{"id":22022,"date":"2016-06-27T08:00:50","date_gmt":"2016-06-27T00:00:50","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=22022"},"modified":"2016-06-27T09:54:49","modified_gmt":"2016-06-27T01:54:49","slug":"%e5%ad%a6%e6%9c%af%e5%b9%b2%e8%b4%a7-%e4%b8%8d%e5%be%97%e4%b8%8d%e8%af%b4-%e6%9c%89%e6%9c%ba%e5%a4%aa%e9%98%b3%e8%83%bd%e7%94%b5%e6%b1%a0%e7%9a%84%e9%87%8d%e8%a6%81%e5%8f%82%e6%95%b0","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=22022","title":{"rendered":"\u5b66\u672f\u5e72\u8d27 | \u89e3\u5256\u4e13\u4e1a\u597d\u6587\u2014\u2014\u8bf4\u8bf4\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u7684\u91cd\u8981\u53c2\u6570\u53ca\u8868\u5f81"},"content":{"rendered":"

\u4eb2\u7231\u7684\u5c0f\u4f19\u4f34\u4eec\uff0c\u4e0a\u4e00\u6b21\u6211\u4eec\u8c08\u4e86\u300aTEM\u597d\u57fa\u53cb\u2014 Digital Micrograph\u529f\u80fd\u53ca\u4f7f\u7528\u6559\u7a0b<\/strong>\u300b<\/a><\/p>\n

\u8fd9\u4e00\u6b21\u6211\u4eec\u6765\u8c08\u4e00\u8c08\u672a\u6765\u65b0\u80fd\u6e90\u7684\u53d1\u5c55\u65b9\u5411\u2014\u2014\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\uff01<\/p>\n

\u4e00\u3001\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60<\/span>\u5668\u4ef6\u7684\u4e94\u4e2a\u91cd\u8981\u53c2\u6570<\/strong><\/p>\n

\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u4e3b\u8981\u7684\u6027\u80fd\u53c2\u6570\u5305\u62ec\uff1a\u5149\u7535\u8f6c\u6362\u6548\u7387\uff08Power Conversion Efficiency<\/span><\/span>\uff0c\u7b80\u5199\u4e3aPCE<\/span>\uff09\u3001\u5f00\u8def\u7535\u538b\uff08Open-circuit Voltage<\/span>\uff0c\u7b80\u5199\u4e3aV<\/em>OC<\/sub><\/span>\uff09\u3001\u77ed\u8def\u7535\u6d41\uff08Short-circuit Current Density<\/span>\uff0c\u7b80\u5199\u4e3aJ<\/em>SC<\/sub><\/span>\uff09\u3001\u586b\u5145\u56e0\u5b50\uff08Fill Factor<\/span>\uff0c\u7b80\u5199\u4e3aFF\uff09\u548c\u5916\u91cf\u5b50\u6548\u7387\uff08External Quantum Efficiency<\/span>\uff0c\u7b80\u5199\u4e3aEQE<\/span>\uff09\u3002\u5982\u56fe1-3\uff08b\uff09\u6240\u793a\uff0c\u5149\u4f0f\u6027\u80fd\u7684\u4f18\u52a3\u4e3b\u8981\u4f53\u73b0\u5728PCE\u7684\u6570\u503c\u4e0a\uff0c\u800cPCE\u7684\u6570\u503c\u4e0eV<\/em>OC<\/sub>\u3001J<\/em>SC<\/sub>\u3001FF\u8fd9\u4e09\u4e2a\u53c2\u6570\u7d27\u5bc6\u76f8\u5173\u3002<\/p>\n

<\/a><\/p>\n

\u56fe1-3\uff08a\uff09\u6d3b\u6027\u5c42\u7ed9\u53d7\u4f53\u6750\u6599\u80fd\u7ea7\u89e3\u6790\u793a\u610f\u56fe\uff08b\uff09\u7535\u6d41\u7535\u538b\u66f2\u7ebf\u56fe<\/p>\n

