{"id":219053,"date":"2021-03-11T12:00:21","date_gmt":"2021-03-11T04:00:21","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=219053"},"modified":"2021-03-11T12:10:32","modified_gmt":"2021-03-11T04:10:32","slug":"%ef%bc%88%e5%b7%b2%e6%a0%a1%e7%a8%bf%e4%bb%b6%ef%bc%89%e9%bb%84%e7%bb%b4-%e9%99%88%e6%b0%b8%e5%8d%8e-%e5%86%89%e6%99%a8%e9%91%ab-adv-mater-%e7%bb%bc%e8%bf%b0%ef%bc%9a%e6%ba%b6%e5%89%82%e5%b7%a5","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=219053","title":{"rendered":"\u9ec4\u7ef4\/\u9648\u6c38\u534e\/\u5189\u6668\u946b Adv. Mater.\u7efc\u8ff0\uff1a\u6eb6\u5242\u5de5\u7a0b\u52a9\u529b\u5927\u6279\u91cf\u5236\u5907\u9499\u949b\u77ff\u592a\u80fd\u7535\u6c60\u7684\u6700\u65b0\u8fdb\u5c55"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u6709\u673a-\u65e0\u673a\u6742\u5316\u9499\u949b\u77ff\u6750\u6599\u5177\u6709\u5438\u6536\u7cfb\u6570\u9ad8\u3001\u5e26\u9699\u53ef\u8c03\u3001\u53cc\u6781\u6027\u7535\u8377\u8fc1\u79fb\u7387\u9ad8\u3001\u6fc0\u5b50\u7ed3\u5408\u80fd\u4f4e\u7b49\u4f18\u70b9\uff0c\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u592a\u9633\u80fd\u7535\u6c60\u3001\u53d1\u5149\u5668\u4ef6\u7b49\u5404\u79cd\u5149\u7535\u548c\u7535\u5b50\u5e94\u7528\u9886\u57df\u3002\u5176\u4e2d\uff0c\u9499\u949b\u77ff\u578b\u592a\u9633\u80fd\u7535\u6c60\uff08PSCs\uff09\u7684\u529f\u7387\u8f6c\u6362\u6548\u7387\uff08PCE\uff09\u9ad8\u8fbe25.5%\uff0c\u4e0e\u5927\u591a\u6570\u57fa\u4e8e\u5168\u65e0\u673a\u5149\u5438\u6536\u5242\u7684\u5149\u4f0f\u6280\u672f\u76f8\u5f53\u3002\u6b64\u5916\uff0c\u9499\u949b\u77ff\u8584\u819c\u7684\u6eb6\u6db2\u53ef\u52a0\u5de5\u6027\u6781\u5927\u7684\u7b80\u5316\u4e86PSCs\u7684\u6210\u819c\u5de5\u827a\uff0c\u964d\u4f4e\u4e86PSCs\u7684\u5236\u9020\u6210\u672c\u3002\u6700\u91cd\u8981\u7684\u662f\uff0c\u5176\u5728\u5236\u9020\u67d4\u6027\u5668\u4ef6\u65b9\u9762\u663e\u793a\u51fa\u5de8\u5927\u7684\u6f5c\u529b\u3002\u76ee\u524d\uff0c\u987a\u5e8f\u6c89\u79ef\u3001\u6c14\u76f8\u8f85\u52a9\u6eb6\u6db2\u5904\u7406\u7b49\u591a\u79cd\u6eb6\u6db2\u6210\u819c\u6280\u672f\u6765\u5236\u5907\u9ad8\u8d28\u91cf\u7684\u9499\u949b\u77ff\u8584\u819c\u3002\u9700\u6ce8\u610f\uff0c\u65e0\u8bba\u91c7\u7528\u54ea\u79cd\u6eb6\u6db2\u6280\u672f\uff0c\u6eb6\u5242\u90fd\u662f\u975e\u5e38\u91cd\u8981\u7684\uff0c\u5176\u4e2d\u6eb6\u5242\u7684\u7279\u6027\u5bf9\u6210\u819c\u8fc7\u7a0b\u4ee5\u53ca\u6c89\u79ef\u9499\u949b\u77ff\u8584\u819c\u7684\u8d28\u91cf\u8d77\u7740\u5173\u952e\u4f5c\u7528\u3002\u6eb6\u5242\u662f\u9499\u949b\u77ff\u524d\u9a71\u4f53\u6750\u6599\u6eb6\u89e3\u7684\u4ecb\u8d28\uff0c\u6eb6\u5242\u7684\u7279\u5b9a\u5b98\u80fd\u56e2\u5bf9\u6eb6\u5242\u4e0e\u9499\u949b\u77ff\u524d\u9a71\u4f53\u7684\u914d\u4f4d\u6709\u91cd\u8981\u5f71\u54cd\u3002\u540c\u65f6\uff0c\u6eb6\u5242\u7684\u6781\u6027\u51b3\u5b9a\u4e86\u5176\u914d\u4f4d\u80fd\u529b\uff0c\u800c\u6eb6\u5242\u7684\u914d\u4f4d\u80fd\u529b\u5bf9\u9499\u949b\u77ff\u7ed3\u6784\u7684\u7ed3\u6676\u6709\u5f88\u5927\u7684\u5f71\u54cd\uff0c\u5728\u5f88\u5927\u7a0b\u5ea6\u4e0a\u51b3\u5b9a\u4e86\u9499\u949b\u77ff\u6676\u4f53\u7684\u6210\u6838\u548c\u751f\u957f\u4ee5\u53ca\u6c89\u79ef\u7684\u9499\u949b\u77ff\u8584\u819c\u7684\u5f62\u8c8c\u3002\u56e0\u6b64\uff0c\u901a\u8fc7\u8c03\u8282\u6eb6\u5242\u7684\u7279\u6027\uff0c\u53ef\u4ee5\u6709\u6548\u5730\u63a7\u5236\u6eb6\u6db2\u5904\u7406\u9499\u949b\u77ff\u8584\u819c\u7684\u6210\u819c\u52a8\u529b\u5b66\u548c\u6210\u819c\u8d28\u91cf\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u897f\u5317\u5de5\u4e1a\u5927\u5b66\u9ec4\u7ef4\u9662\u58eb\u548c\u5189\u6668\u946b\u526f\u6559\u6388\u4ee5\u53ca\u5357\u4eac\u5de5\u4e1a\u5927\u5b66\u9648\u6c38\u534e\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba<\/strong>\u62a5\u9053\u4e86\u6709\u5173\u524d\u9a71\u4f53\u6eb6\u6db2\u6eb6\u5242\u5de5\u7a0b\u52a9\u529b\u5927\u9762\u79ef\u5236\u5907\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff08PSCs\uff09\u7684\u6700\u65b0\u7efc\u8ff0\u3002\u9996\u5148\uff0c\u4f5c\u8005\u91cd\u70b9\u4ecb\u7ecd\u4e86\u524d\u9a71\u4f53\u6eb6\u6db2\u6eb6\u5242\u5de5\u7a0b\u5728\u914d\u4f4d\u8c03\u63a7\u548c\u964d\u4f4e\u6bd2\u6027\u65b9\u9762\u7684\u7814\u7a76\u8fdb\u5c55\u3002\u63a5\u7740\uff0c\u4f5c\u8005\u7cfb\u7edf\u5730\u8ba8\u8bba\u4e86\u4e0d\u540c\u6eb6\u5242\u5728\u964d\u4f4e\u6eb6\u5242\u4f53\u7cfb\u6bd2\u6027\u3001\u8c03\u8282\u524d\u9a71\u4f53\u6eb6\u6db2\u7684\u914d\u4f4d\u6027\u80fd\u3001\u63a7\u5236\u9499\u949b\u77ff\u8584\u819c\u7684\u6210\u819c\u8fc7\u7a0b\u4ee5\u53ca\u8c03\u8282PSCs\u5149\u4f0f\u6027\u80fd\u65b9\u9762\u7684\u7269\u7406\u548c\u5316\u5b66\u7279\u6027\u3002\u6700\u540e\uff0c\u4f5c\u8005\u8fd8\u63d0\u4f9b\u4e86\u9499\u949b\u77ff\u524d\u9a71\u4f53\u6eb6\u6db2\u6eb6\u5242\u5de5\u7a0b\u5bf9\u9ad8\u6027\u80fdPSCs\u7684\u672a\u6765\u5de5\u4e1a\u751f\u4ea7\u7684\u91cd\u8981\u5c55\u671b\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u00a0\u201cSolvent Engineering of the Precursor Solution toward Large-Area Production of Perovskite Solar Cells\u201d\u00a0<\/strong>\u53d1\u5e03\u5728\u56fd\u9645\u8457\u540d\u671f\u520a\u00a0Adv. Mater.<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\u3001PSCs\u4e2d\u524d\u9a71\u4f53\u6eb6\u6db2\u6eb6\u5242\u5de5\u7a0b\u7684\u6700\u65b0\u8fdb\u5c55<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe\u4e8c\u3001\u9ad8D<\/em>N<\/sub>\u6eb6\u5242\u7684\u914d\u4f4d\u80fd\u529b<\/strong>
\n \"\"a\uff09\u5728\u6eb6\u5242\u6052\u5b9a\u84b8\u53d1\u901f\u7387\u4e0b\uff0c\u9499\u949b\u77ff\u524d\u9a71\u4f53\u6eb6\u6db2\u7684\u6d53\u5ea6\u53d8\u5316\u4e0e\u65f6\u95f4\u7684\u5173\u7cfb\uff1b<\/p>\n

