{"id":217633,"date":"2021-02-09T12:00:23","date_gmt":"2021-02-09T04:00:23","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=217633"},"modified":"2021-02-09T11:37:05","modified_gmt":"2021-02-09T03:37:05","slug":"%e6%82%89%e5%b0%bc%e5%a4%a7%e5%ad%a6%e9%99%88%e5%85%83%e5%9b%a2%e9%98%9fadv-eng-mater-%ef%bc%9a%e9%92%b4%e9%93%81%e9%93%ac%e4%b8%89%e5%85%83%e6%b0%a2%e6%b0%a7%e5%8c%96%e7%89%a9%e7%be%9f%e5%9f%ba","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=217633","title":{"rendered":"\u6089\u5c3c\u5927\u5b66\u9648\u5143\u56e2\u961fAdv. Eng. Mater.\uff1a\u94b4\u94c1\u94ec\u4e09\u5143\u6c22\u6c27\u5316\u7269(\u7f9f\u57fa\u6c27\u5316\u7269)\u4f5c\u4e3a\u9ad8\u6548\u6790\u6c27\u53cd\u5e94\u50ac\u5316\u5242"},"content":{"rendered":"<p><strong><b>\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n<p>\u6790\u6c27\u53cd\u5e94\uff08OER\uff09\u662f\u5f88\u591a\u80fd\u91cf\u8f6c\u6362\u548c\u5b58\u50a8\u8bbe\u5907\u7684\u5173\u952e\u63a7\u901f\u53cd\u5e94\uff0c\u5305\u62ec\u6c34\u7535\u89e3\u69fd\u548c\u53ef\u5145\u7535\u91d1\u5c5e-\u7a7a\u6c14\u7535\u6c60\u3002\u8fd9\u4e2a\u590d\u6742\u7684\u56db\u7535\u5b50\u53cd\u5e94\u6d89\u53ca\u591a\u79cd\u53cd\u5e94\u4e2d\u95f4\u4f53\u548c\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u50ac\u5316\u5242\u7ed3\u6784\u7684\u53d8\u5316\uff0c\u9700\u8981\u5927\u91cf\u7684\u80fd\u91cf\u8f93\u5165\u3002\u94f1\u548c\u948c\u6c27\u5316\u7269\u5bf9OER\u5177\u6709\u8f83\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\uff1b\u7136\u800c\uff0c\u5176\u9ad8\u6210\u672c\u548c\u4f4e\u7a33\u5b9a\u6027\u4e25\u91cd\u9650\u5236\u4e86\u5176\u5e94\u7528\u3002\u6700\u8fd1\u7684\u7814\u7a76\u4e2d\uff0c\u94b4\u6c22\u6c27\u5316\u7269\uff08(\u7f9f\u57fa\u6c27\u5316\u7269)\u5f15\u8d77\u4e86\u4eba\u4eec\u7684\u6781\u5927\u5174\u8da3\uff0c\u56e0\u4e3a\u94b4\u8868\u73b0\u51fat<sup>5<\/sup><sub>2<\/sub><sub>g<\/sub>\u00a0e<sup>1<\/sup><sub>g<\/sub>\u7535\u5b50\u6784\u578b\uff0c\u6709\u5229\u4e8e\u548cOER\u7684\u4e2d\u95f4\u4ea7\u7269\uff08\u5982OH*\u3001O*\u548cOOH*\uff09\u7684\u7ed3\u5408\u3002\u94b4\u5728OER\u8fc7\u7a0b\u4e2d\u4e5f\u4f1a\u53d1\u751f\u6c27\u5316\u8fd8\u539f\u8f6c\u53d8\uff0c\u5373\u5728Co<sup>2+<\/sup>\/Co<sup>3+<\/sup>\u548cCo<sup>3+<\/sup>\/Co<sup>4+<\/sup>\u95f4\u8f6c\u5316\uff0c\u9ad8\u4ef7\u7684\u94b4\uff08Co<sup>\uff08<\/sup><sup>3+\u03b4<\/sup><sup>\uff09+<\/sup>\uff0c1&gt;\u03b4&gt; 