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loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-222886\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-2-2.png\" alt=\"\" width=\"600\" height=\"518\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-2-2.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-2-2-300x259.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe2 \u540c\u6b65x\u5c04\u7ebf\u6280\u672f\u5728SSBs\u754c\u9762\u53cd\u5e94\u673a\u7406\u7814\u7a76\u4e2d\u7684\u5e94\u7528\u3002(A)\u6df1\u5ea6XPS\uff0c(B)\u591a\u79cdX\u5c04\u7ebf\u6280\u672f\uff0c(C)\u539f\u4f4d\u9ad8\u6e29XAS\u548cXPS\uff0c(D)\u539f\u4f4dXANES<\/p>\n<p>\u4e3a\u4e86\u8fdb\u4e00\u6b65\u63ed\u793aSSBs\u5728\u52a8\u6001\u8fc7\u7a0b\u4e2d\u7684\u754c\u9762\u884c\u4e3a\uff0c\u8fd8\u5efa\u7acb\u4e86\u539f\u73b0\u573a\u539f\u4f4d\u7684X\u5c04\u7ebf\u6280\u672f\u3002\u5982\u56fe2C\u6240\u793a\uff0cYildiz\u7b49\u5229\u7528\u539f\u4f4d\u540c\u6b65XRD\u3001XPS\u3001XAS\u7b49\u65b9\u6cd5\uff0c\u5bf9LLZO\u4e0eLiCoO<sub>2<\/sub>(LCO)\u754c\u9762\u5728\u9000\u706b\u6e29\u5ea6\u4e0b\u7684\u7ed3\u6784\u3001\u5316\u5b66\u548c\u7535\u8377\u8f6c\u79fb\u7535\u963b\u8fdb\u884c\u4e86\u5168\u9762\u7684\u4e86\u89e3\u3002\u9996\u5148\uff0c\u91c7\u7528\u540c\u6b65XPS\u548cXAS\u7814\u7a76\u4e86\u754c\u9762\u533a\u57df\u7684\u53cd\u5e94\u6df1\u5ea6\uff0c\u4ee5\u53ca\u7535\u6781\u548cSSEs\u5bf9\u5e94\u7684\u6c27\u5316\u72b6\u6001\u3002LCO\/LLZO\u6837\u54c1\u7684Co\u7684K\u8fb9\u3001Co\u7684L\u8fb9\u548cO\u7684K\u8fb9\u7684XAS\u5149\u8c31\u8868\u660e\uff0c\u9000\u706b\u8fc7\u7a0b\u8bf1\u53d1\u4e86Co\u5143\u7d20\u7684\u6c27\u5316\uff0c\u800cLLZO\u5728\u754c\u9762\u5904\u53d1\u751f\u5206\u89e3\u3002\u6b64\u5916\uff0c\u8be5\u7814\u7a76\u5728O<sub>2<\/sub>\u6c14\u6c1b\u52a0\u70ed\u8fc7\u7a0b\u4e2d\u8fdb\u884c\u4e86O\u7684K\u8fb9\u539f\u4f4dXAS\u548cC 1s\u7684\u539f\u4f4dXPS\uff0c\u4ee5\u63ed\u5f00\u8868\u9762\u6742\u8d28Li<sub>2<\/sub>CO<sub>3<\/sub>\u7684\u5206\u89e3\u8fc7\u7a0b\u3002\u6700\u540e\uff0c\u7ed3\u5408\u540c\u6b65XRD\u548cEXAFS\u7814\u7a76\u8868\u660e,500 \u2103\u9000\u706b\u540e\uff0c\u5728\u6df1\u5ea6\u4e3a20 