{"id":219854,"date":"2021-04-05T06:33:48","date_gmt":"2021-04-04T22:33:48","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=219854"},"modified":"2021-04-04T21:35:11","modified_gmt":"2021-04-04T13:35:11","slug":"%e6%a2%b3%e7%90%86%ef%bc%9anature%e5%ad%90%e5%88%8a%e5%8f%88%e6%8a%a5%e9%81%93%e4%ba%86%e5%9b%ba%e6%80%81%e7%94%b5%e6%b1%a0%e5%93%aa%e4%ba%9b%e6%9c%80%e6%96%b0%e7%aa%81%e7%a0%b4%ef%bc%9f","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=219854","title":{"rendered":"\u68b3\u7406\uff1aNature\u5b50\u520a\u53c8\u62a5\u9053\u4e86\u56fa\u6001\u7535\u6c60\u54ea\u4e9b\u6700\u65b0\u7a81\u7834\uff1f"},"content":{"rendered":"

\u7535\u5316\u5b66\u50a8\u80fd\u7cfb\u7edf\uff0c\u5982\u9502\u79bb\u5b50\u7535\u6c60\uff0c\u53ef\u63d0\u4f9b\u9ad8\u6548\u3001\u53ef\u9760\u7684\u7535\u80fd\u50a8\u5b58\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u4fbf\u643a\u5f0f\u7535\u5b50\u4ea7\u54c1\u548c\u7535\u52a8\u6c7d\u8f66\u3002\u7136\u800c\uff0c\u76ee\u524d\u7684\u5546\u7528\u9502\u79bb\u5b50\u7535\u6c60\u4f7f\u7528\u53ef\u71c3\u7684\u6709\u673a\u6db2\u4f53\u7535\u89e3\u8d28\uff0c\u56e0\u6b64\u5728\u8fc7\u5ea6\u5145\u7535\u6216\u6ee5\u7528\u64cd\u4f5c\u671f\u95f4\uff0c\u7279\u522b\u662f\u5728\u5927\u89c4\u6a21\u5e94\u7528\u4e2d\uff0c\u5b58\u50a8\u706b\u707e\u98ce\u9669\u3002\u57fa\u4e8e\u6b64\uff0c\u4eba\u4eec\u4e00\u76f4\u8ba4\u4e3a\u7528\u56fa\u4f53\u7535\u89e3\u8d28\u4ee3\u66ff\u6db2\u4f53\u7535\u89e3\u8d28\u53ef\u4ee5\u907f\u514d\u5b89\u5168\u9690\u60a3\u3002<\/b><\/strong>\u7136\u800c\uff0c\u56fa\u6001\u7535\u6c60\u7684\u53d1\u5c55\u5728\u5f88\u5927\u7a0b\u5ea6\u4e0a\u53d6\u51b3\u4e8e\u5177\u6709\u5feb\u901f\u79bb\u5b50\u5bfc\u7535\u6027\u7684\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u53d1\u5c55\u3002<\/p>\n

\u672c\u671f\uff0c\u7b14\u8005\u603b\u7ed3\u4e86\u8fd1\u671f\u5728\u56fa\u6001\u7535\u89e3\u8d28\u548c\u56fa\u6001\u7535\u6c60\u9886\u57df\u7684\u7814\u7a76\u8fdb\u5c55\u3002<\/p>\n

1. \u56fa\u6001\u9502\u79bb\u5b50\u7535\u6c60<\/b><\/strong><\/p>\n

\uff081\uff09Nat. Mater.:\u7535\u89e3\u8d28\u7194\u878d\u6e17\u900f\u5236\u9020\u65e0\u673a\u5168\u56fa\u6001\u9502\u79bb\u5b50\u7535\u6c60<\/b><\/strong><\/p>\n

\u5168\u56fa\u6001\u9502\u91d1\u5c5e\u548c\u9502\u79bb\u5b50\u7535\u6c60\u91c7\u7528\u65e0\u673a\u56fa\u6001\u7535\u89e3\u8d28\uff0c\u4e3a\u7535\u52a8\u6c7d\u8f66\u548c\u5176\u4ed6\u5e94\u7528\u63d0\u4f9b\u4e86\u66f4\u9ad8\u7684\u5b89\u5168\u6027\u3002\u7136\u800c\uff0c\u5f53\u524d\u7684\u65e0\u673a\u5168\u56fa\u6001\u9502\u79bb\u5b50\u7535\u6c60\u5236\u9020\u6280\u672f\u53d7\u5230\u9ad8\u6210\u672c\u3001\u8fc7\u91cf\u7684\u56fa\u6001\u7535\u89e3\u8d28\u548c\u5bfc\u7535\u6dfb\u52a0\u5242\uff0c\u4ee5\u53ca\u4f4e\u4f53\u79ef\u80fd\u91cf\u5bc6\u5ea6\u7684\u56f0\u6270\u3002\u76ee\u524d\u7684\u5236\u9020\u65b9\u6cd5\u5355\u72ec\u5236\u9020\u70e7\u7ed3\u9676\u74f7\u56fa\u6001\u7535\u89e3\u8d28\u819c\u548c\u7535\u6c60\u7535\u6781\uff0c\u7136\u540e\u5c0f\u5fc3\u5806\u53e0\u548c\u70e7\u7ed3\u5728\u4e00\u8d77\u3002\u5728\u6b64\uff0c\u7f8e\u56fd\u4f50\u6cbb\u4e9a\u7406\u5de5\u5b66\u9662Gleb Yushin<\/b><\/strong>\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u79cd\u98a0\u8986\u6027\u7684\u5236\u9020\u6280\u672f\uff0c\u964d\u4f4e\u4e86\u5236\u9020\u6210\u672c\uff0c\u63d0\u9ad8\u4e86\u6240\u6709\u56fa\u4f53\u7535\u6c60\u7684\u4f53\u79ef\u80fd\u91cf\u5bc6\u5ea6\u3002\u8be5\u65b9\u6cd5\u6a21\u4eff\u4e86\u5546\u7528\u6db2\u6001\u7535\u89e3\u8d28\u9502\u79bb\u5b50\u7535\u6c60\u7684\u4f4e\u6210\u672c\u5236\u9020\u5de5\u827a\uff0c\u4f7f\u7528\u4f4e\u7194\u70b9\u7684\u56fa\u6001\u7535\u89e3\u8d28\uff0c\u8fd9\u4e9b\u7535\u89e3\u8d28\u5728\u9002\u5ea6\u5347\u9ad8\u7684\u6e29\u5ea6\u4e0b(\u7ea6300\u2103\u6216\u66f4\u4f4e)\u4ee5\u6db2\u6001\u6e17\u900f\u5230\u81f4\u5bc6\u7684\u70ed\u7a33\u5b9a\u7535\u6781\u4e2d\uff0c\u7136\u540e\u5728\u51b7\u5374\u8fc7\u7a0b\u4e2d\u56fa\u5316\u3002\u8be5\u5de5\u827a\u7684\u7535\u6781\u548c\u7535\u6c60\u5236\u9020\u4e0e\u76ee\u524d\u9502\u79bb\u5b50\u7535\u6c60\u517c\u5bb9\uff0c\u8fd9\u5927\u5927\u964d\u4f4e\u4e86\u5de5\u4e1a\u5e94\u7528\u7684\u963b\u788d\u3002\u8fd9\u79cd\u9ad8\u6548\u8282\u80fd\u7684\u65b9\u6cd5\u88ab\u7528\u4e8e\u5236\u5907\u5177\u6709LiNi0.33<\/sub>Mn0.33<\/sub>Co0.33<\/sub>O2<\/sub>\u6b63\u6781\u548cLi4<\/sub>Ti5<\/sub>O12<\/sub>\u548c\u77f3\u58a8\u8d1f\u6781\u7684\u5168\u56fa\u6001\u9502\u79bb\u5b50\u7535\u6c60\uff0c\u5176\u826f\u597d\u6027\u80fd\u8868\u73b0\u4e3a\u52a0\u901f\u5168\u56fa\u6001\u9502\u79bb\u5b50\u7535\u6c60\u5e94\u7528\uff0c\u4ee5\u5b9e\u73b0\u66f4\u5b89\u5168\u7684\u7535\u529b\u8fd0\u8f93\u5f00\u8f9f\u4e86\u65b0\u7684\u673a\u9047\u3002<\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u56fe1\u00a0\u7535\u89e3\u8d28\u7194\u878d\u6e17\u900f\u793a\u610f\u56fe\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aElectrolyte melt infiltration for scalable manufacturing of inorganic all-solid-state lithium-ion batteries<\/p>\n

