{"id":217217,"date":"2021-02-15T06:46:54","date_gmt":"2021-02-14T22:46:54","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=217217"},"modified":"2021-02-14T22:28:19","modified_gmt":"2021-02-14T14:28:19","slug":"mofs%e6%88%90%e6%9e%9c%e9%a1%b6%e5%88%8a%e6%9c%80%e6%96%b0%e5%8a%a8%e6%80%81%e9%80%9f%e8%a7%88","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=217217","title":{"rendered":"MOFs\u6210\u679c\u9876\u520a\u6700\u65b0\u52a8\u6001\u901f\u89c8"},"content":{"rendered":"

MOFs\u662f\u8fd1\u5341\u5e74\u6765\u53d1\u5c55\u8fc5\u901f\u7684\u4e00\u79cd\u914d\u4f4d\u805a\u5408\u7269\uff0c\u5177\u6709\u4e09\u7ef4\u7684\u5b54\u7ed3\u6784\uff0c\u81ea\u7ec4\u88c5\u5f62\u6210\u5177\u6709\u5468\u671f\u6027\u7f51\u72b6\u9aa8\u67b6\u7684\u7ed3\u6784\uff0c\u6784\u6210\u7a7a\u95f43D\u5ef6\u4f38\uff0c\u7cfb\u6cb8\u77f3\u548c\u78b3\u7eb3\u7c73\u7ba1\u4e4b\u5916\u7684\u53c8\u4e00\u7c7b\u91cd\u8981\u7684\u65b0\u578b\u591a\u5b54\u6750\u6599\uff0c\u5728\u50ac\u5316\u3001\u50a8\u80fd\u548c\u5206\u79bb\u7b49\u7b49\u4e2d\u90fd\u6709\u5e7f\u6cdb\u5e94\u7528\u3002\u7b14\u8005\u5b9a\u671f\u68b3\u7406\u8fd1\u671f\u6750\u6599\u7c7b\u7cfb\u5217\u520a\u4e2dMOFs\u7684\u76f8\u5173\u6587\u7ae0\uff0c\u4e00\u8d77\u4e86\u89e3\u4e0b\u76f8\u5173\u7814\u7a76\uff01<\/p>\n

E<\/b><\/strong>ES<\/b><\/strong>\uff1a\u77f3\u58a8\u70ef\u7eb3\u7c73\u7247\u652f\u6491NiFe-MOF: \u9ad8\u6548\u8d85\u7a33\u5b9a\u7535\u6781\u7528\u4e8e\u53ef\u6301\u7eed\u78b1\u6027\u9634\u79bb\u5b50\u4ea4\u6362\u819c\u7535\u89e3\u6c34<\/b><\/strong><\/p>\n

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\u56fe1\u00a0NiFe-BTC-GNPs MOF\u57281M KOH\u6eb6\u6db2\u4e2d\u7684OER\u6027\u80fd<\/p>\n

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J<\/b><\/strong>ACS<\/b><\/strong>\uff1a\u4e3b<\/b><\/strong>\u5ba2\u4f53\u591a\u7ec4\u5206\u50ac\u5316\u4f53\u7cfb\u4e2d\u8bbe\u8ba1\u7b2c\u4e8c\u914d\u4f4d\u76f8\u4e92\u4f5c\u7528\u7528\u4e8e<\/b><\/strong>CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u52a0\u6c22\u5236\u7532\u9187<\/b><\/strong><\/p>\n

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\u56fe3\u00a0\u7b2c\u4e8c\u914d\u4f4d\u76f8\u4e92\u4f5c\u7528\u63d0\u9ad8\u50ac\u5316\u6027\u80fd\u7684\u50ac\u5316\u5242<\/p>\n

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A<\/b><\/strong>M<\/b><\/strong>\uff1a\u6676\u683c\u5339\u914d<\/b><\/strong>\u5bfc\u7535\u591a\u5b54MOF\/LDH\u5f02\u8d28\u7eb3\u7c73\u7ba1\u9635\u5217<\/b><\/strong>\u7528\u4e8e<\/b><\/strong>\u9ad8\u6548\u6c34\u6c27\u5316<\/b><\/strong><\/p>\n

