{"id":216786,"date":"2021-01-27T11:30:01","date_gmt":"2021-01-27T03:30:01","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=216786"},"modified":"2021-01-27T09:53:19","modified_gmt":"2021-01-27T01:53:19","slug":"%e6%97%a0%e9%94%82%e8%b4%9f%e6%9e%81%e7%94%b5%e6%b1%a0%e7%a0%94%e7%a9%b6%e6%88%90%e6%9e%9c%e5%a4%a7%e6%a2%b3%e7%90%86","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=216786","title":{"rendered":"\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u7814\u7a76\u6210\u679c\u5927\u68b3\u7406"},"content":{"rendered":"<p><strong><b>\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/b><\/strong><\/p>\n<p>\u7531\u4e8e\u50a8\u80fd\u7cfb\u7edf\u5bf9\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u9502\u7535\u6c60\u7684\u9700\u6c42\u8fc5\u901f\u589e\u957f\uff0c\u5e76\u4e14\u5168\u7403\u9502\u50a8\u5907\u4e0d\u8db3\uff0c\u6709\u9650\u7684\u9502\uff08\u4f8b\u5982\u539a\u5ea6\u4e3a20\u03bcm\u6216\u66f4\u8584\uff09\u4f5c\u4e3a\u9633\u6781\u7684\u88c5\u7f6e\u4e3a\u9ad8\u5b89\u5168\u6027\u548c\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u9502\u91d1\u5c5e\u7535\u6c60\u7684\u5e7f\u6cdb\u5e94\u7528\u63d0\u4f9b\u4e00\u6761\u6377\u5f84\u3002\u8584\u8584\u7684\u9502\u7b94\u7684\u9ad8\u6210\u672c\u4e0e\u5927\u91cf\u8fc7\u91cf\u9502\u5e26\u6765\u7684\u4e25\u91cd\u5b89\u5168\u9690\u60a3\u4e4b\u95f4\u7684\u77db\u76fe\uff0c\u6fc0\u53d1\u4e86\u4f7f\u7528\u96f6\u8fc7\u91cf\u9502\u8d1f\u6781\u7684\u9502\u91d1\u5c5e\u7535\u6c60\uff08\u4e5f\u79f0\u4e3a\u65e0\u9502\u8d1f\u6781\u7535\u6c60\uff09\u7684\u53d1\u5c55\u3002\u5728\u8fd9\u7bc7\u6587\u7ae0\u4e2d\uff0c\u65e8\u5728\u91cd\u70b9\u4ecb\u7ecd\u5168\u9762\u8bc4\u4f30\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u7684\u4e3b\u8981\u8fdb\u5c55\u548c\u4ecd\u7136\u5b58\u5728\u7684\u969c\u788d\uff0c\u4ee5\u53ca\u5bf9\u6700\u65b0\u7684\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u8bbe\u8ba1\u7684\u7b56\u7565\u8fdb\u884c\u4e86\u8ba8\u8bba\u3002<\/p>\n<p><strong><b>\u3010\u56fe\u6587\u89e3\u6790\u3011<\/b><\/strong><\/p>\n<p><strong><b>1\u3001\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u7684\u4ecb\u7ecd<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-216802 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-27-1.png\" alt=\"\" width=\"600\" height=\"383\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-27-1.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-27-1-300x192.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe1. \u9502\u79bb\u5b50\u7535\u6c60\u4e0e\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u5bf9\u6bd4<\/p>\n<p style=\"text-align: center;\">\u203b<a href=\"https:\/\/doi.org\/10.1002\/aenm.202000804\"><em><u><i>Adv. Energy Mater. (2020<\/i><\/u><\/em><em><u><i>)<\/i><\/u><\/em><em><u><i>\u00a02000804<\/i><\/u><\/em><\/a><\/p>\n<p>\u5728\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u4e2d\uff0c\u6240\u6709\u6d3b\u6027\u9502\u79bb\u5b50\u6700\u521d\u90fd\u5b58\u50a8\u5728\u9634\u6781\u6750\u6599\u4e2d\uff0c\u5728\u521d\u59cb\u5145\u7535\u8fc7\u7a0b\u4e2d\uff0c\u9502\u79bb\u5b50\u4ece\u9634\u6781\u63d0\u53d6\uff0c\u79fb\u81f3\u9633\u6781\uff0c\u5e76\u76f4\u63a5\u539f\u4f4d\u7535\u9540\u5728\u88f8\u96c6\u6d41\u4f53\u4e0a\u3002\u968f\u540e\uff0c\u5728\u653e\u7535\u8fc7\u7a0b\u4e2d\uff0c\u5c06\u6d3b\u6027\u9502\u79bb\u5b50\u4ece\u539f\u4f4d\u5f62\u6210\u7684\u9502\u9633\u6781\u4e0a\u5265\u79bb\uff0c\u5e76\u5d4c\u5165\u5230\u9634\u6781\u4e2d\u3002\u7531\u4e8e\u6ca1\u6709\u60f0\u6027\u4e3b\u4f53\u548c\u91d1\u5c5e\u9502\u9633\u6781\uff0c\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u7684\u4f53\u79ef\u53ef\u4ee5\u6700\u5c0f\u5316\uff0c\u5e76\u5177\u6709\u6700\u5927\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002\u4f8b\u5982\uff0c\u901a\u8fc7\u7528\u8fc7\u91cf20\uff05\u7684\u9502\u91d1\u5c5e\u9633\u6781\u4ee3\u66ff\u77f3\u58a8\u9633\u6781\uff0c\u53d1\u73b0\u6bd4\u80fd\uff08Wh kg<sup>-1<\/sup>\uff09\u548c\u80fd\u91cf\u5bc6\u5ea6\uff08Wh L<sup>-1<\/sup>\uff09\u5206\u522b\u63d0\u9ad8\u4e86\u7ea635\uff05\u548c50\uff05\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u5728\u76f8\u540c\u7684\u7535\u6c60\u53c2\u6570\u4e0b\uff0c\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u4f34\u968f\u66f4\u9ad8\u7684\u5de5\u4f5c\u7535\u538b\uff080.1 V\uff09\uff0c\u6bd4\u80fd\u91cf\u548c\u80fd\u91cf\u5bc6\u5ea6\u5206\u522b\u589e\u52a0\u4e86\u7ea645\uff05\u548c60\uff05\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u4e0d\u4ec5\u4e0e\u5f53\u524d\u4f7f\u7528\u7684\u9502\u79bb\u5b50\u7535\u6c60\u5236\u9020\u57fa\u7840\u8bbe\u65bd\u826f\u597d\u517c\u5bb9\uff0c\u800c\u4e14\u8fd8\u8282\u7701\u4e86\u4e0e\u77f3\u58a8\u8d1f\u6781\u751f\u4ea7\u76f8\u5173\u7684\u6210\u672c\uff0c\u907f\u514d\u4f7f\u7528\u6602\u8d35\u7684N-\u7532\u57fa-2-\u5421\u54af\u70f7\u916e\uff08NMP\uff09\u6eb6\u5242\u5e76\u7b80\u5316\u4e86\u7535\u6781\u6d46\u6599\u6d82\u5e03\u5236\u5907\u7684\u65b9\u6cd5\u3002<\/p>\n<p><strong><b>2\u3001\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u5b58\u5728\u7684\u95ee\u9898<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-216794 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-11-10.png\" alt=\"\" width=\"600\" height=\"262\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-11-10.