{"id":22112,"date":"2016-06-25T18:44:48","date_gmt":"2016-06-25T10:44:48","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=22112"},"modified":"2017-03-04T22:53:56","modified_gmt":"2017-03-04T14:53:56","slug":"chemistry-of-materials%e6%96%87%e7%8c%ae%e6%8e%a8%e8%8d%90-%e7%94%b1%e7%ba%b3%e7%b1%b3%e6%99%b6%e4%bd%93%e7%94%9f%e9%95%bf%e8%80%8c%e6%88%90%e7%9a%84%e7%b4%a7%e5%af%86%e7%bb%93","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=22112","title":{"rendered":"Chemistry of Materials\u6587\u732e\u63a8\u8350\u2014\u2014\u7531\u7eb3\u7c73\u6676\u4f53\u751f\u957f\u800c\u6210\u7684\u7d27\u5bc6\u7ed3\u5408\u9ad8\u500d\u7387Li4Ti5O12\u8d1f\u6781\u6750\u6599  (\u6e05\u534e\u2022\u6df1\u5733)"},"content":{"rendered":"<p>\u9502\u79bb\u5b50\u7535\u6c60\u7684\u5546\u54c1\u5316\u9769\u65b0\u4e86\u7535\u5b50\u6d88\u8d39\u4ea7\u54c1\u7684\u9762\u8c8c\uff0c\u7531\u4e8e\u9502\u79bb\u5b50\u7535\u6c60\u4f7f\u7528\u5bff\u547d\u957f\uff0c\u5b89\u5168\u6027\u80fd\u9ad8\uff0c\u53ef\u4ee5\u5feb\u901f\u5145\u653e\u7535\u7b49\u4f18\u70b9\uff0c\u4ece\u6b64\u5728\u4e16\u754c\u8303\u56f4\u5185\u6380\u8d77\u4e86\u9502\u79bb\u5b50\u7535\u6c60\u7684\u7814\u7a76\u70ed\u6f6e\uff0c\u63a8\u52a8\u4e86\u9502\u79bb\u5b50\u7535\u6c60\u5de5\u4e1a\u7684\u8fc5\u731b\u53d1\u5c55\u3002\u53ef\u662f\u76ee\u524d\u7684\u5546\u7528\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599\u4e3a\u77f3\u58a8\u6750\u6599\uff0c\u5b83\u7684\u5e94\u7528\u5b58\u5728\u4e00\u5b9a\u7684\u74f6\u9888\uff0c\u5b89\u5168\u6027\u5dee\u3001\u5145\u7535\u901f\u5ea6\u6162\u3001\u5faa\u73af\u5bff\u547d\u77ed\u7b49\u56e0\u7d20\u5236\u7ea6\u7740\u5b83\u7684\u53d1\u5c55\uff0c\u56e0\u6b64\uff0c\u9700\u8981\u5f00\u53d1\u66f4\u5b89\u5168\u3001\u5bff\u547d\u66f4\u957f\u7684\u3001\u53ef\u5feb\u901f\u5145\u7535\u7684\u8d1f\u6781\u6750\u6599\u3002<\/p>\n<p>\u5728\u6240\u6709\u7684\u5907\u9009\u8d1f\u6781\u6750\u6599\u4e2d\uff0c\u949b\u9178\u9502\u6750\u6599\u662f\u4e00\u4e2a\u4e0d\u9519\u7684\u9009\u62e9\u3002\u4f5c\u4e3a\u201c\u96f6\u5e94\u53d8\u201d\u6750\u6599\uff0c\u5c16\u6676\u77f3\u578b\u7684\u949b\u9178\u9502\u5177\u6709\u5f88\u591a\u4f18\u70b9\uff1a\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u4f53\u79ef\u51e0\u4e4e\u4e0d\u53d1\u751f\u53d8\u5316\uff0c\u5177\u6709\u4f18\u5f02\u7684\u5faa\u73af\u6027\u80fd\uff1b\u79bb\u5b50\u6269\u6563\u901f\u7387\u8f83\u9ad8\uff0c\u6bd4\u78b3\u8d1f\u6781\u9ad8\u4e00\u4