uff0c\u8fd9\u4e00\u50ac\u5316\u5242\u5728\u4e00\u6c27\u5316\u78b3\u6c27\u5316\u65b9\u9762\u5c55\u73b0\u51fa\u4e86\u4ece\u4f4e\u6e29\u5230\u9ad8\u6e29\u7684\u9ad8\u7a33\u5b9a\u6027\u548c\u6d3b\u6027\u3002<\/p>\n<p><strong><b>\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>https:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/smll.202000749<\/p>\n<p><strong><b>MOF<\/b><\/strong><strong><b>\u8f6c\u53d8\u6210\u78b3\u6750\u6599<\/b><\/strong><\/p>\n<p>\u9664\u4e86\u53ef\u4ee5\u5408\u6210\u91d1\u5c5e\/\u91d1\u5c5e\u6c27\u5316\u7269\u7eb3\u7c73\u9897\u7c92\u4ee5\u5916\uff0c\u5728\u975e\u6c27\u5316\u6761\u4ef6\u4e0b\u7684MOF\u70ed\u89e3\u8fd8\u80fd\u5bfc\u81f4\u5269\u4f59\u914d\u4f53\u9aa8\u67b6\u4f5c\u4e3a\u78b3\u7ed3\u6784\u3002\u8fd9\u4e00\u78b3\u9aa8\u67b6\u7ed3\u6784\u5728\u67d0\u4e9b\u5e94\u7528\u91cc\uff0c\u51ed\u501f\u78b3\u652f\u67b6\u77f3\u58a8\u76f8\u7684\u9ad8\u5bfc\u7535\u6027\u800c\u53ef\u4ee5\u4f5c\u4e3a\u7535\u6c60\u7535\u6781\u3002\u7136\u800c\uff0cMOF\u884d\u751f\u7684\u65b0\u578b\u78b3\u6750\u6599\u5728\u78b3\u5316\u8fc7\u7a0b\u4e2d\u5e38\u5e38\u65e0\u6cd5\u907f\u514d\u5411\u5185\u6536\u7f29\u73b0\u8c61\uff0c\u4e25\u91cd\u9650\u5236\u4e86\u8fd9\u7c7b\u6750\u6599\u7684\u5e94\u7528\u62d3\u5c55\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-216719 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u72476-7.png\" alt=\"\" width=\"554\" height=\"256\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u72476-7.png 554w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u72476-7-300x139.png 300w\" sizes=\"(max-width: 554px) 100vw, 554px\" \/><\/p>\n<p style=\"text-align: center;\"><strong><b>\u56fe6 <\/b><\/strong><strong><b>HMCNCs<\/b><\/strong><strong><b>\u7684\u5236\u5907\u793a\u610f\u56fe<\/b><\/strong><\/p>\n<p><strong><b>\u5357\u4eac\u7406\u5de5\u5927\u5b66\u7684\u674e\u5065\u751f\u3001\u738b\u8fde\u519b\u548c\u6606\u58eb\u5170\u5927\u5b66\u7684\u4f59\u627f\u5fe0<\/b><\/strong>\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u5f00\u53d1\u4e86\u4e00\u79cd\u786c\u754c\u9762\u8bf1\u5bfc\u5411\u5916\u6536\u7f29\u7b56\u7565\uff0c\u53ef\u4ee5\u5229\u7528ZIF-8\u7eb3\u7c73\u7acb\u65b9\u4f5c\u4e3a\u524d\u9a71\u4f53\u5408\u6210\u7a7a\u5fc3\u4ecb\u5b54\u78b3\u7eb3\u7c73\u7ba1\uff08HMCNCs\uff09\uff08\u56fe6\uff09\u3002\u8be5HMCNCs\u5448\u73b0\u51fa\u7acb\u65b9\u5f62\u8c8c\uff0c\u5176\u7c92\u5f84\u5219\u6bd4ZIF-8\u7eb3\u7c73\u7acb\u65b9\u7a0d\u5927\u3002\u7531\u4e8e\u72ec\u7279\u7684\u5411\u5916\u6536\u7f29\u8fc7\u7a0b\uff0c\u5747\u4e00\u78b3\u7eb3\u7c73\u7acb\u65b9\u5177\u6709\u7a7a\u8154\u3001\u5fae\u5b54\u5916\u58f3\u4ee5\u53ca\u5185\u90e8\u4ecb\u5b54\u58c1\u7ed3\u6784\u3002\u5176\u4e2d\uff0c\u5b54\u5c3a\u5bf8\u53ef\u8fbe\u523025\u7eb3\u7c73\uff0c\u8868\u9762\u79ef\u548c\u5b54\u9699\u5219\u5206\u522b\u53ef\u9ad8\u8fbe1085.7 m<sup>2<\/sup>\u00a0g<sup>\u22121<\/sup>\u548c3.77cm<sup>3<\/sup>\u00a0g<sup>\u22121<\/sup>\uff0c\u540c\u65f6\u542b\u6c2e\u91cf\u4e3a12.2%\u3002\u5f53\u4f5c\u4e3a\u9502-\u786b\u5316\u7852\u7535\u6c60\u7684\u8d1f\u6781\u6750\u6599\u4f7f\u7528\u65f6\uff0c100\u6b21\u5faa\u73af\u540eHMCNCs\u57280.2 