{"id":217260,"date":"2021-02-05T12:00:12","date_gmt":"2021-02-05T04:00:12","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=217260"},"modified":"2021-02-05T09:56:48","modified_gmt":"2021-02-05T01:56:48","slug":"%e7%a2%b3%e9%98%b3%e6%9e%81%e6%9d%90%e6%96%99%ef%bc%9a%e9%92%a0%e7%a6%bb%e5%ad%90%e7%94%b5%e6%b1%a0%e5%92%8c%e9%92%be%e7%a6%bb%e5%ad%90%e7%94%b5%e6%b1%a0%e7%9a%84%e8%af%a6%e7%bb%86%e6%af%94%e8%be%83","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=217260","title":{"rendered":"\u78b3\u9633\u6781\u6750\u6599\uff1a\u94a0\u79bb\u5b50\u7535\u6c60\u548c\u94be\u79bb\u5b50\u7535\u6c60\u7684\u8be6\u7ec6\u6bd4\u8f83"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/b><\/strong><\/p>\n

\u4f5c\u4e3a\u65b0\u578b\u7684\u201c\u540e\u9502\u79bb\u5b50\u7535\u6c60\u201d\uff0c\u94a0\u79bb\u5b50\u7535\u6c60\/\u94be\u79bb\u5b50\u7535\u6c60\uff08SIBs\/PIBs\uff09\u7531\u4e8e\u5176\u4e30\u5bcc\u7684Na\/K\u8d44\u6e90\u800c\u5728\u5927\u89c4\u6a21\u50a8\u80fd\u5e94\u7528\u4e2d\u663e\u793a\u51fa\u5e7f\u9614\u7684\u5e94\u7528\u524d\u666f\u3002\u7814\u7a76\u7ed3\u679c\u8868\u660e\uff0c\u78b3\u9633\u6781\u6750\u6599\u662fSIBs\u548cPIBs\u7684\u6709\u6548\u7684\u5019\u9009\u6750\u6599\u3002\u5c3d\u7ba1\u4e24\u79cd\u78b1\u6027\u79bb\u5b50\u7535\u6c60\u5177\u6709\u76f8\u4f3c\u7684\u5185\u90e8\u6210\u5206\u548c\u7535\u5316\u5b66\u53cd\u5e94\u673a\u7406\uff0c\u4f46\u5728\u78b3\u9633\u6781\u6750\u6599\u4e2d\uff0cNa+<\/sup>\u548cK+<\/sup>\u7684\u5b58\u50a8\/\u91ca\u653e\u884c\u4e3a\u5e76\u4e0d\u5b8c\u5168\u76f8\u540c\u3002\u56e0\u6b64\uff0c\u7f3a\u4e4f\u5bf9\u78b3\u9633\u6781\u6750\u6599\u4e2dNa+<\/sup>\/K+<\/sup>\u50a8\u5b58\u884c\u4e3a\u7684\u5168\u9762\u6bd4\u8f83\u3002\u4e3a\u4e86\u66f4\u6e05\u695a\u5730\u4e86\u89e3\u8fd9\u4e9b\u673a\u5236\u4ee5\u83b7\u5f97\u7406\u60f3\u7684\u6027\u80fd\uff0c\u5728\u8fd9\u7bc7\u6587\u7ae0\u4e2d\uff0c\u65e8\u5728\u4ecb\u7ecd\u4e09\u79cd\u6f5c\u5728\u7684Na+<\/sup>\/K+<\/sup>\u50a8\u5b58\/\u91ca\u653e\u884c\u4e3a\uff0c\u5373\uff081\uff09\u5d4c\u5165\/\u8131\u5d4c\u673a\u5236\uff0c\uff082\uff09\u5438\u9644\/\u89e3\u5438\u673a\u5236\u548c\uff083\uff09\u5b54\u586b\u5145\u673a\u5236\u3002\u53e6\u5916\u603b\u7ed3\u4e86\u78b3\u9633\u6781\u6750\u6599\uff08\u77f3\u58a8\uff0c\u77f3\u58a8\u70ef\uff0c\u786c\u78b3\u548c\u8f6f\u78b3\uff09\u7684\u53d1\u5c55\u72b6\u51b5\uff0c\u5e76\u5bf9SIBs\u548cPIBs\u4e4b\u95f4\u7684\u8fdb\u884c\u5168\u9762\u6bd4\u8f83\u3002<\/p>\n

\u3010\u56fe\u6587\u89e3\u6790\u3011<\/b><\/strong><\/p>\n

1\u3001<\/b><\/strong>SIBs\u548cPIBs<\/b><\/strong>\u7684\u5e94\u7528<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe1. SIBs\u548cPIBs\u6f5c\u5728\u5e94\u7528\u7684\u793a\u610f\u56fe<\/p>\n