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-11-10-300x131.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe2. \u65e0\u9502\u8d1f\u6781\u7535\u6c60\u5b58\u5728\u7684\u95ee\u9898<\/p>\n<p style=\"text-align: center;\">\u203b<a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.chemrev.7b00115\"><em><u><i>Chem. Rev. 117 (2017) 10403\u201310473<\/i><\/u><\/em><\/a><\/p>\n<p>\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u867d\u7136\u6709\u7740\u8f83\u591a\u7684\u6709\u70b9\u5982\uff1a\u4f53\u79ef\u80fd\u91cf\u5bc6\u5ea6\u53ef\u63d0\u9ad885.5%\uff08\u8003\u8651\u4f53\u79ef\u81a8\u80c0\uff1a57.1%\uff09\uff0c\u65e0\u9700\u8003\u8651\u6b63\u8d1f\u6781\u5bb9\u91cf\u5339\u914d\u95ee\u9898\uff08N\/P=1\uff09\uff0c\u5236\u5907\u5de5\u827a\u7b80\u5355\u7b49\u3002\u4f46\u662f\u5176\u4e5f\u5b58\u5728\u8bf8\u591a\u7684\u6311\u6218\uff0c\u5982\uff1a<\/p>\n<p>\u4e0d\u5747\u5300\u7684\u9502\u6c89\u79ef\u4f1a\u52a0\u901f\u9502\u679d\u6676\u7684\u751f\u957f\uff0c\u964d\u4f4e\u6c89\u79ef\u7684\u9502\u7684\u5229\u7528\u7387\uff0c\u5e76\u6700\u7ec8\u964d\u4f4e\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\uff1bSEI\u7684\u91cd\u590d\u5f62\u6210\u4e0d\u7a33\u5b9a\u6027\u4f1a\u52a0\u901f\u7535\u89e3\u6db2\u7684\u6d88\u8017\u5e76\u9650\u5236\u9502\u7684\u542b\u91cf\uff0c\u8fc5\u901f\u964d\u4f4e\u4e86\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u7684\u5e93\u4ed1\u6548\u7387\u548c\u5bb9\u91cf\u4fdd\u6301\u7387\uff1b\u9502\u679d\u6676\u7684\u751f\u957f\u4f1a\u5bfc\u81f4\u6b7b\u9502\u7684\u751f\u6210\uff0c\u4f7f\u5f97\u7535\u6c60\u53d1\u751f\u8f83\u5927\u7684\u4f53\u79ef\u81a8\u80c0\u3002<\/p>\n<p><strong><b>3\u3001\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u7814\u53d1\u4e3b\u8981\u7b56\u7565<\/b><\/strong><\/p>\n<p>3.1 \u7535\u89e3\u6db2\u8bbe\u8ba1<\/p>\n<p>\u8bb8\u591a\u5148\u524d\u7684\u7814\u7a76\u8868\u660e\uff0c\u96c6\u6d41\u4f53\u4e0a\u6c89\u79ef\u9502\u7684\u5f62\u6001\u53d7\u9502\u76d0\u548c\u6eb6\u5242\u7684\u5f71\u54cd\u3002<strong><b>\u6eb6\u5242\u5316\u7684\u5f3a\u5ea6\uff0c\u76d0\u7684\u79bb\u89e3\u5ea6\u4ee5\u53ca\u9634\u79bb\u5b50\u548c\u6eb6\u5242\u7684\u9634\u6781\u7a33\u5b9a\u6027\u90fd<\/b><\/strong><strong><b>\u51b3\u5b9a\u7740<\/b><\/strong><strong><b>\u6700\u7ec8SEI\u7684\u8d28\u91cf\u3002<\/b><\/strong>\u56e0\u6b64\uff0c\u4f18\u5316\u7535\u89e3\u6db2\u662f\u5b9e\u73b0\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u6210\u529f\u7684\u81f3\u5173\u91cd\u8981\u4e14\u6709\u6548\u7684\u65b9\u6cd5\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-216787 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-2-21.png\" alt=\"\" width=\"600\" height=\"277\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-2-21.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-2-21-300x139.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe3.\u00a0\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u4e2d\u5e38\u7528\u6eb6\u5242\u548c\u9502\u76d0\u7684\u4f7f\u7528\u9891\u7387<\/p>\n<p style=\"text-align: center;\">\u203b<a href=\"https:\/\/doi.org\/10.1016\/j.nanoen.2020.105344\"><em><u><i>Nano Energy 78 (2020) 105344<\/i><\/u><\/em><\/a><\/p>\n<p>3.1.1 \u5355\u76d0&amp;\u53cc\u76d0\u7535\u89e3\u6db2<\/p>\n<p>2019\u5e74<strong><b>\u52a0\u62ff\u5927\u8fbe\u5c14\u8c6a\u65af\u5927\u5b66<\/b><\/strong><strong><b>J. R. Dahn\u6559\u6388<\/b><\/strong>\u5c55\u793a\u4e86\u4e00\u79cd\u5b9e\u7528\u7684<strong><b>\u53cc\u76d0\uff08<\/b><\/strong><strong><b>0.6 M LiDFOB\/0.6 M LiBF<\/b><\/strong><strong><sub><b>4<\/b><\/sub><\/strong><strong><b>\uff09\u78b3\u9178\u76d0\u57fa\u7535\u89e3\u8d28<\/b><\/strong>\u7684\u957f\u5bff\u547d\u65e0\u8d1f\u6781\u7535\u6c60\uff0c90\u6b21\u5faa\u73af\u540e\u62e5\u670980%\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\u3002\u4e0e\u5355\u76d0\u7535\u89e3\u8d28\u7ec4\u5408\u7269\u76f8\u6bd4\uff0c\u53cc\u76d0\u5171\u6df7\u7269\u5728\u53d8\u5316\u7684\u7535\u6c60\u7535\u538b\u4e0b\u8868\u73b0\u66f4\u597d\uff0c\u5e76\u4e14\u8f83\u5c11\u4f9d\u8d56\u4e8e\u5916\u90e8\u538b\u529b\u6765\u83b7\u5f97\u826f\u597d\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-216788 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-3-21.png\" alt=\"\" width=\"600\" height=\"444\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-3-21.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-3-21-300x222.