0\uff09\u88ab\u8ba4\u4e3a\u662f\u6d3b\u6027\u50ac\u5316\u4e2d\u5fc3\u3002\u8fd9\u4e2a\u8fc7\u7a0b\u9700\u8981\u5927\u91cf\u7684\u8f6c\u5316\u80fd\u91cf\u3002\u964d\u4f4e\u8fd9\u79cd\u8f6c\u5316\u80fd\u53ef\u4ee5\u63d0\u9ad8\u94b4\u50ac\u5316\u5242\u7684\u50ac\u5316\u6d3b\u6027\u3002\u4f8b\u5982\uff0c\u5728\u94b4\u94c1\u94a8\u4e09\u5143\u50ac\u5316\u5242\u4e2d\uff0c\u5168\u7a7ad\u8f68\u9053\u7684W<sup>6+<\/sup>\u53ef\u4ee5\u63a5\u53d7\u94b4\u7684\u7535\u5b50\uff0c\u4fc3\u8fdbCo<sup>2+<\/sup>\u5411Co<sup>3+<\/sup>\u7684\u8f6c\u5316\uff0c\u662f\u76ee\u524d\u62a5\u9053\u7684\u6700\u597d\u7684OER\u50ac\u5316\u5242\u4e4b\u4e00\u3002\u94bc\u4e5f\u6709\u7c7b\u4f3c\u7684\u6548\u679c\u3002\u8fdb\u4e00\u6b65\uff0c\u5b9e\u9a8c\u548c\u8ba1\u7b97\u7814\u7a76\u8868\u660e\uff0c\u4fee\u6539\u94b4\u4f4d\u70b9\u7684\u5c40\u90e8\u73af\u5883\u53ef\u4ee5\u4f18\u5316\u5b83\u4eec\u4e0e\u6c27\u4e2d\u95f4\u4f53\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u63d0\u9ad8\u50ac\u5316\u6d3b\u6027\u3002\u5df2\u7ecf\u63a2\u7d22\u4e86\u51e0\u79cd\u65b9\u6cd5\u5305\u62ec\u521b\u5efa\u6c27\u7f3a\u9677\u6216\u91d1\u5c5e\u7f3a\u9677\uff0c\u7528\u787c\u3001\u6c2e\u3001\u78f7\u6216\u786b\u53d6\u4ee3\u6c27\uff0c\u6216\u63ba\u6742\u5176\u4ed6\u8fc7\u6e21\u91d1\u5c5e\uff0c\u5982\u94c1\u3001\u9530\u548c\u954d\u3002\u94ec\u5728\u5143\u7d20\u5468\u671f\u8868\u4e0a\u548c\u94a8\u5728\u540c\u4e00\u65cf\u3002Cr<sup>6+<\/sup>\u5bf9\u94b4\u7684\u50ac\u5316\u6d3b\u6027\u4e5f\u6709\u4fc3\u8fdb\u4f5c\u7528\u3002\u94ec\u5728\u5730\u58f3\u4e2d\u7684\u4e30\u5ea6\u662f\u94a8\u7684127\u500d\uff0c\u800c\u4e14\u6bd4\u94a8\u4fbf\u5b9c\u5f97\u591a\uff1b\u56e0\u6b64\uff0c\u5b83\u53ef\u80fd\u4f1a\u4f7f\u94b4\u6c22\u6c27\u5316\u7269\uff08(\u7f9f\u57fa\u6c27\u5316\u7269)\u50ac\u5316\u5242\u66f4\u5177\u6210\u672c\u6548\u76ca\u3002\u867d\u7136\u5df2\u6709\u7814\u7a76\u63a2\u7d22\u5229\u7528\u94ec\u4fc3\u8fdb\u94b4\u7684OER\u6d3b\u6027\uff0c\u4f46\u94ec\u7684\u786e\u5207\u4f5c\u7528\u5c1a\u672a\u5b8c\u5168\u4e86\u89e3\uff0c\u6700\u4f18\u7684\u50ac\u5316\u5143\u7d20\u7ec4\u6210\u4e5f\u5c1a\u4e0d\u6e05\u695a\u3002<\/p>\n<p><strong><b>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c\u5728<strong><b>\u6089\u5c3c\u5927\u5b66<\/b><\/strong><strong><b>\u9b4f\u529b\u535a\u58eb\u548c<\/b><\/strong><strong><b>\u9648\u5143<\/b><\/strong><strong><b>\u6559\u6388\u56e2\u961f<\/b><\/strong>\uff0c\u5c06\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u8ba1\u7b97\u4e0e\u50ac\u5316\u5242\u8868\u5f81\u76f8\u7ed3\u5408\u6765\u89e3\u51b3\u8fd9\u4e24\u4e2a\u95ee\u9898\u3002\u5728DFT\u8ba1\u