nm\u5904LCO\u548cLLZO\u754c\u9762\u5f62\u6210\u4e86La-Co-O\u7684\u4e8c\u6b21\u76f8\u3002\u8fd9\u4e9b\u7ed3\u679c\u8868\u660e\uff0c\u5728\u8f83\u4f4e\u7684\u6e29\u5ea6\u3001\u8f83\u77ed\u7684\u65f6\u95f4\u5c3a\u5ea6\u548c\u65e0CO<sub>2<\/sub>\u7684\u73af\u5883\u4e2d\u5728\u9676\u74f7\u6b63\u6781-\u7535\u89e3\u8d28\u754c\u9762\u4e0a\u83b7\u5f97Li<sup>+<\/sup>\u7684\u5feb\u901f\u8f6c\u79fb\u662f\u53ef\u4ee5\u5b9e\u73b0\u7684\u3002\u5728\u57fa\u4e8e\u786b\u5316\u7269\u7535\u89e3\u8d28\u7684SSBs\u4e2d\uff0cSun\u7b49\u4eba\u5229\u7528\u539f\u4f4dXANES\u7814\u7a76\u4e86\u5404\u79cd\u8d1f\u6781\u6750\u6599\u4e0e\u786b\u5316\u7269\u4e4b\u95f4\u7684\u754c\u9762\u53cd\u5e94\u673a\u7406\u3002\u5176\u4e2d\u4e00\u9879\u7814\u7a76\u662f\u9610\u660e\u5bcc\u954d\u5c42\u72b6LiNi<sub>0.8<\/sub>Mn<sub>0.1<\/sub>Co<sub>0.1<\/sub>O<sub>2<\/sub>(NMC811)\u6b63\u6781\u4e0eLi<sub>10<\/sub>GeP<sub>2<\/sub>S<sub>12<\/sub>(LGPS)SSEs\u4e4b\u95f4\u7684\u754c\u9762\u884c\u4e3a\u3002\u4eceS\u7684\u539f\u4f4dK\u8fb9\u4e00\u9636\u5bfc\u6570\u6620\u5c04\u8c31(\u56fe2D)\u53ef\u4ee5\u770b\u51fa\uff0c\u7eafNMC811\u7684LGPS\u5728\u7535\u5316\u5b66\u8fc7\u7a0b\u4e2d\u662f\u4e0d\u7a33\u5b9a\u7684\u3002LGPSs\u5728\u521d\u59cb\u5145\u7535\u8fc7\u7a0b\u4e2d\u5448\u73b0\u4e9a\u7a33\u6001\u4e2d\u95f4\u6001\uff0c\u90e8\u5206LGPSs\u968f\u540e\u88ab\u5206\u89e3\u5f62\u6210Li<sub>2<\/sub>S\u6742\u8d28\u76f8\u3002\u6b64\u5916\uff0c\u7ed3\u5408TEM\u8868\u5f81\uff0c\u8bc1\u660e\u4e86\u5faa\u73af\u8fc7\u7a0b\u4e2dNMC811\u4ece\u8868\u9762\u5230\u5757\u4f53\u7684\u5fae\u7ed3\u6784\u9000\u5316\u6240\u5bfc\u81f4\u7684\u6b63\u6781\u9897\u7c92\u8868\u9762\u7684\u88c2\u75d5\u5fae\u7ed3\u6784\uff0c\u6b63\u6781\u8868\u9762\u8fc7\u6e21\u91d1\u5c5e\u7684\u8fd8\u539f\u548c\u6b63\u6781\u5c42\u7ed3\u6784\u5230\u5ca9\u76d0\u7ed3\u6784\u7684\u6f14\u5316\u8fc7\u7a0b\u3002\u672c\u7814\u7a76\u8fd8\u91c7\u7528\u4e86\u6b63\u6781\u539f\u5b50\u5c42\u6c89\u79ef(ALD)\u6280\u672f\uff0c\u8fdb\u4e00\u6b65\u7814\u7a76\u4e86\u6b63\u6781\u754c\u9762\u7684\u7a33\u5b9a\u6027\uff0c\u539f\u5b50\u5c42\u6c89\u79efLiNbO<sub>x<\/sub>\u6d82\u5c42\u6709\u52a9\u4e8e\u4fdd\u62a4NMC811\u6b63\u6781\u7684\u5b8c\u6574\u6027\uff0c\u5e76\u7a33\u5b9a\u4e0eLGPS\u56fa\u6001\u7535\u89e3\u8d28\u7684\u754c\u9762\u3002<\/p>\n<p><strong>\u56fa\u4f53\u6838\u78c1\u5171\u632f<\/strong><\/p>\n<p>\u6838\u78c1\u5171\u632f\u4fe1\u53f7\u6765\u6e90\u4e8e\u5916\u78c1\u573a\u4e0e\u88ab\u7814\u7a76\u6838\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u3002\u8fd9\u4e00\u539f\u7406\u4ece\u6839\u672c\u4e0a\u51b3\u5b9a\u4e86\u6838\u78c1\u5171\u632f\u53ef\u4ee5\u63a2\u6d4b\u6750\u6599\u4e2d\u7684\u6bcf\u4e2a\u539f\u5b50\u4f4d\u7f6e\u3002\u8fd1\u5e74\u6765\uff0c\u56fa\u4f53\u6838\u78c1\u5171\u632f(SS