MOFs\u7ed3\u5408\u5230\u4e0d\u540c\u7684\u591a\u7ec4\u5206\u6750\u6599\u4e2d\uff0c\u4ee5\u7cbe\u786e\u6784\u5efa\u5b9a\u5411\u5f02\u8d28\u7ed3\u6784\u662f\u4e00\u9879\u5f15\u4eba\u6ce8\u76ee\u7684\u7814\u7a76\uff0c\u4f46\u7531\u4e8e\u5176\u754c\u9762\u80fd\u548c\u6210\u6838\u52a8\u529b\u5b66\u7684\u4e0d\u540c\u800c\u96be\u4ee5\u5b9e\u73b0\u3002\u5728\u6b64\uff0c\u4e00\u79cd\u6709\u524d\u666f\u7684\u6676\u683c\u5339\u914d\u751f\u957f\u7b56\u7565\u88ab\u8bc1\u660e\uff1a\u5bfc\u7535MOF\/\u5c42\u72b6\u53cc\u6c22\u6c27\u5316\u7269(cMOF\/LDH)\u5f02\u8d28\u7eb3\u7c73\u7ba1\u9635\u5217\u5177\u6709\u9ad8\u5ea6\u6709\u5e8f\u7684\u5206\u7ea7\u591a\u5b54\u7ed3\u6784\uff0c\u80fd\u591f\u5b9e\u73b0\u8d85\u9ad8\u6548\u7684\u6790\u6c27\u53cd\u5e94(OER)\u3002\u9655\u897f\u5e08\u8303\u5927\u5b66Quanguo Zhai\u6559\u6388\u8054\u5408\u65b0\u5357\u5a01\u5c14\u58eb\u5927\u5b66Chuan Zhao\u6559\u6388\u5229\u7528CoNiFe-LDH\u7eb3\u7c73\u7ebf\u4f5c\u4e3a\u5185\u90e8\u6a21\u677f\uff0c\u901a\u8fc7\u9576\u5d4ccMOF\u548c\u5339\u914d\u4e24\u4e2a\u6676\u683c\u4f53\u7cfb\u6765\u8bbe\u8ba1\u754c\u9762\uff0c\u4ece\u800c\u5728LDH\u7eb3\u7c73\u7ebf\u4e0a\u63a5\u679dcMOF\/LDH\u5f02\u8d28\u7ed3\u6784\u3002\u901a\u8fc7\u4e0d\u65ad\u8c03\u8282\u76f8\u53d8\u7a0b\u5ea6\uff0c\u5236\u5907\u51fa\u4e86\u4e00\u7c7b\u5206\u5c42\u591a\u5b54cMOF\/LDH\u5f02\u8d28\u7eb3\u7c73\u7ba1\u9635\u5217\u3002cMOF\u548cLDH\u7ec4\u5206\u7684\u534f\u540c\u6548\u5e94\u663e\u8457\u63d0\u9ad8\u4e86\u5f02\u8d28\u7eb3\u7c73\u7ba1\u9635\u5217\u7684\u5316\u5b66\u7ed3\u6784\u548c\u7535\u5b50\u7ed3\u6784\u53ca\u5176\u7535\u6d3b\u6027\u8868\u9762\u79ef\u3002\u4f18\u5316\u540e\u7684\u5f02\u8d28\u7eb3\u7c73\u7ba1\u9635\u5217\u8868\u73b0\u51fa\u975e\u51e1\u7684OER\u6d3b\u6027\uff0c\u5176\u8d85\u4f4e\u8fc7\u7535\u538b\u5206\u522b\u4e3a216\u548c227 mV\uff0c\u7535\u6d41\u5bc6\u5ea6\u5206\u522b\u4e3a50\u548c100 mA cm\u22122<\/sup>\uff0cTafel\u659c\u7387\u4e3a34.1 mV dec\u22121<\/sup>\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cLattice Matching Growth of Conductive Hierarchical\u00a0Porous MOF\/LDH Heteronanotube Arrays for Highly\u00a0Efficient Water Oxidation\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728AM\u4e0a\u3002DOI: 10.1002\/adma.202006351<\/p>\n