7b97\u7684\u6307\u5bfc\u4e0b\uff0c\u5408\u6210\u4e86\u4e00\u7cfb\u5217\u5143\u7d20\u7ec4\u6210\u53ef\u8c03\u7684\u975e\u6676\u94b4(Co)\u94c1\uff08Fe\uff09\u94ec(Cr)(\u6c27)\u4e09\u5143\u6c22\u6c27\u5316\u7269\uff08(\u7f9f\u57fa\u6c27\u5316\u7269)\u3002\u7ed3\u679c\u8868\u660e\uff0cCo<sub>5<\/sub>Fe<sub>3<\/sub>Cr<sub>2<\/sub>\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a10 mA cm<sup>&#8211;<\/sup><sup>2<\/sup>\u65f6\u8fc7\u7535\u4f4d\u4e3a232 mV\u65f6\u3002\u5b83\u7684\u94b4\u57fa\u8d28\u91cf\u6d3b\u5ea6\u4e3a1486 A\u00a0g<sup>&#8211;<\/sup><sup>1<\/sup>\uff0c\u7ffb\u8f6c\u9891\u7387\u4e3a0.23 s<sup>&#8211;<\/sup><sup>1<\/sup>\uff0c\u6bd4\u5355\u91d1\u5c5e\u6c22\u6c27\u94b4\u9ad8\u4e24\u4e2a\u6570\u91cf\u7ea7\u3002X\u5c04\u7ebf\u5438\u6536\u548c\u5149\u7535\u5b50\u5149\u8c31\u663e\u793a\uff0c\u94ec\u4fc3\u8fdb\u94b4\u539f\u5b50\u5360\u636e\u516b\u9762\u4f53\u4f4d\u70b9\uff0c\u5e76\u6539\u53d8\u94b4\u7684\u7535\u5b50\u7ed3\u6784\u3002\u51c6\u539f\u4f4d\u7535\u5b50\u80fd\u91cf\u635f\u5931\u8c31\u8fdb\u4e00\u6b65\u5b9e\u9a8c\u8bc1\u5b9e\uff0c\u94ec\u52a0\u901f\u4e86Co<sup>2+<\/sup>\u7684\u9884\u6c27\u5316\uff0c\u4f7f\u5176\u8fbe\u5230\u66f4\u9ad8\u7684\u4ef7\u6001\uff0c\u4ece\u800c\u663e\u8457\u63d0\u9ad8\u4e86\u50ac\u5316\u6d3b\u6027\u3002\u7814\u7a76\u7ed3\u679c\u4e3a\u94b4\u94c1\u94ec\u4e09\u5143\u6c22\u6c27\u5316\u7269\u4f5c\u4e3a\u9ad8\u6548\u7684OER\u50ac\u5316\u5242\u94fa\u5e73\u4e86\u9053\u8def\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a\u201c<strong><b>Co\u2013Fe\u2013Cr(oxy)Hydroxides as Efficient Oxygen Evolution Reaction Catalysts<\/b><\/strong>\u201d\u53d1\u8868\u5728\u4e86<strong><b>Adv. <\/b><\/strong><strong><b>Eng<\/b><\/strong><strong><b>. Mater.<\/b><\/strong>\u4e0a\u3002<\/p>\n<p><strong><b>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n<p><strong><b>\u56fe1 <\/b><\/strong><strong><b>\u7406\u8bba\u9884\u6d4b<\/b><\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-217634\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/02\/1-7.jpg\" alt=\"\" width=\"600\" height=\"394\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/02\/1-7.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/02\/1-7-300x197.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" 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wp-image-217635\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/02\/2-7.jpg\" alt=\"\" width=\"600\" height=\"587\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/02\/2-7.