{"id":221166,"date":"2021-04-30T06:54:56","date_gmt":"2021-04-29T22:54:56","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=221166"},"modified":"2021-04-29T20:55:13","modified_gmt":"2021-04-29T12:55:13","slug":"%e4%b8%8a%e6%b5%b7%e7%a7%91%e5%a4%a7%e6%9d%8e%e6%b6%9b%e5%9b%a2%e9%98%9fangewandte-chemie%ef%bc%9a%e4%bd%bf%e7%94%a8%e9%85%8d%e4%bd%8d%e4%ba%a4%e8%81%94%e8%a1%a8%e9%9d%a2%e6%94%b9%e6%80%a7%e6%96%b9","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=221166","title":{"rendered":"\u4e0a\u6d77\u79d1\u5927\u674e\u6d9b\u56e2\u961fAngewandte Chemie\uff1a\u4f7f\u7528\u914d\u4f4d\u4ea4\u8054\u8868\u9762\u6539\u6027\u65b9\u6cd5\u5728\u805a\u5408\u7269\u57fa\u4f53\u4e2d\u5b9e\u73b0\u7406\u60f3\u7684\u91d1\u5c5e-\u6709\u673a\u6846\u67b6\u9897\u7c92\u5206\u6563\u6027"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n

\u5c06\u7eb3\u7c73\u6750\u6599\u6dfb\u52a0\u5242\u5206\u6563\u5230\u805a\u5408\u7269\u57fa\u4f53\u4e2d\u662f\u63d0\u9ad8\u805a\u5408\u7269\u7684\u673a\u68b0\u3001\u7535\u6c14\u3001\u5149\u5b66\u548c\u8d28\u91cf\u4f20\u8f93\u7279\u6027\u7684\u6709\u6548\u9014\u5f84\u3002\u7136\u800c\uff0c\u5b9e\u73b0\u8fd9\u79cd\u6539\u8fdb\u7684\u5173\u952e\u662f\u5efa\u7acb\u76f8\u5bb9\u7684\u586b\u6599-\u57fa\u4f53\u754c\u9762\uff0c\u4ee5\u63a7\u5236\u7eb3\u7c73\u6750\u6599\u5728\u57fa\u4f53\u4e2d\u7684\u5206\u6563\u6027\u3002\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08MOF\uff09\u4f5c\u4e3a\u4e00\u7c7b\u65b0\u7684\u591a\u5b54\u6750\u6599\uff0c\u5f53\u4e0e\u805a\u5408\u7269\u57fa\u4f53\u6df7\u5408\u65f6\uff0cMOF\u7684\u591a\u5b54\u6027\u53ef\u4ee5\u6539\u5584\u805a\u5408\u7269\u7684\u6c14\u4f53\u4f20\u8f93\u7279\u6027\u3002\u4f46MOF\u9897\u7c92\u56e2\u805a\u662f\u4e00\u4e2a\u53cd\u590d\u51fa\u73b0\u7684\u73b0\u8c61\uff0c\u8fd9\u901a\u5e38\u8868\u660e\u754c\u9762\u76f8\u5bb9\u6027\u8f83\u5dee\uff0c\u56e0\u6b64\u4e0e\u819c\u7684\u673a\u68b0\u548c\u4f20\u8d28\u7279\u6027\u7684\u4e0b\u964d\u5bc6\u5207\u76f8\u5173\u3002\u9075\u5faa\u201c\u540c\u7c7b\u76f8\u6eb6\u201d\u7684\u539f\u5219\uff0c\u901a\u5e38\u91c7\u7528\u7684\u7b56\u7565\u662f\u901a\u8fc7\u8868\u9762\u6539\u6027\u6765\u63d0\u9ad8MOF\u5728\u805a\u5408\u7269\u57fa\u8d28\u4e2d\u7684\u5206\u6563\u6027\u3002\u4f8b\u5982\uff0c\u7528\u758f\u6c34\u5c0f\u5206\u5b50\u6539\u6027MOF\u8868\u9762\u53ef\u4ee5\u63d0\u9ad8\u5176\u5728\u975e\u6781\u6027\u805a\u5408\u7269\u4ecb\u8d28\u4e2d\u7684\u5206\u6563\u6027\u3002\u7136\u800c\uff0c\u5c0f\u5206\u5b50\u6539\u6027\u5242\u5bb9\u6613\u6269