b\uff09\u5728\u7f13\u6162\u548c\u5feb\u901f\u6eb6\u5242\u84b8\u53d1\u4e0b\uff0c\u4ece\u524d\u9a71\u4f53\u6eb6\u6db2\u4e2d\u751f\u957f\u7684\u9499\u949b\u77ff\u6676\u4f53\u7684\u6210\u6838\/\u751f\u957f\u7ade\u4e89\u6a21\u578b\uff1b<\/p>\n

c\uff09D<\/em>N<\/sub>\u548cPb2+<\/sup>\u914d\u4f4d\u80fd\u529b\u4e4b\u95f4\u7684\u5173\u7cfb\uff0c\u5176\u4e2d\u4e0d\u540c\u6eb6\u5242\u53ef\u5728\u4e0d\u540c\u52a0\u5de5\u6761\u4ef6\u4e0b\u4f7f\u7528\uff1b<\/p>\n

d\uff09D<\/em>N<\/sub>\u4e0ePb2+<\/sup>\u914d\u4f4d\u80fd\u529b\u4e4b\u95f4\u7684\u5173\u7cfb\uff0c\u5176\u4e2d\u5728\u4e0d\u540c\u52a0\u5de5\u6761\u4ef6\u4e0b\u53ef\u4ee5\u4f7f\u7528\u4e0d\u540c\u6eb6\u5242\uff1b<\/p>\n

e\uff09Ostwald\u6a21\u578b\u7684\u793a\u610f\u56fe\uff0c\u663e\u793a\u4e86\u9499\u949b\u77ff\u6676\u7c92\u968f\u7740\u9000\u706b\u65f6\u95f4\u7684\u52a8\u6001\u7c97\u5316\u8fc7\u7a0b\u3002<\/p>\n