https:\/\/www.nature.com\/articles\/s41563-021-00943-2<\/p>\n

\uff082\uff09<\/b><\/strong>Nat. Commun.: Li<\/b><\/strong>1.5<\/b><\/sub><\/strong>La<\/b><\/strong>1.5<\/b><\/sub><\/strong>MO<\/b><\/strong>6<\/b><\/sub><\/strong>(M=W<\/b><\/strong>6+<\/b><\/sup><\/strong>\uff0cTe<\/b><\/strong>6+<\/b><\/sup><\/strong>)\u4f5c\u4e3a\u5168\u56fa\u6001\u9502\u79bb\u5b50\u7535\u6c60\u7684\u65b0\u578b\u5bcc\u9502\u53cc\u9499\u949b\u77ff\u7cfb\u5217<\/b><\/strong><\/p>\n

\u56fa\u6001\u7535\u6c60\u662f\u4e00\u79cd\u5b89\u5168\u5b9e\u73b0\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u65b9\u6cd5\uff0c\u4f46\u8fd9\u79cd\u7ed3\u6784\u9762\u4e34\u7740\u7535\u6781\u548c\u56fa\u4f53\u7535\u89e3\u8d28\u4e4b\u95f4\u754c\u9762\u95ee\u9898\u7684\u6311\u6218\u3002\u5728\u6b64\uff0c\u82f1\u56fd\u8c22\u83f2\u5c14\u5fb7\u5927\u5b66Edmund J. Cussen\u3001Serena A. Corr<\/b><\/strong>\u56e2\u961f\u5f00\u53d1\u4e86\u4e00\u4e2a\u65b0\u7684\u53cc\u9499\u949b\u77ff\u7cfb\u5217Li1.5<\/sub>La1.5<\/sub>MO6<\/sub>(M=W6+<\/sup>\uff0cTe6+<\/sup>)\uff0c\u5176\u4e2d\u975e\u5e38\u89c1\u7684\u9502\u79bb\u5b50\u5206\u5e03\u5b9e\u73b0\u4e86\u5b8f\u89c2\u79bb\u5b50\u6269\u6563\uff0c\u7279\u5b9a\u7684\u7ec4\u6210\u8bbe\u8ba1\u4f7f\u5176\u53ef\u540c\u65f6\u4f5c\u4e3a\u8d1f\u6781\u6216\u56fa\u4f53\u7535\u89e3\u8d28\u3002\u94a8\u7684\u5f15\u5165\u5141\u8bb8\u57281 V\u4ee5\u4e0b\u53ef\u9006\u7684\u9502\u79bb\u5b50\u5d4c\u5165\uff0c\u4f7f\u5176\u80fd\u591f\u7528\u4f5c\u8d1f\u6781(\u521d\u59cb\u6bd4\u5bb9\u91cf> 200 mAh g-1<\/sup>\uff0c\u4f53\u79ef\u53d8\u5316\u975e\u5e38\u4f4e\uff0c\u4e3a0.2%)\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u7528\u78b2\u66ff\u4ee3\u94a8\u53ef\u5b9e\u73b0\u6c27\u5316\u8fd8\u539f\u7a33\u5b9a\u6027\uff0c\u4ece\u800c\u53ef\u5c06\u9499\u949b\u77ff\u4f5c\u4e3a\u56fa\u76f8\u7535\u89e3\u8d28\uff0c\u8be5\u7535\u89e3\u8d28\u5177\u6709\u9ad8\u8fbe5 V\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u548c\u5fae\u89c2\u9502\u79bb\u5b50\u6269\u6563\u7684\u4f4e\u6d3b\u5316\u80fd\u52bf\u5792(< 0.2 eV)\u3002\u8de8\u591a\u4e2a\u5c3a\u5ea6\u548c\u65f6\u95f4\u5c3a\u5ea6\u7684\u8868\u5f81\uff0c\u53ef\u5145\u5206\u63ed\u793a\u8fd9\u7c7b\u6750\u6599\u4e2d\u7684\u7ed3\u6784-\u6027\u8d28\u5173\u7cfb\uff0c\u5e76\u4e14\u5bf9\u4f7f\u7528\u4e24\u79cd\u7ec4\u5408\u7269\u7684\u56fa\u6001\u7535\u6c60\u7684\u521d\u6b65\u6d4b\u8bd5\u8868\u660e\uff0c\u6676\u683c\u5339\u914d\u7b56\u7565\u662f\u5168\u56fa\u6001\u7535\u6c60\u7684\u5e0c\u671b\u3002<\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u56fe2\u00a0Li1.5<\/sub>La1.5<\/sub>MO6<\/sub>(M=W6+<\/sup>\uff0cTe6+<\/sup>)\u53cc\u9499\u949b\u77ff\u7684\u6676\u4f53\u7ed3\u6784\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aLi1.5<\/sub>La1.5<\/sub>MO6<\/sub>(M=W6+<\/sup>, Te6+<\/sup>) as a new series of lithium-rich double perovskites for all-solid-state lithium-ion batteries<\/p>\n

https:\/\/www.nature.com\/articles\/s41467-020-19815-5<\/u><\/a><\/p>\n

\uff083\uff09Nat. Mater.:<\/b><\/strong>\u00a0<\/b><\/strong>\u9610\u660e\u56fa\u4f53\u7535\u89e3\u8d28\u4e2d\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u4e0e\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u7684\u5173\u7cfb<\/b><\/strong><\/p>\n