\u6563\u5230MOF\u7684\u5b54\u9699\u4e2d\uff0c\u5bfc\u81f4\u5b54\u9699\u5835\u585e\uff0c\u5b54\u9699\u7387\u964d\u4f4e\u3002\u8981\u4f7f\u5c0f\u5206\u5b50\u6539\u6027\u5242\u7684\u5316\u5b66\u6027\u8d28\u4e0e\u819c\u79d1\u5b66\u4e2d\u7ecf\u5e38\u9047\u5230\u7684\u5404\u79cd\u805a\u5408\u7269\u5b8c\u5168\u5339\u914d\u4e5f\u662f\u4e00\u79cd\u6311\u6218\u3002\u539f\u5219\u4e0a\uff0c\u7528\u4e0e\u57fa\u4f53\u805a\u5408\u7269\u76f8\u540c\u7684\u805a\u5408\u7269\u6216\u805a\u5408\u7269\u6bb5\u63a5\u679dMOF\u8868\u9762\u5e94\u8be5\u662f\u201c\u540c\u7c7b\u76f8\u6eb6\u201d\u7684\u7406\u60f3\u63cf\u8ff0\u3002\u7136\u800c\uff0c\u76ee\u524d\u53ef\u5b9e\u73b0\u7684\u5c06\u805a\u5408\u7269\u63a5\u679d\u5230MOF\u8868\u9762\u7684\u4f8b\u5b50\u5927\u591a\u9650\u4e8e\u53ef\u81ea\u7531\u805a\u5408\u7684\u805a\u5408\u7269\uff08\u5982\u7532\u57fa\u4e19\u70ef\u9178\u916f\u3001\u4e19\u70ef\u9178\u916f\u548c\u82ef\u4e59\u70ef\u7b49\uff09\uff0c\u8fd9\u4e9b\u805a\u5408\u7269\u901a\u5e38\u4e0d\u88ab\u89c6\u4e3a\u6c14\u4f53\u5206\u79bb\u819c\u7684\u5b9e\u7528\u6750\u6599\u3002\u76f8\u53cd\uff0c\u5c3d\u7ba1\u8bb8\u591a\u7f29\u5408\u805a\u5408\u7269\uff0c\u5982\u805a\u9170\u4e9a\u80fa\uff08PI\uff09\u3001\u805a\u781c\uff08PSF\uff09\u3001\u805a\u919a\u781c\uff08PESU\uff09\u3001\u56fa\u6709\u5fae\u5b54\u805a\u5408\u7269\uff08PIM\uff09\u3001\u805a\u78b3\u9178\u916f\uff08PC\uff09\u7b49\u662f\u819c\u76f8\u5173\u7814\u7a76\u7684\u4e3b\u8981\u53c2\u4e0e\u8005\uff0c\u4f46\u5c06\u5b83\u4eec\u4fee\u9970\u5230MOF\u8868\u9762\u5219\u975e\u5e38\u5177\u6709\u6311\u6218\u6027\u3002\u4e00\u79cd\u5b9e\u7528\u7684\u65b9\u6cd5\u662f\u5c06\u805a\u9170\u4e9a\u80fa\u5171\u4ef7\u63a5\u679d\u5230\u9884\u529f\u80fd\u5316\u7684MOF\u914d\u4f53\u4e0a\uff0c\u6216\u4ece\u9884\u529f\u80fd\u5316\u7684MOF\u914d\u4f53\u4e0a\u63a5\u679d\u5230\u805a\u9170\u4e9a\u80fa\u4e0a\uff0c\u4e0d\u5e78\u7684\u662f\uff0c\u8fd9\u9650\u5236\u4e86\u5b83\u5728\u80fa\u57faMOF\u4e0a\u7684\u4f7f\u7528\u3002\u6700\u8fd1\uff0c\u8be5\u5c0f\u7ec4\u62a5\u544a\u4e86\u4f7f\u7528\u91d1\u5c5e\u6709\u673a\u7eb3\u7c73\u80f6\u56ca\uff08MONC\uff09PgC5<\/sub>Cu\uff0c\u4f5c\u4e3a\u4e00\u4e2a\u591a\u9f7f\u5206\u5b50\u8282\u70b9\uff0c\u901a\u8fc7\u5176\u66b4\u9732\u7684Cu\u5f00\u653e\u91d1\u5c5e\u4f4d\u70b9\uff08OMS\uff09\u6765\u914d\u4f4d\u4ea4\u8054\u5404\u79cd\u7f29\u5408\u805a\u5408\u7269\u3002\u4e0e\u5171\u4ef7\u4ea4\u8054\u76f8\u6bd4\uff0c\u914d\u4f4d\u4ea4\u8054\u66f4\u5177\u6709\u666e\u9002\u6027\uff0c\u56e0\u4e3aOMS\u53ef\u4ee5\u4e0e\u51e0