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/02\/2-7-300x294.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a\uff0cb)Co<sub>5<\/sub>Fe<sub>3<\/sub>Cr<sub>2<\/sub>\u6c22\u6c27\u5316\u7269\u7684a) SEM\u548cb) TEM\u56fe\u50cf\u3002(a)\u4e2d\u7684\u63d2\u56fe\u663e\u793a\u4e86Co<sub>5<\/sub>Fe<sub>3<\/sub>Cr<sub>2<\/sub>\u7684\u7a33\u5b9a\u80f6\u4f53\u6c34\u6eb6\u6db2\u3002(b)\u7684\u63d2\u56fe\u663e\u793a\u4e86\u76f8\u5e94\u7684SAED\u6a21\u5f0f\u3002<\/p>\n<p>c) \u9ad8\u89d2\u5ea6\u73af\u5f62\u6697\u573a-\u626b\u63cf\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\u56fe\u50cf\u548c\u76f8\u5173EDX\u5143\u7d20\u5206\u5e03\u7ed3\u679c\u3002<\/p>\n<p>d)\u4e0d\u540c\u50ac\u5316\u5242\u4e2dCo K\u8fb9\u7684k<sup>3<\/sup>\u52a0\u6743\u5085\u91cc\u53f6\u53d8\u6362\u5ef6\u4f38X\u5149\u5438\u6536\u5fae\u7ec6\u7ed3\u6784\u5206\u6790\u3002<\/p>\n<p><strong><b>\u56fe3 Co<\/b><\/strong><strong><sub><b>a<\/b><\/sub><\/strong><strong><b>Fe<\/b><\/strong><strong><sub><b>b<\/b><\/sub><\/strong><strong><b>Cr<\/b><\/strong><strong><sub><b>c<\/b><\/sub><\/strong><strong><b>\u6c22\u6c27\u5316\u7269\u7684<\/b><\/strong><strong><b>\u5149\u8c31\u7535\u5b50\u7ed3\u6784<\/b><\/strong><strong><b>\u8868\u5f81<\/b><\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-217636\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/02\/3-7.jpg\" alt=\"\" width=\"600\" height=\"347\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/02\/3-7.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/02\/3-7-300x174.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a)\u4e0d\u540c\u50ac\u5316\u5242\u4e2db) Co, c) Fe, d) Cr\u548ce) O\u7684XPS\u548cEELS\u8c31\u3002(b)\u63d2\u56fe:\u8ba1\u7b97Co<sub>a<\/sub>Fe<sub>b<\/sub>Cr<sub>c<\/sub>\u00a0\u6c22\u6c27\u5316\u7269\u7684Co L<sub>3<\/sub>\/L<sub>2<\/sub>\u5f3a\u5ea6\u6bd4\u3002<\/p>\n<p><strong><b>\u56fe4 Co<\/b><\/strong><strong><sub><b>a<\/b><\/sub><\/strong><strong><b>Fe<\/b><\/strong><strong><sub><b>b<\/b><\/sub><\/strong><strong><b>Cr<\/b><\/strong><strong><sub><b>c<\/b><\/sub><\/strong><strong><b>\u00a0(\u6c27)\u6c22\u6c27\u5316\u7269<\/b><\/strong><strong><b>\u7684\u7535\u5316\u5b66\u8868\u5f81<\/b><\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-217637\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/02\/4-7.jpg\" alt=\"\" width=\"600\" height=\"503\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/02\/4-7.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/02\/4-7-300x252.