{"id":222724,"date":"2021-06-03T06:42:19","date_gmt":"2021-06-02T22:42:19","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=222724"},"modified":"2021-06-02T20:42:33","modified_gmt":"2021-06-02T12:42:33","slug":"%e5%8d%97%e5%bc%80%e4%b8%8a%e6%b5%b7%e5%ba%94%e7%94%a8%e7%89%a9%e7%90%86%e6%89%80-nature%e5%ad%90%e5%88%8a%ef%bc%9a%e6%9c%80%e4%bd%b3%e5%82%a8li%e6%80%a7%e8%83%bd%ef%bc%81%e5%85%b7%e6%9c%89%e5%8f%af","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=222724","title":{"rendered":"\u5357\u5f00&\u4e0a\u6d77\u5e94\u7528\u7269\u7406\u6240 Nature\u5b50\u520a\uff1a\u6700\u4f73\u50a8Li\u6027\u80fd\uff01\u5177\u6709\u53ef\u9006\u5f62\u6210\u914d\u4f4d\u952e\u7684Sn-MOFs\u6765\u5b9e\u73b0"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u53ef\u518d\u5145\u7535\u9502\u79bb\u5b50\u7535\u6c60\uff08LIBs\uff09\u5177\u6709\u9ad8\u80fd\u91cf\u548c\u9ad8\u529f\u7387\u5bc6\u5ea6\u7684\u4f18\u70b9\uff0c\u5e7f\u6cdb\u7684\u5e94\u7528\u4e8e\u7535\u52a8\u6c7d\u8f66\u7b49\u4fbf\u643a\u5f0f\u7535\u5b50\u4ea7\u54c1\u9886\u57df\u3002\u5176\u4e2d\uff0c\u9521\uff08Sn\uff09\u57fa\u6750\u6599\uff08Sn\u548cSnO2<\/sub>\u7b49\uff09\u4f5c\u4e3a\u5927\u5bb9\u91cf\u8d1f\u6781\u6750\u6599\u65f6\uff0c\u5177\u6709Sn\u542b\u91cf\u4e30\u5bcc\u3001\u9ad8\u7406\u8bba\u5bb9\u91cf\uff08994 mAh g-1<\/sup>\uff09\u548c\u9002\u5b9c\u8d1f\u6781\u7535\u538b\u7684\u4f18\u70b9\u800c\u88ab\u5e7f\u6cdb\u7814\u7a76\u3002\u7136\u800c\uff0cSn\u57fa\u6750\u6599\u5728\u9502\uff08Li\uff09\u5408\u91d1\u5316\u548c\u8131\u5408\u91d1\u8fc7\u7a0b\u4e2d\u7684\u4f53\u79ef\u53d8\u5316\u8f83\u5927\uff08\u7ea6260%\uff09\uff0c\u901a\u5e38\u4f1a\u5f15\u8d77\u673a\u68b0\u65ad\u88c2\u3001\u9897\u7c92\u81a8\u80c0\u548c\u56fa\u4f53\u7535\u89e3\u8d28\u754c\u9762\u5c42\u4e0d\u7a33\u5b9a\u7b49\u95ee\u9898\uff0c\u963b\u788d\u53cd\u5e94\u52a8\u529b\u5b66\uff0c\u964d\u4f4e\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u867d\u7136\u7eb3\u7c73\u5316\u3001\u5408\u91d1\u5316\u6539\u6027\u7b49\u7b56\u7565\u88ab\u7528\u4e8e\u5f00\u53d1\u7406\u60f3\u7684\u7535\u6781\u6750\u6599\uff0c\u4f46\u662f\u7eb3\u7c73\u6750\u6599\u76f8\u5bf9\u8f83\u4f4e\u7684\u81f4\u5bc6\u5ea6\u548c\u5927\u91cfLi\u975e\u6d3b\u6027\u57fa\u56e2\u7684\u52a0\u5165\u964d\u4f4e\u4e