\u4e4e\u4efb\u4f55\u6781\u6027\u6709\u673a\u529f\u80fd\u5206\u5b50\u76f8\u4e92\u4f5c\u7528\uff0c\u5305\u62ec\u7fb0\u57fa\u3001\u78fa\u9170\u57fa\u3001\u8148\u57fa\u3001\u7f9f\u57fa\u548c\u7fa7\u57fa\u7b49\u3002\u6211\u4eec\u5047\u8bbe\uff0c\u5982\u679cMOF\u8868\u9762\u53ef\u4ee5\u7528\u4e00\u5c42PgC5<\/sub>Cu\u8fdb\u884c\u9884\u529f\u80fd\u5316\uff0c\u90a3\u4e48\u5404\u79cd\u7f29\u5408\u805a\u5408\u7269\u968f\u540e\u53ef\u4ee5\u901a\u8fc7\u914d\u4f4d\u4ea4\u8054\u529f\u80fd\u5316\u5230MOF\u8868\u9762\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5728\u4e0a\u6d77\u79d1\u6280\u5927\u5b66\u674e\u6d9b<\/b><\/strong>\u6559\u6388<\/b><\/strong>\u56e2\u961f<\/b><\/strong>\u5e26\u9886\u4e0b\uff0c\u9996\u6b21\u4ecb\u7ecd\u4e86\u7528\u805a\u9170\u4e9a\u80fa\u3001\u805a\u781c\u3001\u805a\u78b3\u9178\u916f\u548c\u672c\u5f81\u5fae\u5b54\u6027\u805a\u5408\u7269-1\uff08PIM-1\uff09\u5bf9\u5404\u79cdMOF\u8868\u9762\u8fdb\u884c\u6539\u6027\u7684\u53ef\u63a8\u5e7f\u65b9\u6cd5\u3002\u8be5\u65b9\u6cd5\u9996\u5148\u5229\u7528\u9759\u7535\u5438\u9644\u4f5c\u7528\uff0c\u5728\u5e26\u6b63\u7535\u8377\u7684MOF\u8868\u9762\u5feb\u901f\u6539\u6027\u4e00\u5c42\u5e26\u8d1f\u7535\u8377\u7684\u91d1\u5c5e\u6709\u673a\u7eb3\u7c73\u80f6\u56caPgC5<\/sub>Cu\u3002\u5728\u4e0e\u805a\u5408\u7269\u6df7\u5408\u540e\uff0cPgC5<\/sub>Cu\u4e0a\u7684\u94dc\u5f00\u653e\u91d1\u5c5e\u4f4d\u70b9\u5728\u70ed\u6d3b\u5316\u540e\u914d\u4f4d\u4ea4\u8054\u8868\u9762\u805a\u5408\u7269\u4e0a\u7684\u6781\u6027\u5b98\u80fd\u56e2\uff0c\u4ece\u800c\u5f62\u6210\u5747\u5300\u7684\u4e9a10nm\u805a\u5408\u7269\u6d82\u5c42\u3002\u56e2\u961f\u5b9a\u91cf\u5206\u6790\u4e86MOF\u9897\u7c92\u4e4b\u95f4\u7684\u81ea\u7531\u8def\u5f84\u95f4\u8ddd\u5206\u5e03\uff0c\u8bc1\u660e\u5f53\u8868\u9762\u805a\u5408\u7269\u4e0e\u57fa\u4f53\u805a\u5408\u7269\u76f8\u5339\u914d\u65f6\uff0cMOF\u7684\u5206\u6563\u6027\u4e0d\u4ec5\u5728\u89c6\u89c9\u4e0a\u5f97\u5230\u4e86\u6539\u5584\uff0c\u800c\u4e14\u4e5f\u53d1\u73b0\u4e0e\u7406\u8bba\u9884\u6d4b\u7684\u7406\u60f3\u5206\u6563\u6a21\u578b\u5b8c\u5168\u4e00\u81f4\uff0c\u8be5\u6a21\u578b\u6ca1\u6709\u805a\u96c6\u9a71\u52a8\u529b\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a\u201cCoating the Right Polymer: Achieving Ideal Metal\u2010Organic Framework Particle Dispersibility in Polymer Matrixes Using a Coordinative Crosslinking Surface Modification Method\u201d<\/b><\/strong>\u53d1\u8868\u5728\u4e86Angewandte Chemie<\/b><\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

