{"id":221984,"date":"2021-05-17T06:55:46","date_gmt":"2021-05-16T22:55:46","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=221984"},"modified":"2021-05-16T21:55:58","modified_gmt":"2021-05-16T13:55:58","slug":"nature-materials%ef%bc%9a%e8%81%9a%e5%90%88%e7%89%a9%e5%a4%8d%e5%90%88%e7%94%b5%e8%a7%a3%e8%b4%a8%e5%8a%a9%e5%8a%9bli%e5%9f%ba%e7%94%b5%e6%b1%a0%e8%8e%b7%e6%96%b0%e7%94%9f%ef%bc%81","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=221984","title":{"rendered":"Nature Materials\uff1a\u805a\u5408\u7269\u590d\u5408\u7535\u89e3\u8d28\u52a9\u529bLi\u57fa\u7535\u6c60\u83b7\u65b0\u751f\uff01"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u56fa\u6001\u805a\u5408\u7269\u7535\u89e3\u8d28\uff08SPEs\uff09\u5728\u590d\u5174\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u9502\uff08Li\uff09\u57fa\u7535\u6c60\u65b9\u9762\u53d7\u5230\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002\u867d\u7136\u9502\u79bb\u5b50\u7535\u6c60\uff08LIBs\uff09\u56e0\u5176\u76f8\u5bf9\u8f83\u9ad8\u7684\u6bd4\u80fd\u91cf\u548c\u529f\u7387\u5bc6\u5ea6\u5728\u50a8\u80fd\u9886\u57df\u53d1\u6325\u7740\u91cd\u8981\u4f5c\u7528\uff0c\u4f46\u662f\u5b83\u4eec\u6b63\u63a5\u8fd1\u7406\u8bba\u6781\u9650\uff08\u7ea6400 Wh kg-1<\/sup>\uff09\u3002\u76ee\u524d\uff0c\u7814\u7a76\u4eba\u5458\u4e3b\u8981\u96c6\u4e2d\u5728\u65b0\u578b\u7535\u6781\u6750\u6599\u4e0a\uff0c\u4ee5\u63d0\u9ad8Li\u57fa\u7535\u6c60\u7684\u5bb9\u91cf\u3002\u5728\u6b63\u6781\u65b9\u9762\uff0c\u9502-\u7a7a\u6c14\u7535\u6c60\u548c\u9502-\u786b\u7535\u6c60\u662f\u4e3b\u8981\u7684\u524d\u6cbf\u5019\u9009\u7535\u6c60\u3002\u5728\u8d1f\u6781\u5904\uff0c\u9502\u91d1\u5c5e\u53ef\u4ee5\u4ee3\u66ff\u77f3\u58a8\uff0c\u4f7f\u8d1f\u6781\u80fd\u91cf\u5bc6\u5ea6\u63d0\u9ad8\u7ea610\u500d\u3002\u7136\u800c\uff0c\u5728\u957f\u671f\u7684\u5145\u653e\u7535\u5faa\u73af\u8fc7\u7a0b\u4e2d\uff0c\u7535\u6781\u7684\u53d1\u5c55\u9700\u8981\u4e00\u79cd\u80fd\u591f\u963b\u6b62\u4e0d\u53ef\u9006\u53cd\u5e94\u548c\u679d\u6676\u751f\u957f\u7684\u7535\u89e3\u8d28\u3002\u5176\u4e2d\uff0cSPEs\u4e0d\u4ec5\u63d0\u4f9b\u673a\u68b0\u521a\u5ea6\u6765\u963b\u6b62\u679d\u6676\uff0c\u800c\u4e14\u63d0\u4f9b\u6bd4\u6db2\u4f53\u7535\u89e3\u8d28\u66f4\u5b89\u5168\u7684\u64cd\u4f5c\u3002\u57fa\u4e8e\u6781\u786c\u7684\u53cc\u87ba\u65cb\u78fa\u5316\u82b