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe4. \u5355\u76d0\u548c\u53cc\u76d0\u7535\u89e3\u8d28\u5728\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u7684\u7535\u5316\u5b66\u884c\u4e3a<\/p>\n<p style=\"text-align: center;\">\u203b<a href=\"https:\/\/www.nature.com\/articles\/s41560-019-0428-9\"><em><u><i>Nat. Energy 4 (2019) 683\u2013689<\/i><\/u><\/em><\/a><\/p>\n<p>2020\u5e74\uff0c<strong><b>J. R. Dahn\u6559\u6388<\/b><\/strong>\u540c\u6837\u4f7f\u7528\u8fd9\u79cd<strong><b>\u8d2b\u6db2\u6001\u7535\u89e3\u6db2\uff08<\/b><\/strong><strong><b>2.2 ml Ah<\/b><\/strong><strong><sup><b>-1<\/b><\/sup><\/strong><strong><b>\/2.6 g Ah<\/b><\/strong><strong><sup><b>-1<\/b><\/sup><\/strong><strong><b>\uff09<\/b><\/strong>\u5bf9\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u7684\u5bb9\u91cf\u8870\u51cf\u884c\u4e3a\u8fdb\u884c\u4e86\u8868\u5f81\u3002\u901a\u8fc7\u626b\u63cf\u7535\u5b50\u663e\u5fae\u955c\uff08SEM\uff09\u548cX\u5c04\u7ebf\u65ad\u5c42\u626b\u63cf\u6210\u50cf\u7cfb\u7edf\u89c2\u5bdf\u4e86\u539f\u59cb\u91d1\u5c5e\u9502\u5f62\u8c8c\u7684\u6076\u5316\uff0c\u5e76\u901a\u8fc7\u4f7f\u7528<strong><b>\u6838\u78c1\u5171\u632f\u6ce2\u8c31\u6cd5\u548c\u8d85\u58f0\u6ce2\u900f\u5c04\u6cd5<\/b><\/strong>\u68c0\u6d4b\u7535\u89e3\u8d28\u964d\u89e3\u548c\u8017\u5c3d\u7684\u6839\u672c\u539f\u56e0\uff0c\u800c\u4e14\u968f\u7740\u7535\u89e3\u8d28\u8017\u5c3d\uff0c\u9502\u5b54\u9699\u7387\u9010\u6e10\u589e\u52a0\u3002\u6b64\u5916\uff0c\u5728\u5b89\u5168\u6027\u6d4b\u8bd5\u65b9\u9762\uff0c\u901a\u8fc7\u6d4b\u91cf\u5728<strong><b>\u9488\u523a\u8bd5\u9a8c<\/b><\/strong>\u8fc7\u7a0b\u4e2d\u7684\u6e29\u5ea6\u4ee5\u76d1\u6d4b\u5b89\u5168\u6027\u3002\u6700\u540e\uff0c\u4f5c\u8005\u5229\u7528\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\u83b7\u5f97\u7684\u542f\u53d1\u5f00\u53d1\u4e86\u4e00\u79cd\u4f18\u5316\u7684<strong><b>\u53cc\u76d0\u9ad8\u6d53\u5ea6\u7535\u89e3\u6db2\uff082 M LiDFOB\u548c1.4 M LiBF<\/b><\/strong><strong><sub><b>4<\/b><\/sub><\/strong><strong><b>\uff09<\/b><\/strong>\uff0c\u5c06\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u7684\u5faa\u73af\u5bff\u547d\u5ef6\u957f\u5230200\u6b21\uff0c\u5e76\u4fdd\u630180%\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-216791 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-7-17.png\" alt=\"\" width=\"600\" height=\"374\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-7-17.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-7-17-300x187.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe5. \u9502\u5b54\u9699\u7387\u589e\u52a0\u7684\u5f71\u54cd<\/p>\n<p style=\"text-align: center;\">\u203b<a href=\"https:\/\/doi.org\/10.1038\/s41560-020-0668-8\"><em><u><i>Nat. Energy 5 (2020) 693\u2013702<\/i><\/u><\/em><\/a><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-216790 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-6-16.png\" alt=\"\" width=\"600\" height=\"233\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-6-16.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-6-16-300x117.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe6. \u9488\u523a\u5b9e\u9a8c<\/p>\n<p style=\"text-align: center;\">\u203b<a href=\"https:\/\/doi.org\/10.1038\/s41560-020-0668-8\"><em><u><i>Nat. Energy 5 (2020) 693\u2013702<\/i><\/u><\/em><\/a><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-216789 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-5-20.png\" alt=\"\" width=\"600\" height=\"256\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-5-20.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-5-20-300x128.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe7. \u53cc\u76d0\u9ad8\u6d53\u5ea6\u7535\u89e3\u6db2\u5e94\u7528<\/p>\n<p style=\"text-align: center;\">\u203b<a href=\"https:\/\/doi.org\/10.1038\/s41560-020-0668-8\"><em><u><i>Nat<\/i><\/u><\/em><em><u><i>.<\/i><\/u><\/em><em><u><i>\u00a0Energy 5 (2020) 693\u2013702<\/i><\/u><\/em><\/a><\/p>\n<p>3.1.2 \u4f4e\u6d53\u5ea6&amp;\u9ad8\u6d53\u5ea6\u7535\u89e3\u6db2<\/p>\n<p>\u7531\u4e8e\u9ad8\u6d53\u5ea6\u7535\u89e3\u6db2\u4e2d\u6e38\u79bb\u6eb6\u5242\u5206\u5b50\u7684\u6bd4\u4f8b\u975e\u5e38\u4f4e\uff0c\u56e0\u6b64\u76d0-\u6eb6\u5242\u7ec4\u5408\u6613\u4e8e\u5c06\u6700\u4f4e\u672a\u5360\u636e\u5206\u5b50\u8f68\u9053\uff08LUMO\uff09\u7684\u4f4d\u7f6e\u4ece\u6eb6\u5242\u79fb\u5411\u76d0\uff0c\u8fd9\u53ef\u80fd\u4f1a\u5bfc\u81f4\u9502\u76d0\u9634\u79bb\u5b50\u7ec4\u5408\u7684\u4f18\u5148\u51cf\u5c11\uff0c\u4ece\u800c\u5bfc\u81f4\u5f62\u6210\u6301\u4e45\u8010\u7528\u4e14\u5bcc\u542b\u65e0\u673a\u6210\u5206\u7684SEI\u6216\u9634\u6781\u7535\u89e3\u8d28\u4e2d\u95f4\u76f8\uff08CEI\uff09\uff0c\u4ece\u800c\u63d0\u9ad8\u4e86Li\u79bb\u5b50\u7684\u5229\u7528\u7387\u3002\u9ad8\u6d53\u5ea6\u7535\u89e3\u6db2\u901a\u5e38\u6709\u5982\u4e0b\u529f\u80fd\uff1a<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-216792 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-9-10.png\" alt=\"\" width=\"600\" height=\"694\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-9-10.