\u56fe1 MONC\u4ecb\u5bfc\u7684MOF\u8868\u9762\u6539\u6027\u805a\u5408\u7269\u7684\u793a\u610f\u56fe<\/b><\/strong>\"\"<\/p>\n

\u56fe2 U66<\/b><\/strong>@<\/b><\/strong>Pg\u7684<\/b><\/strong>\u5f62\u8c8c\u548c\u7ed3\u6784\u8868\u5f81<\/b><\/strong>\"\"<\/p>\n

\uff08A\uff09UiO-66-NH2<\/sub>\u6ee4\u997c\u5728DCM\u4e2d\u7684\u7167\u7247\uff08\u5de6\uff09\u3002\u7136\u540e\u52a0\u5165\u5c11\u91cfPgC5<\/sub>Cu\u6eb6\u6db2\u5230\u5c0f\u74f6\uff08\u4e2d\u95f4\uff09\u3002MOF\u6837\u54c1\u901a\u8fc7\u8d85\u58f0\u5206\u6563\uff0c\u5e76\u79bb\u5fc3\u56de\u6536\uff08\u53f3\uff09\u3002<\/p>\n

\uff08B\uff09U66@Pg\u7684TEM\u56fe\u50cf\u548c\uff08C\uff09EDS\u5143\u7d20\u56fe\uff0c\u6bd4\u4f8b\u5c3a\uff1a100 nm\u3002<\/p>\n

\uff08D\uff09U66@Pg\u7684XPS\u5149\u8c31\u3002<\/p>\n

\uff08E\uff09UiO-66-NH2<\/sub>\uff08i\uff09\u548cU66@Pg\uff08ii\uff09\u7684\u6c34\u63a5\u89e6\u89d2\u6d4b\u91cf\u3002<\/p>\n

\uff08F\uff09PgC5<\/sub>Cu\u548cMOF\u5728PgC5<\/sub>Cu\u5438\u9644\u4e4b\u524d\uff08\u84dd\u8272\uff09\u548c\u4e4b\u540e\uff08\u7eff\u8272\uff09\u7684Zeta\u7535\u4f4d\u3002<\/p>\n

\u56fe3 <\/b><\/strong>\u6539\u6027<\/b><\/strong>UiO-66-NH<\/b><\/strong>2<\/b><\/sub><\/strong>\u7684\u5f62\u8c8c\u548c\u7ed3\u6784\u8868\u5f81<\/b><\/strong>\"\"<\/p>\n

\uff08A\uff09U66@PgPI\u7684TEM\u56fe\u50cf\uff0c\u6bd4\u4f8b\u5c3a\uff1a100 nm\u3002<\/p>\n

\uff08B\uff09MOF\u6d88\u89e3\u540ePI\u80f6\u56ca\u7684TEM\u56fe\u50cf\uff0c\u6bd4\u4f8b\u5c3a\uff1a100 nm\u3002<\/p>\n

\uff08C\uff09U66@PgPI\u7684EDS\u5143\u7d20\u5206\u5e03\u56fe\uff0c\u6bd4\u4f8b\u5c3a\uff1a100 nm\u3002<\/p>\n

\uff08D\uff09\u8868\u9762\u6539\u6027\u524d\u540ePI\u548cUiO-66-NH2<\/sub>\u7684FT-IR\u5149\u8c31\u3002<\/p>\n

