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a\uff09\u5728\u626b\u63cf\u901f\u5ea6\u4e3a50 mV s–<\/sup>1<\/sup>\u7684CO2<\/sub>\u9971\u548c\u76840.1 M KHCO3<\/sub>\u6c34\u6eb6\u6db2\u4e2d\uff0cCuS\u3001CuSx<\/sub>-1-cycle\u3001CuSx<\/sub>-DSV\u548cCuSx<\/sub>-100-cycle\u56db\u4e2a\u50ac\u5316\u5242\u7684\u7ebf\u6027\u626b\u63cf\u4f0f\u5b89\u66f2\u7ebf\u3002<\/p>\n

b\uff09\u5728H-cell\u4f53\u7cfb\u4e2d\u4f7f\u7528CuSx<\/sub>-DSV\u4f5c\u4e3a\u50ac\u5316\u5242\u5f97\u5230\u7684CO2<\/sub>RR\u4ea7\u7269\u5206\u5e03\u3002<\/p>\n

c\uff09\u4e0a\u8ff0\u56db\u79cd\u50ac\u5316\u5242\u5728\u4e0d\u540c\u7535\u4f4d\u4e0b\u5bf9\u5e94\u7684\u6b63\u4e19\u9187\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u3002<\/p>\n

d \uff09\u56db\u79cd\u50ac\u5316\u5242\u5728\u7535\u4f4d\u4e3a-1.05 V\u00a0vs.\u00a0RHE\u4e0b\u7684FEn-PrOH<\/sub>\u548cFEn-PrOH<\/sub>\/FEC1+C2+C3<\/sub>\u7684\u6bd4\u503c\u3002<\/p>\n

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f\uff09\u5728H-cell\uff08\u84dd\u8272\u66f2\u7ebf\uff09\u548c\u6d41\u52a8\u6c60\uff08\u7ea2\u8272\u66f2\u7ebf\uff09\u4f53\u7cfb\u4e0b\uff0cCuSx<\/sub>-DSV\u4f5c\u4e3a\u50ac\u5316\u5242\u83b7\u5f97\u6b63\u4e19\u9187\u7684\u90e8\u5206\u7535\u6d41\u5bc6\u5ea6\u4e0e\u7535\u4f4d\u7684\u5173\u7cfb\u3002a-d\uff09\u548ce-f\uff09\u4e2d\u7684\u6570\u636e\u5206\u522b\u5728H-cell\u548c\u6d41\u52a8\u6c60\u4e2d\u6d4b\u8bd5\u83b7\u5f97\u3002 b\u2013d\uff09\u548cf\uff09\u4e2d\u7684\u8bef\u5dee\u7ebf\u68d2\u5bf9\u5e94\u4e8e\u4e09\u4e2a\u6d4b\u91cf\u503c\u7684\u5e73\u5747\u503c\u00b1\u6807\u51c6\u504f\u5dee\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/b><\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u56e2\u961f\u9996\u5148\u901a\u8fc7\u7406\u8bba\u8ba1\u7b97\u9884\u6d4b\u4e86\u5728\u516d\u65b9\u76f8CuS(100)\u6676\u9762\u4e0a\u5f62\u6210\u7684\u53cc\u786b\u7a7a\u4f4d\u53ef\u4ee5\u4f5c\u4e3aCO2<\/sub>RR\u7684\u7535\u50ac\u5316\u6d3b\u6027\u4e2d\u5fc3\uff0c\u5b8c\u6210CO-CO\u4e8c\u805a\u5e76\u7a33\u5b9aOCCO*\u4e2d\u95f4\u4f53\uff0c\u540c\u65f6\u80fd\u7ee7\u7eed\u8fdb\u884cCO-OCCO\u5076\u8054\u5f62\u6210\u6b63\u4e19\u9187\u7684\u5173\u952e*C3<\/sub>\u4e2d\u95f4\u4f53\u3002\u968f\u540e\uff0c\u5f00\u53d1\u4e86\u4e00\u79cd\u7b80\u4fbf\u6709\u6548\u7684\u9502\u7535\u5316\u5b66\u8c03\u63a7\u65b9\u6cd5\uff0c\u53ef\u83b7\u5f97\u9ad8\u5bc6\u5ea6\u7684\u53cc\u786b\u7a7a\u4f4d\u3002\u5728H-cell\u4e2d\uff0c\u6b63\u4e19\u9187\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u53ef\u4ee5\u63d0\u9ad8\u523015.4%\uff0c\u5728\u6d41\u52a8\u6c60\u4e2d\uff0c\u6b63\u4e19\u9187\u7684\u5206\u7535\u6d41\u5bc6\u5ea6\u53ef\u8fdb\u4e00\u6b65\u63d0\u9ad8\u52309.9 mA cm–<\/sup>2<\/sup>\uff0c\u8fd9\u4e0e\u7535\u5316\u5b66CO2<\/sub>RR\u4e2d\u62a5\u9053\u7684\u6700\u4f73\u503c\u76f8\u5f53\u3002\u56e2\u961f\u7684\u5de5\u4f5c\u63d0\u51fa\u4e86\u4e00\u4e2a\u5f88\u6709\u5438\u5f15\u529b\u7684\u7b56\u7565\uff0c\u5373\u5229\u7528\u9502\u7535\u5316\u5b66\u8c03\u63a7\u65b9\u6cd5\u6765\u5236\u9020\u591a\u79cd\u79bb\u5b50\u7a7a\u4f4d\u4f5c\u4e3a\u7535\u50ac\u5316\u5242\u7684\u6d3b\u6027\u4f4d\u70b9\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5<\/b><\/strong>\uff1aDouble sulfur vacancies by lithium tuning enhance CO<\/u>2<\/sub><\/u>\u00a0electroreduction to n-propanol<\/u><\/a>\uff08Nat. Commun.\uff0c2021\uff0cDOI\uff1a10.1038\/s41467-021-21901-1\uff09<\/p>\n