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-9-10-259x300.png 259w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe8.\u00a0\u9ad8\u6d53\u5ea6\u7535\u89e3\u6db2\u7684\u529f\u80fd<\/p>\n<p style=\"text-align: center;\">\u203b<a href=\"https:\/\/doi.org\/10.1038\/s41560-019-0336-z\"><em><u><i>Nat<\/i><\/u><\/em><em><u><i>.<\/i><\/u><\/em><em><u><i>\u00a0Energy 4 (2019) 269\u2013280<\/i><\/u><\/em><\/a><\/p>\n<p>2016\u5e74<strong><b>\u897f\u5317\u592a\u5e73\u6d0b\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u5f20\u7ee7\u5149<\/b><\/strong><strong><b>\u6559\u6388<\/b><\/strong>\u62a5\u544a\u4e86\u4f7f\u7528\u7531<strong><b>1\uff0c2-\u4e8c\u7532\u6c27\u57fa\u4e59\u70f7\uff08DME\uff09\u6eb6\u5242\u548c\u9ad8\u6d53\u5ea6LiFSI\u76d0\u7ec4\u6210\u7684\u9ad8\u6d53\u5ea6\u7535\u89e3<\/b><\/strong><strong><b>\u6db2<\/b><\/strong>\u7684\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u8bbe\u8ba1\uff08Cu || LiFePO<sub>4<\/sub>\uff09\u3002\u8fd9\u79cd\u7535\u6c60\u4ee5\u4f18\u5316\u7684\u5145\u7535\/\u653e\u7535\u5faa\u73af\u65f6\uff0c\u53ef\u63d0\u4f9b\u8f83\u9ad8\u7684\u521d\u59cb\u653e\u7535\u5bb9\u91cf\uff0c\u5e76\u4e14\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7684\u5e73\u5747CE\u5927\u4e8e99.8\uff05\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-216793 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-10-12.png\" alt=\"\" width=\"600\" height=\"376\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-10-12.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-10-12-300x188.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe9.\u00a01 M LiPF<sub>6<\/sub>-EC\/DMC\u548c4 M LiFSI-DME\u7684\u65e0\u9633\u6781\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd<\/p>\n<p style=\"text-align: center;\">\u203b<a href=\"https:\/\/doi.org\/10.1002\/adfm.201602353\"><em><u><i>Adv. Funct. Mater. 26 <\/i><\/u><\/em><em><u><i>(<\/i><\/u><\/em><em><u><i>2016) 7094\u20137102<\/i><\/u><\/em><\/a><\/p>\n<p>3.2 \u96c6\u6d41\u4f53\u8bbe\u8ba1<\/p>\n<p>\u4f5c\u4e3a\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u7684\u5173\u952e\u7ec4\u4ef6\uff0c\u96c6\u6d41\u4f53\u5bf9\u7535\u5316\u5b66\u6027\u80fd\u5177\u6709\u81f3\u5173\u91cd\u8981\u7684\u5f71\u54cd\u3002\u53ef\u5145\u7535\u7535\u6c60\u4e2d\u7684\u96c6\u6d41\u4f53\u901a\u5e38\u5fc5\u987b\u6ee1\u8db3\u4ee5\u4e0b\u5fc5\u8981\u7279\u6027\uff1a<strong><b>\uff081\uff09\u9ad8\u7535\u5b50\u4f20\u5bfc\u6027\uff1b\uff082\uff09\u4f18\u5f02\u7684\u5316\u5b66\u548c\u7535\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u53ef\u62b5\u6297\u8150\u8680\u548c<\/b><\/strong><strong><b>\u526f<\/b><\/strong><strong><b>\u53cd\u5e94\uff1b\uff083\uff09\u4f18\u5f02\u7684\u673a\u68b0\u5f3a\u5ea6\uff1b<\/b><\/strong><strong><b>\uff08<\/b><\/strong><strong><b>4\uff09\u51fa\u8272\u7684\u70ed\u7a33\u5b9a\u6027\uff0c\u53ef\u9002\u5e94\u8f83\u5bbd\u7684\u5de5\u4f5c\u6e29\u5ea6\u3002<\/b><\/strong>\u5bf9\u4e8e\u65e0\u9502\u8d1f\u6781\u7535\u6c60\uff0c\u5c06\u6765\u81ea\u9634\u6781\u7684\u6709\u9650\u9502\u6e90\u76f4\u63a5\u9540\u5230\u5f02\u7269\u9633\u6781\u96c6\u6d41\u4f53\u4e0a\u662f\u975e\u5e38\u5173\u952e\u7684\u6b65\u9aa4\u3002 \u56e0\u6b64\uff0c\u96c6\u6d41\u4f53\u7684\u8bbe\u8ba1\u5bf9\u4e8e\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u4e5f\u81f3\u5173\u91cd\u8981\u3002<\/p>\n<p><strong><b>\u65af\u5766\u798f\u5927\u5b66\u5d14\u5c79\u6559\u6388<\/b><\/strong>\u57282016\u5e74\u7684\u4e00\u9879\u7814\u7a76\u4e2d\u8868\u660e\uff0c\u7535\u9540\u9502\u91d1\u5c5e\u7684\u5f62\u6838\u8d85\u7535\u52bf\u9ad8\u5ea6\u4f9d\u8d56\u6c89\u79ef\u886c\u5e95\u3002\u6d4b\u8bd5\u4e86\u4e00\u7cfb\u5217\u91d1\u5c5e\u57fa\u6750\u7684\u9502\u6c89\u79ef\uff0c\u53d1\u73b0\u4e0e\u9502\u91d1\u5c5e\u5177\u6709\u6700\u5927\u6676\u4f53\u5931\u914d\u7684\u57fa\u6750\u8868\u73b0\u51fa\u6700\u9ad8\u7684\u6210\u6838\u8d85\u7535\u52bf\u3002<strong><b>\u91d1\u5c5e\u9502\u5177\u6709\u4f53\u5fc3\u7acb\u65b9\uff08BCC\uff09\u6676\u4f53\u7ed3\u6784\uff0c\u56e0\u6b64\u6709\u5229\u5730\u6c89\u79ef\u5728\u5177\u6709BCC\u7ed3\u6784\u7684\u57fa\u677f\u4e0a\u3002\u9502\u4e5f\u6709\u5229\u5730\u6c89\u79ef\u5728\u90e8\u5206\u9502\u91d1\u5c5e\u589e\u6eb6\u6216\u4e0e\u9502\u91d1\u5c5e\u5408\u91d1\u5316\u7684\u4eb2<\/b><\/strong><strong><b>\u9502<\/b><\/strong><strong><b>\u6750\u6599\u4e0a\u3002<\/b><\/strong>\u8fd9\u5305\u62ec\u91d1\u7b49\u91d1\u5c5e\uff0c\u5c3d\u7ba1\u5b83\u5177\u6709\u9762\u5fc3\u7acb\u65b9\uff08FCC\uff09\u6676\u4f53\u7ed3\u6784\u3002\u8fd9\u9879\u7814\u7a76\u7740\u91cd\u6307\u51fa\uff0c\u94dc\u5177\u6709FCC\u6676\u4f53\u7ed3\u6784\u5e76\u4e14\u4e0d\u5177\u6709\u9502\u91d1\u5c5e\u7684\u6eb6\u89e3\u6027\uff0c\u56e0\u6b64\u5b83\u662f\u9502\u91d1\u5c5e\u6700\u4e0d\u5229\u7684\u6c89\u79ef\u57fa\u5e95\u4e4b\u4e00\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-216795 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-15-8.png\" alt=\"\" width=\"600\" height=\"821\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-15-8.