\uff08E\uff09\u8868\u9762\u6539\u6027\u524d\u540eUiO-66-NH2<\/sub>\u5728DCM\u4e2d\u7684\u6d41\u4f53\u52a8\u529b\u5b66\u7c92\u5f84\u3002<\/p>\n

\uff08F\uff09\u7eafPSF\uff08\u9ed1\u8272\uff09\u3001U66@PgPSF-\u65e0\u6fc0\u6d3b\uff08\u7ea2\u8272\uff09\u548cU66@PgPSF\uff08\u84dd\u8272\uff09\u7684DMA\u56fe\u53ca\u5176\u5bf9\u5e94\u7684Tg<\/sub>\u3002<\/p>\n

\u56fe4 UiO-66-NH<\/b><\/strong>2<\/b><\/sub><\/strong>\u7684<\/b><\/strong>N<\/b><\/strong>2<\/b><\/sub><\/strong>\u5438\u9644-\u89e3\u5438\u7b49\u6e29\u7ebf<\/b><\/strong>\"\"<\/p>\n

\uff08A\uff09UiO-66-NH2<\/sub>\uff08\u7ea2\u8272\uff09\u3001U66@Pg\uff08\u84dd\u8272\uff09\u548cU66@PgPI\uff08\u7eff\u8272\uff09\u572877K\u65f6\u7684N2<\/sub>\u5438\u9644-\u89e3\u5438\u7b49\u6e29\u7ebf\u3002<\/p>\n

\uff08B\uff09\u5f52\u4e00\u5316\u4e3aMOF\u8d28\u91cf\u7684\u76f8\u540c\u6837\u54c1\u7684N2<\/sub>\u5438\u9644-\u89e3\u5438\u7b49\u6e29\u7ebf\u3002<\/p>\n

\u56fe<\/b><\/strong>5<\/b><\/strong>\u00a0<\/b><\/strong>\u6539\u6027MOF\u7684TEM\u56fe<\/b><\/strong>\"\"<\/p>\n

\uff08A-C\uff09U66@PgPSF (Ai)\uff0c U66@PgPIM-1 (Bi)\uff0c U66@PgPC (Ci)\u548cPSF (Aii)\uff0c PIM-1 (Bii)\uff0c PC (Cii)\u80f6\u56ca\u7ecfMOF\u6d88\u89e3\u540e\u7684TEM\u56fe\u50cf\uff0c\u6bd4\u4f8b\u5c3a\uff1a100 nm\u3002<\/p>\n

\uff08D-F\uff09\u5bf9ZIF-8@PgPI (Di)\u3001ZIF-67@PgPI (Ei)\u3001MOF-801@PgPI (Fi)\u53ca\u5176\u5404\u81ea\u7684PI\u80f6\u56ca\u7ecfMOF\u6d88\u89e3\u540e\u7684TEM\u56fe\u50cf\uff0c\u6bd4\u4f8b\u5c3a\uff1a100 nm\u3002<\/p>\n

\u56fe<\/b><\/strong>6<\/b><\/strong>\u00a0UiO-66-NH<\/b><\/strong>2<\/b><\/sub><\/strong>\uff08\u5e72\uff09<\/b><\/strong>\u548c<\/b><\/strong>UiO-66-NH<\/b><\/strong>2<\/b><\/sub><\/strong>\u60ac\u6d6e\u6db2<\/b><\/strong>\u7684TEM\u56fe<\/b><\/strong>\"\"<\/p>\n

\uff08A\uff09UiO-66-NH2<\/sub>\uff08\u5e72\uff09\u5728PSF (i)\u3001PI (ii)\u548cPIM-1 (iii)\u57fa\u4f53\u4e2d\u5206\u6563\u7684\u8d85\u8584\u5207\u7247\uff08100 nm\uff09\u7684TEM\u56fe\u50cf\u3002\u6bd4\u4f8b\u5c3a\uff1a1\u03bcm\u3002<\/p>\n