86\u6574\u4e2a\u7535\u6c60\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002\u540c\u65f6\uff0c\u8fd9\u79cd\u6750\u6599\u7684\u5408\u6210\u8fc7\u7a0b\u590d\u6742\u4e14\u4e25\u683c\u3002\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08MOFs\uff09\u5177\u6709\u89c4\u5219\u4e14\u53ef\u8c03\u7684\u7ec4\u6210\u548c\u8868\u9762\u79ef\u53ef\u8c03\u7684\u5b54\u7ed3\u6784\uff0c\u4e3a\u5b58\u50a8Li\u63d0\u4f9b\u4e86\u6d3b\u6027\u4f4d\u70b9\u548c\u660e\u786e\u7684\u9502\u79bb\u5b50\u4f20\u8f93\u9014\u5f84\uff0c\u5728\u5b58\u50a8Li\u9886\u57df\u6709\u5e7f\u9614\u7684\u5e94\u7528\u524d\u666f\u3002\u5177\u6709Sn-O\u914d\u4f4d\u952e\u7684Sn\u57faMOFs\u53ef\u4ee5\u514b\u670dSn\u8d1f\u6781\u7684\u5267\u70c8\u4f53\u79ef\u53d8\u5316\uff0c\u5e76\u963b\u788d\u7c92\u5b50\u751f\u957f\u548c\u805a\u96c6\uff0c\u540c\u65f6\u6709\u673a\u914d\u4f53\u8fd8\u53ef\u4ee5\u4e3a\u5b58\u50a8Li\u63d0\u4f9b\u6d3b\u6027\u4f4d\u70b9\u3002\u56e0\u6b64\uff0c\u7ed3\u5408\u5408\u91d1\u578b\u91d1\u5c5e\u4e2d\u5fc3\u548c\u6d3b\u6027\u6709\u673a\u914d\u4f53\u7684\u4f18\u70b9\uff0c\u8bbe\u8ba1\u826f\u597d\u7684Sn\u57faMOF\u7535\u6781\u53ef\u4ee5\u5e94\u7528\u4e8e\u5b58\u50a8Li\u3002\u6b64\u5916\uff0c\u76ee\u524d\u5c1a\u672a\u62a5\u9053\u7528\u4e8e\u5b58\u50a8Li\u7684Sn\u57faMOFs\u7684\u8be6\u7ec6\u8bbe\u8ba1\u548c\u6784\u5efa\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5357\u5f00\u5927\u5b66\u5e08\u552f\u6559\u6388\u548c\u4e2d\u79d1\u9662\u4e0a\u6d77\u5e94\u7528\u7269\u7406\u7814\u7a76\u6240\u53f8\u9510\u7814\u7a76\u5458\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba<\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u901a\u8fc7\u914d\u4f4d\u5316\u5b66\u548c\u7535\u5316\u5b66\u7684\u7ed3\u5408\uff0c\u5236\u5907\u51fa\u9ad8\u6027\u80fd\u9502\u79bb\u5b50\u7535\u6c60\uff08LIBs\uff09\u8d1f\u6781\u6750\u6599\u3002\u8be5\u65b9\u6cd5\u662f\u901a\u8fc7\u4e24\u4e2a\u7b49\u7f51\u72b6\u7684Sn\u57faMOFs\u4eceSn2<\/sub>(dobdc)\u548c\u4e00\u4e2a\u5c0f\u76842, 5-\u4e8c\u6c27\u57fa-1,4-\u82ef\u4e8c\u7532\u9178\uff08H4<\/sub>dobdc\uff09\u8fde\u63a5\u4f53\u5230Sn2<\/sub>(dobpdc)\u548c\u4e00\u4e2a\u6269\u5c55\u76844, 4-\u4e8c\u6c27\u57fa\u8054\u82ef-3, 