\u56fe\u4e09\u3001\u4e0d\u540c\u6837\u54c1\u7684\u7406\u5316\u8868\u5f81<\/strong>
\n \"\"a\uff09\u7eafDMF\u3001PbI2<\/sub>-DMF\u7edc\u5408\u7269\u3001PbI2<\/sub>-MAI-DMF\u7edc\u5408\u7269\u548cMAPbI3<\/sub>\u7684\u5085\u7acb\u53f6\u53d8\u6362\u7ea2\u5916\uff08FTIR\uff09\u5149\u8c31\uff1b<\/p>\n

b\uff09\u968f\u7740MAI\u6d53\u5ea6\u4ece6-24\u00d710-3<\/sup> M\uff0cDMF\u4e2d250\u00d710-6<\/sup> M PbI2<\/sub>\u6eb6\u6db2\u7684\u5438\u6536\u5149\u8c31\uff1b<\/p>\n

c\uff09\u4e0d\u540c\u6837\u54c1\u7684Pb L<\/em>-III\u8fb9\u7f18X\u5c04\u7ebf\u5438\u6536\u5728\u8fd1\u8fb9\u7f18\u7ed3\u6784\uff08XANES\uff09\u5149\u8c31\uff1b<\/p>\n

d\uff09DMSO\u3001PbI2<\/sub>\u00b7DMSO\u548cMAI\u00b7PbI2<\/sub>\u00b7DMSO\u7684FTIR\u5149\u8c31\uff1b<\/p>\n

e\uff09\u5229\u7528\u4e0d\u540c\u6eb6\u5242\u5f62\u6210\u7684\u4e2d\u95f4\u76f8\u7684FTIR\u5149\u8c31\uff1b<\/p>\n

f\uff09\u5728\u524d\u9a71\u4f53\u6eb6\u6db2\u4e2d\u4ee5\u4e0d\u540cPbI2<\/sub>: DMSO\u6bd4\u6c89\u79ef\u5728NiO\/FTO\u57fa\u5e95\u4e0a\u7684MAPbI3<\/sub>\u8584\u819c\u7684SEM\u548c\u6a2a\u622a\u9762SEM\u56fe\u50cf\u3002<\/p>\n

\u56fe\u56db\u3001\u4f4eDN\u7684\u6eb6\u5242\u914d\u4f4d\u80fd\u529b<\/strong>
\n \"\"a\uff09\u4f7f\u7528\u5e38\u89c4\u9ad8\u6cb8\u70b9\u548c\u9ad8DN\u6781\u6027\u975e\u8d28\u5b50\u6eb6\u5242\u4ece\u524d\u9a71\u4f53\u6eb6\u6db2\u4e2d\u6c89\u79ef\u5927\u9762\u79efMAPbI3<\/sub>\u8584\u819c\u7684D-bar\u6d82\u5c42\u5de5\u827a\u793a\u610f\u56fe\uff1b<\/p>\n

b\uff09\u4f7f\u7528DMF\u3001DMA\u3001DMSO\u548cGBL\u7684\u6781\u6027\u975e\u8d28\u5b50\u6eb6\u5242\uff0c\u4ece\u4e0d\u540c\u7684\u524d\u9a71\u4f53\u6eb6\u6db2\u5236\u5907\u5e72\u71e5MAPbI3<\/sub>\u8584\u819c\u7684\u5149\u5b66\u663e\u5fae\u955c\u56fe\u50cf\uff1b<\/p>\n

c\uff09\u6eb6\u4e8e\u7eafACN\u548cACN\/MA\u4f5c\u4e3a\u6eb6\u5242\u7684CH3<\/sub>NH3<\/sub>I: PbI2<\/sub>\u9499\u949b\u77ff\u524d\u9a71\u4f53\u7684\u56fe\u7247\uff1b<\/p>\n

d\uff09\u4f7f\u7528ACN\/MA\u4f5c\u4e3a\u6eb6\u5242\uff0c\u901a\u8fc7\u65cb\u6d82\u4ece\u524d\u9a71\u4f53\u6eb6\u6db2\u4e2d\u6c89\u79efMAPbI3<\/sub>\u8584\u819c\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

e\uff09\u9ad8\u955c\u9762\u4e14\u65e0\u9488\u5b54\u7684MAPbI3<\/sub>\u8584\u819c\u7684\u4e00\u5f20125 cm2<\/sup>\u7684\u7167\u7247\uff1b<\/p>\n

f\uff09\u57fa\u4e8eACN\/MA\u7684PSCs\u5668\u4ef6\u7684\u7535\u6d41-\u7535\u538b\uff08J<\/em>–V<\/em>\uff09\u7279\u6027\uff1b<\/p>\n

g\uff09\u6c89\u79ef\u5728\u6d82\u6709SnO2<\/sub>\u7684FTO\u57fa\u677f\u4e0a\u7684MAPbI3<\/sub>\u8584\u819c\u7684\u56fe\u7247\uff1b<\/p>\n

h\uff09\u6bcf\u4e2a\u533a\u57df\u6027\u80fd\u6700\u4f73\u7684PSCs\u5668\u4ef6\u7684PCE\u3002<\/p>\n

\u56fe\u4e94\u3001\u57fa\u4e8e\u4e0d\u540c\u524d\u9a71\u4f53\u6eb6\u6db2\u7684PSCs\u7684\u6027\u80fd<\/strong>
\n \"\"a\uff09MMA\/THF\/ACN\u6eb6\u5242\u4f53\u7cfb\u4e2d\u7684MAPbI3<\/sub>\u672c\u5f81\u6676\u4f53\u548cMA(MMA)n<\/sub>PbI3<\/sub>\u524d\u9a71\u4f53\u6eb6\u6db2\u7684\u7ed3\u6784\u793a\u610f\u56fe\uff1b<\/p>\n

b\uff09\u7535\u89e3\u6c60\u7684\u793a\u610f\u56fe\uff0c\u663e\u793a\u79bb\u5b50\u7535\u89e3\u8d28\u4e2d\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\uff1b<\/p>\n

c\uff09\u4f7f\u7528\u4e0d\u540c\u524d\u9a71\u4f53\u6eb6\u6db2\u4f5c\u4e3a\u7535\u89e3\u8d28\u7684\u7535\u89e3\u6c60\u7684\u4e0d\u540c\u6027\u80fd\uff1b<\/p>\n