e2a\u6570\u91cf\u7ea7\uff0c\u53ef\u4ee5\u5feb\u901f\u5145\u7535\uff1b\u8f83\u9ad8\u7684\u5145\u653e\u7535\u5e73\u53f0\uff08~1.55V\uff09\u53ef\u4ee5\u907f\u514d\u7535\u89e3\u6db2\u7684\u5206\u89e3\uff0c\u7535\u6c60\u5b89\u5168\u6027\u80fd\u597d\u3002\u56e0\u6b64\uff0c\u4f5c\u4e3a\u8d1f\u6781\u6750\u6599\u7684\u949b\u9178\u9502\u80fd\u591f\u5927\u5e45\u5ea6\u63d0\u9ad8\u9502\u79bb\u5b50\u7535\u6c60\u7684\u5b89\u5168\u6027\u3001\u5feb\u5145\u6027\u80fd\u548c\u4f7f\u7528\u5bff\u547d\uff0c\u5e76\u9010\u6e10\u6210\u4e3a\u5f53\u4eca\u793e\u4f1a\u7684\u7814\u7a76\u70ed\u70b9\u3002<\/p>\n<p>\u4f46\u662f\u949b\u9178\u9502\u6750\u6599\u7684\u672c\u5f81\u7535\u5b50\u7535\u5bfc\u7387\u4f4e\uff0c\u4e3a\u4e86\u63d0\u9ad8\u6750\u6599\u7684\u500d\u7387\u6027\u80fd\uff0c\u56fd\u5185\u5916\u5408\u6210\u4e86\u8bb8\u591a\u7eb3\u7c73\u7247\uff0c\u7eb3\u7c73\u68d2\u7b49\u6750\u6599\uff0c\u8fd9\u7c7b\u6750\u6599\u6bd4\u8868\u9762\u79ef\u5927\uff0c\u80fd\u591f\u589e\u5927\u6750\u6599\u4e0e\u7535\u89e3\u6db2\u7684\u63a5\u89e6\u9762\u79ef\uff0c\u7f29\u77ed\u9502\u79bb\u5b50\u6269\u6563\u8def\u5f84\uff0c\u4f7f\u5176\u500d\u7387\u6027\u80fd\u4f18\u5f02\u3002\u4f46\u662f\u5b83\u7684\u632f\u5b9e\u5bc6\u5ea6\u4f4e\uff0c\u5c06\u5bfc\u81f4\u7535\u6c60\u7684\u4f53\u79ef\u80fd\u91cf\u5bc6\u5ea6\u4f4e\u3002<\/p>\n<p>\u4e3a\u6b64\uff0c\u5408\u6210\u7531\u7eb3\u7c73\u4e00\u6b21\u5fae\u6676\u7ec4\u6210\u5fae\u7c73\u4e8c\u6b21\u9897\u7c92\u6210\u4e3a\u4e86\u7814\u7a76\u70ed\u70b9\uff0c\u56e0\u4e3a\u8fd9\u79cd\u6750\u6599\u65e2\u5177\u7eb3\u7c73\u7ea7\u4e00\u6b21\u9897\u7c92\u8f83\u597d\u7684\u500d\u7387\u6027\u80fd\uff0c\u53c8\u5177\u6709\u5fae\u7c73\u7ea7\u9897\u7c92\u8f83\u9ad8\u7684\u4f53\u79ef\u80fd\u91cf\u5bc6\u5ea6\u548c\u7a33\u5b9a\u6027\u3002<\/p>\n<p>\u4f46\u662f\uff0c\u76ee\u524d\u7531\u4e00\u6b21\u9897\u7c92\u7ec4\u6210\u7684\u5fae\u7c73\u4e8c\u6b21\u9897\u7c92\u7684\u949b\u9178\u9502\u6750\u6599\u7814\u7a76\u76f8\u5bf9\u8f83\u5c11\uff0c\u5408\u6210\u65b9\u6cd5\u591a\u91c7\u7528\u6c34\u70ed\/\u6eb6\u5242\u70ed\u6216\u55b7\u96fe\u5e72\u71e5\u6cd5\uff0c\u80fd\u8017\u9ad8;\u800c\u4e14\u6240\u5408\u6210\u51fa\u7684\u949b\u9178\u9502\u4e8c\u6b21\u9897\u7c92\u7684\u5747\u4e00\u6027\u3001\u5355\u5206\u6563\u6027\u4ee5\u53ca\u4e00\u6b21\u9897\u7c92\u6392\u5217\u7684\u81f4\u5bc6\u5ea6\u5747\u4e0d\u662f\u7279\u522b\u7406\u60f3\uff1b\u53cd\u5e94\u591a\u91c7\u7528\u4e24\u6b65\u6cd5\uff0c\u5373\u5148\u5408\u6210\u7eb3\u7c73\u7ea7\u9897\u7c92\u518d\u7ec4\u88c5\u6210\u5fae\u7c73\u7ea7\u9897\u7c92\uff0c\u53cd\u5e94\u6761\u4ef6\u8f83\u4e3a\u590d\u6742\u3002<\/p>\n<p><span