\u5168\u56fa\u6001\u9502\u79bb\u5b50\u7535\u6c60\u6709\u671b\u4ee5\u66f4\u5927\u7684\u4f53\u79ef\u548c\u91cd\u91cf\u80fd\u91cf\u5bc6\u5ea6,\u5b9e\u73b0\u66f4\u5b89\u5168\u7684\u7535\u5316\u5b66\u50a8\u80fd\u3002\u4f46\u76ee\u524d\u5b58\u5728\u7684\u4e3b\u8981\u95ee\u9898\u662f\u56fa\u4f53\u7535\u89e3\u8d28\u6709\u9650\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u548c\u76f8\u5173\u7684\u6709\u5bb3\u526f\u53cd\u5e94\uff0c\u76ee\u524d\u6211\u4eec\u5bf9\u6b64\u7406\u89e3\u6709\u9650\u3002\u5728\u6b64\uff0c\u8377\u5170\u4ee3\u5c14\u592b\u7279\u7406\u5de5\u5927\u5b66Marnix Wagemaker\u3001Swapna Ganapathy<\/b><\/strong>\u56e2\u961f\u8bc1\u660e\u4e86\u5bf9\u4e8e\u786b\u94f6\u9517\u77ff\u578b\u3001\u77f3\u69b4\u77f3\u578b\u548cNASICON\u7c7b\u578b\u578b\u56fa\u4f53\u7535\u89e3\u8d28\uff0c\u901a\u8fc7\u56fa\u4f53\u7535\u89e3\u8d28\u7684(\u53bb)\u9502\u5316\u72b6\u6001\uff0c\u8fdb\u5165\u70ed\u529b\u5b66\u7a33\u5b9a\u7684\u5206\u89e3\u4ea7\u7269\uff0c\u6709\u5229\u7684\u5206\u89e3\u9014\u5f84\u662f\u95f4\u63a5\u7684\uff0c\u800c\u4e0d\u662f\u76f4\u63a5\u7684\u3002\u7ed3\u679c\u662f\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u7a97\u53e3\uff0c\u660e\u663e\u5927\u4e8e\u76f4\u63a5\u5206\u89e3\u7684\u9884\u6d4b\u503c\uff0c\u63ed\u793a\u4e86\u7a33\u5b9a\u6027\u7a97\u53e3\u7684\u5408\u7406\u5316\u3002\u9664\u4e86\u5206\u89e3\u4ea7\u7269\u7684\u8d21\u732e\u4e4b\u5916\uff0c\u89c2\u5bdf\u5230\u7684\u786b\u94f6\u9517\u77ff\u578b\u4e9a\u7a33\u5b9a(\u53bb\u9502\u5316)\u56fa\u4f53\u7535\u89e3\u8d28\u8d21\u732e\u4e86\u5168\u56fa\u6001\u7535\u6c60\u7684(\u975e)\u53ef\u9006\u5faa\u73af\u5bb9\u91cf\uff0c\u5168\u9762\u89e3\u91ca\u4e86\u56fa\u4f53\u7535\u89e3\u8d28\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u3002\u63d0\u51fa\u673a\u7406\u7684\u672c\u8d28\u8868\u660e\uff0c\u8fd9\u662f\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u4e00\u4e2a\u5173\u952e\u65b9\u9762\uff0c\u6307\u5bfc\u5168\u56fa\u6001\u7535\u6c60\u7684\u754c\u9762\u548c\u6750\u6599\u8bbe\u8ba1\u3002<\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u56fe3\u00a0\u94f6\u6a44\u6984\u77f3LPSC\u7684\u6c27\u5316(\u8131\u9502)\u548c\u8fd8\u539f(\u9502\u5316)\u7535\u5316\u5b66\u6d3b\u6027\u793a\u610f\u56fe\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aClarifying the relationship between redox activity and electrochemical stability in solid electrolytes<\/p>\n

https:\/\/www.nature.com\/articles\/s41563-019-0576-0<\/p>\n

2. \u56fa\u6001\u9502\u91d1\u5c5e\u7535\u6c60<\/b><\/strong><\/p>\n

\uff081\uff09Joule\uff1a\u542b\u91d1\u5c5e\u9502\u7684\u9502\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u70ed\u7a33\u5b9a\u6027<\/b><\/strong><\/p>\n