d\uff09\u539f\u59cbMAPbI3<\/sub>\u9499\u949b\u77ff\u8584\u819c\u3001MA-MAPbI3<\/sub>\u8584\u819c\u548c\u6f02\u767dMAPbI3<\/sub>\u8584\u819c\u7684XRD\u56fe\u8c31\uff1b<\/p>\n

e\uff09\u4f7f\u7528\u4e0d\u540c\u524d\u9a71\u4f53\u6eb6\u6db2\uff0c\u5668\u4ef6\u9762\u79ef\u4e3a0.5 cm2<\/sup>\u00a0PSCs\u7684J<\/em>–V<\/em>\u7279\u6027\uff1b<\/p>\n

f\uff09\u4f7f\u7528\u4e0d\u540c\u524d\u9a71\u4f53\u6eb6\u6db2\u66b4\u9732\u4e8e\u73af\u5883\u4e2d\uff0c\u5e76\u968f\u7740\u76f8\u5bf9\u6e7f\u5ea6\u7684\u589e\u52a0\uff0c\u6d4b\u91cfPSCs\u5668\u4ef6\u7684\u7a33\u5b9a\u6027\u3002<\/p>\n

\u56fe\u516d\u3001\u9152\u7cbe\u6eb6\u5242<\/strong>
\n \"\"a\uff09\u524d\u9a71\u4f53\u6eb6\u89e3\u4e2d\u6eb6\u5242\u9009\u62e9\u5bf9\u5065\u5eb7\u7684\u5173\u6ce8\u65e5\u76ca\u589e\u52a0\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

b\uff09\u57fa\u4e8e\u4ee5\u4e59\u9187\/\u9178\u4ee5v\/v=1\/1 \u964d\u4f4eGBL\u7684\u4f53\u79ef\u767e\u5206\u6bd4\u5f97\u51fa\u7684\u524d\u9a71\u4f53\u6eb6\u6db2\u56fe\u7247\uff1b<\/p>\n

c-e\uff09\u6765\u81ea\u5177\u6709\u4e0d\u540c\u6bd4\u4f8b\u3001\u7eafGBL\u6eb6\u5242\u548c\u7eafDMF\u6eb6\u5242\u7684\u5171\u6eb6\u5242\u7cfb\u7edf\u7684\u9499\u949b\u77ff\u5c42\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

f\uff09\u5229\u7528\u4e0d\u540c\u7684\u52a9\u6eb6\u5242\u7cfb\u7edf\u5236\u5907\u7684\u4ee3\u8868\u6027PSCs\u5668\u4ef6\u7684J<\/em>–V<\/em>\u66f2\u7ebf\uff1b<\/p>\n

g\uff09GBL\/EtOH\/AcOH\u52a9\u6eb6\u5242\u7cfb\u7edf\u7684\u53f6\u7247\u6d82\u5c42\u7535\u6c60\u548c\u7ec4\u4ef6\u7684J<\/em>–V<\/em>\u66f2\u7ebf\u3002<\/p>\n

\u56fe\u4e03\u3001H2<\/sub>O\u4f5c\u4e3a\u52a9\u6eb6\u5242<\/strong>
\n \"\"a\uff09\u7b2c\u4e00\u6b65\u4e2d\u4f7f\u7528Pb(NO3<\/sub>)2<\/sub>\u6c34\u6eb6\u6db2\u5236\u5907MAPbI3<\/sub>\u8584\u819c\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

b\uff09\u57fa\u4e8ePb(NO3<\/sub>)2<\/sub>\u7684\u6c34\u6027\u548c\u57fa\u4e8ePbI2<\/sub>\/DMF\u7684PSCs\u7684J<\/em>–V<\/em>\u66f2\u7ebf\uff0c\u5728\u9633\u5149\u7167\u5c04\u4e0b\u8fdb\u884c\u8fdb\u4e00\u6b65\u7684\u77ac\u6001\u6fc0\u5149\u5206\u6790\uff1b<\/p>\n

c\uff09\u572820\uff05RH\u7684\u6697\u5ba4\u4e2d\u5b58\u50a8\u5404\u79cd\u65f6\u95f4\u524d\u540e\uff0c\u76f8\u5e94PSCs\u7684PCE\u5f52\u4e00\u5316\u56fe\uff1b<\/p>\n

d\uff09\u91d1\u5c5e\u785d\u9178\u76d0\u524d\u9a71\u4f53\u8584\u819c\u548c\u6240\u5f97\u9499\u949b\u77ff\u8584\u819c\u7684XRD\u3002<\/p>\n

\u56fe\u516b\u3001H2<\/sub>O\u4f5c\u4e3a\u5355\u6eb6\u5242<\/strong>
\n \"\"a\uff09\u542b\u6709\u4e0d\u540c\u4f53\u79ef\u7684H2<\/sub>O\u4e0eDMF\u7684PbI2<\/sub>\/DMF\u60ac\u6d6e\u6db2\u7684\u7167\u7247\uff1b<\/p>\n

b\uff09\u7531\u4e0d\u540c\u4f53\u79ef\u7684H2<\/sub>O\u4e0eDMF\u5236\u6210\u7684\u9499\u949b\u77ff\u8584\u819c\u7684SEM\u56fe\u50cf\u3002<\/p>\n

c\uff09\u5728\u9ed1\u6697\u548c\u660e\u4eae\u4e0b\u6d4b\u5f97\u7684PSC\u7684J<\/em>–V<\/em>\u66f2\u7ebf\u3002<\/p>\n

d\uff09\u5177\u6709\u5404\u79cdH2<\/sub>O\u542b\u91cf\u7684\u9499\u949b\u77ff\uff08CH3<\/sub>NH3<\/sub>PbI3-x<\/sub>Clx<\/sub>\uff09\u524d\u4f53\u6eb6\u6db2\u7684\u7167\u7247\u3002<\/p>\n

e\uff0cf\uff09\u5206\u522b\u7531\u65e0\u6c34\u524d\u4f53\u548c\u542b\u6c34\u524d\u4f53\u5236\u5907\u7684\u9499\u949b\u77ff\u8584\u819c\u7684SEM\u56fe\u50cf\u3002<\/p>\n

g\uff09\u5728\u53cd\u5411\u626b\u63cf\u548c\u6b63\u5411\u626b\u63cf\u4e2d\u6d4b\u91cf\u7684\u57fa\u4e8eH2<\/sub>O-20\uff05\u524d\u4f53\u6eb6\u6db2\u7684\u51a0\u519bPSCs\u8bbe\u5907\u7684J<\/em>–V<\/em>\u66f2\u7ebf\u3002<\/p>\n