NMR)\u7531\u4e8e\u5177\u6709\u63a2\u6d4b\u7279\u5b9a\u539f\u5b50\u6838\u7684\u5c40\u90e8\u7ed3\u6784\u548c\u79bb\u5b50\u52a8\u529b\u5b66\u7684\u80fd\u529b\uff0c\u5df2\u6210\u4e3a\u5206\u6790\u539f\u5b50\u6c34\u5e73\u4e0a\u79bb\u5b50\u8fd0\u52a8\u548c\u5c40\u90e8\u7ed3\u6784\u4e0d\u53ef\u7f3a\u5c11\u7684\u8868\u5f81\u65b9\u6cd5\u3002\u901a\u8fc7\u591a\u79cd\u6838\u78c1\u5171\u632f\u65b9\u6cd5\u7684\u5e94\u7528\uff0c\u53ef\u4ee5\u83b7\u5f97\u4e30\u5bcc\u7684\u7ed3\u6784\u548c\u52a8\u6001\u4fe1\u606f\u3002\u8fd9\u4e9b\u65b9\u6cd5\u5305\u62ec(i)\u63d0\u4f9b\u56fa\u6001\u7535\u89e3\u8d28\u7684\u7cbe\u786e\u5c40\u90e8\u7ed3\u6784\u4ee5\u53ca\u754c\u9762\u7269\u79cd\u7684\u8bc6\u522b\u7684\u9b54\u672f\u89d2\u65cb\u8f6c(MAS)NMR\uff1b(ii)\u5bf9\u4e0d\u540c\u65f6\u95f4\/\u957f\u5ea6\u5c3a\u5ea6\u4e0b\u79bb\u5b50\u8fd0\u52a8\u5f88\u654f\u611f\u7684\u8109\u51b2\u573a\u68af\u5ea6(PFG)NMR\u548cNMR\u5f1b\u8c6b\u65f6\u95f4\u6d4b\u91cf\u3002\u4f8b\u5982\uff0cPFG NMR\u6280\u672f\u6d4b\u91cf\u7684\u65f6\u95f4\u5c3a\u5ea6\u4e3a10<sup>-2<\/sup>~10<sup>-1<\/sup>\u00a0s\uff0c\u5bf9\u5e94\u7684\u957f\u5ea6\u5c3a\u5ea6\u7ea6\u4e3a1 \u03bcm\u3002NMR\u5f1b\u8c6b\u7684\u65b9\u6cd5\u5305\u62ec\u81ea\u65cb\u6676\u683c\u5f1b\u8c6b(T<sub>1<\/sub>)\uff0c\u65cb\u8f6c\u81ea\u65cb\u5f1b\u8c6b(T<sub>2<\/sub>)\u548c\u81ea\u65cb\u6676\u683c\u5f1b\u8c6b\u65cb\u8f6c\u6846\u67b6(T<sub>1\u03c1<\/sub>)\uff0c\u5b83\u4eec\u5bf910<sup>-10<\/sup>~10<sup>-3<\/sup>\u00a0s\u65f6\u95f4\u5c3a\u5ea6\u5185\u7684\u5355\u4e00\u8f6c\u6362\u975e\u5e38\u654f\u611f(T<sub>1<\/sub>\uff0cT<sub>2<\/sub>\u548cT<sub>1\u03c1<\/sub>\u7684\u7279\u5b9a\u65f6\u95f4\u5c3a\u5ea6\uff0c\u89c1\u56fe3)\u3002\u6b64\u5916, \u4e0eT<sub>2<\/sub>\u8d1f\u76f8\u5173\u7684\u6838\u78c1\u5171\u632f\u4fe1\u53f7\u7ebf\u5bbd\u4e5f\u53ef\u4ee5\u7528\u4e8e\u5b9a\u6027\u5206\u6790\u6750\u6599\u4e2d\u7684\u79bb\u5b50\u8fd0\u52a8\uff1b(iii)\u53ef\u7528\u4e8e\u63a2\u7d22\u4e24\u4e2a\u4e0d\u540c\u5316\u5b66\u4f4d\u70b9\u8fd0\u8f93\u8def\u5f84\u548c\u901f\u7387\u7684\u4e8c\u7ef4\u4ea4\u6362\u5149\u8c31(2D