style=\"color: #800080;\"><strong>\u6e05\u534e\u5927\u5b66\u535a\u58eb\u751f\u5bfc\u5e08\u8d3a\u8273\u5175<\/strong><\/span>\u4ecb\u7ecd\uff0c\u201c\u4e3a\u4e86\u89e3\u51b3\u8fd9\u4e2a\u95ee\u9898\uff0c\u6211\u4eec\u5bf9\u5fae\u7c73\u7ea7\u949b\u9178\u9502\u8fdb\u884c\u7ed3\u6784\u4f18\u5316\u8bbe\u8ba1\uff0c\u7814\u7a76\u901a\u8fc7\u4e00\u6b65\u6cd5\u5236\u5907\u51fa\u8be5\u79cd\u6750\u6599\uff0c\u4e14\u65e0\u9700\u6c34\u70ed\/\u6eb6\u5242\u70ed\u6216\u55b7\u96fe\u5e72\u71e5\u8fc7\u7a0b\uff1b\u5bf9\u5408\u6210\u8fc7\u7a0b\u4e2d\u53cd\u5e94\u6761\u4ef6\u8fdb\u884c\u63a7\u5236\uff0c\u5b9e\u73b0\u5bf9\u5176\u5c3a\u5bf8\u3001\u5f62\u8c8c\u548c\u7eb3\u7c73\u5fae\u6676\u6676\u7c92\u5927\u5c0f\u7684\u8c03\u63a7\uff0c\u5e76\u5bf9\u5176\u6676\u4f53\u751f\u957f\u673a\u7406\u8fdb\u884c\u7cfb\u7edf\u7814\u7a76\u3002\u201d<\/p>\n<p><span style=\"color: #800080;\"><strong>\u8bba\u6587\u7b2c\u4e00\u4f5c\u8005\u6e05\u534e\u5927\u5b66\u7814\u7a76\u751f\u738b\u8d85<\/strong><\/span>\u8868\u793a\u201c\u6211\u4eec\u901a\u8fc7\u4e00\u6b65\u6cd5\u81ea\u7ec4\u88c5\u751f\u957f\u4e86\u9ad8\u5bc6\u5ea6\u7eb3-\u5fae\u7d27\u5bc6\u7ed3\u6784\u7403\u5f62\u949b\u9178\u9502\uff0c\u8fd9\u79cd\u7d27\u5bc6\u7eb3-\u5fae\u7403\u5f62\u6750\u6599\u632f\u5b9e\u5bc6\u5ea6\u8fbe\u52301.2 g\/cm<sup>3<\/sup>\uff0c\u4e14\u78b3\u542b\u91cf\u53ea\u6709\u7ea60.4%\uff0c\u540c\u65f6\u5177\u6709\u5f88\u5c0f\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u662f\u53d1\u5c55\u9ad8\u4f53\u79ef\u80fd\u91cf\u5bc6\u5ea6\u4e14\u65e0\u80c0\u6c14\u884c\u4e3a\u949b\u9178\u9502\u7535\u6c60\u7406\u60f3\u7684\u7535\u6781\u6750\u6599\uff1b\u7535\u5316\u5b66\u7814\u7a76\u7ed3\u679c\u8868\u660e\uff0c\u5176\u5177\u6709\u975e\u5e38\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\u548c\u5faa\u73af\u6027\u80fd\uff0c\u4e14\u8f6f\u5305\u88c5\u7535\u6c60\u572830C\/30C\u5145\u653e\u753520000\u6b21\u8fc7\u7a0b\u4e2d\u65e0\u660e\u663e\u5bb9\u91cf\u8870\u51cf\u53ca\u80c0\u6c14\u884c\u4e3a\u3002\u5e76\u9996\u6b21\u53d1\u73b0\u7d27\u5bc6\u7ed3\u6784\u7403\u5f62\u949b\u9178\u9502\u7684\u7eb3\u7c73\u6676\u754c\u53ef\u5f62\u6210\u826f\u597d\u7684\u79bb\u5b50\u548c\u7535\u5b50\u5bfc\u7535\u7f51\u7edc\uff1b\u7814\u7a76\u6210\u679c\u4e3a\u9ad8\u5bc6\u5ea6\u7535\u6c60\u6750\u6599\u7684\u8bbe\u8ba1\u548c\u5236\u5907\u63d0\u4f9b\u4e86\u826f\u597d\u7684\u601d\u8def\u3002\u9ad8\u5bc6\u5ea6\u7eb3-\u5fae\u7d27\u5bc6\u7ed3\u6784\u7403\u5f62\u949b\u9178\u9502\u5177\u6709\u4f18\u5f02\u7684\u4ea7\u4e1a\u5316\u524d\u666f\u3002\u201d<\/p>\n<p><strong>\u56fe\u6587\u89e3\u8bfb<\/strong><\/p>\n<p><a