\u203bAdv. Energy Mater. 2021, 2003640<\/i><\/u><\/em><\/a><\/p>\n

\u4e3a\u4e86\u5145\u5206\u8c03\u8282\u548c\u5229\u7528\u95f4\u6b47\u6027\u80fd\u6e90\uff08\u592a\u9633\u80fd\uff0c\u98ce\u80fd\uff0c\u751f\u7269\u8d28\u80fd\uff0c\u5730\u70ed\uff0c\u6c34\u7b49\uff09\uff0c\u5f00\u53d1\u9ad8\u6027\u80fd\u78b1\u79bb\u5b50\u7535\u6c60\u53d8\u5f97\u8d8a\u6765\u8d8a\u7d27\u8feb\u3002\u9502\u79bb\u5b50\u7535\u6c60\uff08LIBs\uff09\u662f\u78b1\u6027\u79bb\u5b50\u7535\u6c60\u4e2d\u6700\u6210\u719f\u7684\u7535\u6c60\u7cfb\u7edf\uff0c\u5e76\u4e14\u7531\u4e8e\u6700\u4f4e\u7684\u6807\u51c6\u7535\u6781\u7535\u4f4d\uff08Li+<\/sup>\/Li\u4e3a-3.04 V\uff0cNa+<\/sup>\/Na\u4e3a-2.71 V\uff0cK+<\/sup>\/K\u4e3a-2.93 V\uff09\u800c\u88ab\u516c\u8ba4\u4e3a\u7406\u60f3\u7684\u9ad8\u538b\u7535\u6c60\uff0c\u8fd9\u4f7f\u9502\u79bb\u5b50\u7535\u6c60\u5177\u6709\u8f83\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002\u4f46\u662f\uff0c\u6709\u9650\u7684\u9502\u8d44\u6e90\u548c\u4e0d\u5747\u5300\u7684\u9502\u5206\u5e03\u4f7f\u5176\u96be\u4ee5\u6ee1\u8db3\u4f4e\u6210\u672c\uff0c\u9ad8\u6027\u80fd\u7684\u5927\u578b\u50a8\u80fd\u8bbe\u5907\u7684\u9700\u6c42\u3002\u8fd1\u5e74\u6765\uff0c\u7531\u4e8e\u94a0\/\u94be\u4e30\u5bcc\u5ea6\u9ad8\uff0c\u5206\u5e03\u5747\u5300\uff0cSIBs\u548cPIBs\u6210\u672c\u4f4e\u7b49\u660e\u663e\u4f18\u52bf\uff0c\u5b83\u4eec\u6210\u4e3a\u4e86\u5927\u4f17\u5173\u6ce8\u7684\u5bf9\u8c61\uff0c\u8fd9\u4e9b\u4f18\u70b9\u662f\u5927\u578b\u5b58\u50a8\u7cfb\u7edf\u4e2d\u9ad8\u6027\u80fd\u4e8c\u6b21\u7535\u6c60\u7684\u7406\u60f3\u9009\u62e9\u7684\u91cd\u70b9\u3002<\/p>\n

2\u3001<\/b><\/strong>Na<\/b><\/strong>+<\/b><\/sup><\/strong>\/K<\/b><\/strong>+<\/b><\/sup><\/strong>\u7684\u5b58\u50a8\u673a\u7406<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe2. \u78b3\u9633\u6781\u6750\u6599\u4e2dNa+<\/sup>\/K+<\/sup>\u7684\u5b58\u50a8\u673a\u7406<\/p>\n

\u203bAdv. Energy Mater. 2021, 2003640<\/i><\/u><\/em><\/a><\/p>\n

\u901a\u5e38\uff0cNa+<\/sup>\/K+<\/sup>\u6709\u4e09\u79cd\u79bb\u5b50\u5b58\u50a8\u6a21\u5f0f\uff0c\u5206\u522b\u5982\u4e0b\uff1a<\/p>\n

\uff081\uff09\u5d4c\u5165<\/b><\/strong>\/\u8131\u5d4c\u673a\u5236<\/b><\/strong>\uff1a<\/b><\/strong>\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\uff0cNa+<\/sup>\/K+<\/sup>\u4ece\u78b3\u6750\u6599\u7684\u4e2d\u95f4\u5c42\u4e2d\u5d4c\u5165\/\u8131\u5d4c\uff0c\u79bb\u5b50\u7684\u5b58\u50a8\u80fd\u529b\u53d6\u51b3\u4e8e\u79bb\u5b50\u534a\u5f84\uff0c\u4e2d\u95f4\u5c42\u7684\u7ed3\u6784\u4ee5\u53caNa\/K-\u5316\u5408\u7269\u7684\u70ed\u529b\u5b66\u7a33\u5b9a\u6027\u3002<\/p>\n

\uff082\uff09\u5438\u9644<\/b><\/strong>\/\u89e3\u5438\u673a\u5236<\/b><\/strong>\uff1a<\/b><\/strong>\u901a\u5e38\uff0c\u6742\u539f\u5b50\uff0c\u8fb9\u7f18\u548c\u7f3a\u9677\u90e8\u4f4d\u4e0a\u7684\u79bb\u5b50\u5438\u9644\u88ab\u8ba4\u4e3a\u662f\u5438\u9644\u673a\u7406\u3002Na+<\/sup>\/K+<\/sup>\u5438\u9644\u5728\u78b3\u9633\u6781\u7684\u8868\u9762\u6216\u8fd1\u8868\u9762\u4e0a\uff0c\u56e0\u6b64\u5b58\u50a8\u5bb9\u91cf\u53d6\u51b3\u4e8e\u78b3\u6750\u6599\u7684\u6bd4\u8868\u9762\u79ef\u548c\u5438\u9644\u6d3b\u6027\u4f4d\u70b9\uff08\u6742\u539f\u5b50\uff0c\u8fb9\u7f18\u548c\u7f3a\u9677\u4f4d\u70b9\uff09\u3002<\/p>\n

\uff083\uff09\u586b\u5145\u673a\u5236\uff1a<\/b><\/strong>\u5bf9\u4e8e\u5177\u6709\u5927\u91cf\u5b54\u9699\u7684\u78b3\u6750\u6599\uff0cNa+<\/sup>\/K+<\/sup>\u53ef\u4ee5\u586b\u5145\u5b54\u9699\u4ee5\u5b9e\u73b0\u79bb\u5b50\u5b58\u50a8\u3002<\/p>\n

3\u3001\u78b3\u9633\u6781\u6750\u6599\u4e2d<\/b><\/strong>Na<\/b><\/strong>+<\/b><\/sup><\/strong>\/K<\/b><\/strong>+<\/b><\/sup><\/strong>\u7684\u50a8\u5b58\u884c\u4e3a<\/b><\/strong><\/p>\n

3.1\u3001\u77f3\u58a8<\/p>\n

3.1.1\u3001Na+<\/sup>\u7684\u50a8\u5b58\u884c\u4e3a<\/p>\n

\u5c3d\u7ba1SIBs\u7684\u5145\u7535\/\u653e\u7535\u673a\u7406\u4e0eLIBs\u76f8\u4f3c\uff0c\u4f46Na+<\/sup>\u663e\u793a\u51fa\u5b8c\u5168\u4e0d\u540c\u7684\u77f3\u58a8\u9633\u6781\u5b58\u50a8\u884c\u4e3a\u3002\u7531\u4e8eNa+<\/sup>\u534a\u5f84\u5927\uff0c\u7535\u79bb\u52bf\u9ad8\u4ee5\u53ca\u4f38\u5c55\u7684C-C\u952e\u957f\u53d8\u5316\u5927\uff0c\u56e0\u6b64Na+<\/sup>\u5f88\u96be\u63d2\u5165\u4e2d\u95f4\u5c42\u5f62\u6210\u7a33\u5b9a\u7684Na-C\u5316\u5408\u7269\u3002<\/p>\n