1\uff09\u5f00\u8def\u7535\u538b\uff0cV<\/em>OC<\/sub><\/strong><\/p>\n

V<\/em>OC<\/sub>\u662f\u592a\u9633\u80fd\u7535\u6c60\u5916\u7535\u8def\u65ad\u5f00\u6216\u7535\u6d41\u4e3a\u96f6\u65f6\u7684\u7535\u538b\uff0c\u5373\u662f\u6700\u5927\u8f93\u51fa\u7535\u538b\uff08\u56fe1-3\uff08b\uff09\uff09,\u662fJ-V<\/em>\u66f2\u7ebf\u4e2d\u6a2a\u5750\u6807\u4e3a0\u65f6\u7eb5\u5750\u6807\u6240\u5bf9\u5e94\u7684\u6570\u503c\u3002\u4e00\u822cV<\/em>OC<\/sub>\u503c\u8d8a\u5927\uff0c\u5176PCE\u503c\u8d8a\u5927\u3002V<\/em>OC<\/sub>\u4e0eD-A\u6750\u6599\u7684\u7c7b\u578b\u3001\u914d\u6bd4\u3001\u5668\u4ef6\u7ed3\u6784\u7b49\u6709\u5173\u3002\u5bf9\u4e8e\u5355\u5c42\u5668\u4ef6\uff0cV<\/em>OC<\/sub>\u7531\u6b63\u8d1f\u7535\u6781\u7684\u529f\u51fd\u4e4b\u5dee\u6240\u51b3\u5b9a\uff1b\u7136\u800c\u5bf9\u4e8e\u672c\u4f53\u5f02\u8d28\u7ed3\u7ed3\u6784\u5668\u4ef6\uff0cV<\/em>OC<\/sub>\u4e3b\u8981\u53d6\u51b3\u4e8e\u7ed9\u4f53\u7684HOMO\u80fd\u7ea7\u548c\u53d7\u4f53\u7684LUMO\u80fd\u7ea7\u7684\u80fd\u7ea7\u4e4b\u5dee\uff0c\u5373E<\/em>2\uff08\u56fe1-3\uff08a\uff09\uff09\u3002<\/p>\n

2\uff09\u77ed\u8def\u7535\u6d41\uff0cJ<\/em>SC<\/sub><\/strong><\/p>\n

J<\/em>SC<\/sub>\u662f\u592a\u9633\u80fd\u7535\u6c60\u4e0a\u65bd\u52a0\u7535\u538b\u4e3a\u96f6\u65f6\u5916\u7535\u8def\u4e0a\u7684\u7535\u6d41\u5bc6\u5ea6\uff08\u56fe1-3\uff08b\uff09\uff09\uff0c\u662fJ-V<\/em>\u66f2\u7ebf\u4e2d\u7eb5\u5750\u6807\u4e3a0\u65f6\u6a2a\u5750\u6807\u6240\u5bf9\u5e94\u7684\u6570\u503c\u3002\u4e00\u822cJ<\/em>SC<\/sub>\u503c\u8d8a\u5927\uff0c\u5176PCE\u503c\u8d8a\u5927\u3002J<\/em>SC<\/sub>\u4e0e\u5668\u4ef6\u7684\u5236\u5907\u5de5\u827a\u548cD-A\u6750\u6599\u7c7b\u578b\u6709\u5173\uff0c\u5982D-A\u6750\u6599\u7684\u914d\u6bd4\u3001\u6dfb\u52a0\u5242\u7684\u79cd\u7c7b\u3001\u9000\u706b\u3001\u754c\u9762\u4fee\u9970\u7b49\u5747\u53ef\u5f71\u54cdJ<\/em>SC<\/sub>\u7684\u6570\u503c\u3002<\/p>\n

3\uff09\u586b\u5145\u56e0\u5b50\uff0cFF<\/strong><\/p>\n

FF\u4e3a\u5728\u4e00\u5b9a\u8d1f\u8f7d\u4e0b\u592a\u9633\u80fd\u7535\u6c60\u63d0\u4f9b\u7684\u6700\u5927\u529f\u7387\u4e0eV<\/em>OC<\/sub>\u3001J<\/em>SC<\/sub>\u4e58\u79ef\u4e4b\u6bd4\uff0c\u5b83\u8868\u793a\u5668\u4ef6\u80fd\u591f\u5bf9\u5916\u754c\u63d0\u4f9b\u7684\u6700\u5927\u8f93\u51fa\u529f\u7387\u7684\u80fd\u529b\u53c2\u6570\uff0c\u56fe1-3\uff08b\uff09\uff1a<\/p>\n

FF = (V<\/em>max<\/sub>\u00d7J<\/em>max<\/sub>)\/(V<\/em>OC<\/sub>\u00d7J<\/em>SC<\/sub>) = Pmax<\/sub>\/(V<\/em>OC<\/sub>\u00d7J<\/em>SC<\/sub>)\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 \uff08\u5f0f1-1\uff09<\/p>\n

\u5176\u4e2d\uff0cV<\/em>max<\/sub>\u548cJ<\/em>max<\/sub>\u5206\u522b\u4e3a\u6700\u5927\u8f93\u51fa\u529f\u7387\u70b9Pmax<\/sub>\u7684\u7535\u538b\u548c\u7535\u6d41\u3002FF\u662f\u8003\u91cf\u7535\u6c60\u8f93\u51fa\u6027\u80fd\u7684\u4e00\u4e2a\u91cd\u8981\u53c2\u6570\uff0c\u5176FF\u503c\u8d8a\u5927\uff0cPCE\u503c\u5c31\u8d8a\u5927\u3002<\/p>\n