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a-c)Co<sub>a<\/sub>Fe<sub>b<\/sub>Cr<sub>c<\/sub>\u4e09\u5143\u6c22\u6c27\u5316\u7269\u57281\u00a0M\u00a0KOH\u7535\u89e3\u8d28\u4e2d\u7684\u7684\u50ac\u5316\u6027\u80fda)\u00a0\u03b7<sub>10<\/sub>\u8fc7\u7535\u52bf\uff0cb)Tafel\u659c\u7387\u548cc)\u8f6c\u5316\u901f\u7387\u03b7 =\u00a0300 mV\u65f6\u3002<\/p>\n<p>d-e)\u00a0\u6700\u4f18\u6bd4\u4f8b\u4e09\u5143\u50ac\u5316\u5242\u53ca\u5176\u4ed6\u53c2\u6bd4\u50ac\u5316\u5242\u7684d) LSV\u66f2\u7ebf(95% iR-\u8865\u507f)\u00a0\u548ce) Tafel\u66f2\u7ebf\u3002<\/p>\n<p>f) Co<sub>5<\/sub>Fe<sub>3<\/sub>Cr<sub>2<\/sub>\u6c22\u6c27\u5316\u7269(\u65e0iR\u8865\u507f)\u7684\u7a33\u5b9a\u6027\u6d4b\u8bd5\u548cCo,Fe,Cr\u5728\u7535\u6781\u4e0a\u7684\u5143\u7d20\u4fdd\u7559\u7387\u3002<\/p>\n<p>g)\u56fe1c\u4e2d\u63cf\u8ff0\u7684\u4e0d\u540c\u8868\u9762\u6a21\u578b\u7684\u8ba1\u7b97\u81ea\u7531\u80fd\u56fe\u8c31\u3002<\/p>\n<p>h)\u7406\u8bba\u8fc7\u7535\u4f4d\u4e0e\u5b9e\u9a8c\u8fc7\u7535\u4f4d\u7684\u76f8\u5173\u6027\u3002\u6570\u503c\u5206\u522b\u53c2\u8003CoOOH\u6a21\u578b\u548c\u5355\u91d1\u5c5eCo\u6837\u54c1\u3002<\/p>\n<p><strong><b>\u56fe5<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>Co<\/b><\/strong><strong><sub><b>a<\/b><\/sub><\/strong><strong><b>F<\/b><\/strong><strong><sub><b>e<\/b><\/sub><\/strong><strong><b>bCr<\/b><\/strong><strong><sub><b>c<\/b><\/sub><\/strong><strong><b>(\u6c27)\u6c22\u6c27\u5316\u7269\u7684\u539f\u5b50\u7ed3\u6784\u5206\u6790<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-217638\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/02\/5-5.jpg\" alt=\"\" width=\"600\" height=\"194\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/02\/5-5.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/02\/5-5-300x97.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a) Co<sub>5<\/sub>Fe<sub>3<\/sub>Cr<sub>2<\/sub>\u4e0d\u540c\u7535\u538b\u4e0b\u7c7b\u539f\u4f4dL-edge EELS\u8c31\u56fe\u3002<\/p>\n<p>b)\u4e0d\u540c\u7535\u4f4d\u4e0bL<sub>3<\/sub>\/L<sub>2<\/sub>\u7684\u6bd4\u4f8b\u3002<\/p>\n<p>c)\u4e0d\u540c\u50ac\u5316\u5242\u57280.5 M