\u65e9\u57282015\u5e74\uff0c\u56fd\u7acb\u9996\u5c14\u5927\u5b66<\/b><\/strong>Kisuk Kang<\/b><\/strong>\u6559\u6388<\/b><\/strong>\u62a5\u9053\u4e86\u5728\u4e0d\u540c\u7535\u89e3\u8d28\uff08NaPF<\/b><\/strong>6<\/b><\/sub><\/strong>-EC\/DEC\uff0cNaPF<\/b><\/strong>6<\/b><\/sub><\/strong>-DMC\u548cNaPF<\/b><\/strong>6<\/b><\/sub><\/strong>-DEGDME\uff09<\/b><\/strong>\u7684\u77f3\u58a8\u4e2dNa+<\/sup>\u7684\u50a8\u5b58\u884c\u4e3a\uff0c\u63ed\u793a\u4e86Na+<\/sup>\u5728\u78b3\u9178\u76d0\u57fa\u7535\u89e3\u8d28\u4e2d\u7684\u7535\u5316\u5b66\u6d3b\u6027\u4e0d\u9ad8\u3002\u4f46\u662f\u5728\u6709\u919a\u57fa\u7535\u89e3\u8d28\u7684\u60c5\u51b5\u4e0b\uff0c\u77f3\u58a8\u9633\u6781\u57282500\u6b21\u5faa\u73af\u4e2d\u663e\u793a\u51fa\u4f18\u5f02\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u5e76\u63ed\u793a\u4e86Na+<\/sup>\u6eb6\u5242\u5171\u5d4c\u5165\u673a\u7406\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3.\u00a0Na+<\/sup>\u5728\u4e0d\u540c\u7535\u89e3\u8d28\u7684\u77f3\u58a8\u4e2d\u7684\u5b58\u50a8\u884c\u4e3a<\/p>\n

\u203bAdv. Funct. Mater. 25 (2015) 534\u2013541<\/i><\/u><\/em><\/a><\/p>\n

\u968f\u540e\u57282017\u5e74\uff0cKisuk Kang\u6559\u6388<\/b><\/strong>\u901a\u8fc7\u5bf9\u78b1\u91d1\u5c5e\uff08AM=Li\uff0cNa\uff0cK\uff0cRb\uff0cCs\uff09-\u77f3\u58a8\u63d2\u5c42\u5316\u5408\u7269\u7684\u7cfb\u7edf\u7814\u7a76\uff0c\u8bc1\u660e\u4e86\u4e0d\u826f\u7684Na-\u77f3\u58a8\u76f8\u4e92\u4f5c\u7528\u4f1a\u5bfc\u81f4\u4e0d\u7a33\u5b9a\u7684\u94a0-\u77f3\u58a8\u63d2\u5c42\u5316\u5408\u7269\uff08Na-GICs\uff09\u751f\u6210\u3002\u7ed3\u679c\u8868\u660e\uff0c[Na-\u7ebf\u6027<\/b><\/strong>–<\/b><\/strong>\u919a]<\/b><\/strong>+<\/b><\/sup><\/strong>\u53ef\u4ee5\u63d2\u5165\u5230\u77f3\u58a8\u9633\u6781\u4e2d\uff0c\u56e0\u4e3a\u5176\u9ad8\u7684Na-\u6eb6\u5242\u5316\u80fd\u548c\u6700\u4f4e\u7684LUMO\u4fc3\u4f7fNa-\u6eb6\u5242\u5316\u5408\u7269\u4fdd\u6301\u7a33\u5b9a\u5e76\u9632\u6b62\u5316\u5408\u7269\u5206\u89e3\u3002<\/b><\/strong>\u56e0\u6b64\uff0cNa+<\/sup>\u53ef\u4ee5\u4ee5\u5171\u63d2\u5165\u7684\u5f62\u5f0f\u63d2\u5165\u77f3\u58a8\u5939\u5c42\u4e2d\u4ee5\u5f62\u6210\u7a33\u5b9a\u7684Na-GICs\uff0c\u5e76\u4e14\u53ef\u4ee5\u6709\u6548\u6539\u5584\u77f3\u58a8\u9633\u6781\u7684Na+<\/sup>\u50a8\u5b58\u5bb9\u91cf\uff0c\u500d\u7387\u6027\u80fd\u548c\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n

\"\"<\/p>\n

\u56fe4. AM-GICs\u7684\u5f62\u6210\u80fd\u503c\u53ca\u5176\u5f71\u54cd\u56e0\u7d20<\/p>\n

\u203bAdv. Energy Mater. 7 <\/i><\/u><\/em>(<\/i><\/u><\/em>2017) 1601519<\/i><\/u><\/em><\/a><\/p>\n

\"\"<\/p>\n

\u56fe5. Na-\u6eb6\u5242\u5171\u5d4c\u5165\u884c\u4e3a<\/p>\n

\u203bAdv. Energy Mater. 7 <\/i><\/u><\/em>(<\/i><\/u><\/em>2017) 1601519<\/i><\/u><\/em><\/a><\/p>\n

3.1.2\u3001K+<\/sup>\u7684\u50a8\u5b58\u884c\u4e3a<\/p>\n

PIBs\u4e0eSIBs\u4e00\u6837\uff0c\u7531\u4e8eK+<\/sup>\u534a\u5f84\u5927\u4e14\u8fc1\u79fb\u7f13\u6162\uff0c\u56e0\u6b64K+<\/sup>\u4e5f\u5f88\u96be\u63d2\u5165\u77f3\u58a8\u4e2d\u95f4\u5c42\u5f62\u6210\u7a33\u5b9a\u7684K-C\u5316\u5408\u7269\uff08K-GICs\uff09\u3002<\/p>\n