\u56fe4\u00a0MOF\/LDH\u5f02\u8d28\u7eb3\u7c73\u7ba1\u7ed3\u6784\u7684\u6784\u9020\u673a\u7406<\/p>\n

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A<\/b><\/strong>ngew<\/b><\/strong>.<\/b><\/strong>\uff1aM<\/b><\/strong>OF\u652f\u6491\u7684\u5206\u5b50\u7535\u50ac\u5316\u6c27\u8fd8\u539f\u53cd\u5e94<\/b><\/strong><\/p>\n

\u5408\u6210\u5206\u5b50\u652f\u6491\u7684\u590d\u5408\u6750\u6599\u662f\u63d0\u9ad8\u5206\u5b50\u7535\u50ac\u5316\u7684\u4e00\u79cd\u9014\u5f84\uff0c\u9655\u897f\u5e08\u8303\u5927\u5b66Rui Cao\u6559\u6388\u62a5\u9053\u4e86MOF\u652f\u6491\u7684Co\u535f\u5549\u5316\u5408\u7269\u6765\u63d0\u9ad8\u6c27\u8fd8\u539f\u53cd\u5e94(ORR)\u7684\u6d3b\u6027\u548c\u9009\u62e9\u6027\u3002Co\u535f\u5549\u53ef\u4ee5\u901a\u8fc7\u914d\u4f53\u4ea4\u6362\u5728MOF\u8868\u9762\u4e0a\u63a5\u679d\u3002\u5229\u7528\u8be5\u65b9\u6cd5\u5236\u5907\u4e86\u535f\u5549@MOF\u6742\u5316\u4f53\u3002\u63a5\u679d\u4e0e\u672a\u63a5\u679d\u535f\u5549\u76f8\u6bd4\uff0cCo\u535f\u5549\u7684ORR\u6d3b\u6027\u589e\u5f3a\uff0c\u5176\u534a\u6ce2\u7535\u4f4d\u6709\u8f83\u5927\u7684\u9633\u6781\u504f\u79fb(> 70 mV)\u3002\u4f7f\u7528\u6d3b\u6027MOFs\u8fdb\u884c\u8fc7\u6c27\u5316\u7269\u8fd8\u539f\uff0c\u6bcfO2<\/sub>\u8f6c\u79fb\u7684\u7535\u5b50\u6570\u4ece2.65\u589e\u52a0\u52303.70\uff0c\u5bf94e ORR\u7684\u9009\u62e9\u6027\u663e\u8457\u63d0\u9ad8\u3002\u7ed3\u679c\u8868\u660e\uff0cCo\u535f\u5549\u4e2dO2<\/sub>\u8fd8\u539f\u751f\u6210\u7684H2<\/sub>O2<\/sub>\u5728MOF\u8868\u9762\u8fdb\u4e00\u6b65\u88ab\u8fd8\u539f\u3002\u4f5c\u4e3a\u4e00\u4e2a\u5b9e\u8df5\u8bc1\u660e\uff0c\u8fd9\u4e9b\u6df7\u5408\u6750\u6599\u88ab\u7528\u4f5c\u950c-\u7a7a\u6c14\u7535\u6c60\u7684\u7a7a\u6c14\u7535\u6781\u50ac\u5316\u5242\uff0c\u5176\u6027\u80fd\u4e0ePt\u57fa\u6750\u6599\u76f8\u5f53\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cMetal-Organic Framework-Supported Molecular Electrocatalysis\u00a0for the Oxygen Reduction Reaction\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Angew.\u4e0a\u3002DOI: 10.1002\/anie.202016024<\/p>\n

\u56fe5\u00a0\u5206\u5b50\u50ac\u5316\u5242\u8f6c\u5316\u4e3a\u591a\u76f8\u50ac\u5316\u5242<\/p>\n

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Nature Commun<\/b><\/strong>.\uff1a<\/b><\/strong>MOF-in-COF\u5206\u5b50\u7b5b\u819c\u7528\u4e8e\u9009\u62e9\u6027\u6c22\u5206\u79bb<\/b><\/strong><\/p>\n