4\uff09\u5149\u7535\u8f6c\u6362\u6548\u7387\uff0cPCE<\/strong><\/p>\n

PCE\u8868\u660e\u4e86\u5165\u5c04\u5149\u7684\u80fd\u91cf\u6709\u591a\u5c11\u53ef\u4ee5\u8f6c\u5316\u6210\u6709\u6548\u7684\u7535\u80fd\uff0c\u662fPmax<\/sub>\uff08\u6700\u5927\u8f93\u51fa\u529f\u7387\uff09\u4e0ePin<\/sub>\uff08\u5165\u5c04\u5355\u8272\u5149\u529f\u7387\uff09\u7684\u6bd4\u503c\uff1a<\/p>\n

PCE = Pmax<\/sub>\/Pin<\/sub> = (V<\/em>OC<\/sub>\u00d7J<\/em>SC<\/sub>\u00d7FF)\/Pin\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 <\/sub>\u00a0\u00a0\u00a0\u00a0\u00a0\uff08\u5f0f1-2\uff09<\/p>\n

\u7531\u4e8e\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u4e2d\u7ed9\u4f53\u6750\u6599\u7684\u5149\u8c31\u54cd\u5e94\u8303\u56f4\u6bd4\u8f83\u7a84\uff0c\u5728\u592a\u9633\u5149\u4e0b\u7684\u80fd\u91cf\u8f6c\u5316\u6548\u7387\u8981\u4f4e\u4e8e\u5176\u5355\u8272\u5149\u7167\u5c04\u4e0b\u7684\u80fd\u91cf\u8f6c\u5316\u6548\u7387\u3002\u7531\u6b64\u53ef\u77e5\uff0c\u8981\u83b7\u5f97\u9ad8\u7684PCE\uff0c\u5c31\u8981\u8c03\u63a7\u597dV<\/em>OC<\/sub>\u3001J<\/em>SC<\/sub>\u3001FF\u7684\u503c\u3002\u6750\u6599\u7684\u7c7b\u578b\u548c\u7eaf\u5ea6\u3001\u5668\u4ef6\u7ed3\u6784\u53ca\u5236\u5907\u65b9\u6cd5\u5747\u53ef\u80fd\u5f71\u54cd\u7535\u6c60\u7684PCE\u3002<\/p>\n

5\uff09\u5916\u91cf\u5b50\u6548\u7387\uff0cEQE<\/strong><\/p>\n

EQE\u662f\u6307\u5bf9\u7279\u5b9a\u6ce2\u957f\u7535\u6c60\u6536\u96c6\u7535\u5b50\u6570\u548c\u5668\u4ef6\u6240\u5438\u6536\u5149\u5b50\u6570\u7684\u6bd4\u503c\uff1a<\/p>\n

EQE=1240\u00d7J<\/em>SC<\/sub>\/(\u03bb<\/em>\u00d7Pin<\/sub>)\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 \uff08\u5f0f1-3\uff09<\/p>\n

\u8981\u53d6\u5f97\u9ad8\u7684PCE\uff0c\u9ad8\u7684EQE\u662f\u5fc5\u8981\u6761\u4ef6\u3002EQE\u53ef\u4ee5\u53cd\u6620\u5bf9\u4e0d\u540c\u6ce2\u957f\u5355\u8272\u5149\u7684\u5438\u6536\u6548\u5e94\u3002\u6539\u5584\u7ed9\u4f53\u6750\u6599\u5bf9\u592a\u9633\u5149\u8c31\u7684\u5438\u6536\u6027\u80fd\u3001\u63d0\u9ad8\u8f7d\u6d41\u5b50\u7684\u6536\u96c6\u6548\u7387\u3001\u589e\u5f3a\u6fc0\u5b50\u7684\u6269\u6563\u80fd\u529b\u5747\u6709\u5229\u4e8eEQE\u7684\u63d0\u9ad8\u3002<\/p>\n

\u4e8c\u3001\u8868\u5f81\u592a\u9633\u80fd\u7535\u6c60\u6750\u6599\u624b\u6bb5<\/strong><\/p>\n

\"2\" \"3\" \"4\"<\/p>\n

\u4ee5\u6587\u4e2d\u6750\u6599\uff08\u89c1\u6587\u540e\u53c2\u8003\u6587\u732e\uff09P1\u3001P2\u3001 P3\u4e3a\u4f8b\uff0c\u8bf4\u660e\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u7684\u8868\u5f81\u65b9\u6cd5\u3002<\/p>\n

1<\/strong>\u3001\u805a\u5408\u7269\uff08<\/strong>P1-P3<\/strong>\uff09\u7684\u70ed\u5b66\u6027\u80fd<\/strong><\/p>\n

\u805a\u5408\u7269\u7684\u70ed\u5b66\u6027\u80fd\u901a\u8fc7TGA\u66f2\u7ebf\u8fdb\u884c\u8868\u5f81\uff0c\u53c2\u89c1\u56fe2-3\u6240\u793a\u3002\u805a\u5408\u7269P1\u3001P2\u548cP3\u51fa\u73b05%\u5931\u91cd\u7684\u6e29\u5ea6\u5206\u522b\u4e3a334 \u00b0C\u3001337 \u00b0C\u548c336 \u00b0C\uff0c\u805a\u5408\u7269\u6709\u826f\u597d\u7684\u70ed\u7a33\u5b9a\u6027\uff0c\u4fdd\u8bc1\u4e86\u592a\u9633\u80fd\u7535\u6c60\u5668\u4ef6\u7684\u4f7f\u7528\u5bff\u547d\u3002<\/p>\n