href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/\uff11.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-22125\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/\uff11.png\" alt=\"\uff11\" width=\"740\" height=\"486\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/\uff11.png 740w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/\uff11-300x197.png 300w\" sizes=\"(max-width: 740px) 100vw, 740px\" \/><\/a><\/p>\n<p style=\"text-align: center;\">\u56fe1. \u7403\u5f62LTO\u7684\u5408\u6210\u6d41\u7a0b\u56fe<\/p>\n<p><strong>\u5408\u6210\u65b9\u5f0f\uff1a<\/strong><\/p>\n<p>\uff081\uff09\u5c0616ml\u7684\u949b\u9178\u56db\u4e01\u916f\uff08TBT\uff09\u52a0\u5165\u5230200ml\u7684\u65e0\u6c34\u4e59\u9187\u4e2d\uff0c\u78c1\u529b\u6405\u62cc30min\uff1b<\/p>\n<p>\uff082\uff09\u968f\u540e\u5411\u6df7\u5408\u6db2\u4e2d\u52a0\u51654.03g\u918b\u9178\u9502\uff08LiAc\uff09\u548c2.0g\u5341\u516d\u70f7\u80fa\uff08HDA\uff09\uff0cHDA\u7684\u4f5c\u7528\u662f\u8bf1\u5bfc\u5f62\u6210\u65e0\u5b9a\u578b\u7684TiO<sub>2<\/sub>\/Li<sup>+<\/sup>\u7403\uff1b<\/p>\n<p>\uff083\uff09\u4e3a\u4e86\u6c34\u89e3TBT\uff0c\u5728\u6301\u7eed\u6405\u62cc\u7684\u60c5\u51b5\u4e0b\uff0c\u5411\u6df7\u5408\u6db2\u4e2d\u9010\u6ef4\u52a0\u5165 NH<sub>3<\/sub>\u2219H<sub>2<\/sub>O (25%)5.5ml\uff0c\u6eb6\u6db2\u7531\u900f\u660e\u8272\u53d8\u4e3a\u4e73\u767d\u8272\uff0c\u6b64\u8fc7\u7a0b\u4e2dTBT\u5148\u6c34\u89e3\u4e3aTi(OC<sub>4<\/sub>H<sub>9<\/sub>)<sub>4-x<\/sub>(OH)<sub>x<\/sub>\u968f\u540e\u6c34\u89e3\u4e3aTi(OH)<sub>4<\/sub>\uff1b<\/p>\n<p>\uff084\uff09\u5c06\u6eb6\u6db2\u572880\u2103\u4e0b\u5e72\u71e524\u5c0f\u65f6\uff0c\u83b7\u5f97\u767d\u8272\u7c89\u672b\uff0c\u8fd9\u4e2a\u8fc7\u7a0b\u4e2dTi(OH)<sub>4<\/sub>\u53d8\u4e3a\u7403\u5f62TiO<sub>2<\/sub>\/Li<sup>+<\/sup>\uff0c\uff1b<\/p>\n<p>\uff085\uff09\u5c06\u767d\u8272\u7c89\u672b\u5206\u522b\u5728Ar\u6c14\u6c1b\u4e0b\uff0c600\u3001700\u548c800\u2103\u70e7\u7ed3\uff0c\u83b7\u5f97\u7070\u8272LTO\u7c89\u672b<\/p>\n<p><a href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/\uff12-1.