\u3010\u56e2\u961f\u4ecb\u7ecd\u3011<\/b><\/strong><\/p>\n

\u00a0<\/b><\/strong>\u90d1\u803f\u950b \u6559\u6388\u3002\u590d\u65e6\u5927\u5b66\u6559\u6388\u3001\u535a\u58eb\u751f\u5bfc\u5e08\u3001\u56fd\u5bb6\u6770\u51fa\u9752\u5e74\u79d1\u5b66\u57fa\u91d1\u83b7\u5f97\u8005\u3001\u6559\u80b2\u90e8\u9752\u5e74\u957f\u6c5f\u5b66\u8005\u3001\u4e2d\u56fd\u5316\u5b66\u4f1a\u9ad8\u7ea7\u4f1a\u5458\u3002<\/b><\/strong>2000\u5e74\u672c\u79d1\u6bd5\u4e1a\u4e8e\u590d\u65e6\u5927\u5b66\u5316\u5b66\u7cfb\uff0c2007\u5e74\u83b7\u5f97\u7f8e\u56fd\u54c8\u4f5b\u5927\u5b66\u7269\u7406\u5316\u5b66\u535a\u58eb\u5b66\u4f4d\uff0c\u4e4b\u540e\u5728\u7f8e\u56fd\u897f\u5317\u5927\u5b66\u8fdb\u884c\u535a\u58eb\u540e\u7814\u7a76\uff0c2010\u5e74\u8d77\u5728\u590d\u65e6\u5927\u5b66\u5148\u8fdb\u6750\u6599\u5b9e\u9a8c\u5ba4\u4e0e\u5316\u5b66\u7cfb\u5de5\u4f5c\u3002\u4ece\u4e8b\u7eb3\u7c73\u529f\u80fd\u6750\u6599\u7684\u8bbe\u8ba1\u5408\u6210\uff0c\u53ca\u5176\u5728\u78b3\u57fa\u80fd\u6e90\u5316\u5b66\u50ac\u5316\u7684\u7814\u7a76\u3002\u66fe\u83b7\u5f97\u4e2d\u56fd\u5316\u5b66\u4f1a\u9752\u5e74\u5316\u5b66\u5956\u3001Clarivate\u5168\u7403\u9ad8\u88ab\u5f15\u79d1\u5b66\u5bb6\u3001\u5b9d\u94a2\u57fa\u91d1\u4f1a\u4f18\u79c0\u6559\u5e08\u5956\u3001\u6559\u80b2\u90e8\u62d4\u5c16\u8ba1\u5212\u4f18\u79c0\u5bfc\u5e08\u5956\u3001\u4e0a\u6d77\u5e02\u4e1c\u65b9\u5b66\u8005\u7279\u8058\u6559\u6388\u3001\u4e0a\u6d77\u5e02\u4e94\u56db\u9752\u5e74\u5956\u7ae0\u3001Nano Research Young Innovators Award in NanoEnergy\u7b49\u8363\u8a89\u3002\u517c\u4efb\u56fd\u9645\u671f\u520aJournal of Colloid and Interface Science\u7684\u526f\u4e3b\u7f16\u3001\u4e2d\u56fd\u5316\u5b66\u4f1a\u9752\u59d4\u4f1a\u59d4\u5458\u3001\u4e2d\u56fd\u4fa8\u8054\u9752\u59d4\u4f1a\u59d4\u5458\u3001\u4e2d\u56fd\u79d1\u534f\u82f1\u624d\u8ba1\u5212\u5b66\u79d1\u5bfc\u5e08\u7b49\u3002\u76ee\u524d\u5df2\u5728\u56fd\u9645\u5b66\u672f\u671f\u520a\u4e0a\u53d1\u8868SCI\u8bba\u6587180\u4f59\u7bc7\uff0c\u670920\u4f59\u7bc7\u5165\u9009ESI\u9ad8\u5f15\u8bba\u6587\uff0c\u8bba\u6587\u7684\u603b\u4ed6\u5f15\u6b21\u6570 1\u4e077\u5343\u4f59\u6b21\uff08h-index 66\uff09<\/p>\n