<\/a><\/p>\n

\u56fe2-3\u805a\u5408\u7269\uff08P1-P3\uff09\u5728\u5347\u6e29\u901f\u7387\u4e3a10 \u00b0C min-1<\/sup>\u3001\u6c2e\u6c14\u6761\u4ef6\u4e0b\u7684TGA\u66f2\u7ebf<\/p>\n

2<\/strong>\u3001\u805a\u5408\u7269\uff08<\/strong>P1-P3<\/strong>\uff09\u7684\u5149\u5b66\u6027\u80fd<\/strong><\/p>\n

\u56fe2-4\u663e\u793a\u4e86\u805a\u5408\u7269\uff08P1-P3\uff09\u5728\u6c2f\u4eff\u6eb6\u6db2\u548c\u65cb\u6d82\u8584\u819c\u7684\u5438\u6536\u5149\u8c31\u56fe\uff0c\u76f8\u5e94\u6570\u636e\u53c2\u89c1\u88682-2\u3002\u4e09\u4e2a\u805a\u5408\u7269\u5728550~620 nm\u8303\u56f4\u4e2d\u663e\u793a\u4e86\u4e24\u4e2a\u5438\u6536\u5cf0\u3002<\/p>\n

\"6\"<\/p>\n

\u56fe2-4\u805a\u5408\u7269\uff08P1-P3\uff09\u5728\u4e09\u6c2f\u6eb6\u6db2\uff08a\uff09\u53ca\u56fa\u6001\u8584\u819c\uff08b\uff09\u72b6\u6001\u4e0b\u7684\u7d2b\u5916-\u53ef\u89c1\uff08UV-vis\uff09\u5438\u6536\u5149\u8c31<\/p>\n

\u88682-2\u805a\u5408\u7269\uff08P1-P3\uff09\u7684\u5149\u5b66\u6027\u80fd\u548c\u7535\u5b50\u80fd\u7ea7<\/p>\n\n\n\n\n\n\n\n
polymer<\/td>\n\u03bb<\/em>max<\/sub>a<\/sup><\/p>\n

(nm)<\/td>\n

\u03bb<\/em>max<\/sub>b<\/sup><\/p>\n

(nm)<\/td>\n

\u03bb<\/em>onset<\/sub>b<\/sup><\/p>\n

(nm)<\/td>\n

E<\/em>g<\/sub>opt c<\/sup><\/p>\n

(eV)<\/td>\n

E<\/em>ox<\/sub><\/p>\n

(V)<\/td>\n

E<\/em>HOMO<\/sub>d<\/sup><\/p>\n

(eV)<\/td>\n

E<\/em>LUMO<\/sub>e<\/sup><\/p>\n

(eV)<\/td>\n<\/tr>\n

P1<\/td>\n624<\/td>\n633<\/td>\n694<\/td>\n1.79<\/td>\n1.01<\/td>\n-5.43<\/td>\n-3.64<\/td>\n<\/tr>\n
P2<\/td>\n606<\/td>\n624<\/td>\n684<\/td>\n1.81<\/td>\n1.10<\/td>\n-5.52<\/td>\n-3.71<\/td>\n<\/tr>\n
P3<\/td>\n622<\/td>\n628<\/td>\n698<\/td>\n1.78<\/td>\n0.93<\/td>\n-5.35<\/td>\n-3.57<\/td>\n<\/tr>\n
P4<\/td>\n625<\/td>\n625<\/td>\n670<\/td>\n1.85<\/td>\n0.60<\/td>\n-5.31<\/td>\n-3.56<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u6839\u636e\u5149\u5b66\u5e26\u9699\u7684\u8ba1\u7b97\u516c\u5f0f\u8ba1\u7b97\u5f97\u5230\u805a\u5408\u7269P1\u3001P2\u548cP3\u7684\u5149\u5b66\u5e26\u9699\uff08E<\/em>g<\/sub>opt<\/sup>\uff09\u5206\u522b\u4e3a1.79 eV\u30011.81 eV\u548c1.78 eV\u3002\u4ece\u88682-2\u4e2d\u53ef\u4ee5\u770b\u51fa\uff0c\u6ca1\u6709\u5171\u8f6d\u4fa7\u94fe\u7684\u805a\u5408\u7269P1\u3001\u6709\u7740\u534a\u5171\u8f6d\u4fa7\u94fe\u7684\u805a\u5408\u7269P2\u548cP3\u3001\u5171\u8f6d\u4fa7\u94fe\u805a\u5408\u7269P4\u6709\u7740\u76f8\u4f3c\u7684\u5149\u5b66\u6027\u80fd\u3002<\/p>\n