KHCO<sub>3<\/sub>\u4e2d\u6027\u7535\u89e3\u6db2\u4e0b\u7684LSV\u66f2\u7ebf\u3002<\/p>\n<p><strong><b>\u3010\u5c0f\u7ed3\u3011<\/b><\/strong><\/p>\n<p>\u7efc\u4e0a\u6240\u8ff0\uff0c\u65e0\u8bba\u662f\u5728\u78b1\u6027\u8fd8\u662f\u4e2d\u6027\u7535\u89e3\u8d28\u4e2d\uff0c\u94ec\u90fd\u5728\u94b4\u94c1\u94ec\u4e09\u5143\u6c22\u6c27\u5316\u7269\uff08(\u7f9f\u57fa\u6c27\u5316\u7269\u50ac\u5316\u5242\u4e2d\u8d77\u7740\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\u3002DFT\u6a21\u62df\u7ed3\u679c\u8868\u660e\uff0c\u94ec\u53ef\u4ee5\u4fc3\u8fdb\u94b4\u5728OER\u6761\u4ef6\u4e0b\u7684\u4ef7\u6001\u8f6c\u53d8\uff0c\u5e76\u901a\u8fc7\u7535\u5b50\u534f\u540c\u4f5c\u7528\u63d0\u9ad8\u94b4\u7684\u6d3b\u6027\u3002\u5b9e\u9a8cX\u5c04\u7ebf\u5149\u8c31\u7ed3\u679c\u8bc1\u5b9e\uff0c\u94ec\u4fc3\u8fdb\u94b4\u5360\u636e\u5728\u516b\u9762\u4f53\u4f4d\u70b9\uff0c\u5e76\u8c03\u63a7\u94b4\u7684\u7535\u5b50\u7ed3\u6784\u3002\u5728\u6700\u4f73\u914d\u6bd4\u4e0b\uff0cCo<sub>5<\/sub>Fe<sub>3<\/sub>Cr<sub>2<\/sub>\u6c22\u6c27\u5316\u7269\u50ac\u5316\u5242\u5728\u03b7 = 10\u65f6\u53ef\u63d0\u4f9b232mV\u4f4e\u8fc7\u7535\u4f4d\uff0c \u94b4\u57fa\u8d28\u91cf\u6d3b\u5ea6\u4e3a1486.0 A g<sup>\u22121<\/sup>,TOF\u4e3a0.23 s<sup>\u22121<\/sup>\u3002\u51c6\u539f\u4f4dEELS\u7814\u7a76\u9a8c\u8bc1\u4e86\u6700\u521d\u7684DFT\u9884\u6d4b\uff0c\u5373\u94ec\u52a0\u901f\u4e86Co<sup>2+<\/sup>\u7684\u53bb\u8d28\u5b50\u8026\u5408\u9884\u6c27\u5316\u4e3aCo<sup>3+<\/sup>\u6216Co<sup>3+\u03b4<\/sup>\uff0c\u4ece\u800c\u663e\u8457\u63d0\u9ad8\u4e86\u50ac\u5316\u6d3b\u6027\u3002\u4e86\u89e3\u94ec\u7684\u4f5c\u7528\u548c\u786e\u5b9a\u94b4\u94c1\u94ec\u4e09\u5143\u6c22\u6c27\u5316\u7269\u7684\u6700\u4f73\u5143\u7d20\u7ec4\u6210\uff0c\u4e3a\u5176\u4f5c\u4e3a\u9ad8\u6548OER\u50ac\u5316\u5242\u7684\u5b9e\u9645\u80fd\u91cf\u5b58\u50a8\u548c\u8f6c\u5316\u5e94\u7528\u6253\u5f00\u4e86\u5927\u95e8\u3002<\/p>\n<p><strong><b>\u6587\u732e\u94fe\u63a5<\/b><\/strong>\uff1a<a href=\"https:\/\/doi.org\/10.1002\/aenm.202003412\"><u>Co\u2013Fe\u2013Cr(oxy)Hydroxides as Efficient Oxygen Evolution Reaction Catalysts<\/u><\/a>\uff08Adv. Eng. Mater.\uff0c2021\uff0cDOI\uff1a10.1002\/aenm.202003412\uff09<\/p>\n<p>\u56e2\u961f\u5728\u8be5\u9886\u57df\u5de5\u4f5c\u6c47\u603b<\/p>\n<p>\u591a\u5143\u8fc7\u6e21\u91d1\u5c5e\u6790\u6c27\u53cd\u5e94\u548c\u6c27\u8fd8\u539f\u50ac\u5316\u5242<\/p>\n<ol>\n<li>Co-Fe-Cr (oxy)hydroxides as efficient oxygen evolution reaction catalysts\uff0c\uff08 Eng. Mater.