3\u9999\u805a\u9170\u80fa\u4e0e\u79bb\u5b50\u6db2\u4f53\uff08IL\uff09\u548c\u9502\u76d0\u7ec4\u5408\u7684\u56fa\u6001\u5206\u5b50-\u79bb\u5b50\u590d\u5408\uff08MIC\uff09\u7535\u89e3\u8d28\uff0c\u901a\u8fc7\u6539\u53d8\u805a\u5408\u7269\u542b\u91cf\u3001\u79bb\u5b50\u7c7b\u578b\u3001\u91d1\u5c5e\u76d0\u7c7b\u578b\u548c\u8d1f\u8f7d\u91cf\uff0c\u53ef\u4ee5\u5e7f\u6cdb\u5730\u8c03\u8282MIC\u7684\u6027\u80fd\u3002\u7814\u7a76\u4eba\u5458\u5f00\u53d1\u4e86\u8bb8\u591a\u57fa\u4e8eIL\u7684\u51dd\u80f6\u7535\u89e3\u8d28\uff08\u79bb\u5b50\u51dd\u80f6\u6216\u79bb\u5b50\u51dd\u80f6\uff09\uff0c\u5c06IL\u7684\u4e0d\u53ef\u71c3\u6027\u4e0e\u673a\u68b0\u652f\u6491\u57fa\u8d28\u7ed3\u5408\u8d77\u6765\u3002\u7136\u800c\uff0c\u8fd9\u4e9b\u51dd\u80f6\u53ea\u6709\u5728\u63ba\u6742\u6709\u673a\u7535\u89e3\u8d28\u65f6\u624d\u663e\u793a\u51fa\u5b9e\u9645\u7684\u9502\u91d1\u5c5e\u5faa\u73af\u6027\u80fd\uff0c\u6709\u673a\u7535\u89e3\u8d28\u63d0\u9ad8\u4e86\u5bfc\u7535\u6027\uff0c\u4f46\u5f15\u5165\u4e86\u6325\u53d1\u6027\u6db2\u4f53\uff0c\u964d\u4f4e\u4e86\u8fc7\u70ed\u548c\u706b\u707e\u7684\u5b89\u5168\u6027\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u7f8e\u56fd\u5f17\u5409\u5c3c\u4e9a\u7406\u5de5\u5b66\u9662\u4e0e\u5dde\u7acb\u5927\u5b66Louis A. Madsen\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba<\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u56fa\u6001MIC\u7535\u89e3\u8d28\uff0c\u5176\u4e0d\u542b\u6325\u53d1\u6027\u6eb6\u5242\uff0c\u4e14\u663e\u793a\u51fa\u9ad8\u79bb\u5b50\u5bfc\u7535\u6027\u3001\u6709\u5229\u7535\u6781-\u7535\u89e3\u8d28\u63a5\u89e6\u548c\u9ad8\u70ed\u7a33\u5b9a\u6027\uff0c\u540c\u65f6\u5177\u6709\u8db3\u591f\u7684\u6a21\u91cf\u4f5c\u4e3aLi\u91d1\u5c5e\u7535\u6c60\u7684\u9694\u819c\u3002\u5728\u7535\u89e3\u8d28\u4e2d\u52a0\u5165Li\u76d0\u53ef\u4ee5\u589e\u52a0Li\u79bb\u5b50\u7684\u5bfc\u7535\u6027\uff0c\u5e76\u4e14\u4e3a\u7535\u6781\u4e0a\u7684\u53cd\u5e94\u63d0\u4f9bLi\u79bb\u5b50\u3002\u901a\u8fc7\u5b9e\u9a8c\u8868\u660e\uff0c\u5728\u5305\u542bN-\u4e19\u57fa-N-\u7532\u57fa\u5421\u54af\u70f7\u53cc\uff08\u6c1f\u78fa\u9170\u57fa\uff09\u9170\u4e9a\u80fa\uff08C3<\/sub>mpyrFSI\uff09\u4e0eLiFSI\uff083.2 mol