3<\/strong>\u3001\u805a\u5408\u7269\uff08<\/strong>P1-P3<\/strong>\uff09\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n

\u7528CV\u66f2\u7ebf\u7814\u7a76\u805a\u5408\u7269\u6216\u6709\u673a\u5c0f\u5206\u5b50\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u4ee5\u83b7\u5f97\u805a\u5408\u7269\u6216\u6709\u673a\u5c0f\u5206\u5b50\u7684HOMO\u4e0eLUMO\u7684\u80fd\u7ea7\u503c\u3002\u4f7f\u7528\u6807\u51c6\u7684\u4e09\u7535\u6781\u8fdb\u884c\u6d4b\u8bd5\uff08\u5de5\u4f5c\u7535\u6781\uff1a\u6d82\u6709\u805a\u5408\u7269\u6216\u6709\u673a\u5c0f\u5206\u5b50\u8584\u819c\u7684\u73bb\u78b3\u7535\u6781\uff1b\u5bf9\u7535\u6781\uff1a\u94c2\u4e1d\uff1b\u53c2\u6bd4\u7535\u6781\uff1aAg\/AgCl\u7535\u6781\uff1b\u7535\u89e3\u6db2\uff1a0.1 mol\/L Bu4<\/sub>NPF6<\/sub>\/CH3<\/sub>CN\uff09\u3002\u5728\u5ba4\u6e29\u3001\u6c2e\u6c14\u6c14\u6c1b\u300150 mv\/s\u6761\u4ef6\u4e0b\u5f97\u5230\u6240\u6d4b\u7269\u8d28\u7684CV\u66f2\u7ebf\uff08\u56fe2-5\uff09<\/p>\n

<\/a><\/p>\n

\u56fe2-5\u805a\u5408\u7269\uff08P1-P3\uff09\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\u56fe<\/p>\n

\u5982\u56fe2-5\u6240\u793a\uff0c\u805a\u5408\u7269\uff08P1\u3001P2\u3001P3\uff09\u7684\u8d77\u59cb\u6c27\u5316\u7535\u4f4d\u5206\u522b\u4e3a1.01 V\u30011.10 V\u30010.93 V\uff0c\u5bf9\u5e94\u7684HOMO\u80fd\u7ea7\u4e3a-5.43 eV\u3001-5.52 eV\u3001-5.35 eV\uff0c\u4e09\u4e2a\u805a\u5408\u7269\uff08P1\u3001P2\u3001P3\uff09\u90fd\u5c55\u793a\u4e86\u76f8\u5bf9\u8f83\u4f4e\u7684HOMO\u80fd\u7ea7\u3002<\/p>\n

4<\/strong>\u3001\u805a\u5408\u7269\uff08<\/strong>P1-P3<\/strong>\uff09\u7684\u5149\u4f0f\u6027\u80fd<\/strong><\/p>\n

\u4e3a\u7814\u7a76\u805a\u5408\u7269\uff08P1\u3001P2\u3001P3\uff09\u7684\u5149\u4f0f\u6027\u80fd\uff0c\u7528\u65b0\u5408\u6210\u7684\u805a\u5408\u7269\uff08P1\u3001P2\u3001P3\uff09\u4f5c\u4e3aD\uff0c\u5bcc\u52d2\u70ef\u884d\u751f\u7269PC61<\/sub>BM\u4f5c\u4e3aA\uff0c\u6309\u7167\u4e0d\u540c\u7684\u6bd4\u4f8b\u5171\u6df7\u4f5c\u4e3a\u6d3b\u6027\u5c42\u5236\u6210\u4f53\u5f02\u8d28\u7ed3\u592a\u9633\u80fd\u7535\u6c60\u3002PC61<\/sub>BM\u88ab\u7528\u5728\u592a\u9633\u80fd\u7535\u6c60\u5668\u4ef6\u7684\u6d3b\u6027\u5c42\u4e2d\u4ee5\u5f62\u6210D-A\u7c7b\u578b\u7684\u4f53\u5f02\u8d28\u7ed3\u7ed3\u6784\uff0c\u6709\u5229\u4e8e\u7535\u8377\u5728D-A\u754c\u9762\u7684\u8f6c\u79fb\uff0c\u8fdb\u800c\u52a0\u5f3a\u5176\u5149\u4f0f\u6027\u80fd\u3002\u56fe2-6\u4e3a\u805a\u5408\u7269\u4e0ePC61<\/sub>BM\u5728\u6700\u4f18\u6bd4\u4e3a1:1\u7684\u6761\u4ef6\u4e0b\u7684J-V<\/em>\u66f2\u7ebf\u56fe\uff0c\u76f8\u5bf9\u5e94\u7684\u6570\u636e\u53c2\u89c1\u88682-3\u3002<\/p>\n