\uff0c2021\uff0cDOI\uff1a10.1002\/aenm.202003412\uff09<\/li>\n<li>Octahedral coordinated trivalent cobalt enriched multimetal\u00a0oxygen-evolution catalysts,\u00a0Advanced Energy Materials,\u00a02020, 17,\u00a02002593 DOI\uff1a1002\/aenm.202002593<\/li>\n<li>Catalytic activity atlas of ternary Co-Fe-V metal oxides for oxygen evolution reaction, \u200bJournal of Materials Chemistry A, 2020, 8, 15951-15961 DOI:1039\/D0TA04088F<\/li>\n<li>3dtransition-metal-mediated columbite nanocatalysts\u00a0for decentralized electrosynthesis of hydrogen peroxide\uff0cSmall, 2021, DOI:1002\/smll.202007249<\/li>\n<\/ol>\n<p>\u57fa\u4e8e\u5206\u5b50\u50ac\u5316\u5242\u7684\u975e\u5747\u76f8\u50ac\u5316\u5242<\/p>\n<ol start=\"5\">\n<li>One-dimensional van der Waals heterostructures as efficient metal-free oxygen\uff0cACS\u00a0Nano, 2021, DOI:1021\/acsnano.0c10242<\/li>\n<li>The intrinsic activity of metal centers in metal\u2013nitrogen\u2013carbon single-atom catalysts for hydrogen peroxide synthesis, Journal of the American Chemical Society,\u00a02020, 142, 52, 21861\u201321871DOI: 1021\/jacs.0c10636<\/li>\n<\/ol>\n<p>\u7814\u7a76\u56e2\u961f\u7f51\u7ad9\uff1a <a href=\"https:\/\/yuanchenlab.org\"><u>https:\/\/yuanchenlab.org<\/u><\/a><\/p>\n<p>\u672c\u6587\u7531<strong><b>\u6728\u6587\u97ec<\/b><\/strong>\u7ffb\u8bd1\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c<u>\u6295\u7a3f\u90ae\u7bb1<\/u><u>tougao@cailiaoren.com<\/u><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u6790\u6c27\u53cd\u5e94\uff08OER\uff09\u662f\u5f88\u591a\u80fd\u91cf\u8f6c\u6362\u548c\u5b58\u50a8\u8bbe\u5907\u7684\u5173\u952e\u63a7\u901f\u53cd\u5e94\uff0c\u5305\u62ec\u6c34\u7535\u89e3\u69fd\u548c\u53ef\u5145\u7535\u91d1\u5c5e-\u7a7a\u6c14\u7535\u6c60\u3002\u8fd9\u4e2a\u590d\u6742\u7684\u56db\u7535\u5b50\u53cd\u5e94\u6d89\u53ca\u591a\u79cd\u53cd\u5e94\u4e2d\u95f4\u4f53\u548c\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u50ac\u5316\u5242&#8230;<\/p>\n","protected":false},"author":2109,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[3369,2639,3066],"class_list":["post-217633","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-dft","tag-2639","tag-3066"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/217633"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/2109"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=217633"}],"version-history":[{"count":2,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/217633\/revisions"}],"predecessor-version":[{"id":217658,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/217633\/revisions\/217658"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=217633"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=217633"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=217633"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}