\uff08B\uff09UiO-66-NH2<\/sub>\u60ac\u6d6e\u6db2\u5206\u6563\u5728PSF (i)\u3001PI (ii)\u548cPIM-1 (iii)\u57fa\u8d28\u4e2d\u3002 U66@PgPIM-1\u5206\u6563\u5728PSF\uff08Ci\uff09\u4e2d\uff1b U66@PgPSF\u5206\u6563\u5728PI\uff08Cii\uff09\u4e2d\uff1b U66@PgPI\u5206\u6563\u5728PIM-1\uff08Ciii\uff09\u4e2d\u3002<\/p>\n

\uff08D\uff09PSF\u3001PI\u548cPIM-1\u6539\u6027\u7684UiO-66-NH2<\/sub>\u5206\u522b\u5206\u6563\u5728PSF\u3001PI\u548cPIM-1\u57fa\u4f53\u4e2d\uff0c\u6bd4\u4f8b\u5c3a\uff1a1\u03bcm\u3002<\/p>\n

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\u3010\u5c0f\u7ed3\u3011<\/b><\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u56e2\u961f\u9996\u6b21\u5c55\u793a\u4e86\u7528\u4e09\u79cd\u4e0d\u540c\u7c7b\u522b\u7684\u7f29\u5408\u805a\u5408\u7269\uff08PSF\u3001PI\u548cPIM\uff09\u6539\u6027MOF\u8868\u9762\u7684\u901a\u7528\u65b9\u6cd5\u3002\u5728\u8fd9\u4e2a\u8fc7\u7a0b\u4e2d\uff0c\u94dcMONC\u4ecb\u4f53\u9996\u5148\u88ab\u9759\u7535\u5438\u9644\u5728MOF\u8868\u9762\uff0c\u7136\u540e\u4f5c\u4e3a\u591a\u9f7f\u4ea4\u8054\u5242\uff0c\u901a\u8fc7\u5176OMSs\u4ea4\u8054\u76f8\u90bb\u7684\u805a\u5408\u7269\u94fe\u3002\u6709\u4e86\u4e0e\u57fa\u4f53\u805a\u5408\u7269\u5b8c\u5168\u5339\u914d\u7684\u5408\u9002\u7684\u805a\u5408\u7269\u6d82\u5c42\uff0cMOF\u7684\u5206\u6563\u6027\u4e0d\u518d\u53d6\u51b3\u4e8e\u57fa\u4f53\uff0c\u4ece\u800c\u5b9e\u73b0\u4e86MOF\u5728\u7edf\u8ba1\u4e0a\u7684\u968f\u673a\u5206\u6563\u3002\u56e2\u961f\u9884\u8ba1\uff0c\u8fd9\u79cd\u65b9\u6cd5\u5c06\u5728\u8bb8\u591aMOF\u805a\u5408\u7269\u590d\u5408\u6750\u6599\u7684\u6784\u5efa\u4e2d\u5f97\u5230\u5e94\u7528\uff0c\u56e0\u4e3aMOF\u7684\u5206\u6563\u6027\u662f\u4e00\u4e2a\u5173\u952e\u56e0\u7d20\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5<\/b><\/strong>\uff1aCoating the Right Polymer: Achieving Ideal Metal\u2010Organic Framework Particle Dispersibility in Polymer Matrixes Using a Coordinative Crosslinking Surface Modification Method<\/u><\/a>\uff08Angewandte Chemie\uff0c2021\uff0cDOI:10.1002\/ange.202104487\uff09<\/p>\n