3-\u4e8c\u7532\u9178\uff08H4<\/sub>dobpdc\uff09\u8fde\u63a5\u4f53\u6765\u8bc1\u660e\u3002\u7531Sn2+<\/sup>\u79bb\u5b50\u548c\u6709\u673a\u914d\u4f53\u5f62\u6210\u7684\u914d\u4f4d\u5355\u5143\u4e0d\u4ec5\u53ef\u4ee5\u6709\u6548\u5229\u7528\u4e30\u5bcc\u7684\u6d3b\u6027\u4f4d\u70b9\uff0c\u63d0\u4f9b\u9ad8\u6bd4\u5bb9\u91cf\uff0c\u800c\u4e14\u8fd8\u53ef\u4ee5\u51cf\u7f13\u4f53\u79ef\u53d8\u5316\uff0c\u4ee5\u4fdd\u8bc1\u53ef\u9006\u53cd\u5e94\u7684\u957f\u671f\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u914d\u4f53\u7684\u5ef6\u4f38\u63d0\u9ad8\u4e86\u6d3b\u6027\u4f4d\u70b9\u7684\u5229\u7528\u7387\u548c\u6709\u5229\u7684\u53cd\u5e94\u52a8\u529b\u5b66\uff0c\u5177\u6709\u7b49\u7f51\u72b6\u5ef6\u4f38\u7684\u9aa8\u67b6\u7ed3\u6784\u3002\u5728200\u6b21\u5faa\u73af\u540e\uff0c\u5176\u4ecd\u8868\u73b0\u51fa1018 mAh g-1<\/sup>\u7684\u9ad8\u53ef\u9006\u5bb9\u91cf\u548c\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\uff0c\u4f18\u4e8e\u5176\u4ed6\u914d\u4f4d\u5316\u5408\u7269\u3002\u901a\u8fc7\u539f\u4f4d\u7c89\u672bX\u5c04\u7ebf\u884d\u5c04\uff08PXRD\uff09\u3001X\u5c04\u7ebf\u5438\u6536\u7cbe\u7ec6\u7ed3\u6784\uff08XAFS\uff09\u3001\u9ad8\u5206\u8fa8\u7387TEM\uff08HRTEM\uff09\u8868\u5f81\u3001\u975e\u539f\u4f4dFTIR\u548cXPS\u5149\u8c31\u4ee5\u53ca\u7406\u8bba\u5efa\u6a21\u7684\u7814\u7a76\uff0c\u4f5c\u8005\u8be6\u7ec6\u5206\u6790\u4e86\u8fd9\u4e9bSn\u57faMOF\u5b58\u50a8Li\u7684\u673a\u7406\uff0c\u7a81\u51fa\u4e86\u914d\u4f4d\u952e\u7684\u53ef\u9006\u5f62\u6210\u662f\u89e3\u51b3\u7c92\u5b50\u56e2\u805a\u548c\u5b9e\u73b0\u914d\u4f4d\u5316\u5408\u7269\u4e2d\u4f18\u5f02\u7684\u6d3b\u6027\u4f4d\u70b9\u5229\u7528\u7387\u7684\u6838\u5fc3\u548c\u57fa\u7840\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cReversible formation of coordination bonds in Sn-based metal-organic frameworks for high-performance lithium storage\u201d<\/strong>\u53d1\u5e03\u5728\u56fd\u9645\u8457\u540d\u671f\u520a\u00a0Nature Communications<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\u3001Sn\u57faMOFs\u4f5c\u4e3a\u8d1f\u6781\u6750\u6599\u7684\u5408\u6210\u7b56\u7565<\/strong>
\n \"\"\uff08a\uff09Sn\u57fa\u8d1f\u6781\u6750\u6599\u7684\u4e09\u79cd\u5e38\u89c4\u7b56\u7565\uff1a\u7eb3\u7c73\u5316\u3001\u5408\u91d1\u5316\u6539\u6027\u548c\u78b3\u57fa\u6d82\u5c42\uff1b<\/p>\n