\u56fe\u4e5d\u3001\u57fa\u4e8e\u79bb\u5b50\u6db2\u4f53\uff08ILs\uff09\u7684\u6eb6\u5242<\/strong>
\n \"\"a\uff09\u7531PbI2<\/sub>: MAI\uff081:1\u6469\u5c14\u6bd4\uff09\u5728MAFa\u6eb6\u5242\u4e2d\uff0c\u572850 \u2103\u7684N2<\/sub>\u4e2d\u9000\u706b\u5236\u5907\u9499\u949b\u77ff\u8584\u819c\u7684\u539f\u4f4d\u5e7f\u89d2X\u5c04\u7ebf\u6563\u5c04\uff08WAXS\uff09\u56fe\uff1b<\/p>\n

b\uff09\u5236\u5907\u7684MAPbI3<\/sub>\u9499\u949b\u77ff\u8584\u819c\u7684\u6a2a\u622a\u9762SEM\u548c\u8868\u9762SEM\u56fe\u50cf\uff1b<\/p>\n

c\uff09\u901a\u8fc7\u522e\u6d82\u5de5\u827a\u5236\u5907\u7684MAPbI3<\/sub>\u9499\u949b\u77ff\u8584\u819c\u7684\u70ed\u68af\u5ea6\u8f85\u52a9\u5b9a\u5411\u7ed3\u6676\u8fc7\u7a0b\u793a\u610f\u56fe\uff1b<\/p>\n

d\uff09OPC\u9499\u949b\u77ff\u8584\u819c\u7684XRD\u56fe\uff1b<\/p>\n

e\uff09\u4e0eMAP\u63a5\u89e6\u524d\u7684MAP\u548c\u94c5\u76d0\u7684\u56fe\uff1b<\/p>\n

f\uff09\u6ef4\u6d82\u7684CH3<\/sub>NH3<\/sub>PbBr3-x<\/sub>\u8584\u819c\uff08MAP+PbBr2<\/sub>\uff09\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

g\uff09\u5728\u529e\u516c\u7eb8\u4e0a\u55b7\u58a8\u6253\u5370\u7684CH3<\/sub>NH3<\/sub>PbI3<\/sub>\u7684\u56fe\u3002<\/p>\n

\u56fe\u5341\u3001\u5927\u89c4\u6a21\u751f\u4ea7\u9499\u949b\u77ff\u8584\u819c\u7684\u6eb6\u5242\u5de5\u7a0b<\/strong>
\n \"\"a\uff09\u4f7f\u7528\u4e0d\u540c\u6eb6\u5242\u7684\u5200\u7247\u6d82\u5c42\u6c89\u79ef\u7684\u9499\u949b\u77ff\u8584\u819c\u5728450-700 nm\u8303\u56f4\u5185\u7684\u5e73\u5747\u5438\u5149\u5ea6\u4e0e\u52a0\u5de5\u5ef6\u8fdf\u65f6\u95f4\u7684\u5173\u7cfb\uff1b<\/p>\n

b\uff09\u52a0\u5de5\u5ef6\u8fdf\u65f6\u95f4\u5bf9\u4f7f\u7528\u4e0d\u540c\u6eb6\u5242\u7684PCSs\u5668\u4ef6PCE\u7684\u5f71\u54cd\uff1b<\/p>\n

c\uff09\u5728\u73af\u5883\u6761\u4ef6\u4e0b\uff0cSCD\u6cd5\u56db\u6b65\u539f\u7406\u56fe\uff1b<\/p>\n

d\uff09\u4e0d\u540cGBL\/DMSO\u914d\u6bd4\u4e0b\uff0c\u6df7\u5408\u6eb6\u5242\u4f53\u7cfb\u63a5\u89e6\u89d2\u548c\u7c98\u5ea6\u7684\u53d8\u5316\uff1b<\/p>\n

e\uff09\u7528x-y\u5e73\u9762\u539f\u5b50\u529b\u663e\u5fae\u955c\uff08AFM\uff09\u6d4b\u91cf\u7531GBL\u548cDMSO\u6df7\u5408\u6eb6\u5242\u5f62\u6210\u7684\u9499\u949b\u77ff\u8584\u819c\u3002<\/p>\n