\u5168\u56fa\u6001\u9502\u91d1\u5c5e\u7535\u6c60\u88ab\u8ba4\u4e3a\u662f\u6781\u5177\u524d\u9014\u7684\u4e0b\u4e00\u4ee3\u7535\u6c60\u4f53\u7cfb\u3002\u4f17\u6240\u5468\u77e5\uff0c\u4f20\u7edf\u9502\u79bb\u5b50\u7535\u6c60\u4e2d\u7684\u70ed\u5931\u63a7\u4f1a\u9020\u6210\u5b89\u5168\u9690\u60a3\uff0c\u800c\u9ad8\u6d3b\u6027\u91d1\u5c5e\u9502\u4e0e\u4e0d\u53ef\u71c3\u9676\u74f7\u56fa\u4f53\u7535\u89e3\u8d28\u4e4b\u95f4\u7684\u70ed\u95ee\u9898\u7814\u7a76\u8f83\u5c11\uff0c\u4f46\u5bf9\u5168\u56fa\u6001\u9502\u91d1\u5c5e\u7535\u6c60\u7684\u5b89\u5168\u6027\u81f3\u5173\u91cd\u8981\u3002\u5728\u6b64\uff0c\u4e2d\u79d1\u9662\u7269\u7406\u6240Hong Li\u3001Xiqian Yu\u548c\u7f8e\u56fd\u9a6c\u91cc\u5170\u5927\u5b66Yifei Mo<\/b><\/strong>\u5408\u4f5c\uff0c\u4f7f\u7528\u52a0\u901f\u91cf\u70ed\u4eea\u91cf\u5316\u4e86\u56db\u79cd\u5e38\u89c1\u7684\u91d1\u5c5e\u9502\u6c27\u5316\u7269\u7684\u70ed\u7a33\u5b9a\u6027\u3002\u5728\u4e0e\u9502\u63a5\u89e6\u65f6\uff0c\u5728\u56db\u79cd\u5e7f\u6cdb\u4f7f\u7528\u7684\u56fa\u6001\u7535\u89e3\u8d28\u7684\u52a0\u901f\u91cf\u70ed\u4eea\u6d4b\u8bd5\u671f\u95f4\uff0c\u89c2\u5bdf\u5230\u70ed\u5931\u63a7\uff0c\u800c\u4e0e\u9502\u63a5\u89e6\u7684\u77f3\u69b4\u77f3\u6ca1\u6709\u660e\u663e\u7684\u70ed\u91ca\u653e\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u9ad8\u6e29\u4e0b\u56fa\u6001\u7535\u89e3\u8d28\u4ea7\u751f\u7684\u6c27\u662f\u70ed\u5931\u63a7\u7684\u539f\u56e0\u3002\u7ed3\u679c\u8868\u660e\uff0c\u5728\u6240\u6709\u56fa\u6001\u7535\u6c60\u4e2d\uff0c\u9ad8\u6d3b\u6027\u91d1\u5c5e\u9502\u548c\u6765\u81ea\u56fa\u6001\u7535\u89e3\u8d28\u7684\u6c27\u6c14\uff0c\u5728\u5347\u9ad8\u7684\u6e29\u5ea6\u4e0b\u4f1a\u5e26\u6765\u6f5c\u5728\u7684\u5b89\u5168\u95ee\u9898\uff0c\u5f3a\u8c03\u4e86\u7814\u7a76\u56fa\u6001\u7535\u6c60\u70ed\u5b89\u5168\u95ee\u9898\u7684\u5fc5\u8981\u6027\u3002<\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u56fe4\u00a0\u56fa\u6001\u9502\u91d1\u5c5e\u7535\u6c60\u70ed\u5931\u63a7\u673a\u7406\u793a\u610f\u56fe\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aThe Thermal Stability of Lithium Solid Electrolytes with Metallic Lithium<\/p>\n

https:\/\/www.sciencedirect.com\/science\/article\/abs\/pii\/S2542435120301276?via%3Dihub<\/u><\/a><\/p>\n

\uff082\uff09Adv. Mater.\uff1a\u5728\u5408\u91d1-\u805a\u5408\u7269\u590d\u5408\u7535\u89e3\u8d28\u4e2d\u6784\u5efa\u5bcc\u9502\u4eba\u5de5SEI\u5c42\u5b9e\u73b0\u5168\u56fa\u6001\u9502\u91d1\u5c5e\u7535\u6c60\u7684\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387<\/b><\/strong><\/p>\n

\u4e3a\u4e86\u5b9e\u73b0\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\uff0c\u534e\u5357\u7406\u5de5\u5927\u5b66Min Zhu<\/b><\/strong>\u56e2\u961f\u901a\u8fc7\u6dfb\u52a0\u9502\u57fa\u5408\u91d1\uff0c\u5728\u805a\u5408\u7269\u57fa\u805a(\u73af\u6c27\u4e59\u70f7)-\u53cc(\u4e09\u6c1f\u7532\u78fa\u9170\u57fa)\u9170\u4e9a\u80fa\u9502\u590d\u5408\u56fa\u4f53\u7535\u89e3\u8d28(\u7b80\u79f0PEOm<\/sub>)\u4e2d\uff0c\u6784\u5efa\u4e86\u7ea660 nm\u539a\u7684\u4eba\u9020\u5bcc\u9502\u754c\u9762\u5c42\u3002\u9ad8\u5206\u8fa8\u7387\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\u548c\u7535\u5b50\u80fd\u91cf\u635f\u5931\u8c31\u663e\u793a\uff0c\u5728\u9502\u57fa\u5408\u91d1\u9897\u7c92\u5468\u56f4\u5f62\u6210\u4e86\u4e00\u4e2a\u975e\u6676\u7279\u5f81\u7684\u4eba\u5de5\u754c\u9762\u5c42\uff0c\u9502\u5728\u8be5\u754c\u9762\u5c42\u4e0a\u5448\u68af\u5ea6\u5206\u5e03\u3002\u7535\u5316\u5b66\u5206\u6790\u548c\u7406\u8bba\u5efa\u6a21\u8868\u660e\uff0c\u754c\u9762\u5c42\u63d0\u4f9b\u4e86\u5feb\u901f\u7684\u79bb\u5b50\u4f20\u8f93\u8def\u5f84\uff0c\u5bf9\u5b9e\u73b0PEOm<\/sub>-Li21<\/sub>S5<\/sub>\u590d\u5408\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u9ad8\u7a33\u5b9a\u79bb\u5b50\u7535\u5bfc\u7387\u8d77\u7740\u5173\u952e\u4f5c\u7528\u3002PEOm<\/sub>-5%Li21<\/sub>Si5<\/sub>\u590d\u5408\u7535\u89e3\u8d28\u572830 \u2103\u65f6\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u4e3a3.9\u00d710\u20135<\/sup>\u00a0S cm-1<\/sup>\uff0c\u572845 \u2103\u65f6\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u4e3a5.6\u00d710-4 <\/sup>S cm-1<\/sup>\u3002LiFePO4<\/sub>|PEOm<\/sub>-5%Li21<\/sub>Si5<\/sub>|Li\u5168\u56fa\u6001\u7535\u6c60\u57280.2 C\u548c30 \u2103\u65f6\u53ef\u4fdd\u6301129.2\u00a0mAh\u00a0g\u2212<\/sup>1<\/sup>\u7684\u7a33\u5b9a\u5bb9\u91cf\uff0c\u57280.5 C\u548c45 \u2103\u65f6\u53ef\u4fdd\u6301111.3 mAh\u00a0g\u2212<\/sup>1<\/sup>\u7684\u7a33\u5b9a\u5bb9\u91cf\u3002<\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u56fe5\u00a0PEOm<\/sub>-Lix<\/sub>M (M:Si,Ge\u548cSn)\u7535\u89e3\u8d28\u7684\u5236\u5907\u548c\u56fe\u7247\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aConstructing Li-Rich Artificial SEI Layer in Alloy-Polymer Composite Electrolyte to Achieve High Ionic Conductivity for All Solid-State Lithium Metal Batteries<\/p>\n

https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/adma.202004711<\/u><\/a><\/p>\n

\uff083\uff09Nat. Commun.: \u7528\u4e8e\u65e0\u679d\u6676\u56fa\u4f53\u9502\u91d1\u5c5e\u7535\u6c60\u7684\u67d4\u6027\u7535\u5b50\u963b\u6321\u754c\u9762\u5c4f\u853d<\/b><\/strong><\/p>\n

