{"id":219678,"date":"2021-03-26T06:43:00","date_gmt":"2021-03-25T22:43:00","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=219678"},"modified":"2021-03-25T21:43:14","modified_gmt":"2021-03-25T13:43:14","slug":"%e6%ad%a6%e5%a4%a7%e9%83%91%e5%a4%a7-afm%ef%bc%9a%e4%b8%89%e6%a8%a1%e8%8d%a7%e5%85%89%e5%93%8d%e5%ba%94%ef%bc%81%e6%97%a0%e8%89%b2%e3%80%81%e9%ab%98%e9%9f%a7%e6%80%a7%e7%9a%84%e8%87%aa%e6%84%88","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=219678","title":{"rendered":"\u6b66\u5927&\u90d1\u5927 AFM\uff1a\u4e09\u6a21\u8367\u5149\u54cd\u5e94\uff01\u65e0\u8272\u3001\u9ad8\u97e7\u6027\u7684\u81ea\u6108\u5408\u5f39\u6027\u4f53"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6b66\u6c49\u5927\u5b66\u5434\u4f1f\u6559\u6388\u548c\u90d1\u5dde\u5927\u5b66\u7530\u9752\u52c7\u8bb2\u5e08\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba<\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u53ef\u6253\u5370\u7684\u3001\u4e09\u6a21\u8367\u5149\u54cd\u5e94\u7684\u3001\u65e0\u8272\u7684\u81ea\u6108\u5408\u5f39\u6027\u4f53\uff0c\u5176\u7531\u4e8c\u786b\u952e\u4ea4\u8054\u805a\u6c28\u916f\uff08PU\uff09\u805a\u5408\u7269\u3001\u78b3\u70b9\uff08CDs\uff09\u8367\u5149\u6750\u6599\u548c\u9567\u7cfb\u79bb\u5b50\u63ba\u6742\u7684\u4e0a\u8f6c\u6362\u8367\u5149\u6750\u6599\u7ec4\u5408\u800c\u6210\u3002\u4f5c\u8005\u9009\u62e9\u4e86\u5177\u6709\u6700\u4f73\u673a\u68b0\u6027\u80fd\u548c\u826f\u597d\u53ef\u6062\u590d\u6027\u7684PU\u5f39\u6027\u4f53\uff0c\u5c06\u5176\u4e0eCDs\u7ed3\u5408\u5236\u5907\u4e86\u8367\u5149\u54cd\u5e94\u7684\u5f39\u6027\u4f53\uff08PU-CDs\uff09\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u6240\u5236\u5907\u7684PU-CDs\u4e0d\u4ec5\u8868\u73b0\u51fa\u6bd4\u5148\u524d\u62a5\u9053\u7684\u5ba4\u6e29\u81ea\u6108\u5408\u5f39\u6027\u4f53\u66f4\u597d\u7684\u62c9\u4f38\u5f3a\u5ea6\u548c\u97e7\u6027\uff08\u5206\u522b\u4e3a 20.95 MPa \u548c 85.13 MJ m-3<\/sup>\uff09\uff0c\u800c\u4e14\u8fd8\u8868\u73b0\u51fa\u826f\u597d\u7684\u81ea\u6108\u5408\u6027\u80fd\u5e76\u4e14\u5728\u7d2b\u5916\u5149\u6fc0\u53d1\u4e0b\u5b9e\u73b0\u4e86\u84dd\u8272\u8367\u5149\u53d1\u5c04\u3002\u5728\u6b64\u57fa\u7840\u4e0a\uff0c\u4f5c\u8005\u91c7\u7528\u76f4\u63a5\u4e1d\u7f51\u5370\u5237\u7684\u65b9\u6cd5\u5728\u900f\u660ePU-CDs\u5f39\u6027\u4f53\u4e0a\u5370\u5236\u4e86\u4e00\u7cfb\u5217\u57fa\u4e8e\u6838@\u58f3\u7ed3\u6784\u4e0a\u8f6c\u6362\u6cb9\u58a8\u7684\u53cc\u6a21\u5f0f\u8367\u5149\u56fe\u6848\u3002\u540c\u65f6\uff0c\u8fd8\u6210\u529f\u5730\u5b9e\u73b0\u4e00\u7cfb\u5217\u8367\u5149\u56fe\u6848\u548c\u53d7\u635f\u7535\u5b50\u56fe\u6848\u7684\u81ea\u6108\u5408\u3002\u6240\u8bbe\u8ba1\u7684\u81ea\u6108\u6750\u6599\u4e3a\u4e0b\u4e00\u4ee3\u667a\u80fd\u6750\u6599\u7684\u5f00\u53d1\u548c\u5e94\u7528\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u548c\u91cd\u8981\u6307\u5bfc\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u00a0\u201c Printable, Down\/Up-Conversion Triple-Mode Fluorescence Responsive and Colorless Self-Healing Elastomers with Superior Toughness\u201d<\/strong>\u53d1\u5e03\u5728\u56fd\u9645\u8457\u540d\u671f\u520a\u00a0Adv. Funct. Mater.<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\u3001PU\u5f39\u6027\u4f53\u7684\u5206\u5b50\u7ed3\u6784\u8bbe\u8ba1\uff0c\u5177\u6709\u51fa\u8272\u7684\u97e7\u6027\u3001\u53ef\u62c9\u4f38\u6027\u548c\u81ea\u6108\u5408\u80fd\u529b<\/strong>
\n \"\"a\uff09PU\u5f39\u6027\u4f53\u7684\u5408\u6210\u8def\u7ebf\uff1b<\/p>\n