\uff08b\uff09\u672c\u6587\u7b56\u7565\u4f7f\u7528\u57fa\u4e8eSn\u7684MOF\u8fdb\u884c\u53ef\u9006\u5b58\u50a8Li\uff1b<\/p>\n

\uff08c\uff09\u5408\u6210Sn2<\/sub>(dobdc)\u548cSn2<\/sub>(dobpdc)\u7684\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe\u4e8c\u3001Sn2<\/sub>(dobdc)\u548cSn2<\/sub>(dobpdc)\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong>
\n \"\"\uff08a-b\uff09Sn2<\/sub>(dobdc)\u548cSn2<\/sub>(dobpdc)\u57280.1 mV s-1<\/sup>\u5904\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

\uff08c-d\uff09Sn2<\/sub>(dobdc)\u548cSn2<\/sub>(dobpdc)\u5728\u524d\u4e94\u6b21\u5faa\u73af\u4e2d\u7684\u653e\u7535-\u5145\u7535\u66f2\u7ebf\uff1b<\/p>\n

\uff08e-f\uff09Sn2<\/sub>(dobdc)\u548cSn2<\/sub>(dobpdc)\u7684\u500d\u7387\u6027\u80fd\u548c\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n

\u56fe\u4e09\u3001Sn2<\/sub>(dobdc)\u548cSn2<\/sub>(dobpdc)\u7684\u52a8\u529b\u5b66\u5206\u6790<\/strong>
\n \"\"\uff08a-b\uff09Sn2<\/sub>(dobdc)\u548cSn2<\/sub>(dobpdc)\u7684EIS\uff1b<\/p>\n

\uff08c\uff09Sn2<\/sub>(dobdc)\u548cSn2<\/sub>(dobpdc)\u7684ln(T<\/em>\/R<\/em>ct<\/sub>)\u548c1000\/T<\/em>\u56fe\uff1b<\/p>\n

\uff08d\uff09\u4e24\u4e2aSn-MOF\u7535\u6781\u5728200\u6b21\u5faa\u73af\u540e\u7684EIS\u3002<\/p>\n

\u56fe\u56db\u3001Sn2<\/sub>(dobpdc)\u7535\u6781\u7684\u539f\u4f4dPXRD<\/strong>
\n \"\"\uff08a\uff09\u5728\u539f\u4f4d\u7535\u6c60\u4e2d\u7684\u7b2c1\u6b21\u5faa\u73af\u4e2d\uff0cSn2<\/sub>(dobpdc)\u572850 mA g-1<\/sup>\u4e0b\u7684\u653e\u7535-\u5145\u7535\u66f2\u7ebf\uff1b<\/p>\n

\uff08b\uff09\u5728\u4e0e4a\u4e2d\u7684\u8fc7\u7a0b\u76f8\u5bf9\u5e94\u7684\u4e0d\u540c\u653e\u7535-\u5145\u7535\u72b6\u6001\u4e0b\uff0c\u6536\u96c6\u7684Sn2<\/sub>(dobpdc)\u7684\u539f\u4f4dPXRD\u3002<\/p>\n

\u56fe\u4e94\u3001\u5728Sn2<\/sub>(dobpdc)\u7684\u9502\u5316-\u8131\u9502\u5faa\u73af\u671f\u95f4\uff0c\u51c6\u539f\u4f4dXAFS\u5149\u8c31\u8fdb\u884c\u7ed3\u6784\u8868\u5f81<\/strong>
\n \"\"\uff08a\uff09\u572850 mA g-1<\/sup>\u4e0b\uff0c\u7b2c\u4e8c\u6b21\u653e\u7535-\u5145\u7535\u8fc7\u7a0b\u4e2d\u7684\u8d1f\u8f7d\u66f2\u7ebf\uff0c\u5e26\u6709\u51c6\u539f\u4f4dXAFS\u6d4b\u8bd5\u7684\u6807\u8bb0\u72b6\u6001\uff1b<\/p>\n

\uff08b\uff09\u7528\u4e8e\u51c6\u539f\u4f4dXAFS\u6d4b\u8bd5\u7684\u7ebd\u6263\u7535\u6c60\u6a2a\u622a\u9762\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08c-d\uff09\u9020\u653e\u7535\u8fc7\u7a0b\u4e2d\uff0cSn K<\/em>-edge XANES\uff1b<\/p>\n

\uff08e-f\uff09Sn K<\/em>-edge k3<\/sup>\u52a0\u6743FT-EXAFS\u5149\u8c31\u62df\u5408\u5728R\u7a7a\u95f4\u4e2d\u7684\u653e\u7535-\u5145\u7535\u8fc7\u7a0b\u4e2d\u7684\u9009\u5b9a\u72b6\u6001\uff1b<\/p>\n

\uff08g\uff09\u5728\u51c6\u539f\u4f4d\u7535\u6c60\u4e2d\u4e0d\u540c\u72b6\u6001\u4e0bSn\u539f\u5b50\u5468\u56f4\u8fd1\u90bb\u7684CNs\u3002<\/p>\n