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-large wp-image-22126\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/\uff12-1-687x1024.png\" alt=\"\uff12-1\" width=\"687\" height=\"1024\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/\uff12-1-687x1024.png 687w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/\uff12-1-201x300.png 201w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/\uff12-1.png 740w\" sizes=\"(max-width: 687px) 100vw, 687px\" \/><\/a><\/p>\n<p style=\"text-align: center;\">\u56fe2. \u672a\u70e7\u7ed3\u7684LTO\u548cLTO-700\u3001LTO-800\u4e09\u4e2a\u6837\u54c1\u7684XRD\u56fe\u8c31\u548c\u5438\u9644\u66f2\u7ebf<\/p>\n<p><strong>XRD<\/strong><strong>\u5206\u6790\uff1a<\/strong><\/p>\n<p>LTO-700\u548cLTO-800\u4e0eJCPDS \u5361\u7247 No. 49-0207\u5bf9\u5e94\u826f\u597d\uff0c\u662f\u7a7a\u95f4\u7fa4\u4e3aFd3m\u7684LTO\u3002\u70e7\u7ed3\u6e29\u5ea6\u4e3a800\u2103\u65f6\uff0c\u5cf0\u5f3a\u660e\u663e\u589e\u52a0\u3002\u70e7\u7ed3\u6e29\u5ea6\u4e3a600\u2103\u65f6\u6709\u6742\u5cf0,\u8fd9\u8868\u660e\uff0c\u4e3a\u4e86\u4f7f\u524d\u9a71\u4f53\u5b8c\u5168\u8f6c\u53d8\u4e3aLTO\uff0c\u70e7\u7ed3\u6e29\u5ea6\u5e94\u8be5\u5728700\u2103\u6216\u8005\u66f4\u9ad8\u3002<\/p>\n<p><strong>BET<\/strong><strong>\u5438<\/strong><strong>\\<\/strong><strong>\u8131\u9644\u66f2\u7ebf\u5206\u6790\uff1a<\/strong><\/p>\n<p>\u5f53\u70e7\u7ed3\u6e29\u5ea6\u4ece600\u4e0a\u5347\u5230700\u548c800\u2103\u65f6\uff0c\u8868\u9762\u79ef\u753125.5 m\u00b2 g<sup>-1<\/sup>\u51cf\u5c0f\u52308.6 \u548c 6.2 m\u00b2 g<sup>-1<\/sup>\uff0c\u76f8\u5e94\u7684\u5b54\u4f53\u79ef\u4ece0.076 cm<sup>3<\/sup>g<sup>-1<\/sup>\u4e0b\u964d\u52300.042 \u548c 0.011 cm<sup>3<\/sup>g<sup>-1<\/sup>\u3002\u4e0e\u5176\u4ed6\u5de5\u4f5c\u5bf9LTO\u7403\u7684\u62a5\u9053\u76f8\u6bd4\u8f83\uff0c\u8fd9\u9879\u5de5\u4f5c\u5c06\u8868\u9762\u79ef\u51e0\u4e4e\u964d\u4f4e\u4e86\u4e00\u4e2a\u6570\u91cf\u7ea7\u3002<\/p>\n<p><a href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/3-1-3.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-22127\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/3-1-3.png\" alt=\"3-1\" width=\"740\" height=\"564\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/3-1-3.png 740w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/3-1-3-300x229.png 300w\" sizes=\"(max-width: 740px) 100vw, 740px\" \/><\/a><\/p>\n<p style=\"text-align: center;\">\u56fe3. \u70e7\u7ed3\u524d\u7684SEM(a\uff0cb)\u548cHRTEM\uff08c\uff0cd\uff09\u56fe<\/p>\n<p><strong>\u5f62\u6001\u5206\u6790\uff1a<\/strong><\/p>\n<p>\uff081\uff09\u70e7\u7ed3\u524d\uff0c\u76f4\u5f84\u7ea6\u4e3a400\u2014600nm\uff0c\u5e76\u6709\u4e00\u4e9b\u76f4\u5f84\u4e3a5-20nm\u5de6\u53f3\u7684TiO<sub>2<\/sub>\u9897\u7c92\uff1b<\/p>\n<p>\uff082\uff09TEM\u56fe\u8868\u660e\uff0c\u524d\u9a71\u4f53\u7403\u5e76\u975e\u4e2d\u7a7a\uff0c\u800c\u662f\u5b9e\u5fc3\u7684\u65e0\u5b9a\u5f62\u7ed3\u6784\uff1b<\/p>\n<p><a href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/4-1-1.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-22128\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/4-1-1.png\" alt=\"4-1\" width=\"740\" height=\"555\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/4-1-1.png 740w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/4-1-1-300x225.png 300w\" sizes=\"(max-width: 740px) 100vw, 740px\" \/><\/a><\/p>\n<p style=\"text-align: center;\">\u56fe4. \u5206\u522b\u5728700\u2103\uff08a,b\uff09\u548c800\u2103\uff08c,d\uff09\u4e0b\u70e7\u7ed3\u5f97\u5230\u7684\u7403\u5f62LTO\u7684SEM\u56fe<\/p>\n<p><strong>\u5f62\u6001\u5206\u6790\uff1a<\/strong>\u968f\u7740\u70e7\u7ed3\u6e29\u5ea6\u7684\u5347\u9ad8\uff0cLTO\u7684\u6700\u7ec8\u7c92\u5f84\u4e5f\u663e\u8457\u589e\u5927\u3002\u6839\u636eDebye-Scherrer\u516c\u793a\uff0c\u5f53\u70e7\u7ed3\u6e29\u5ea6\u4ece600\u4e0a\u5347\u5230700\u548c800\u2103\u65f6\uff0c\u5e73\u5747\u76f4\u5f84\u5206\u522b\u589e\u52a036\u300142\u548c55nm\u3002\u6ca1\u6709\u6dfb\u52a0HDA\u7684\u524d\u9a71\u4f53\u70e7\u7ed3\u4e4b\u540e\u7531\u65e0\u89c4\u5219\u7684\u5355\u6676\u9897\u7c92\u7ec4\u6210\uff0c\u8fd9\u8868\u660eHAD\u5728\u5f15\u5bfcLTO\u5f62\u6210\u7403\u5f62\u9897\u7c92\u4e0a\u8d77\u5230\u4e86\u6709\u6548\u4f5c\u7528\u3002<\/p>\n<p><a href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/6-1-1.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-large wp-image-22130\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/6-1-1-684x1024.png\" alt=\"6-1\" width=\"684\" height=\"1024\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/6-1-1-684x1024.png 684w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/6-1-1-200x300.png 200w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/6-1-1.png 740w\" sizes=\"(max-width: 684px) 100vw, 