\u56fa\u6001\u7535\u6c60\u88ab\u8ba4\u4e3a\u662f\u4e0b\u4e00\u4ee3\u9502\u79bb\u5b50\u7535\u6c60\u6280\u672f\uff0c\u56e0\u4e3a\u5b83\u4eec\u5177\u6709\u66f4\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\u548c\u5b89\u5168\u6027\u3002\u7136\u800c\uff0c\u56fa\u6001\u7535\u89e3\u8d28\u7684\u9ad8\u7535\u5bfc\u7387\u5bfc\u81f4\u4e86\u9502\u679d\u6676\u6210\u6838\uff0c\u754c\u9762\u63a5\u89e6\u4e0d\u826f\u5bfc\u81f4\u7684\u7535\u573a\u5206\u5e03\u4e0d\u5747\u5300\uff0c\u4f1a\u8fdb\u4e00\u6b65\u4fc3\u8fdb\u679d\u6676\u6c89\u79ef\u548c\u751f\u957f\uff0c\u5bfc\u81f4\u56fa\u6001\u7535\u6c60\u5feb\u901f\u77ed\u8def\u3002\u5728\u8fd9\u91cc\uff0c\u52a0\u62ff\u5927\u897f\u5b89\u5927\u7565\u5927\u5b66<\/b><\/strong>Xueliang Sun<\/b><\/strong>\u548c\u9752\u5c9b\u5927\u5b66<\/b><\/strong>Xiangxin Guo<\/b><\/strong>\u5408\u4f5c\uff0c\u63d0\u51fa\u4e86\u4e00\u4e2a\u67d4\u6027\u7684\u7535\u5b50\u963b\u6321\u5c4f\u853d\u754c\u9762\uff0c\u6765\u4fdd\u62a4\u77f3\u69b4\u77f3\u7535\u89e3\u8d28\u514d\u53d7\u7535\u5b50\u9000\u5316\u3002\u901a\u8fc7\u539f\u4f4d\u53d6\u4ee3\u53cd\u5e94\u5f62\u6210\u7684\u7535\u5b50\u963b\u6321\u5c4f\u853d\u754c\u9762\uff0c\u4e0d\u4ec5\u53ef\u4ee5\u589e\u52a0\u4eb2\u9502\u6027\uff0c\u8fd8\u53ef\u4ee5\u7a33\u5b9a\u9502\u4f53\u79ef\u53d8\u5316\uff0c\u5728\u91cd\u590d\u5faa\u73af\u8fc7\u7a0b\u4e2d\u4fdd\u6301\u754c\u9762\u7684\u5b8c\u6574\u6027\u3002\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0c\u4ece\u9502\u91d1\u5c5e\u5230\u7535\u5b50\u963b\u6321\u5c4f\u853d\u754c\u9762\u6709\u5f88\u9ad8\u7684\u7535\u5b50\u96a7\u7a7f\u80fd\u5792\uff0c\u8868\u660e\u6709\u5f88\u597d\u7684\u7535\u5b50\u963b\u6321\u80fd\u529b\u3002\u7535\u6c60\u8868\u73b0\u51fa1.2 mA cm\u22122<\/sup>\u7684\u4e34\u754c\u7535\u6d41\u5bc6\u5ea6\u548c\u5ba4\u6e29\u4e0b\u57281\u00a0mA cm\u22122<\/sup>\u4e0b\u8d85\u8fc7400 h\u7684\u7a33\u5b9a\u5faa\u73af\u3002\u8fd9\u4e9b\u7ed3\u679c\u8bc1\u660e\u4e86\u6291\u5236\u9502\u679d\u6676\u7684\u7b56\u7565\u6709\u6548\uff0c\u5e76\u5bf9\u56fa\u6001\u7535\u89e3\u8d28\u548c\u9502\u91d1\u5c5e\u754c\u9762\u7684\u5408\u7406\u8bbe\u8ba1\u63d0\u51fa\u4e86\u65b0\u7684\u89c1\u89e3\u3002<\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u56fe6 \u5728\u4e0d\u540c\u7684\u754c\u9762\u9502\u679d\u6676\u751f\u957f\u60c5\u51b5\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aA flexible electron-blocking interfacial shield for\u00a0dendrite-free solid lithium metal batteries<\/p>\n

https:\/\/www.nature.com\/articles\/s41467-020-20463-y<\/a><\/u><\/p>\n

3. \u56fa\u6001\u9502\u786b\u7535\u6c60<\/b><\/strong><\/p>\n

\uff081\uff09Adv. Mater.\uff1a\u9502\u786b\u7535\u6c60\u7528\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u884d\u751f\u56fa\u4f53\u7535\u89e3\u8d28<\/b><\/strong><\/p>\n