\u56fe\u516d\u3001Sn-MOF\u7684\u53cd\u5e94\u673a\u7406<\/strong><\/p>\n

\"\"<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u8bbe\u8ba1\u4e86\u4e24\u79cdSn\u57faMOFs\uff0c\u5e76\u4e14\u8be6\u7ec6\u7814\u7a76\u4e86\u5176\u5728\u5b58\u50a8Li\u4e2d\u7684\u5e94\u7528\u3002\u8fd9\u4e9b\u7b49\u7f51\u72b6Sn-MOFs\u7684\u914d\u4f4d\u4f53\u5ef6\u4f38\u4f7f\u5176\u6bd4\u5bb9\u91cf\u63d0\u9ad8\u52301018 mAh g-1<\/sup>\uff0c\u5177\u6709\u5f88\u9ad8\u7684\u500d\u7387\u6027\u80fd\u548c\u957f\u671f\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u662f\u5df2\u62a5\u9053\u7684\u914d\u5408\u7269\u4e2d\u5177\u6709\u6700\u597d\u7684\u5b58\u50a8Li\u6027\u80fd\u3002\u901a\u8fc7\u7cfb\u7edf\u5206\u6790\uff08\u5305\u62ecXAFS\uff09\u5bf9\u539f\u5b50\u7cbe\u5ea6\u548c\u7eb3\u7c73\u5c3a\u5ea6\u4e0b\u7684\u673a\u7406\u8fdb\u884c\u4e86\u8be6\u7ec6\u7684\u5206\u6790\uff0c\u63ed\u793a\u4e86\u5bf9\u5b58\u50a8Li\u914d\u4f4d\u5316\u5408\u7269\u7684\u65b0\u8ba4\u8bc6\u3002\u91d1\u5c5e\u4e2d\u5fc3\u548c\u6709\u673a\u914d\u4f53\u7684\u591a\u4e2a\u50a8Li\u4f4d\u70b9\u589e\u5f3a\u4e86\u50a8\u9502\u6027\u80fd\u03c0-\u6709\u673a\u914d\u4f53\u7684\u5171\u8f6d\u4f5c\u7528\u3002\u6700\u91cd\u8981\u7684\u662f\uff0c\u5728\u9502\u5316\u548c\u8131\u9502\u8fc7\u7a0b\u4e2d\u914d\u4f4d\u952e\u7684\u53ef\u9006\u5f62\u6210\uff0c\u5171\u540c\u8d4b\u4e88Sn-MOFs\u9ad8\u53ef\u9006\u5bb9\u91cf\u3001\u826f\u597d\u7684\u901f\u7387\u6027\u80fd\u548c\u7a33\u5b9a\u7684\u5faa\u73af\u6027\u80fd\u3002\u5728\u5206\u5b50\u6c34\u5e73\u4e0a\uff0cSn\u4e2d\u5fc3\u4e0e\u6709\u673a\u6c27\u5316\u8fd8\u539f\u914d\u4f53\u914d\u4f4d\uff0c\u6709\u6548\u5730\u6291\u5236\u4e86Sn\u9897\u7c92\u7684\u7c89\u788e\u548c\u56e2\u805a\uff0c\u4fdd\u8bc1\u4e86\u957f\u671f\u5faa\u73af\u4e2d\u7684\u5bb9\u91cf\u7a33\u5b9a\u6027\u3002\u8be5\u7814\u7a76\u7ed3\u679c\u4e3a\u914d\u5408\u7269\u5b58\u50a8Li\u7684\u673a\u7406\u63d0\u4f9b\u4e86\u65b0\u8ba4\u8bc6\uff0c\u6709\u5229\u4e8e\u9ad8\u6027\u80fd\u7535\u6781\u6750\u6599\u7684\u8bbe\u8ba1\u548c\u5236\u5907\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aReversible formation of coordination bonds in Sn-based metal-organic frameworks for high-performance lithium storage<\/a><\/strong>. Nat. Commun.<\/em>, 2021<\/strong>, DOI: 10.1038\/s41467-021-23335-1.<\/p>\n

\u672c\u6587\u7531CQR\u7f16\u8bd1\u3002<\/p>\n

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