b\uff09PU\u5f39\u6027\u4f53\u7684\u62c9\u4f38\u793a\u610f\u56fe;<\/p>\n

c\uff09PU\u5f39\u6027\u4f53\u7684\u81ea\u4fee\u590d\u8fc7\u7a0b\u7684\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe\u4e8c\u3001PU\u81ea\u4fee\u590d\u5f39\u6027\u4f53\u7684\u8868\u5f81\u548c\u4f18\u5316<\/strong>
\n \"\"a\uff09\u5408\u6210\u7684PU1-PU6\u5f39\u6027\u4f53\u7684\u5e94\u529b-\u5e94\u53d8\u66f2\u7ebf\uff1b<\/p>\n

b\uff09PTMEG-IPDI\u9884\u805a\u7269\u548c\u5236\u5907\u7684PU6\u5f39\u6027\u4f53\u7684FTIR\u5149\u8c31\uff1b<\/p>\n

c\uff09\u65e0\u8272PU6\u5f39\u6027\u4f53\u7684\u5149\u900f\u8fc7\u7387\u56fe\u8c31\u548c\u7167\u7247\uff1b<\/p>\n

d-e\uff09\u54d1\u94c3\u5f62PU6\u5668\u4ef6\u62c9\u8d774\u516c\u65a4\u54d1\u94c3\u7684\u56fe\u50cf\uff0c\u4ee5\u53ca\u5728\u62c9\u4f38\u673a\u4e2d\u8fdb\u884c1200\uff05\u5e94\u53d8\u62c9\u4f38\u6d4b\u8bd5\uff1b<\/p>\n

f\uff09PU6\u81ea\u4fee\u590d\u5f39\u6027\u4f53\u7684AFM\u56fe\u50cf\uff0c\u4e0a\uff1a\u6a21\u91cf\u56fe\u50cf\u3001\u4e0b\uff1a\u7c98\u9644\u529b\u56fe\u50cf\uff1b<\/p>\n

g\uff09\u5728\u4e0d\u540c\u62c9\u4f38\u901f\u7387\u4e0b\uff0cPU6\u6837\u54c1\u7684\u62c9\u4f38\u5e94\u529b-\u5e94\u53d8\u66f2\u7ebf\uff1b<\/p>\n

h\uff09\u5728500\uff05\u5e94\u53d8\u4e0b\u7684\u91cd\u590d\u5faa\u73af\u62c9\u4f38\u8bd5\u9a8c\u66f2\u7ebf\u3002<\/p>\n