\u9502\u786b\u7535\u6c60\u76ee\u524d\u88ab\u8ba4\u4e3a\u662f\u4e0b\u4e00\u4ee3\u50a8\u80fd\u6280\u672f\u7684\u5019\u9009\u4f53\u7cfb\u3002\u7136\u800c\uff0c\u5b83\u4eec\u7684\u5b9e\u9645\u5e94\u7528\u53d7\u5230\u591a\u786b\u5316\u7269\u7a7f\u68ad\u8fd9\u4e00\u5173\u952e\u95ee\u9898\u7684\u963b\u788d\u3002\u7f8e\u56fd\u5f97\u514b\u8428\u65af\u5927\u5b66\u5965\u65af\u6c40\u5206\u6821Arumugam Manthiram<\/b><\/strong>\u56e2\u961f\u63d0\u51fa\u4e86\u4e00\u79cd\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08MOF\uff09\u884d\u751f\u7684\u56fa\u4f53\u7535\u89e3\u8d28\u6765\u89e3\u51b3\u8fd9\u4e00\u95ee\u9898\u3002MOF\u56fa\u4f53\u7535\u89e3\u8d28\u662f\u57fa\u4e8eUIO\u7ed3\u6784\u5f00\u53d1\u7684\uff0c\u901a\u8fc7\u5c06\u78fa\u9178\u9502(-SO3<\/sub>Li)\u57fa\u56e2\u63a5\u679d\u5230UIO\u914d\u4f53\u4e0a\uff0c\u5f97\u5230\u7684-SO3Li\u63a5\u679dUIO (UIOSLi)\u56fa\u4f53\u7535\u89e3\u8d28\uff0c\u5176\u79bb\u5b50\u7535\u5bfc\u7387\u548c\u591a\u786b\u5316\u7269\u6291\u5236\u80fd\u529b\u90fd\u5f97\u5230\u4e86\u6781\u5927\u5730\u63d0\u9ad8\u3002\u57281-\u4e59\u57fa-3-\u7532\u57fa\u54aa\u5511\u5549\u53cc(\u4e09\u6c1f\u7532\u57fa\u78fa\u9170\u57fa)\u4e2d\u6574\u5408\u9502\u57fa\u79bb\u5b50\u6db2\u4f53(Li-IL)\u3001\u53cc(\u4e09\u6c1f\u7532\u57fa\u78fa\u9170\u57fa)\u9170\u4e9a\u80fa\u9502\u540e\uff0c\u6240\u5f97Li-IL\/UIOSLi\u56fa\u4f53\u7535\u89e3\u8d28\u5728\u5ba4\u6e29\u4e0b\u663e\u793a\u51fa3.3\u00d710-4<\/sup>\u00a0S\u00b7cm-1<\/sup>\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u3002\u57fa\u4e8e\u5176\u72ec\u7279\u7684\u7ed3\u6784\uff0cLi-IL\/UIOSLi\u56fa\u4f53\u7535\u89e3\u8d28\u6709\u6548\u5730\u6291\u5236\u591a\u786b\u5316\u7269\u7a7f\u68ad\u548c\u9502\u679d\u6676\u751f\u957f\u3002\u91c7\u7528Li-IL\/UIOSLi\u56fa\u4f53\u7535\u89e3\u8d28\u548cLi2<\/sub>S6<\/sub>\u6b63\u6781\u7535\u89e3\u8d28\u7684\u9502\u786b\u7535\u6c60\uff0c\u8868\u73b0\u51fa\u7a33\u5b9a\u7684\u5faa\u73af\u6027\u80fd\uff0c\u5728250\u6b21\u5faa\u73af\u540e\u4fdd\u630184%\u7684\u521d\u59cb\u5bb9\u91cf\uff0c\u6bcf\u6b21\u5faa\u73af\u7684\u5bb9\u91cf\u8870\u51cf\u7387\u4e3a0.06%\u3002<\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u56fe7\u00a0\u57fa\u4e8eUIO\u7ed3\u6784\u5f00\u53d1\u7684\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u7ed3\u6784\u793a\u610f\u56fe\u548c\u8868\u5f81\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aA Metal Organic Framework Derived Solid Electrolyte for Lithium\u2013Sulfur Batteries<\/p>\n

https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/aenm.202001285<\/u><\/a><\/p>\n

\uff082\uff09Energy Environ. Sci.:<\/b><\/strong>\u00a0<\/b><\/strong>\u5168\u56fa\u6001\u9502\u786b\u7535\u6c60\u4e2d\u591a\u786b\u5316\u7269\u7a7f\u68ad\u548c\u754c\u9762\u6f14\u5316\u7684\u673a\u7406\u7814\u7a76<\/b><\/strong><\/p>\n

\u5168\u56fa\u6001\u9502\u786b\u7535\u6c60\u5177\u6709\u6781\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\u548c\u5b89\u5168\u6027\uff0c\u5df2\u6210\u4e3a\u6781\u5177\u524d\u9014\u7684\u4e0b\u4e00\u4ee3\u50a8\u80fd\u7cfb\u7edf\u3002\u76f4\u63a5\u8ddf\u8e2a\u56fa\u6001\u9502\u786b\u7535\u6c60\u4e2d\u56fa\u4f53-\u56fa\u4f53\u754c\u9762\u7684\u7ed3\u6784\u6f14\u53d8\uff0c\u5bf9\u4e8e\u6df1\u5165\u7406\u89e3\u53cd\u5e94\u673a\u7406\u4ee5\u8fdb\u4e00\u6b65\u63d0\u9ad8\u7535\u5316\u5b66\u6027\u80fd\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u5728\u6b64\uff0c\u4e2d\u79d1\u9662\u5316\u5b66\u6240Rui Wen<\/b><\/strong>\u56e2\u961f\u901a\u8fc7\u5b9e\u65f6\u5149\u5b66\u663e\u5fae\u955c\u6210\u50cf\uff0c\u5bf9\u5de5\u4f5c\u4e2d\u7684\u56fa\u6001\u9502\u786b\u7535\u6c60\u7684\u6b63\u6781\/\u7535\u89e3\u8d28\u548c\u8d1f\u6781\/\u7535\u89e3\u8d28\u754c\u9762\u7684\u6f14\u5316\u8fc7\u7a0b\u8fdb\u884c\u4e86\u539f\u4f4d\u76d1\u6d4b\u3002\u5728\u805a\u5408\u7269-\u9676\u74f7\u590d\u5408\u7535\u89e3\u8d28\u4e2d\uff0c\u4ece\u4eae\u767d\u8272\u5230\u6df1\u68d5\u8272\u7684\u4e0d\u53ef\u9006\u8f6c\u53d8\u5728\u653e\u7535\/\u5145\u7535\u65f6\u88ab\u76f4\u63a5\u6355\u83b7\uff0c\u8fd9\u8868\u660e\u56fa\u6001\u7535\u89e3\u8d28\u4e2d\u591a\u786b\u5316\u7269\u7684\u7a7f\u68ad\u8fc7\u7a0b\uff0c\u4e14\u8fd9\u4e00\u7ed3\u8bba\u5f97\u5230\u4e86XPS\u548c\u62c9\u66fc\u5206\u6790\u7684\u8fdb\u4e00\u6b65\u652f\u6301\u3002\u6b64\u5916\uff0c\u7ed3\u6784\u6f14\u5316\u6e29\u5ea6\u4f9d\u8d56\u6027\u7684\u539f\u4f4d\u53ef\u89c6\u5316\uff0c\u6e05\u695a\u5730\u63ed\u793a\u6e29\u5ea6\u6781\u5927\u5730\u5f71\u54cd\u591a\u786b\u5316\u7269\u7a7f\u68ad\u3001\u56fa\u6001\u7535\u89e3\u8d28\u7684\u4e0d\u53ef\u9006\u4f53\u79ef\u53d8\u5316\u548c\u9502\u91d1\u5c5e\u7684\u4f53\u79ef\u81a8\u80c0\uff0c\u8fd9\u4e9b\u4e0e\u7535\u6c60\u6027\u80fd\u7684\u9000\u5316\u76f4\u63a5\u76f8\u5173\u3002\u8fd9\u4e9b\u7ed3\u679c\u63d0\u4f9b\u4e86\u5bf9\u56fa\u6001\u9502\u786b\u7535\u6c60\u7ed3\u6784\u548c\u7ec4\u5206\u7684\u6f14\u5316\u8fc7\u7a0b\u7684\u6df1\u523b\u89c1\u89e3\uff0c\u53ef\u4ee5\u6307\u5bfc\u4eba\u4eec\u63a2\u7d22\u5728\u56fa\u4f53-\u56fa\u4f53\u754c\u9762\u7684\u7535\u5316\u5b66\u53cd\u5e94\u548c\u5931\u6548\u673a\u7406\u3002\u8bbe\u8ba1\u9ad8\u6027\u80fd\u9502\u786b\u7535\u6c60\u3002<\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u56fe8\u00a0\u56fa\u6001\u9502\u786b\u7535\u6c60\u754c\u9762\u8fc7\u7a0b\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDirect tracking of the polysulfide shuttling and interfacial evolution in all-solid-state lithium\u2013sulfur batteries: a degradation mechanism study<\/p>\n

https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2019\/EE\/C9EE00578A#!divAbstract<\/a><\/u><\/p>\n