EXSY) NMR\u3002\u8fd9\u4e24\u4e2a\u5316\u5b66\u4f4d\u70b9\u65e2\u53ef\u4ee5\u662f\u5355\u4e00\u6750\u6599\u4e5f\u53ef\u4ee5\u662f\u4e0d\u540c\u6750\u6599(\u5982\u6b63\u6781\u548c\u56fa\u6001\u7535\u89e3\u8d28)\u4e2d\u7684\u4e24\u4e2a\u9502\u4f4d\u70b9\uff0c\u53ef\u4ee5\u7814\u7a76\u79bb\u5b50\u5728SSEs\u5185\u548c\u754c\u9762\u4e0a\u7684\u4f20\u8f93\u8def\u5f84\uff1b(4)\u78c1\u5171\u632f\u6210\u50cf(MRI)\u6280\u672f\u5177\u6709\u7a7a\u95f4\u5206\u8fa8\u7387\uff0c\u53ef\u4ee5\u63d0\u4f9b\u754c\u9762\u5fae\u89c2\u7ed3\u6784\u3001\u5f62\u6001\u548c\u5143\u7d20\u5206\u5e03\u7b49\u4fe1\u606f\u3002\u56fe3\u603b\u7ed3\u4e86SS NMR\u65b9\u6cd5\u63d0\u4f9b\u7684\u5404\u79cd\u4fe1\u606f\uff0c\u5305\u62ec\u4f4d\u70b9\u5360\u7387\u3001\u79bb\u5b50\u79fb\u52a8\u3001\u754c\u9762\u4ea7\u7269\u548c\u8fd0\u8f93\u8def\u5f84\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-222887\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-3-2.png\" alt=\"\" width=\"600\" height=\"308\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-3-2.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-3-2-300x154.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe3 \u56fa\u4f53\u6838\u78c1\u65b9\u6cd5\u5728\u56fa\u4f53\u7535\u6c60\u7814\u7a76\u4e2d\u7684\u5e94\u7528\u7efc\u8ff0<\/p>\n<p>\u56e0\u6b64\uff0c\u6838\u78c1\u5171\u632f\u6280\u672f\u5982MAS, 2D-EXSY\u548cMRI\u5bf9\u4e8e\u7814\u7a76\u53d1\u751f\u590d\u6742\u548c\u77ac\u6001\u53cd\u5e94\u7684SSBs\u7684\u754c\u9762\u5316\u5b66\u548c\u7269\u7406\u6027\u8d28\u53c8\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7684\u53ef\u80fd\u3002\u5728SSBs\u4e2d\uff0c\u6b63\u6781\u6750\u6599\u7ecf\u5e38\u4e0eSSBs\u6df7\u5408\uff0c\u7136\u540e\u4f5c\u4e3a\u590d\u5408\u6b63\u6781\u8fdb\u884c\u70ed\u5904\u7406\uff0c\u4ee5\u63d0\u9ad8\u6b63\u6781\u4e0eSSBs\u4e4b\u95f4\u7684\u517c\u5bb9\u6027\u3002Grey\u548c\u540c\u4e8b\u5229\u7528<sup>31<\/sup>P MAS NMR\u7814\u7a76\u4e86LiFePO<sub>4<\/sub>\u6b63\u6781\u548cLi<sub>3+x<\/sub>P<sub>1-x<\/sub>Si<sub>x<\/sub>O<sub>4<\/sub>\u56fa\u6001\u7535\u89e3\u8d28\u6df7\u5408\u7684\u590d\u5408\u6b63\u6781\u7684\u7ec4\u6210\u3002\u7b49\u79bb\u5b50\u70e7\u7ed3(SPS)\u540e\u51fa\u73b0\u7269\u79cdLi<sub>3-z<\/sub>Fe<sub>z<\/sub>P<sub>1-z<\/sub>Si<sub>z<\/sub>O<sub>4<\/sub>\uff0c\u8fd9\u662f\u7531\u4e8eFe\u79bb\u5b50\u4eceLiFePO<sub>4<\/sub>\u5411Li<sub>3+x<\/sub>P<sub>1-x<\/sub>Si<sub>x<\/sub>O<sub>4<\/sub>\u8f6c\u79fb\u7684\u7ed3\u679c\u3002\u7ed3\u679c\u8868\u660e\uff0c\u70ed\u5904\u7406\u4f1a\u7531\u4e8e\u79bb\u5b50\u8fc1\u79fb\u800c\u5f71\u54cd\u590d\u5408\u6b63\u6781\u7684\u6210\u5206\u3002\u9664\u4e86\u6210\u5206\u5916\uff0c\u70ed\u5904\u7406\u4e5f\u5f71\u54cd\u4e86Li\u79bb\u5b50\u5728\u6b63\u6781\/SSE\u754c\u9762\u7684\u8fd0\u8f93\u6027\u80fd\u3002Yu\u548c\u540c\u4e8b\u5229\u7528<sup>7<\/sup>Li\u76842D