\u3010\u56e2\u961f\u4ecb\u7ecd\u3011<\/b><\/strong>\u00a0<\/p>\n

\uff081\uff09\u674e\u6d9b\uff0c\u4e0a\u6d77\u79d1\u6280\u5927\u5b66\u7269\u8d28\u5b66\u9662\u52a9\u7406\u6559\u6388\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\u30022008\u5e74\u672c\u79d1\u6bd5\u4e1a\u4e8e\u590d\u65e6\u5927\u5b66\u5316\u5b66\u7cfb\u30022008-2013\u5e74\u535a\u58eb\u6bd5\u4e1a\u4e8e\u7f8e\u56fd\u5339\u5179\u5821\u5927\u5b66\u5316\u5b66\u7cfb\uff08\u5bfc\u5e08\uff1aNathaniel L. Rosi\uff09\u30022014-2015\u5e74\u5728\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u7cfb\u548c\u52b3\u4f26\u65af\u4f2f\u514b\u5229\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u4ece\u4e8b\u535a\u58eb\u540e\u7814\u7a76\uff08\u5bfc\u5e08\uff1aTing Xu\uff09\u3002\u81ea2015\u5e7411\u6708\u52a0\u5165\u4e0a\u6d77\u79d1\u6280\u5927\u5b66\u7269\u8d28\u79d1\u5b66\u4e0e\u6280\u672f\u5b66\u9662\u4efb\u52a9\u7406\u6559\u6388\u3002\u8bfe\u9898\u7ec4\u4e3b\u8981\u7814\u7a76\u5173\u6ce8\u591a\u5b54\u590d\u5408\u6750\u6599\u5728\u4ecb\u89c2\u5c3a\u5ea6\u4e0a\u7684\u8bbe\u8ba1\u4e0e\u6784\u5efa\uff0c\u81f4\u529b\u4e8e\u4ece\u5206\u5b50\u5c42\u9762\u7406\u89e3\u590d\u5408\u6750\u6599\u754c\u9762\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\uff0c\u5e76\u5229\u7528\u8fd9\u7c7b\u4fe1\u606f\u7ed3\u5408\u4ece\u65e0\u673a\u3001\u6709\u673a\u5230\u9ad8\u5206\u5b50\u7684\u4e00\u7cfb\u5217\u5408\u6210\u624b\u6bb5\u5728\u5404\u4e2a\u5c3a\u5ea6\u8303\u56f4\u5185\u7cbe\u51c6\u63a7\u5236\u590d\u5408\u6750\u6599\u7684\u7ed3\u6784\uff0c\u4ece\u800c\u5e2e\u52a9\u6211\u4eec\u7406\u89e3\u8fd9\u7c7b\u590d\u6742\u4f53\u7cfb\u7684\u6784\u6548\u5173\u7cfb\u3002<\/p>\n

\u8bfe\u9898\u7ec4\u4e3b\u9875\uff1a<\/strong><\/p>\n

www.liresearchlab.com<\/p>\n

\uff082\uff09 \u56e2\u961f\u5728\u8be5\u9886\u57df\u5de5\u4f5c\u6c47\u603b\uff1b<\/p>\n

A Physical Entangling Strategy for Simultaneous Interior and Exterior Modification of Metal-Organic Framework with Polymers. D. Dai, H. Wang, C. Li, X. Qin, T. Li* Angew. Chem. Int. Ed., 2020, DOI: 10.1002\/anie.202016041<\/p>\n

Enhancing the Gas Separation Selectivity of Mixed-Matrix Membranes Using a Dual-Interfacial Engineering Approach. C. Wu, K. Zhang, H. Wang, Y. Fan, S. Zhang, S. He, F. Wang, Y. Tao, X. Zhao, Y. Zhang, Y. Ma, Y. Lee, T. Li* J. Am. Chem. Soc., 2020, 142, 18503\u201318512<\/p>\n

Engineering Plasticization Resistant Gas Separation Membranes Using Metal-Organic Nanocapsules. H. Wang, K. Zhang, P. H. Li, J. Huang, B. Yuan, C. Zhang, Y. Yu, Y. Yang, Y. Lee, T. Li* Chem. Sci., 2020, 11, 4687<\/p>\n

General Way To Construct Micro- and Mesoporous Metal-Organic Framework-Based Porous Liquids. S. He, L. Chen, J. Cui, B. Yuan, H. Wang, F. Wang, Y. Yu, Y. Lee*, T. Li*, J. Am. Chem. Soc., 2019, 141, 19708-19714<\/p>\n

A generalizable method for the construction of MOF@polymer functional composites through surface-initiated atom transfer radical polymerization. S. He, H. Wang, C. Zhang, S. Zhang, Y. Yu, Y. Lee, T. Li*, Chem. Sci., 2019, 10, 1816-1822<\/p>\n

Interfacial Engineering in Metal-Organic Framework-Based Mixed Matrix Membranes Using Covalently Grafted Polyimide Brushes. H. Wang, S. He, X. Qin, C. Li, T. Li*, J. Am. Chem. Soc., 2018, 140,17203-17210<\/p>\n

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