\u3010\u603b\u7ed3\u4e0e\u5c55\u671b\u3011<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u81f4\uff0c\u4f5c\u8005\u7cfb\u7edf\u5730\u7efc\u8ff0\u4e86\u6eb6\u6db2\u6cd5\u5236\u5907PSCs\u524d\u9a71\u4f53\u6eb6\u6db2\u7684\u6eb6\u5242\u5de5\u7a0b\u7814\u7a76\u8fdb\u5c55\u3002\u4f5c\u8005\u7cfb\u7edf\u5730\u56de\u987e\u4e86\u8be5\u8fc7\u7a0b\u7684\u4e24\u6761\u7ebf\u7d22\uff1a1\uff09\u914d\u4f4d\u8c03\u63a7\u548c2\uff09\u964d\u4f4e\u6eb6\u5242\u6bd2\u6027\u3002\u540c\u65f6\uff0c\u8fd8\u5bf9\u5982\u4f55\u5229\u7528\u6eb6\u5242\u5de5\u7a0b\u6280\u672f\u5236\u5907\u9ad8\u8d28\u91cf\u7684\u5927\u9762\u79ef\u9499\u949b\u77ff\u8584\u819c\u4ee5\u6ee1\u8db3PSCs\u5de5\u4e1a\u5316\u751f\u4ea7\u7684\u8981\u6c42\u63d0\u51fa\u4e86\u4e00\u4e9b\u89c1\u89e3\u3002\u76f8\u4fe1\u8fd9\u7bc7\u7efc\u8ff0\u7684\u6700\u65b0\u8fdb\u5c55\u5c06\u5bf9\u6df1\u5165\u7406\u89e3\u548c\u667a\u80fd\u5de5\u7a0b\u9499\u949b\u77ff\u524d\u9a71\u4f53\u6eb6\u6db2\u4e2d\u7684\u6eb6\u5242\u63d0\u4f9b\u6709\u76ca\u7684\u6307\u5bfc\u3002\u4e3a\u4e86\u8fdb\u4e00\u6b65\u6ee1\u8db3PSCs\u672a\u6765\u53ef\u6269\u5c55\u5236\u9020\u7684\u8981\u6c42\uff0c\u6eb6\u5242\u5de5\u7a0b\u662f\u5236\u5907\u9ad8\u6548\u4e14\u53ef\u91cd\u590d\u751f\u4ea7\u7684PSCs\u6a21\u5757\u7684\u5173\u952e\u56e0\u7d20\u3002\u56e0\u6b64\uff0c\u5728\u6eb6\u5242\u5de5\u7a0b\u65b9\u9762\uff0c\u53ef\u4ece\u4ee5\u4e0b\u51e0\u65b9\u9762\u6765\u8fdb\u4e00\u6b65\u5f00\u53d1PSCs\uff1a\uff081\uff09\u5f00\u53d1\u65b0\u578b\u65e0\u6bd2\u3001\u5b89\u5168\u548c\u7a33\u5b9a\u7684\u6eb6\u5242\uff1b\uff082\uff09\u5f00\u53d1\u901a\u7528\u7684\u6eb6\u5242\uff1b\uff083\uff09\u5f00\u53d1\u65e0\u6eb6\u5242\u6210\u819c\u6280\u672f\u3002\u603b\u4e4b\uff0c\u901a\u8fc7\u6eb6\u5242\u5de5\u7a0b\u7684\u8fdb\u4e00\u6b65\u53d1\u5c55\uff0c\u5c06\u66f4\u6709\u52a9\u4e8e\u5927\u9762\u79ef\u5236\u5907\u9ad8\u6027\u80fd\u7684PSCs\u3002\u76f8\u4fe1PSCs\u7684\u672a\u6765\u66f4\u53ef\u671f\uff01<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aSolvent Engineering of the Precursor Solution toward Large-Area Production of Perovskite Solar Cells<\/strong>. Adv. Mater.<\/em>, 2021<\/strong>, DOI: 10.1002\/adma.202005410.<\/p>\n