\u56fe\u4e09\u3001\u900f\u660ePU6\u5f39\u6027\u4f53\u7684\u81ea\u6108\u5408\u548c\u673a\u68b0\u6027\u80fd<\/strong>
\n \"\"a\uff09PU6\u5f39\u6027\u4f53\u7684\u5316\u5b66\u7ed3\u6784\uff0c\u4ee5\u53ca\u5728R.T.\u300125 \u2103\u548c60 \u2103\u4e0b\u81ea\u6108\u5408\u5212\u75d5\u7684PU6\u6837\u54c1\u7684\u5149\u5b66\u663e\u5fae\u955c\u56fe\u50cf\uff1b<\/p>\n

b\uff09\u5728R.T.\u548c60 \u00b0C\u4e0b\uff0c\u539f\u59cb\u53ca\u4e0d\u540c\u81ea\u6108\u65f6\u95f4\u7684\u53d7\u635fPU6\u6837\u54c1\u7684\u5e94\u529b-\u5e94\u53d8\u66f2\u7ebf\uff1b<\/p>\n

c\uff09\u5728R.T.\u548c60 \u00b0C\u4e0b\uff0c\u53d7\u635f\u7684PU6\u6837\u54c1\u7684\u673a\u68b0\u6027\u80fd\u7684\u81ea\u6108\u6548\u7387\uff1b<\/p>\n

d\uff09\u572860\u300190\u548c120 \u2103\u4e0b\uff0cPU6\u5f39\u6027\u4f53\u7684\u50a8\u80fd\u6a21\u91cfG’\u548c\u635f\u8017\u6a21\u91cfG”\u7684\u89d2\u9891\u7387\u03c9\u4f9d\u8d56\u6027\uff1b<\/p>\n

e\uff09\u901a\u8fc7\u4e1d\u7f51\u5370\u5237\u5c06\u94f6\u6d46\u76f4\u63a5\u5728PU6\u5f39\u6027\u4f53\u5370\u5236\u5bfc\u7535\u56fe\u6848\u53ca\u5176\u522e\u64e6\u68c0\u6d4b\u6d4b\u8bd5\u3002<\/p>\n

\u56fe\u56db\u3001\u8367\u5149\u54cd\u5e94\u7684PU-CDs\u81ea\u6108\u5408\u5f39\u6027\u4f53\u7684\u8bbe\u8ba1\u548c\u8868\u5f81<\/strong>
\n \"\"a-b\uff09CDs\u8367\u5149\u6750\u6599\u7684TEM\u548cHRTEM\u56fe\u50cf\uff1b<\/p>\n

c\uff09\u5728\u81ea\u7136\u73af\u5883\u6761\u4ef6\u548cUV\u6fc0\u53d1\u4e0bCDs C4<\/sub>H8<\/sub>O2<\/sub>\u6eb6\u6db2\u7684\u7167\u7247\uff1b<\/p>\n

d\uff09\u5408\u6210\u7684PU-CDs\u81ea\u4fee\u590d\u5f39\u6027\u4f53\u793a\u610f\u56fe\uff0c\u5176\u4e2dCDs\u4e3a\u8367\u5149\u5143\u7d20\uff1b<\/p>\n

e\uff09\u5728\u81ea\u7136\u73af\u5883\u6761\u4ef6\u4e0b\uff0c\u8367\u5149\u54cd\u5e94\u7684PU-CDs\u81ea\u6108\u5f39\u6027\u4f53\u7684\u5149\u900f\u8fc7\u7387\u56fe\u8c31\u53ca\u76f8\u5e94\u7684\u56fe\u50cf\uff1b<\/p>\n

f\uff09\u5728\u7d2b\u5916\u7ebf\u6fc0\u53d1\u4e0b\uff0cPU-CDs\u5f39\u6027\u4f53\u7684\u8367\u5149\u5149\u8c31\u548c\u76f8\u5e94\u7684\u8367\u5149\u7167\u7247\uff1b<\/p>\n

g\uff09\u5728R.T.\u548c60 \u00b0C\u4e0b\uff0cPU-CDs\u5f39\u6027\u4f53\u81ea\u6108\u5408\u5212\u75d5\u7684\u5149\u5b66\u663e\u5fae\u955c\u56fe\u50cf\uff1b<\/p>\n

h\uff09\u5728R.T.\u548c60 \u00b0C\u4e0b\uff0c\u539f\u59cb\u7684\u548c\u4e0d\u540c\u81ea\u6108\u65f6\u95f4\u4e0b\u635f\u574f\u7684PU-CDs\u6837\u54c1\u7684\u5e94\u529b-\u5e94\u53d8\u66f2\u7ebf\uff1b<\/p>\n

