{"id":218252,"date":"2021-02-24T06:30:34","date_gmt":"2021-02-23T22:30:34","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=218252"},"modified":"2021-02-23T15:13:35","modified_gmt":"2021-02-23T07:13:35","slug":"aem%ef%bc%9a%e9%80%9a%e8%bf%87%e6%b0%af%e5%8c%96%e9%94%82%e6%ba%b6%e5%90%8e%e5%a4%84%e7%90%86%e5%88%b6%e5%a4%87%e6%b5%85%e5%8f%97%e4%bd%93%e5%9e%8b%e7%bc%ba%e9%99%b7cu2znsnsse4%e5%a4%aa%e9%98%b3","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=218252","title":{"rendered":"AEM\uff1a\u901a\u8fc7\u6c2f\u5316\u9502\u6eb6\u540e\u5904\u7406\u5236\u5907\u6d45\u53d7\u4f53\u578b\u7f3a\u9677Cu2ZnSn(S,Se)4\u592a\u9633\u80fd\u7535\u6c60"},"content":{"rendered":"<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-218254 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/02\/1-12-e1614045963373.png\" alt=\"\" width=\"600\" height=\"225\" \/><\/p>\n<p>\u7b2c\u4e00\u4f5c\u8005\uff1aMingrui He, Xian Zhang, Jialiang Huang<\/p>\n<p>\u901a\u8baf\u4f5c\u8005\uff1aXiaojing Hao,\u00a0Jinhyeok Kim, Shiyou Chen, Jianjun Li<\/p>\n<p>\u5408\u4f5c\u5355\u4f4d\uff1a\u65b0\u5357\u5a01\u5c14\u58eb\u5927\u5b66\uff0c\u97e9\u56fd\u5168\u5357\u56fd\u7acb\u5927\u5b66\uff0c\u534e\u4e1c\u5e08\u8303\u5927\u5b66\uff0c\u6089\u5c3c\u5927\u5b66\uff0c\u97e9\u56fd\u5149\u5dde\u79d1\u5b66\u6280\u672f\u9662<\/p>\n<p><strong>\u80cc\u666f\u4ecb\u7ecd<\/strong><\/p>\n<p>\u94dc\u950c\u9521\u786b\u7852\uff08CZTSSe\uff09\u6750\u6599\u7531\u4e8e\u5176\u4f4e\u5ec9\u7684\u4ef7\u683c\uff0c\u8fd1\u5e74\u6765\u6210\u4e3a\u8584\u819c\u592a\u9633\u7535\u6c60\u7814\u7a76\u7684\u70ed\u70b9\u3002\u7136\u800c\uff0c\u5728\u5408\u6210CZTSSe\u8fc7\u7a0b\u4e2d\u4f34\u968f\u7740\u5927\u91cf\u6676\u4f53\u7f3a\u9677\u7684\u4ea7\u751f\uff0c\u8fdb\u800c\u964d\u4f4e\u4e86\u7535\u6c60\u7684\u5149\u7535\u8f6c\u5316\u6548\u7387\u3002\u56e0\u6b64\uff0c\u5982\u4f55\u6709\u6548\u8c03\u63a7\u7f3a\u9677\u662f\u8be5\u9886\u57df\u7684\u91cd\u8981\u95ee\u9898\u3002<\/p>\n<p><strong>\u6587\u7ae0\u7b80\u4ecb<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c\u65b0\u5357\u5a01\u5c14\u58eb\u5927\u5b66Xiaojing Hao\u56e2\u961f\uff0c\u97e9\u56fd\u5168\u5357\u56fd\u7acb\u5927\u5b66Jinhyeok Kim\u56e2\u961f\u548c\u534e\u4e1c\u5e08\u8303\u5927\u5b66Shiyou Chen\u56e2\u961f\u901a\u8fc7\u4f7f\u7528\u6c2f\u5316\u9502\u6eb6\u540e\u5904\u7406CZTSSe\u5438\u6536\u5c42\uff0c\u5b9e\u73b0\u4e86\u66f4\u6d45\u7684\u53d7\u4f53\u578b\u7f3a\u9677\uff08Li<sub>Zn<\/sub>\uff09\uff0c\u63d0\u9ad8\u4e86P\u578b\u63ba\u6742\uff0c\u5c06CZTSSe\u592a\u9633\u80fd\u7535\u6c60\u6548\u7387\u63d0\u9ad8\u81f310.7%\u3002\u672c\u6587\u901a\u8fc7\u7eb3\u7c73\u5c3a\u5ea6\u7684\u5316\u5b66\u5206\u6790\uff08atom\u00a0probe tomography\uff09,\u7535\u5b66\u8868\u5f81\u5206\u6790\uff08admittance