EXSY\u5b9a\u91cf\u5730\u8bc1\u660e\u4e0d\u540c\u5236\u5907\u6761\u4ef6\u4e0bLi<sub>2<\/sub>S\u6b63\u6781\u4e0eLi<sub>6<\/sub>PS<sub>5<\/sub>Br SSE\u754c\u9762\u7684\u8fd0\u8f93\u901f\u7387\u3002\u5982\u56fe4\u6240\u793a\uff0c\u6837\u54c1\u7684\u5236\u5907\uff0c\u4f8b\u5982\u7eb3\u7c73\u5316\u548c\u7403\u78e8\u5904\u7406\u4f1a\u52a0\u5febLi\u79bb\u5b50\u5728\u6b63\u6781\/SSEs\u754c\u9762\u5904\u7684\u81ea\u53d1\u4ea4\u6362\u3002\u7136\u800c\uff0c\u7535\u5316\u5b66\u5faa\u73af\u4f1a\u7834\u574f\u8fd9\u79cd\u4ea4\u6362\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u8fd9\u4e24\u9879\u5de5\u4f5c\u4e3b\u8981\u96c6\u4e2d\u5728\u5236\u5907\u8fc7\u7a0b\u4e2d\u7684\u754c\u9762\u95ee\u9898\uff0c\u800c\u4e0d\u662f\u7535\u5316\u5b66\u5faa\u73af\u8fc7\u7a0b\u3002\u5728\u4e0d\u4e45\u7684\u5c06\u6765\uff0c\u539f\u4f4d\u6838\u78c1\u5171\u632f\u6280\u672f\u6709\u671b\u5728\u7814\u7a76\u5de5\u4f5c\u6761\u4ef6\u4e0b\u7684\u79bb\u5b50\u4f20\u8f93\u8fc7\u7a0b\u4e2d\u53d1\u6325\u4f5c\u7528\u3002<\/p>\n<p>\u5728SSBs\u4e2d\uff0c\u8d1f\u6781\/SSEs\u754c\u9762\u4e3b\u8981\u5206\u4e3a\u4e09\u4e2d\u7c7b\u578b\uff0c(i)\u52a8\u6001\u7a33\u5b9a\u7684\u754c\u9762\uff0c\u5982Li\/LLZO\uff1b(ii)\u8fde\u7eed\u53cd\u5e94\u754c\u9762\uff0c\u5982Li\/LGPS\uff1b(iii)\u81ea\u9650\u53cd\u5e94\u754c\u9762\uff0c\u5982Li\/Li<sub>3<\/sub>ClO\u3002\u5bf9\u4e8e\u52a8\u6001\u7a33\u5b9a\u7684\u754c\u9762\uff0c\u4e3b\u8981\u7684\u95ee\u9898\u662fLi\u679d\u6676\u7684\u751f\u957f\u3002\u7531\u4e8e\u5757\u72b6\u91d1\u5c5e\u9502\u548c\u679d\u6676\u91d1\u5c5e\u9502\u7684\u5316\u5b66\u4f4d\u79fb\u4e0d\u540c\uff0cAguesse\u7b49\u4eba\u5229\u7528\u9759\u6001\u56fa\u4f53\u6838\u78c1\u5171\u632f\u6280\u672f\u89c2\u5bdf\u4e86Li<sub>7<\/sub>La<sub>3<\/sub>Zr<sub>2<\/sub>O<sub>12<\/sub>\u4e2dLi\u679d\u6676\u7684\u4fe1\u53f7\u3002\u6700\u8fd1\uff0c\u5982\u56fe4b\u6240\u793a\uff0cGrey\u548c\u540c\u4e8b\u5229\u7528\u4e00\u7ef4\u539f\u4f4d<sup>7<\/sup>Li