2015\u5e74\uff0c\u4fc4\u52d2\u5188\u5dde\u7acb\u5927\u5b66\u7eaa\u79c0\u78ca<\/b><\/strong>\u6559\u6388<\/b><\/strong>\u9996\u6b21\u62a5\u9053\u4e86K<\/b><\/strong>+<\/b><\/sup><\/strong>\u53ef\u4ee5\u5d4c\u5165\u5177\u6709\u4f4e\u5de5\u4f5c\u7535\u52bf\u7684\u77f3\u58a8\u4e2d\uff0c\u4ece\u800c\u5f62\u6210\u4e00\u7cfb\u5217KC<\/b><\/strong>36<\/b><\/sub><\/strong>\uff0cKC<\/b><\/strong>24<\/b><\/sub><\/strong>\u548cKC<\/b><\/strong>8<\/b><\/sub><\/strong>\u7684K-GIC<\/b><\/strong>s<\/b><\/strong>\uff0c\u5145\u653e\u7535\u66f2\u7ebf\u548cXRD\u56fe\u8bc1\u5b9e\u4e86\u8fd9\u4e00\u70b9\uff0c\u5e76\u63d0\u4f9b\u4e86273 mAh g-1<\/sup>\u7684\u9ad8\u53ef\u9006\u5bb9\u91cf\u3002<\/p>\n

\"\"<\/p>\n

\u56fe6. K+<\/sup>\u5728\u77f3\u58a8\u4e2d\u7684\u50a8\u5b58\u884c\u4e3a<\/p>\n

\u203bJ. Am. Chem. Soc. 137<\/i><\/u><\/em>(<\/i><\/u><\/em>2015) 11566\u201311569<\/i><\/u><\/em><\/a><\/p>\n

2019\u5e74\uff0c\u6e56\u5357\u5927\u5b66\u5218\u7ee7\u78ca<\/b><\/strong>\u6559\u6388<\/b><\/strong>\u7ed3\u5408\u539f\u4f4dXRD\uff0c\u539f\u4f4d\u62c9\u66fc\u6620\u5c04\u548cDFT\u6a21\u62df\u8ba1\u7b97\uff0c\u63ed\u793a\u4e86\u77f3\u58a8\u6ce1\u6cab\u7684\u5b9e\u65f6K<\/b><\/strong>+<\/b><\/sup><\/strong>\u5d4c\u5165\/\u8131\u5d4c\u9636\u6bb5\uff1aC\u2194KC<\/b><\/strong>60<\/b><\/sub><\/strong>\u2194KC<\/b><\/strong>48<\/b><\/sub><\/strong>\u2194KC<\/b><\/strong>36<\/b><\/sub><\/strong>\u2194KC<\/b><\/strong>24<\/b><\/sub><\/strong>\/KC<\/b><\/strong>16<\/b><\/sub><\/strong>\u2194KC<\/b><\/strong>8<\/b><\/sub><\/strong>\uff0c\u5206\u9636\u6bb5\u8fc7\u6e21\u6e05\u6670\u53ef\u89c1\u3002<\/p>\n

\"\"<\/p>\n

\u56fe7. \u539f\u4f4dXRD\u8868\u5f81<\/p>\n

\u203bAdv. Energy Mater. 9 (2019) 1900579<\/i><\/u><\/em><\/a><\/p>\n

\"\"<\/p>\n

\u56fe8. \u539f\u4f4d\u62c9\u66fc\u8868\u5f81<\/p>\n

\u203bAdv. Energy Mater. 9 (2019) 1900579<\/i><\/u><\/em><\/a><\/p>\n

\"\"<\/p>\n

\u56fe9. \u7535\u8377\u5b58\u50a8\u673a\u5236<\/p>\n

\u203bAdv. Energy Mater. 9 (2019) 1900579<\/i><\/u><\/em><\/a><\/p>\n

3.2\u3001\u77f3\u58a8\u70ef<\/p>\n

\u81ea\u4ece\u53d1\u73b0\u548c\u5206\u79bb\u77f3\u58a8\u70ef\u4ee5\u6765\uff0c\u7531\u4e8e\u4f18\u5f02\u7684\u6750\u6599\u6027\u80fd\uff08\u5982\u8f83\u597d\u7684\u673a\u68b0\u5f3a\u5ea6\uff0c\u8f83\u9ad8\u7684\u7406\u8bba\u8868\u9762\u548c\u51fa\u8272\u7684\u7535\u5bfc\u7387\uff09\u800c\u8fd0\u7528\u4e8e\u80fd\u91cf\u5b58\u50a8\u9886\u57df\u3002\u7136\u800c\uff0c\u901a\u8fc7\u7406\u8bba\u8ba1\u7b97\uff0c\u539f\u59cb\u7684\u5355\u5c42\u77f3\u58a8\u70ef\u7684\u79bb\u5b50\u5438\u9644\u80fd\u529b\u5f88\u5dee\uff0c\u4e0d\u80fd\u76f4\u63a5\u7528\u4f5cSIBs\/PIBs\u9633\u6781\uff0c\u6240\u4ee5\u9700\u8981\u5f00\u53d1\u66f4\u591a\u7684\u77f3\u58a8\u70ef\u57fa\u7535\u6781\u5236\u5907\u7b56\u7565\uff0c\u4ee5\u5b9e\u73b0\u51fa\u8272\u7684Na+<\/sup>\/K+<\/sup>\u5b58\u50a8\u5bb9\u91cf\u548c\u4f20\u8f93\u52a8\u529b\u5b66\uff0c\u4f8b\u5982\u6676\u4f53\u63a7\u5236\uff08\u6742\u539f\u5b50\u63ba\u6742\uff0c\u8fb9\u7f18\uff0c\u7f3a\u9677\uff09\u548c\u5f62\u6001\u8bbe\u8ba1\u3002<\/b><\/strong><\/p>\n