spectra\uff09\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u9610\u660e\u4e86Li\u5728CZTSSe\u63ba\u6742\u673a\u5236\u3002\u7814\u7a76\u8868\u660e\uff0c\u901a\u8fc7\u8be5\u65b9\u6cd5\u53ef\u5b9e\u73b0Li\u5728CZTSSe\u6676\u754c\u548c\u6676\u4f53\u5185\u90e8\u7684\u5747\u5300\u63ba\u6742\uff0c\u5e76\u5b9e\u73b010%\u4ee5\u4e0a\u7684\u63ba\u6742\u6548\u7387\u30020.006% \u7684Li\u5143\u7d20\u63ba\u6742\u91cf\u5c31\u80fd\u5f15\u516510<sup>17<\/sup>\u00a0cm<sup>-3<\/sup>\u7684Li<sub>Zn<\/sub>\u6d45\u53d7\u4e3b\u7f3a\u9677\uff0c\u4ece\u800c\u663e\u8457\u6539\u53d8CZTSSe\u6750\u6599\u7684P-\u578b\u5bfc\u7535\u673a\u5236\u548c\u592a\u9633\u7535\u6c60\u5668\u4ef6\u6027\u80fd\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a\u201cHigh Efficiency Cu2ZnSn(S,Se)4 Solar Cells with Shallow LiZn Acceptor Defects Enabled by Solution-Based Li Post-Deposition Treatment\u201d\u53d1\u8868\u5728\u4e86Adv.\u00a0Eng. Mater<strong><b>.<\/b><\/strong>\u4e0a\u3002<\/p>\n<p><strong>\u56fe\u6587\u5bfc\u8bfb<\/strong><\/p>\n<p>\u56fe\u4e00 Li\u540e\u5904\u7406\u65b9\u6cd5<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-218255 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/02\/2-12-e1614046014357.png\" alt=\"\" width=\"600\" height=\"268\" \/><\/p>\n<p>a)-d)LiCl\u6eb6\u6db2\u5de5\u827a\u793a\u610f\u56fe\u53caLi\u540e\u5904\u7406\u65b9\u6cd5<\/p>\n<p>e)\u672a\u5904\u7406\u7684CZTSSe\u5438\u6536\u5c42<\/p>\n<p>f)Li\u63ba\u6742\u7684CZTSSe\u5438\u6536\u5c42<\/p>\n<p>\u56fe\u4e8c Li\u5728\u7535\u6c60\u5668\u4ef6\u7684\u5206\u5e03<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-218256 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/02\/3-12-e1614046077574.png\" alt=\"\" width=\"600\" height=\"227\" \/><\/p>\n<p>a) CZTSSe\u548cb)\u9502\u63ba\u6742\u7684CZTSSe\u592a\u9633\u80fd\u7535\u6c60\u7684\u5143\u7d20\u5206\u5e03<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-218257 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/02\/4-10-e1614046118690.png\" alt=\"\" width=\"600\" height=\"434\" \/><\/p>\n<p>Li\u5728CZTSSe\u592a\u9633\u80fd\u7535\u6c60\u4e2d\u76843D\u5206\u5e03\u56fe<\/p>\n<p>\u56fe\u4e09 \u7535\u6c60\u5668\u4ef6\u5149\u4f0f\u6027\u80fd<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-218258 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/02\/5-6-e1614046185233.png\" alt=\"\" width=\"600\" height=\"709\" \/><\/p>\n<p>a)\u7535\u6c60\u5668\u4ef6\u7684J-V\u66f2\u7ebf<\/p>\n<p>b)\u7535\u6c60\u5668\u4ef6\u7684EQE\u66f2\u7ebf<\/p>\n<p>c)\u7535\u6c60\u5668\u4ef6\u7684\u5e26\u9699<\/p>\n<p>d)\u7535\u6c60\u5668\u4ef6\u7684Drive level capacity profiling<\/p>\n<p>e)\u7535\u6c60\u5668\u4ef6\u7684Suns-Voc<\/p>\n<p>f)\u7535\u6c60\u5668\u4ef6\u7684Time-resolved