\u5171\u4ef7\u6709\u673a\u6846\u67b6(COFs)\u662f\u4e00\u79cd\u5f88\u6709\u524d\u9014\u7684\u65b0\u578b\u5206\u5b50\u5206\u79bb\u819c\u6750\u6599\uff0c\u4f46\u5176\u5bbd\u7eb3\u7c73\u5b54\u963b\u788d\u4e86\u5206\u5b50\u7b5b\u5206\u7684\u9009\u62e9\u6027\u6c14\u4f53\u5206\u79bb\u3002\u5728\u6b64\uff0c\u5fb7\u56fd\u6c49\u8bfa\u5a01\u5927\u5b66J\u00fcrgen Caro\uff0c\u5317\u4eac\u5316\u5de5\u5927\u5b66\u5b5f\u6d2a\u6559\u6388\u7b49\u4eba\u63d0\u51fa\u4e86\u4e00\u4e2aMOF-in-COF\u7684\u6982\u5ff5\uff0c\u5728\u4e00\u4e2a\u652f\u6491\u7684COF\u5c42\u5185\u7ea6\u675f\u751f\u957f\u91d1\u5c5e\u6709\u673a\u6846\u67b6(MOFs)\uff0c\u4ee5\u5236\u5907MOF-in-COF\u819c\u3002\u8fd9\u4e9b\u819c\u5177\u6709\u72ec\u7279\u7684MOF-in-COF\u5fae\/\u7eb3\u7c73\u5b54\u7f51\u7edc\uff0c\u8fd9\u53ef\u80fd\u662f\u7531\u4e8e\u57282D COF\u7684\u4e00\u7ef4\u901a\u9053\u4e2d\uff0cMOF\u5f62\u6210\u4e86\u73cd\u73e0\u4e32\u72b6\u7684\u5355\u5143\u94fe\u3002MOF-in-COF\u819c\u5177\u6709\u826f\u597d\u7684\u6c22\u6c14\u900f\u8fc7\u6027(>3000 GPU)\uff0c\u540c\u65f6\u663e\u8457\u63d0\u9ad8\u4e86\u6c22\u5bf9\u5176\u4ed6\u6c14\u4f53\u7684\u5206\u79bb\u9009\u62e9\u6027\u3002H2\/CO2\u548cH2\/CH4\u4f18\u5f02\u7684\u5206\u79bb\u6027\u80fd\u8d85\u8fc7\u4e86Robeson\u4e0a\u9650\uff0c\u5f97\u76ca\u4e8e\u901a\u8fc7MOF-in-COF\u901a\u9053\u7684\u7cbe\u786e\u5c3a\u5bf8\u7b5b\u9009\u548c\u5feb\u901f\u5206\u5b50\u4f20\u8f93\u7684\u534f\u540c\u4f5c\u7528\u3002\u5728MOF-in-COF\u819c\u4e2d\u8fdb\u884c\u4e86\u4e0d\u540c\u7684MOF\u548cCOF\u7ec4\u5408\uff0c\u8bc1\u660e\u4e86\u8bbe\u8ba1\u7b56\u7565\u7684\u591a\u529f\u80fd\u6027\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cMOF-in-COF molecular sieving membrane for\u00a0selective hydrogen separation\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature\u00a0Commun.\u4e0a\u3002DOI: 10.1038\/s41467-020-20298-7<\/p>\n

\u56fe6\u00a0MOF-in-COF\u819c\u7684\u5236\u5907\u53ca\u8868\u5f81<\/p>\n

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N<\/b><\/strong>a<\/b><\/strong>ture<\/b><\/strong>\u00a0Commun<\/b><\/strong>.\uff1a<\/b><\/strong>\u5229\u7528<\/b><\/strong>M<\/b><\/strong>OF\u4ece\u78b3\u6c22\u5316\u5408\u7269\u4e2d\u9009\u62e9\u6027\u6355\u83b7\u4e8c\u6c27\u5316\u78b3<\/b><\/strong><\/p>\n

