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\u7528\u4e8eHER\/HOR\u7684\u4eff\u751f\u7535\u50ac\u5316\u5242<\/b><\/strong><\/p>\n

\u6c22\u6c27\u5316\u53cd\u5e94\uff08HOR\uff09\u548c\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u90fd\u6d89\u53ca\u5230\u4e86\u9178\u6027\u4ecb\u8d28\u4e2d\u7684\u8d28\u5b50\u6216\u8005\u78b1\u6027\u4ecb\u8d28\u4e2d\u7684\u6c22\u6c27\u6839\u79bb\u5b50\u3002\u4e00\u822c\u800c\u8a00\uff0c\u4eba\u4eec\u4f1a\u5229\u7528\u94c2\u50ac\u5316\u8fd8\u539f\u9178\u6765\u4ea7\u751f\u5206\u5b50\u6c22\uff0c\u4ece\u800c\u5b9e\u73b0\u80fd\u6e90\u50a8\u5b58\u548c\u5229\u7528\u3002\u7136\u800c\uff0c\u94c2\u7684\u6210\u672c\u5f88\u9ad8\uff0c\u5f88\u96be\u5b9e\u73b0\u666e\u904d\u7684\u4ea7\u4e1a\u5316\u3002\u800c\u5728\u81ea\u7136\u754c\u4e2d\uff0c\u6c22\u5316\u9176\uff08hydrogenase\uff09\u80fd\u591f\u5229\u7528\u6765\u6e90\u4e30\u5bcc\u7684\u94c1\u6216\u8005\u954d\uff0c\u5b9e\u73b0\u5bf9\u8d28\u5b50\u9012\u9001\u7684\u7cbe\u786e\u63a7\u5236\uff0c\u4ece\u800c\u50ac\u5316\u4ea7\u751f\u6c22\u6c14\u3002\u53d7\u5176\u7ed3\u6784\u542f\u53d1\uff0c\u4eba\u4eec\u53ef\u4ee5\u8bbe\u8ba1\u9ad8\u6548\u4ea7\u6c22\u7684\u5206\u5b50\u50ac\u5316\u5242\u3002\u6700\u5178\u578b\u7684\u5c31\u662f\u7f8e\u56fd\u592a\u5e73\u6d0b\u897f\u5317\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u7684D. L. Dubois<\/b><\/strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u5f00\u53d1\u7684\u4e00\u7cfb\u5217\u954d\u57fa\u50ac\u5316\u5242[5]<\/sup>\u3002\u4ed6\u4eec\u5408\u6210\u4e86\u4ee5[Ni(PPh<\/sup>2<\/sub>NPh<\/sup>)2<\/sub>](BF4<\/sub>)2<\/sub>\u4e3a\u4ee3\u8868\u7684\u954d\u590d\u5408\u7269\uff0c\u5229\u7528\u8d28\u5b50\u5316\u4e8c\u7532\u57fa\u7532\u9170\u80fa\u4f5c\u4e3a\u8d28\u5b50\u6e90\u50ac\u5316\u4ea7\u751f\u6c22\u6c14\uff0c\u5176\u5468\u8f6c\u9891\u7387\u5728\u7eaf\u4e59\u8148\u548c\u542b\u6c34\u4e59\u8148\uff08\u6c34\u6d53\u5ea6\u4e3a1.2 M\uff09\u4e2d\u5206\u522b\u53ef\u4ee5\u8fbe\u523033000\/s\u548c106000\/s\u3002\u7814\u7a76\u663e\u793a\uff0c\u5728\u91d1\u5c5e\u4e2d\u5fc3\u5468\u56f4\u4f5c\u4e3a\u8def\u6613\u65af\u78b1\u7684\u4e0b\u5782\u6c28\u57fa\u8d77\u5230\u4e86\u8d28\u5b50\u8f6c\u53d1\u8bbe\u5907\u7684\u529f\u80fd\uff0c\u80fd\u591f\u663e\u8457\u63d0\u9ad8\u6c22\u952e\u7684\u65ad\u952e\u548c\u7ed3\u5408\u80fd\u529b\uff0c\u4ece\u800c\u5927\u5e45\u63d0\u5347\u6750\u6599\u7684\u50ac\u5316\u6027\u80fd\u3002<\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u56fe3<\/b><\/strong>\u00a0[Ni(PPh<\/sup>2<\/sub>NPh<\/sup>)2<\/sub>](BF4<\/sub>)2<\/sub>\u22192CH3<\/sub>CN\u7684\u56fa\u6001\u5206\u5b50\u7ed3\u6784[<\/sup>5]<\/sup><\/p>\n