MRI\u76d1\u6d4b\u4e86Li<sub>7<\/sub>La<sub>3<\/sub>Zr<sub>2<\/sub>O<sub>12<\/sub>\u4e2dLi\u679d\u6676\u7684\u751f\u957f\u3002\u901a\u8fc7\u539f\u4f4dMRI\u7814\u7a76\u754c\u9762\u7684\u52a8\u6001\u6f14\u53d8\uff0c\u5b8c\u5168\u53ef\u4ee5\u89c2\u5bdf\u5230Li\u679d\u6676\u4ece\u8868\u9762\u751f\u957f\u5f00\u59cb\u5230\u8fde\u63a5\u4e24\u7535\u6781\u7684\u6574\u4e2a\u8fc7\u7a0b\u3002\u8be5\u65b9\u6cd5\u53ef\u8fdb\u4e00\u6b65\u63a2\u7d22Li\u679d\u6676\u7684\u751f\u957f\u901f\u7387\u4e0e\u7535\u6d41\u5bc6\u5ea6\u3001SSE\u9897\u7c92\u539a\u5ea6\u7684\u5173\u7cfb\uff0c\u6709\u671b\u63ed\u793a\u5f71\u54cdLi\u679d\u6676\u5f62\u6210\u548c\u751f\u957f\u7684\u5173\u952e\u56e0\u7d20\u3002\u5bf9\u4e8e\u8fde\u7eed\u53cd\u5e94\u7684\u754c\u9762\uff0c\u4e3b\u8981\u7684\u95ee\u9898\u662f\u754c\u9762\u963b\u6297\u7684\u4e0d\u65ad\u589e\u52a0\u3002Hu\u7b49\u501f\u52a93D MRI\u6280\u672f\uff0c\u5bf9Li\/LGPS\u754c\u9762\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7684\u5206\u5e03\u8fdb\u884c\u4e86\u76d1\u6d4b\uff0c\u5982\u56fe4c\u6240\u793a\u3002\u7136\u800c\uff0cPEO\u6d82\u5c42\u7684LGPS\u53ef\u4ee5\u7ef4\u6301\u5206\u5e03\u76f8\u5bf9\u5747\u5300\u7684Li\u79bb\u5b50\uff0c\u4ece\u800c\u5b9e\u73b0\u8f83\u5c0f\u7684\u754c\u9762\u963b\u6297\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u76ee\u524dMRI\u7684\u65f6\u7a7a\u5206\u8fa8\u7387\u8fd8\u6709\u5f85\u8fdb\u4e00\u6b65\u63d0\u9ad8\uff0c\u8fd9\u9700\u8981\u66f4\u5927\u7684\u78c1\u573a\u68af\u5ea6\u6216\u66f4\u5148\u8fdb\u7684\u6838\u78c1\u5171\u632f\u8109\u51b2\u6280\u672f\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-222888\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-4-3.png\" alt=\"\" width=\"600\" height=\"366\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-4-3.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-4-3-300x183.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe4 SS NMR\u6280\u672f\u5728\u754c\u9762\u8fc1\u79fb\u548c\u5f62\u6001\u6f14\u5316\u7814\u7a76\u4e2d\u7684\u5e94\u7528\u3002(a)2D\u4ea4\u6362\u5149\u8c31\u5b66\uff0c(b)\u4e00\u7ef4\u78c1\u5171\u632f\u56fe\u8c61\uff0c(c)\u4e09\u7ef4\u78c1\u5171\u632f\u56fe\u8c61<\/p>\n<p><strong>\u4e2d\u5b50\u6563\u5c04\u6280\u672f<\/strong><\/p>\n<p>\u88681 \u70ed\u4e2d\u5b50(E = 25.30 meV)\u5bf9\u7535\u6c60\u6750\u6599\u4e2d\u5e38\u89c1\u5143\u7d20\u7684\u6563\u5c04\u957f\u5ea6\u548c\u6563\u5c04\u622a\u9762<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-222889\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-5-3.png\" alt=\"\" width=\"600\" height=\"617\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-5-3.