\u9ad8\u6548\u548c\u53ef\u6301\u7eed\u7684\u4e8c\u6c27\u5316\u78b3\u6355\u83b7\u65b9\u6cd5\u662f\u975e\u5e38\u6709\u7528\u7684\u3002\u6210\u719f\u7684\u6280\u672f\u5305\u62ec\u5438\u6536\u4e8c\u6c27\u5316\u78b3\u7684\u5316\u5b66\u53cd\u5e94\uff0c\u4f46\u5b83\u4eec\u6709\u8bb8\u591a\u7f3a\u70b9\u3002\u91c7\u7528\u5b54\u9699\u7a7a\u95f4\u5927\u5c0f\u548c\u9759\u7535\u52bf\u4e0e\u5206\u5b50CO2<\/sub>\u4e92\u8865\u7684\u591a\u5b54\u7269\u7406\u5438\u9644\u5242\u6355\u83b7CO2<\/sub>\uff0c\u662f\u6709\u5e0c\u671b\u7684\u8282\u80fd\u66ff\u4ee3\u65b9\u6848\u3002\u5728\u8fd9\u91cc\uff0c\u65b0\u897f\u5170\u6885\u897f\u5927\u5b66Shane G. Telfer\u6559\u6388\u7b49\u63d0\u51fa\u4e86\u4e00\u79cd\u8010\u7528\u3001\u53ef\u56de\u6536\u7684\u3001\u5ec9\u4ef7\u7684\u5438\u9644\u5242MUF-16\u3002\u901a\u8fc7\u5438\u9644\u7b49\u6e29\u7ebf\u3001X\u5c04\u7ebf\u6676\u4f53\u5b66\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\uff0c\u8fd9\u79cdMOF\u5728\u5176\u4e00\u7ef4\u901a\u9053\u4e2d\u4ee5\u9ad8\u4eb2\u548c\u529b\u6355\u83b7\u4e8c\u6c27\u5316\u78b3\u3002\u5bf9\u5176\u5b83\u7ade\u4e89\u6027\u6c14\u4f53\u7532\u70f7\uff0c\u4e59\u7094\uff0c\u4e59\u70ef\uff0c\u4e59\u70f7\uff0c\u4e19\u70ef\u548c\u4e19\u70f7\u5177\u6709\u4f4e\u4eb2\u548c\u529b\uff0c\u56e0\u6b64\u5177\u6709\u9ad8\u7684CO2<\/sub>\u5438\u9644\u9009\u62e9\u6027\u3002\u5b9e\u9a8c\u8868\u660e\uff0c\u5bf9CO2<\/sub>\/CH4<\/sub>\u548cCO2<\/sub>\/C2<\/sub>H2<\/sub>\u7684\u7b49\u6469\u5c14\u6df7\u5408\u7269\u9009\u62e9\u6027\u5206\u522b\u4e3a6690\u548c510\u3002\u52a8\u6001\u6761\u4ef6\u4e0b\u7684\u7a81\u7834\u6027\u6c14\u4f53\u5206\u79bb\u5f97\u76ca\u4e8e\u5f31\u5438\u9644\u7ec4\u5206\u6d17\u8131\u7684\u77ed\u65f6\u95f4\u6ede\u540e\uff0c\u4ece\u800c\u63d0\u4f9b\u9ad8\u7eaf\u70c3\u4ea7\u54c1\uff0c\u5305\u62ec\u7eaf\u7532\u70f7\u548c\u4e59\u7094\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cSelective capture of carbon dioxide from\u00a0hydrocarbons using a metal-organic framework\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature Commun.\u4e0a\u3002DOI: 10.1038\/s41467-020-20489-2<\/p>\n

\u56fe7\u00a0MUF-16\u6750\u6599\u7684\u5408\u6210\u4e0e\u7ed3\u6784<\/p>\n

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An<\/b><\/strong>gew<\/b><\/strong>.\uff1a<\/b><\/strong>\u5177\u6709\u589e\u5f3a\u7535\u5bfc\u7387<\/b><\/strong>\u7684<\/b><\/strong>\u8d85\u7a33\u5b9aM-MOFs (M =Co, Ni)\u9ad8\u6027\u80fd\u8d85\u7ea7\u7535\u5bb9\u5668<\/b><\/strong><\/p>\n