\u8fd1\u671f\uff0c\u6cd5\u56fd\u683c\u52d2\u8bfa\u5e03\u5c14\u5927\u5b66\u7684Vincent Artero<\/b><\/strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u5728\u5148\u524d\u7814\u7a76\u7684\u57fa\u7840\u4e0a\u91cd\u65b0\u8bbe\u8ba1\u4e86\u4e00\u79cd\u7528\u4e8e\u6790\u6c22\u53cd\u5e94\u7684\u7eb3\u7c73\u6750\u6599[<\/sup>6]<\/sup>\u3002\u9996\u5148\uff0c\u914d\u4f53\u5229\u7528\u9170\u80fa\u952e\u88ab\u56fa\u5b9a\u5230\u591a\u58c1\u78b3\u7eb3\u7c73\u7ba1\u4e0a\uff0c\u968f\u540e\u954d\u91d1\u5c5e\u4e2d\u5fc3\u901a\u8fc7[Ni(CH3<\/sub>CN)6<\/sub>]2+<\/sup>\u6216\u8005[Ni(H2<\/sub>O)6<\/sub>]2+<\/sup>\u5f15\u5165\u3002\u7814\u7a76\u4eba\u5458\u5c06\u8fd9\u4e9b\u954d\u57fa\u590d\u5408\u7269\u7684\u6d3b\u6027\u4e0e\u5546\u7528\u7684Pt\/C\uff08\u8d28\u91cf\u5206\u6570\u4e3a46%\uff09\u5728\u65cb\u8f6c\u5706\u76d8\u7535\u6781\u4e0a\u8fdb\u884c\u6bd4\u8f83\uff0c\u5176\u4e2d\uff0c\u7535\u6781\u4e0a\u94c2\u7684\u91cf\u7ea6\u4e3a2.5 x10–<\/sup>7<\/sup>\u00a0mol cm–<\/sup>2<\/sup>\uff0c\u800c\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u954d\u5728\u7535\u6781\u4e0a\u7684\u603b\u91cf\u8981\u6bd4\u94c2\u4f4e\u5341\u500d\u5de6\u53f3\u3002\u5728\u5ba4\u6e29\u4e0b\uff0c\u4eff\u751f\u7535\u50ac\u5316\u5242\u7684\u6d3b\u6027\u6bd4\u5546\u7528Pt\/C\u7684\u4f4e\u4e00\u4e2a\u6570\u91cf\u7ea7\uff1b\u572885\u6444\u6c0f\u5ea6\u7684\u64cd\u4f5c\u6761\u4ef6\u4e0b\uff0c\u4eff\u751f\u50ac\u5316\u5242\u5bf9\u6c22\u6c14\u6c27\u5316\u7684\u6d3b\u6027\u53ea\u6bd4\u5546\u7528Pt\/C\u4f4e30%\u5de6\u53f3\uff0c\u800c\u5728\u4ea7\u6c22\u65b9\u9762\u7684\u6027\u80fd\u5374\u6bd4\u5546\u7528\u50ac\u5316\u5242\u8fd8\u9ad8\u51fa20%\u5de6\u53f3\u3002<\/p>\n

\u7528\u4e8e\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u7684\u4eff\u751f\u7535\u50ac\u5316\u5242<\/b><\/strong><\/p>\n