i\uff09\u572860\u300190\u548c120 \u00b0C\u4e0b\uff0c\u8367\u5149\u54cd\u5e94\u7684PU-CDs\u5f39\u6027\u4f53\u7684\u50a8\u80fd\u6a21\u91cfG’\u548c\u635f\u8017\u6a21\u91cfG”\u7684\u89d2\u9891\u7387\u03c9\u4f9d\u8d56\u6027\uff1b<\/p>\n

j\uff09\u6bd4\u8f83\u8be5\u5de5\u4f5c\u4e2d\u62a5\u544a\u7684PU-CDs\u81ea\u6108\u5408\u5f39\u6027\u4f53\u548c\u6587\u732e\u4e2d\u62a5\u9053\u7684\u5176\u4ed6\u5ba4\u6e29\u81ea\u6108\u5408\u5f39\u6027\u4f53\u7684\u201c\u97e7\u6027T\u201d\u548c\u201c\u62c9\u4f38\u5f3a\u5ea6TS\u201d\u3002<\/p>\n

\u56fe\u4e94\u3001\u53cc\u6a21\u5f0fUCF\u6750\u6599\u7684\u8868\u5f81<\/strong>
\n \"\"a\uff09\u6838@\u58f3\u7ed3\u6784\u7684UCF NPs\u4e0a\u8f6c\u6362\u53d1\u5149\u8fc7\u7a0b\u4e2d\u80fd\u91cf\u8fc1\u79fb\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

b-c\uff09\u5185\u6838Er NPs\u7684TEM\u548cHRTEM\u56fe\u50cf\uff1b<\/p>\n

d-e\uff09\u6838@\u58f3\u7ed3\u6784\u7684Er@Nd NPs\u7684HRTEM\u56fe\u50cf\u548c\u76f8\u5e94\u7684\u5c3a\u5bf8\u5206\u5e03\uff1b<\/p>\n

f\uff09\u6838@\u58f3\u7ed3\u6784\u7684Er@Nd NPs\u7684UCF\u5149\u8c31\uff1b<\/p>\n

g\uff09\u5728CIE\u8272\u5ea6\u56fe\u4e0a\uff0c\u6807\u8bb0\u5728980\u548c808 nm\u6fc0\u53d1\u4e0bEr@Nd NPs\u7684\u8367\u5149\u53d1\u5c04\u3002<\/p>\n

\u56fe\u516d\u3001\u5c06\u53cc\u6a21\u5f0f\u4e0a\u8f6c\u6362\u6750\u6599\u96c6\u6210\u5230PU-CDs\u4e2d\u5b9e\u73b0\u4e09\u6a21\u8367\u5149\u54cd\u5e94\u7684\u81ea\u6108\u5408\u7cfb\u7edf<\/strong>
\n \"\"a\uff09\u76f4\u63a5\u5728PU-CDs\u5f39\u6027\u4f53\u4e0a\u4e1d\u7f51\u5370\u5237\u53ef\u8bbe\u8ba1\u7684\u56fe\u6848\u4ee5\u5236\u9020\u81ea\u6108\u5149\u5b66\u5668\u4ef6\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

b\uff09\u5728\u81ea\u7136\u73af\u5883\u3001UV\u3001980nm\u3001808nm\u4e0b\uff0cPU-CDs\u5f39\u6027\u4f53\u4e0a\u5370\u5236\u7684\u7b80\u5355\u53ca\u590d\u6742\u56fe\u6848\u7684\u7167\u7247\uff1b<\/p>\n

c\uff09\u5370\u6709\u5404\u79cd\u56fe\u6848\u7684\u8367\u5149\u54cd\u5e94\u7684PU\u5f39\u6027\u4f53\u6108\u5408\u524d\u540e\u7684\u56fe\u50cf\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1aPrintable, Down\/Up-Conversion Triple-Mode Fluorescence Responsive and Colorless Self-Healing Elastomers with Superior Toughness<\/a><\/strong>. Adv. Funct. Mater.<\/em>, 2021<\/strong>, DOI: 10.1002\/adfm.202100211.<\/p>\n

\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb<\/strong><\/p>\n

\"\"<\/p>\n

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