\u88682-3\u57fa\u4e8e\u805a\u5408\u7269\uff08P1-P3\uff09\u548cPC61<\/sub>BM\u6df7\u5408\u819c\u7684\u592a\u9633\u80fd\u7535\u6c60\u7684\u5149\u4f0f\u6027\u80fd<\/p>\n\n\n\n\n\n\n\n\n\n\n
Polymer<\/td>\nthermal<\/p>\n

annealing<\/td>\n

<\/td>\n<\/td>\n<\/td>\nPCE (%)<\/td>\n<\/tr>\n
V<\/em>OC <\/sub>(V)<\/td>\nJ<\/em>SC<\/sub> (mA\/cm2<\/sup>)<\/td>\nFF (%)<\/td>\nav<\/td>\nmax<\/td>\n<\/tr>\n
P1<\/td>\nN<\/td>\n0.93<\/td>\n7.31<\/td>\n60.60<\/td>\n3.99\u00b10.14<\/td>\n4.13<\/td>\n<\/tr>\n
<\/td>\nY<\/td>\n0.95<\/td>\n6.28<\/td>\n56.42<\/td>\n3.24\u00b10.11<\/td>\n3.35<\/td>\n<\/tr>\n
P2<\/td>\nN<\/td>\n0.96<\/td>\n3.82<\/td>\n55.51<\/td>\n1.95\u00b10.08<\/td>\n2.03<\/td>\n<\/tr>\n
<\/td>\nY<\/td>\n0.99<\/td>\n3.46<\/td>\n57.25<\/td>\n1.88\u00b10.07<\/td>\n1.95<\/td>\n<\/tr>\n
P3<\/td>\nN<\/td>\n0.92<\/td>\n4.92<\/td>\n44.41<\/td>\n1.91\u00b10.10<\/td>\n2.01<\/td>\n<\/tr>\n
<\/td>\nY<\/td>\n0.96<\/td>\n4.52<\/td>\n47.53<\/td>\n2.00\u00b10.06<\/td>\n2.06<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\"8\"<\/p>\n

\u56fe2-6\u9000\u706b\u524d\uff08a\uff09\u548c100 \u00b0C\u9000\u706b\u540e\uff08b\uff09\u5728\u805a\u5408\u7269\u548cPC61<\/sub>BM\u7684\u6bd4\u4f8b\u4e3a1:1\u6761\u4ef6\u4e0b\u7684J-V<\/em>\u66f2\u7ebf<\/p>\n

\u901a\u8fc7\u6d4b\u8bd5\u5728\u6700\u4f18\u6761\u4ef6\u4e0b\uff08\u805a\u5408\u7269\uff1aPC61<\/sub>BM=1:1\uff0cP3\u9000\u706b\u5904\u7406\uff09\u7684\u7535\u6c60\u5668\u4ef6\u7684EQE\u66f2\u7ebf\u6765\u786e\u5b9a\u805a\u5408\u7269\uff08P1\u3001P2\u3001P3\uff09J<\/em>SC<\/sub>\u7684\u51c6\u786e\u6027\uff0c\u8be6\u89c1\u56fe2-7\u3002\u4ece\u56fe\u4e2d\u5f97\u77e5\u57fa\u4e8e\u805a\u5408\u7269\uff08P1\u3001P2\u3001P3\uff09\u7684\u7535\u6c60\u5668\u4ef6\u5728300\u5230700 nm\u4e4b\u95f4\u90fd\u8868\u73b0\u51fa\u4e86\u5149\u54cd\u5e94\u3002\u901a\u8fc7EQE\u66f2\u7ebf\uff0c\u8ba1\u7b97\u51fa\u7535\u6c60\u5668\u4ef6\u7684J<\/em>SC<\/sub>\uff08P1: 7.16 mA\/cm2<\/sup>\uff0cP2: 3.72 mA\/cm2<\/sup>\uff0cP3: 4.47 mA\/cm2<\/sup>\uff09\uff0c\u4e0eJ<\/em>–V<\/em>\u66f2\u7ebf\u83b7\u5f97\u7684J<\/em>SC<\/sub>\uff08P1: 7.31 mA\/cm2<\/sup>\uff0cP2: 3.82 mA\/cm2<\/sup>\uff0cP3: 4.52 mA\/cm2<\/sup>\uff09\u57fa\u672c\u4e00\u81f4\uff0c\u4ece\u800c\u4fdd\u8bc1\u4e86\u6d4b\u91cf\u7684\u6709\u6548\u6027\u3002<\/p>\n

<\/a><\/p>\n

\u56fe2-7\u5728\u6700\u4f18\u6761\u4ef6\u4e0b\u76f8\u5e94\u5668\u4ef6\u7684\u5916\u91cf\u5b50\u6548\u7387\u66f2\u7ebf<\/p>\n

5<\/strong>\u3001\u6750\u6599\u7684\u7a7a\u7a74\u8fc1\u79fb\u7387<\/strong><\/p>\n