\u4e8c\u6c27\u5316\u78b3\u7535\u5316\u5b66\u8fd8\u539f\u80fd\u591f\u6539\u5584\u6e29\u5ba4\u6548\u5e94\u3001\u4ea7\u751f\u6709\u7528\u7684\u5316\u5b66\u54c1\uff0c\u4e00\u76f4\u662f\u79d1\u7814\u4eba\u5458\u5173\u6ce8\u7684\u70ed\u95e8\u7814\u7a76\u65b9\u5411\u3002\u8fd9\u4e00\u8fc7\u7a0b\u6d89\u53ca\u5230\u5c06\u4e8c\u6c27\u5316\u78b3\u8f6c\u53d8\u6210\u6d3b\u5316\u78b3\u5f62\u5f0f\u7684\u591a\u8d28\u5b50\u548c\u591a\u7535\u5b50\u8def\u5f84\uff0c\u5177\u6709\u7f13\u6162\u52a8\u529b\u5b66\u7279\u70b9\uff0c\u5e76\u5bf9\u8fd8\u539f\u7535\u52bf\u8981\u6c42\u6781\u9ad8\u3002\u7279\u522b\u662f\u5c06\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u6210\u4e00\u6c27\u5316\u78b3\uff0c\u4e00\u76f4\u662f\u8270\u5de8\u7684\u6311\u6218\u3002\u5728\u81ea\u7136\u754c\u4e2d\uff0c\u5149\u5408\u6210\u8fc7\u7a0b\u662f\u5b9e\u73b0\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u7684\u4e3b\u8981\u9014\u5f84\u3002\u5728\u8fd9\u4e00\u8fc7\u7a0b\u4e2d\uff0c\u9176\u4f1a\u96c6\u4e2d\u5728\u6d3b\u6027\u4f4d\u70b9\u9644\u8fd1\uff0c\u663e\u8457\u63d0\u9ad8\u5c40\u90e8\u4e8c\u6c27\u5316\u78b3\u6d53\u5ea6\uff0c\u4ece\u800c\u6700\u5c0f\u5316\u6c27\u6c14\/\u4e8c\u6c27\u5316\u78b3\u6bd4\u4f8b\uff0c\u5373\u4f7f\u5728\u6c27\u6c14\u5b58\u5728\u7684\u60c5\u51b5\u4e0b\u4e5f\u80fd\u5f3a\u5316\u4e8c\u6c27\u5316\u78b3\u8f6c\u5316\u6210\u8461\u8404\u7cd6\u7684\u80fd\u529b\u3002<\/p>\n