kg-1<\/sup>\uff09\u7684\u79bb\u5b50\u6db2\u4f53\u7535\u89e3\u8d28\uff08ILEs\uff09\u4e2d\uff0cLi\u91d1\u5c5e\u7684\u5faa\u73af\u901f\u7387\u5f88\u9ad8\u3002\u57fa\u4e8e\u4e0e\u79bb\u5b50\u6db2\u4f53\u548c\u6d53\u9502\u76d0\u7ed3\u5408\u7684\u53d6\u5411\u6db2\u6676\u805a\u5408\u7269\u7684\u5206\u5b50\u79bb\u5b50\u590d\u5408\u7535\u89e3\u8d28\uff0c\u4e0d\u4ec5\u5b9e\u73b0\u9ad8Li\u5bc6\u5ea6\u3001\u9ad8\u5f3a\u5ea6\uff08200 MPa\uff09\u548c\u4e0d\u53ef\u71c3\u6027\uff0c\u800c\u4e14\u5177\u6709\u51fa\u8272\u7684Li+\u7535\u5bfc\u7387\uff08\u572825 \u00b0C\u65f6\u4e3a1 mS cm-1<\/sup>\uff09\u548c\u7535\u5316\u5b66\u7a33\u5b9a\u6027\uff08\u5bf9\u6bd4Li|Li+<\/sup>\u4e3a5.6 V\uff09\uff0c\u540c\u65f6\u6291\u5236\u4e86\u679d\u6676\u7684\u751f\u957f\u4e14\u8868\u73b0\u51fa\u8f83\u4f4e\u7684\u754c\u9762\u7535\u963b\uff0832 \u03a9 cm2<\/sup>\uff09\uff0c\u4ee5\u53ca\u5728Li\u5bf9\u79f0\u7535\u6c60\u5faa\u73af\u8fc7\u7a0b\u4e2d\u663e\u793a\u51fa\u8fc7\u7535\u4f4d\uff08\u57281 mA cm-2<\/sup>\u65f6\u2264120 mV\uff09\u3002\u5f02\u8d28\u76d0\u63ba\u6742\u5de5\u827a\u4f1a\u4fee\u6539\u5c40\u90e8\u6709\u5e8f\u7684\u805a\u5408\u7269\u79bb\u5b50\u7ec4\u88c5\uff0c\u4ee5\u7ed3\u5408\u586b\u5145\u6709\u7f3a\u9677\u7684LiFSI\u548cLiBF4<\/sub>\u7eb3\u7c73\u6676\u4f53\u7684\u6676\u95f4\u7f51\u7edc\uff0c\u4ece\u800c\u6781\u5927\u589e\u5f3aLi+<\/sup>\u4f20\u8f93\u3002\u603b\u4e4b\uff0c\u8fd9\u79cd\u6a21\u5757\u5316\u6750\u6599\u5236\u9020\u5e73\u53f0\u5c06\u9676\u74f7\u7c7b\u5bfc\u4f53\u7684\u5feb\u901f\u4f20\u8f93\u4e0e\u805a\u5408\u7269\u7535\u89e3\u8d28\u7684\u4f18\u5f02\u67d4\u6027\u7ed3\u5408\u8d77\u6765\uff0c\u4e3a\u5b89\u5168\u3001\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u80fd\u91cf\u5b58\u50a8\u548c\u8f6c\u6362\u5e94\u7528\u63d0\u4f9b\u4e86\u524d\u666f\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cSolid-state rigid-rod polymer composite electrolytes with nanocrystalline lithium ion pathways\u201d<\/strong>\u53d1\u5e03\u5728\u56fd\u9645\u8457\u540d\u671f\u520aNature Materials<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\u3001\u5f62\u6210LiMICs\u7684\u5236\u9020\u8fc7\u7a0b<\/strong>
\n \"\"\uff08a\uff09\u6b65\u9aa41\u663e\u793aRMIC\u7684\u5236\u9020\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\uff09\u6b65\u9aa42\u663e\u793a\u7b2c\u4e8c\u4e2a\u79bb\u5b50\u4ea4\u6362\u8fc7\u7a0b\uff0c\u5176\u4e2d\u5c06RMIC\u7684\u5207\u7247\u622a\u9762\u6d78\u5165\u4e86ILE\u4e2d\uff1b<\/p>\n