\u8fd1\u5e74\u6765\uff0c\u77f3\u58a8\u70ef\u57fa\u9633\u6781\u5728SIBs\u4e2d\u7684\u5e94\u7528\u5907\u53d7\u5173\u6ce8\uff0c\u5e76\u4e14\u901a\u8fc7Na+<\/sup>\/K+<\/sup>\u5728\u8868\u9762\u7684\u201c\u5438\u9644\u201d\u63d0\u4f9b\u4e86\u76f8\u5f53\u5927\u7684\u5bb9\u91cf\u30022020\u5e74\uff0c\u4f5b\u7f57\u91cc\u8fbe\u5dde\u7acb\u5927\u5b66<\/b><\/strong>Jose L. Mendoza-Cortes<\/b><\/strong>\u6559\u6388<\/b><\/strong>\u6784\u5efa\u4e86\u56db\u5c42\u77f3\u58a8\u70ef\u6a21\u578b\u6765\u7814\u7a76\u91d1\u5c5e\uff08<\/b><\/strong>M = Li\uff0cNa\u548cK\uff09\u63d2\u5c42\u5316\u5b66\uff0c\u5e76\u63d0\u4f9b\u4e86\u4e24\u4e2aC<\/b><\/strong>6<\/b><\/sub><\/strong>M\u548cC<\/b><\/strong>8<\/b><\/sub><\/strong>M\u6a21\u578b<\/b><\/strong>\u3002<\/b><\/strong>\u8ba1\u7b97\u7ed3\u679c\u8868\u660e\uff0cNa+<\/sup>\u63d2\u5c42\u4e0d\u540c\u9636\u6bb5\u7684\u7ed3\u5408\u80fd\u660e\u663e\u9ad8\u4e8eK+<\/sup>\u63d2\u5c42\u7684\u7ed3\u5408\u80fd\uff0c\u8fd9\u8868\u660eNa+<\/sup>\u63d2\u5c42\u5728\u51e0\u5c42\u77f3\u58a8\u70ef\u4e2d\u7684\u70ed\u529b\u5b66\u4e0d\u7a33\u5b9a\u6027\u3002<\/p>\n

\"\"<\/p>\n

\u56fe10.\u00a0\u56db\u5c42\u77f3\u58a8\u70ef\u9633\u6781\u4e2d\u91d1\u5c5e\u63d2\u5c42\u5316\u5b66\u7684\u6a21\u578b<\/p>\n

\u203bACS Appl. Mater. Interfaces 12 (2020) 19393\u201319401<\/i><\/u><\/em><\/a><\/p>\n

\u5b9e\u9a8c\u548c\u8ba1\u7b97\u7814\u7a76\u8868\u660e\uff0cNa+<\/sup>\u4e0d\u5229\u4e8e\u5438\u9644\u5728\u5355\u5c42\u77f3\u58a8\u70ef\u8868\u9762\uff0c\u56e0\u6b64\u5177\u6709\u8f83\u4f4e\u7684Na+<\/sup>\u5b58\u50a8\u5bb9\u91cf\u3002\u5c3d\u7ba1K+<\/sup>\uff081.38\u00c5\uff09\u7684\u5c3a\u5bf8\u6bd4Na+<\/sup>\uff080.97\u00c5\uff09\u5927\uff0c\u4f46\u77f3\u58a8\u70ef\u57fa\u6750\u6599\u4e3aPIBs\u7684\u66f4\u9ad8\u5b58\u50a8\u5bb9\u91cf\u63d0\u4f9b\u4e86\u66f4\u591a\u7684K+<\/sup>\u5b58\u50a8\u4f4d\u70b9\uff0c\u8fd9\u5f52\u56e0\u4e8e\u4f4eK+<\/sup>\u6269\u6563\u52bf\u5792\u548c\u589e\u5f3a\u7684\u77f3\u58a8\u70ef\u5438\u9644K+<\/sup>\u7684\u70ed\u529b\u5b66\u7a33\u5b9a\u6027\u3002 \u7efc\u4e0a\u6240\u8ff0\uff0c\u77f3\u58a8\u70ef\u57fa\u6750\u6599\u56e0\u5176\u8f83\u9ad8\u7684K+<\/sup>\u50a8\u5b58\u80fd\u529b\u548c\u53cd\u5e94\u52a8\u529b\u5b66\u800c\u5728PIBs\u65b9\u9762\u663e\u793a\u51fa\u66f4\u597d\u7684\u5e94\u7528\u524d\u666f\u3002<\/p>\n

3.3\u3001\u786c\u78b3<\/p>\n

\u901a\u5e38\uff0c\u786c\u78b3\u6750\u6599\u7531\u626d\u66f2\u7684\u77f3\u58a8\u70ef\u7eb3\u7c73\u7247\uff0c\u65e0\u89c4\u5206\u5e03\u7684\u77f3\u58a8\u5316\u5fae\u533a\uff0c\u4e30\u5bcc\u7684\u7a7a\u9699\u6216\u5b54\u7ec4\u6210\u3002\u4e0e\u7f13\u6162\u7684\u53cd\u5e94\u52a8\u529b\u5b66\u548c\u4e0d\u826f\u7684\u77f3\u58a8\u7ed3\u6784\u7a33\u5b9a\u6027\u4e0d\u540c\uff0c\u786c\u78b3\u5177\u6709\u8f83\u5feb\u7684Na+<\/sup>\/K+<\/sup>\u4f20\u8f93\u901f\u7387\uff0c\u5e76\u4e14\u7531\u4e8e\u5b54\u4e30\u5bcc\u4e14\u5c42\u95f4\u95f4\u8ddd\u5927\u800c\u53ef\u4ee5\u51cf\u7f13\u4f53\u79ef\u81a8\u80c0\uff0c\u56e0\u6b64\u9002\u5408Na+<\/sup>\/K+<\/sup>\u5b58\u50a8\u3002\u786c\u78b3\u4e2d\u94a0\u7684\u5b58\u50a8\u673a\u7406\u5305\u62ec\u201c\u5438\u9644<\/b><\/strong>-\u5d4c\u5165<\/b><\/strong>\u201d<\/b><\/strong>\u673a\u7406\uff0c<\/b><\/strong>\u201c<\/b><\/strong>\u5d4c\u5165-\u5438\u9644<\/b><\/strong>\u201d<\/b><\/strong>\u673a\u7406\u548c<\/b><\/strong>\u201c<\/b><\/strong>\u5d4c\u5165-\u5b54\u586b\u5145<\/b><\/strong>\u201d<\/b><\/strong>\u673a\u7406\u3002<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe11.\u00a0\u786c\u78b3\u4e2d\u94a0\u7684\u5b58\u50a8\u673a\u7406<\/p>\n

