{"id":219426,"date":"2021-03-19T08:05:35","date_gmt":"2021-03-19T00:05:35","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=219426"},"modified":"2021-03-19T08:05:35","modified_gmt":"2021-03-19T00:05:35","slug":"%e4%b8%ad%e7%a7%91%e5%a4%a7%e6%9c%80%e6%96%b0science-%e5%88%86%e5%b8%83%e8%a3%81%e5%89%aa%e7%a2%b3-%e6%b0%9f%e9%94%ae","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=219426","title":{"rendered":"\u4e2d\u79d1\u5927\u6700\u65b0Science: \u5206\u5e03\u88c1\u526a\u78b3-\u6c1f\u952e"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u6c1f\u65e2\u662f\u7535\u8d1f\u6027\u6700\u5927\u7684\u5143\u7d20\uff0c\u4e5f\u5177\u6709\u6781\u5c0f\u7684\u539f\u5b50\u534a\u5f84\uff0c\u4ece\u800c\u4f7f\u542b\u6c1f\u5316\u5408\u7269\u5c55\u73b0\u51fa\u8bf8\u591a\u72ec\u7279\u7684\u6027\u8d28\u3002\u7279\u522b\u662f\u5728\u836f\u7269\u5b66\u6216\u8005\u519c\u7528\u5316\u5b66\u9886\u57df\u7684\u7814\u7a76\u4e2d\uff0c\u5e38\u5e38\u901a\u8fc7\u5f15\u5165\u6c1f\u539f\u5b50\u6765\u6539\u6027\u78b3\u57fa\u5316\u5408\u7269\u7684\u6027\u8d28\u3002\u56e0\u6b64\uff0c\u5982\u4f55\u9ad8\u6548\u6e29\u548c\u5236\u5907\u5355\u6c1f\u548c\u53cc\u6c1f\u6709\u673a\u7269\u4ece\u800c\u964d\u4f4e\u751f\u4ea7\u6210\u672c\u4e00\u76f4\u662f\u57fa\u7840\u7814\u7a76\u548c\u4ea7\u4e1a\u754c\u7684\u70ed\u70b9\u95ee\u9898\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n

\u8fd1\u671f\uff0c\u52a0\u5dde\u5927\u5b66\u6d1b\u6749\u77f6\u5206\u6821\u7684\u7684<\/strong>Kendall N. Houk<\/strong>\u548c\u4e2d\u79d1\u5927\u7684\u6c6a\u4e49\u4e30<\/strong>\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u53d7\u5230\u751f\u7269\u5408\u6210DNA\u8fc7\u7a0b\u7684\u542f\u53d1\uff0c\u53d1\u73b0\u901a\u8fc7\u81ea\u65cb\u4e2d\u5fc3\u8f6c\u79fb\u673a\u5236\u53ef\u4ee5\u7528\u4e8e\u4e09\u6c1f\u4e59\u9178\u884d\u751f\u7269\u7684\u78b3-\u6c1f\u952e\u65ad\u88c2\u3002\u57fa\u4e8e\u6b64\uff0c\u7814\u7a76\u4eba\u5458\u5c06\u542b\u4e09\u6c1f\u7532\u57fa\u7684\u4e09\u6c1f\u4e59\u9170\u80fa\u6216\u8005\u4e09\u6c1f\u4e59\u9178\u916f\u7b49\u548c\u8def\u6613\u65af\u78b1-\u787c\u70f7\u5316\u5408\u7269\u7b49\u6df7\u5408\u5f62\u6210\u53cd\u5e94\u4f53\u7cfb\u3002\u901a\u8fc7\u52a0\u70ed\uff0c\u53cd\u5e94\u4f53\u7cfb\u4ea7\u751f\u8def\u6613\u65af\u78b1-\u787c\u81ea\u7531\u57fa\uff0c\u968f\u540e\u4e0e\u4e09\u6c1f\u7532\u57fa\u5206\u5b50\u4f5c\u7528\u5e76\u53d1\u751f\u81ea\u65cb\u4e2d\u5fc3\u8f6c\u79fb\uff0c\u4ece\u800c\u5728\u6d88\u9664\u6c1f\u79bb\u5b50\u7684\u540c\u65f6\u751f\u6210\u4e8c\u6c1f\u7532\u57fa\u81ea\u7531\u57fa\u3002\u540c\u7406\uff0c\u8fdb\u4e00\u6b65\u53d1\u751f\u81ea\u65cb\u4e2d\u5fc3\u8f6c\u79fb\u53cd\u5e94\u53ef\u83b7\u5f97\u5355\u6c1f\u7532\u57fa\u81ea\u7531\u57fa\u3002\u8fd9\u4e9b\u81ea\u7531\u57fa\u53ef\u8fdb\u4e00\u6b65\u53cd\u5e94\uff0c\u6700\u7ec8\u751f\u6210\u53cc\u6c1f\u6216\u8005\u5355\u6c1f\u6709\u673a\u7269\u3002\u8be5\u5de5\u4f5c\u8ba4\u4e3a\uff0c\u7814\u7a76\u4ece\u6210\u672c\u4f4e\u5ec9\u7684\u4e09\u6c1f\u4e59\u9178\u884d\u751f\u7269\u51fa\u53d1\uff0c\u9ad8\u6548\u53ef\u63a7\u5408\u6210\u4e86\u53cc\u6c1f\/\u5355\u6c1f\u5316\u5408\u7269\uff0c\u53d1\u5c55\u4e86\u4e00\u79cd\u5236\u5907\u542b\u6c1f\u6709\u673a\u5316\u5408\u7269\u7684\u65b0\u9014\u5f84\u30022021\u5e7403\u670819\u65e5\uff0c\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201cSequential C\u2013F bond functionalizations of trifluoroacetamides and acetates via spin-center shifts<\/strong>\u201d\u7684\u6587\u7ae0\u5728\u7ebf\u53d1\u8868\u5728Science<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb<\/strong>\u3011<\/p>\n

\u56fe1<\/strong> \u57fa\u4e8e\u4e09\u6c1f\u5316\u78b3\u57fa\u56e2\u7684\u78b3-\u6c1f\u952e\u529f\u80fd\u5316\u7b56\u7565<\/strong><\/p>\n

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\u56fe<\/strong>2<\/strong> \u5355<\/strong>\/<\/strong>\u53cc\u6c34\u6c1f\u5316\u53cd\u5e94<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>3 <\/strong>\u8131\u6c1f\u5076\u8054\u53cd\u5e94<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>4 <\/strong>\u4e24\u9636\u6bb5\u4e2d\u7684\u591a\u79cd\u81ea\u7531\u57fa\u9677\u9631<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>5 <\/strong>\u5408\u6210\u5e94\u7528<\/strong><\/p>\n

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\u56fe<\/strong>6 <\/strong>\u673a\u7406\u7814\u7a76<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>7 <\/strong>\u8ba1\u7b97\u7814\u7a76<\/strong><\/p>\n

\u00a0\"\"<\/strong><\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aSequential C\u2013F bond functionalizations of trifluoroacetamides and acetates via spin-center shifts<\/strong><\/a>\uff08Science, 2021, DOI: 10.1126\/science.abg0781\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u5b66\u672f\u7ec4NanoCJ\u4f9b\u7a3f\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

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