Zheng Research Group\u4e3b\u9875http:\/\/www.nanolab.fudan.edu.cn\/chinese.html<\/b><\/u><\/strong><\/a><\/p>\n

\u00a0<\/b><\/strong>\u674e\u4e9a\u98de \u6559\u6388\u3002<\/b><\/strong>\u5357\u4eac\u5e08\u8303\u5927\u5b66\u5316\u5b66\u4e0e\u6750\u6599\u79d1\u5b66\u5b66\u9662\u6559\u6388\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\u30022006\u5e74\u4e8e\u91cd\u5e86\u5927\u5b66\u83b7\u5f97\u7406\u5b66\u5b66\u58eb\u5b66\u4f4d\uff0c2011\u5e746\u6708\u4e8e\u5357\u5f00\u5927\u5b66\u83b7\u5f97\u7406\u5b66\u535a\u58eb\u5b66\u4f4d\uff0c2011\u5e748\u6708\u81f32013\u5e749\u6708\u5728\u6ce2\u591a\u9ece\u5404\u5927\u5b66\u5316\u5b66\u7cfb\u4ece\u4e8b\u535a\u58eb\u540e\u7814\u7a76\uff0c2013\u5e7410\u6708\u83b7\u8058\u201c\u6c5f\u82cf\u7279\u8058\u6559\u6388\u201d\u5230\u5357\u4eac\u5e08\u8303\u5927\u5b66\u5316\u5b66\u4e0e\u6750\u6599\u79d1\u5b66\u5b66\u9662\u5de5\u4f5c\uff0c\u4efb\u6559\u6388\u3001\u535a\u58eb\u751f\u5bfc\u5e08\u30022015\u5e74\u83b7\u5f97\u57fa\u91d1\u59d4\u4f18\u79c0\u9752\u5e74\u57fa\u91d1\u548c\u6c5f\u82cf\u7701\u6770\u51fa\u9752\u5e74\u57fa\u91d1\u7684\u8d44\u52a9\uff0c2016\u5e74\u5165\u9009\u6c5f\u82cf\u7701\u201c\u53cc\u521b\u4eba\u624d\u201d\u8ba1\u5212\uff0c2017\u5165\u9009\u4e2d\u7ec4\u90e8\u201c\u4e07\u4eba\u8ba1\u5212\u201d\u9752\u5e74\u62d4\u5c16\u4eba\u624d\u8ba1\u5212\u30022018\u5e74\u83b7\u5f97\u6c5f\u82cf\u7701\u5316\u5b66\u5316\u5de5\u5b66\u9662\u201c\u6234\u5b89\u90a6\u9752\u5e74\u521b\u65b0\u5956\u201d\u3002\u674e\u4e9a\u98de\u957f\u671f\u4ece\u4e8b\u4e8c\u7ef4\u6750\u6599\u7684\u7406\u8bba\u4e0e\u8ba1\u7b97\u7814\u7a76\uff0c\u5728\u4e8c\u7ef4\u6750\u6599\u7684\u7269\u6027\u8c03\u63a7\u548c\u65b0\u9896\u4e8c\u7ef4\u6750\u6599\u8bbe\u8ba1\u65b9\u9762\u505a\u51fa\u4e86\u4e00\u7cfb\u5217\u5177\u6709\u521b\u65b0\u6027\u7684\u5de5\u4f5c\u3002\u622a\u81f3\u76ee\u524d\u4ee5\u7b2c\u4e00\/\u901a\u8baf\u4f5c\u8005\u8eab\u4efd\u53d1\u8868\u5728Nat. Chem.\u3001Nat. Catal.\u3001J. Am. Chem. Soc.(6)\u3001Angew. Chem. Int. Ed.(7)\u3001Nat. Commun.(4)\u7b49\u671f\u520a\u53d1\u8868\u8bba\u6587\u8bba\u658790\u4f59\u7bc7\u3002\u6240\u53d1\u8868\u8bba\u6587\u5171\u88ab\u4ed6\u5f1510500\u4f59\u6b21\uff0c24\u7bc7\u8bba\u6587\u5165\u9009ESI\u9ad8\u88ab\u5f15\u8bba\u6587\uff0c\u5165\u90092019\u30012020\u5e74\u5ea6 Clarivate\u5168\u7403\u9ad8\u88ab\u5f15\u79d1\u5b66\u5bb6\u3002<\/p>\n

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