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-15-8-219x300.png 219w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe10.\u00a0\u9502\u5728\u5404\u79cd\u57fa\u6750\u4e0a\u6c89\u79ef\u8fc7\u7535\u52bf<\/p>\n<p style=\"text-align: center;\">\u203b<a href=\"https:\/\/doi.org\/10.1038\/nenergy.2016.10\"><em><u><i>Nat. Energy 1 (2016) 16010<\/i><\/u><\/em><\/a><\/p>\n<p>\u524d\u9762\u8ba8\u8bba\u94dc\u4e0d\u5177\u6709\u9502\u91d1\u5c5e\u7684\u6eb6\u89e3\u6027\uff0c\u4e14Cu\uff088.96 g\/cm<sup>3<\/sup>\uff09\u6709\u7740\u6bd4\u9502\uff080.5 g\/cm<sup>3<\/sup>\uff09\u66f4\u9ad8\u7684\u5bc6\u5ea6\u3002\u6545\u76f4\u63a5\u7528\u5728\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u4e2d\u80fd\u91cf\u5bc6\u5ea6\u8f83\u4f4e\uff08&lt;350 Wh\/kg\uff09\u3002\u76ee\u524d\u65e0\u8d1f\u6781\u8bbe\u8ba1\u6709\u4e24\u79cd\u53ef\u80fd\u7684\u65b9\u6cd5\uff1a\uff08i\uff09\u5b8c\u5168\u66ff\u4ee3\u94dc\u4f5c\u4e3a\u96c6\u6d41\u4f53\uff0c\uff08ii\uff09\u5728\u94dc\u4e0a\u6d82\u4e00\u5c42\u4fee\u9970\u5c42\u3002<\/p>\n<p>3.2.1 \u65b0\u578b\u96c6\u6d41\u4f53<\/p>\n<p><strong><b>\u5361\u5185\u57fa\u6885\u9686\u5927\u5b66<\/b><\/strong><strong><b>Venkatasubramanian Viswanathan<\/b><\/strong>\u57fa\u4e8e\u7535\u50ac\u5316\u89c2\u70b9\u7684\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff0c\u901a\u8fc7\u70ed\u529b\u5b66\u5206\u6790\u8ba1\u7b97\u4e86\u591a\u79cd\u96c6\u6d41\u4f53\u4e0a\u7684\u9502\u6210\u6838\u8d85\u7535\u52bf\u548c\u8868\u9762\u6269\u6563\u6d3b\u5316\u80fd\u3002<strong><b>\u53d1\u73b0\u6d3b\u5316\u80fd\u548c\u5b8c\u5168<\/b><\/strong><strong><b>\u8986\u76d6\u7684Li\u8868\u9762\u7684\u5438\u9644\u7113\u4e4b\u95f4\u6709\u5f88\u5f3a\u7684\u76f8\u5173\u6027<\/b><\/strong><strong><b>\uff0c<\/b><\/strong><strong><b>\u4f4e\u9502\u5438\u9644\u80fd\uff08\u63a5\u8fd1\u96f6\uff09\u7684<\/b><\/strong><strong><b>\u96c6\u6d41\u4f53<\/b><\/strong><strong><b>\u6709\u5229\u4e8e\u5b9e\u73b0\u5747\u5300\u4e14\u5e73\u5766\u7684\u9502\u6c89\u79ef\u5f62\u6001\u3002<\/b><\/strong>\u7406\u8bba\u4e0a\u7684\u7814\u7a76\u8868\u660e\uff0c\u5404\u79cd<strong><b>\u9502\u5408\u91d1<\/b><\/strong>\uff08\u5982Li\u2013Mg\uff0cLi\u2013Sn\uff0cLi\u2013Pb\uff0cLi\u2013Si\uff0cLi\u2013Ag\uff0cLi\u2013Cd\uff0cLi\u2013B\uff0cLi\u2013Al\uff0cLi\u2013Zn\u7b49\uff09\u90fd\u53ef\u4ee5\u7528\u4f5c\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u7684\u9633\u6781\u96c6\u6d41\u4f53\uff0c\u4ee5\u5b9e\u73b0\u8f83\u4f4e\u7684\u6210\u6838\u8d85\u7535\u52bf\u548c\u66f4\u597d\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-216796 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-16-7.png\" alt=\"\" width=\"500\" height=\"435\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-16-7.png 500w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-16-7-300x261.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/> <img loading=\"lazy\" decoding=\"async\" class=\"wp-image-216797 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-17-2.png\" alt=\"\" width=\"500\" height=\"425\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-17-2.png 500w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-17-2-300x255.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe11.\u00a0\u9502\u5728\u5404\u79cd\u57fa\u6750\u4e0a\u6c89\u79ef\u8fc7\u7535\u52bf<\/p>\n<p style=\"text-align: center;\">\u203b<a href=\"https:\/\/doi.org\/10.1021\/acsenergylett.9b02306\"><em><u><i>ACS Energy Lett. 4 (2019) 2952\u20132959<\/i><\/u><\/em><\/a><\/p>\n<p>\u96c6\u6d41\u4f53\u9664\u4e86\u5177\u6709\u4f4e\u9502\u5438\u9644\u80fd\u5916\uff0c\u8fd8\u5e94\u5177\u5907\u8f83\u4f4e\u7684\u5bc6\u5ea6\u4ee5\u83b7\u5f97\u66f4\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002<strong><b>\u65af\u5766\u798f\u5927\u5b66\u5d14\u5c79\u6559\u6388<\/b><\/strong>\u57282020\u5e74\u62a5\u544a\u4e86\u4e00\u79cd\u590d\u5408\u5f0f\u96c6\u6d41\u4f53\u8bbe\u8ba1\uff0c\u8be5\u8bbe\u8ba1\u53ef\u540c\u65f6\u6700\u5927\u7a0b\u5ea6\u5730<strong><b>\u51cf\u5c11\u7535\u6c60\u5185\u7684\u201c\u6b7b\u91cd\u201d\u5e76\u63d0\u9ad8\u9632\u706b\u5b89\u5168\u6027<\/b><\/strong>\u3002\u901a\u8fc7\u5c06\u5d4c\u6709\u78f7\u9178\u4e09\u82ef\u916f\u963b\u71c3\u5242\u7684\u805a\u9170\u4e9a\u80fa\u5939\u5728\u4e24\u4e2a\u8d85\u8584\u94dc\u5c42\uff08\u7ea6500\u03bcm\uff09\u4e4b\u95f4\uff0c\u5236\u5f97\u8d85\u8f7b\u7684\u805a\u9170\u4e9a\u80fa\u57fa\u96c6\u7535\u5668\uff08\u539a9\u03bcm\uff0c\u6bd4\u91cd1.54\u03bcmg\/cm<sup>-2<\/sup>\uff09\u3002\u4e0e\u7ec4\u88c5\u6709\u6700\u8584\u7684\u5546\u7528\u91d1\u5c5e\u7b94\u96c6\u7535\u5668\uff08\u7ea66\u03bcm\uff09\u7684\u9502\u79bb\u5b50\u7535\u6c60\u76f8\u6bd4\uff0c\u914d\u5907\u4e86\u8fd9\u79cd\u590d\u5408\u96c6\u6d41\u4f53\u7684\u7535\u6c60\u53ef\u4ee5\u5b9e\u73b016-26\uff05\u7684\u6bd4\u80fd\u91cf\u63d0\u9ad8\uff0c\u5e76\u5728\u77ed\u8def\u548c\u70ed\u5931\u63a7\u7b49\u6781\u7aef\u6761\u4ef6\u4e0b\u8fc5\u901f\u81ea\u7184\u3002\u8be5\u7814\u7a76\u4e3b\u8981\u91c7\u7528Gr\u4e3a\u8d1f\u6781\u6750\u6599\uff0c\u5c3d\u7ba1\u4e0e\u4f20\u7edf\u7684\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u6709\u4e9b\u533a\u522b\uff0c\u4f46\u662f<strong><b>\u8d85\u8f7b\u4e14\u52a9\u71c3\u7684\u96c6\u6d41\u4f53<\/b><\/strong>\u5bf9\u4e8e\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u548c\u9ad8\u5b89\u5168\u6027\u7684\u7535\u6c60\u8bbe\u8ba1\u975e\u5e38\u6709\u4ef7\u503c\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-216798 