4. \u56fa\u6001\u94a0\u79bb\u5b50\/\u94a0\u91d1\u5c5e\u7535\u6c60<\/b><\/strong><\/p>\n

\uff081\uff09Nat. Commun.:\u7528\u4e8e\u9ad8\u7535\u538b\u3001\u957f\u5faa\u73af\u5bff\u547d\u56fa\u6001\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u6b63\u6781-\u56fa\u4f53\u7535\u89e3\u8d28\u590d\u5408\u7269<\/b><\/strong><\/p>\n

\u53ef\u5145\u7535\u56fa\u6001\u94a0\u79bb\u5b50\u7535\u6c60\u4e3a\u66f4\u5b89\u5168\u3001\u66f4\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u80fd\u91cf\u5b58\u50a8\u5e26\u6765\u4e86\u5de8\u5927\u7684\u5e0c\u671b\u3002\u7136\u800c\uff0c\u76ee\u524d\u786b\u5316\u7269\u57fa\u56fa\u4f53\u7535\u89e3\u8d28\u548c\u9ad8\u538b\u6c27\u5316\u7269\u6b63\u6781\u4e4b\u95f4\u7684\u5dee\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u9650\u5236\u4e86\u5b83\u4eec\u7684\u957f\u5faa\u73af\u6027\u80fd\u548c\u5b9e\u7528\u6027\u3002\u5728\u6b64\uff0c\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u5723\u5730\u4e9a\u54e5\u5206\u6821Shyue Ping Ong\u3001Ying Shirley Meng\u3001Abhik Banerjee\u548c\u52a0\u5dde\u5927\u5b66\u5723\u5df4\u5df4\u62c9\u5206\u6821Rapha<\/b><\/strong>\u00eb<\/b><\/strong>le J. Cl\u00e9ment<\/b><\/strong>\u5408\u4f5c\uff0c\u62a5\u9053\u4e86\u79bb\u5b50\u5bfc\u4f53Na3-x<\/sub>Y1-x<\/sub>Zrx<\/sub>Cl6<\/sub>(NYZC)\uff0c\u5b83\u65e2\u5177\u6709\u7535\u5316\u5b66\u7a33\u5b9a\u6027(\u9ad8\u8fbe3.8 V\u00a0vs. Na\/Na+<\/sup>)\uff0c\u53c8\u4e0e\u6c27\u5316\u7269\u6b63\u6781\u5316\u5b66\u517c\u5bb9\u3002\u5176\u5728\u5ba4\u6e29\u4e0b\u5177\u6709\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u4e3a6.6\u00d710-5<\/sup>\u00a0S cm-1<\/sup>\uff0c\u6bd4\u6c27\u5316\u7269\u6d82\u5c42\u9ad8\u51e0\u4e2a\u6570\u91cf\u7ea7\uff0c\u8fd9\u5f52\u56e0\u4e8e\u4e30\u5bcc\u7684\u94a0\u7a7a\u4f4d\u548c\u534f\u540c\u7684MCl6<\/sub>\u65cb\u8f6c\uff0c\u5b9e\u73b0\u4e86\u6781\u4f4e\u7684\u754c\u9762\u963b\u6297\u3002\u4e00\u4e2a\u7531NaCrO2<\/sub>+NYZC\u590d\u5408\u6b63\u6781\u3001Na3<\/sub>PS4<\/sub>\u7535\u89e3\u8d28\u548cNa-Sn\u8d1f\u6781\u7ec4\u6210\u7684\u56fa\u6001\u7535\u6c60\uff0c\u5728\u5ba4\u6e29\u4e0b\u8868\u73b0\u51fa97.1%\u7684\u9996\u6b21\u5faa\u73af\u5e93\u4ed1\u6548\u7387\uff0c\u572840 \u2103\u4e0b\u53ef\u4ee5\u5faa\u73af1000\u6b21\u4ee5\u4e0a\uff0c\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a89.3%\u3002\u8fd9\u4e00\u53d1\u73b0\u7a81\u51fa\u4e86\u5364\u5316\u7269\u5728\u5168\u56fa\u6001\u94a0\u79bb\u5b50\u7535\u6c60\u5e94\u7528\u4e2d\u7684\u5de8\u5927\u6f5c\u529b\u3002<\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u56fe9\u00a0Zr\u63ba\u6742\u5bf9\u4e8eNa3<\/sub>YCl6<\/sub>\u7684\u6027\u8d28\u5f71\u54cd\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aA stable cathode-solid electrolyte composite for high-voltage, long-cycle-life solid-state sodium-ion batteries<\/p>\n

https:\/\/www.nature.com\/articles\/s41467-021-21488-7<\/u><\/a><\/p>\n

\uff082\uff09<\/b><\/strong>Energy Environ. Sci.:<\/b><\/strong>\u00a0<\/b><\/strong>\u949d\u5316\u6b63\u6781\/\u787c\u6c22\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u754c\u9762\u5b9e\u73b0\u76844 V\u5ba4\u6e29\u5168\u56fa\u6001\u94a0\u91d1\u5c5e\u7535\u6c60<\/b><\/strong><\/p>\n