684px\" \/><\/a><\/p>\n<p>\u56fe5. LTO\u7403\u5f62\u9897\u7c92\u5206\u522b\u5728700\u2103\uff08a,b\uff09\u548c800\u2103\uff08c,d\uff09\u65f6\u7684HRTEM\u56fe\u3002e\uff0cf\u5206\u522b\u4e3aLTO-700\u7684\u6676\u754c\uff0c\u5176\u4e2d\uff08f\uff09\u7684\u63d2\u56fe\u4e3a\u5bf9\u5e94\u7684SAED\u56fe\u3002g\uff0ch\u56fe\u4e3aLTO-700\u7684\u9897\u7c92\u5256\u9762SEM\u56fe\u3002<\/p>\n<p><strong>\u5f62\u6001\u5206\u6790\uff1a<\/strong>\uff081\uff09\u4ecea\u548cc\u56fe\uff0c\u53ef\u4ee5\u5f88\u660e\u663e\u7684\u770b\u51fa\uff0cLTO-700\u548cLTO-800\u65e2\u975e\u4e2d\u7a7a\u7ed3\u6784\u4e5f\u975e\u5b54\u72b6\u7ed3\u6784\uff0c\u800c\u662f\u539f\u4f4d\u751f\u957f\u7684\u56fa\u6001\u7ed3\u5408\u4f53\uff1b<\/p>\n<p>\uff082\uff09b\u548cd\u56fe\u4e2d\uff0c\u6676\u683c\u7ed3\u6784\u660e\u663e\uff0c\u955c\u9762\u95f4\u8ddd\u4e3a0.48nm\uff0c\u8fd9\u4e0eLTO\u7684\uff08111\uff09\u9762\u4e00\u81f4\u3002LTO\u7403\u5916\u5c42\u88ab\u4e00\u5c42\u539a\u5ea6\u7ea61nm\u7684\u78b3\u5c42\u5305\u8986\uff0c\u78b3\u6e90\u4e3aHDA\u3002\u7531\u4e8eHDA\u7684\u5c01\u7aef\u5242\u63a7\u5236\u7740TBT\u7684\u6c34\u89e3\u53cd\u5e94\u5e76\u5f15\u5bfcLTO\u524d\u9a71\u4f53\u7684\u81ea\u7ec4\u88c5\uff0c\u56e0\u6b64LTO\u524d\u8eaf\u4f53\u7684\u6d53\u5ea6\u5bf9\u5f62\u6210\u65e0\u5b9a\u578b\u78b3\u5c42\u548cLTO\u7eb3\u7c73\u6676\u4f53\u5f71\u54cd\u5f88\u5927\uff1b<\/p>\n<p>\uff083\uff09e\uff0cf\u56fe\u8868\u660e\uff0cLTO\u7684\u6676\u4f53\u7ed3\u6784\u826f\u597d\uff0c\u800c\u4e14\u6676\u754c\u4e0a\u6ca1\u6709\u78b3\u5c42\uff0c\u78b3\u53ea\u5305\u8986\u5728\u7403\u5f62\u9897\u7c92\u7684\u5916\u5c42<\/p>\n<p>\uff084\uff09g\uff0ch\u7684\u9897\u7c92\u5256\u9762\u56fe\u66f4\u6e05\u6670\u7684\u8bc1\u660e\u4e86\uff0cLTO\u4e3a\u5b9e\u5fc3\u7ed3\u6784\u3002<\/p>\n<p>\u78b3\u5305\u8986\u5c42\u7684\u4f5c\u7528\uff1a\u5176\u5bf9\u7535\u5b50\u7535\u5bfc\u7387\u7684\u589e\u52a0\u5f71\u54cd\u5f88\u5927\uff0cLTO-700\u7684\u7535\u5b50\u7535\u5bfc\u7387\u4e3a3.8\u00d710<sup>\u2212<\/sup><sup>6<\/sup> S cm<sup>\u2212<\/sup><sup>1<\/sup>\uff0c\u8fdc\u8d85\u51faLTO\u7684\u672c\u5f81\u7535\u5bfc\u738710<sup>\u2212<\/sup><sup>13<\/sup> S cm<sup>\u2212<\/sup><sup>1<\/sup>\uff0c\u800c\u7535\u5b50\u7535\u5bfc\u7387\u7684\u589e\u52a0\u5bf9LTO\u7403\u4f53\u8868\u9762\u7535\u8377\u5feb\u901f\u8f6c\u79fb\u8d77\u5230\u51b3\u5b9a\u6027\u4f5c\u7528\u3002<\/p>\n<p><a href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/7-10.