\u203bAdv. Energy Mater. 7 (2017) 1700403<\/i><\/u><\/em><\/a><\/p>\n

\u203bAdv. Energy Mater. 8 (2018) 1703217<\/i><\/u><\/em><\/a><\/p>\n

\u76ee\u524d\uff0c\u5173\u4e8e\u786c\u78b3\u4e2dK+<\/sup>\u5b58\u50a8\u884c\u4e3a\u7684\u7814\u7a76\u5e76\u4e0d\u591a\uff0c\u5176\u4e2d\u4e24\u79cd\u5178\u578b\u7684\u94be\u5316\/\u53bb\u94be\u5316\u7535\u4f4d\u5206\u5e03\u56fe\u5982\u4e0b\u56fe\uff0c\u4e00\u79cd\u662f<\/b><\/strong>\u7c7b\u4f3c\u4e0eS<\/b><\/strong>IB<\/b><\/strong>s\u7684<\/b><\/strong>\u8fd1\u659c\u7ebf\uff0c\u53e6\u4e00\u79cd\u662f\u659c\u533a\u548c\u51c6<\/b><\/strong>\u9ad8<\/b><\/strong>\u533a\u3002<\/b><\/strong>\u901a\u5e38\uff0c\u659c\u533a\u57df\u5f52\u56e0\u4e8e\u8868\u9762\u9a71\u52a8\u7684K+<\/sup>\u5b58\u50a8\u884c\u4e3a\uff0c\u51c6\u9ad8\u533a\u5f52\u56e0\u4e8eK+<\/sup>\u63d2\u5c42\u884c\u4e3a\u3002<\/p>\n

\"\"<\/p>\n

\u56fe12.\u00a0\u786c\u78b3\u4e2d\u94be\u7684\u5b58\u50a8\u673a\u7406<\/p>\n

\u203bAdv. Energy Mater. 10 (2020) 2000283<\/i><\/u><\/em><\/a><\/p>\n

\u7136\u800c\uff0c\u4e00\u65b9\u9762\uff0c\u786c\u78b3\u4e2d\u7684K+<\/sup>\u5b58\u50a8\u80fd\u529b\u4f4e\u4e8eNa+<\/sup>\u5b58\u50a8\u80fd\u529b\uff0c\u8fd9\u8868\u660e\u786c\u78b3\u6750\u6599\u63d0\u4f9b\u4e86\u66f4\u591a\u7684Na+<\/sup>\u50a8\u5b58\u4f4d\u70b9\u3002\u53e6\u4e00\u65b9\u9762\uff0c\u94a0\u5316\u548c\u53bb\u94a0\u5316\u5e73\u53f0\u533a\u57df\u5747\u4f4e\u4e8e0.1V\uff0c\u76f8\u53cd\uff0c\u94be\u5316\u548c\u53bb\u94be\u5316\u5e73\u53f0\u533a\u57df\u5747\u57280.5 V\u4ee5\u4e0b\u3002\u6240\u4ee5\u4ece\u7535\u6c60\u80fd\u91cf\u5bc6\u5ea6\u7684\u89d2\u5ea6\u6765\u770b\uff0c\u5f53\u4f7f\u7528\u786c\u78b3\u4f5c\u4e3a\u9633\u6781\u65f6\uff0cSIBs\u6bd4PIBs\u66f4\u5177\u4f18\u52bf\u3002<\/b><\/strong><\/p>\n

3.4\u3001\u8f6f\u78b3<\/p>\n

\u8f6f\u78b3\u662f\u4e00\u79cd\u6709\u5e8f\u78b3\u5c42\uff0c\u65e0\u5e8f\u7ed3\u6784\u7684\u7279\u6b8a\u78b3\u6750\u6599\uff0c\u53ef\u4ee5\u901a\u8fc7\u70ed\u5904\u7406\u6765\u8c03\u8282\u8f6f\u78b3\u7684\u77f3\u58a8\u5316\u7a0b\u5ea6\u3002\u00a0\u4e0e\u786c\u78b3\u4e0d\u540c\uff0c\u8f6f\u78b3\u57282500\u00b0C\u9000\u706b\u65f6\u53ef\u4ee5\u8f6c\u53d8\u4e3a\u77f3\u58a8\u3002\u6700\u91cd\u8981\u7684\u662f\u53ef\u4ee5\u63a7\u5236\u8f6f\u78b3\u7684\u5c42\u95f4\u8ddd\uff0c\u4ece\u800c\u63d0\u9ad8Na+<\/sup>\/K+<\/sup>\u4f20\u8f93\u52a8\u529b\u5b66\u3002<\/p>\n

\u4e2d\u79d1\u9662\u80e1\u6c38\u80dc\u7814\u7a76\u5458\u548c\u9646\u96c5\u7fd4\u526f\u7814\u7a76\u5458<\/b><\/strong>\u901a\u8fc7\u63a7\u5236\u78b3\u5316\u6e29\u5ea6\u7814\u7a76\u4e86\u6ca5\u9752\u78b3\uff08PC\uff09\u7684\u6cbf\u6a2a\u5411ab\u65b9\u5411\uff08La\uff09\u7684\u77f3\u58a8\u5316\u7a0b\u5ea6\u548c\u77f3\u58a8\u5c42\u957f\u5ea6\u3002<\/b><\/strong>\u4e0e\u5e38\u89c4\u7684\u9ad8\u6e29\u65b9\u6cd5\u76f8\u6bd4\uff0c\u8fd9\u79cd\u7b80\u5355\u7684\u4f4e\u6e29\u7b56\u7565\u66f4\u5177\u6210\u672c\u6548\u76ca\uff0c\u5728800\u00b0C\u7684\u4f4e\u6e29\u4e0b\u5408\u6210\u7684\u6027\u80fd\u6700\u4f73\u7684\u78b3\u9633\u6781\u5177\u6709\u660e\u663e\u7684\u659c\u7387\u4e3b\u5bfc\u7279\u5f81\uff0c\u540c\u65f6\u5177\u6709\u53ef\u9006\u5bb9\u91cf\u548c\u8f83\u9ad8\u7684\u9996\u5708\u5e93\u4f26\u6548\u7387\uff0c\u4ece\u800c\u5927\u5927\u51cf\u8f7b\u4e86\u5bf9\u91d1\u5c5e\u7535\u9540\u548c\u6781\u5316\u7684\u62c5\u5fe7\uff0c\u6700\u7ec8\u5b9e\u73b0\u4e86\u5b89\u5168\u548c\u5feb\u901f\u5145\u7535\u7684NIBs\u3002<\/p>\n