\u53d7\u6b64\u542f\u53d1\uff0c\u4eba\u4eec\u8fdb\u884c\u4e86\u5168\u65b0\u7684\u7535\u6781\u8bbe\u8ba1\uff0c\u4f7f\u5f97\u7535\u6781\u8868\u9762\u7684\u5c40\u90e8\u4e8c\u6c27\u5316\u78b3\u6d53\u5ea6\u80fd\u591f\u5927\u5e45\u63d0\u9ad8\uff0c\u4ece\u800c\u6539\u5584\u4e8c\u6c27\u5316\u78b3\u7535\u8fd8\u539f\u6027\u80fd\u3002\u5982\u65af\u5766\u798f\u5927\u5b66\u7684\u5d14\u5c79<\/b><\/strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09\u56e2\u961f\u4ece\u80ba\u90e8\u80ba\u6ce1\u7ed3\u6784\u4e2d\u83b7\u5f97\u7075\u611f[<\/sup>7]<\/sup>\uff0c\u8bbe\u8ba1\u4e86\u53ef\u589e\u52a0\u4e8c\u6c27\u5316\u78b3\u6d53\u5ea6\u7684\u65b0\u578b\u7535\u6781\u3002\u80ba\u6ce1\u7531\u8d85\u8584\u7684\u4e0a\u76ae\u7ec6\u80de\u819c\u6784\u6210\uff0c\u5177\u6709\u4f4e\u900f\u6c34\u6027\u548c\u9ad8\u6c14\u4f53\u6269\u6563\u80fd\u529b\u3002\u5728\u80ba\u5faa\u73af\u8fc7\u7a0b\u4e2d\uff0c\u5438\u5165\u7684\u7a7a\u6c14\u80fd\u591f\u8fc5\u901f\u5230\u8fbe\u80ba\u6ce1\u548c\u8840\u6db2\u7ec6\u80de\uff0c\u5728\u6b64\u8840\u7ea2\u86cb\u767d\u7ed3\u5408\u7a7a\u6c14\u4e2d\u7684\u6c27\u6c14\u5e76\u91ca\u653e\u4e8c\u6c27\u5316\u78b3\u3002\u800c\u5728\u7814\u7a76\u4eba\u5458\u8bbe\u8ba1\u7684\u80ba\u6ce1\u4eff\u751f\u7535\u6781\uff08\u7ea620-80\u7eb3\u7c73\u539a\uff09\u7ed3\u6784\u4e2d\uff0c\u4f5c\u4e3a\u50ac\u5316\u5242\u7684\u91d1\u7eb3\u7c73\u9897\u7c92\u5c42\uff08\u8d1f\u8f7d\u91cf\u7ea6\u4e3a0.15 mg cm–<\/sup>2<\/sup>\uff09\u88ab\u55b7\u6e85\u5728\u805a\u4e59\u70ef\u8584\u819c\u3002\u805a\u4e59\u70ef\u8584\u819c\u5177\u6709\u4eb2\u6c34\u6027\u548c\u4ea4\u9519\u7684\u7ea4\u7ef4\u7f51\u7edc\u7ed3\u6784\uff0c\u5141\u8bb8\u4e8c\u6c27\u5316\u78b3\u6beb\u65e0\u963b\u62e6\u5730\u6269\u6563\u5230\u50ac\u5316\u5242\u5c42\u4e2d\u3002\u4e3a\u4e86\u66f4\u8fdb\u4e00\u6b65\u5730\u590d\u5236\u5177\u6709\u53ef\u8f93\u8fd0\u6c14\u4f53\u7684\u5fae\u7ba1\u7ed3\u6784\u7684\u80ba\u6ce1\uff0c\u7814\u7a76\u4eba\u5458\u8fd8\u5c06\u91d1\u7eb3\u7c73\u9897\u7c92\u6d82\u8986\u7684\u805a\u4e59\u70ef\u8584\u819c\u8fdb\u884c\u6eda\u5236\u3001\u5bc6\u5c01\u5f62\u6210\u53cc\u5c42\u888b\u578b\u7ed3\u6784\u3002\u5206\u522b\u5229\u7528\u9634\u79bb\u5b50\u4ea4\u6362\u8584\u819c\u548c\u4e8c\u6c27\u5316\u78b3\u9971\u548c\u7684\u78b3\u9178\u6c22\u94be\uff080.5 M KHCO3<\/sub>\uff09\u4f5c\u4e3a\u5206\u79bb\u5668\u548c\u7535\u89e3\u8d28\uff0c\u8fd9\u4e00\u7535\u6781\u53ef\u5728H\u578b\u7535\u6c60\u4e2d\u5b8c\u6210\u4e8c\u6c27\u5316\u78b3\u7535\u8fd8\u539f\u8fc7\u7a0b\u3002\u6570\u636e\u663e\u793a\uff0c\u8be5\u7cfb\u7edf\u5bf9\u751f\u4ea7\u4e00\u6c27\u5316\u78b3\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u53ef\u8fbe\u523092%\u5de6\u53f3\uff0c\u5728-0.6 V vs. RHE\u5904\u7684\u7535\u6d41\u5bc6\u5ea6\u4ea6\u53ef\u8fbe\u5230-25 mA cm-2<\/sup>\u3002<\/p>\n

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\u53c2\u8003\u6587\u732e<\/b><\/strong><\/p>\n

[1] Bhunia S., et al. J. Am. Chem. Soc. 2018, 140, 30, 9444\u20139457<\/p>\n

[2] Wei\u00a0P.-J.,\u00a0et al. Angew. Chem. Int. Ed. 2014, 53, 1 \u2013 6.<\/p>\n

[3] Vinyard\u00a0D.J.,\u00a0et al. PNAS, 2019, 116, 38, 18917\u201318922.<\/p>\n

[4] Wang Y., et al. Adv. Sci., 2015, 2, 1500003.<\/p>\n

[5] Helm\u00a0M. L., et\u00a0al. Science, 2011, 333, 863-866.<\/p>\n

[6]\u00a0Huan T. N., et al. Energy Environ. Sci., 2016, 9, 940\u2013947.<\/p>\n

[7] Li\u00a0J., et\u00a0al.\u00a0Nat.\u00a0Catal.,\u00a02018,\u00a01, 592-600.<\/p>\n

[8] Roy S., et al. J. Am. Chem. Soc., 2017, 139, 3685\u20133696.<\/p>\n

[9] Dubey A., et al. ACS Catal., 2017, 7, 3864\u20133868.<\/p>\n

\u672c\u6587\u7531NanoCJ\u4f9b\u7a3f\u3002<\/p>\n

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