photoluminescence<\/p>\n<p>\u56fe\u56db \u7f3a\u9677\u8868\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-218259 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/02\/6-6-e1614046295217.png\" alt=\"\" width=\"600\" height=\"462\" \/><\/p>\n<p>a)-b)\u7535\u6c60\u5668\u4ef6\u7684Admittance spectra<\/p>\n<p>c)\u7535\u6c60\u5668\u4ef6\u7684Arrhenius plots<\/p>\n<p>d)\u7535\u6c60\u5668\u4ef6\u7684\u7f3a\u9677\u6001\u5bc6\u5ea6<\/p>\n<p>\u56fe\u4e94 \u7406\u8bba\u8ba1\u7b97<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-218260 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/02\/7-5-e1614046337712.png\" alt=\"\" width=\"600\" height=\"259\" \/><\/p>\n<p>a)\u4e0d\u540cLi\u76f8\u5173\u7f3a\u9677\u7684\u5f62\u6210\u80fd<\/p>\n<p>b)\u4e0d\u540cLi\u76f8\u5173\u7f3a\u9677\u5728\u5e26\u9699\u7684\u4f4d\u7f6e<\/p>\n<p>c)Li<sub>Zn<\/sub>\u00a0\u7f3a\u9677\u5728\u6676\u683c\u7684\u4f4d\u7f6e<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aHigh Efficiency Cu2ZnSn(S,Se)4\u00a0Solar Cells with Shallow LiZn\u00a0Acceptor Defects Enabled by Solution\u2010Based Li Post\u2010Deposition Treatment.\u00a0Adv. Energy Mater.\u00a02021, 2003783.\u00a0<a href=\"https:\/\/doi.org\/10.1002\/aenm.202003783\">https:\/\/doi.org\/10.1002\/aenm.202003783<\/a><\/p>\n<p>\u56e2\u961f\u5728\u8be5\u9886\u57df\u7684\u76f8\u5173\u6587\u732e\u63a8\u8350<\/p>\n<p>1. Li, J., Huang, Y., Huang, J., Liang, G., Zhang, Y., Rey, G., &#8230; &amp; Green, M. A. (2020). Defect Control for 12.5% Efficiency Cu2ZnSnSe4 Kesterite Thin\u2010Film Solar Cells by Engineering of Local Chemical Environment.\u00a0Advanced Materials,\u00a032(52), 2005268.<\/p>\n<p>2. Liu, F., Zeng, Q., Li, J., Hao, X., Ho-Baillie, A., Tang, J., &amp; Green, M. A. (2020). Emerging inorganic compound thin film photovoltaic materials: Progress, challenges and strategies.\u00a0Materials Today.<\/p>\n<p>3. Tang, R., Wang, X., Lian, W., Huang, J., Wei, Q., Huang, M., &#8230; &amp; Chen, T. (2020). Hydrothermal deposition of antimony selenosulfide thin films enables solar cells with 10% efficiency.\u00a0Nature Energy,\u00a05(8), 587-595.<\/p>\n<p>4. Zeng, Q., Lai, Y., Jiang, L., Liu, F., Hao, X., Wang, L., &amp; Green, M. A. (2020). Integrated Photorechargeable Energy Storage System: Next\u2010Generation Power Source Driving the Future.\u00a0Advanced Energy Materials,\u00a010(14), 1903930.<\/p>\n<p>5. Deng, H., Zeng, Y., Ishaq, M., Yuan, S., Zhang, H., Yang, X., &#8230; &amp; Tang, J. (2019). Quasiepitaxy strategy for efficient full\u2010inorganic Sb2S3 solar cells.\u00a0Advanced Functional Materials,\u00a029(31), 1901720.