\"\"<\/p>\n

\u56fe13.\u00a0\u4f4e\u6e29\u7b56\u7565\u4e0e\u5e38\u89c4\u9ad8\u6e29\u7b56\u7565\u5bf9\u6bd4<\/p>\n

\u203bAngew.Chem. Int.Ed. 58 (2019) 4361\u20134365<\/i><\/u><\/em><\/a><\/p>\n

\"\"<\/p>\n

\u56fe14.\u00a0\u62c9\u66fc\u4e0e\u7535\u6c60\u6027\u80fd<\/p>\n

\u203bAngew.Chem. Int.Ed. 58 (2019) 4361\u20134365<\/i><\/u><\/em><\/a><\/p>\n

\u7531\u4e8eK+<\/sup>\u7684\u534a\u5f84\u8f83\u5927\uff0c\u5728K+<\/sup>\u5d4c\u5165\/\u8131\u5d4c\u8fc7\u7a0b\u4e2d\u53ef\u80fd\u4f1a\u5bfc\u81f4\u8f6f\u78b3\u7684\u5c42\u95f4\u81a8\u80c0\/\u6536\u7f29\u8f83\u5927\uff0c\u7279\u522b\u662f\u5bf9\u4e8e\u5177\u6709\u9ad8\u77f3\u58a8\u5316\u7a0b\u5ea6\u7684\u8f6f\u78b3\u3002\u4e3a\u907f\u514d\u4e25\u91cd\u7684\u7ed3\u6784\u53d8\u5316\uff0c\u9700\u8981\u53d1\u5177\u6709\u826f\u597d\u7ed3\u6784\u7a33\u5b9a\u6027\u7684\u8f6f\u78b3\u3002K+<\/sup>\u7684\u5b58\u50a8\u884c\u4e3a\u53d6\u51b3\u4e8e\u8f6f\u78b3\u7684\u77f3\u58a8\u5316\u7a0b\u5ea6\uff0c\u5bf9\u4e8e\u5177\u6709\u8f83\u9ad8\u77f3\u58a8\u5316\u7a0b\u5ea6\u7684\u8f6f\u78b3\u6750\u6599\uff0cK+<\/sup>\u53ef\u4ee5\u63d2\u5165\u77f3\u58a8\u5316\u5c42\u4e2d\u5e76\u5438\u9644\u5728\u65e0\u5b9a\u5f62\u78b3\u7684\u8868\u9762\u4e0a\u3002<\/p>\n

2018\u5e74\u5317\u4eac\u5316\u5de5\u5927\u5b66\u5b8b\u6000\u6cb3\u6559\u6388\u548c\u5367\u9f99\u5c97\u5927\u5b66\u90ed\u518d\u840d\u6559\u6388<\/b><\/strong>\u62a5\u9053\u4e86\u77f3\u58a8\u4e2d\u7a7a\u78b3\u7eb3\u7c73\u7ba1\u5177\u6709\u8f83\u9ad8\u7684\u77f3\u58a8\u5316\u5ea6<\/b><\/strong>\uff0c\u907f\u514d\u4e86\u5c42\u95f4\u6ed1\u79fb\u548c\u5404\u5411\u5f02\u6027\u7684\u964d\u4f4e\uff0c\u4ece\u800c\u786e\u4fdd\u4e86\u7ed3\u6784\u7684\u5b8c\u6574\u6027\uff0c\u6709\u6548\u5730\u51cf\u7f13\u4e86K+<\/sup>\u5b58\u50a8\u548c\u91ca\u653e\u8fc7\u7a0b\u4e2d\u7684\u5e94\u53d8\u677e\u5f1b\u3002<\/p>\n

\"\"<\/p>\n

\u56fe15.\u00a0\u77f3\u58a8\u4e2d\u7a7a\u78b3\u7eb3\u7c73\u7ba1\u5b58\u50a8\u94be<\/p>\n

\u203bAdv. Energy Mater. 8 (2018) 1801149<\/i><\/u><\/em><\/a><\/p>\n

\u3010\u7ed3\u8bba\u4e0e\u5c55\u671b\u3011<\/b><\/strong><\/p>\n

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\"\"<\/p>\n

\u56fe16. \u78b3\u9633\u6781\u6750\u6599\u4e2dNa+<\/sup>\/K+<\/sup>\u5b58\u50a8\u884c\u4e3a\u5bf9\u6bd4\u793a\u610f\u56fe<\/p>\n