\u4e3a\u4e86\u8fdb\u4e00\u6b65\u7814\u7a76\u57fa\u4e8e\u5782\u60ac\u567b\u5429\u4fa7\u94fe\u7684\u805a\u5408\u7269\u5728\u5149\u4f0f\u6027\u80fd\u4e0a\u7684\u5dee\u5f02\uff0c\u901a\u8fc7\u7a7a\u95f4\u9650\u5236\u7535\u6d41\u7684\u65b9\u6cd5\uff08SCLC\uff09\u6d4b\u8bd5\u76f8\u5e94\u5668\u4ef6\u7684\u7a7a\u7a74\u8fc1\u79fb\u7387\u3002\u6d4b\u8bd5\u7ed3\u679c\u8be6\u89c1\u56fe2-8\u3002<\/p>\n

<\/a><\/p>\n

\u8f83\u9ad8\u7684\u7a7a\u7a74\u8fc1\u79fb\u7387\u6709\u5229\u4e8e\u7a7a\u7a74\u5728\u6d3b\u6027\u5c42\u4e2d\u7684\u4f20\u8f93\uff0c\u80fd\u591f\u6709\u6548\u5730\u63d0\u9ad8\u592a\u9633\u80fd\u7535\u6c60\u7684J<\/em>SC<\/sub>\u548cFF\u503c\u3002<\/p>\n

6<\/strong>\u3001\u805a\u5408\u7269\uff08<\/strong>P1-P3<\/strong>\uff09\u7684\u5f62\u8c8c\u7814\u7a76<\/strong><\/p>\n

\u7528AFM\u8c03\u67e5\u805a\u5408\u7269\/PC61<\/sub>BM\u6df7\u5408\u8584\u819c\u7684\u5f62\u8c8c\uff0c\u8fdb\u4e00\u6b65\u4e86\u89e3\u805a\u5408\u7269\uff08P1-P3\uff09\u7535\u6c60\u5668\u4ef6\u6027\u80fd\u4e4b\u95f4\u7684\u5dee\u5f02\u3002<\/p>\n

\"11\"<\/p>\n

\u56fe2-9\u805a\u5408\u7269\uff08P1-P3\uff09\u5728\u6700\u4f18\u6761\u4ef6\u4e0b\u7684\u539f\u5b50\u529b\u663e\u5fae\u955c\u5f62\u8c8c(ace)\u53ca\u76f8\u5206\u79bb(bdf)\u56fe\u50cf\uff0c\u56fe\u50cf\u5c3a\u5bf84\u00d74\u5fae\u7c73<\/p>\n

\u4e09\u3001\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u9762\u4e34\u7684\u673a\u9047\u4e0e\u6311\u6218<\/strong><\/p>\n

\u673a\u9047<\/strong><\/span><\/p>\n

\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u5177\u6709\u5982\u4e0b\u4f18\u70b9\uff1a<\/p>\n

\uff081\uff09\u5316\u5b66\u53ef\u53d8\u6027\u5927\uff0c\u539f\u6599\u6765\u6e90\u5e7f\u6cdb\uff1b<\/p>\n

\uff082\uff09\u6709\u591a\u79cd\u9014\u5f84\u53ef\u6539\u53d8\u548c\u63d0\u9ad8\u6750\u6599\u5149\u8c31\u5438\u6536\u80fd\u529b\uff0c\u6269\u5c55\u5149\u8c31\u5438\u6536\u8303\u56f4\uff0c\u5e76\u63d0\u9ad8\u8f7d\u6d41\u5b50\u7684\u4f20 \u9001\u80fd\u529b\uff1b<\/p>\n

\uff083\uff09\u52a0\u5de5\u5bb9\u6613\uff0c\u53ef\u91c7\u7528\u65cb\u8f6c\u6cd5\u3001\u6d41\u5ef6\u6cd5\u5927\u9762\u79ef\u6210\u819c\uff0c\u8fd8\u53ef\u8fdb\u884c\u62c9\u4f38\u53d6\u5411\u4f7f\u6781\u6027\u5206\u5b50\u89c4\u6574\u6392 \u5217\uff0c\u91c7\u7528LB\u819c\u6280\u672f\u5728\u5206\u5b50\u751f\u957f\u65b9\u5411\u63a7\u5236\u819c\u7684\u539a\u5ea6\uff1b<\/p>\n

\uff084\uff09\u5bb9\u6613\u8fdb\u884c\u7269\u7406\u6539\u6027\uff0c\u5982\u91c7\u7528\u9ad8\u80fd\u79bb\u5b50\u6ce8\u5165\u63ba\u6742\u6216\u8f90\u7167\u5904\u7406\u53ef\u63d0\u9ad8\u8f7d\u6d41\u5b50\u7684\u4f20\u5bfc\u80fd\u529b\uff0c \u51cf\u5c0f\u7535\u963b\u635f\u8017\u63d0\u9ad8\u77ed\u8def\u7535\u6d41\uff1b<\/p>\n