\u4e3a\u5168\u56fa\u6001\u7535\u6c60\u8bbe\u8ba1\u80fd\u591f\u627f\u53d7\u4e0e\u78b1\u91d1\u5c5e\u8d1f\u6781\u548c\u9ad8\u538b\u6b63\u6781\u63a5\u89e6\u7684\u6781\u7aef\u7535\u5316\u5b66\u6761\u4ef6\u4e0b\u5de5\u4f5c\u7684\u56fa\u4f53\u7535\u89e3\u8d28\u5177\u6709\u6311\u6218\u6027\uff0c\u5c24\u5176\u662f\u5f53\u7535\u6c60\u7684\u5faa\u73af\u7535\u538b\u8d85\u8fc74V\u65f6\u3002\u5728\u6b64\uff0c\u745e\u58eb\u8054\u90a6\u6750\u6599\u79d1\u5b66\u548c\u6280\u672f\u5b9e\u9a8c\u5ba4Arndt Remhof<\/b><\/strong>\u56e2\u961f\u8bc1\u660e\u7531\u4e24\u79cd\u6c27\u5316\u7a33\u5b9a\u6027\u4e0d\u540c\u7684\u7b3c\u72b6\u9634\u79bb\u5b50\u6784\u5efa\u7684\u787c\u6c22\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28Na4<\/sub>(CB11<\/sub>H12<\/sub>)2<\/sub>(B12<\/sub>H12<\/sub>)\uff0c\u80fd\u591f\u6709\u6548\u949d\u53164V\u7ea7\u6b63\u6781\u7684\u754c\u9762\uff0c\u5e76\u9632\u6b62\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7684\u963b\u6297\u589e\u52a0\u3002\u7814\u7a76\u8868\u660e[B12<\/sub>H12<\/sub>]2-<\/sup>\u9634\u79bb\u5b50\u57284.2 V\u4ee5\u4e0b\u5206\u89e3\u5f62\u6210\u949d\u5316\u754c\u9762\u5c42\uff0c\u800c[CB11<\/sub>H12<\/sub>]–<\/sup>\u9634\u79bb\u5b50\u4fdd\u6301\u5b8c\u6574\uff0c\u5728\u6574\u4e2a\u5c42\u4e0a\u63d0\u4f9b\u8db3\u591f\u7684\u79bb\u5b50\u5bfc\u7535\u6027\u3002\u672c\u7814\u7a76\u9996\u6b21\u5c55\u793a\u4e86\u4e00\u79cd4 V\u7ea7\u787c\u6c22\u5316\u7269\u57fa\u5168\u56fa\u6001\u7535\u6c60\uff0c\u8be5\u7535\u6c60\u7ed3\u5408\u4e86\u94a0\u91d1\u5c5e\u8d1f\u6781\u548c\u65e0\u94b4Na3<\/sub>(VOPO4<\/sub>)2<\/sub>F\u6b63\u6781\uff0c\u6ca1\u6709\u4efb\u4f55\u4eba\u5de5\u4fdd\u62a4\u6d82\u5c42\u3002\u5f53\u5faa\u73af\u52304.15V\u65f6\uff0c\u7535\u6c60\u5728C\/10\u4e0b\u7684\u653e\u7535\u5bb9\u91cf\u4e3a104 mAh g-1<\/sup>\u548c\u5728C\/5\u4e0b99 mAh g-1<\/sup>\u3002\u5728\u5ba4\u6e29\u548c\uff1c0.2MPa\u7684\u538b\u529b\u4e0b\uff0c\u7ecf\u8fc7800\u6b21\u5faa\u73af\u540e\uff0c\u5176\u5bb9\u91cf\u548c\u80fd\u91cf\u4fdd\u6301\u7387\u5206\u522b\u4e3a78%\u548c76%\u3002\u5c06\u538b\u529b\u589e\u52a0\u52303.2 MPa\uff0c\u5728C\/10\u4e0b\u653e\u7535\u5bb9\u91cf\u8fbe\u5230117 mAh g-1<\/sup>\uff0c\u8d28\u91cf\u8d1f\u8f7d\u4e3a8.0 mg cm-2<\/sup>\uff0c\u5bf9\u5e94\u4e8e\u63a5\u8fd11.0 mAh cm-2<\/sup>\u7684\u9762\u79ef\u5bb9\u91cf\u3002\u8be5\u7535\u6c60\u4fdd\u6301\u4e86\u8fc4\u4eca\u4e3a\u6b62\u62a5\u9053\u7684\u5168\u56fa\u6001\u94a0\u7535\u6c60\u4e2d\u6700\u9ad8\u7684\u5e73\u5747\u653e\u7535\u7535\u6c60\u7535\u538b3.8 V\u548c\u6bcf\u4e2a\u6b63\u6781\u6d3b\u6027\u6750\u6599\u7684\u6bd4\u80fd\u91cf\uff0c\u5f3a\u8c03\u4e86\u787c\u6c22\u5316\u7269\u4f5c\u4e3a\u7535\u89e3\u8d28\u7528\u4e8e\u5168\u56fa\u6001\u7535\u6c60\u6280\u672f\u7684\u6f5c\u529b\u3002<\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u56fe10\u00a04V Na3<\/sub>(VOPO4<\/sub>)2<\/sub>F|Na4<\/sub>(CB11<\/sub>H12<\/sub>)2(B12<\/sub>H12<\/sub>)|Na\u5168\u56fa\u6001\u7535\u6c60\u7684\u622a\u9762SEM\u56fe\u50cf\u548c\u793a\u610f\u56fe\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a4 V room-temperature all-solid-state sodium battery enabled by a passivating cathode\/hydroborate solid electrolyte interface<\/p>\n

https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2020\/EE\/D0EE01569E#!divAbstract<\/p>\n

\u672c\u6587\u7531Nelson\u4f9b\u7a3f\u3002<\/p>\n

\u672c\u5185\u5bb9\u4e3a\u4f5c\u8005\u72ec\u7acb\u89c2\u70b9\uff0c\u4e0d\u4ee3\u8868\u6750\u6599\u4eba\u7f51\u7acb\u573a\u3002<\/p>\n

\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u7535\u5316\u5b66\u50a8\u80fd\u7cfb\u7edf\uff0c\u5982\u9502\u79bb\u5b50\u7535\u6c60\uff0c\u53ef\u63d0\u4f9b\u9ad8\u6548\u3001\u53ef\u9760\u7684\u7535\u80fd\u50a8\u5b58\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u4fbf\u643a\u5f0f\u7535\u5b50\u4ea7\u54c1\u548c\u7535\u52a8\u6c7d\u8f66\u3002\u7136\u800c\uff0c\u76ee\u524d\u7684\u5546\u7528\u9502\u79bb\u5b50\u7535\u6c60\u4f7f\u7528\u53ef\u71c3\u7684\u6709\u673a\u6db2\u4f53\u7535\u89e3\u8d28\uff0c\u56e0\u6b64\u5728\u8fc7\u5ea6\u5145\u7535…<\/p>\n","protected":false},"author":11454,"featured_media":219865,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1187],"tags":[],"class_list":["post-219854","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zhuanlan"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/219854"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=219854"}],"version-history":[{"count":4,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/219854\/revisions"}],"predecessor-version":[{"id":220224,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/219854\/revisions\/220224"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/219865"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=219854"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=219854"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=219854"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}