\u203bAdv. Energy Mater. 2021, 2003640<\/i><\/u><\/em><\/a><\/p>\n

\u8fc4\u4eca\u4e3a\u6b62\uff0c\u5728NIBs\/PIBs\u7814\u7a76\u9886\u57df\u5df2\u7ecf\u8fdb\u884c\u4e86\u8bb8\u591a\u52aa\u529b\u548c\u5c1d\u8bd5\uff0c\u4f46\u662f\u4ecd\u7136\u9700\u8981\u89e3\u51b3\u4e00\u4e9b\u5173\u952e\u95ee\u9898\uff1a\uff081\uff09\u5c3d\u7ba1\u77f3\u58a8\u9633\u6781\u901a\u8fc7\u4f7f\u7528\u57fa\u4e8e\u919a\u7684\u7535\u89e3\u8d28\u53ef\u63d0\u4f9b\u76f8\u5f53\u5927\u7684Na+<\/sup>\u5b58\u50a8\u5bb9\u91cf\u548c\u4f18\u5f02\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u4f46\u7531\u4e8e\u57fa\u4e8e\u919a\u7684\u7535\u89e3\u8d28\u7684\u7535\u538b\u7a97\u53e3\u7a84\uff0c\u6240\u4ee5\u5728\u5168\u7535\u6c60\u7684\u5b9e\u9645\u5e94\u7528\u4e2d\u53d7\u5230\u4e86\u4e00\u5b9a\u7684\u9650\u5236\u3002\u56e0\u6b64\uff0c\u6709\u5fc5\u8981\u5f00\u53d1\u65b0\u578b\u7684SIBs\u7535\u89e3\u8d28\uff0c\u5176\u5177\u6709\u5bbd\u7684\u7535\u538b\u8303\u56f4\u4ee5\u5339\u914d\u77f3\u58a8\u9633\u6781\u548c\u9ad8\u538b\u9634\u6781\u3002<\/b><\/strong>\uff082\uff09\u9700\u8981\u8bbe\u8ba1\u548c\u5236\u5907\u65b0\u578b\u7684\u6742\u5316\u78b3\u590d\u5408\u6750\u6599\u3002<\/b><\/strong>\u7ed3\u5408\u81ea\u8eab\u7684\u4f18\u52bf\uff08\u4f8b\u5982\u786c\u78b3\u7684\u9ad8\u5ea6\u7ed3\u6784\u7a33\u5b9a\u6027\uff0c\u77f3\u58a8\u70ef\u7684\u5feb\u901f\u8fd0\u8f93\u548c\u7a33\u5b9a\u7684\u5e73\u53f0\uff09\uff0c\u4e0d\u540c\u79cd\u7c7b\u7684\u78b3\u6750\u6599\u53ef\u4ee5\u534f\u540c\u6539\u5584Na+<\/sup>\/K+<\/sup>\u7684\u5b58\u50a8\u6027\u80fd\uff0c\u5e76\u83b7\u5f97\u9ad8\u5bb9\u91cf\uff0c\u957f\u671f\u5faa\u73af\u7a33\u5b9a\u6027\u548c\u9ad8\u500d\u7387\u6027\u80fd\u3002\uff083\uff09\u8fd8\u5e94\u6ce8\u610f\u5176\u4ed6\u4e00\u4e9b\u95ee\u9898\uff0c\u4f8b\u5982\u8bbe\u8ba1\u78b3\u6750\u6599\u7684\u4f4e\u5e94\u53d8\u7ed3\u6784\uff0c\u63d0\u9ad8\u78b3\u6750\u6599\u4e0e\u7535\u89e3\u8d28\u4e4b\u95f4\u7684\u76f8\u5bb9\u6027\uff0c\u964d\u4f4e\u78b3\u6750\u6599\u7684\u6210\u672c\uff0c<\/b><\/strong>\u901a\u8fc7\u4f7f\u7528\u78b3\u6750\u6599\u548c\u91cf\u5316\u78b3\u6750\u6599\u7684\u5546\u4e1a\u5316\u6307\u6807\u6765\u4f18\u5316\u5168\u7535\u6c60\u7684\u5236\u5907<\/b><\/strong>\u3002<\/p>\n

\u3010\u53c2\u8003\u6587\u732e\u3011<\/b><\/strong><\/p>\n

[1]Carbon Anode Materials: A Detailed Comparison between Na\u2010ion and K\u2010ion Batteries. Adv.<\/em>\u00a0<\/span>Energy<\/span> Mater. 2021, 2003640<\/i><\/u><\/em>.<\/p>\n

[2]Sodium Storage Behavior in Natural Graphite using Ether\u2010based Electrolyte Systems. Adv.<\/em><\/span> Funct. Mater. 25 (2015) 534\u2013541<\/i><\/u><\/em>.<\/p>\n

[3]Conditions for Reversible Na Intercalation in Graphite: Theoretical Studies on the Interplay Among Guest Ions, Solvent, and Graphite Host. Adv.<\/em><\/span> Energy Mater. 7 <\/i><\/u><\/em>(<\/i><\/u><\/em>2017) 1601519<\/i><\/u><\/em>.<\/p>\n

[4]Carbon Electrodes for K-Ion Batteries. J.\u00a0<\/span>Am. Chem. Soc. 137<\/i><\/u><\/em>(<\/i><\/u><\/em>2015) 11566\u201311569<\/i><\/u><\/em>.<\/p>\n

[5]Unraveling the Potassium Storage Mechanism in Graphite Foam.<\/i> Adv.<\/span>Energy Mater. 9 (2019) 1900579<\/i><\/u><\/em>.<\/p>\n

[6]Impact of Surface Modification on the Lithium, Sodium, and Potassium Intercalation Efficiency and Capacity of Few-Layer Graphene Electrodes. ACS Appl. Mater. Interfaces 12 (2020) 19393\u201319401<\/i><\/u><\/em>.<\/i><\/em><\/p>\n

[7]Manipulating Adsorption\u2013Insertion Mechanisms in Nanostructured Carbon Materials for High\u2010Efficiency Sodium Ion Storage.<\/i> Adv.\u00a0<\/span>Energy Mater. 7 (2017) 1700403<\/i><\/u><\/em>.<\/u><\/p>\n

[8]Elucidation of the Sodium\u2010Storage Mechanism in Hard Carbons. Adv.<\/em><\/span> Energy Mater. 8 (2018) 1703217<\/i><\/u><\/em>.<\/u><\/p>\n

[9]Revealing the Intercalation Mechanisms of Lithium, Sodium, and Potassium in Hard Carbon. Adv.<\/em><\/span> Energy Mater. 10 (2020) 2000283<\/i><\/u><\/em>.<\/u><\/p>\n

[10]Slope\u2010Dominated Carbon Anode with High Specific Capacity and Superior Rate Capability for High Safety Na\u2010Ion Batteries. Angew.\u00a0<\/span>Chem. Int.Ed. 58 (2019) 4361\u20134365<\/i><\/u><\/em>.<\/p>\n

[11]Graphitic Carbon Nanocage as a Stable and High Power Anode for Potassium\u2010Ion Batteries. Adv.<\/span>Energy Mater. 8 (2018) 1801149<\/i><\/u><\/em>.<\/p>\n

\u672c\u6587\u7531FAB\u4f9b\u7a3f\u3002<\/span><\/p>\n

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\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n

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