\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb<\/strong><\/p>\n

\"\"<\/p>\n

\u9ec4\u7ef4\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u9662\u58eb\u3001\u4fc4\u7f57\u65af\u79d1\u5b66\u9662\u5916\u7c4d\u9662\u58eb\u3001\u4e9a\u592a\u6750\u6599\u79d1\u5b66\u9662\u9662\u58eb\u3001\u4e1c\u76df\u5de5\u7a0b\u4e0e\u6280\u672f\u79d1\u5b66\u9662\u5916\u7c4d\u9662\u58eb\u3001\u5df4\u57fa\u65af\u5766\u79d1\u5b66\u9662\u5916\u7c4d\u9662\u58eb<\/strong>\u3002\u6559\u6388\u3001\u535a\u5bfc\uff0c\u6709\u673a\u7535\u5b50\u3001\u5851\u6599\u7535\u5b50\u3001\u5370\u5237\u7535\u5b50\u3001\u751f\u7269\u7535\u5b50\u53ca\u67d4\u6027\u7535\u5b50\u5b66\u5bb6\u3002\u9ec4\u7ef4\u9662\u58eb\u662f\u201c\u957f\u6c5f\u5b66\u8005\u201d\u7279\u8058\u6559\u6388\uff0c\u56fd\u5bb6\u201c\u6770\u51fa\u9752\u5e74\u79d1\u5b66\u57fa\u91d1\u201d\u83b7\u5f97\u8005\uff0c\u56fd\u5bb6\u9ad8\u5c42\u6b21\u4eba\u624d\u8ba1\u5212\u5165\u9009\u8005\uff0c\u201c973\u201d\u9879\u76ee\u9996\u5e2d\u79d1\u5b66\u5bb6\u3002\u4e9a\u592a\u5730\u533a\u5de5\u7a0b\u7ec4\u7ec7\u8054\u5408\u4f1a\uff08FEIAP\uff09\u4e3b\u5e2d\uff0c\u4fc4\u7f57\u65af\u79d1\u5b66\u9662\u540d\u8a89\u535a\u58eb\u3001\u82f1\u56fd\u8c22\u83f2\u5c14\u5fb7\u5927\u5b66\u540d\u8a89\u535a\u58eb\uff0c\u82f1\u56fd\u7687\u5bb6\u5316\u5b66\u4f1a\u4f1a\u58eb\u3001\u7f8e\u56fd\u5149\u5b66\u5b66\u4f1a\u4f1a\u58eb\u3001\u56fd\u9645\u5149\u5b66\u5de5\u7a0b\u5b66\u4f1a\u4f1a\u58eb\u3002\u66fe\u4e24\u6b21\u83b7\u5f97\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u5956\u4e8c\u7b49\u5956\u3001\u4e09\u6b21\u83b7\u5f97\u9ad8\u7b49\u5b66\u6821\u79d1\u5b66\u7814\u7a76\u4f18\u79c0\u6210\u679c\u5956\uff08\u79d1\u5b66\u6280\u672f\uff09\u81ea\u7136\u79d1\u5b66\u5956\u4e00\u7b49\u5956\uff0c\u4ee5\u53ca\u4f55\u6881\u4f55\u5229\u57fa\u91d1\u201c\u79d1\u5b66\u4e0e\u6280\u672f\u8fdb\u6b65\u5956\u201d\u7b49\uff0c\u6210\u679c\u5165\u56f4\u4e2d\u56fd\u201c\u9ad8\u7b49\u5b66\u6821\u5341\u5927\u79d1\u6280\u8fdb\u5c55\u201d\u3002\u9ec4\u7ef4\u9662\u58eb\u5728\u67d4\u6027\u7535\u5b50\u5b66\u3001\u7279\u522b\u662f\u6709\u673a\u7535\u5b50\u5b66\u7b49\u9886\u57df\u53d6\u5f97\u4e86\u5927\u91cf\u7cfb\u7edf\u6027\u3001\u521b\u65b0\u6027\u7684\u7814\u7a76\u6210\u679c\uff0c\u4ee5\u7b2c\u4e00\u6216\u901a\u8baf\u4f5c\u8005\u8eab\u4efd\u5728Nature\u3001Nature Materials\u3001Nature Nanotechnology\u3001Nature Photonics\u3001Nature Energy\u3001Nature Chemistry\u3001Nature Electronics\u4ee5\u53caNature Communications\u7b49\u56fd\u9645\u4e3b\u6d41SCI\u5b66\u672f\u671f\u520a\u53d1\u8868\u7814\u7a76\u8bba\u6587860\u4f59\u7bc7\uff0ch\u56e0\u5b50\u4e3a131\uff0c\u56fd\u9645\u540c\u884c\u5f15\u7528\u903e90000\u6b21\uff0c\u662f\u6750\u6599\u79d1\u5b66\u4e0e\u5316\u5b66\u9886\u57df\u5168\u7403\u9ad8\u88ab\u5f15\u5b66\u8005\u3002\u83b7\u6388\u6743\u7f8e\u56fd\u3001\u65b0\u52a0\u5761\u548c\u4e2d\u56fd\u7b49\u56fd\u53d1\u660e\u4e13\u5229360\u4f59\u9879\uff0c\u51fa\u7248\u4e86\u300a\u6709\u673a\u7535\u5b50\u5b66\u300b\u300a\u751f\u7269\u5149\u7535\u5b50\u5b66\u300b\u300a\u6709\u673a\u8584\u819c\u6676\u4f53\u7ba1\u6750\u6599\u5668\u4ef6\u548c\u5e94\u7528\u300b\u300a\u6709\u673a\u5149\u7535\u5b50\u6750\u6599\u5728\u751f\u7269\u533b\u5b66\u4e2d\u7684\u5e94\u7528\u300b\u300aOLED\u663e\u793a\u6280\u672f\u300b\u7b49\u5b66\u672f\u4e13\u8457\u3002<\/p>\n

\"\"\u9648\u6c38\u534e\uff0c\u5c31\u804c\u4e8e\u5357\u4eac\u5de5\u4e1a\u5927\u5b66\u5148\u8fdb\u6750\u6599\u7814\u7a76\u9662\uff0c\u6559\u6388\u3001\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u5148\u8fdb\u80fd\u6e90\u6750\u6599\u6240\u6240\u957f<\/strong>\u3002\u5165\u9009\u56fd\u5bb6\u6d77\u5916\u9ad8\u5c42\u6b21\u4eba\u624d\u8ba1\u5212\uff0c\u83b7\u5f97\u6c5f\u82cf\u7701\u7279\u8058\u6559\u6388\u548c\u6c5f\u82cf\u7701\u6770\u51fa\u9752\u5e74\u57fa\u91d1\u9879\u76ee\u3002\u957f\u671f\u56f4\u7ed5\u6709\u673a\u53ca\u9499\u949b\u77ff\u5149\u7535\u6750\u6599\u4e0e\u5668\u4ef6\u7684\u5173\u952e\u79d1\u5b66\u95ee\u9898\uff0c\u5f00\u5c55\u9ad8\u6548\u7a33\u5b9a\u5149\u7535\u5668\u4ef6\u7684\u7814\u7a76\u5de5\u4f5c\u3002\u8fd1\u5e74\u6765\uff0c\u5728\u6709\u673a\u53ca\u9499\u949b\u77ff\u5149\u7535\u6750\u6599\u4e0e\u5668\u4ef6\u9886\u57df\u53d1\u8868\u8bba\u6587100\u4f59\u7bc7\uff0c\u5305\u62ecNature Photonics\u3001Nature Energy\u3001Nature Communications\u3001Chem\u3001Chemical Society Review\u3001Advanced Materials\u3001Light: Science & Applications\u3001Nano Letters\u3001Angewandte Chemie International Edition\u7b49\uff0c\u4ed6\u5f154000\u4f59\u6b21\uff0ch\u56e0\u5b5036\uff0c\u591a\u7bc7\u9ad8\u88ab\u5f15\u8bba\u6587\u3002\u7533\u8bf7\/\u6388\u6743\u4e2d\u56fd\u4e13\u522911\u9879\u3001\u7f8e\u56fd\u4e13\u52291\u9879\u3002\u4e3b\u6301\u591a\u9879\u56fd\u5bb6\u548c\u7701\u90e8\u7ea7\u57fa\u91d1\u9879\u76ee\u3002<\/p>\n