A g<sup>\u22121<\/sup>\u548c5.0 A g<sup>\u22121<\/sup>\u5904\u8fd8\u53ef\u4ee5\u5206\u522b\u5c55\u73b0812.6 mA h g<sup>\u22121<\/sup>\u7684\u7a33\u5b9a\u5bb9\u91cf\u548c455.1 mA h g<sup>\u22121<\/sup>\u7684\u4f18\u5f02\u500d\u7387\u6027\u80fd\u3002<\/p>\n<p><strong><b>\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>https:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/adfm.201705253<\/p>\n<p><strong><b>MOF\u8f6c\u53d8\u6210\u5355\u5c42MOF\u7eb3\u7c73\u7247<\/b><\/strong><\/p>\n<p>MOF\u7684\u6613\u53d8\u6027\u4e5f\u53ef\u4ee5\u4f7f\u5236\u5907MOF\u7eb3\u7c73\u7247\u6210\u4e3a\u53ef\u80fd\u3002\u6bd4\u5982\uff0c\u5229\u7528\u5316\u5b66\u6216\u8005\u673a\u68b0\u5265\u79bb\u53ef\u4ee5\u4ece3D MOFs\u4e2d\u5206\u79bb\u51fa2D MOFs\u3002\u7279\u522b\u662f\u7b80\u5355\u7684\u673a\u68b0\u5265\u79bb\u624b\u6bb5\uff0c\u4e00\u822c\u53ef\u5229\u7528\u5c42\u72b6MOFs\u4e2d\u8f83\u5f31\u7684\u8303\u5fb7\u74e6\u5c14\u65af\u4f5c\u7528\uff1b\u800c\u901a\u8fc7\u91d1\u5c5e-\u914d\u4f53\u914d\u4f4d\u952e\u7684\u673a\u68b0\u7834\u574f\u6765\u5236\u5907MOF\u7eb3\u7c73\u7247\u4e5f\u662f\u4e00\u79cd\u65b0\u5174\u7684\u624b\u6bb5\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-216720 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u72477-6.png\" alt=\"\" width=\"454\" height=\"233\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u72477-6.png 454w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u72477-6-300x154.png 300w\" sizes=\"(max-width: 454px) 100vw, 454px\" \/><\/p>\n<p style=\"text-align: center;\"><strong><b>\u56fe7 MOF\u7eb3\u7c73\u7247\u7684\u5236\u5907\u793a\u610f\u56fe<\/b><\/strong><\/p>\n<p>\u4f8b\u5982<strong><b>\u5251\u6865\u5927\u5b66\u7684<\/b><\/strong><strong><b>Clare P. Grey<\/b><\/strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09\u8bfe\u9898\u7ec4\u5c31\u62a5\u9053\u4e86\u4e00\u79cd3D MOFs\u2014\u2014<strong><b>hcp<\/b><\/strong>\u00a0UiO-67(Hf)\uff0c\u53ef\u4ee5\u5728\u7532\u9187\u4e2d\u4f5c\u4e3a\u524d\u9a71\u4f53\u901a\u8fc7\u7814\u78e8\u6216\u8005\u8d85\u58f0\u7b49\u673a\u68b0\u624b\u6bb5\u5236\u5907\u7eb3\u7c73\u7247\uff08\u56fe7\uff09\u3002\u7531\u4e8e\u51dd\u805a\u201c\u53cc\u7c07\u201d\uff08Hf<sub>12<\/sub>O<sub>8<\/sub>(OH)<sub>14<\/sub>\uff09\u6210\u5f62\u673a\u5236\uff08\u7c7b\u4f3c\u4e8e\u5728\u6c27\u5316\u7269\u6846\u67b6\u4e2d\u7f29\u805a\u914d\u4f4d\u591a\u9762\u4f53\uff09\uff0c\u8be5MOF\u5177\u6709\u8f83\u4f4e\u7684\u914d\u4f53\uff1a\u91d1\u5c5e\u6bd4\u4f8b\uff0c\u662f\u4e00\u79cd\u914d\u4f53\u7f3a\u4e4f\u7684\u5c42\u72b6\u6750\u6599\u3002\u5c42\u72b6<strong><b>hcp<\/b><\/strong>\u00a0UiO-67\u80fd\u591f\u53cd\u5e94\u8fdb\u4e00\u6b65\u53ef\u9006\u5f62\u6210\u4e8c\u7ef4MOFs\u2014\u2014<strong><b>hxl<\/b><\/strong>\u00a0UiO-67\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u4e09\u7ef4<strong><b>hcp<\/b><\/strong>\u00a0UiO-6\u548c\u4e8c\u7ef4<strong><b>hxl<\/b><\/strong>\u00a0UiO-67\u5728\u8d85\u58f0\u6216\u8005\u7814\u78e8\u4f5c\u7528\u4e0b\uff0c\u4ed6\u4eec\u7684\u94ea-\u7fa7\u9178\u76d0\u952e\u53ef\u4ee5\u88ab\u7834\u574f\uff0c\u4ece\u800c\u8fdb\u4e00\u6b65\u5265\u79bb\u5f62\u6210MOF\u7eb3\u7c73\u7247\u3002<\/p>\n<p><strong><b>\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.7b00106<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-216721 