{"id":218413,"date":"2021-02-26T08:50:57","date_gmt":"2021-02-26T00:50:57","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=218413"},"modified":"2021-03-03T11:47:29","modified_gmt":"2021-03-03T03:47:29","slug":"%e4%b8%ad%e7%a7%91%e5%a4%a7%e5%a4%a7%e8%bf%9e%e5%8c%96%e7%89%a9%e6%89%80-science%e6%8f%ad%e7%a4%ba%e7%94%b5%e5%ad%90%e8%a7%92%e5%8a%a8%e9%87%8f%e5%af%b9%e5%8f%8d%e5%ba%94%e5%8a%a8%e5%8a%9b","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=218413","title":{"rendered":"\u4e2d\u79d1\u5927&\u5927\u8fde\u5316\u7269\u6240 Science:\u63ed\u793a\u7535\u5b50\u89d2\u52a8\u91cf\u5bf9\u53cd\u5e94\u52a8\u529b\u5b66\u7684\u5f71\u54cd"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u5206\u5b50\u53cd\u5e94\u52a8\u529b\u5b66\u662f\u5728\u5fae\u89c2\u5c42\u6b21\u4e0a\u5bf9\u5316\u5b66\u53cd\u5e94\u8fc7\u7a0b\u8fdb\u884c\u52a8\u529b\u5b66\u7814\u7a76\u3002\u53d1\u5c55\u81f3\u4eca\uff0c\u5316\u5b66\u53cd\u5e94\u52a8\u529b\u5b66\u7684\u7814\u7a76\u7ecf\u5386\u4e86\u4ece\u4ea7\u7269\u91cf\u5b50\u632f\u52a8\u6001\u5206\u8fa8\u7387\u5230\u8f6c\u52a8\u6001\u5206\u8fa8\u7387\u7684\u53d1\u5c55\u3002\u7136\u800c\uff0c\u7535\u5b50\u81ea\u65cb-\u8f68\u9053\u4f5c\u7528\u5728\u5316\u5b66\u53cd\u5e94\u52a8\u529b\u5b66\u4e2d\u6240\u626e\u6f14\u7684\u89d2\u8272\u4f9d\u7136\u662f\u4e00\u4e2a\u6709\u8da3\u4e14\u6709\u5f85\u89e3\u51b3\u7684\u95ee\u9898\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n

\u8fd1\u671f\uff0c\u4e2d\u79d1\u5927\u7684\u738b\u5174\u5b89\u548c\u4e2d\u79d1\u9662\u5927\u8fde\u5316\u7269\u6240\u7684\u6768\u5b66\u660e\u3001\u5b59\u5fd7\u521a<\/strong>\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u5408\u4f5c\u7814\u7a76\u4e86\u5177\u6709\u5206\u6ce2\u5171\u632f\u7684F+HD\u53cd\u5e94\u7684\u52a8\u529b\u5b66\u8fc7\u7a0b\uff0c\u5e76\u9996\u6b21\u53d1\u73b0\u7535\u5b50\u89d2\u52a8\u91cf\u5bf9\u5316\u5b66\u53cd\u5e94\u5fae\u5206\u622a\u9762\u7684\u5f71\u54cd\u3002\u5229\u7528\u9ad8\u5206\u8fa8\u6210\u50cf\u6280\u672f\uff0c\u7814\u7a76\u4eba\u5458\u5728F + HD \u2192 HF + D\u53cd\u5e94\u4e2d\u5206\u6ce2\u5171\u632f\u9644\u8fd1\u7684\u5fae\u5206\u622a\u9762\u4e2d\u89c2\u5bdf\u5230\u4e86\u7279\u6b8a\u7684\u9a6c\u8e44\u94c1\u5f62\u56fe\u6848\u3002\u8fdb\u4e00\u6b65\u5730\u7406\u8bba\u5206\u6790\u53d1\u73b0\uff0c\u8fd9\u4e00\u7279\u6b8a\u56fe\u6848\u6e90\u81ea\u4e8eF\u539f\u5b50\u7684\u7535\u5b50\u89d2\u52a8\u91cf\u6548\u5e94\u80fd\u591f\u5c06\u5355\u4e00\u7684\u5206\u6ce2\u5171\u632f\u53ef\u4ee5\u53d8\u6210\u5177\u6709\u56db\u91cd\u7cbe\u7ec6\u7ed3\u6784\u7684\u5206\u6ce2\u5171\u632f\uff0c\u4ece\u800c\u6539\u53d8\u5316\u5b66\u53cd\u5e94\u4ea7\u7269\u7684\u89d2\u5ea6\u5206\u5e03\u3002\u8fd9\u4e00\u53d1\u73b0\u4e3a\u201c\u81ea\u65cb-\u8f68\u9053\u76f8\u4e92\u4f5c\u7528\u5f71\u54cd\u53cd\u5e94\u52a8\u529b\u5b66\u201d\u63d0\u4f9b\u4e86\u4e00\u4e2a\u5178\u578b\u7684\u6848\u4f8b\u30022021\u5e7402\u670826\u65e5\uff0c\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201cQuantum interference between spin-orbit split partial waves in the F + HD <\/strong>\u2192<\/strong> HF + D reaction<\/strong>\u201d\u7684\u6587\u7ae0\u5728\u7ebf\u53d1\u8868\u5728Science<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb<\/strong>\u3011<\/p>\n

\u56fe1 \u78b0\u649e\u80fd\u4e3a2.10 kcal\/mol\u6c34\u5e73\u7684F + HD \u2192 HF + D\u53cd\u5e94\u4e2d\u7684D-\u539f\u5b50\u4ea7\u7269<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>2<\/strong> F + HD <\/strong>\u2192 HF + D\u53cd\u5e94\u7684\u5b9e\u9a8c\u548c\u7406\u8bbaDCSs\u5206\u6790\u6bd4\u8f83<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>3 <\/strong>HF<\/strong>\u4ea7\u7269\u901a\u9053\u7684\u51e0\u7387\u51fd\u6570<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>4 <\/strong>\u5171\u632f\u4ecb\u5bfc\u53cd\u5e94\u673a\u5236\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>5 HF<\/strong>\u901a\u9053\u7684<\/strong>DCSs<\/strong><\/p>\n

\"\"<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aQuantum interference between spin-orbit split partial waves in the F + HD \u2192 HF + D reaction<\/a>\uff08Science, 2021, DOI: 10.1126\/science.abf4205\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u5b66\u672f\u7ec4NanoCJ\u4f9b\u7a3f\u3002<\/p>\n

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