\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u6750\u6599\u7531\u4e8e\u5176\u5316\u5b66\u7a33\u5b9a\u6027\u5dee\u3001\u7535\u89e3\u8d28\u5bfc\u7535\u6027\u5dee\u800c\u6210\u4e3a\u4e00\u79cd\u5177\u6709\u6311\u6218\u6027\u7684\u80fd\u91cf\u50a8\u5b58\/\u8f6c\u6362\u7535\u6781\u3002\u5728\u8fd9\u91cc\uff0c\u897f\u5317\u5927\u5b66Jun Hu\u3001Zhengqiang Xia\u6559\u6388\u901a\u8fc7\u4f18\u5316\u7684Co\/Ni\u6bd4\u3001MOF\u5c3a\u5bf8\u548c\u914d\u4f53\u7684\u5171\u8f6d\u5ea6\u76f8\u7ed3\u5408\u7684\u65b9\u6cd5\u5236\u5907\u7eb3\u7c73\u5c3a\u5ea6\u7684MOF, Co0.24<\/sub>Ni0.76<\/sub>-bpa-200\uff0c\u5177\u6709\u8d85\u9ad8\u7684\u7a33\u5b9a\u6027\u548c\u7f55\u89c1\u7684\u534a\u5bfc\u4f53\u884c\u4e3a(\u03c3 = 4.2 \u00d710-3<\/sup>\u00a0S m-1<\/sup>)\u3002DFT\u7814\u7a76\u8868\u660e\uff0c\u9002\u5f53\u7684Ni2+<\/sup>\u63ba\u6742\u964d\u4f4e\u4e86\u4f53\u7cfb\u7684\u6d3b\u5316\u80fd\uff0c\u4ece\u800c\u4ea7\u751f\u66f4\u9ad8\u7684\u8f7d\u6d41\u5b50\u6d53\u5ea6\uff0c\u5f3a\u79bb\u57df\u7684N\u7ed9\u4f53\u914d\u4f53\u663e\u8457\u589e\u52a0\u4e86\u91d1\u5c5e-\u914d\u4f53\u8f68\u9053\u7684\u91cd\u53e0\u4ee5\u5b9e\u73b0\u6709\u6548\u7684\u7535\u8377\u8fc1\u79fb\uff0c\u5bfc\u81f4\u8fde\u7eed\u7684\u901a\u952e(-CoNi-N-CoNi-)\u221e<\/sub>\u4f20\u5bfc\u8def\u5f84\u3002\u8be5\u7ed3\u6784\u7279\u5f81\u4f7fMOF\u5728\u539f\u59cbMOF\u57fa\u7535\u6781\u4e2d\u5177\u670986.5%(10000\u6b21\u5faa\u73af)\u7684\u826f\u597d\u5faa\u73af\u7a33\u5b9a\u6027\u548c1927.14 F g-1<\/sup>\u7684\u9ad8\u6bd4\u7535\u5bb9\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cTailoring electronic structure and size of ultrastable M-MOFs (M =Co, Ni) with enhanced electroconductivity for high-performance\u00a0supercapacitor\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Angew.\u4e0a\u3002DOI: 10.1002\/anie.202100123<\/p>\n

\u56fe8\u00a0\u9010\u6b65\u88c1\u526a\u5143\u4ef6\u7684\u7535\u5b50\u7ed3\u6784\u5408\u6210\u9ad8\u6027\u80fdMOF\u57fa\u7535\u6781\u7684\u539f\u7406\u56fe<\/p>\n

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\u672c\u6587\u7531Junas\u4f9b\u7a3f\u3002<\/p>\n

\u672c\u5185\u5bb9\u4e3a\u4f5c\u8005\u72ec\u7acb\u89c2\u70b9\uff0c\u4e0d\u4ee3\u8868\u6750\u6599\u4eba\u7f51\u7acb\u573a\u3002<\/p>\n

\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n

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