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-18.png\" alt=\"\" width=\"600\" height=\"246\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-18.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-18-300x123.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe12.\u00a0\u8d85\u8f7b\u4e14\u52a9\u71c3\u7684\u96c6\u6d41\u4f53\u8bbe\u8ba1<\/p>\n<p style=\"text-align: center;\">\u203b<a href=\"https:\/\/doi.org\/10.1038\/s41560-020-00702-8\"><em><u><i>Nat<\/i><\/u><\/em><em><u><i>.<\/i><\/u><\/em><em><u><i>\u00a0Energy 5 (2020) 786\u2013793<\/i><\/u><\/em><\/a><\/p>\n<p>3.2.2 \u96c6\u6d41\u4f53\u8868\u9762\u4fee\u9970<\/p>\n<p>\u8fd1\u671f\uff0c<strong><b>\u4e2d\u79d1\u9662\u7d22\u938f\u654f\u3001\u9648\u7acb\u6cc9\u9662\u58eb\u56e2\u961f<\/b><\/strong>\u4f7f\u7528<strong><b>\u5916\u5ef6\u611f\u5e94\u7535\u9540\u96c6\u6d41\u4f53\uff08<\/b><\/strong><strong><b>E-Cu\uff09<\/b><\/strong><strong><b>\u6765<\/b><\/strong><strong><b>\u5ef6\u957f\u65e0\u9502<\/b><\/strong><strong><b>\u8d1f<\/b><\/strong><strong><b>\u6781\u7535\u6c60\u7684\u4f7f\u7528\u5bff\u547d\u3002<\/b><\/strong>E-Cu\u4e0a\u7684\u529f\u80fd\u5c42\u901a\u8fc7\u5408\u91d1\u5316\u65b9\u5f0f\u8fdb\u884cLi\u7684\u5b58\u50a8\uff0c\u5f62\u6210\u5916\u5ef6\u8bf1\u5bfc\u5c42\uff0c\u8be5\u5c42\u8868\u73b0\u51fa\u5feb\u901f\u7684Li<sup>+<\/sup>\u8868\u9762\u6269\u6563\uff0c\u4ece\u800c\u5bfc\u81f4Li\u5916\u5ef6\u751f\u957f\u3002\u6b64\u5916\uff0c\u8fd9\u79cd\u5408\u91d1\u5316\u8fc7\u7a0b\u8fd8\u4fc3\u8fdb\u4e86\u5bccLiF\u56fa\u4f53\u7535\u89e3\u8d28\u4e2d\u95f4\u76f8\uff08SEI\uff09\u7684\u5f62\u6210\uff0c\u8fd9\u5bf9\u4e8e\u5747\u5300\u7684Li\u9540\u975e\u5e38\u6709\u7528\u3002\u7531\u4e8e\u5916\u5ef6\u751f\u957f\u548c\u5bccLiF\u7684SEI\u7684\u4f18\u52bf\uff0cE-Cu\/Li\u4e0d\u5bf9\u79f0\u7535\u6c60\u7684\u521d\u59cb\u5e93\u4f26\u6548\u7387\u4ece93.24\uff05\u63d0\u9ad8\u523098.24\uff05\uff0c\u5728\u6709\u9650\u7684\u7535\u89e3\u6db2\u7684\u60c5\u51b5\u4e0b\uff08E\/C\u6bd4\u4e3a2 g Ah<sup>-1<\/sup>\uff09\uff0c<strong><b>\u65e0<\/b><\/strong><strong><b>\u8d1f<\/b><\/strong><strong><b>\u6781NCM811\/E-Cu<\/b><\/strong><strong><b>\u8f6f\u5305<\/b><\/strong><strong><b>\u7535\u6c60\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\u4ece66\uff05\u63d0\u9ad8\u523084\uff05\uff0c\u80fd\u91cf\u5bc6\u5ea6\u9ad8\u8fbe420 Wh kg<\/b><\/strong><strong><sup><b>-1<\/b><\/sup><\/strong><strong><b>\uff09\u3002<\/b><\/strong>\u8fd9\u79cd\u7b56\u7565\u5728\u5f00\u53d1\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u4e14\u957f\u5bff\u547d\u7535\u6c60\u4ee5\u5ef6\u957f\u6709\u7740\u91cd\u8981\u7684\u501f\u9274\u610f\u4e49\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-216799 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-19.png\" alt=\"\" width=\"600\" height=\"251\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-19.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-19-300x126.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe13.\u00a0\u5916\u5ef6\u8bf1\u5bfc\u9502\u6c89\u79ef\u8bbe\u8ba1<\/p>\n<p style=\"text-align: center;\">\u203b<a href=\"https:\/\/doi.org\/10.1002\/aenm.202003709\"><em><u><i>Adv. Energy Mater. (20<\/i><\/u><\/em><em><u><i>21)<\/i><\/u><\/em><em><u><i>\u00a02003709<\/i><\/u><\/em><\/a><\/p>\n<p>3.3 \u6d4b\u8bd5\u65b9\u6cd5\u4f18\u5316<\/p>\n<p>\u9664\u4e86\u4f18\u5316\u96c6\u6d41\u4f53\u548c\u7535\u89e3\u6db2\u4e4b\u5916\uff0c\u5982\u4f55\u91c7\u7528\u5408\u9002\u7684\u6d4b\u8bd5\u65b9\u6848\u6765\u907f\u514dLi\u679d\u6676\u751f\u957f\u4ee5\u5ef6\u957f\u5faa\u73af\u5bff\u547d\uff0c\u8fd9\u6210\u4e3a\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u7684\u5173\u952e\u95ee\u9898\u3002\u4e0d\u540c\u7684\u6d4b\u8bd5\u6761\u4ef6\u4f1a\u5f71\u54cd\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u7684\u9502\u6c89\u79ef\u8d28\u91cf\uff0c\u7535\u89e3\u6db2\u7a33\u5b9a\u6027\uff0c\u7535\u6781\/\u7535\u89e3\u8d28\u63a5\u89e6\u7b49\u3002\u4f17\u591a\u7814\u7a76\u5c0f\u7ec4\u5728\u8fd9\u65b9\u9762\u505a\u51fa\u4e86\u91cd\u5927\u8d21\u732e\uff0c\u5305\u62ec<strong><b>\u6e29\u5ea6\uff0c\u538b\u529b\uff0c\u622a\u6b62\u7535\u538b<\/b><\/strong>\u7b49\u3002<\/p>\n<p>2018\u5e74<strong><b>\u52a0\u62ff\u5927\u8fbe\u5c14\u8c6a\u65af\u5927\u5b66<\/b><\/strong><strong><b>J. R. Dahn\u6559\u6388<\/b><\/strong>\u4f7f\u7528\u8d85\u9ad8\u7cbe\u5ea6\u5145\u7535\u5668\uff08UHPC\uff09\u6d4b\u8bd5\u4e86\u9ad8\u538bNMC 