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-5-3-292x300.png 292w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u8fd1\u5341\u5e74\u6765\uff0c\u4e2d\u5b50\u6563\u5c04\u4f5c\u4e3a\u7814\u7a76\u6750\u6599\u548c\u7535\u6c60\u7cfb\u7edf\u7684\u6709\u529b\u5de5\u5177\u53d7\u5230\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\u30022006\u5e74\u6a61\u6811\u5cad\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u5bf9\u6563\u88c2\u4e2d\u5b50\u6e90(SNS)\u7684\u8c03\u8bd5\u8fdb\u4e00\u6b65\u63a8\u52a8\u4e86\u4e2d\u5b50\u6563\u5c04\u7684\u5e94\u7528\u3002\u76ee\u524d\uff0cSNS\u5df2\u6210\u4e3a\u4e16\u754c\u4e0a\u62e5\u6709\u5927\u91cf\u4eea\u5668\u8bbe\u5907\u7684\u6700\u5f3a\u5927\u8109\u51b2\u4e2d\u5b50\u6e90\u5b9e\u9a8c\u5ba4\u3002\u5b83\u4e0e\u4e16\u754c\u4e0a\u5176\u4ed6\u4e2d\u5b50\u6563\u5c04\u8bbe\u5907\u4e00\u8d77\uff0c\u4e3a\u6750\u6599\u7814\u7a76\u63d0\u4f9b\u4e86\u5de8\u5927\u7684\u673a\u9047\u3002\u4e0e\u5176\u4ed6\u8868\u5f81\u6280\u672f\u76f8\u6bd4\uff0c\u4e2d\u5b50\u6563\u5c04\u6709\u5176\u72ec\u7279\u7684\u4f18\u70b9\uff0c\u5176\u4e2d\u4e00\u4e9b\u5bf9\u7535\u6c60\u6750\u6599\u7684\u7814\u7a76\u5177\u6709\u91cd\u8981\u7684\u73b0\u5b9e\u610f\u4e49\u3002\u9996\u5148\uff0c\u4e2d\u5b50\u76f4\u63a5\u4e0e\u539f\u5b50\u6838\u76f8\u4e92\u4f5c\u7528\uff0c\u800c\u4e14\u5b83\u4eec\u4e00\u822c\u4e0d\u4e0e(\u6210\u5bf9\u7684)\u7535\u5b50\u76f8\u4e92\u4f5c\u7528\u3002\u663e\u7136\uff0c\u4e2d\u5b50\u53ef\u4ee5\u975e\u5e38\u6df1\u5165\u5730\u6e17\u5165\u6750\u6599\uff0c\u800c\u4e14\u4e2d\u5b50\u6563\u5c04\u901a\u5e38\u88ab\u8ba4\u4e3a\u662f\u4e00\u79cd\u5757\u4f53\u548c\u975e\u7834\u574f\u6027\u7684\u63a2\u9488\uff0c\u8fd9\u4e00\u7279\u5f81\u5c06\u6781\u5927\u5730\u6709\u5229\u4e8e\u539f\u4f4d\u548c\/\u6216\u73b0\u573a\u64cd\u4f5c\u7814\u7a76\u3002\u5176\u6b21\uff0c\u539f\u5b50\u6838\u7684\u4e2d\u5b50\u6563\u5c04\u957f\u5ea6\u6216\u622a\u9762\u662f\u7531\u5176\u539f\u5b50\u5e8f\u6570\u548c\u540c\u4f4d\u7d20\u51b3\u5b9a\u7684(\u89c1\u88681)\u3002\u5b83\u5728\u5468\u671f\u8868\u4e2d\u7684\u503c\u4e0ex\u5c04\u7ebf\u6563\u5c04\u622a\u9762\u7684\u660e\u663e\u8d8b\u52bf\u76f8\u6bd4\u4f3c\u4e4e\u662f\u76f8\u5f53\u968f\u673a\u7684\uff1a\u540e\u8005\u53ea\u662f\u7b80\u5355\u5730\u4e0e\u539