\uff08c-d\uff09RMIC-5\u548cRMIC-15\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08e-f\uff09\u6b65\u9aa42\u4e4b\u540e\uff0c\u6676\u754c\u4e3b\u8981\u53d8\u4e3a\u7f29\u5408\u76d0\u76f8\uff0c\u5176\u7531\u5f62\u6210\u53ef\u652f\u6301\u5feb\u901fLi+<\/sup>\u4f20\u8f93\u7684\u5bfc\u7535\u7f51\u7edc\u7684\u7eb3\u7c73\u6676\u7c92\u7ec4\u6210\u3002<\/p>\n

\uff08g\uff09\u5bf9\u9f50\u7684LC\u6676\u7c92\u7684\u5f62\u6001\u5305\u542bPBDT\u53cc\u87ba\u65cb\u68d2\uff0c\u5176\u4e3b\u8981\u586b\u5145\u6709\u6d3b\u52a8IL\u9633\u79bb\u5b50\u3002<\/p>\n

\u56fe\u4e8c\u3001RMICs\u548cLiMICs\u7684X\u5c04\u7ebf\u884d\u5c04\u56fe<\/strong>
\n \"\"\uff08a\uff09RMIC\u7684\u7c89\u672bX\u5c04\u7ebf\u884d\u5c04\u56fe\uff1b<\/p>\n

\uff08b\uff09\u5728RMIC\u4e2d\uff0c\u4f5c\u4e3a\u5236\u5907\u5de5\u827a\u6b65\u9aa41\u7684\u7ed3\u679c\uff0c\u7528\u9ed1\u8272\u5b9e\u7ebf\u548c\u865a\u7ebf\u8868\u793aPBDT LC\u6676\u7c92\u548c\u6676\u754c\u5145\u6ee1\u975e\u6676\u6001IL\uff1b<\/p>\n

\uff08c\uff09LiMIC\u7684X\u5c04\u7ebf\u884d\u5c04\u56fe\uff1b<\/p>\n

\uff08d\uff09\u5728LiMIC\u4e2d\uff0cPBDT LC\u6676\u7c92\u95f4\u5b58\u5728\u539f\u4f4d\u5f62\u6210\u7684\u9ad8\u7f3a\u9677\u7eb3\u7c73\u6676\u7ed3\u6784\uff0c\u7531\u7eff\u8272\u5f62\u72b6\u548c\u9ed1\u70b9\u8868\u793a\uff1b<\/p>\n

\uff08e\uff09\u5728a\u548cc\u4e2d\u63d0\u53d6\u7684X\u5c04\u7ebf\u884d\u5c04\u56fe\u50cf\u76841D\u5149\u8c31\uff1b<\/p>\n

\uff08f\uff09LiMIC\u7684X\u5c04\u7ebf\u884d\u5c04\u56fe\u7684Le Bail\u7cbe\u4fee\u7ed3\u679c\u3002<\/p>\n

\u56fe\u4e09\u3001RMICs\u548cLiMICs\u7684\u5316\u5b66\u9274\u522b\u3001\u6269\u6563\u7cfb\u6570\u3001\u6d3b\u5316\u80fd\u548c\u4f20\u8f93\u673a\u7406<\/strong>
\n \"\"\uff08a\uff09\u7eafIL\uff08C2<\/sub>mimBF4<\/sub>\uff09\u3001ILE\uff08C3<\/sub>mpyrFSI\u548c50 mol\uff05LiFSI\uff09\u3001RMIC\u548cLiMIC\u4e2d\u9633\u79bb\u5b50\u76841<\/sup>H NMR\u5149\u8c31\uff1b<\/p>\n

\uff08b\uff09\u56fa\u4f53LiFSI\u3001\u56fa\u4f53LiBF4<\/sub>\u3001RMIC\u548cLiMIC\u768419<\/sup>F NMR\u5149\u8c31\uff1b<\/p>\n

\uff08c\uff09\u6db2\u6001ILE\u548cLiMIC\u76847<\/sup>Li\u5149\u8c31\uff1b<\/p>\n

\uff08d\uff09RMICs\u548cLiMICs\u4e2d\u4f9d\u8d56\u6e29\u5ea6\u7684D<\/em>cations<\/sub>\u548cD<\/em>anions<\/sub>(D<\/em>ions<\/sub>)\uff1b<\/p>\n

\uff08e\uff09ILE\u548cLiMICs\u4e2d\u4f9d\u8d56\u6e29\u5ea6\u7684DLi+<\/sub>\uff1b<\/p>\n

\uff08f\uff09\u4ece\u6269\u6563\u7ed3\u679c\u7684Arrhenius\u62df\u5408\u83b7\u5f97\u7684\u9633\u79bb\u5b50\u548c\u9634\u79bb\u5b50\u7684E<\/em>a<\/sub>\u503c\uff1b<\/p>\n

\uff08g\uff09C3<\/sub>mpyr+<\/sup>\u5206\u914d\u4e3a\u5c40\u90e8\u6392\u5217\u7684LC\u6676\u7c92\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08h\uff09\u4eceArrhenius\u62df\u5408\u83b7\u5f97\u7684Li+<\/sup>\u7684E<\/em>a<\/sub>\u503c\uff1b<\/p>\n