\"\"\u5189\u6668\u946b\uff0c\u897f\u5317\u5de5\u4e1a\u5927\u5b66\u67d4\u6027\u7535\u5b50\u7814\u7a76\u9662\uff0c\u526f\u6559\u6388<\/strong>\u3002\u957f\u671f\u81f4\u529b\u4e8e\u6709\u673a-\u65e0\u673a\u6742\u5316\u9499\u949b\u77ff\u6750\u6599\u4f53\u7cfb\u5728\u80fd\u6e90\u5668\u4ef6\u4e2d\u7684\u5e94\u7528\u7814\u7a76\uff0c\u8fd1\u5e74\u6765\u91cd\u70b9\u805a\u7126\u5728\u73af\u5883\u53cb\u597d\u578b\u975e\u94c5\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u9886\u57df\u3002\u8fd1\u5e74\u6765\u5171\u53d1\u8868SCI\u8bba\u658740\u4f59\u7bc7\u3002\u4ee5\u7b2c\u4e00\/\u901a\u8baf\u4f5c\u8005\u5728Chem. Soc. Rev., Joule, Adv. Mater., ACS Energy Letters, Adv. Funct. Mater., J. Mater. Chem. A\u7b49\u9886\u57df\u5185\u4e2d\u91cd\u8981\u671f\u520a\u53d1\u8868\u8bba\u658716\u4f59\u7bc7\uff0c\u5176\u4e2d4\u7bc7\u5165\u9009ESI\u9ad8\u88ab\u5f15\u8bba\u6587\u3002Google Scholar\u88ab\u5f15\u75281700\u4f59\u6b21\uff0ch\u56e0\u5b50\u4e3a22\u3002\u4e3b\u6301\u548c\u53c2\u4e0e\u591a\u9879\u56fd\u5bb6\u7701\u90e8\u7ea7\u79d1\u7814\u9879\u76ee\u3002<\/p>\n

\u8bfe\u9898\u7ec4\u76f8\u5173\u6587\u7ae0\u63a8\u8350\uff1a<\/strong><\/p>\n

1. H. Ren, S. Yu, L. Chao, Y. Xia, Y. Sun, S. Zuo, F. Li, T. Niu, Y. Yang, H. Ju, B. Li, H. Du, X. Gao, J. Zhang, J. Wang, L. Zhang,* Y. Chen,* W. Huang,* \u201cEfficient and stable Ruddlesden-Popper perovskite solar cell with tailored interlayer molecular interaction\u201d Nat. Photonics.<\/em> 14 (2020<\/strong>) 154-163. https:\/\/doi.org\/10.1038\/s41566-019-0572-6<\/p>\n

2. Liang, C., Gu, H., Xia, Y. et al. Two-dimensional Ruddlesden\u2013Popper layered perovskite solar cells based on phase-pure thin films. Nat. Energy<\/em> 6, 38\u201345 (2020<\/strong>). https:\/\/doi.org\/10.1038\/s41560-020-00721-5.<\/p>\n

3. L. Chao, Y. Xia, B. Li, G. Xing, Y. Chen,* Wei Huang,* \u201cRoom Temperature Molten Salt for Facile Fabrication of Efficient and Stable Perovskite Solar Cells in Ambient Air\u201d Chem<\/em> 5 (2019<\/strong>) 995-1006. https:\/\/doi.org\/10.1016\/j.chempr.2019.02.025<\/p>\n

4. D. Li, L. Chao, C. Chen, X. Ran, Y. Wang, T. Niu, S. Lv, H. Wu, Yi. Xia, C. Ran, L. Song, S. Chen, Y. Chen, W. Huang. In Situ Interface Engineering for Highly Efficient Electron-Transport-Layer-Free Perovskite Solar Cells. Nano lett.<\/em> 20 5799-5806 (2020<\/strong>). https:\/\/doi.org\/10.1021\/acs.nanolett.0c01689<\/p>\n

5. L. Chao, T. Niu, H. Gu, Y. Chen, W. Huang, Origin of high efficiency and long-term stability in ionic liquid perovskite photovoltaic. Research<\/em> 2020<\/strong> (2020) 2616345. https:\/\/doi.org\/10.34133\/2020\/2616345<\/p>\n

6. Efficient and Stable Low-Dimensional Ruddlesden-Popper Perovskite Solar Cells Enabled by Reducing Tunnel Barrier. J. Phys. Chem. Lett.<\/em> https:\/\/doi.org\/10.1021\/acs.jpclett.9b00276<\/p>\n

7. Tailoring Component Interaction for Air-Processed Efficient and Stable All-Inorganic Perovskite Photovoltaic. Angew. Chem. Int. Ed.<\/em> 59 13354-13361 (2020<\/strong>) https:\/\/doi.org\/10.1002\/anie.202004256<\/p>\n

\u672c\u6587\u7531CQR\u7f16\u8bd1\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1atougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu.<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011 \u6709\u673a-\u65e0\u673a\u6742\u5316\u9499\u949b\u77ff\u6750\u6599\u5177\u6709\u5438\u6536\u7cfb\u6570\u9ad8\u3001\u5e26\u9699\u53ef\u8c03\u3001\u53cc\u6781\u6027\u7535\u8377\u8fc1\u79fb\u7387\u9ad8\u3001\u6fc0\u5b50\u7ed3\u5408\u80fd\u4f4e\u7b49\u4f18\u70b9\uff0c\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u592a\u9633\u80fd\u7535\u6c60\u3001\u53d1\u5149\u5668\u4ef6\u7b49\u5404\u79cd\u5149\u7535\u548c\u7535\u5b50\u5e94\u7528\u9886\u57df…<\/p>\n","protected":false},"author":7770,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[533],"tags":[3888],"class_list":["post-219053","post","type-post","status-publish","format-standard","hentry","category-zongshu","tag-pscs"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/219053"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/7770"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=219053"}],"version-history":[{"count":4,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/219053\/revisions"}],"predecessor-version":[{"id":219102,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/219053\/revisions\/219102"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=219053"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=219053"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=219053"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}