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u72478-5.png\" alt=\"\" width=\"600\" height=\"416\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u72478-5.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u72478-5-300x208.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong><b>\u56fe8 \u5206\u5b50\u7b5b\u7eb3\u7c73\u7247\u7684\u201c\u81ea\u4e0a\u800c\u4e0b\u201d\u5236\u5907\u65b9\u6cd5<\/b><\/strong><\/p>\n<p>\u9664\u6b64\u4e4b\u5916\uff0c<strong><b>\u4e2d\u79d1\u9662\u5927\u8fde\u5316\u7269\u6240\u7684\u6768\u7ef4\u614e\u548cYanshuo Li<\/b><\/strong>\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u4ece\u5206\u5b50\u7b5b\u8584\u819c\u9886\u57df\u51fa\u53d1\uff0c\u63a2\u7d22\u4e86MOF\u7eb3\u7c73\u7247\u65e0\u635f\u5265\u79bb\u7684\u7814\u7a76\u3002\u5982\u56fe8\u6240\u793a\uff0c\u4f5c\u8005\u6210\u529f\u5730\u4ece\u5c42\u72b6MOFs\u4e2d\u5408\u6210\u4e86\u8d85\u8584\u7eb3\u7c73\u7247\uff0c\u5176\u539a\u5ea6\u867d\u7136\u53ea\u67091\u7eb3\u7c73\u5de6\u53f3\uff0c\u4f46\u6a2a\u5411\u9762\u79ef\u548c\u7ed3\u6676\u5ea6\u90fd\u975e\u5e38\u53ef\u89c2\u3002\u7814\u7a76\u4eba\u5458\u7528\u5230\u7684\u5c42\u72b6MOF\u524d\u9a71\u4f53\u4e3aZn<sub>2<\/sub>(bim)<sub>4<\/sub>\uff0c\u5176\u4e8c\u7ef4\u5c42\u5177\u6709<strong><em><b><i>c<\/i><\/b><\/em><\/strong>\u8f74\u53d6\u5411\uff0c\u5e76\u4e14\u7531\u8303\u5fb7\u74e6\u5c14\u65af\u4f5c\u7528\u76f8\u4e92\u8fde\u63a5\u3002\u9488\u5bf9\u8fd9\u4e00\u6750\u6599\uff0c\u7814\u7a76\u5f00\u53d1\u4e86\u4e00\u79cd\u8f6f\u7269\u7406\u5265\u79bb\u8fc7\u7a0b\uff1a\u5148\u5bf9Zn<sub>2<\/sub>(bim)<sub>4<\/sub>\u8fdb\u884c\u6e7f\u7403\u78e8\u5904\u7406\uff0c\u518d\u5728\u6325\u53d1\u6027\u6eb6\u5242\u4e2d\u8fdb\u884c\u8d85\u58f0\u5265\u79bb\u3002\u7531\u6b64\u5236\u5f97\u7684\u7eb3\u7c73\u7247\u53ef\u4f5c\u4e3a\u8d85\u8584\u5206\u5b50\u7b5b\u7684\u6784\u5efa\u5355\u5143\uff0c\uff0c\u901a\u8fc7\u6291\u5236\u7eb3\u7c73\u7247\u4e4b\u95f4\u7684\u5c42\u72b6\u5806\u79ef\uff0c\u66f4\u662f\u53ef\u4ee5\u5b9e\u73b0\u9ad8\u8fbe\u51e0\u5343\u4e2aGPU\u7684\u6c22\u6c14\u6e17\u900f\u6027\u80fd\uff0c\u540c\u65f6\u63d0\u5347\u6c22\u6c14\/\u4e8c\u6c27\u5316\u78b3\u9009\u62e9\u6027\u8d85\u8fc7200\u3002<\/p>\n<p><strong><b>\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>https:\/\/science.sciencemag.org\/lookup\/doi\/10.1126\/science.1254227<\/p>\n<p>\u672c\u6587\u7531NanoCJ\u4f9b\u7a3f\u3002<\/p>\n<p>\u672c\u5185\u5bb9\u4e3a\u4f5c\u8005\u72ec\u7acb\u89c2\u70b9\uff0c\u4e0d\u4ee3\u8868\u6750\u6599\u4eba\u7f51\u7acb\u573a\u3002<\/p>\n<p>\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u5f15\u8a00 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