\uff08i\uff09\u7535\u89e3\u8d28\u7ed3\u6784\u793a\u610f\u56fe\uff0c\u663e\u793a\u6676\u754c\u4e2d\u7eb3\u7c73\u6676LiBF4<\/sub>\u548cLiFSI\u7684\u5f62\u6210\u673a\u7406\u3002<\/p>\n

\u56fe\u56db\u3001\u79bb\u5b50\u7535\u5bfc\u7387\u3001\u6d3b\u5316\u80fd\u3001Li+<\/sup>\u8f6c\u79fb\u6570\u3001\u7535\u5316\u5b66\u7a97\u53e3\u3001Li\u5bf9\u79f0\u7535\u6c60\u5faa\u73af\u6027\u80fd\u548cMICs\u4e2d\u7684\u754c\u9762\u7535\u8377\u8f6c\u79fb\u7535\u963b<\/strong>
\n \"\"\uff08a\uff09\u7528\u4e8e\u63d0\u53d6RMICs\u548cLiMICs\u4e2d\u79bb\u5b50\u7535\u5bfc\u7387\u7684\u6d3b\u5316\u80fd\uff08E<\/em>a<\/sub>\uff09\u7684Arrhenius\u56fe\uff1b<\/p>\n

\uff08b\uff09\u6bd4\u8f83\u6839\u636e\u7535\u5bfc\u7387\u7ed3\u679c\u83b7\u5f97Ea\u503c\u4e0e\u57fa\u4e8eLi+<\/sup>\u548cIL\u9633\u79bb\u5b50NMR\u6269\u6563\u6cd5\u7ed3\u679c\u7684Arrhenius\u62df\u5408\u7684IL\u9633\u79bb\u5b50\u548cLi+<\/sup>\u7684E<\/em>a<\/sub>\u503c\uff1b<\/p>\n

\uff08c\uff09\u572810 mV\u6781\u5316\u4e0b\u4f7f\u7528LiMICs\u7684\u5bf9\u79f0Li|Li\u7535\u6c60\u4e2d\u7684\u7a33\u6001\u7535\u6d41\uff1b<\/p>\n

\uff08d\uff09\u5728LiMIC-15\u4e2d\u4ee55 mV s-1<\/sup>\u7684\u626b\u63cf\u901f\u7387\u8fdb\u884cLi\u7535\u9540\u548c\u5265\u79bb\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\uff1b<\/p>\n

\uff08e\uff09\u4f7f\u7528LiMIC-15\u7684\u5bf9\u79f0Li|Li\u7535\u6c60\u7684\u7535\u6c60\u7535\u538b\u4e0e\u65f6\u95f4\u7684\u5173\u7cfb\uff1b<\/p>\n

\uff08f\uff09LiMIC-15\u7684\u7535\u6d41\u5bc6\u5ea6\uff08J<\/em>\uff09\u53d8\u5316\u4e4b\u524d\u626b\u63cf\u7684\u76f8\u5e94\u963b\u6297\u8c31\uff08\u771f\u5b9e\u963b\u6297Z<\/em>real<\/sub>\u548c\u865a\u62df\u963b\u6297Z<\/em>imag<\/sub>\uff09\u3002<\/p>\n

\u56fe\u4e94\u3001RMICs\u548cLiMICs\u7684\u70ed\u5b66\u548c\u529b\u5b66\u6027\u80fd<\/strong>
\n \"\"\uff08a\uff09DSC\u663e\u793aLiMICs\u548cRMICs\u4e4b\u95f4\u5b58\u5728\u660e\u663e\u5dee\u5f02\uff1b<\/p>\n

\uff08b\uff09DMA\u663e\u793aRMICs\u548cLiMICs\u5728-30\u81f3180 \u00b0C\u7684\u673a\u68b0\u6027\u80fd\u3002<\/p>\n

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\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1aSolid-state rigid-rod polymer composite electrolytes with nanocrystalline lithium ion pathways<\/a><\/strong>. Natrue Materials<\/em>, 2021<\/strong>, 10.1038\/s41563-021-00995-4<\/p>\n

\u672c\u6587\u7531CQR\u7f16\u8bd1\u3002<\/p>\n

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