\uff085\uff09\u7535\u6c60\u5236\u4f5c\u7684\u7ed3\u6784\u591a\u6837\u5316\uff1b<\/p>\n

\uff086\uff09\u4ef7\u683c\u4fbf\u5b9c\u3002\u6709\u673a\u9ad8\u5206\u5b50\u534a\u5bfc\u4f53\u6750\u6599\u7684\u5408\u6210\u5de5\u827a\u6bd4\u8f83\u7b80\u5355\uff0c\u5982\u915e\u83c1\u7c7b\u67d3\u6599\u65e9\u5df2\u5b9e\u73b0\u5de5\u4e1a \u5316\u751f\u4ea7\uff0c\u56e0\u800c\u6210\u672c\u4f4e\u5ec9\u3002\u8fd9\u662f\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u5b9e\u7528\u5316\u6700\u5177\u6709\u7ade\u4e89\u80fd\u529b\u7684\u56e0\u7d20\u3002<\/p>\n

\uff087\uff09\u53ef\u964d\u89e3\uff0c\u5bf9\u73af\u5883\u7684\u6c61\u67d3\u5c0f\u3002<\/p>\n

\u6311\u6218<\/strong><\/span><\/p>\n

\u7136\u800c\u4e0e\u65e0\u673a\u7845\u592a\u9633\u80fd\u7535\u6c60\u76f8\u6bd4\uff0c\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u5728\u8f6c\u6362\u6548\u7387\u3001\u5149\u8c31\u54cd\u5e94\u8303\u56f4\u3001\u7535\u6c60\u7684\u7a33\u5b9a\u6027\u65b9\u9762\uff0c\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u8fd8\u6709\u5f85\u63d0\u9ad8\u3002\u5404\u79cd\u7814\u7a76\u8868\u660e\uff0c\u51b3\u5b9a\u5149\u7535\u6548\u7387\u7684\u57fa\u672c\u635f\u5931\u673a\u5236\u4e3b\u8981\u6709\uff1a<\/p>\n

1.\u534a\u5bfc\u4f53\u8868\u9762\u548c\u524d\u7535\u6781\u7684\u5149\u53cd\u5c04\uff1b<\/p>\n

2.\u7981\u5e26\u8d8a\u5bbd\u6ca1\u6709\u5438\u6536\u7684\u5149\u4f20\u64ad\u8d8a\u5927\uff1b<\/p>\n

3.\u7531\u9ad8\u80fd\u5149\u5b50\u5728\u5bfc\u5e26\u548c\u4ef7\u5e26\u4e2d\u4ea7\u751f\u7684\u7535\u5b50\u548c\u7a7a\u7a74\u7684\u80fd\u91cf\u9a71\u6563\uff1b<\/p>\n

4.\u5149\u7535\u5b50\u548c\u5149\u7a7a\u7a74\u5728\u5149\u7535\u6c60\u7684\u5149\u7167\u9762\u548c\u4f53\u5185\u7684\u590d\u5408\uff1b<\/p>\n

5.\u6709\u673a\u67d3\u6599\u7684\u9ad8\u7535\u963b\u548c\u4f4e\u7684\u8f7d\u6d41\u5b50\u8fc1\u79fb\u7387\u3002<\/p>\n

\u7efc\u5408\u6765\u770b\uff0c\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u4f9d\u65e7\u9762\u4e34\u7740\u5149\u7535\u8f6c\u5316\u6548\u7387\u4f4e\uff0c\u6210\u672c\u8f83\u9ad8\uff0c\u96be\u4ee5\u5927\u9762\u79ef\u5e94\u7528\u751f\u4ea7\u7b49\u96be\u9898\uff0c\u4e9f\u5f85\u79d1\u7814\u4eba\u5458\u7ee7\u7eed\u52aa\u529b\u63a2\u7d22\u53d1\u73b0\uff01<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u5e72\u8d27\u7ec4 \u5927\u5b8b \u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u53c2\u8003\u6587\u732e\uff1a<\/p>\n

“Novel pendent thiophene side\u2010chained benzodithiophene for polymer solar cells.” Journal of Polymer Science Part A: Polymer Chemistry<\/i> 53.13 (2015): 1558-1566.<\/p>\n

\u6b22\u8fce\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41 422065952<\/a>\u201d\uff0c\u4f18\u79c0\u7855\u535a\u4eec\uff0c\u4e00\u8d77\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u5e72\u8d27\u7ec4\u5427\uff0c\u4f20\u64ad\u77e5\u8bc6\uff0c\u5c55\u73b0\u624d\u534e\uff0c \u52a9\u529b\u6750\u6599\u79d1\u7814\uff0c\u79c1\u4fe1\u8d1f\u8d23\u4eba\u201c\u6de1\u5e74\u534e\uff08 QQ:601416321\uff09 \u201d\u62a5\u540d\uff01<\/p>\n

\u6b22\u8fce\u5404\u5927\u8bfe\u9898\u7ec4\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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