532 || Cu\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u3002\u5728\u4e24\u79cd\u4e0d\u540c\u7684\u7535\u89e3\u8d28\u914d\u65b9\u4e0b\uff0c\u4f7f\u7528\u4f4e\u538b\u548c\u9ad8\u538b\u5bf9\u7535\u6c60\u8fdb\u884c\u5faa\u73af\u3002\u5c06\u8fd9\u4e9b\u7535\u6c60\u7684\u4e0b\u9650\u622a\u6b62\u7535\u538b\u4ece3.6 V\u66f4\u6539\u4e3a1.25 V\uff0c\u4f1a\u4e25\u91cd\u5f71\u54cd\u5176\u5bb9\u91cf\u4fdd\u6301\u80fd\u529b\u548c\u5e93\u4ed1\u6548\u7387\u3002\u653e\u7535\u81f33.6 V\u7684\u7535\u6c60\u663e\u793a\u51fa\u8f83\u9ad8\u7684\u521d\u59cbCE\uff08&gt; 99.8\uff05\uff09\uff0c\u57285-10\u4e2a\u5faa\u73af\u540e\u8fc5\u901f\u4e0b\u964d\uff0c\u5e76\u7a33\u5b9a\u5728\u66f4\u4f4e\u7684\u503c\uff08&lt;99\uff05\uff09\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u653e\u7535\u81f31.25 V\u7684\u7535\u6c60\u5728\u6052\u5b9a\u7684CE &lt;99\uff05\u65f6\u663e\u793a<strong><b>\u7ebf\u6027\u5bb9\u91cf\u8870\u51cf<\/b><\/strong>\u3002\u6240\u4ee5\u4ec5\u901a\u8fc75-10\u6b21\u5faa\u73af\u540e\uff0c\u5c31\u53ef\u4ee5\u901a\u8fc7\u6df1\u653e\u7535\u7535\u6c60\u7684CE\u6d4b\u91cf\u6765\u51c6\u786e\u9884\u6d4b\u5faa\u73af\u5bff\u547d\u8d8b\u52bf\u3002\u8fd9\u4e9b\u7ed3\u679c\u8868\u660e\uff0c<strong><b>\u65e0<\/b><\/strong><strong><b>\u9502\u8d1f<\/b><\/strong><strong><b>\u6781\u7535\u6c60\u4e0d\u4ec5\u662f\u4e00\u79cd\u5177\u6709\u6781\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u6f5c\u529b\u7684\u65b0\u578b\u7535\u6c60\uff0c\u800c\u4e14\u662f\u4e00\u79cd\u7528\u4e8e\u8bc4\u4f30\u5168\u7535\u6c60\u6761\u4ef6\u4e0b\u9502\u91d1\u5c5e\u5faa\u73af\u6548\u7387\u7684\u5feb\u901f\u6709\u6548\u65b9\u6cd5\u3002<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-216800 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-20-1.png\" alt=\"\" width=\"600\" height=\"207\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-20-1.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-20-1-300x104.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe14.\u00a0\u538b\u529b\uff0c\u622a\u6b62\u7535\u538b\u548c\u7535\u89e3\u6db2\u5bf9\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u5faa\u73af\u6027\u80fd\u7684\u5f71\u54cd<\/p>\n<p style=\"text-align: center;\">\u203b<a href=\"https:\/\/doi.org\/10.1149\/2.0641814jes\"><em><u><i>J. Electrochem. Soc. 165 (2018) A3321-A3325<\/i><\/u><\/em><\/a><\/p>\n<p>2019\u5e74<strong><b>J. R. Dahn\u6559\u6388<\/b><\/strong>\u4f7f\u7528\u4e24\u79cd\u4e0d\u540c\u7684\u7535\u89e3\u8d28\uff081M LiPF<sub>6<\/sub>\u00a0FEC\uff1aDEC\uff081\uff1a2\uff09\u548c1M LiPF<sub>6<\/sub>\u00a0FEC\uff1aTFEC\uff081\uff1a2\uff09\uff09\uff0c\u5c06\u7535\u6c60\u538b\u529b\u6d4b\u91cf\u503c\u9650\u5236\u572875\u20132205 kPa\u4e4b\u95f4\uff0c\u8bc4\u4f30\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u3002\u53d1\u73b0\u5c06\u521d\u59cb\u5e73\u5747\u538b\u529b\u4ece75\u20132200 kPa\u589e\u52a0\u901a\u5e38\u53ef\u4ee5\u6539\u5584\u5faa\u73af\u5bff\u547d\uff0c\u5176\u4e2d\u538b\u529b\u57281200 kPa\u65f6\u6027\u80fd\u6700\u597d\u3002\u53e6\u5916\u8fd8\u53d1\u73b0\u538b\u529b\u589e\u52a0\u5bf9\u4f7f\u7528\u4e0d\u540c\u6eb6\u5242\u7cfb\u7edf\u7684\u7535\u6c60\u6027\u80fd\u7684\u5f71\u54cd\u5e76\u4e0d\u4e00\u6837\uff0c\u8fd9\u8868\u660e<strong><b>\u7535\u89e3<\/b><\/strong><strong><b>\u6db2<\/b><\/strong><strong><b>\u7684\u7269\u7406\u7279\u6027\u5728\u53d71200\u81f32200 kPa\u8f83\u9ad8\u538b\u529b\u9650\u5236\u7684\u7535\u6c60\u4e2d\u8d77\u7740\u91cd\u8981\u4f5c\u7528\u3002<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-216801 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-26-1.png\" alt=\"\" width=\"600\" height=\"194\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-26-1.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/01\/\u56fe\u7247-26-1-300x97.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe15.\u00a0\u538b\u529b\u5bf9\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u5faa\u73af\u6027\u80fd\u7684\u5f71\u54cd<\/p>\n<p style=\"text-align: center;\">\u203b<a href=\"https:\/\/doi.org\/10.1149\/2.0091908jes\"><em><u><i>J. Electrochem. Soc. 166 (2019) A1291-A1299<\/i><\/u><\/em><\/a><\/p>\n<p><strong><b>\u3010\u7ed3\u8bba\u4e0e\u5c55\u671b\u3011<\/b><\/strong><\/p>\n<p>\u65e0\u9633\u6781\u5168\u7535\u6c60\u662f\u9502\u91d1\u5c5e\u7535\u6c60\u5f00\u53d1\u4e2d\u7684\u91cd\u8981\u91cc\u7a0b\u7891\u3002\u53ef\u9002\u7528\u4e8e\u4efb\u4f55\u7ed9\u5b9a\u7684\u542b\u9502\u9634\u6781\u7cfb\u7edf\uff0c\u7531\u4e8e\u5b8c\u5168\u6d88\u9664\u4e86\u6240\u6709\u9633\u6781\u6d3b\u6027\u6750\u6599\u5e76\u5229\u7528\u4e86\u4ece\u9634\u6781\u8f93\u51fa\u7684\u6700\u5927\u53ef\u80fd\u7535\u538b\uff0c\u56e0\u6b64\u65e0\u9633\u6781\u7684\u5168\u7535\u6c60\u53ef\u63d0\u4f9b\u6700\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u5982\u679c\u8981\u9762\u5411\u5b9e\u9645\u8fd0\u7528\uff0c\u9700\u8981\u4ece\u7535\u6c60\u7cfb\u7edf\u7684\u5404\u4e2a\u90e8\u5206\u8fdb\u884c\u4f18\u5316\u6539\u8fdb\uff0c\u5305\u62ec\u7535\u89e3\u6db2\uff0c\u96c6\u6d41\u4f53\u548c\u6d4b\u8bd5\u624b\u6bb5\u7b49\u3002\u53e6\u5916\u65e0\u9502\u8d1f\u6781\u7535\u6c60\u4e5f\u53ef\u4ee5\u4ece\u6700\u771f\u5b9e\u7684\u610f\u4e49\u4e0a\u5bf9\u5bb9\u91cf\u635f\u5931\u673a\u5236\u8fdb\u884c\u8bca\u65ad\u8bc4\u4f30\uff0c\u56e0\u4e3a\u7531\u4e8e\u7f3a\u5c11\u8fc7\u91cf\u7684\u9502\uff0c\u53ef\u4ee5\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u76f4\u63a5\u76d1\u63a7\u7535\u6c60\u4e2d\u7684\u9502\u5b58\u91cf\u3002<\/p>\n<p><strong><b>\u3010\u53c2\u8003\u6587\u732e\u3011<\/b><\/strong><\/p>\n<p>[1] Anode-Free Full Cells: A Pathway to High-Energy DensityLithium-Metal Batteries.<em><i>\u00a0Adv.\u00a0<\/i><\/em><em><i> Energy Mater. (2020<\/i><\/em><em><i>)<\/i><\/em><em><i>\u00a02000804<\/i><\/em>.<\/p>\n<p>[2] Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review. <em>Chem.<\/em>\u00a0<em><i>Rev. 117 (2017) 10403\u201310473<\/i><\/em>.<\/p>\n<p>[3] Recently advances and perspectives of anode-free rechargeable batteries. <em><i>Nano Energy 78 (2020) 105344<\/i><\/em>.<\/p>\n<p>[4] Long cycle life and dendrite-free lithium morphology in anode-free lithium pouch cells enabled by a dual-salt liquid electrolyte. <em>Nat.\u00a0<i>Energy 4 (2019) 683\u2013689<\/i><\/em>.<\/p>\n<p>[5] Diagnosing and correcting anode-free cell failure via electrolyte and morphological analysis. <em><i>Nat<\/i><\/em><em><i>.\u00a0<\/i><\/em><em><i>Energy 5 (2020) 693\u2013702<\/i><\/em>.<\/p>\n<p>[6] Advances and issues in developing salt-concentrated battery electrolytes. <em><i>Nat<\/i><\/em><em><i>.\u00a0<\/i><\/em><em><i>Energy 4 (2019) 269\u2013280<\/i><\/em>.<\/p>\n<p>[7] Anode-Free Rechargeable Lithium Metal Batteries. <em><i>Adv.\u00a0<\/i><\/em><em><i>Funct. Mater. 26 <\/i><\/em><em><i>(<\/i><\/em><em><i>2016) 7094\u20137102<\/i><\/em>.<\/p>\n<p>[8] Selective deposition and stable encapsulation of lithium through heterogeneous seeded growth.\u00a0<em>Nat.\u00a0<\/em> <em><i> Energy 1 (2016) 16010<\/i><\/em>.<\/p>\n<p>[9] Computational Screening of Current Collectors for Enabling Anode-Free Lithium Metal Batteries. <em><i>ACS Energy Lett. 4 (2019) 2952\u20132959<\/i><\/em>.<\/p>\n<p>[10] Selective deposition and stable encapsulation of lithium through heterogeneous seeded growth. <em><i>Nat<\/i><\/em><em><i>.\u00a0<\/i><\/em><em><i>Energy 5 (2020) 786\u2013793<\/i><\/em>.<\/p>\n<p>[11] Epitaxial Induced Plating Current\u2010Collector Lasting Lifespan of Anode\u2010Free Lithium Metal Battery. <em><i>Adv.<\/i><\/em><em><i>\u00a0Energy Mater. (20<\/i><\/em><em><i>21)<\/i><\/em><em><i>2003709<\/i><\/em>.<\/p>\n<p>[12] Measuring the Coulombic Efficiency of Lithium Metal Cycling in Anode-Free Lithium Metal Batteries. <em>J.\u00a0<i>Electrochem. Soc. 165 (2018) A3321-A3325<\/i><\/em>.<\/p>\n<p>[13] Exploring the Impact of Mechanical Pressure on the Performance of Anode-Free Lithium Metal Cells.<em><i>\u00a0J. Electrochem. Soc. 166 (2019) A1291-A1299<\/i><\/em>.<\/p>\n<p>\u672c\u6587\u7531FAB\u4f9b\u7a3f\u3002<\/p>\n<p>\u672c\u5185\u5bb9\u4e3a\u4f5c\u8005\u72ec\u7acb\u89c2\u70b9\uff0c\u4e0d\u4ee3\u8868\u6750\u6599\u4eba\u7f51\u7acb\u573a\u3002<\/p>\n<p>\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u80cc\u666f\u4ecb\u7ecd\u3011 \u7531\u4e8e\u50a8\u80fd\u7cfb\u7edf\u5bf9\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u9502\u7535\u6c60\u7684\u9700\u6c42\u8fc5\u901f\u589e\u957f\uff0c\u5e76\u4e14\u5168\u7403\u9502\u50a8\u5907\u4e0d\u8db3\uff0c\u6709\u9650\u7684\u9502\uff08\u4f8b\u5982\u539a\u5ea6\u4e3a20\u03bcm\u6216\u66f4\u8584\uff09\u4f5c\u4e3a\u9633\u6781\u7684\u88c5\u7f6e\u4e3a\u9ad8\u5b89\u5168\u6027\u548c\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u9502\u91d1\u5c5e&#8230;<\/p>\n","protected":false},"author":11454,"featured_media":216803,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1187],"tags":[],"class_list":["post-216786","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zhuanlan"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/216786"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=216786"}],"version-history":[{"count":2,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/216786\/revisions"}],"predecessor-version":[{"id":216805,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/216786\/revisions\/216805"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/216803"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=216786"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=216786"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=216786"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}