<\/p>\n<p>6. Cui, X., Sun, K., Huang, J., Yun, J. S., Lee, C. Y., Yan, C., &#8230; &amp; Hao, X. (2019). Cd-Free Cu 2 ZnSnS 4 solar cell with an efficiency greater than 10% enabled by Al 2 O 3 passivation layers.\u00a0Energy &amp; Environmental Science,\u00a012(9), 2751-2764.<\/p>\n<p>7. Liu, X., Zhang, Y., Shi, L., Liu, Z., Huang, J., Yun, J. S., &#8230; &amp; Hao, X. (2018). Exploring Inorganic Binary Alkaline Halide to Passivate Defects in Low\u2010Temperature\u2010Processed Planar\u2010Structure Hybrid Perovskite Solar Cells.\u00a0Advanced Energy Materials,\u00a08(20), 1800138.<\/p>\n<p>8. Yan, C., Huang, J., Sun, K., Johnston, S., Zhang, Y., Sun, H., &#8230; &amp; Hao, X. (2018). Cu 2 ZnSnS 4 solar cells with over 10% power conversion efficiency enabled by heterojunction heat treatment.\u00a0Nature Energy,\u00a03(9), 764-772.<\/p>\n<p>9. Park, J., Huang, J., Yun, J., Liu, F., Ouyang, Z., Sun, H., &#8230; &amp; Hao, X. (2018). The Role of Hydrogen from ALD\u2010Al2O3 in Kesterite Cu2ZnSnS4 Solar Cells: Grain Surface Passivation.\u00a0Advanced Energy Materials,\u00a08(23), 1701940.<\/p>\n<p>10. Gu, Y., Shen, H., Ye, C., Dai, X., Cui, Q., Li, J., &#8230; &amp; Lin, H. (2018). All\u2010Solution\u2010Processed Cu2ZnSnS4 Solar Cells with Self\u2010Depleted Na2S Back Contact Modification Layer.\u00a0Advanced Functional Materials,\u00a028(14), 1703369.<\/p>\n<p>11. Liu, F., Yan, C., Huang, J., Sun, K., Zhou, F., Stride, J. A., &#8230; &amp; Hao, X. (2016). Nanoscale microstructure and chemistry of Cu2ZnSnS4\/CdS interface in kesterite Cu2ZnSnS4 solar cells.\u00a0Advanced Energy Materials,\u00a06(15), 1600706.<\/p>\n<p>12. Sun, K., Yan, C., Liu, F., Huang, J., Zhou, F., Stride, J. A., &#8230; &amp; Hao, X. (2016). Over 9% efficient kesterite Cu2ZnSnS4 solar cell fabricated by using Zn1\u2013xCdxS buffer layer.\u00a0Advanced Energy Materials,\u00a06(12), 1600046.<\/p>\n<p>\u672c\u6587\u7531\u4f5c\u8005\u6295\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u7b2c\u4e00\u4f5c\u8005\uff1aMingrui He, Xian Zhang, Jialiang Huang \u901a\u8baf\u4f5c\u8005\uff1aXiaojing Hao,\u00a0Jinhyeok Kim, Shi&#8230;<\/p>\n","protected":false},"author":11454,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-218252","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/218252"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=218252"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/218252\/revisions"}],"predecessor-version":[{"id":218268,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/218252\/revisions\/218268"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=218252"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=218252"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=218252"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}