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-22131\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/7-10.png\" alt=\"7\" width=\"740\" height=\"855\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/7-10.png 740w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/7-10-260x300.png 260w\" sizes=\"(max-width: 740px) 100vw, 740px\" \/><\/a><\/p>\n<p>\u56fe6. \u5206\u522b\u5728700\u2103\uff08a\uff09\u548c800\u2103\uff08b\uff09\u70e7\u7ed3\u7684LTO\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\uff08c\uff09\u56fe\u4e3a\u4e0d\u540c\u500d\u7387\u4e0b\u7684\u653e\u7535\u5bb9\u91cf\uff1b\uff08d\uff09\u56fe\u4e3a10C\u4e0b\u7684\u5faa\u73af\u6027\u80fd\u56fe\u3002<\/p>\n<p><strong>\u534a\u7535\u6c60\u7535\u5316\u5b66\u6027\u80fd\u5206\u6790\uff1a<\/strong>\u6570\u636e\u4e00\u76ee\u4e86\u7136\uff0c\u65e0\u9700\u8fc7\u591a\u89e3\u91ca<\/p>\n<p>\u5176\u4e2d\uff0ca\u56fe\u4e3a\u7535\u538b\u8303\u56f4\u4e3a1.0-2.5V\u65f6\uff0c\u5206\u522b\u57280.1\u523030C\u500d\u7387\u4e0b\u7684\u653e\u7535\u66f2\u7ebf\u56fe\uff0c0.1C\u65f6\u7684\u653e\u7535\u5bb9\u91cf\u4e3a174.8 mAhg<sup>\u2212<\/sup><sup>1<\/sup>\u63a5\u8fd1175 mAhg<sup>\u2212<\/sup><sup>1<\/sup>\u7684\u7406\u8bba\u5bb9\u91cf\uff0c\u572830C\u65f6\uff0c\u5bb9\u91cf\u4ecd\u7136\u80fd\u8fbe\u5230119.6 mAhg<sup>-1<\/sup><sup>\uff0c<\/sup>\u662f0.1C\u768468.4%<\/p>\n<p><a href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/8-1-1.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-large wp-image-22132\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/8-1-1-689x1024.png\" alt=\"8-1\" width=\"689\" height=\"1024\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/8-1-1-689x1024.png 689w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/8-1-1-202x300.png 202w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/8-1-1.png 740w\" sizes=\"(max-width: 689px) 100vw, 689px\" \/><\/a><\/p>\n<p>\u56fe7. 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href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/\uff19.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-22133\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/\uff19.png\" alt=\"\uff19\" width=\"740\" height=\"333\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/\uff19.png 740w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/06\/\uff19-300x135.png 300w\" sizes=\"(max-width: 740px) 100vw, 740px\" \/><\/a><\/p>\n<p>\u56fe8. 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