f\u5b50\u5e8f\u6570\u6216\u7535\u5b50\u5bc6\u5ea6\u6210\u6bd4\u4f8b\u3002\u7ed3\u679c\u8868\u660e\uff0c\u4e00\u4e9b\u8f7b\u5143\u7d20\u5982H\u3001Li\u3001O\u3001N\u7b49\u5177\u6709\u8f83\u9ad8\u7684\u4e2d\u5b50\u6563\u5c04\u622a\u9762\uff0c\u751a\u81f3\u6bd4\u4e00\u4e9b\u91cd\u5143\u7d20\u7684\u6563\u5c04\u622a\u9762\u8fd8\u8981\u9ad8\u3002\u8fd9\u8ba9\u6211\u4eec\u53ef\u4ee5\u76f4\u63a5\u786e\u5b9a\u8fd9\u4e9b\u8f7b\u5143\u7d20\u5728\u6676\u4f53\u7ed3\u6784\u4e2d\u7684\u5750\u6807\uff0c\u4e5f\u8ba9\u6211\u4eec\u53ef\u4ee5\u4ece\u91cd\u5143\u7d20\u7684\u80cc\u666f\u4e2d\u83b7\u5f97\u8f7b\u5143\u7d20\u7684\u56fe\u50cf(\u4e0ex\u5c04\u7ebf\u6210\u50cf\u76f8\u53cd)\u3002\u6b64\u5916\uff0c\u76f8\u90bb\u5143\u7d20\u548c\u4e0d\u540c\u540c\u4f4d\u7d20\u7684\u540c\u4e00\u5143\u7d20\u4e4b\u95f4\u7684\u4e2d\u5b50\u6563\u5c04\u957f\u5ea6\u53ef\u80fd\u6709\u5f88\u5927\u5dee\u5f02\uff0c\u8fd9\u5bf9\u533a\u5206\u90bb\u8fd1\u8fc7\u6e21\u91d1\u5c5e\u3001\u7814\u7a76\u63ba\u6742\u6548\u5e94\u548c\u63a2\u7d22\u540c\u4f4d\u7d20\u6807\u8bb0\u975e\u5e38\u6709\u76ca\u3002\u7b2c\u4e09\uff0c\u4e2d\u5b50\u4e0d\u4ec5\u5177\u6709\u53ef\u4e0e\u539f\u5b50\u95f4\u8ddd\u79bb\u76f8\u6bd4\u8f83\u7684\u6ce2\u957f\uff0c\u800c\u4e14\u5b83\u4eec\u7684\u80fd\u91cf\u548c\u52a8\u91cf\u4e5f\u53ef\u4e0e\u632f\u52a8\u548c\u6269\u6563\u7684\u57fa\u672c\u6fc0\u53d1\u76f8\u6bd4\u8f83\u3002\u56e0\u6b64\uff0c\u4e0e\u4f7f\u7528\u5149\u5b50\u7684\u5149\u5b66\u63a2\u6d4b\u5668\u76f8\u6bd4\uff0c\u4e2d\u5b50\u662f\u7814\u7a76\u58f0\u5b50\u548c\u8f93\u8fd0\u7279\u6027\u7684\u7406\u60f3\u7c92\u5b50\u3002\u88682\u63d0\u4f9b\u4e86\u4e2d\u5b50\u6563\u5c04\u6280\u672f\u7684\u5217\u8868\u4ee5\u53ca\u6bcf\u79cd\u6280\u672f\u7684\u7b80\u8981\u63cf\u8ff0\u3002<\/p>\n<p>\u88682 \u4e2d\u5b50\u6563\u5c04\u6280\u672f\u53ca\u5176\u5e94\u7528<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-222890\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-6-3.png\" alt=\"\" width=\"600\" height=\"501\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-6-3.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-6-3-300x251.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" 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Xiang et al.,\u00a0Advanced characterization techniques for solid state lithium battery research. 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